CA2219385C - Polyester fiber with improved abrasion resistance - Google Patents
Polyester fiber with improved abrasion resistance Download PDFInfo
- Publication number
- CA2219385C CA2219385C CA 2219385 CA2219385A CA2219385C CA 2219385 C CA2219385 C CA 2219385C CA 2219385 CA2219385 CA 2219385 CA 2219385 A CA2219385 A CA 2219385A CA 2219385 C CA2219385 C CA 2219385C
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- CA
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- Prior art keywords
- lcp
- pet
- abrasion resistance
- monofilaments
- papermaking
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F1/00—Wet end of machines for making continuous webs of paper
- D21F1/0027—Screen-cloths
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D1/00—Woven fabrics designed to make specified articles
- D03D1/0035—Protective fabrics
- D03D1/0041—Cut or abrasion resistant
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
- D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/573—Tensile strength
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S162/00—Paper making and fiber liberation
- Y10S162/902—Woven fabric for papermaking drier section
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3146—Strand material is composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3976—Including strand which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous composition, water solubility, heat shrinkability, etc.]
Abstract
Papermaking fabrics comprising monofilaments of blended polyethylene terephthalate (PET) and liquid crystalline polymer (LCP). The monofilaments are particularly useful in forming and dryer fabrics. The papermaking fabrics have significantly improved abrasion resistance characteristics over fabrics comprising monofilaments of pure PET.
Description
CA 0221938~ 1997-10-24 POLYESTER FIBER WITH IMPROVED ABRASION RESISTANCE
BACRGROUND OF THE I~v~NllON
The present invention relates to monofilaments which contain a polymer of polyethylene terephthalate (PET) and liquid crystalline polymer (LCP). These monofilaments have improved abrasion resistance and are suited for use in papermaking fabrics. The monofilaments are particularly suitable for use in papermaking fabrics used in the forming and dryer sections.
Field of the Invention Papermaking machines use fabrics which may be forming fabrics, press felts or dryer fabrics according to the function performed in the papermaking process. The design and composition of papermaking fabrics used on each section of the papermaking machines varies in accordance with function.
The papermaking process starts in the forming section of the papermaking machine where aqueous pulp slurry is deposited onto a forming fabric having desired characteristics for retaining the fibers while allowing the water to pass through to the fabric. The aqueous paper web created by this process is then transferred to and carried by a press felt through the press section where additional water is removed by conveying the paper web through one or more press nips. The paper web is then transferred to and carried through the drying section of the dryer fabric to remove additional water through forced evaporation.
CA 0221938~ 1997-10-24 Monofilament fabrics must withstand the adverse environment in the papermaking process. In the forming section of the papermaking process, the fabrics are subjected to changes in temperature, compression and elongation forces, and abrasive chemicals. In the dryer section of the papermaking process, the fabrics must withstand moist and dry heat. The forming and dryer fabrics are in contact with the aqueous paper sheet on one side and the papermaking machine on the other side. Accordingly, forming and dryer fabrics desirably must possess several characteristics to function properly in this environment.
Forming fabrics must have a mesh weave that is fine enough to separate the fiber from the slurry yet avoid marking the paper. The forming fabric must also be open enough to have good drainage for the initial water removal that facilitates paper formation and it must be resistant to degradation resulting from exposure to chemicals in the paper furnish in the forming section of the papermaking machines. Furthermore, the forming fabric must withstand high tensile loads in the machine direction and compressive buckling loads in the cross-machine direction.
Dryer fabrics must have enough permeability to allow the passage of vapor through the fabric. The fabric must be resistant to degradation from moist and dry heat.
Additionally, the dryer fabric must permit uniform and measured drying of the paper sheet.
Forming fabrics and dryer fabrics must be abrasion resistant to withstand both the continuous papermaking CA 0221938~ 1997-10-24 machine and paper sheet contact during the papermaking process. They must be structurally stable to support the paper sheet while stress forces are placed on it during use.
The fabrics must resist stretch under the tension imposed by the powered rolls which drive the fabric.
Description of the Prior Art Prominent monofilaments used in papermaking forming fabrics include polyester, particularly polyethylene terephthalate (PET). It is known in the art to blend these PET polymers with other polymers, such as polyethylene or polybutylene terephthalate, to vary the characteristics of the resulting monofilaments.
Polyethylene terephthalate (PET), an aliphatic-aromatic polymer, is known to exhibit good chemical and dimensional stability, acceptable weaving characteristics, such as tensile strength and loop strength, low moisture gain, good crimpability and heat setting properties. However, PET
monofilaments do not have good abrasion resistance, especially at higher speeds, and are known to degrade when exposed to harsh chemical environments for significant periods of time. Stabilizing additives and stabilization techniques may extend the useful life of the PET for a relatively short period of time. Typically, the PET
monofilaments degrade and require replacement in about thirty to sixty days.
Liquid Crystalline Polymers (LCP) are polymers which retain a high degree of crystalline order when in a melt CA 0221938~ 1997-10-24 phase. LCPs are composed of long and slender molecules and readily orient in the direction of material flow. As the LCP solidifies, the molecule orientation is maintained.
P-hydroxy benzoic acid is a known copolymer in certain LCP compositions. Additionally, p-hydroxy benzoic acid and similar compounds are disclosed as a copolymer in several patents. U.S. Patent No. 4,663,423 (Yamada et al.) discloses p-hydroxy benzoic acid as a copolymer with terephthalic acid. U.S. Patent No. 4,666,764 (Kobayashi et al.) discloses a water-repellent anti-static fabric composed of terephthalic acid and naphthalene-dicarboxylic acid or hydroxyethoxy benzoic acid and p-hydroxy benzoic acid copolymer. U.S. Patent No. 4,975,326 (Buyalos et al.) discloses PET with minor amounts of bibenzoic acid copolymer.
Mixtures of PET with LCP are discussed in Nonisothermal Elonqational Behavior of Blends with Liquid Crystalline Polymers, Polymer Engineering and Science, May 1994, Vol.
34, No. 10, pp. 799-803. Although the article discusses a broad range of proportions in PET/LCP blends, it is silent about abrasion resistance or defined proportions of LCP
which are operable in papermaking fabrics.
Although these references disclose various combinations of chemical compositions, they do not recognize the advantages of using a LCP based polymer as a blend with PET
for making monofilaments used in papermaking fabrics.
CA 0221938~ 1997-10-24 SUMMARY OF THE lNV~NllON
The present invention concerns PET/LCP blended monofilaments which are particularly suitable for use in papermaking machine fabrics. The monofilaments of PET
blended with LCP provide improved abrasion resistance. This is a particularly desirable characteristic for monofilaments used in papermaking forming and dryer fabrics.
The monofilaments of the present invention can be woven into papermaking fabrics according to conventional weaving techniques. The type and density of the weave will depend on the type of paper and papermaking operation for which the fabric is to be used. The PET/LCP based monofilaments may be interwoven with monofilaments containing other chemical compositions.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is a graph showing abrasion resistance improvements of PET with increased amounts of LCP according to the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
This invention relates to monofilaments which contain blended polyethylene terephthalate and liquid crystalline polymer. The high degree of crystalline orientation of the LCP is believed to enhance the abrasion resistance in blends with PET. Acceptable LCPs must have a temperature range compatible with PET and be extrudable. In the preferred embodiment, the LCP component of these monofilament blends CA 0221938~ 1997-10-24 is made from 6-hydroxy-2-naphthoic acid and p-hydroxy benzoic acid.
