CA2218611A1 - Hazardous or toxic waste material storage apparatus and associated method - Google Patents
Hazardous or toxic waste material storage apparatus and associated method Download PDFInfo
- Publication number
- CA2218611A1 CA2218611A1 CA002218611A CA2218611A CA2218611A1 CA 2218611 A1 CA2218611 A1 CA 2218611A1 CA 002218611 A CA002218611 A CA 002218611A CA 2218611 A CA2218611 A CA 2218611A CA 2218611 A1 CA2218611 A1 CA 2218611A1
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- CA
- Canada
- Prior art keywords
- waste material
- hazardous
- container
- inner container
- toxic waste
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65F—GATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
- B65F1/00—Refuse receptacles; Accessories therefor
- B65F1/14—Other constructional features; Accessories
- B65F1/16—Lids or covers
- B65F1/1615—Lids or covers with means for locking, fastening or permanently closing thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/20—Agglomeration, binding or encapsulation of solid waste
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65F—GATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
- B65F1/00—Refuse receptacles; Accessories therefor
- B65F1/14—Other constructional features; Accessories
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
- G21F9/04—Treating liquids
- G21F9/20—Disposal of liquid waste
- G21F9/22—Disposal of liquid waste by storage in a tank or other container
Abstract
The hazardous or toxic waste material storage apparatus includes a flexible inner container (2) for receiving the hazardous waste material or toxic waste material with the inner container (2) having at least one zone of expansion (24) which is substantially more expandable than other portions of the inner container (2). The inner container (2) which holds the hazardous or toxic waste material is sealed and disposed within an outer container (40) which is preferably composed of a flexible material. The inner container (2) preferably occupies less than the full volume of the outer container (40) so as to permit relative movement therebetween. A sealing disc (70) may function as a closure for the outer container (40) and may be mechanically engaged with portions of the outer container (40) to retain the same in position. In one embodiment, an inflatable member (150) is disposed within the outer container (40) so as to reduce the amount of unoccupied space within the outer container (40).
Description
W 096/3302~ PCTrUS96/OSO51 HAZARDOUS OX TOXIC WASTE MATERLAL STORAGE APPAR~TUS
AND ASSOCIATED ME l ~OD
BACKGROUND OF THE INVENTION
1. Field of the Invention The present invention relates to ~)~dLlls and an ~c~i~tfd method for transporting and storing hazardous or toxic waste so as to resist undesired exposure of the toxic or otherwise harmful waste mAtPriAl to the surrounding environment during shipment and storage and, more .~-ific~lly, the present invention relates to a stress-absorbing, two-conl;~inf,, combination employed for such plll~O3eS.
AND ASSOCIATED ME l ~OD
BACKGROUND OF THE INVENTION
1. Field of the Invention The present invention relates to ~)~dLlls and an ~c~i~tfd method for transporting and storing hazardous or toxic waste so as to resist undesired exposure of the toxic or otherwise harmful waste mAtPriAl to the surrounding environment during shipment and storage and, more .~-ific~lly, the present invention relates to a stress-absorbing, two-conl;~inf,, combination employed for such plll~O3eS.
2. Des~,liytion of the Prior Art For many years, gov~ t~1 agencies have become concerned about the hazards people, Anim~l~ and the environment are exposed to due to hazardous or toxic waste materials. Such conc~rn~ have resulted in lf~i~l~tion and regulations at both the federal and state level in the United States, as well as in nl~ e U~IS other countries. Such CQIl~f.l.c have resulted in the need to cat~,~,o.~ mAtPri~lc in accoldance with degree of risk, as well as ~e speeific nature of cc nl~ l;on and tolerable con~entrAtions of these mAt~ri~ in air, water, and soil. Whether one is con~i~iprin~ nuclear materials, heavy metals, or .'~ 1 co.,.~unds, for ~ plc, the attention directed toward these problems has focused on c1~ in~l;ng or ~--;ni---;~ the use of m~t~ri~l~ that arepotentially haL~udous, re~ Ji~l;on of e~ tin~ hd~ous waste sites, and transport and safe disposal of h~dous waste m~teri~l~
There are many in~ tri~l and labulalul y activities which produce hazardous or to~ic waste m~teri~l as a by-product on an ongoing basis. It has been known to render benign hazardous or toxic waste mAtPri~lc in ~ by ~loce~;ng soil, water or air. It has also been known to remove haz~do~ls or toxic waste materials and to convert them to a safe, storable m~t~ri~l by means, such as cllp-m~ conversion or storing the same in glass or concrete storage cor,~in~ from which the materials will not leach.
Often railroad or truck acci~Pnt~ result in spillage of hazardous waste or toxic waste m~t~ri~ls and, thereby, create a h~7~rdous condition. There is, therefore, an ongoing need to provide improved means for safe transport and storage of hazardous or toxic waste m~t~ri~l~
W 096/33028 PCTrUS96/05051 There has been a great deal of prior art dealing with p~ ginE of products other than hazardous or toxic waste which involve providing both inner and outerconti~;n~.~. For eY~mple, ordina,y dry cereal p~ ging cont~in~ a paper inner bagwithin which the product is cont~ine~ and an outer box which must be oi)en~d te~ gain access to the inner bag.
U.S. Patent 1,197,018 discloses the use of a wire or rod, open frame outer cont~inf r within which a bag may be introduced. The compocite package is said to serve as a shipping cont~infr. See also U.S. Patent 1,495,000.
U.S. Patent 2,748,673 discloses the use of a shipping coh~i~incr having a bag for bulk m~t~ri~lc which is introduced either into outer metal container or an outer box.
It has been known to provide a cont~inPr which is flexible and made from a tube by providing suitable closure members at the ends thereof. See U.S. Patent 3,85 1 ,688.
There rem~inc, ~ erur~ a very real and s~lJs~ t;~l need for lmproved ~pp~ s and mPthotlc for L,dns~3.ling and storing hazardous waste m~tfri~lc SUMMARY OF THE INVI~ON
The present invention has met the above-dcs~ libed need by providing a flexible inner co..l;-;nf-r within which the h~dous or toxic waste is sealed with the inner ~nl;.;r.F r having at least one zone of P~ncion which is slll3st~nti~lly more expandable than other portions of the inner co~ ;nf ~ . The inner con~inel is introduced into an outer cor,l;~;nel. The zones of expansion may be provided by pleats formed within the wall of the inner conl~hle. such that the pleats open to permit expansion of the container and close to provide re~rtion of the corl~i-ler. The zones of ey~ncion may be structured so as to provide circumferential expansion of the cOht~.~f l or axial expansion of the con~iner, or both. Forces applied to hazardous or toxic waste material in the inner cont~inf r will re~l,onsi.~ely cause portions of the pleat to open and transfer the force to the outer cOIl~illf - . The outer container is preferably composed of a resilient material.
A sealing disc may cOO~ldt~; with the upper portion of the outer container to close the outer container once the sealed hazardous or toxic waste material containin~ inner cont~;..er is in position within the outer con~illel. In general, the inner container will occupy slightly less than the full volume of the chamber defined by the outer container W 096/33028 PCTrUS96/05051 in order to permit movement therebetween as a shock-absorbing means. Also, the use of zones of expansion in the inner cont~inPr f~ilit~tPs shock transfer to the outer container by inner con~i.ler e~n~ion In one embo~li m~nt, inflatable means are disposed within the inner S container so as to permit inflation of the same to reduce the void volume within the outer cont~in~r exteriorly of the inner co~ in~l.
A cG,l~s~nding method involves introducing hazardous or toxic waste material into the inner coh~ cr to the desired volume, sealing the inner container, introducing the inner container into the outer cQnt~inpr and closing and securing the outer contzlinPr.
It is an object of the present invention to provide for safe and economical ns~,l and storage of hazardous or toxic waste materials.
It is a further object of the present invention to provide apparatus and an ~soc;~ed method which f~ilit~tes ~ ir~tion of any shock loads upon the containerlS system such as during lldnS~l~ and h~n~lling, for Pl~mp1e It is a further object of the present invention to provide such appa dtUS and an ~ci~tp~l method which f~ lit~f~PS reuse of the outer container or permanent storage within the outer c~ n~;--n~.l.
It is a further object of the present invention to provide sealed containers such that any effort to tamper with the same to gain access to the hazardous or toxic waste m~teri~ will readily be apl)~.lt.
It is a further object of the present invention to provide such apparatus wherein a relatively ir.cA~.Isive inner container is employed in combination with a reusable outer cont~inPr.
2S It is a further object of the present invention to provide such a~,a dlus which will f~cilit~tç ready h~n-lling of the d~>pald~lls without exposing the workers to undue risk of contact with the hazardous or toxic waste m~t~ri~
These and other objects of the present invention will be more fully P understood from the following descliplion of the invention on reference to the illllstr~tions appended hereto.
W 096/33028 PCTrUS96/05051 BRIEF DESCRIPIION OF DRAWINGS
Figure 1 is a partially sch~--m~tic partially exploded ~.~ e view of a form of inner container of the present invention.
Figure 2 is a cross-sectional illustration of the container of Figure 1 taken through 2-2 of Figure 1.
Figure 3 is a partially cross-sectional illustration of a portion of a closure for the inner co"tainer of Figure 1.
Figure 4 is a partially s~hPm~tic illustration showing the inner container disposed within the outer container with the latter being in the open position.
Figures 5 and 6 show respectively top plan and elevational views of a sealing disc employable in the appa,dtus of the present invention.
Figure 7 is a partially ~h~m~tic cross-sectional illustration of a closed assembly of the present invention.
Figure 8 is a top plan view of the closed assembly of Figure 7.
Figure 9 is a fr~f~ment~ry section showing a portion of a locking member employable in securin~ the outer conl~;n- ~ in a closed position.
Figure 10 is a partially sch~ lic cross-sectional illustration showing another embotlimpnt of the present invention.
DR~CRIPIION OF THE PREFE~R~Fn EM~OI~IMFl~S
12efçrTin~ again to Figures 1 and 2, there is shown an inner container 2 which is a flexible bag-like container of generally cylindrical shape and has a top wall 4 with an opening 6, through which solid waste material has been introduced into the cor.t~incr and a sidewall 10. A closure IllClllbL,l 8 is secured to the top wall 4 of the COI,I;.ii,f r so as to provide a sealed cont~in~. of hazardous or toxic waste material. In a plc~.~cd embodiment, the sealed cont~inpr will contain a quantity of waste material such that the pleats will be closed or only partially open to thereby permit further expansion responsive to application of a shock load to the inner container. Also, this means that the container occupies slightly less than the full interior volume of the outer container to permit expansion of the zones of expansion formed in the cont~intor wall 10 to thereby transfer applied forces to the outer container and resist undesired fracture of the inner conliline~.. The degree to which the we~hone~ zone or zones will expand will bedetermined by the direction in which the force is applied.
W 096/33028 PCT~US96/OS051 S
The container may advantageously be made of any suitable material which, in some in~t~nces, may vary depen~linP: upon the nature of the hazardous or toxic waste m~tPri~l cont~inpd therein. The inner con~i.ler may be made of a thermoplastic or t thermosetting m~tPri~l. It is plcÇe.lcd that the cont~inet be made by blow molding so as to provide a se~m1ess CQI.~ r. Among the plGfc~lcd m~t~ri~lc are polyvinyl chloride, cilieQnç coated polyvinyl chloride, polyethylene, bidirP~ction~l polypropylene and polyurethane. Disposed within the sidewall 10 of the container eyten~linE generally vertically as shown in Figure 2 are a plurality of we~kPnPd zones 12, 14, 16, 18 which, in the form shown, are integrally forrned pleated portions of the container wall. In the forrn ill~-ct ~tPd each of the longitu-~in~lly orient~Pd zones of expansion have a plurality of pleats which when opened tend to cause generally circumferential expansion of the inner cont~inPr. When the pleats are closed, or partially closed, circumferential contraction of the cont~iner will result. It will be appreciated that while four zones of eYr~n~ion 12, 14, 16, 18 generally, equally spaced circumferentially, have been provided in this embollimpnt~ more or less zones each cOfiti inin~ more or less pleats may be employed, if desired. The zones of eYr~ncion are substantially more expansible than other portions of the inner conl~h~ ~. It will be appreciated that the we~k~nPd zones are provided to f~ilit~tP force in~uc~d eyr~n~ion~ but plcr~-, bly have adequate strength to resist fracture and w~de;.il~d spilling of the waste material into the outer cQnl~in~ r.
Referring still to Figures 1 and 2, thcre is shown a zonc of e~n~iQn 24 which consists of a plurality of circumferentially substantially continuous pleats the opening of which will cause expansion of the container in a generally axial direction and closing of which will cause restriction of the container in a generally axial direction.
In the plcrcll~ d embo~iment of the invention, the circumferential zone of eYr~n~ion 24 will have fli~coi-~ ies where they intersect with the continuous vertical pleats 12, 14, 16 and 18.