Fig. 1 shows increased fabric abrasion resistance of PET as it is blended with increasing amounts of LCP. As seen in Fig. 1, monofilaments of pure PET have an abrasion resistance of 2000 cycles per break. With a blend of 97.5%
PET and 2. 5% LCP, the abrasion resistance is 4214. When PET
is blended with LCP in a proportion of 95%/5%, the abrasion resistance is 4950. Abrasion resistance of PET
significantly improves with blended amounts of 1-10% LCP.
The following examples 1-16 use varying amounts of blended PET and LCP manufactured according to the parameters listed in tables 1-4. The particular grades of PET and LCP
within these tests were grouped for comparison as examples 1-5, 6-9, 10-12, and 13-16.
Examples 1-5 In examples 1-5, monofilaments of PET blended with varying amounts of LCP were compared. The PET was a low molecular weight PET resin of IV=0.74, made by Hoechst-Celanese, under the trade name T-26. The PET was mixed with 0, 5, 5, 10 and 25 percent weight of LCP. The LCP was made by Hoechst-Celanese, under the trademark VECTRATM A950. The LCP was composed of 73 mole percent of p-hydroxy benzoic acid and 27 mole percent of 6-hydroxy-2-naphthoic acid. The formed monofilaments were 0.25 to 0.3 mm in diameter. The monofilaments were tested for abrasion resistance and/or breaking strength.
CA 0221938~ 1997-10-24 Example 1 Monofilaments of pure polyethylene terephthalate were prepared in accordance with the specified parameters of Table 1. The abrasion resistance was 3831 and 3270 cycles per break.
Example 2 A monofilament was produced by blending 95%
polyethylene terephthalate and 5% liquid crystalline polymer in accordance with the specified parameters of Table 1. The monofilament was extremely brittle and abrasion resistance testing was not performed. The breaking strength of the monofilament was 2.951 grams per denier.
CA 0221938~ 1997-10-24 Table 1 Example 1 2 3 4 5 Pump (cm3/min.) 110 110 110 110 110 Barrel Zone 1 (~F) 551.1 549.1 549.8 549.8 549.8 Barrel Zone 2 (~F) 550.4 549.1 549.8 549.8 549.8 Barrel Zone 3 (~F) 550.4 549.8 549.8 549.1 549.1 Barrel Zone 4 (~F) 551.8 549.1 549.8 550.4 549.8 Flange (~F) 553.1 547.7 549.1 550.4 549.8 Spinhead 6 (~F) 551.8 549.1 551.8 550.4 549.8 Spinhead 7 (~F) 550.4 549.8 550.4 550.4 549.8 Spinhead 8 (~F) 552.4 552.4 551.1 549.8 549.8 Spinhead 9 (~F) 550.4 549.1 548.4 546.4 544.4 Spinhead 10 (~F) 551.1 549.8 549.8 549.8 549.1 Godet 1 (fpm) 43 43 43 40 37.5 Godet 2 (fpm) 193 172 172 172 172 Godet 3 (fpm) 216 200 200 200 200 Godet 4 (fpm) 183.8 172 184 184 184 Oven 1 (~F) 241.5 300.1 299.6 320.2 320.2 Oven 2 (~F) 380.3 375.6 374.5 374.5 375.1 Oven 3 (~F) 459 449.5 424.7 424.7 425.7 Pump A 57.3 60.9 57.3 56 58.5 Pump S (cm3/min.) 109.9 109.9 109.9 109.9 109.9 Extruder (Amp) 38 38.8 35.9 37.1 37.6 Screw speed 42.9 42.9 45.0 42.6 43.7 Pressure 1 (psi) 2316 2409 2546 2414 2448 Pressure 2 (psi) 997 987 987 1006 992 Pressure 4 (psi) 219 215 210 215 215 Quench Bath (~F) 150.6 149.7 149.8 150 149.8 Air Gap 2" 2" 2" 2" 2"
Melt (~F) -- -- 568.6 567.3 566.6 LCP (~ weight) 0 5 5 10 25 Abrasions 3831/ -- 1948/ 1924/ --(cycles/break) 3270 1956 1973 Example 3 A monofilament was produced by blending 95~
polyethylene terephthalate and 5~ liquid crystalline polymer in accordance with the specified parameters of Table 1. The breaking strength was 3.183 grams per denier. The abrasion resistance was 1948 and 1956 cycles per break.
CA 022l938~ l997-l0-24 Example 4 A monofilament was produced by blending 90~
polyethylene terephthalate and 10~ liquid crystalline polymer in accordance with the specified parameters of Table 1. Breaking strength was 3.796 grams per denier. The abrasion resistance was 1924 and 1973 cycles per break.
Example 5 A monofilament was produced by blending 75~
polyethylene terephthalate and 25% liquid crystalline polymer in accordance with the specified parameters of Table 1. The monofilament broke before abrasion resistance measurements were performed.
Examples 1- 5 used a lower molecular weight PET (IV
0.74). The breaking strength of the monofilament of example 2 was low at 2.951 grams per denier. In example 3, the abrasion resistance of 1948 and 1956 cycles per break was significantly less than pure PET monofilaments with an abrasion resistance of 3831 and 3270 cycles per break. The breaking strength in example 3 also was low at 3.183 grams per denier. In example 4, the abrasion resistance of 1924 and 1973 cycles per break was significantly less than pure PET monofilaments. Although the breaking strength was higher for the monofilament of example 4 than the monofilament of example 3, it was low at 3.796 grams per denier. These runs show no significant improvement in mechanical properties or abrasion resistance of the blended PET/LCP monofilaments over 100~ PET monofilaments.
CA 0221938~ 1997-10-24 Examples 6-9 In examples 6-9, additional monofilaments of PET
blended with varying amounts of LCP were compared. The PET
was a higher molecular weight PET resin than for examples 1-5, with an IV = 0.95 (m.w. = 26,336), made by Shell, under the trademark VITUFTM 9501. The PET was mixed with 0, 5, 5 and 10 percent weight of LCP. The LCP was produced by Hoechst-Celanese, under the trademark VECTRATM A950. Several abrasion resistance measurements were made for the formed monofilaments, which were averaged for the measurements listed in examples 6-9. The monofilaments were 0. 25 to 0. 3 mm in diameter.
Example 6 A monofilament of pure polyethylene terephthalate was produced in accordance with the parameters set forth in Table 2. The abrasion resistance averaged 2163.
Example 7 A monofilament of 95~ PET was mixed with 5~ LCP in accordance with the parameters set forth in Table 2. The abrasion resistance averaged 5290. The breaking strength was 5.086 grams per denier.
Example 8 A monofilament of 95~ PET was mixed with 5~ LCP in accordance with the parameters set forth in Table 2. The abrasion resistance averaged 4789.
CA 0221938~ 1997-10-24 Example 9 A monofilament of 90~ PET was mixed with 10~ LCP in accordance with the parameters set forth in Table 2. The monofilament broke easily and no abrasion resistance measurements were obtained.