In general, it will be plcfe.lcd that the zones of expansion permit axial exr~n~ion of the cont~inP by about 5 to 20 percent and circumferential expansion of about S to 20 percent. In the exr~n~ state, the inner container 2 will contact the outer cont~iner 40.
~eferring to Figure 3, a prert;ll~ means of sealing the container once the hazardous or toxic waste materials have been introduced into the same will be considered.
W 096/33028 PCT/US96/OSOSl -- 6 -It is pl~fel-~d that the closure 8 consist of a substrate 28 which may be the same m~t~-ri~l out of which the inner container is made overlying which is a met~lli7Pd surface such as a l~,..;n~tod metal foil. The application of ultrasonic energy to the closure 8 by an ultrasonic tr~ncducer will result in bonding of the closure 8 to the top wall 4 of inner S container 2 in a circumferentially, continuous manner along the annular contact which includes points 32 and 34. For example, low frequency ultrasonic waves may be employed to self-bond thermoplastic m~tt~ri~lc In a yre~ell~d emb~iment, top wall 4 may be made with a greater wall thicknP-cc than the rem~inder of the inner cont~in~-r 2 to f~rilit~te effective securement of closure 8.
As an alternative, the closure 8 could be secured to the inner container by a suitable adhesive. The contact _one 32 may be of any suitable adhesive which is positioned in an annular pattern so as to provide a continuous seal. If desired, a yl~ s~
sensitive adhesive may be employed. In the ~lfern~tive~ thermally activated adhesive or thermal self bonding may be employed.
It will be ayylccialed that the size of the opening 6 of inner container 2 in the form shown is of large ~ te~ and may be employed conveniently with solid hazardous or toxic waste. With liquid or gel waste, the opening may be of smaller Referring to Figure 4, there is shown the inner container 2 positioned within the outer container 40. The outer container 40 is, preferably, generally cylindrical and has a chall,bel 42 which is of greater volume than the inner container 2 sealed with the hazardous or toxic waste material therein. The outer container may preferably be made of a resilient m~tt~ri~l, such as rubber or fiber reinforced rubber, such as a container which has layers of fiberglass screen or web intcl~osed between layers of rubber. The outer c~n~;nP- 40 should preferably be made of a material that is impermeable to the hazardous or toxic waste material to be stored or transported. It is p~fell. d that the fiber reinforcement be oriented generally circumferentially within the body of the e~tern~l cont~inpr to thereby provide a higher degree of resilient expansion of the cont~in~r in a generally axial direction than in a circumferential direction. The fiberglass layers may be offset from the circumferential direction by about 30 to 45 degrees or, if desired, from other offset layers in the opposite direction. One or more W 096/330~8 PCTAUS96/OSOSl other layers may be positioned in a circumferential direction, if desired. These layers serve to resist circumferential eYr~n~i- n while pc.llliuing some shock-absorbing axial eYp~ on In the open position shown in Figure 4, there is adequate clearance at the coll~iner opening 46 to introduce the inner cont~in~- 2. The upper portion 48 of outer co"t~iner, in this positio~, has its circumferentially, continuous upper portion, angled generally upwardly and outwardly. A preferably continuous outwardly open annularrecess 50 is provided on the outer surface of the upper portion 48. A plurality of individual locking element~, such as 52, 54, are secured to the upper portion 48 of outer container 40. These Pl~mPnt~ may conveniently be made of metal wire. An inwardlyprojecting annular rib 60 on the inner surface of outer col.l~inF~ 40 serves to provide a support for the overlying sealing disc which will be ciesc-ibe~ hereinafter.
Referring to Figures S and 6, the sealing disc, which is gempr~lly disk-like, has an upper surface 62 with an upwardly open, conLinuous annular groove 64. Theund~ rdce 66, in the form shown, is genP,r~lly planar.
~2~of~.rrin~ to Figure 7, there is shown the assembly in closed position with the filled and sealed inner co~ nF~ 2rlisrosF~ within outer co~ f l 40 with the sealing disc 70 having its upper surface 62 facing upwardly and the upper portion 48 of the outer cont:~inFr 40 rotated generally inwardly such that the sealing disc 70 iS urged between underlying annular rib 60 and the upper portion 48 of outer container 40 to, thereby, provide a closed ch~.. b~- for inner c~nt;~in~r 2. Securing the outer container in this position is an annular band 72 which is introduced into recess S0 so as to resist radially outward rotational movement of upper portion 48. The band 72 may be made of metal, such as steel or st~inlP-s~ steel, or a woven strap, for eY~mrle. In this manner, the sealed inner co~t~inçr 2, which cor~ -c the hazardous or toxic waste m~t~ri~l, iS secured ~ithin the outer con~in~,r 40.
It is prefe.led that, in genp~ the inner con~il-er 2 will have a wall thit~l~ne.5s of about 0.25 to 6.0 mm and ~-efeldbly about O.S to l.S mm. The outer corlt~iner 40 will generally have a wall thi~nP-~s of about 2.0 to l.S mm and preferably about 3.0 to S.0 mm.
Referring to Figures 8 and 9, there is shown a plan view of the outer container 40 in its closed condition with a plurality of generally hook-shaped individual locking members 78,80, 82,84 having a dc wnwdr~lly projecting rib 90 which is received W O 96/33028 PCTrUS9G/05051 within upwardly open groove 64 of the sealing disc 70. In this manner, intim~tP
retention of the hazardous or toxic waste material conl~ining inner container 2 is provided. Should the cor~l~inel assembly, during ~hi~ en~ or storage, be subjected to impact, the resilient outer container 40 will absorb impact forces due to the construction which provides directional strength and the ability to rç~iliPntly deform. The eYr~nciQn t zones will permit a change of the shape and size of the inner container 2 to cause it to conform to the outer co,ll~inP~ 40 to transfer force thereto and resist undesired fracture of the inner co~ le. 2. It will be a~l~iated that this cushioning effect serves to f~cilit~tP Pnh~ncP~I safety in absorbing shock loads applied to the cQnt~inPr~ thereby resisting undesired contact between the hazardous or toxic waste materials and the PYtern~l environment.
It will be appreciated that the inner container may be retained in the outer cont~in~qr for in-lefinite storage or the inner con~iller may be removed and stored or discarded and the outer cont~inPr reused ~eppn~lin~ upon the nature of the material and the objectives of the user.