Table 2 Example 6 7 8 9 Pump (cm3/min.) 70 70 70 70 Barrel Zone 1 (~F) 561.2 559.8 559.8 559.8 Barrel Zone 2 (~F) 575.3 574.6 575.3 575.3 Barrel Zone 3 (~F) 549.8 550.4 549.8 550.4 Barrel Zone 4 (~F) 541.0 538.3 538.3 541.0 Flange (~F) 580.7 578.0 578.9 578.0 Spinhead 6 (~F) 539.7 540.3 540.3 540.3 Spinhead 7 (~F) 540.3 539.7 539.7 540.3 Spinhead 8 (~F) 574.6 574.6 574.6 574.6 Spinhead 9 (~F) 574.6 574.6 574.6 574.6 Spinhead 10 (~F) 574.0 574.6 574.0 574.6 Godet 1 (fpm) 40 40 45 45 Godet 2 (fpm) 172 172 172 170 Godet 3 (fpm) 200 200 200 121 Godet 4 (fpm) 184 184 184 120 Oven 1 (~F) 248.4 249.4 249.4 300.1 Oven 2 (~F) 369.8 379.3 379.3 380.3 Oven 3 (~F) 444.7 449.5 450.5 449.0 Pump A 53.6 52.4 52.4 59.7 Pump S (cm3/min.) 69.9 69.9 69.9 69.9 Extruder (Amp) 41.2 40 43.7 41.6 Screw speed 21.2 23.5 24.0 25.7 Pressure 1 (psi) 1788 1520 1475 1127 Pressure 2 (psi) 1480 1285 1275 941 Pressure 4 (psi) 78 73 68 53 Quench Bath (~F) 139.6 152.3 151.1 151.0 Air Gap ln 1" 1" 1"
Melt (~F) 602 605.6 605.6 609.6 LCP (~ weight) 0 5 5 10 Abrasions (cycles/break) 2163 5290 4789 CA 0221938~ 1997-10-24 Examples 6-9 used a high molecular weight PET, PET-9501 resin, with 0, 5, 5, and 10 percent weight LCP. At 0~ LCP, the abrasion resistance was 2163 cycles per break. When LCP
was blended at 5~, the abrasion resistance was 5290 and 4789 cycles per break. However, at 10~ LCP, the monofilaments became extremely brittle. Significant improvement was seen in the mechanical properties and abrasion resistance in monofilaments of 1-10~ LCP blended with high molecular weight PET.
Examples 10-12 In examples 10-12, additional monofilaments of PET
blended with varying amounts of LCP were compared. The PET
was made by Shell, under the trademark VITUFTM 9501. The PET
was mixed with 2, 4, and 6 percent weight of LCP. The LCP
was produced by Hoechst-Celanese, under the trademark VECTRATM A950. The resulting monofilaments were tested for abrasion resistance. The monofilaments were approximately 0.4 mm in diameter.
Example 10 98~ polyethylene terephthalate was blended with 2 liquid crystalline polymer in accordance with the parameters set forth in Table 3. The abrasion resistance averaged 2642 cycles per break.
CA 0221938~ 1997-10-24 Example 11 96% polyethylene terephthalate was blended with 4%
liquid crystalline polymer in accordance with the parameters set forth in Table 3. The abrasion resistance averaged 3186 cycles per break.
Example 12 94% polyethylene terephthalate was blended with 6%
liquid crystalline polymer in accordance with the parameters set forth in Table 3. The abrasion resistance averaged 3176 cycles per break.
In addition to examples 10-12, the PET was extruded into a monofilament with 0 percent weight LCP. Abrasion resistance averaged 2063.
Examples 10-12 were run at 98/2, 96/4 and 94/6 percent weight PET/LCP blended compositions. At 2% LCP, the abrasion resistance averaged 2642. At 4% LCP, the abrasion resistance was 3186 and at 6% LCP the abrasion resistance was 3176. The pure PET monofilament had an abrasion resistance average of 2063. The abrasion resistance improved significantly with the addition of LCP, but formed a plateau at 4%-6% LCP.
Examples 13-16 Examples 13-16 compare blended monofilaments of PET
with varying amounts of LCP and a fluoropolymer. The PET
was made by Shell, under the trademark VITUFTM 9501. The LCP
was produced by Hoechst-Celanese, under the trademark CA 0221938~ 1997-10-24 VECTRATM A950. The fluoropolymer was a pellet ethylene tetrafluoroethylene copolymer sold under the trademark TEFZELTM210, produced by E.I. duPont de Nemours & Co., of Wilmington, Delaware. The monofilaments were formed from blends of PET/fluoropolymer/LCP in proportions of 100/0/0, 95/5/0, 93/5/2 and 91/5/4 percent weight.
Table 3 Example 10 11 12 Pump (cm3/min.) 75 75 75 Barrel Zone 1 (~F) 559.2 560.5 559.8 Barrel Zone 2 (~F) 574.0 574.6 574.6 Barrel Zone 3 (~F) 549.8 549.8 549.8 Barrel Zone 4 (~F) 540.3 540.3 538.3 Spinhead 6 (~F) 549.8 549.8 550.4 Spinhead 7 (~F) 550.4 548.4 549.8 Spinhead 8 (~F) 574.6 574 574.6 Spinhead 9 (~F) 547.6 574.6 574.6 Spinhead 10 (~F) 575.3 574.6 574.6 Godet 1 (fpm) 40 40 47.5 Godet 2 (fpm) 172 172 172 Godet 3 (fpm) 200 200 200 Godet 4 (fpm) 184 184 184 Oven 1 (~F) 249.4 249.4 249.4 Oven 2 (~F) 379.3 379.3 380.3 Oven 3 (~F) 450 449.5 449.0 Pump A 52.4 51.2 59.7 Pump S (cm3/min.) 75.0 75 75 Extruder (Amp) 38.8 40.4 38.8 Screw speed 24.0 24.3 26.2 Pressure 1 (psi) 1837 1568 1901 Pressure 2 (psi) 679 576 1055 Pressure 4 (psi) 39 39 0 Quench Bath (~F) 140.2 150.6 150 Air Gap 1" 1" 1"
LCP (~ weight) 2 4 6 Abrasions (cycles/break) 2642 3186 3176 CA 0221938~ 1997-10-24 Example 13 Polyethylene terephthalate was formed into a monofilament in accordance with the parameters set forth in Table 4. No LCP or TEFZELTM was included in the monofilament. Abrasion resistance was measured at 2105 cycles per break.
Example 14 93g6 PET was blended with 5~ TEFZELTM and 2~ LCP in accordance with the parameters set forth in Table 4.
Abrasion resistance was measured at 2781.
Example 15 91~ PET was blended with 5~ TEFZELTM and 4~ LCP in accordance with the parameters set forth in Table 4.
Abrasion resistance was measured at 3020.
Example 16 95~ PET was blended with 5~ TEFZELTM and yielded an abrasion resistance of 2626.
As seen in examples 13-16, the addition of TEFZELTM did not confer any significant advantage to the abrasion resistance over non-fluouropolymer blends when used in combination with LCP blended with PET. At 95% PET and 5~
TEFZELTM, the abrasion resistance was 2626. When 5~ TEFZELTM
and 2~ LCP were blended with 93~ PET, the abrasion resistance was 2781. At 91~ PET, 5~ TEFZELTM and 4~ LCP, the abrasion resistance was 3020. The monofilaments of examples CA 0221938~ 1997-10-24 7 and 8, with 95~ PET and 5~ LCP, had an abrasion resistance of 5290 and 4789, respectively.
Table 4 Example 13 14 15 Pump (cm3/min.) 70 70 70 Barrel Zone 1 (~F) 549.8 549.8 551.1 Barrel Zone 2 (~F) 574.6 574.6 575.3 Barrel Zone 3 (~F) 549.8 550.4 549.8 Barrel Zone 4 (~F) 537.0 535.6 539.0 Spinhead 6 (~F) 540.3 539.0 540.3 Spinhead 7 (~F) 539.7 539.7 540.3 Spinhead 8 (~F) 574.6 574.6 574.6 Spinhead 9 (~F) 574.6 574.6 574.6 Spinhead 10 (~F) 574.6 574.6 574.6 Godet 1 (fpm) 40 47.5 47.5 Godet 2 (fpm) 172 172 172 Godet 3 (fpm) 200 200 200 Godet 4 (fpm) 184 184 184 Oven 1 (~F) 249.4 249.4 248.9 Oven 2 (~F) 380.9 379.8 379.8 Oven 3 (~F) 450.0 449.0 449.5 Pump A 56 49.9 47.5 Pump S (cm3/min.) 69.9 69.9 69.9 Extruder A 41.6 40.4 37.6 Extruder S 22.9 22.4 23 Pressure 1 (psi) 2443 1217 1153 Pressure 2 (psi) 2712 1388 1231 Pressure 4 (psi) -- -- --Quench Bath (~F) 149.5 149.7 150.2 Air Gap 1" 1" 1"
LCP/TEFZELTM (~ weight) 0/0 2/5 4/5 Abrasions (cycles/ break) 2105 2781 3020 Industrial Monofilaments Industrial monofilaments were produced for a paper forming fabric. The monofilaments were made at 2.5~ and 5 CA 0221938~ 1997-10-24 LCP blended with 97.5~ and 95~ PET, respectively. The PET
was made by Shell under the trademark VITUFTM9504, with an IV
= 0.95 (m.w. = 26,336). The LCP was produced by Hoechst-Celanese, under the trademark VECTRATM A950.
Table 5 Example Industrial Industrial Monofilament 1 Monofilament 2 Barrel Zone 1 (~F) 540.1 540.1 Barrel Zone 2 (~F) 540.0 540.1 Barrel Zone 3 (~F) 540.5 540.3 Barrel Zone 4 (~F) 540.3 540.5 Spinhead 6 (~F) 529.4 530.0 Spinhead 7 (~F) 530.0 530.2 Spinhead 8 (~F) 550.0 549.3 Spinhead 9 (~F) 557.9 557.7 Spinhead 10 (~F) 550.1 550.1 Godet 1 (fpm) 80.0 80.0 Godet 2 (fpm) 377.4 377.4 Godet 3 (fpm) 422.7 422.7 Godet 4 (fpm) 398.7 398.7 Oven 1 (~F) 260.1 260.1 Oven 2 (~F) 350.1 349.8 Oven 3 (~F) 490.0 490.8 Pump A 67.1 66.4 Pump S (cm3/min.) 350.0 350.0 Extruder A 30.4 29.7 Pressure 1 (psi) 1815 1956 Pressure 2 (psi) 1484 1509 Pressure 3 (psi) 754 737 Pressure 4 (psi) 701 682 LCP ( ~ weight) 2.5 5.0 Abrasions (cycles/break) 4214 4950 Industrial Monofilament 1 A first industrial monofilament was made of 97.5~ PET
and 2.5~ LCP in accordance with the parameters set forth in CA 022l938~ l997-l0-24 table 5. The abrasion resistance was 4214 cycles per break.
Breaking strength averaged 5.313 grams per denier.
Industrial Monofilament 2 A second industrial monofilament was made of 95~ PET
and 5% LCP in accordance with the parameters set forth in table 5. The abrasion resistance was 4950 cycles per break.
The breaking strength averaged 5.369 grams per denier.
Comparison Monofilament An industrial monofilament of 100~ PET was made. The abrasion resistance was 2000 cycle per break.
The industrial monofilaments with 2.5% LCP and 5~ LCP
show an excellent abrasion resistance of 4214 and 4950 cycles per break, respectively. Additionally, the monofilament of 2.5~ LCP and 5~ LCP have breaking strengths of 5.313 and 5.194, respectively. Orientation of the LCP
appears to conform easily within the spinneret at the given temperatures of the process to make industrial monofilaments. The mechanical properties were excellent and abrasion resistance significantly improved with the addition of 2.5~ LCP and 5~ LCP over the pure PET monofilament.
The foregoing examples illustrate particular embodiments of the invention and provide monofilaments suitable for use in papermaking fabrics, particularly forming and dryer fabrics, and are not intended to limit the scope of the invention.
* * *
BACRGROUND OF THE I~v~NllON
The present invention relates to monofilaments which contain a polymer of polyethylene terephthalate (PET) and liquid crystalline polymer (LCP). These monofilaments have improved abrasion resistance and are suited for use in papermaking fabrics. The monofilaments are particularly suitable for use in papermaking fabrics used in the forming and dryer sections.
Field of the Invention Papermaking machines use fabrics which may be forming fabrics, press felts or dryer fabrics according to the function performed in the papermaking process. The design and composition of papermaking fabrics used on each section of the papermaking machines varies in accordance with function.
The papermaking process starts in the forming section of the papermaking machine where aqueous pulp slurry is deposited onto a forming fabric having desired characteristics for retaining the fibers while allowing the water to pass through to the fabric. The aqueous paper web created by this process is then transferred to and carried by a press felt through the press section where additional water is removed by conveying the paper web through one or more press nips. The paper web is then transferred to and carried through the drying section of the dryer fabric to remove additional water through forced evaporation.
CA 0221938~ 1997-10-24 Monofilament fabrics must withstand the adverse environment in the papermaking process. In the forming section of the papermaking process, the fabrics are subjected to changes in temperature, compression and elongation forces, and abrasive chemicals. In the dryer section of the papermaking process, the fabrics must withstand moist and dry heat. The forming and dryer fabrics are in contact with the aqueous paper sheet on one side and the papermaking machine on the other side. Accordingly, forming and dryer fabrics desirably must possess several characteristics to function properly in this environment.
Forming fabrics must have a mesh weave that is fine enough to separate the fiber from the slurry yet avoid marking the paper. The forming fabric must also be open enough to have good drainage for the initial water removal that facilitates paper formation and it must be resistant to degradation resulting from exposure to chemicals in the paper furnish in the forming section of the papermaking machines. Furthermore, the forming fabric must withstand high tensile loads in the machine direction and compressive buckling loads in the cross-machine direction.
Dryer fabrics must have enough permeability to allow the passage of vapor through the fabric. The fabric must be resistant to degradation from moist and dry heat.
Additionally, the dryer fabric must permit uniform and measured drying of the paper sheet.
Forming fabrics and dryer fabrics must be abrasion resistant to withstand both the continuous papermaking CA 0221938~ 1997-10-24 machine and paper sheet contact during the papermaking process. They must be structurally stable to support the paper sheet while stress forces are placed on it during use.
The fabrics must resist stretch under the tension imposed by the powered rolls which drive the fabric.
Description of the Prior Art Prominent monofilaments used in papermaking forming fabrics include polyester, particularly polyethylene terephthalate (PET). It is known in the art to blend these PET polymers with other polymers, such as polyethylene or polybutylene terephthalate, to vary the characteristics of the resulting monofilaments.