Referring to Figure 10, a further embodiment of the invention will be considered. In this embo~3imP-nt, an inner container 102 which is only partially filled or otherwise shorter than the outer cor t~inPr 140 is sealed by closure 108 and is disposed within outer cont~inpr 140 with the sealing disc 142 secured to the upper portion 148 of the outer con~ine. 140. This embodiment also has zones of expansion 118, 124.
Intc.~osed between the inner container 102 and the undersurface of sealing disc 104 is an inflatable conlainel 150 which may be generally cylindrical so as to conform in size and shape to the inner surface of the outer container 140. By connP~;I;ng tube 152, which passes through an opening in sealing disc 142, to a source of coll.~l- ssed air or a suitable liquid the inflatable member 150 may be inflated so as to permit it to occupy a portion of the volume of the chamber defined by the outer con~iner 140 and, thereby, provide further cushioning action against impact loading. It will be appreciated that the eYp~n-l~ble container 150 need not be inflated to occupy the full volume portion not occupied by inner container 102 as the zones of expansion will also serve to absorb a portion of any shock loads imposed on the container assembly. Also, if desired, inflation of container 150 may be effected prior to insertion in outer container 140 and tube 152 may be Plimin~t~.
W096/33028 PCTrUS96/05051 _ 9 _ The present mPthod, therefore, involves introduçing hazardous or toxic waste m~t~ri~l into a flexible inner container which has at least one zone of e~ ncion~
sealing the inner container and inserting it into an outer cont~inPr which is subsequently closed. The volume of hazardous or toxic waste m~terial in the inner conl;~h-f L is less than the volume of the chamber defined by the outer cont~in~r. As a result, shock loading causes e~ran~ n of the e~n~lable zones to, thereby, transfer the force to the outer container and ~ i~t~ the shock load and resist undesired breakage of the inner co~t~;nçr. It is yl~,fell~ that the zones of çYr~n~i~n include at least one of generally circumferentially, ~bsl;.nt;~11y continuous pleats or gen~rally axially o~ n~d pleats, or both, all formed within the inner co~ in~ body. In one embc~im~ont an inflatable or infl~ted container is introduced into the outer col,~ine~ after positioning the sealed hazardous or toxic waste material col.li.;ning inner cont~iner into the chamber defined by the outer container, after which the outer containt~r is closed. This inflatable cont~inpr serves as a cushion which ~ r~tes shock loads applied to the assembly.
The invention may be employed s~lcce~fully with a wide variety of h~lous or toxic waste m~t~ri~l in various forms, inc~ ing liquids, gels, granular and yo~der materi~l It will be ~ t~i therefore, that the present invention provides an economical reliable means for tran~ ing and storing h~dl.lous or toxic waste m~t~ri~l and providing a flexible, esp~nd~l-le, or cu~hion~d inner col.l;~inf r and an outer cont~ine~
which secures the sealed inner con~;lln?r and rl~mren~ impact loading applied to the assembly. The invention conte.,.plates use of an inexpensive inner container to store the waste m~t~ri~l and an outer CO~ r to absorb shocks and protect the inner cont~ine~
from fracture. The assembly may be employed for ~.l~anent storage or the inner cC)nl; in-o- may be removed and the outer container reused with a different inner container.
All of this is accomrli~hed in an easy to use, economical manner.
Whereas particular embo~iimentc of the invention have been described herein for ~u,l~03es of illustration, it will be evident to those skilled in the art that nu...e~ s variations of the details may be made without departing from the invention as defined in the appended claims.
There are many in~ tri~l and labulalul y activities which produce hazardous or to~ic waste m~teri~l as a by-product on an ongoing basis. It has been known to render benign hazardous or toxic waste mAtPri~lc in ~ by ~loce~;ng soil, water or air. It has also been known to remove haz~do~ls or toxic waste materials and to convert them to a safe, storable m~t~ri~l by means, such as cllp-m~ conversion or storing the same in glass or concrete storage cor,~in~ from which the materials will not leach.
Often railroad or truck acci~Pnt~ result in spillage of hazardous waste or toxic waste m~t~ri~ls and, thereby, create a h~7~rdous condition. There is, therefore, an ongoing need to provide improved means for safe transport and storage of hazardous or toxic waste m~t~ri~l~
W 096/33028 PCTrUS96/05051 There has been a great deal of prior art dealing with p~ ginE of products other than hazardous or toxic waste which involve providing both inner and outerconti~;n~.~. For eY~mple, ordina,y dry cereal p~ ging cont~in~ a paper inner bagwithin which the product is cont~ine~ and an outer box which must be oi)en~d te~ gain access to the inner bag.
U.S. Patent 1,197,018 discloses the use of a wire or rod, open frame outer cont~inf r within which a bag may be introduced. The compocite package is said to serve as a shipping cont~infr. See also U.S. Patent 1,495,000.
U.S. Patent 2,748,673 discloses the use of a shipping coh~i~incr having a bag for bulk m~t~ri~lc which is introduced either into outer metal container or an outer box.
It has been known to provide a cont~inPr which is flexible and made from a tube by providing suitable closure members at the ends thereof. See U.S. Patent 3,85 1 ,688.
There rem~inc, ~ erur~ a very real and s~lJs~ t;~l need for lmproved ~pp~ s and mPthotlc for L,dns~3.ling and storing hazardous waste m~tfri~lc SUMMARY OF THE INVI~ON
The present invention has met the above-dcs~ libed need by providing a flexible inner co..l;-;nf-r within which the h~dous or toxic waste is sealed with the inner ~nl;.;r.F r having at least one zone of P~ncion which is slll3st~nti~lly more expandable than other portions of the inner co~ ;nf ~ . The inner con~inel is introduced into an outer cor,l;~;nel. The zones of expansion may be provided by pleats formed within the wall of the inner conl~hle. such that the pleats open to permit expansion of the container and close to provide re~rtion of the corl~i-ler. The zones of ey~ncion may be structured so as to provide circumferential expansion of the cOht~.~f l or axial expansion of the con~iner, or both. Forces applied to hazardous or toxic waste material in the inner cont~inf r will re~l,onsi.~ely cause portions of the pleat to open and transfer the force to the outer cOIl~illf - . The outer container is preferably composed of a resilient material.