Polyethylene terephthalate (PET), an aliphatic-aromatic polymer, is known to exhibit good chemical and dimensional stability, acceptable weaving characteristics, such as tensile strength and loop strength, low moisture gain, good crimpability and heat setting properties. However, PET
monofilaments do not have good abrasion resistance, especially at higher speeds, and are known to degrade when exposed to harsh chemical environments for significant periods of time. Stabilizing additives and stabilization techniques may extend the useful life of the PET for a relatively short period of time. Typically, the PET
monofilaments degrade and require replacement in about thirty to sixty days.
Liquid Crystalline Polymers (LCP) are polymers which retain a high degree of crystalline order when in a melt CA 0221938~ 1997-10-24 phase. LCPs are composed of long and slender molecules and readily orient in the direction of material flow. As the LCP solidifies, the molecule orientation is maintained.
P-hydroxy benzoic acid is a known copolymer in certain LCP compositions. Additionally, p-hydroxy benzoic acid and similar compounds are disclosed as a copolymer in several patents. U.S. Patent No. 4,663,423 (Yamada et al.) discloses p-hydroxy benzoic acid as a copolymer with terephthalic acid. U.S. Patent No. 4,666,764 (Kobayashi et al.) discloses a water-repellent anti-static fabric composed of terephthalic acid and naphthalene-dicarboxylic acid or hydroxyethoxy benzoic acid and p-hydroxy benzoic acid copolymer. U.S. Patent No. 4,975,326 (Buyalos et al.) discloses PET with minor amounts of bibenzoic acid copolymer.
Mixtures of PET with LCP are discussed in Nonisothermal Elonqational Behavior of Blends with Liquid Crystalline Polymers, Polymer Engineering and Science, May 1994, Vol.
34, No. 10, pp. 799-803. Although the article discusses a broad range of proportions in PET/LCP blends, it is silent about abrasion resistance or defined proportions of LCP
which are operable in papermaking fabrics.
Although these references disclose various combinations of chemical compositions, they do not recognize the advantages of using a LCP based polymer as a blend with PET
for making monofilaments used in papermaking fabrics.
CA 0221938~ 1997-10-24 SUMMARY OF THE lNV~NllON
The present invention concerns PET/LCP blended monofilaments which are particularly suitable for use in papermaking machine fabrics. The monofilaments of PET
blended with LCP provide improved abrasion resistance. This is a particularly desirable characteristic for monofilaments used in papermaking forming and dryer fabrics.
The monofilaments of the present invention can be woven into papermaking fabrics according to conventional weaving techniques. The type and density of the weave will depend on the type of paper and papermaking operation for which the fabric is to be used. The PET/LCP based monofilaments may be interwoven with monofilaments containing other chemical compositions.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is a graph showing abrasion resistance improvements of PET with increased amounts of LCP according to the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
This invention relates to monofilaments which contain blended polyethylene terephthalate and liquid crystalline polymer. The high degree of crystalline orientation of the LCP is believed to enhance the abrasion resistance in blends with PET. Acceptable LCPs must have a temperature range compatible with PET and be extrudable. In the preferred embodiment, the LCP component of these monofilament blends CA 0221938~ 1997-10-24 is made from 6-hydroxy-2-naphthoic acid and p-hydroxy benzoic acid.
Fig. 1 shows increased fabric abrasion resistance of PET as it is blended with increasing amounts of LCP. As seen in Fig. 1, monofilaments of pure PET have an abrasion resistance of 2000 cycles per break. With a blend of 97.5%
PET and 2. 5% LCP, the abrasion resistance is 4214. When PET
is blended with LCP in a proportion of 95%/5%, the abrasion resistance is 4950. Abrasion resistance of PET
significantly improves with blended amounts of 1-10% LCP.
The following examples 1-16 use varying amounts of blended PET and LCP manufactured according to the parameters listed in tables 1-4. The particular grades of PET and LCP
within these tests were grouped for comparison as examples 1-5, 6-9, 10-12, and 13-16.
Examples 1-5 In examples 1-5, monofilaments of PET blended with varying amounts of LCP were compared. The PET was a low molecular weight PET resin of IV=0.74, made by Hoechst-Celanese, under the trade name T-26. The PET was mixed with 0, 5, 5, 10 and 25 percent weight of LCP. The LCP was made by Hoechst-Celanese, under the trademark VECTRATM A950. The LCP was composed of 73 mole percent of p-hydroxy benzoic acid and 27 mole percent of 6-hydroxy-2-naphthoic acid. The formed monofilaments were 0.25 to 0.3 mm in diameter. The monofilaments were tested for abrasion resistance and/or breaking strength.
CA 0221938~ 1997-10-24 Example 1 Monofilaments of pure polyethylene terephthalate were prepared in accordance with the specified parameters of Table 1. The abrasion resistance was 3831 and 3270 cycles per break.
Example 2 A monofilament was produced by blending 95%
polyethylene terephthalate and 5% liquid crystalline polymer in accordance with the specified parameters of Table 1. The monofilament was extremely brittle and abrasion resistance testing was not performed. The breaking strength of the monofilament was 2.951 grams per denier.
CA 0221938~ 1997-10-24 Table 1 Example 1 2 3 4 5 Pump (cm3/min.) 110 110 110 110 110 Barrel Zone 1 (~F) 551.1 549.1 549.8 549.8 549.8 Barrel Zone 2 (~F) 550.4 549.1 549.8 549.8 549.8 Barrel Zone 3 (~F) 550.4 549.8 549.8 549.1 549.1 Barrel Zone 4 (~F) 551.8 549.1 549.8 550.4 549.8 Flange (~F) 553.1 547.7 549.1 550.4 549.8 Spinhead 6 (~F) 551.8 549.1 551.8 550.4 549.8 Spinhead 7 (~F) 550.4 549.8 550.4 550.4 549.8 Spinhead 8 (~F) 552.4 552.4 551.1 549.8 549.8 Spinhead 9 (~F) 550.4 549.1 548.4 546.4 544.4 Spinhead 10 (~F) 551.1 549.8 549.8 549.8 549.1 Godet 1 (fpm) 43 43 43 40 37.5 Godet 2 (fpm) 193 172 172 172 172 Godet 3 (fpm) 216 200 200 200 200 Godet 4 (fpm) 183.8 172 184 184 184 Oven 1 (~F) 241.5 300.1 299.6 320.2 320.2 Oven 2 (~F) 380.3 375.6 374.5 374.5 375.1 Oven 3 (~F) 459 449.5 424.7 424.7 425.7 Pump A 57.3 60.9 57.3 56 58.5 Pump S (cm3/min.) 109.9 109.9 109.9 109.9 109.9 Extruder (Amp) 38 38.8 35.9 37.1 37.6 Screw speed 42.9 42.9 45.0 42.6 43.7 Pressure 1 (psi) 2316 2409 2546 2414 2448 Pressure 2 (psi) 997 987 987 1006 992 Pressure 4 (psi) 219 215 210 215 215 Quench Bath (~F) 150.6 149.7 149.8 150 149.8 Air Gap 2" 2" 2" 2" 2"
Melt (~F) -- -- 568.6 567.3 566.6 LCP (~ weight) 0 5 5 10 25 Abrasions 3831/ -- 1948/ 1924/ --(cycles/break) 3270 1956 1973 Example 3 A monofilament was produced by blending 95~
polyethylene terephthalate and 5~ liquid crystalline polymer in accordance with the specified parameters of Table 1. The breaking strength was 3.183 grams per denier. The abrasion resistance was 1948 and 1956 cycles per break.
CA 022l938~ l997-l0-24 Example 4 A monofilament was produced by blending 90~
polyethylene terephthalate and 10~ liquid crystalline polymer in accordance with the specified parameters of Table 1. Breaking strength was 3.796 grams per denier. The abrasion resistance was 1924 and 1973 cycles per break.
Example 5 A monofilament was produced by blending 75~
polyethylene terephthalate and 25% liquid crystalline polymer in accordance with the specified parameters of Table 1. The monofilament broke before abrasion resistance measurements were performed.
Examples 1- 5 used a lower molecular weight PET (IV
0.74). The breaking strength of the monofilament of example 2 was low at 2.951 grams per denier. In example 3, the abrasion resistance of 1948 and 1956 cycles per break was significantly less than pure PET monofilaments with an abrasion resistance of 3831 and 3270 cycles per break. The breaking strength in example 3 also was low at 3.183 grams per denier. In example 4, the abrasion resistance of 1924 and 1973 cycles per break was significantly less than pure PET monofilaments. Although the breaking strength was higher for the monofilament of example 4 than the monofilament of example 3, it was low at 3.796 grams per denier. These runs show no significant improvement in mechanical properties or abrasion resistance of the blended PET/LCP monofilaments over 100~ PET monofilaments.
CA 0221938~ 1997-10-24 Examples 6-9 In examples 6-9, additional monofilaments of PET
blended with varying amounts of LCP were compared. The PET
was a higher molecular weight PET resin than for examples 1-5, with an IV = 0.95 (m.w. = 26,336), made by Shell, under the trademark VITUFTM 9501. The PET was mixed with 0, 5, 5 and 10 percent weight of LCP. The LCP was produced by Hoechst-Celanese, under the trademark VECTRATM A950. Several abrasion resistance measurements were made for the formed monofilaments, which were averaged for the measurements listed in examples 6-9. The monofilaments were 0. 25 to 0. 3 mm in diameter.
Example 6 A monofilament of pure polyethylene terephthalate was produced in accordance with the parameters set forth in Table 2. The abrasion resistance averaged 2163.
Example 7 A monofilament of 95~ PET was mixed with 5~ LCP in accordance with the parameters set forth in Table 2. The abrasion resistance averaged 5290. The breaking strength was 5.086 grams per denier.
Example 8 A monofilament of 95~ PET was mixed with 5~ LCP in accordance with the parameters set forth in Table 2. The abrasion resistance averaged 4789.
CA 0221938~ 1997-10-24 Example 9 A monofilament of 90~ PET was mixed with 10~ LCP in accordance with the parameters set forth in Table 2. The monofilament broke easily and no abrasion resistance measurements were obtained.
Table 2 Example 6 7 8 9 Pump (cm3/min.) 70 70 70 70 Barrel Zone 1 (~F) 561.2 559.8 559.8 559.8 Barrel Zone 2 (~F) 575.3 574.6 575.3 575.3 Barrel Zone 3 (~F) 549.8 550.4 549.8 550.4 Barrel Zone 4 (~F) 541.0 538.3 538.3 541.0 Flange (~F) 580.7 578.0 578.9 578.0 Spinhead 6 (~F) 539.7 540.3 540.3 540.3 Spinhead 7 (~F) 540.3 539.7 539.7 540.3 Spinhead 8 (~F) 574.6 574.6 574.6 574.6 Spinhead 9 (~F) 574.6 574.6 574.6 574.6 Spinhead 10 (~F) 574.0 574.6 574.0 574.6 Godet 1 (fpm) 40 40 45 45 Godet 2 (fpm) 172 172 172 170 Godet 3 (fpm) 200 200 200 121 Godet 4 (fpm) 184 184 184 120 Oven 1 (~F) 248.4 249.4 249.4 300.1 Oven 2 (~F) 369.8 379.3 379.3 380.3 Oven 3 (~F) 444.7 449.5 450.5 449.0 Pump A 53.6 52.4 52.4 59.7 Pump S (cm3/min.) 69.9 69.9 69.9 69.9 Extruder (Amp) 41.2 40 43.7 41.6 Screw speed 21.2 23.5 24.0 25.7 Pressure 1 (psi) 1788 1520 1475 1127 Pressure 2 (psi) 1480 1285 1275 941 Pressure 4 (psi) 78 73 68 53 Quench Bath (~F) 139.6 152.3 151.1 151.0 Air Gap ln 1" 1" 1"
Melt (~F) 602 605.6 605.6 609.6 LCP (~ weight) 0 5 5 10 Abrasions (cycles/break) 2163 5290 4789 CA 0221938~ 1997-10-24 Examples 6-9 used a high molecular weight PET, PET-9501 resin, with 0, 5, 5, and 10 percent weight LCP. At 0~ LCP, the abrasion resistance was 2163 cycles per break. When LCP
was blended at 5~, the abrasion resistance was 5290 and 4789 cycles per break. However, at 10~ LCP, the monofilaments became extremely brittle. Significant improvement was seen in the mechanical properties and abrasion resistance in monofilaments of 1-10~ LCP blended with high molecular weight PET.
Examples 10-12 In examples 10-12, additional monofilaments of PET
blended with varying amounts of LCP were compared. The PET
was made by Shell, under the trademark VITUFTM 9501. The PET
was mixed with 2, 4, and 6 percent weight of LCP. The LCP
was produced by Hoechst-Celanese, under the trademark VECTRATM A950. The resulting monofilaments were tested for abrasion resistance. The monofilaments were approximately 0.4 mm in diameter.
Example 10 98~ polyethylene terephthalate was blended with 2 liquid crystalline polymer in accordance with the parameters set forth in Table 3. The abrasion resistance averaged 2642 cycles per break.
CA 0221938~ 1997-10-24 Example 11 96% polyethylene terephthalate was blended with 4%
liquid crystalline polymer in accordance with the parameters set forth in Table 3. The abrasion resistance averaged 3186 cycles per break.
Example 12 94% polyethylene terephthalate was blended with 6%
liquid crystalline polymer in accordance with the parameters set forth in Table 3. The abrasion resistance averaged 3176 cycles per break.
In addition to examples 10-12, the PET was extruded into a monofilament with 0 percent weight LCP. Abrasion resistance averaged 2063.
Examples 10-12 were run at 98/2, 96/4 and 94/6 percent weight PET/LCP blended compositions. At 2% LCP, the abrasion resistance averaged 2642. At 4% LCP, the abrasion resistance was 3186 and at 6% LCP the abrasion resistance was 3176. The pure PET monofilament had an abrasion resistance average of 2063. The abrasion resistance improved significantly with the addition of LCP, but formed a plateau at 4%-6% LCP.
Examples 13-16 Examples 13-16 compare blended monofilaments of PET
with varying amounts of LCP and a fluoropolymer. The PET
was made by Shell, under the trademark VITUFTM 9501. The LCP
was produced by Hoechst-Celanese, under the trademark CA 0221938~ 1997-10-24 VECTRATM A950. The fluoropolymer was a pellet ethylene tetrafluoroethylene copolymer sold under the trademark TEFZELTM210, produced by E.I. duPont de Nemours & Co., of Wilmington, Delaware. The monofilaments were formed from blends of PET/fluoropolymer/LCP in proportions of 100/0/0, 95/5/0, 93/5/2 and 91/5/4 percent weight.