A sealing disc may cOO~ldt~; with the upper portion of the outer container to close the outer container once the sealed hazardous or toxic waste material containin~ inner cont~;..er is in position within the outer con~illel. In general, the inner container will occupy slightly less than the full volume of the chamber defined by the outer container W 096/33028 PCTrUS96/05051 in order to permit movement therebetween as a shock-absorbing means. Also, the use of zones of expansion in the inner cont~inPr f~ilit~tPs shock transfer to the outer container by inner con~i.ler e~n~ion In one embo~li m~nt, inflatable means are disposed within the inner S container so as to permit inflation of the same to reduce the void volume within the outer cont~in~r exteriorly of the inner co~ in~l.
A cG,l~s~nding method involves introducing hazardous or toxic waste material into the inner coh~ cr to the desired volume, sealing the inner container, introducing the inner container into the outer cQnt~inpr and closing and securing the outer contzlinPr.
It is an object of the present invention to provide for safe and economical ns~,l and storage of hazardous or toxic waste materials.
It is a further object of the present invention to provide apparatus and an ~soc;~ed method which f~ilit~tes ~ ir~tion of any shock loads upon the containerlS system such as during lldnS~l~ and h~n~lling, for Pl~mp1e It is a further object of the present invention to provide such appa dtUS and an ~ci~tp~l method which f~ lit~f~PS reuse of the outer container or permanent storage within the outer c~ n~;--n~.l.
It is a further object of the present invention to provide sealed containers such that any effort to tamper with the same to gain access to the hazardous or toxic waste m~teri~ will readily be apl)~.lt.
It is a further object of the present invention to provide such apparatus wherein a relatively ir.cA~.Isive inner container is employed in combination with a reusable outer cont~inPr.
2S It is a further object of the present invention to provide such a~,a dlus which will f~cilit~tç ready h~n-lling of the d~>pald~lls without exposing the workers to undue risk of contact with the hazardous or toxic waste m~t~ri~
These and other objects of the present invention will be more fully P understood from the following descliplion of the invention on reference to the illllstr~tions appended hereto.
W 096/33028 PCTrUS96/05051 BRIEF DESCRIPIION OF DRAWINGS
Figure 1 is a partially sch~--m~tic partially exploded ~.~ e view of a form of inner container of the present invention.
Figure 2 is a cross-sectional illustration of the container of Figure 1 taken through 2-2 of Figure 1.
Figure 3 is a partially cross-sectional illustration of a portion of a closure for the inner co"tainer of Figure 1.
Figure 4 is a partially s~hPm~tic illustration showing the inner container disposed within the outer container with the latter being in the open position.
Figures 5 and 6 show respectively top plan and elevational views of a sealing disc employable in the appa,dtus of the present invention.
Figure 7 is a partially ~h~m~tic cross-sectional illustration of a closed assembly of the present invention.
Figure 8 is a top plan view of the closed assembly of Figure 7.
Figure 9 is a fr~f~ment~ry section showing a portion of a locking member employable in securin~ the outer conl~;n- ~ in a closed position.
Figure 10 is a partially sch~ lic cross-sectional illustration showing another embotlimpnt of the present invention.
DR~CRIPIION OF THE PREFE~R~Fn EM~OI~IMFl~S
12efçrTin~ again to Figures 1 and 2, there is shown an inner container 2 which is a flexible bag-like container of generally cylindrical shape and has a top wall 4 with an opening 6, through which solid waste material has been introduced into the cor.t~incr and a sidewall 10. A closure IllClllbL,l 8 is secured to the top wall 4 of the COI,I;.ii,f r so as to provide a sealed cont~in~. of hazardous or toxic waste material. In a plc~.~cd embodiment, the sealed cont~inpr will contain a quantity of waste material such that the pleats will be closed or only partially open to thereby permit further expansion responsive to application of a shock load to the inner container. Also, this means that the container occupies slightly less than the full interior volume of the outer container to permit expansion of the zones of expansion formed in the cont~intor wall 10 to thereby transfer applied forces to the outer container and resist undesired fracture of the inner conliline~.. The degree to which the we~hone~ zone or zones will expand will bedetermined by the direction in which the force is applied.
W 096/33028 PCT~US96/OS051 S
The container may advantageously be made of any suitable material which, in some in~t~nces, may vary depen~linP: upon the nature of the hazardous or toxic waste m~tPri~l cont~inpd therein. The inner con~i.ler may be made of a thermoplastic or t thermosetting m~tPri~l. It is plcÇe.lcd that the cont~inet be made by blow molding so as to provide a se~m1ess CQI.~ r. Among the plGfc~lcd m~t~ri~lc are polyvinyl chloride, cilieQnç coated polyvinyl chloride, polyethylene, bidirP~ction~l polypropylene and polyurethane. Disposed within the sidewall 10 of the container eyten~linE generally vertically as shown in Figure 2 are a plurality of we~kPnPd zones 12, 14, 16, 18 which, in the form shown, are integrally forrned pleated portions of the container wall. In the forrn ill~-ct ~tPd each of the longitu-~in~lly orient~Pd zones of expansion have a plurality of pleats which when opened tend to cause generally circumferential expansion of the inner cont~inPr. When the pleats are closed, or partially closed, circumferential contraction of the cont~iner will result. It will be appreciated that while four zones of eYr~n~ion 12, 14, 16, 18 generally, equally spaced circumferentially, have been provided in this embollimpnt~ more or less zones each cOfiti inin~ more or less pleats may be employed, if desired. The zones of eYr~ncion are substantially more expansible than other portions of the inner conl~h~ ~. It will be appreciated that the we~k~nPd zones are provided to f~ilit~tP force in~uc~d eyr~n~ion~ but plcr~-, bly have adequate strength to resist fracture and w~de;.il~d spilling of the waste material into the outer cQnl~in~ r.
Referring still to Figures 1 and 2, thcre is shown a zonc of e~n~iQn 24 which consists of a plurality of circumferentially substantially continuous pleats the opening of which will cause expansion of the container in a generally axial direction and closing of which will cause restriction of the container in a generally axial direction.
In the plcrcll~ d embo~iment of the invention, the circumferential zone of eYr~n~ion 24 will have fli~coi-~ ies where they intersect with the continuous vertical pleats 12, 14, 16 and 18.
In general, it will be plcfe.lcd that the zones of expansion permit axial exr~n~ion of the cont~inP by about 5 to 20 percent and circumferential expansion of about S to 20 percent. In the exr~n~ state, the inner container 2 will contact the outer cont~iner 40.
~eferring to Figure 3, a prert;ll~ means of sealing the container once the hazardous or toxic waste materials have been introduced into the same will be considered.