Table 3 Example 10 11 12 Pump (cm3/min.) 75 75 75 Barrel Zone 1 (~F) 559.2 560.5 559.8 Barrel Zone 2 (~F) 574.0 574.6 574.6 Barrel Zone 3 (~F) 549.8 549.8 549.8 Barrel Zone 4 (~F) 540.3 540.3 538.3 Spinhead 6 (~F) 549.8 549.8 550.4 Spinhead 7 (~F) 550.4 548.4 549.8 Spinhead 8 (~F) 574.6 574 574.6 Spinhead 9 (~F) 547.6 574.6 574.6 Spinhead 10 (~F) 575.3 574.6 574.6 Godet 1 (fpm) 40 40 47.5 Godet 2 (fpm) 172 172 172 Godet 3 (fpm) 200 200 200 Godet 4 (fpm) 184 184 184 Oven 1 (~F) 249.4 249.4 249.4 Oven 2 (~F) 379.3 379.3 380.3 Oven 3 (~F) 450 449.5 449.0 Pump A 52.4 51.2 59.7 Pump S (cm3/min.) 75.0 75 75 Extruder (Amp) 38.8 40.4 38.8 Screw speed 24.0 24.3 26.2 Pressure 1 (psi) 1837 1568 1901 Pressure 2 (psi) 679 576 1055 Pressure 4 (psi) 39 39 0 Quench Bath (~F) 140.2 150.6 150 Air Gap 1" 1" 1"
LCP (~ weight) 2 4 6 Abrasions (cycles/break) 2642 3186 3176 CA 0221938~ 1997-10-24 Example 13 Polyethylene terephthalate was formed into a monofilament in accordance with the parameters set forth in Table 4. No LCP or TEFZELTM was included in the monofilament. Abrasion resistance was measured at 2105 cycles per break.
Example 14 93g6 PET was blended with 5~ TEFZELTM and 2~ LCP in accordance with the parameters set forth in Table 4.
Abrasion resistance was measured at 2781.
Example 15 91~ PET was blended with 5~ TEFZELTM and 4~ LCP in accordance with the parameters set forth in Table 4.
Abrasion resistance was measured at 3020.
Example 16 95~ PET was blended with 5~ TEFZELTM and yielded an abrasion resistance of 2626.
As seen in examples 13-16, the addition of TEFZELTM did not confer any significant advantage to the abrasion resistance over non-fluouropolymer blends when used in combination with LCP blended with PET. At 95% PET and 5~
TEFZELTM, the abrasion resistance was 2626. When 5~ TEFZELTM
and 2~ LCP were blended with 93~ PET, the abrasion resistance was 2781. At 91~ PET, 5~ TEFZELTM and 4~ LCP, the abrasion resistance was 3020. The monofilaments of examples CA 0221938~ 1997-10-24 7 and 8, with 95~ PET and 5~ LCP, had an abrasion resistance of 5290 and 4789, respectively.
Table 4 Example 13 14 15 Pump (cm3/min.) 70 70 70 Barrel Zone 1 (~F) 549.8 549.8 551.1 Barrel Zone 2 (~F) 574.6 574.6 575.3 Barrel Zone 3 (~F) 549.8 550.4 549.8 Barrel Zone 4 (~F) 537.0 535.6 539.0 Spinhead 6 (~F) 540.3 539.0 540.3 Spinhead 7 (~F) 539.7 539.7 540.3 Spinhead 8 (~F) 574.6 574.6 574.6 Spinhead 9 (~F) 574.6 574.6 574.6 Spinhead 10 (~F) 574.6 574.6 574.6 Godet 1 (fpm) 40 47.5 47.5 Godet 2 (fpm) 172 172 172 Godet 3 (fpm) 200 200 200 Godet 4 (fpm) 184 184 184 Oven 1 (~F) 249.4 249.4 248.9 Oven 2 (~F) 380.9 379.8 379.8 Oven 3 (~F) 450.0 449.0 449.5 Pump A 56 49.9 47.5 Pump S (cm3/min.) 69.9 69.9 69.9 Extruder A 41.6 40.4 37.6 Extruder S 22.9 22.4 23 Pressure 1 (psi) 2443 1217 1153 Pressure 2 (psi) 2712 1388 1231 Pressure 4 (psi) -- -- --Quench Bath (~F) 149.5 149.7 150.2 Air Gap 1" 1" 1"
LCP/TEFZELTM (~ weight) 0/0 2/5 4/5 Abrasions (cycles/ break) 2105 2781 3020 Industrial Monofilaments Industrial monofilaments were produced for a paper forming fabric. The monofilaments were made at 2.5~ and 5 CA 0221938~ 1997-10-24 LCP blended with 97.5~ and 95~ PET, respectively. The PET
was made by Shell under the trademark VITUFTM9504, with an IV
= 0.95 (m.w. = 26,336). The LCP was produced by Hoechst-Celanese, under the trademark VECTRATM A950.
Table 5 Example Industrial Industrial Monofilament 1 Monofilament 2 Barrel Zone 1 (~F) 540.1 540.1 Barrel Zone 2 (~F) 540.0 540.1 Barrel Zone 3 (~F) 540.5 540.3 Barrel Zone 4 (~F) 540.3 540.5 Spinhead 6 (~F) 529.4 530.0 Spinhead 7 (~F) 530.0 530.2 Spinhead 8 (~F) 550.0 549.3 Spinhead 9 (~F) 557.9 557.7 Spinhead 10 (~F) 550.1 550.1 Godet 1 (fpm) 80.0 80.0 Godet 2 (fpm) 377.4 377.4 Godet 3 (fpm) 422.7 422.7 Godet 4 (fpm) 398.7 398.7 Oven 1 (~F) 260.1 260.1 Oven 2 (~F) 350.1 349.8 Oven 3 (~F) 490.0 490.8 Pump A 67.1 66.4 Pump S (cm3/min.) 350.0 350.0 Extruder A 30.4 29.7 Pressure 1 (psi) 1815 1956 Pressure 2 (psi) 1484 1509 Pressure 3 (psi) 754 737 Pressure 4 (psi) 701 682 LCP ( ~ weight) 2.5 5.0 Abrasions (cycles/break) 4214 4950 Industrial Monofilament 1 A first industrial monofilament was made of 97.5~ PET
and 2.5~ LCP in accordance with the parameters set forth in CA 022l938~ l997-l0-24 table 5. The abrasion resistance was 4214 cycles per break.
Breaking strength averaged 5.313 grams per denier.
Industrial Monofilament 2 A second industrial monofilament was made of 95~ PET
and 5% LCP in accordance with the parameters set forth in table 5. The abrasion resistance was 4950 cycles per break.
The breaking strength averaged 5.369 grams per denier.
Comparison Monofilament An industrial monofilament of 100~ PET was made. The abrasion resistance was 2000 cycle per break.
The industrial monofilaments with 2.5% LCP and 5~ LCP
show an excellent abrasion resistance of 4214 and 4950 cycles per break, respectively. Additionally, the monofilament of 2.5~ LCP and 5~ LCP have breaking strengths of 5.313 and 5.194, respectively. Orientation of the LCP
appears to conform easily within the spinneret at the given temperatures of the process to make industrial monofilaments. The mechanical properties were excellent and abrasion resistance significantly improved with the addition of 2.5~ LCP and 5~ LCP over the pure PET monofilament.
The foregoing examples illustrate particular embodiments of the invention and provide monofilaments suitable for use in papermaking fabrics, particularly forming and dryer fabrics, and are not intended to limit the scope of the invention.
* * *
Claims (11)
1. A papermaking fabric having improved abrasion resistance including monofilaments of approximately 100 percent weight of a combination of polyethylene terephthalate and liquid crystalline polymer.
2. The papermaking fabric according to claim 1 wherein the liquid crystalline polymer is present in an amount of about 1 percent weight to about 10 percent weight.
3. The papermaking fabric according to claim 2 wherein the liquid crystalline polymer is present in an amount of about 2.5 percent weight to about 6 percent weight.
4. The papermaking fabric according to claim 3 wherein the liquid crystalline polymer is present in an amount of about 4 percent weight to about 6 percent weight.
5. The papermaking fabric according to claim 1 wherein the liquid crystalline polymer comprises
6-hydroxy-2-naphthoic acid and p-hydroxy benzoic acid.
6. The papermaking fabric according to claim 5 wherein the liquid crystalline polymer is composed of about 60 to about 80 mole percent 6-hydroxy-2-naphthoic acid and about 20 to about 40 mole percent p-hydroxy benzoic acid.
6. The papermaking fabric according to claim 5 wherein the liquid crystalline polymer is composed of about 60 to about 80 mole percent 6-hydroxy-2-naphthoic acid and about 20 to about 40 mole percent p-hydroxy benzoic acid.
7. The papermaking fabric according to claim 6 wherein the liquid crystalline polymer is composed of about 70 mole percent 6-hydroxy-2-naphthoic acid and from about 30 mole percent p-hydroxy benzoic acid.
8. The papermaking fabric according to claim 1 wherein the monofilaments are melt extruded.
9. The papermaking fabric according to claim 1 wherein the fabric is a papermaking forming fabric.
10. The papermaking fabric according to claim 1 wherein the fabric is a papermaking dryer fabric.
11. A papermaking fabric having improved abrasion resistance including monofilaments consisting essentially of approximately 100 percent weight of a combination of polyethylene terephthalate and liquid crystalline polymer.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/771,245 US5692938A (en) | 1996-12-20 | 1996-12-20 | Polyester fiber with improved abrasion resistance |
| US08/771,245 | 1996-12-20 |
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| Publication Number | Publication Date |
|---|---|
| CA2219385A1 CA2219385A1 (en) | 1998-06-20 |
| CA2219385C true CA2219385C (en) | 2000-07-11 |
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| CA 2219385 Expired - Fee Related CA2219385C (en) | 1996-12-20 | 1997-10-24 | Polyester fiber with improved abrasion resistance |
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| Country | Link |
|---|---|
| US (1) | US5692938A (en) |
| EP (1) | EP0966559A4 (en) |
| AU (1) | AU734181B2 (en) |
| BR (1) | BR9714223A (en) |
| CA (1) | CA2219385C (en) |
| NO (1) | NO992953L (en) |
| WO (1) | WO1998028472A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19828517C2 (en) * | 1998-06-26 | 2000-12-28 | Johns Manville Int Inc | Monofilaments based on polyethylene-2,6-naphthalate |
| DE19834008C2 (en) | 1998-07-29 | 2000-11-30 | Johns Manville Int Inc | Monofilament bicomponent threads of the core sheath type, process for their production and their use |
| GB0221643D0 (en) * | 2002-09-18 | 2002-10-30 | Voith Fabrics Heidenheim Gmbh | Papermachine clothing with wear-resistant weave |
| US8372232B2 (en) | 2004-07-20 | 2013-02-12 | Neenah Paper, Inc. | Heat transfer materials and method of use thereof |
| US20070173585A1 (en) * | 2004-12-22 | 2007-07-26 | Sevenich Gregory J | Polyester nanocomposite filaments and fiber |
| US20070243360A1 (en) * | 2006-04-14 | 2007-10-18 | Antony Morton | Reinforcement of fabric edges |
| US9469941B2 (en) | 2011-07-01 | 2016-10-18 | Empire Technology Development Llc | Paraben derivatives for preserving cellulosic materials |
| WO2013006160A1 (en) * | 2011-07-01 | 2013-01-10 | Empire Technology Development Llc | Paraben derivatives for preserving cellulosic materials |
| CN103276471B (en) * | 2013-06-27 | 2016-05-25 | 河南华丰网业科技股份有限公司 | The preparation method of wear-resisting monofilament for wire-cloth |
| CN112501954A (en) * | 2020-11-23 | 2021-03-16 | 江苏展宝新材料有限公司 | Preparation method of LCP film |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3761348A (en) * | 1972-02-17 | 1973-09-25 | Monsanto Co | Bicomponent filament |
| JPS60219224A (en) * | 1984-04-16 | 1985-11-01 | Teijin Ltd | Polyester and its production |
| JPS61194275A (en) * | 1985-02-25 | 1986-08-28 | 帝人株式会社 | Antistatic polyester knitted fabric having water repellency |
| US4975326A (en) * | 1987-06-03 | 1990-12-04 | Allied-Signal Inc. | High strength polyester yarn for improved fatigue resistance |
| US5169711A (en) * | 1988-08-05 | 1992-12-08 | Jwi Ltd. | Paper makers forming fabric |
| EP0618942A4 (en) * | 1991-12-23 | 1994-11-17 | Akzo Nobel Nv | Blend of polyethylene terephthalate matrix and thermotropic liquid crystal block copolymer. |
| EP0642552A1 (en) * | 1992-05-29 | 1995-03-15 | Akzo Nobel N.V. | Blend of flexible coil polymer and thermotropic liquid crystalline oligomer |
-
1996
- 1996-12-20 US US08/771,245 patent/US5692938A/en not_active Expired - Fee Related
-
1997
- 1997-10-24 CA CA 2219385 patent/CA2219385C/en not_active Expired - Fee Related
- 1997-11-25 WO PCT/US1997/021415 patent/WO1998028472A1/en active IP Right Grant
- 1997-11-25 BR BR9714223A patent/BR9714223A/en unknown
- 1997-11-25 EP EP97948468A patent/EP0966559A4/en not_active Withdrawn
- 1997-11-25 AU AU54536/98A patent/AU734181B2/en not_active Ceased
-
1999
- 1999-06-17 NO NO992953A patent/NO992953L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0966559A4 (en) | 2000-08-23 |
| US5692938A (en) | 1997-12-02 |
| NO992953D0 (en) | 1999-06-17 |
| AU5453698A (en) | 1998-07-17 |
| EP0966559A1 (en) | 1999-12-29 |
| AU734181B2 (en) | 2001-06-07 |
| BR9714223A (en) | 2000-04-18 |
| CA2219385A1 (en) | 1998-06-20 |
| NO992953L (en) | 1999-06-17 |
| WO1998028472A1 (en) | 1998-07-02 |
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| Date | Code | Title | Description |
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| EEER | Examination request | ||
| MKLA | Lapsed |