W 096/33028 PCT/US96/OSOSl -- 6 -It is pl~fel-~d that the closure 8 consist of a substrate 28 which may be the same m~t~-ri~l out of which the inner container is made overlying which is a met~lli7Pd surface such as a l~,..;n~tod metal foil. The application of ultrasonic energy to the closure 8 by an ultrasonic tr~ncducer will result in bonding of the closure 8 to the top wall 4 of inner S container 2 in a circumferentially, continuous manner along the annular contact which includes points 32 and 34. For example, low frequency ultrasonic waves may be employed to self-bond thermoplastic m~tt~ri~lc In a yre~ell~d emb~iment, top wall 4 may be made with a greater wall thicknP-cc than the rem~inder of the inner cont~in~-r 2 to f~rilit~te effective securement of closure 8.
As an alternative, the closure 8 could be secured to the inner container by a suitable adhesive. The contact _one 32 may be of any suitable adhesive which is positioned in an annular pattern so as to provide a continuous seal. If desired, a yl~ s~
sensitive adhesive may be employed. In the ~lfern~tive~ thermally activated adhesive or thermal self bonding may be employed.
It will be ayylccialed that the size of the opening 6 of inner container 2 in the form shown is of large ~ te~ and may be employed conveniently with solid hazardous or toxic waste. With liquid or gel waste, the opening may be of smaller Referring to Figure 4, there is shown the inner container 2 positioned within the outer container 40. The outer container 40 is, preferably, generally cylindrical and has a chall,bel 42 which is of greater volume than the inner container 2 sealed with the hazardous or toxic waste material therein. The outer container may preferably be made of a resilient m~tt~ri~l, such as rubber or fiber reinforced rubber, such as a container which has layers of fiberglass screen or web intcl~osed between layers of rubber. The outer c~n~;nP- 40 should preferably be made of a material that is impermeable to the hazardous or toxic waste material to be stored or transported. It is p~fell. d that the fiber reinforcement be oriented generally circumferentially within the body of the e~tern~l cont~inpr to thereby provide a higher degree of resilient expansion of the cont~in~r in a generally axial direction than in a circumferential direction. The fiberglass layers may be offset from the circumferential direction by about 30 to 45 degrees or, if desired, from other offset layers in the opposite direction. One or more W 096/330~8 PCTAUS96/OSOSl other layers may be positioned in a circumferential direction, if desired. These layers serve to resist circumferential eYr~n~i- n while pc.llliuing some shock-absorbing axial eYp~ on In the open position shown in Figure 4, there is adequate clearance at the coll~iner opening 46 to introduce the inner cont~in~- 2. The upper portion 48 of outer co"t~iner, in this positio~, has its circumferentially, continuous upper portion, angled generally upwardly and outwardly. A preferably continuous outwardly open annularrecess 50 is provided on the outer surface of the upper portion 48. A plurality of individual locking element~, such as 52, 54, are secured to the upper portion 48 of outer container 40. These Pl~mPnt~ may conveniently be made of metal wire. An inwardlyprojecting annular rib 60 on the inner surface of outer col.l~inF~ 40 serves to provide a support for the overlying sealing disc which will be ciesc-ibe~ hereinafter.
Referring to Figures S and 6, the sealing disc, which is gempr~lly disk-like, has an upper surface 62 with an upwardly open, conLinuous annular groove 64. Theund~ rdce 66, in the form shown, is genP,r~lly planar.
~2~of~.rrin~ to Figure 7, there is shown the assembly in closed position with the filled and sealed inner co~ nF~ 2rlisrosF~ within outer co~ f l 40 with the sealing disc 70 having its upper surface 62 facing upwardly and the upper portion 48 of the outer cont:~inFr 40 rotated generally inwardly such that the sealing disc 70 iS urged between underlying annular rib 60 and the upper portion 48 of outer container 40 to, thereby, provide a closed ch~.. b~- for inner c~nt;~in~r 2. Securing the outer container in this position is an annular band 72 which is introduced into recess S0 so as to resist radially outward rotational movement of upper portion 48. The band 72 may be made of metal, such as steel or st~inlP-s~ steel, or a woven strap, for eY~mrle. In this manner, the sealed inner co~t~inçr 2, which cor~ -c the hazardous or toxic waste m~t~ri~l, iS secured ~ithin the outer con~in~,r 40.
It is prefe.led that, in genp~ the inner con~il-er 2 will have a wall thit~l~ne.5s of about 0.25 to 6.0 mm and ~-efeldbly about O.S to l.S mm. The outer corlt~iner 40 will generally have a wall thi~nP-~s of about 2.0 to l.S mm and preferably about 3.0 to S.0 mm.
Referring to Figures 8 and 9, there is shown a plan view of the outer container 40 in its closed condition with a plurality of generally hook-shaped individual locking members 78,80, 82,84 having a dc wnwdr~lly projecting rib 90 which is received W O 96/33028 PCTrUS9G/05051 within upwardly open groove 64 of the sealing disc 70. In this manner, intim~tP
retention of the hazardous or toxic waste material conl~ining inner container 2 is provided. Should the cor~l~inel assembly, during ~hi~ en~ or storage, be subjected to impact, the resilient outer container 40 will absorb impact forces due to the construction which provides directional strength and the ability to rç~iliPntly deform. The eYr~nciQn t zones will permit a change of the shape and size of the inner container 2 to cause it to conform to the outer co,ll~inP~ 40 to transfer force thereto and resist undesired fracture of the inner co~ le. 2. It will be a~l~iated that this cushioning effect serves to f~cilit~tP Pnh~ncP~I safety in absorbing shock loads applied to the cQnt~inPr~ thereby resisting undesired contact between the hazardous or toxic waste materials and the PYtern~l environment.
It will be appreciated that the inner container may be retained in the outer cont~in~qr for in-lefinite storage or the inner con~iller may be removed and stored or discarded and the outer cont~inPr reused ~eppn~lin~ upon the nature of the material and the objectives of the user.
Referring to Figure 10, a further embodiment of the invention will be considered. In this embo~3imP-nt, an inner container 102 which is only partially filled or otherwise shorter than the outer cor t~inPr 140 is sealed by closure 108 and is disposed within outer cont~inpr 140 with the sealing disc 142 secured to the upper portion 148 of the outer con~ine. 140. This embodiment also has zones of expansion 118, 124.
Intc.~osed between the inner container 102 and the undersurface of sealing disc 104 is an inflatable conlainel 150 which may be generally cylindrical so as to conform in size and shape to the inner surface of the outer container 140. By connP~;I;ng tube 152, which passes through an opening in sealing disc 142, to a source of coll.~l- ssed air or a suitable liquid the inflatable member 150 may be inflated so as to permit it to occupy a portion of the volume of the chamber defined by the outer con~iner 140 and, thereby, provide further cushioning action against impact loading. It will be appreciated that the eYp~n-l~ble container 150 need not be inflated to occupy the full volume portion not occupied by inner container 102 as the zones of expansion will also serve to absorb a portion of any shock loads imposed on the container assembly. Also, if desired, inflation of container 150 may be effected prior to insertion in outer container 140 and tube 152 may be Plimin~t~.
W096/33028 PCTrUS96/05051 _ 9 _ The present mPthod, therefore, involves introduçing hazardous or toxic waste m~t~ri~l into a flexible inner container which has at least one zone of e~ ncion~
sealing the inner container and inserting it into an outer cont~inPr which is subsequently closed. The volume of hazardous or toxic waste m~terial in the inner conl;~h-f L is less than the volume of the chamber defined by the outer cont~in~r. As a result, shock loading causes e~ran~ n of the e~n~lable zones to, thereby, transfer the force to the outer container and ~ i~t~ the shock load and resist undesired breakage of the inner co~t~;nçr. It is yl~,fell~ that the zones of çYr~n~i~n include at least one of generally circumferentially, ~bsl;.nt;~11y continuous pleats or gen~rally axially o~ n~d pleats, or both, all formed within the inner co~ in~ body. In one embc~im~ont an inflatable or infl~ted container is introduced into the outer col,~ine~ after positioning the sealed hazardous or toxic waste material col.li.;ning inner cont~iner into the chamber defined by the outer container, after which the outer containt~r is closed. This inflatable cont~inpr serves as a cushion which ~ r~tes shock loads applied to the assembly.
The invention may be employed s~lcce~fully with a wide variety of h~lous or toxic waste m~t~ri~l in various forms, inc~ ing liquids, gels, granular and yo~der materi~l It will be ~ t~i therefore, that the present invention provides an economical reliable means for tran~ ing and storing h~dl.lous or toxic waste m~t~ri~l and providing a flexible, esp~nd~l-le, or cu~hion~d inner col.l;~inf r and an outer cont~ine~
which secures the sealed inner con~;lln?r and rl~mren~ impact loading applied to the assembly. The invention conte.,.plates use of an inexpensive inner container to store the waste m~t~ri~l and an outer CO~ r to absorb shocks and protect the inner cont~ine~
from fracture. The assembly may be employed for ~.l~anent storage or the inner cC)nl; in-o- may be removed and the outer container reused with a different inner container.
All of this is accomrli~hed in an easy to use, economical manner.
Whereas particular embo~iimentc of the invention have been described herein for ~u,l~03es of illustration, it will be evident to those skilled in the art that nu...e~ s variations of the details may be made without departing from the invention as defined in the appended claims.
Claims (27)
1. Hazardous or toxic waste material storage apparatus comprising a flexible inner container for receiving said waste material, said inner container having at least one zone of expansion which is substantially more expandable than other portions of said inner container which are not within said zones of expansion, and an outer container within which said inner container is disposed.
2. The hazardous or toxic waste material storage apparatus of claim 1 including said zones of expansion being integrally formed pleated portions of said inner container which permit container expansion and container retraction.
3. The hazardous or toxic waste material storage apparatus of claim 1 including said zones of expansion being structured to provide generally circumferential expansion of said inner container.
4. The hazardous or toxic waste material storage apparatus of claim 1 including said zones of expansion being structured to provide generally axial expansion of said inner container.
5. The hazardous or toxic waste material storage apparatus of claim 2 including said zones of expansion being structured to provide both generally circumferential expansion of said inner container and generally axial expansion of said container.
6. The hazardous or toxic waste material storage apparatus of claim 3 including closure means for sealing said inner container after introduction of said waste material.
7. The hazardous or toxic waste material storage apparatus of claim 6 including said closure means being securable to said inner container at least in part by ultrasonic means.
8. The hazardous or toxic waste material storage apparatus of claim 1 including said outer container composed of a fiber reinforced resilient material.
9. The hazardous or toxic waste material storage apparatus of claim 8 including said outer container being composed of a fiberglass reinforced rubber material,
10. The hazardous or toxic waste material storage apparatus of claim 1 including sealing disc means secured to said outer container in overlying relationship with respect to said inner container to cooperate with said outer container to define an inner container receiving chamber.
11. The hazardous or toxic waste material storage apparatus of claim 10 including said outer container having an upper portion which is movable between an open position and a closed position, and in said closed position said outer container engages said sealing disc means.
12. The hazardous or toxic waste material storage apparatus of claim 11 including said sealing disc means and said upper portion of said outer container being mechanically interengaged when said outer container is in said closed position.
13. The hazardous or toxic waste material storage apparatus of claim 10 including said outer container chamber having a volume greater than said inner container when it has said toxic material secured therein.
14. The hazardous or toxic waste material storage apparatus of claim 13 including inflatable means disposed in said chamber between said sealing disc means and said inner container, and means for inflating said inflatable means, whereby said inflatable means may be inflated to fill at least a portion of said chamber volume.
15. The hazardous or toxic waste material storage apparatus of claim 5 including said zones of expansion each permitting expansion of said inner container by about 5 to 20 percent.
16. The hazardous or toxic waste material storage apparatus of claim 7 including said inner container closure means having a sonically conductive surface.
17. The hazardous or toxic waste material storage apparatus of claim 11 including locking means for retaining said upper portion of said outer container in closed position.
18. The hazardous or toxic waste material storage apparatus of claim 13 including inflatable means disposed in said chamber for filling at least a portion of said chamber.
19. The hazardous or toxic waste material storage apparatus of claim 5 including said zones of expansion being expandable to contact said outer container,
20. A method of storing a hazardous or toxic waste material comprising, introducing said hazardous or toxic waste material into a flexible inner container having at least one zone of expansion which is substantially more expandable than portions of the inner container which are not within said zones of expansion, sealing said inner container, introducing said inner container into an outer container, and closing said outer container.
21. The method of claim 20 including sealing said inner container at least in part by ultrasonic means.
22. The method of claim 20 including providing as said zones of expansion a plurality of pleated portions which open to provide expansion of said inner container and close to provide retraction thereof.
23. The method of claim 20 including introducing a quantity of said waste material into said inner container such that the inner container when introduced into said outer container does not fill said outer container, whereby relative movement between said inner and outer container will be permitted.
24. The method of claim 23 including introducing a sealing disc between said inner container and an upper portion of said outer container so as to cause said sealing disc means and said outer container to define a chamber within which said inner container is confined.
25. The method of claim 24 including securing said sealing disc means in position by interengagement with a said upper portion of said outer container.
26. The method of claim 20 including positioning inflatable means within said outer container and after introducing said sealed waste material containing inner container into said chamber inflating said inflatable member to substantially immobilize said inner container within said chamber except for permitting movement of said zones of expansion.
27. The method of claim 20 including introducing inflated means into said outer container to occupy a portion thereof.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/426,375 | 1995-04-21 | ||
| US08/426,375 US5562592A (en) | 1995-04-21 | 1995-04-21 | Hazardous or toxic waste material storage apparatus and associated method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2218611A1 true CA2218611A1 (en) | 1996-10-24 |
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ID=23690547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002218611A Abandoned CA2218611A1 (en) | 1995-04-21 | 1996-04-11 | Hazardous or toxic waste material storage apparatus and associated method |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5562592A (en) |
| EP (1) | EP0821624B1 (en) |
| AT (1) | ATE250989T1 (en) |
| AU (1) | AU692704B2 (en) |
| CA (1) | CA2218611A1 (en) |
| DE (1) | DE69630216D1 (en) |
| WO (1) | WO1996033028A1 (en) |
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|---|---|---|---|---|
| US5833069A (en) * | 1996-08-14 | 1998-11-10 | Jones; David G. | Inflatable protective container for bottles and the like |
| US6495846B1 (en) * | 1999-02-25 | 2002-12-17 | James A. Vaughan | Apparatus and method for nuclear waste storage |
| US6264055B1 (en) * | 2000-02-28 | 2001-07-24 | The United States Of America As Represented By The United States Department Of Energy | Containment canister for capturing hazardous waste debris during piping modifications |
| US6667084B2 (en) | 2000-06-07 | 2003-12-23 | Leifheit Ag | Waste containers |
| DE10028298A1 (en) * | 2000-06-07 | 2001-12-13 | Leifheit Ag | Waste collector |
| US7778711B2 (en) | 2001-08-31 | 2010-08-17 | Bio Control Medical (B.C.M.) Ltd. | Reduction of heart rate variability by parasympathetic stimulation |
| US20050286674A1 (en) * | 2004-06-29 | 2005-12-29 | The Regents Of The University Of California | Composite-wall radiation-shielded cask and method of assembly |
| US20070095423A1 (en) * | 2005-10-19 | 2007-05-03 | Fres-Co System Usa, Inc. | Apparatus and method for filling void in an outer container having a liquid-containing flexible package held therein |
| FR2906638B1 (en) * | 2006-09-29 | 2008-12-19 | Lemer Prot Anti X Par Abrevati | NEW ARMORED CONTAINER STRUCTURE FOR TRANSPORTING AND STORING A RADIOACTIVE SOURCE FOR MEDICAL USE |
| CA2679808A1 (en) * | 2009-09-19 | 2011-03-19 | Jennifer Macewan | Flexible organic waste receptacle |
| CN104347146A (en) * | 2013-07-26 | 2015-02-11 | 中广核工程有限公司 | Nuclear power station high-dose-rate compressible maintenance waste disposal method |
| US9856078B2 (en) * | 2015-09-17 | 2018-01-02 | Manuel Martinez | Smart garbage container with animal deterrence enhancement |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1197018A (en) * | 1912-12-14 | 1916-09-05 | Wilber Emery | Shipping-case. |
| US1495000A (en) * | 1922-05-23 | 1924-05-20 | John S Cuthbertson | Closure for receptacles |
| US2748673A (en) * | 1951-03-09 | 1956-06-05 | Hedwin Corp | Liner for composite containers |
| NL7108899A (en) * | 1971-06-28 | 1973-01-02 | ||
| US4016096A (en) * | 1974-09-04 | 1977-04-05 | Groupement pour les Activities Atomiques et Advancees "GAAA" | Method and device for closing a receptacle for radioactive wastes |
| US4330072A (en) * | 1976-05-05 | 1982-05-18 | National Dispenser Company | Dispenser with side spout for flowable material |
| GB1580259A (en) * | 1976-05-05 | 1980-11-26 | Mastman G J | Handactuated liquid dispenser |
| US4122980A (en) * | 1977-07-25 | 1978-10-31 | Gary J. Mastman | Container top with integral stopper |
| US4436693A (en) * | 1981-09-18 | 1984-03-13 | Automation Industries, Inc. | Non-impacting loose rod storage canister |
| US4784802A (en) * | 1984-07-05 | 1988-11-15 | Westinghouse Electric Corp. | Nuclear waste disposal site |
| US4907717A (en) * | 1988-02-18 | 1990-03-13 | Kubofcik Kenneth W | Low-level radiation waste management system |
| DE3833134A1 (en) * | 1988-09-29 | 1990-04-12 | Siemens Ag | Device for keeping radioactive materials |
| US4919569A (en) * | 1988-11-10 | 1990-04-24 | Wittenzellner Siegfried | Process for disposing of waste |
| US5416253A (en) * | 1990-11-15 | 1995-05-16 | Lockheed Corporation | Cleaning formulation and method of wipe cloth disposal |
| TW207982B (en) * | 1992-04-17 | 1993-06-21 | Brainpower Inc | System for confining articles in a container |
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1995
- 1995-04-21 US US08/426,375 patent/US5562592A/en not_active Expired - Fee Related
-
1996
- 1996-04-11 DE DE69630216T patent/DE69630216D1/en not_active Expired - Lifetime
- 1996-04-11 AT AT96910819T patent/ATE250989T1/en not_active IP Right Cessation
- 1996-04-11 CA CA002218611A patent/CA2218611A1/en not_active Abandoned
- 1996-04-11 AU AU53905/96A patent/AU692704B2/en not_active Ceased
- 1996-04-11 EP EP96910819A patent/EP0821624B1/en not_active Expired - Lifetime
- 1996-04-11 WO PCT/US1996/005051 patent/WO1996033028A1/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| EP0821624A1 (en) | 1998-02-04 |
| EP0821624A4 (en) | 1999-01-27 |
| US5562592A (en) | 1996-10-08 |
| ATE250989T1 (en) | 2003-10-15 |
| DE69630216D1 (en) | 2003-11-06 |
| EP0821624B1 (en) | 2003-10-01 |
| AU5390596A (en) | 1996-11-07 |
| AU692704B2 (en) | 1998-06-11 |
| WO1996033028A1 (en) | 1996-10-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |