CA2214076A1 - Platinum skeleton alloy-supported electrocatalyst, electrode using the electrocatalyst, and process for producing the electrocatalyst - Google Patents
Platinum skeleton alloy-supported electrocatalyst, electrode using the electrocatalyst, and process for producing the electrocatalyst Download PDFInfo
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- CA2214076A1 CA2214076A1 CA002214076A CA2214076A CA2214076A1 CA 2214076 A1 CA2214076 A1 CA 2214076A1 CA 002214076 A CA002214076 A CA 002214076A CA 2214076 A CA2214076 A CA 2214076A CA 2214076 A1 CA2214076 A1 CA 2214076A1
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- Prior art keywords
- alloy
- platinum
- supported
- catalyst
- electrocatalyst
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- 239000010411 electrocatalyst Substances 0.000 title claims abstract description 33
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 title claims description 279
- 238000000034 method Methods 0.000 title claims description 32
- 230000008569 process Effects 0.000 title claims description 8
- 239000003054 catalyst Substances 0.000 claims abstract description 174
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 162
- 239000000956 alloy Substances 0.000 claims abstract description 162
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 93
- 239000010953 base metal Substances 0.000 claims abstract description 75
- 239000010949 copper Substances 0.000 claims abstract description 42
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 23
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000001301 oxygen Substances 0.000 claims abstract description 22
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 22
- 229910001260 Pt alloy Inorganic materials 0.000 claims abstract description 19
- 229910052802 copper Inorganic materials 0.000 claims abstract description 14
- 239000011651 chromium Substances 0.000 claims abstract description 13
- 230000007547 defect Effects 0.000 claims abstract description 12
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 9
- 229910052733 gallium Inorganic materials 0.000 claims abstract description 8
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 7
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 7
- 239000010941 cobalt Substances 0.000 claims abstract description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 7
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052697 platinum Inorganic materials 0.000 claims description 84
- 239000006104 solid solution Substances 0.000 claims description 51
- 229910052799 carbon Inorganic materials 0.000 claims description 47
- 239000013078 crystal Substances 0.000 claims description 43
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 40
- 239000000446 fuel Substances 0.000 claims description 36
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 16
- 239000000243 solution Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229910002804 graphite Inorganic materials 0.000 claims description 9
- 239000010439 graphite Substances 0.000 claims description 9
- 239000006229 carbon black Substances 0.000 claims description 8
- 239000012528 membrane Substances 0.000 claims description 7
- 239000005871 repellent Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- 239000012298 atmosphere Substances 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000000706 filtrate Substances 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 abstract description 9
- 230000010757 Reduction Activity Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 description 51
- 239000000203 mixture Substances 0.000 description 35
- 229910018883 Pt—Cu Inorganic materials 0.000 description 23
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 21
- 230000000694 effects Effects 0.000 description 21
- 238000002441 X-ray diffraction Methods 0.000 description 20
- 239000002002 slurry Substances 0.000 description 15
- 239000003792 electrolyte Substances 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000000843 powder Substances 0.000 description 13
- 230000008859 change Effects 0.000 description 12
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 12
- 239000008367 deionised water Substances 0.000 description 12
- 229910021641 deionized water Inorganic materials 0.000 description 12
- 238000002386 leaching Methods 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
- 238000006722 reduction reaction Methods 0.000 description 11
- 238000004458 analytical method Methods 0.000 description 10
- 238000005275 alloying Methods 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000012018 catalyst precursor Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000002243 precursor Substances 0.000 description 8
- 230000009467 reduction Effects 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 229910002845 Pt–Ni Inorganic materials 0.000 description 6
- 239000011572 manganese Substances 0.000 description 6
- -1 polytetrafluoroethylene Polymers 0.000 description 6
- ZSBXGIUJOOQZMP-JLNYLFASSA-N Matrine Chemical compound C1CC[C@H]2CN3C(=O)CCC[C@@H]3[C@@H]3[C@H]2N1CCC3 ZSBXGIUJOOQZMP-JLNYLFASSA-N 0.000 description 5
- 229910001873 dinitrogen Inorganic materials 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 239000011261 inert gas Substances 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 229910017061 Fe Co Inorganic materials 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 4
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical group [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- 229910020630 Co Ni Inorganic materials 0.000 description 3
- 229910002440 Co–Ni Inorganic materials 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- WBLJAACUUGHPMU-UHFFFAOYSA-N copper platinum Chemical compound [Cu].[Pt] WBLJAACUUGHPMU-UHFFFAOYSA-N 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 229910001092 metal group alloy Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 229910000531 Co alloy Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229920000137 polyphosphoric acid Polymers 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000001132 ultrasonic dispersion Methods 0.000 description 2
- 239000003039 volatile agent Substances 0.000 description 2
- 101100452593 Caenorhabditis elegans ina-1 gene Proteins 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000000441 X-ray spectroscopy Methods 0.000 description 1
- CLBRCZAHAHECKY-UHFFFAOYSA-N [Co].[Pt] Chemical compound [Co].[Pt] CLBRCZAHAHECKY-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910000905 alloy phase Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 229910021386 carbon form Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002484 cyclic voltammetry Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- FISIIUFDCAMIGR-UHFFFAOYSA-N difluoromethanedisulfonic acid Chemical compound OS(=O)(=O)C(F)(F)S(O)(=O)=O FISIIUFDCAMIGR-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- PCLURTMBFDTLSK-UHFFFAOYSA-N nickel platinum Chemical compound [Ni].[Pt] PCLURTMBFDTLSK-UHFFFAOYSA-N 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229940083608 sodium hydroxide Drugs 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003930 superacid Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/925—Metals of platinum group supported on carriers, e.g. powder carriers
- H01M4/926—Metals of platinum group supported on carriers, e.g. powder carriers on carbon or graphite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/92—Metals of platinum group
- H01M4/921—Alloys or mixtures with metallic elements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0005—Acid electrolytes
- H01M2300/0008—Phosphoric acid-based
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0082—Organic polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
An electrocatalyst comprising an alloy of platinum with a base metal selected from the group consisting of gallium, vanadium, chromium, manganese, iron, cobalt, nickel and copper, having a structure of vacant lattice site type lattice defects; the alloy being supported on a conductive carbon powder. The electrocatalyst is useful as a platinum-supported catalyst for an electrode, and has a superior electrochemical oxygen reduction activity and has platinum alloy particles having less base metal component.
Description
TITLE OF THE INVENTION
PLATINUM SKELETON ALLOY-SUPPORTED ELECTROCATALYST, ELECTRODE
USING THE ELECTROCATALYST, AND PROCESS FOR PRODUCING THE
ELECTROCATALYST
BACKGROUND OF THE INVENTION
l. Field of the Invention This invention relates to a catalyst for electrode (hereinafter referred to as ~electrocatalyst~) for acid electrolyte type fuel cells such as phosphoric acid type fuel cells or proton-exchange membrane type fuel cells.
PLATINUM SKELETON ALLOY-SUPPORTED ELECTROCATALYST, ELECTRODE
USING THE ELECTROCATALYST, AND PROCESS FOR PRODUCING THE
ELECTROCATALYST
BACKGROUND OF THE INVENTION
l. Field of the Invention This invention relates to a catalyst for electrode (hereinafter referred to as ~electrocatalyst~) for acid electrolyte type fuel cells such as phosphoric acid type fuel cells or proton-exchange membrane type fuel cells.
2. Description of the Prior Art Catalysts comprising a conductive carbon powder carrier on which platinum (Pt) is dispersedly supported and having a corrosion resistance to phosphoric acid heated at a high temperature of about 200~ are conventionally used as electrocatalysts for the phosphoric acid type fuel cells. Furthermore, in recent years, catalysts comprising a conductive carbon powder on CA 02214076 1997-08-2~
which an alloy of platinum with a base metal element such as gallium, titanium, vanadium, chromium, iron, cobalt, nickel or copper is supported have been developed in order to improve the activity of oxygen reduction reaction in the cathode (U.S. Patent Nos. 4,186110 and 4,447,506, Japanese Pre-exAmin~tion Patent Publication (kokai) Nos. 60-7941, 61-8851 and 62-163746, etc.). Meanwhile, as electrocatalysts for proton-exchange membrane type fuel cells, platinum black catalysts have been used from old times, but catalysts comprising a conductive carbon powder on which platinum is highly dispersedly supported are now put into use so that the amount of platinum used can be reduced. Also in such catalysts, researches are made on catalysts formed of an alloy with a base metal so that the oxygen reduction activity of the cathode can be improved ~G. T~mi7h~oni & G.A. Capuano, J. Electrochem. Soc., Vo.141, No.4 (1994)].
Such platinum alloy-supported catalysts are usually produced in the following way. First, platinum is supported on a conductive carbon p~wder to prepare a platinum-supported carbon powder (a precursor), and then this precursor platinum-supported carbon powder is added in an aqueous solution of a compound such as a salt of base metal element to fix the base metal component on the CA 022l4076 l997-08-25 platinum-supported carbon by the aid of an alkali such as sodium-hydroxide or ammonia or a reducing agent such as hydrazine or for~l in, followed by treatment in a stream of nitrogen or in a stream of hydrogen at a high temperature of 800~ to l,000~ to alloy the base metal and platinum.
Such platinum alloy-supported catalysts have an improved oxygen reduction activity compared with the precursor platinum-supported carbon powder and hence are known to be greatly improved in current-voltage characteristics (I-V characteristics;
the same applies hereinafter) when used as cathode catalysts for phosphoric acid type fuel cells.
Japanese Pre-~minAtion Patent Publication (kokai) No. 3-I27459 reports that in the production of such an alloy-supported catalyst all the base metal used is not completely made into an alloy and is partly deposited on and adheres to the carbon surface, and it is proposed to remove free base metal by washing the catalyst with an aqueous dilute acid solution to thereby suppress the wetting of the catalyst to the electrolyte so that the cell can have a longer lifetime.
Advantages of skeleton catalysts whose representative is Raney nickel are also known from old times.
Platinum skeleton catalyst electrodes prepared by dissolving the base metal component out of an electrode formed of an alloy of platinum with a base metal, not supported on a carrier, were studied in the 1960's as electrodes for 5 fuel cells (U.S. Patent No. 3, 429, 750). Meanwhile, a platinum-supported skeleton catalyst prepared by removing Fe from a Pt-Fe alloy-supported catalyst (U.S. Patent No.
4,187, 200) iS known to exhibit a high activity in hydrogenation reaction, but there is no disclosure as to whether it is useful as an electrocatalyst.
Under operation conditions of fuel cells in which an acid electrolyte and oxygen are present together, not only the base metal not alloyed with platinum but also the base metal in platinum-base metal alloy crystals can not avoid gradually dissolving in the electrolyte. The base metal having dissolved in the electrolyte is either reduced at a portion having a more basic potential in the cell to become deposited there, or crystallized because of a lowering of solubility at a lower-temperature portion to become deposited, thus there is a possibility of clogging pores of a gas diffusion electrode. Especially in the case of proton-exchange membrane type fuel cells, there is also a possibility that base metal ions react with the electrolyte to cause a lowering of the conductivity of the electrolyte.
Hence, in order to make fuel cells have a longer lifetime, it is desired to make the base metal less dissolve out of the alloy.
Meanwhile, in the base metal/platinum alloy-supported catalysts, it is usually indispensable to alloy the materials at a high temperature in the step of preparation. As a result of this high-temperature treatment, the platinum is alloyed with the base metal and at the same time may cause crystal growth.
Hence, it is not always easy to prepare a platinum alloy catalyst having, e.g., an average crystal particle size not larger than 50 A (angstrom, 1 A = O.l nm;
the same applies hereinafter). Accordingly, it is sought to provide as an electrocatalyst for fuel cells a platinum-supported catalyst that retains crystal-forms of an alloy highly active in oxygen reduction and yet has platinum alloy particles made finer and also containing less base metal component.
SUMMARY OF THE INVENTION
To solve the above problems, the present inventors made extensive studies on how the crystal forms of platinum alloys supported on carbon affect the activity and lifetime required as electrocatalysts for fuel cells. As the result, they have discovered , - 6 -that a skeleton catalyst comprising an alloy of platinum with a specific base metal component, the base metal component having been selectively removed from alloy crystals, exhibits an unexpectedly high activity and long-term stability as a fuel cell electrocatalyst, and thus have accomplished the present invention, More specifically, the electrocatalyst of the present invention is a catalyst comprising an alloy of platinum with at least one base metal selected from the group consisting of gallium, vanadium, chromium, manganese, iron, cobalt, nickel and copper, having a structure of vacant lattice site type lattice defects (hereinafter said alloy being referred to as "platinum skeleton alloy~) and a conductive carbon powder, the alloy being supported on the conductive carbon powder (hereinafter the catalyst being referred to as "platinum skeleton alloy supported catalyst").
The platinum skeleton alloy catalyst of the present invention has a lattice constant compressed to the one comparable to a base metal-rich solid solution alloy and has a smaller crystallite diameter, and hence can have a very higher mass activity for the oxygen reduction reaction in the cathode of fuel cells than conventional catalysts of - platinum-base metal alloy-supported on carbon. Moreover, because of a greatly controlled content of the base metal, the catalyst has a superior long-term stability, and acid electrolyte fuel cells using this catalyst exhibit a higher out-put and a longer lifetime, and can be greatly effective in practical use.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is a graph showing the relationship between Pt-Cu atomic ratio and face-centered cubic lattice constant of a platinum-copper solid solution alloy supported on a carbon carrier.
Fig. 2 is a graph showing chanyes with time of IR-free terminal voltages in a test in which phosphoric acid fuel cells respectively having as the cathode an electrode using a catalyst according to an example of the present invention and and electrode using a catalyst according to a comparative example are operated at a constant current density.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
- Electrocatalyst -Platinum skeleton alloy:
The platinum skeleton alloy which is an active metal of the catalyst of the present invention is supported on a conductive carbon powder in the state of fine particles.
The platinum skeleton alloy is an alloy in which the base metal in the crystal lattice of a precursor thereof, a platinum-base metal alloy, has been removed at least in part. This precursor alloy S is a substitutional solid solution alloy. In general, single platinum is face-centered cubic (fcc), and substitutional solid solution alloys formed by alloying platinum and other metal elements may have various crystal forms. However, solid solution alloys formed by alloying platinum and at least one base metal selected from the group consisting of gallium, vanadium, chromium, manganese, iron, cobalt, nickel and copper have any of disordered face-centered cubic, ordered cubic and ordered tetragonal forms. In addition, in these alloys, the diffraction angle 2 ~ corresponding to the main diffraction line (lll) in their X-ray diffraction is present on the side of a higher angle than that of the single platinum, and crystal lattice constant ac of the cubic alloys or lattice constants ae and ct of the tetragonal alloys has/have the relationship of ac < aO, or at{3/(2+at2/Ct2)~l/2 < aO~ with respect to lattice constant aO of the single platinum.
It has been found that, when the base metal only is selectively removed at least in part from such a CA 02214076 1997-08-2~
platinum-base metal alloy while retaining the crystal form of the alloy, the lattice sites having been held by the base metal become vacant, so that an alloy having vacant lattice site type lattice defects, i.e., the platinum skeleton alloy can be obtained. With an increase in the degree at which the base metal is removed, the alloy becomes finer as a result of the break of alloy particles.
Such a platinum skeleton alloy retains its original crystal form even though the compositional proportion of platinum has become larger than the original solid solution alloy, and hence it exhibits a higher oxygen reduction activity than the single platinum of course and than any compositionally corresponding solid solution alloys lS (having substantially no vacant lattice site).
In the platinum skeleton alloy supported catalyst of the present invention, there are no particular limitations on the amount of the platinum and base metal to be supported on the carrier, conductive carbon powder, and on the atomic ratio of platinum to base metal. Preferably, the platinum may be supported in an amount of 1% to 60%, and particularly preferably 5% to 50%, based on the whole catalyst (the amount of the metal to be supported, based on the whole catalyst, is indicated by weight; the same applies CA 02214076 1997-08-2~
hereinafter); in the case of a cathode catalyst for phosphoric acid type fuel cells, particularly preferably from 5% to 30%, and in the case of a cathode catalyst for proton-exchange membrane type fuel cells, particularly preferably from 20% to 50%.
The amount of the base metal r~-ining in the platinum skeleton alloy may be 0% in an extreme case, but there is no advantage in practical use if it is completely removed. In usual cases, the platinum and base metal in the platinum skeleton alloy may preferably be in an atomic ratio of from 1:1 to 1:0.05, and particularly preferably from 1:0.5 to 1:0.1.
Conductive carbon powder:
As the conductive carbon powder used as a carrier in the electrocatalyst of the present invention, any conductive carbon powders known as carriers for fuel cell electrocatalysts may be used.
More specifically, carbon black powders such as oil furnace black and acetylene black may be used which have characteristics of a BET specific surface area of from 50 to 1,500 m2/g, a graphite (002) crystallite diameter of from 7 to 80 A, a graphite crystal interlattice distance dc (002) of from 3.40 to 3.70 A, and a DBP oil absorption of from 50 to 700 ml/100 gC. These carbon black may be CA 02214076 1997-08-2~
heated at 1,600~ to 2,800~ in an inert gas or in vacuo in order to improve durability under conditions where acid electrolyte fuel cells are used, or may be heated at 500~
to 900~ in an atmosphere of water vapor to improve surface roughness so that the volatile components can be removed and also the catalyst active metal can be more stably supported. In particular, as the carrier of the cathode catalyst for phosphoric acid type fuel cells, at least partially graphitized carbon black having a BET specific surface area of from 50 to 180 m2/g and a graphite (002) crystallite diameter of from 10 to 70 A is preferred. As the carrier of the cathode catalyst for proton-exchange membrane type fuel cells, carbon black having a BET specific surface area of from 120 to 1,500 mZ/g and a graphite (002) crystallite diameter of from 7 to 35 A is particularly preferred.
- Production of Electrocatalyst -The electrocatalyst ofplatinum skeleton alloy supported on carbon of the present invention, having the structure of vacant lattice site type lattice defects described above, can be produced in the following way.
That is, in the first step, the solid solution alloy of platinum with at least one base metal selected from the group consisting of gallium, vanadium, chromium, manganese, iron, cobalt, nickel and copper is supported on the conductive carbon powder in a highly dispersed state to form a catalyst precursor of platinum alloy supported S on carbon. Next, in the second step, the catalyst precursor is subjected to treatment to selectively remove only the base metal component at least in part from the crystal lattice of catalyst precursor while retaining the crystal form to thereby bring about the structure of vacant lattice site type lattice defects, thus the desired catalyst can be produced.
There are no particular limitations on methods for preparing the precursor catalyst of platinum alloy supported on carbon so long as the ordered alloy or disordered solid solution alloy is formed in a highly dispersed state. Various known preparation methods may be used, as exemplified by an alloying method in which catalyst components are supported in a single-step followed by heat treatment, an alloying method in which the catalyst component is supported in a multiple-step followed by heat treatment, and a method in which the base metal is alloyed and supported on a platinum-supported carbon powder (the electroless plating method).
As a degree of alloying, it is preferred that the greater part (90% or more) of the base metal supported on carbon is present as an alloy with platinum and the base metal present apart from platinum on the carbon is less than 10%, or that the greater part (90% or more) of the platinum supported on carbon is present as an alloy with base metal and the platinum present singly by itself on the carbon is less than 10%. They can be alloyed in such a sufficient degree in the following way: For example, in the case of an alloying method in which catalyst components are supported in a two-step followed by heat treatment, first the platinum is supported on carbon powder in a highly dispersed state to prepare a platinum-supported carbon powder. Next, this IS platinum-supported carbon powder is slurried in an aqueous dilute solution of a salt of the base metal element, and the base metal element is adsorbed or fixed on the platinum-supported carbon powder by alkali treatment or wet-process reduction, followed by filtration, washing and drying to prepare a-base metal and platinum-supported carbon powder as a precursor or intermediate. Then, this is retained in an inert gas such as nitrogen or helium, in vacuo or in a stream of hydrogen gas, at a temperature necessary and sufficient for completely alloying the base CA 022l4076 l997-08-2 metal and platinum supported on the carbon carrier and of a degree not to cause excessive aggregation (sintering) of the alloy crystals formed, and for a necessary and sufficient time, followed by cooling to room temperature. These conditions depend on the method for obtaining the desired catalyst of platinum alloy supported on carbon carrier. The alloying by heat treatment may preferably be carried out at a temperature of, e.g., from 750~ to 1,000~, and more preferably from 800~ to 900~, for a retention time of from 1 minute to 5 hours, and more preferably from 20 minutes to 2 hours.
Whether or not the precursor or intermediate obtained in the first step is in a sufficiently alloyed state can be ascertained by various methods. For example, it can be microscopically ascertained by observation of powder using an analytical trAn~mi~sion electron microscope.
More specifically, it can be ascertained when, in a transmission electron microscope (TEM) image of 300,000 to - 20 1,000,000 magnifications, every particle of metal particles of tens of angstroms in diameter, supported on the surfaces of carbon particles of hundreds of angstroms in primary particle diameter, gives values of elementary analysis which are almost in conformity with the alloy composition of the whole powder (bulk) in respect of its energy dispertive X-ray spectroscopy (EDX) and on the other hand the EDX at every part of the carbon carrier detects no significant presence of each of the base metal and the platinum alone.
The state of being alloyed can be macroscopically ascertained by plotting lattice constants vs. alloy compositions of solid solution alloys.
More specifically, catalyst of platinum alloy-supported on carbon carrier with a series of composition are prepared by changing the atomic ratio of platinum to base metal, and X-ray diffraction lattice constants of the respective alloys are measured to plot the composition vs.
lattice constant on X-Y coordinates, where the Vegard law is established so long as a perfect solid solution alloy is formed within a given compositional range, and the lattice constants of the alloy are on a diagonal line connecting the respective lattice constants of the single platinum and the single base metal or a curve which is close thereto.
The second step in the production process of the catalyst of the present invention will be detailed below. The second step is the step of making treatment to selectively remove only the base metal component at least in part from the crystal lattice of the catalyst precursor of platinum alloy-supported on carbon carrier while retaining the structure and physical properties of the carbon carrier and while retaining the crystal form of the platinum alloy supported thereon, to thereby bring about the structure of vacant lattice site type lattice defects;
thus the catalyst of platinum skeleton alloy-supported on carbon carrier being obtained.
There are no particular limitations on methods for the above so long as they are methods of selectively removing only the base metal component from the alloy crystal lattice while retaining the crystal form of the platinum alloy without changing the structure and physical properties of the carbon carrier. For example, known methods can be used in which the catalyst precursor of platinum alloy-supported on carbon is treated with an aqueous solution of an acid that dissolves the base metal element but does not dissolve the platinum (i.e., liquid-phase leaching), or heat-treated in a gas stream of a gas of an element or compound that forms a volatile compound with the base metal element but does not form a volatile compound with the platinum, as exemplified by chlorine (Cl2) or carbon monoxide (CO) (i.e., gas-phase leaching). There are no particular limitations on the rate of removal of the base metal element. As stated previously, the base metal may be completely removed from the alloy crystal lattice without changing the crystal form, and it is not impossible to do so, but not essential in practical use. In usual cases, the base metal may be removed in such an amount of 20% to 99%, and preferably from 30~ to 95%, of its content in the original platinum solid solution alloy.
Any excessive leaching is not preferable because it may cause a change in crystal form. Any excessive application of heat during the leaching or after the leaching or any leaching carried out under conditions that may cause dissolution of platinum in the alloy is not preferable because it might cause a change in lattice constants of platinum to change into the e~uilibrium lattice constants of the platinum-rich solid solution alloy corresponding to the composition which would be formed if the dissolution occurs (i.e., change into an alloy of crystal structure having no vacant lattice sites).
It is also not preferable that the structure and physical properties of the carrier conductive carbon powder greatly change with the leaching treatment of the base metal.
If the structure of carbon is cut off or the corrosion of surfaces proceeds, there is a possibility of causing CA 022l4076 l997-08-2 the supported solid solution alloy to come off, dissolve or aggregate.
As a method for selectively removing the base metal component from the crystal lattice while retaining S the crystal form of the catalyst precursor, supported platinum solid solution alloy without changing the structure and physical properties of the carbon carrier, it is preferable to suspend the platinum solid solution alloy-supported carbon powder in phosphoric acid heated to 100~ to 200~ or in an a~ueous mineral acid solution kept at a temperature of room temperature to 100~ in an atmosphere where the oxygen pressure has been made lower than air, preferably in an atmosphere containing substantially no oxygen, e.g., in a stream of nitrogen, and maintain the resultant suspension with stirring for a certain time, followed by cooling, filtering, and washing with hot deionized water until the filtrate has an electrical conductivity of 20 ~ S/cm or - 20 less, and subsequently drying in vacuo or in an stream of nitrogen gas at 110~ to obtaln the desired catalyst. As the mineral acid, sulfuric acid and nitric acid are preferred, which may preferably be in a concentration of from 0.1 to 1.0 N. The heated phosphoric acid may CA 02214076 1997-08-2~
preferably be in a concentration of from 85 to 105%.
If such wet leaching with an acid is carried out in the atmospheric environment, the catalyst is exposed to an open-circuit potential of 1 V or higher at the interface where the catalyst slurry come into contact with oxygen, so that the platinum may dissolve out of the alloy or the corrosion of the carbon powder may proceed, thus such leaching is not preferred. In the atmospheric environment, the lattice constant of the platinum skeleton alloy tends to greatly come near to that of the platinum-rich solid solution alloy.
Whether or not the platinum skeleton alloy supported carrier has been formed as a result of the second step can be ascertained in the following way. First, elementary analysis of the catalyst obtained is carried out to make sure that only the base metal has been removed out of the initially supported alloy and the platinum and carbon have been recovered. Powder process XRD (X-ray diffractometry) of the catalyst is further carried out to make sure that the crystal form of the original platinum solid solution alloy is retained, and that the lattice constant is retained substantially in the state of the original solid solution alloy though a little change may occur, that is, it is close to that of the original base metal-rich solid solution alloy rather than to the lattice constant that the resultant platinum skeleton alloy would have, if it were a solid solution alloy.
Whether or not the supported platinum skeleton alloy used in the present invention has the structure of vacant lattice site type lattice defects, i.e., a non-equilibrium crystal structure can be ascertained in the following way. The powder of the platinum skeleton alloy supported catalyst of the present invention is subjected to in situ XRD in an atmosphere of inert gas or in vacuo. As the temperature is gradually raised from room temperature up to a temperature to be used when the materials are alloyed, it is ascertained that the crystal form and lattice constant of the alloy change from those of the platinum skeleton alloy to those of the solid solution alloy corresponding to the platinum-rich composition from which the base metal has been removed. Even after cooling to room temperature, the change in crystal form and lattice constant that has taken place during the temperature rise is maintained, and the crystal form and lattice constant no longer return to those of the original platinum skeleton alloy. That is, in the platinum skeleton alloy supported catalyst obtained in the second step, the platinum skeleton alloy still retains, in the platinum-rich composition from which the base metal has been removed, the equilibrium crystal form and lattice constant in the base metal-rich composition. Thus, the platinum skeleton alloy is shown to have a structure of vacant lattice site type lattice defects.
The BET specific surface area of the catalyst is measured and the carbon graphite ( 002) crystallite diameter and crystal interlattice distance are analyzed by XRD to ascertain that there is no change in structure and physical properties of the carrier carbon.
There are also no particular limitations on the platinum crystallite diameter of the platinum skeleton alloy supported catalyst of the present invention, thus obtained. It may preferably be from 15 to 100 A, and particularly preferably from 20 to 60 A.
There are still also no particular limitations on the metal surface area of the platinum. It may preferably be from 30 to 200 m2/g Pt, and particularly preferably from 50 to 150 m2/g Pt. In the present specification, the metal surface area of platinum is indicated as an electrochemical metal surface area EC. MSA (m2/g Pt) obtained by measuring electrical quantity of hydrogen absorption on the platinum surface in the cathodic sweep of cyclic voltammetry made on catalyst electrodes.
- Characteristics -In the present specification, the electrochemical oxygen reduction activity of the catalyst is evaluated onthe basis of mass activity. The mass activity is determined in the following way. In an oxygen-electrode half cell (~2 half cell), a current density (mA/cm2) obtained at a potential of plus 900 mV vs. a reference hydrogen electrode (RHE, the same applied hereinafter) is determined, and the resultant value is divided by a platinum loading amount (mg Pt/cm2) per electrode unit area to give a current density per unit platinum mass, i.e., the mass activity (mA/mg Pt).
Stated more specifically, first, according to the electrode preparation method described later, the carbon carrier catalyst powder is bound to carbon paper together with water-repellent binder to form a gas diffusion electrode, and its catalyst-layer side is disposed to the 105~ phosphoric acid heated to 200~ and the opposite side exposed to a stream of oxygen ( ~2) gas. This is incorporated in a half cell apparatus, and the current density (mA/cmZ) produced is determined when a voltage of 900 mV (IR-free) vs. the reference hydrogen electrode (RHE) is applied between the working electrode and the platinum CA 02214076 1997-08-2~
mesh counter electrode, and the resultant value is divided by a platinum loading amount (mg Pt/cm2) per electrode unit area to give the mass activity (mA/mg Pt).
In the platinum skeleton alloy supported catalyst of S the present invention, the platinum is very highly activated.
Especially when used as the cathode electrode for fuel cells, it exhibits a higher oxygen reduction activity than the platinum single supported catalyst as a matter of course and than any of the catalyst precursor having platinum alloy supported on carbon, with no vacant lattice sites and the catalyst of solid solution alloy supported having the composition corresponding to that after removal of the base metal but having no vacant lattice sites.
A typical platinum supported catalyst (20%Pt/C) has a mass activity of 39 mA/mg Pt, and a known catalyst A
of base metal-rich platinum-base metal alloy-supported on carbon (19% Pt-6% Cu/C) and a known catalyst B of platinum-rich platinum-base metal alloy-supported on carbon (20% Pt-1.5% Cu/C) have a mass activity of 69 mA/mg Pt and 70 mA/mg Pt, respectively. In contrast, the catalyst of platinum skeleton alloy-supported on carbon (20% Pt-2.6%
Cu/C) of the present invention, originating from the catalyst A, has a mass activity of 80 mA/mg Pt, showing a higher activity than any of known catalysts.
The platinum skeleton alloy supported catalyst of the present invention was used in the air-electrode cathode, a conventional platinum supported catalyst was used in the anode and an SiC
matrix sheet impregnated with 105% phosphoric acid was held between a pair of these electrodes to set up a small-size single cell. Under the conditions that air was passed through the cathode and hydrogen gas or the reformate model gas comprised of 80% hydrogen and 20% CO2 was passed through the anode, a long-term operation test for thousands of hours or longer was carried out at a constant cell temperature in the range of 190~ to 220~C. In such a test, it has been found that the cell using the catalyst of the present invention in the cathode has a higher initial ter~inA1 voltage, and has a smaller rate of deterioration of the ter~inAl voltage when operated at a constant current density and has been made stabler than any of the single - 20 platinum supported catalyst, the catalyst precursor of platinum alloy supported on carbon having no vacant lattice sites and the platinum solid solution alloy supported on carbon having the same composition as that of the present invention but having no vacant lattice sites.
- Electrode for Fuel Cells -The electrode for fuel cells employing theplatinum skeleton alloy supported catalyst of the present S invention will be described below.
This electrode for fuel cells comprises the platinum skeleton alloy supported catalyst described above and a water-repellent binder which are bound to a conductive and porous support substrate. In addition, especially as the electrode for phosphoric acid type fuel cells, it is essential for the support substrate to be acid-resistant.
As the water-repellent binder, polymer binders as exemplified by polytetrafluoroethylene, polyfluoroethylene propylene and perfluoroalkoxypolyethylene may be used. As the conductive and acid-resistant porous support substrate, gas-permeable carbon paper which have been subjected to water-repellency treatment with the above water-repellent binder, or a mesh screen of metal such as, tantalum and niobium may be used. This is especially useful as the electrode for acid electrolyte fuel cells, in particular, as the oxygen reduction cathode of phosphoric acid type fuel cells.
The electrode of the present invention can be produced, e.g., in the following way. First, the platinum skeleton alloy supported catalyst obtained as described above is mixed with a suspension of polytetrafluoroethylene to form a uniform suspension.
Meanwhile, carbon paper having been subjected to water-repellency treatment with a s; m; 1 ~r acid-resistant polymer material is prepared, and the uniform mixture suspension of the above catalyst and the water-repellent binder is coated thereon by filtration suction, spraying or roll coating, followed by pressure bonding and then baking in an atmosphere of inert gas.
The platinum skeleton alloy may preferably be present on the electrode support substrate only in an catalytically effective amount, which is usually in the range of from O.l to 3 mg, more preferably from O. 2 to 2 mg, and still more preferably from 0.5 to 1 mg, in terms of platinum per square centimeter of geometrical surface area of the electrode support substrate.
The present electrode can be used as a gas diffusion electrode such as a button cell, a gas sensor electrode or an electrolysis electrode, and is especially suitable as an electrode for acid electrolyte fuel cells. As electrolytes used in such fuel cells may include phosphoric acid, sulfuric acid, hydrochloric acid, and super acid such as trifluoromethanesulfonic acid, difluoromethanedisulfonic acid and polytrifluoroethylenesulfonic acid, or mixtures of any of these.
EXAMPLES
The present invention will now be described below in greater detail by way of Examples and Comparative Examples. The present invention is by no means limited to these.
1.-Production of catalyst:
Comparative Example 1 (Production Example 1) Production of ~latinum skeleton alloY supported catalyst:
In 1,500 ml of deionized water containing 4.0 g of glacial acetic acid, 81 g of heat-treated conductive carbon black (trade name: W LCAN XC-72R, available from Cabot Corp.) having a specific surface area of 110 mZ/g was dispersed by ultrasonic dispersion machine and made into a slurry. In 600 ml of deionized water, 9.0 g of platinum as H2Pt(OH)6 was dissolved together with amine to prepare a platinum solution. The platinum solution was added to CA 02214076 1997-08-2~
the carbon slurry with stirring. Thereafter 50 g of an aqueous 5% formic acid solution was added as a reducing agent, and the temperature was then raised to 95~.
After the mixture was maintained at 95~ for 30 minutes, it S was cooled to room temperature, followed by filtration and then washing with deionized water. The filtered cake thus obtained was dried in a stream of nitrogen at 95~ for 16 hours. Powder process XRD of the resultant 10 wt.% Pt/C
(C-l*) (the asterisk * means Comparative Example;
the same applies hereinafter) revealed that it had a Pt (111) crystallite diameter of 15 A and a face-centered cubic lattice constant a of 3.923 A.
Comparative Example 2 ~Production Examples 2 to 9) Production of platinum-copper alloy-supported catalysts:
In 1,000 ml of deionized water, 50 g of Pt/C powder (C-l*) obtained in Production Example 1 was dispersed by means of an ultrasonic dispersion machine and made into a slurry. To this slurry, 150 ml of an aqueous solution containin~-0.435 g of Cu-as copper (II) nitrate was added with the slurry being stirred thoroughly vigorously, and thereafter the pH of the slurry was adjusted to 8.0 while slowly dropwise adding an 5%
hydrazine dilute aqueous solution. After stirring at room temperature for 1 hour, the slurry was filtered and then washed with deionized water. Thereafter, the resultant cake was dried in a stream of nitrogen at 95~ for 16 hours.
Subse~uently, this was kept in a stream of 7% by volume of hydrogen (the balance being nitrogen) at 900~ for 1.2 hour, and thereafter cooled to room temperature to obtain Pt-Cu alloy/C (C-2*). As a result of elementary analysis, metal components were each in a content of Pt: 10.2 wt.%, and Cu: 0.87 wt.%, and Pt:Cu atomic ratio was 79%:21%.
Its XRD revealed that the face-centered cubic solid soIution alloy had a crystallite diameter of 40 A and a lattice constant a of 3.876 A. From XRD spectra of the alloy-supported catalyst, only a face-centered cubic solid solution alloy phase was detected, and neither a diffraction peak of single platinum nor a diffraction peak of single Cu was not detected at all.
In the observation on an analytical transmission electron microscope, the analysis by EDX of individual metal particles supported on carbon ascertained that the alloy composition for each particle all well corresponded to Pt:Cu atomic ratio of the bulk, thus the metal components had been substantially completely alloyed, and almost no single-platinum particles and single-copper particles were present.
The same procedure as the above was repeated but variously changing the amount of copper to produce Pt-Cu solid solution alloy-supported-on-carbon catalysts (C-3*) to (C-9*), and their lattice constants were measured by XRD.
Com~arative Example 3 (Production Example 10) Production of copper supported catalyst:
The procedure of Production Example 2 was repeated except that the 10% Pt/C was replaced with 45 g of carbon powder used in Production Example 1 to make it into a slurry, followed by addition of an aqueous copper (II) nitrate solution contAin-ng 5.0 g of Cu. Thus, 10%
Cu/C catalyst powder (C-10*) was obtained. Its XRD revealed that the supported face-centered cubic Cu had a lattice constant a of 3. 620 A.
Pt:Cu atomic ratio (composition) and face-centered cubic (fcc) solid solution alloy lattice constants are given together in Table 1.
Table 1 Composition and lattice constant of Pt-Cu alloy supported on carbon Catalyst Analytical quantity Composition Lattice No. of supported metal (atomic ratio) constant Pt(wt%) Cu(wt%) Pt(%) Cu(%) (A) C-l* 10. 30 0 100 0 3.923 C-2* 10.24 0.87 79 21 3.876 C-3* 9.99 1.02 76 24 3.863 C-4* 9.90 1.64 66 34 3.842 C-5* 9.84 3.10 51 49 3.793 C-6* 9.73 5.01 39 61 3.756 C-7* 9.47 6.58 32 68 3.738 C-8* 9.34 8.06 27 73 3.723 C-9* 8.51 14.3 16 84 3.687 C-10* 0 10.1 0 100 3.620 The relationship between composition (or atomic ratio) and solid solution alloy face-centered cubic lattice constant a in the above Pt-Cu alloy supported catalyst is shown in Fig. 1. The plotting of the composition and lattice constant of the catalysts (C-l*) to (C-10*) of Production Examples 1 to 10 gave the Vegard law's curve as shown in Fig. 1. As is seen therefrom, the Pt-Cu alloys in the Pt-Cu alloys supported on carbon form substantially perfect solid solution alloys over the whole compositional range of from Cu 100% to Pt 100%, according to the Vegard law.
Example 1 (Production Example 11) Production of Platinum skeleton alloy supported catalyst:
20 g of the Pt-Cu alloy-supported catalyst (C-9*) powder of Comparative Example 3 was put into a 300 ml Teflon beaker with a cover, and 160 ml of 105% polyphosphoric acid was added thereto, followed by stirring while purging the inside of the beaker with nitrogen gas, using a stirring rod made of Teflon, so as to maintain the state of uniform suspension. The beaker was heated on a mantle heater to raise the temperature to 200~, and the temperature was maintained with stirring for 4 hours.
After cooling to room temperature, the slurry obtained was poured into 300 ml of cold deionized water to effect dilution, followed by filtration. The resultant solid was -20 washed with deionized water until the filtrate ~me to have a lower conductivity than 20 ~ S /cm, and the cake obtained was dried at 95~ in a stream of nitrogen for 16 hours to obtain Pt-Cu alloy-supported catalyst (C-ll), the Pt-Cu alloy having been subjected to leaching. Its CA 022l4076 l997-08-2 elementary analysis revealed that it had composition of 9. 8%
Pt-1.03% Cu/C (Pt:Cu atomic ratio being 76:24). Analysis of a mixed solution of the filtrate and the washing liquid revealed that Platinum dissolved out in a very small quantity (not more than 1% of the Platinum charged) and only Cu was selectively dissolved out. The XRD revealed that the catalyst had a Pt (111) crystallite diameter of 39 A and a face-centered cubic lattice constant a of 3.745 A.
Incidentally, the alloy crystal lattice constant corresponding to the composition with a Pt:Cu ratio of 76:24 readable from the Vegard law's curve in Fig. 1 was a = 3.868 A. As a matter of fact, the solid solution alloy-supported catalyst (C-3*) having thé composition with a Pt:Cu ratio of 76:24, separately IS produced from 10% Pt/C (C-l*) according to Production Example 2 had a lattice constant of 3. 863 A.
Thus, the C-ll, despite having the composition with a Pt:Cu ratio of 76:24, had a lattice constant which was greatly smaller than the lattice constant 3. 868 A of -20 the solid solution alloy corresponding to this composition and was close to the a = 3. 687 A of the starting solid solution alloy having a Pt:Cu ratio of 16:84. Even though the Cu in the Pt-Cu alloy had been removed, the lattice constant was given as if the Cu were present, and hence the present catalyst (C-ll) was identified as a skeleton catalyst having the structure of vacant lattice site type lattice defects. A
programmed-temperature XRD cell was packed with powder of S C-11, and the XRD spectrum at each temperature was measured while raising temperature from room temperature such as 50~, 100~ and 150~ at the intervals of 50~ in a stream of nitrogen gas. As a result, although the lattice constant was a = 3. 790 A at 300~C, showing almost no change from the state at room temperature, it was a = 3. 852 A at 700~, showing a change to the lattice constant close to the - Vegard law's curve in Fig. 1.
Thus, also from the change in lattice constant upon heating to a high temperature in an inert gas, it was confirmed that the catalyst C-ll was a skeleton catalyst having the structure of vacant lattice site type lattice defects.
The locations of C-9*, C-ll and C-3* are plotted in Fig. 1.
Comparati~re Example 4 (Production Example 12) Production of platinum supported catalyst:
A 20~ Pt/C catalyst (C-12*) was produced in the same manner as in Comparative Example 1 except that 72 g CA 02214076 1997-08-2~
of carbon black powder was slurried in deionized water containing 8.0 g of glacial acetic acid, an aqueous amine solution of H2Pt(OH) 6 in an amount corresponding to 18.0 g of Platinum was added, followed by reduction with 100 g of an aqueous 5%
formic acid solution.
Comparative Example 5 (Production Example 13) Production of platinum-copper alloy supported catalyst:
The procedure of Production Example 3 was repeated except that 50 g of the Pt/C catalyst (C-12*) of Production Example 12 was used and, to 2,500 ml of its deionized water slurry, 150 ml of an aqueous solution containing 3.2 g of Cu as copper (II) nitrate was added. Thus, a Pt-Cu alloy/C catalyst (C-13*) was obtained. Its elementary analysis revealed that it contained 18.8% by weight of Pt and 6.0% by weight of Cu in terms of dry weight, having a Pt:Cu atomic ratio of 50:50, and its XRD revealed that the catalyst was an alloy-supported catalyst having a Pt (111) crystallite diameter of 45 A and a face-centered cubic lattice constant a of 3.790 A.
The catalyst C-13* is an alloy-supported catalyst originating from 20% Pt/C, but its lattice constant is on the Vegard law's curve of the composition-lattice constant correlation of the Pt-Cu alloy-supported catalyst originating from 10~ Pt/C.
Example 2 (Production Example 14) Production of platinum skeleton alloy supported catalyst (C-14):
The procedure of Example 1 was repeated except that the Pt-Cu alloy-supported catalyst (C-13*) obtained in Production Example 13 was maintained in a stream of nitrogen gas in a 105% phosphoric acid slurry at 200 C for 2 hours. Thus, a leaching residue (C-14) was obtained. Its elementary analysis revealed that it contained 19.7% by weight of Pt and 2.6% by weight of Cu in terms of dry weight (Pt:Cu atomic ratio being 71:29), and its XRD revealed that it was a catalyst having a Pt (111) crystallite diameter of 38 A and a face-centered cubic lattice constant a of 3.812 A. As viewed from Fig. 1, the lattice constant of the face-centered cubic solid solution alloy corresponding to the alloy having Pt:Cu atomic ratio of 71:29 is a = 3.852 A, and hence the catalyst C-14 was identified as a platinum skeleton catalyst.
Comparative Example 6 (Production Example 15) Production of platinum-cobalt alloy supported catalyst (C-15*):
The procedure of Production Example 3 was repeated except that 50 g of the Pt/C catalyst (C-12*) of Production Example 12 was slurried in deionized water and 150 ml of an agueous solution containing 3.2 g of Co as cobalt (II) nitrate was added. Thus, a Pt-Co alloy/C catalyst (C-15*) was obtained. Its elementary analysis revealed that it contained 18.9% by weight of Pt and 5.7% by weight of Co in terms of dry weight (Pt:Co atomic ratio being 50:50), and its XRD revealed that the catalyst was a solid solution alloy-supported catalyst comprised of only a face-centered cubic alloy having a crystallite diameter of 32 A and a lattice constant a of 3.767 A.
Example 3 (Production Example 16~
Production of platinum skeleton alloy supported catalyst (C-16~:
The procedure of Example 1 was repeated except that the Pt-Co solid solution alloy-supported catalyst (C-15*) obtained in Productlon Example 15 was used. Thus, a leaching residue (C-16) was obtained. Its elementary analysis and XRD revealed that it contained 19.9 by weight of Pt and 1.2~ by weight of Co in terms of dry weight (Pt:Co atomic ratio being 83:17) and it was a CA 02214076 1997-08-2~
face-centered cubic alloy catalyst having a crystallite diameter of 29 A and a lattice constant a of 3.787 A.
Meanwhile, in a Pt-Co solid solution alloy-supported catalyst (C-17*) separately produced (as Production Example 17) in the same manner as in Production Example 15 except that the amount of Co charged was changed to 0.60 g, its XRD showed a face-centered cubic lattice constant a of 3.860 A. That is, the C-16, despite having the same composition as C-17*, had a clearly smaller lattice constant, which was close to that of the Co-rich alloy supported in the catalyst C-15* before removal of Co, and hence it was identified as a skeleton alloy-supported catalyst from the lattice sites of which Co was removed.
Comparative Example 7 (Production Example 18) Production of platinum-nickel alloy supported catalyst (C-18*):
The procedure of Production Example 3 was repeated except that the Pt/C catalyst (C-12*) of Production Example 12 was used and, to a slurry thereof, an aqueous solution containing 4.0 g of Ni as nickel (II) nitrate was dropwise added. Thus, a Pt-Ni solid solution alloy supported catalyst (C-18*) was obtained. Its XRD revealed that it was comprised of a face-centered cubic alloy having a lattice constant a of 3. 762 A.
Example 4 (Production Example 19) Production of ~latinum skeleton alloy supported catalyst rc-19) The procedure of Example 1 was repeated except that the Pt-Ni alloy-supported catalyst (C-18*) obtained in Production Example 18 was used, 100 ml of the 105 polyphosphoric acid was replaced with 100 ml of a 0.5N aqueous nitric acid solution and the mixture was maintained in a stream of nitrogen gas at 60~ for 5 hours. Thus, a platinum skeleton alloy supported catalyst (C-19) was obtained, having a Pt:Ni atomic ratio of 75:25 and comprised of a face-centered cubic alloy having a lattice constant a of 3.784 A. Meanwhile, in a catalyst of Pt-Ni solid solution alloy having a Pt:Ni atomic ratio of 75:25 supported on carbon (C-20*) separately produced (in Production Example 20) in the same manner as in Production Example 17 except that the amount of Ni charged was changed to 0.85 g, it had a face-centered cubic lattice constant a of 3. 860 A.
which an alloy of platinum with a base metal element such as gallium, titanium, vanadium, chromium, iron, cobalt, nickel or copper is supported have been developed in order to improve the activity of oxygen reduction reaction in the cathode (U.S. Patent Nos. 4,186110 and 4,447,506, Japanese Pre-exAmin~tion Patent Publication (kokai) Nos. 60-7941, 61-8851 and 62-163746, etc.). Meanwhile, as electrocatalysts for proton-exchange membrane type fuel cells, platinum black catalysts have been used from old times, but catalysts comprising a conductive carbon powder on which platinum is highly dispersedly supported are now put into use so that the amount of platinum used can be reduced. Also in such catalysts, researches are made on catalysts formed of an alloy with a base metal so that the oxygen reduction activity of the cathode can be improved ~G. T~mi7h~oni & G.A. Capuano, J. Electrochem. Soc., Vo.141, No.4 (1994)].
Such platinum alloy-supported catalysts are usually produced in the following way. First, platinum is supported on a conductive carbon p~wder to prepare a platinum-supported carbon powder (a precursor), and then this precursor platinum-supported carbon powder is added in an aqueous solution of a compound such as a salt of base metal element to fix the base metal component on the CA 022l4076 l997-08-25 platinum-supported carbon by the aid of an alkali such as sodium-hydroxide or ammonia or a reducing agent such as hydrazine or for~l in, followed by treatment in a stream of nitrogen or in a stream of hydrogen at a high temperature of 800~ to l,000~ to alloy the base metal and platinum.
Such platinum alloy-supported catalysts have an improved oxygen reduction activity compared with the precursor platinum-supported carbon powder and hence are known to be greatly improved in current-voltage characteristics (I-V characteristics;
the same applies hereinafter) when used as cathode catalysts for phosphoric acid type fuel cells.
Japanese Pre-~minAtion Patent Publication (kokai) No. 3-I27459 reports that in the production of such an alloy-supported catalyst all the base metal used is not completely made into an alloy and is partly deposited on and adheres to the carbon surface, and it is proposed to remove free base metal by washing the catalyst with an aqueous dilute acid solution to thereby suppress the wetting of the catalyst to the electrolyte so that the cell can have a longer lifetime.
Advantages of skeleton catalysts whose representative is Raney nickel are also known from old times.
Platinum skeleton catalyst electrodes prepared by dissolving the base metal component out of an electrode formed of an alloy of platinum with a base metal, not supported on a carrier, were studied in the 1960's as electrodes for 5 fuel cells (U.S. Patent No. 3, 429, 750). Meanwhile, a platinum-supported skeleton catalyst prepared by removing Fe from a Pt-Fe alloy-supported catalyst (U.S. Patent No.
4,187, 200) iS known to exhibit a high activity in hydrogenation reaction, but there is no disclosure as to whether it is useful as an electrocatalyst.
Under operation conditions of fuel cells in which an acid electrolyte and oxygen are present together, not only the base metal not alloyed with platinum but also the base metal in platinum-base metal alloy crystals can not avoid gradually dissolving in the electrolyte. The base metal having dissolved in the electrolyte is either reduced at a portion having a more basic potential in the cell to become deposited there, or crystallized because of a lowering of solubility at a lower-temperature portion to become deposited, thus there is a possibility of clogging pores of a gas diffusion electrode. Especially in the case of proton-exchange membrane type fuel cells, there is also a possibility that base metal ions react with the electrolyte to cause a lowering of the conductivity of the electrolyte.
Hence, in order to make fuel cells have a longer lifetime, it is desired to make the base metal less dissolve out of the alloy.
Meanwhile, in the base metal/platinum alloy-supported catalysts, it is usually indispensable to alloy the materials at a high temperature in the step of preparation. As a result of this high-temperature treatment, the platinum is alloyed with the base metal and at the same time may cause crystal growth.
Hence, it is not always easy to prepare a platinum alloy catalyst having, e.g., an average crystal particle size not larger than 50 A (angstrom, 1 A = O.l nm;
the same applies hereinafter). Accordingly, it is sought to provide as an electrocatalyst for fuel cells a platinum-supported catalyst that retains crystal-forms of an alloy highly active in oxygen reduction and yet has platinum alloy particles made finer and also containing less base metal component.
SUMMARY OF THE INVENTION
To solve the above problems, the present inventors made extensive studies on how the crystal forms of platinum alloys supported on carbon affect the activity and lifetime required as electrocatalysts for fuel cells. As the result, they have discovered , - 6 -that a skeleton catalyst comprising an alloy of platinum with a specific base metal component, the base metal component having been selectively removed from alloy crystals, exhibits an unexpectedly high activity and long-term stability as a fuel cell electrocatalyst, and thus have accomplished the present invention, More specifically, the electrocatalyst of the present invention is a catalyst comprising an alloy of platinum with at least one base metal selected from the group consisting of gallium, vanadium, chromium, manganese, iron, cobalt, nickel and copper, having a structure of vacant lattice site type lattice defects (hereinafter said alloy being referred to as "platinum skeleton alloy~) and a conductive carbon powder, the alloy being supported on the conductive carbon powder (hereinafter the catalyst being referred to as "platinum skeleton alloy supported catalyst").
The platinum skeleton alloy catalyst of the present invention has a lattice constant compressed to the one comparable to a base metal-rich solid solution alloy and has a smaller crystallite diameter, and hence can have a very higher mass activity for the oxygen reduction reaction in the cathode of fuel cells than conventional catalysts of - platinum-base metal alloy-supported on carbon. Moreover, because of a greatly controlled content of the base metal, the catalyst has a superior long-term stability, and acid electrolyte fuel cells using this catalyst exhibit a higher out-put and a longer lifetime, and can be greatly effective in practical use.
BRIEF DESCRIPTION OF THE DRAWINGS
Fig. 1 is a graph showing the relationship between Pt-Cu atomic ratio and face-centered cubic lattice constant of a platinum-copper solid solution alloy supported on a carbon carrier.
Fig. 2 is a graph showing chanyes with time of IR-free terminal voltages in a test in which phosphoric acid fuel cells respectively having as the cathode an electrode using a catalyst according to an example of the present invention and and electrode using a catalyst according to a comparative example are operated at a constant current density.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
- Electrocatalyst -Platinum skeleton alloy:
The platinum skeleton alloy which is an active metal of the catalyst of the present invention is supported on a conductive carbon powder in the state of fine particles.
The platinum skeleton alloy is an alloy in which the base metal in the crystal lattice of a precursor thereof, a platinum-base metal alloy, has been removed at least in part. This precursor alloy S is a substitutional solid solution alloy. In general, single platinum is face-centered cubic (fcc), and substitutional solid solution alloys formed by alloying platinum and other metal elements may have various crystal forms. However, solid solution alloys formed by alloying platinum and at least one base metal selected from the group consisting of gallium, vanadium, chromium, manganese, iron, cobalt, nickel and copper have any of disordered face-centered cubic, ordered cubic and ordered tetragonal forms. In addition, in these alloys, the diffraction angle 2 ~ corresponding to the main diffraction line (lll) in their X-ray diffraction is present on the side of a higher angle than that of the single platinum, and crystal lattice constant ac of the cubic alloys or lattice constants ae and ct of the tetragonal alloys has/have the relationship of ac < aO, or at{3/(2+at2/Ct2)~l/2 < aO~ with respect to lattice constant aO of the single platinum.
It has been found that, when the base metal only is selectively removed at least in part from such a CA 02214076 1997-08-2~
platinum-base metal alloy while retaining the crystal form of the alloy, the lattice sites having been held by the base metal become vacant, so that an alloy having vacant lattice site type lattice defects, i.e., the platinum skeleton alloy can be obtained. With an increase in the degree at which the base metal is removed, the alloy becomes finer as a result of the break of alloy particles.
Such a platinum skeleton alloy retains its original crystal form even though the compositional proportion of platinum has become larger than the original solid solution alloy, and hence it exhibits a higher oxygen reduction activity than the single platinum of course and than any compositionally corresponding solid solution alloys lS (having substantially no vacant lattice site).
In the platinum skeleton alloy supported catalyst of the present invention, there are no particular limitations on the amount of the platinum and base metal to be supported on the carrier, conductive carbon powder, and on the atomic ratio of platinum to base metal. Preferably, the platinum may be supported in an amount of 1% to 60%, and particularly preferably 5% to 50%, based on the whole catalyst (the amount of the metal to be supported, based on the whole catalyst, is indicated by weight; the same applies CA 02214076 1997-08-2~
hereinafter); in the case of a cathode catalyst for phosphoric acid type fuel cells, particularly preferably from 5% to 30%, and in the case of a cathode catalyst for proton-exchange membrane type fuel cells, particularly preferably from 20% to 50%.
The amount of the base metal r~-ining in the platinum skeleton alloy may be 0% in an extreme case, but there is no advantage in practical use if it is completely removed. In usual cases, the platinum and base metal in the platinum skeleton alloy may preferably be in an atomic ratio of from 1:1 to 1:0.05, and particularly preferably from 1:0.5 to 1:0.1.
Conductive carbon powder:
As the conductive carbon powder used as a carrier in the electrocatalyst of the present invention, any conductive carbon powders known as carriers for fuel cell electrocatalysts may be used.
More specifically, carbon black powders such as oil furnace black and acetylene black may be used which have characteristics of a BET specific surface area of from 50 to 1,500 m2/g, a graphite (002) crystallite diameter of from 7 to 80 A, a graphite crystal interlattice distance dc (002) of from 3.40 to 3.70 A, and a DBP oil absorption of from 50 to 700 ml/100 gC. These carbon black may be CA 02214076 1997-08-2~
heated at 1,600~ to 2,800~ in an inert gas or in vacuo in order to improve durability under conditions where acid electrolyte fuel cells are used, or may be heated at 500~
to 900~ in an atmosphere of water vapor to improve surface roughness so that the volatile components can be removed and also the catalyst active metal can be more stably supported. In particular, as the carrier of the cathode catalyst for phosphoric acid type fuel cells, at least partially graphitized carbon black having a BET specific surface area of from 50 to 180 m2/g and a graphite (002) crystallite diameter of from 10 to 70 A is preferred. As the carrier of the cathode catalyst for proton-exchange membrane type fuel cells, carbon black having a BET specific surface area of from 120 to 1,500 mZ/g and a graphite (002) crystallite diameter of from 7 to 35 A is particularly preferred.
- Production of Electrocatalyst -The electrocatalyst ofplatinum skeleton alloy supported on carbon of the present invention, having the structure of vacant lattice site type lattice defects described above, can be produced in the following way.
That is, in the first step, the solid solution alloy of platinum with at least one base metal selected from the group consisting of gallium, vanadium, chromium, manganese, iron, cobalt, nickel and copper is supported on the conductive carbon powder in a highly dispersed state to form a catalyst precursor of platinum alloy supported S on carbon. Next, in the second step, the catalyst precursor is subjected to treatment to selectively remove only the base metal component at least in part from the crystal lattice of catalyst precursor while retaining the crystal form to thereby bring about the structure of vacant lattice site type lattice defects, thus the desired catalyst can be produced.
There are no particular limitations on methods for preparing the precursor catalyst of platinum alloy supported on carbon so long as the ordered alloy or disordered solid solution alloy is formed in a highly dispersed state. Various known preparation methods may be used, as exemplified by an alloying method in which catalyst components are supported in a single-step followed by heat treatment, an alloying method in which the catalyst component is supported in a multiple-step followed by heat treatment, and a method in which the base metal is alloyed and supported on a platinum-supported carbon powder (the electroless plating method).
As a degree of alloying, it is preferred that the greater part (90% or more) of the base metal supported on carbon is present as an alloy with platinum and the base metal present apart from platinum on the carbon is less than 10%, or that the greater part (90% or more) of the platinum supported on carbon is present as an alloy with base metal and the platinum present singly by itself on the carbon is less than 10%. They can be alloyed in such a sufficient degree in the following way: For example, in the case of an alloying method in which catalyst components are supported in a two-step followed by heat treatment, first the platinum is supported on carbon powder in a highly dispersed state to prepare a platinum-supported carbon powder. Next, this IS platinum-supported carbon powder is slurried in an aqueous dilute solution of a salt of the base metal element, and the base metal element is adsorbed or fixed on the platinum-supported carbon powder by alkali treatment or wet-process reduction, followed by filtration, washing and drying to prepare a-base metal and platinum-supported carbon powder as a precursor or intermediate. Then, this is retained in an inert gas such as nitrogen or helium, in vacuo or in a stream of hydrogen gas, at a temperature necessary and sufficient for completely alloying the base CA 022l4076 l997-08-2 metal and platinum supported on the carbon carrier and of a degree not to cause excessive aggregation (sintering) of the alloy crystals formed, and for a necessary and sufficient time, followed by cooling to room temperature. These conditions depend on the method for obtaining the desired catalyst of platinum alloy supported on carbon carrier. The alloying by heat treatment may preferably be carried out at a temperature of, e.g., from 750~ to 1,000~, and more preferably from 800~ to 900~, for a retention time of from 1 minute to 5 hours, and more preferably from 20 minutes to 2 hours.
Whether or not the precursor or intermediate obtained in the first step is in a sufficiently alloyed state can be ascertained by various methods. For example, it can be microscopically ascertained by observation of powder using an analytical trAn~mi~sion electron microscope.
More specifically, it can be ascertained when, in a transmission electron microscope (TEM) image of 300,000 to - 20 1,000,000 magnifications, every particle of metal particles of tens of angstroms in diameter, supported on the surfaces of carbon particles of hundreds of angstroms in primary particle diameter, gives values of elementary analysis which are almost in conformity with the alloy composition of the whole powder (bulk) in respect of its energy dispertive X-ray spectroscopy (EDX) and on the other hand the EDX at every part of the carbon carrier detects no significant presence of each of the base metal and the platinum alone.
The state of being alloyed can be macroscopically ascertained by plotting lattice constants vs. alloy compositions of solid solution alloys.
More specifically, catalyst of platinum alloy-supported on carbon carrier with a series of composition are prepared by changing the atomic ratio of platinum to base metal, and X-ray diffraction lattice constants of the respective alloys are measured to plot the composition vs.
lattice constant on X-Y coordinates, where the Vegard law is established so long as a perfect solid solution alloy is formed within a given compositional range, and the lattice constants of the alloy are on a diagonal line connecting the respective lattice constants of the single platinum and the single base metal or a curve which is close thereto.
The second step in the production process of the catalyst of the present invention will be detailed below. The second step is the step of making treatment to selectively remove only the base metal component at least in part from the crystal lattice of the catalyst precursor of platinum alloy-supported on carbon carrier while retaining the structure and physical properties of the carbon carrier and while retaining the crystal form of the platinum alloy supported thereon, to thereby bring about the structure of vacant lattice site type lattice defects;
thus the catalyst of platinum skeleton alloy-supported on carbon carrier being obtained.
There are no particular limitations on methods for the above so long as they are methods of selectively removing only the base metal component from the alloy crystal lattice while retaining the crystal form of the platinum alloy without changing the structure and physical properties of the carbon carrier. For example, known methods can be used in which the catalyst precursor of platinum alloy-supported on carbon is treated with an aqueous solution of an acid that dissolves the base metal element but does not dissolve the platinum (i.e., liquid-phase leaching), or heat-treated in a gas stream of a gas of an element or compound that forms a volatile compound with the base metal element but does not form a volatile compound with the platinum, as exemplified by chlorine (Cl2) or carbon monoxide (CO) (i.e., gas-phase leaching). There are no particular limitations on the rate of removal of the base metal element. As stated previously, the base metal may be completely removed from the alloy crystal lattice without changing the crystal form, and it is not impossible to do so, but not essential in practical use. In usual cases, the base metal may be removed in such an amount of 20% to 99%, and preferably from 30~ to 95%, of its content in the original platinum solid solution alloy.
Any excessive leaching is not preferable because it may cause a change in crystal form. Any excessive application of heat during the leaching or after the leaching or any leaching carried out under conditions that may cause dissolution of platinum in the alloy is not preferable because it might cause a change in lattice constants of platinum to change into the e~uilibrium lattice constants of the platinum-rich solid solution alloy corresponding to the composition which would be formed if the dissolution occurs (i.e., change into an alloy of crystal structure having no vacant lattice sites).
It is also not preferable that the structure and physical properties of the carrier conductive carbon powder greatly change with the leaching treatment of the base metal.
If the structure of carbon is cut off or the corrosion of surfaces proceeds, there is a possibility of causing CA 022l4076 l997-08-2 the supported solid solution alloy to come off, dissolve or aggregate.
As a method for selectively removing the base metal component from the crystal lattice while retaining S the crystal form of the catalyst precursor, supported platinum solid solution alloy without changing the structure and physical properties of the carbon carrier, it is preferable to suspend the platinum solid solution alloy-supported carbon powder in phosphoric acid heated to 100~ to 200~ or in an a~ueous mineral acid solution kept at a temperature of room temperature to 100~ in an atmosphere where the oxygen pressure has been made lower than air, preferably in an atmosphere containing substantially no oxygen, e.g., in a stream of nitrogen, and maintain the resultant suspension with stirring for a certain time, followed by cooling, filtering, and washing with hot deionized water until the filtrate has an electrical conductivity of 20 ~ S/cm or - 20 less, and subsequently drying in vacuo or in an stream of nitrogen gas at 110~ to obtaln the desired catalyst. As the mineral acid, sulfuric acid and nitric acid are preferred, which may preferably be in a concentration of from 0.1 to 1.0 N. The heated phosphoric acid may CA 02214076 1997-08-2~
preferably be in a concentration of from 85 to 105%.
If such wet leaching with an acid is carried out in the atmospheric environment, the catalyst is exposed to an open-circuit potential of 1 V or higher at the interface where the catalyst slurry come into contact with oxygen, so that the platinum may dissolve out of the alloy or the corrosion of the carbon powder may proceed, thus such leaching is not preferred. In the atmospheric environment, the lattice constant of the platinum skeleton alloy tends to greatly come near to that of the platinum-rich solid solution alloy.
Whether or not the platinum skeleton alloy supported carrier has been formed as a result of the second step can be ascertained in the following way. First, elementary analysis of the catalyst obtained is carried out to make sure that only the base metal has been removed out of the initially supported alloy and the platinum and carbon have been recovered. Powder process XRD (X-ray diffractometry) of the catalyst is further carried out to make sure that the crystal form of the original platinum solid solution alloy is retained, and that the lattice constant is retained substantially in the state of the original solid solution alloy though a little change may occur, that is, it is close to that of the original base metal-rich solid solution alloy rather than to the lattice constant that the resultant platinum skeleton alloy would have, if it were a solid solution alloy.
Whether or not the supported platinum skeleton alloy used in the present invention has the structure of vacant lattice site type lattice defects, i.e., a non-equilibrium crystal structure can be ascertained in the following way. The powder of the platinum skeleton alloy supported catalyst of the present invention is subjected to in situ XRD in an atmosphere of inert gas or in vacuo. As the temperature is gradually raised from room temperature up to a temperature to be used when the materials are alloyed, it is ascertained that the crystal form and lattice constant of the alloy change from those of the platinum skeleton alloy to those of the solid solution alloy corresponding to the platinum-rich composition from which the base metal has been removed. Even after cooling to room temperature, the change in crystal form and lattice constant that has taken place during the temperature rise is maintained, and the crystal form and lattice constant no longer return to those of the original platinum skeleton alloy. That is, in the platinum skeleton alloy supported catalyst obtained in the second step, the platinum skeleton alloy still retains, in the platinum-rich composition from which the base metal has been removed, the equilibrium crystal form and lattice constant in the base metal-rich composition. Thus, the platinum skeleton alloy is shown to have a structure of vacant lattice site type lattice defects.
The BET specific surface area of the catalyst is measured and the carbon graphite ( 002) crystallite diameter and crystal interlattice distance are analyzed by XRD to ascertain that there is no change in structure and physical properties of the carrier carbon.
There are also no particular limitations on the platinum crystallite diameter of the platinum skeleton alloy supported catalyst of the present invention, thus obtained. It may preferably be from 15 to 100 A, and particularly preferably from 20 to 60 A.
There are still also no particular limitations on the metal surface area of the platinum. It may preferably be from 30 to 200 m2/g Pt, and particularly preferably from 50 to 150 m2/g Pt. In the present specification, the metal surface area of platinum is indicated as an electrochemical metal surface area EC. MSA (m2/g Pt) obtained by measuring electrical quantity of hydrogen absorption on the platinum surface in the cathodic sweep of cyclic voltammetry made on catalyst electrodes.
- Characteristics -In the present specification, the electrochemical oxygen reduction activity of the catalyst is evaluated onthe basis of mass activity. The mass activity is determined in the following way. In an oxygen-electrode half cell (~2 half cell), a current density (mA/cm2) obtained at a potential of plus 900 mV vs. a reference hydrogen electrode (RHE, the same applied hereinafter) is determined, and the resultant value is divided by a platinum loading amount (mg Pt/cm2) per electrode unit area to give a current density per unit platinum mass, i.e., the mass activity (mA/mg Pt).
Stated more specifically, first, according to the electrode preparation method described later, the carbon carrier catalyst powder is bound to carbon paper together with water-repellent binder to form a gas diffusion electrode, and its catalyst-layer side is disposed to the 105~ phosphoric acid heated to 200~ and the opposite side exposed to a stream of oxygen ( ~2) gas. This is incorporated in a half cell apparatus, and the current density (mA/cmZ) produced is determined when a voltage of 900 mV (IR-free) vs. the reference hydrogen electrode (RHE) is applied between the working electrode and the platinum CA 02214076 1997-08-2~
mesh counter electrode, and the resultant value is divided by a platinum loading amount (mg Pt/cm2) per electrode unit area to give the mass activity (mA/mg Pt).
In the platinum skeleton alloy supported catalyst of S the present invention, the platinum is very highly activated.
Especially when used as the cathode electrode for fuel cells, it exhibits a higher oxygen reduction activity than the platinum single supported catalyst as a matter of course and than any of the catalyst precursor having platinum alloy supported on carbon, with no vacant lattice sites and the catalyst of solid solution alloy supported having the composition corresponding to that after removal of the base metal but having no vacant lattice sites.
A typical platinum supported catalyst (20%Pt/C) has a mass activity of 39 mA/mg Pt, and a known catalyst A
of base metal-rich platinum-base metal alloy-supported on carbon (19% Pt-6% Cu/C) and a known catalyst B of platinum-rich platinum-base metal alloy-supported on carbon (20% Pt-1.5% Cu/C) have a mass activity of 69 mA/mg Pt and 70 mA/mg Pt, respectively. In contrast, the catalyst of platinum skeleton alloy-supported on carbon (20% Pt-2.6%
Cu/C) of the present invention, originating from the catalyst A, has a mass activity of 80 mA/mg Pt, showing a higher activity than any of known catalysts.
The platinum skeleton alloy supported catalyst of the present invention was used in the air-electrode cathode, a conventional platinum supported catalyst was used in the anode and an SiC
matrix sheet impregnated with 105% phosphoric acid was held between a pair of these electrodes to set up a small-size single cell. Under the conditions that air was passed through the cathode and hydrogen gas or the reformate model gas comprised of 80% hydrogen and 20% CO2 was passed through the anode, a long-term operation test for thousands of hours or longer was carried out at a constant cell temperature in the range of 190~ to 220~C. In such a test, it has been found that the cell using the catalyst of the present invention in the cathode has a higher initial ter~inA1 voltage, and has a smaller rate of deterioration of the ter~inAl voltage when operated at a constant current density and has been made stabler than any of the single - 20 platinum supported catalyst, the catalyst precursor of platinum alloy supported on carbon having no vacant lattice sites and the platinum solid solution alloy supported on carbon having the same composition as that of the present invention but having no vacant lattice sites.
- Electrode for Fuel Cells -The electrode for fuel cells employing theplatinum skeleton alloy supported catalyst of the present S invention will be described below.
This electrode for fuel cells comprises the platinum skeleton alloy supported catalyst described above and a water-repellent binder which are bound to a conductive and porous support substrate. In addition, especially as the electrode for phosphoric acid type fuel cells, it is essential for the support substrate to be acid-resistant.
As the water-repellent binder, polymer binders as exemplified by polytetrafluoroethylene, polyfluoroethylene propylene and perfluoroalkoxypolyethylene may be used. As the conductive and acid-resistant porous support substrate, gas-permeable carbon paper which have been subjected to water-repellency treatment with the above water-repellent binder, or a mesh screen of metal such as, tantalum and niobium may be used. This is especially useful as the electrode for acid electrolyte fuel cells, in particular, as the oxygen reduction cathode of phosphoric acid type fuel cells.
The electrode of the present invention can be produced, e.g., in the following way. First, the platinum skeleton alloy supported catalyst obtained as described above is mixed with a suspension of polytetrafluoroethylene to form a uniform suspension.
Meanwhile, carbon paper having been subjected to water-repellency treatment with a s; m; 1 ~r acid-resistant polymer material is prepared, and the uniform mixture suspension of the above catalyst and the water-repellent binder is coated thereon by filtration suction, spraying or roll coating, followed by pressure bonding and then baking in an atmosphere of inert gas.
The platinum skeleton alloy may preferably be present on the electrode support substrate only in an catalytically effective amount, which is usually in the range of from O.l to 3 mg, more preferably from O. 2 to 2 mg, and still more preferably from 0.5 to 1 mg, in terms of platinum per square centimeter of geometrical surface area of the electrode support substrate.
The present electrode can be used as a gas diffusion electrode such as a button cell, a gas sensor electrode or an electrolysis electrode, and is especially suitable as an electrode for acid electrolyte fuel cells. As electrolytes used in such fuel cells may include phosphoric acid, sulfuric acid, hydrochloric acid, and super acid such as trifluoromethanesulfonic acid, difluoromethanedisulfonic acid and polytrifluoroethylenesulfonic acid, or mixtures of any of these.
EXAMPLES
The present invention will now be described below in greater detail by way of Examples and Comparative Examples. The present invention is by no means limited to these.
1.-Production of catalyst:
Comparative Example 1 (Production Example 1) Production of ~latinum skeleton alloY supported catalyst:
In 1,500 ml of deionized water containing 4.0 g of glacial acetic acid, 81 g of heat-treated conductive carbon black (trade name: W LCAN XC-72R, available from Cabot Corp.) having a specific surface area of 110 mZ/g was dispersed by ultrasonic dispersion machine and made into a slurry. In 600 ml of deionized water, 9.0 g of platinum as H2Pt(OH)6 was dissolved together with amine to prepare a platinum solution. The platinum solution was added to CA 02214076 1997-08-2~
the carbon slurry with stirring. Thereafter 50 g of an aqueous 5% formic acid solution was added as a reducing agent, and the temperature was then raised to 95~.
After the mixture was maintained at 95~ for 30 minutes, it S was cooled to room temperature, followed by filtration and then washing with deionized water. The filtered cake thus obtained was dried in a stream of nitrogen at 95~ for 16 hours. Powder process XRD of the resultant 10 wt.% Pt/C
(C-l*) (the asterisk * means Comparative Example;
the same applies hereinafter) revealed that it had a Pt (111) crystallite diameter of 15 A and a face-centered cubic lattice constant a of 3.923 A.
Comparative Example 2 ~Production Examples 2 to 9) Production of platinum-copper alloy-supported catalysts:
In 1,000 ml of deionized water, 50 g of Pt/C powder (C-l*) obtained in Production Example 1 was dispersed by means of an ultrasonic dispersion machine and made into a slurry. To this slurry, 150 ml of an aqueous solution containin~-0.435 g of Cu-as copper (II) nitrate was added with the slurry being stirred thoroughly vigorously, and thereafter the pH of the slurry was adjusted to 8.0 while slowly dropwise adding an 5%
hydrazine dilute aqueous solution. After stirring at room temperature for 1 hour, the slurry was filtered and then washed with deionized water. Thereafter, the resultant cake was dried in a stream of nitrogen at 95~ for 16 hours.
Subse~uently, this was kept in a stream of 7% by volume of hydrogen (the balance being nitrogen) at 900~ for 1.2 hour, and thereafter cooled to room temperature to obtain Pt-Cu alloy/C (C-2*). As a result of elementary analysis, metal components were each in a content of Pt: 10.2 wt.%, and Cu: 0.87 wt.%, and Pt:Cu atomic ratio was 79%:21%.
Its XRD revealed that the face-centered cubic solid soIution alloy had a crystallite diameter of 40 A and a lattice constant a of 3.876 A. From XRD spectra of the alloy-supported catalyst, only a face-centered cubic solid solution alloy phase was detected, and neither a diffraction peak of single platinum nor a diffraction peak of single Cu was not detected at all.
In the observation on an analytical transmission electron microscope, the analysis by EDX of individual metal particles supported on carbon ascertained that the alloy composition for each particle all well corresponded to Pt:Cu atomic ratio of the bulk, thus the metal components had been substantially completely alloyed, and almost no single-platinum particles and single-copper particles were present.
The same procedure as the above was repeated but variously changing the amount of copper to produce Pt-Cu solid solution alloy-supported-on-carbon catalysts (C-3*) to (C-9*), and their lattice constants were measured by XRD.
Com~arative Example 3 (Production Example 10) Production of copper supported catalyst:
The procedure of Production Example 2 was repeated except that the 10% Pt/C was replaced with 45 g of carbon powder used in Production Example 1 to make it into a slurry, followed by addition of an aqueous copper (II) nitrate solution contAin-ng 5.0 g of Cu. Thus, 10%
Cu/C catalyst powder (C-10*) was obtained. Its XRD revealed that the supported face-centered cubic Cu had a lattice constant a of 3. 620 A.
Pt:Cu atomic ratio (composition) and face-centered cubic (fcc) solid solution alloy lattice constants are given together in Table 1.
Table 1 Composition and lattice constant of Pt-Cu alloy supported on carbon Catalyst Analytical quantity Composition Lattice No. of supported metal (atomic ratio) constant Pt(wt%) Cu(wt%) Pt(%) Cu(%) (A) C-l* 10. 30 0 100 0 3.923 C-2* 10.24 0.87 79 21 3.876 C-3* 9.99 1.02 76 24 3.863 C-4* 9.90 1.64 66 34 3.842 C-5* 9.84 3.10 51 49 3.793 C-6* 9.73 5.01 39 61 3.756 C-7* 9.47 6.58 32 68 3.738 C-8* 9.34 8.06 27 73 3.723 C-9* 8.51 14.3 16 84 3.687 C-10* 0 10.1 0 100 3.620 The relationship between composition (or atomic ratio) and solid solution alloy face-centered cubic lattice constant a in the above Pt-Cu alloy supported catalyst is shown in Fig. 1. The plotting of the composition and lattice constant of the catalysts (C-l*) to (C-10*) of Production Examples 1 to 10 gave the Vegard law's curve as shown in Fig. 1. As is seen therefrom, the Pt-Cu alloys in the Pt-Cu alloys supported on carbon form substantially perfect solid solution alloys over the whole compositional range of from Cu 100% to Pt 100%, according to the Vegard law.
Example 1 (Production Example 11) Production of Platinum skeleton alloy supported catalyst:
20 g of the Pt-Cu alloy-supported catalyst (C-9*) powder of Comparative Example 3 was put into a 300 ml Teflon beaker with a cover, and 160 ml of 105% polyphosphoric acid was added thereto, followed by stirring while purging the inside of the beaker with nitrogen gas, using a stirring rod made of Teflon, so as to maintain the state of uniform suspension. The beaker was heated on a mantle heater to raise the temperature to 200~, and the temperature was maintained with stirring for 4 hours.
After cooling to room temperature, the slurry obtained was poured into 300 ml of cold deionized water to effect dilution, followed by filtration. The resultant solid was -20 washed with deionized water until the filtrate ~me to have a lower conductivity than 20 ~ S /cm, and the cake obtained was dried at 95~ in a stream of nitrogen for 16 hours to obtain Pt-Cu alloy-supported catalyst (C-ll), the Pt-Cu alloy having been subjected to leaching. Its CA 022l4076 l997-08-2 elementary analysis revealed that it had composition of 9. 8%
Pt-1.03% Cu/C (Pt:Cu atomic ratio being 76:24). Analysis of a mixed solution of the filtrate and the washing liquid revealed that Platinum dissolved out in a very small quantity (not more than 1% of the Platinum charged) and only Cu was selectively dissolved out. The XRD revealed that the catalyst had a Pt (111) crystallite diameter of 39 A and a face-centered cubic lattice constant a of 3.745 A.
Incidentally, the alloy crystal lattice constant corresponding to the composition with a Pt:Cu ratio of 76:24 readable from the Vegard law's curve in Fig. 1 was a = 3.868 A. As a matter of fact, the solid solution alloy-supported catalyst (C-3*) having thé composition with a Pt:Cu ratio of 76:24, separately IS produced from 10% Pt/C (C-l*) according to Production Example 2 had a lattice constant of 3. 863 A.
Thus, the C-ll, despite having the composition with a Pt:Cu ratio of 76:24, had a lattice constant which was greatly smaller than the lattice constant 3. 868 A of -20 the solid solution alloy corresponding to this composition and was close to the a = 3. 687 A of the starting solid solution alloy having a Pt:Cu ratio of 16:84. Even though the Cu in the Pt-Cu alloy had been removed, the lattice constant was given as if the Cu were present, and hence the present catalyst (C-ll) was identified as a skeleton catalyst having the structure of vacant lattice site type lattice defects. A
programmed-temperature XRD cell was packed with powder of S C-11, and the XRD spectrum at each temperature was measured while raising temperature from room temperature such as 50~, 100~ and 150~ at the intervals of 50~ in a stream of nitrogen gas. As a result, although the lattice constant was a = 3. 790 A at 300~C, showing almost no change from the state at room temperature, it was a = 3. 852 A at 700~, showing a change to the lattice constant close to the - Vegard law's curve in Fig. 1.
Thus, also from the change in lattice constant upon heating to a high temperature in an inert gas, it was confirmed that the catalyst C-ll was a skeleton catalyst having the structure of vacant lattice site type lattice defects.
The locations of C-9*, C-ll and C-3* are plotted in Fig. 1.
Comparati~re Example 4 (Production Example 12) Production of platinum supported catalyst:
A 20~ Pt/C catalyst (C-12*) was produced in the same manner as in Comparative Example 1 except that 72 g CA 02214076 1997-08-2~
of carbon black powder was slurried in deionized water containing 8.0 g of glacial acetic acid, an aqueous amine solution of H2Pt(OH) 6 in an amount corresponding to 18.0 g of Platinum was added, followed by reduction with 100 g of an aqueous 5%
formic acid solution.
Comparative Example 5 (Production Example 13) Production of platinum-copper alloy supported catalyst:
The procedure of Production Example 3 was repeated except that 50 g of the Pt/C catalyst (C-12*) of Production Example 12 was used and, to 2,500 ml of its deionized water slurry, 150 ml of an aqueous solution containing 3.2 g of Cu as copper (II) nitrate was added. Thus, a Pt-Cu alloy/C catalyst (C-13*) was obtained. Its elementary analysis revealed that it contained 18.8% by weight of Pt and 6.0% by weight of Cu in terms of dry weight, having a Pt:Cu atomic ratio of 50:50, and its XRD revealed that the catalyst was an alloy-supported catalyst having a Pt (111) crystallite diameter of 45 A and a face-centered cubic lattice constant a of 3.790 A.
The catalyst C-13* is an alloy-supported catalyst originating from 20% Pt/C, but its lattice constant is on the Vegard law's curve of the composition-lattice constant correlation of the Pt-Cu alloy-supported catalyst originating from 10~ Pt/C.
Example 2 (Production Example 14) Production of platinum skeleton alloy supported catalyst (C-14):
The procedure of Example 1 was repeated except that the Pt-Cu alloy-supported catalyst (C-13*) obtained in Production Example 13 was maintained in a stream of nitrogen gas in a 105% phosphoric acid slurry at 200 C for 2 hours. Thus, a leaching residue (C-14) was obtained. Its elementary analysis revealed that it contained 19.7% by weight of Pt and 2.6% by weight of Cu in terms of dry weight (Pt:Cu atomic ratio being 71:29), and its XRD revealed that it was a catalyst having a Pt (111) crystallite diameter of 38 A and a face-centered cubic lattice constant a of 3.812 A. As viewed from Fig. 1, the lattice constant of the face-centered cubic solid solution alloy corresponding to the alloy having Pt:Cu atomic ratio of 71:29 is a = 3.852 A, and hence the catalyst C-14 was identified as a platinum skeleton catalyst.
Comparative Example 6 (Production Example 15) Production of platinum-cobalt alloy supported catalyst (C-15*):
The procedure of Production Example 3 was repeated except that 50 g of the Pt/C catalyst (C-12*) of Production Example 12 was slurried in deionized water and 150 ml of an agueous solution containing 3.2 g of Co as cobalt (II) nitrate was added. Thus, a Pt-Co alloy/C catalyst (C-15*) was obtained. Its elementary analysis revealed that it contained 18.9% by weight of Pt and 5.7% by weight of Co in terms of dry weight (Pt:Co atomic ratio being 50:50), and its XRD revealed that the catalyst was a solid solution alloy-supported catalyst comprised of only a face-centered cubic alloy having a crystallite diameter of 32 A and a lattice constant a of 3.767 A.
Example 3 (Production Example 16~
Production of platinum skeleton alloy supported catalyst (C-16~:
The procedure of Example 1 was repeated except that the Pt-Co solid solution alloy-supported catalyst (C-15*) obtained in Productlon Example 15 was used. Thus, a leaching residue (C-16) was obtained. Its elementary analysis and XRD revealed that it contained 19.9 by weight of Pt and 1.2~ by weight of Co in terms of dry weight (Pt:Co atomic ratio being 83:17) and it was a CA 02214076 1997-08-2~
face-centered cubic alloy catalyst having a crystallite diameter of 29 A and a lattice constant a of 3.787 A.
Meanwhile, in a Pt-Co solid solution alloy-supported catalyst (C-17*) separately produced (as Production Example 17) in the same manner as in Production Example 15 except that the amount of Co charged was changed to 0.60 g, its XRD showed a face-centered cubic lattice constant a of 3.860 A. That is, the C-16, despite having the same composition as C-17*, had a clearly smaller lattice constant, which was close to that of the Co-rich alloy supported in the catalyst C-15* before removal of Co, and hence it was identified as a skeleton alloy-supported catalyst from the lattice sites of which Co was removed.
Comparative Example 7 (Production Example 18) Production of platinum-nickel alloy supported catalyst (C-18*):
The procedure of Production Example 3 was repeated except that the Pt/C catalyst (C-12*) of Production Example 12 was used and, to a slurry thereof, an aqueous solution containing 4.0 g of Ni as nickel (II) nitrate was dropwise added. Thus, a Pt-Ni solid solution alloy supported catalyst (C-18*) was obtained. Its XRD revealed that it was comprised of a face-centered cubic alloy having a lattice constant a of 3. 762 A.
Example 4 (Production Example 19) Production of ~latinum skeleton alloy supported catalyst rc-19) The procedure of Example 1 was repeated except that the Pt-Ni alloy-supported catalyst (C-18*) obtained in Production Example 18 was used, 100 ml of the 105 polyphosphoric acid was replaced with 100 ml of a 0.5N aqueous nitric acid solution and the mixture was maintained in a stream of nitrogen gas at 60~ for 5 hours. Thus, a platinum skeleton alloy supported catalyst (C-19) was obtained, having a Pt:Ni atomic ratio of 75:25 and comprised of a face-centered cubic alloy having a lattice constant a of 3.784 A. Meanwhile, in a catalyst of Pt-Ni solid solution alloy having a Pt:Ni atomic ratio of 75:25 supported on carbon (C-20*) separately produced (in Production Example 20) in the same manner as in Production Example 17 except that the amount of Ni charged was changed to 0.85 g, it had a face-centered cubic lattice constant a of 3. 860 A.
In the same manner as the above, Pt-Cr, Pt-Mn, Pt-Ga-Co, Pt-V-Fe and Pt-Fe-Co solid solution alloy-supported catalysts C-21*, C-24*, C-27*,C-30* and C-33* were produced from 20% Pt/C.
From these catalysts, Cr, Mn, Ga/Co, V/Fe and Fe/Co were respectively removed in the same manner as in Example l to obtain the corresponding platinum skeleton alloy supported catalysts C-22, C-25, C-28, C-31 and C-34, respectively. The lattice constants of these original base metal-rich platinum solid solution alloy-supported catalysts and platinum skeleton alloy-supported catalysts were given for comparison in Table 2, together with the lattice constants of alloy-supported catalysts C-23*, C-26*, IS C-29*, C-32* and C-35* separately produced, having the composition respectively corresponding to the skeleton catalysts.
Table 2 Solid Skeleton Solid solution alloy (B) solution alloy (A) alloy (C) with com-position of (B) Pt:Cr C-21* C-22 C-23*
Atomic ratio: 52:48 78:22 78:22 Crystal Disordered Disordered Disordered form: fcc fcc fcc Lattice constant: 3.849 3.857 3.879 Pt:Mn C-24* C-25 C-26*
Atomic ratio: 45:55 76:22 76:22 Crystal form: Tetragonal Tetragonal Ordered Lattice a=b=4.004 a=b=3.974 cubic constant: c=3.676 c=3.719 3.885 Pt:Ga:Co C-27* C-28 C-29*
Atomic ratio: 51:24:25 79:9:12 79:9:12 Crystal Disordered Disordered Disordered form: fcc fcc fcc Lattice constant: 3.840 3.856 3.885 Pt:V:Fe C-30* C-31 C-32*
Atomic ratio: 50:25:25 76:13:11 76:13:11 Crystal Disordered Disordered Disordered form: fcc fcc fcc Lattice constant: 3.854 3.863 3.889 Pt:Fe:Co C-33* C-34 C-35*
Atomic ratio: 48:26:26 74:13:13 74:13:13 Crystal Ordered Ordered Disordered form: cubic cubic fcc Lattice constant: 3.783 3.816 3.864 Comparative Example 8 (Production Examples 36 & 37) Production of platinum-supported catalysts:
CA 022l4076 l997-08-2 The procedure of Production Example 1 was repeated except that the heat-treated carbon black having a specific surface area of 110 m2/g was replaced with untreated carbon black (trade name: W LCAN XC- 72R, available from Cabot Corp.) having a specific surface area of 260 m2/g and the charging ratio of carbon:Pt was changed to follow Production Example 11. Thus, a 30% Pt/C catalyst (C-36*) and a 4096 Pt/C catalyst (C-37*) were produced.
Example 5 (Production Examples 38 & 39) Production of platinum skeleton alloy supported catalysts:
The procedure of Comparative Example 2 was repeated except that the 10% Pt-C catalyst (C-l*) used therein was replaced with 50 g of 30% Pt/C catalyst (C-36*), which was slurried in 3,000 ml of deionized water, and that an aqueous solution of a mixture of cobalt (II) nitrate containing 2.25 g of Co and nickel (II) nitrate containing 2.25 g of Ni, in place of Cu, was added. Thus, a Pt-CO-Ni solid solution alloy-supported catalyst (C-38*) was obtained. Subsequently, this was treated in the same manner as in Example 1 to obtain a platinum skeleton alloy supported catalyst (C-39) having the composition with a Pt:Co:Ni atomic ratio of 74:13:13.
Meanwhile, from C-36*, a solid solution alloy-supported catalyst (C-40*) ha~ing the same composition was directly produced.
Similarly, to 50 g of 40~ Pttc catalyst (C-37*), an aqueous solution of copper (II) nitrate containing 6.5 g of Cu was added to produce a Pt-Cu solid solution alloy-supported catalyst (C-41*). This was treated in the same manner as in Example 1 to produce a platinum skeleton alloy-supported catalyst (C-42) having the composition with a Pt:Cu atomic ratio of 72:28. Also, from C-37*, a solid solution alloy-supported catalyst (C-43*) having the same composition was directly produced.
The crystal forms and lattice constants of these alloy supported in the catalysts were given for comparison in Table 3.
Table 3 Solid Skeleton Solid solution alloy (B) solution alloy (A) alloy (C) with com-position of (B) Pt:Co:Ni C-38* C-39 C-40*
Atomic ratio: 50:25:25 74:13:13 74:13:13 Crystal Disordered Disordered Disordered form: fcc fcc fcc Lattice constant: 3.774 3.797 3.845 Pt:Cu C-41* C-42 C-43*
Atomic ratio: 50:50 72:28 72:28 Crystal Disordered Disordered Disordered form: fcc fcc fcc Lattice constant: 3.791 3.809 3.852 2. Production of electrode:
The catalysts C-l*, C-3*, C-9*, C-ll and C-12* to C-43* obtained in the foregoing Production Examples 1, 3, 9 and 11 to 43, respectively, were each ultrasonically dispersed in an aqueous polytetrafluoroethylene dispersion (trade name: TEFLON TFE-30, available from Du Pont) to obtain a uniform slurry containing the catalyst and the polytetrafluoroethylene in a dried-weight ratio of 50:50. To this mixture slurry, aluminum chloride was added to form a flocculent precipitate. This flocculent precipitate was deposited (built-up) on a carbon paper support substrate (trade name: TGP-H-12, available from Toray Industries, Inc.) having been made water-repellent with polytetrafluoroethylene, and was then pressed, followed by drying and thereafter baking in a stream of nitrogen at 350~ for 15 minutes to obtain an electrode. Electrodes produced using the catalysts C-l*, C-3*, C-9*, C-ll and C-12* to C-43* are called E-l*, E-3*, E-9*, E-ll and E-12* to E-43*, respectively. These electrodes were all produced so as to contain the catalyst in an amount of 5.0 mg (in terms of dry weight) per 1 cm2 of the electrode. The electrodes having the catalysts according to Examples and Comparative Examples, thus produced, were put to the following performance tests. -3. Performance Tests (1) Test for mass activity on oxygen reduction reaction:
A circular electrode test piece of 24 mm in diameter was, on its side coated with catalyst layer, brought into contact with a 105% phosphoric acid electrolyte kept at 200~, and, to the other gaseous diffusion layer side, oxygen (~2) was fed at a flow rate of 600 ml/min. This electrode was set as a working electrode, and a reference hydrogen electrode (RHE) was made of a Luggin tube subjected to bubbling with hydrogen gas along a platinum wire.
A counter electrode made of a platinum mesh was provided.
Electric currents were passed between the working electrode and the counter electrode at various current densities ranging from 0 to 600 mA/cm2, where their polarization potential was measured. Internal resistance (IR) was corrected by the current interruption method. With respect to the respective electrodes E-l*, E-3*, E-9*, E-11 and E-12* to E-43*, internal resistance-free (IR-free) electrode potentials to current densities were plotted on a semilogarithmic graph to determine the current density at plus 900 mV vs. the RHE, and the mass activity (mA/mg Pt) of each catalyst was determined from the values obtained. Results are given in Tables 4 to 7.
Table 4 Catalyst Electrode EC.MSA Oxygen No. Constitution (m2/g) reduction mass activity (~ A/mgPt) C-l* 10~ Pt/C E-l* 120 40 C-9* Pt-Cu(16:84) E-9* 72 70 alloy/C
C-ll Pt-Cu(16:24) E-ll 91 86 skeleton alloy/C
C-3* Pt-Cu(76:24) E-3* 75 68 alloy/C
Table 5 Catalyst Electrode EC.MSA Oxygen No. Constitution (mZ/g) reduction mass activity (~ A/mgPt) C-12* 20~ Pt/C E-12* 116 39 C-13* Pt-Cu(50:50) alloy/C E-13* 68 69 C-14 Pt-Cu(71:29) skeleton E-14 77 80 alloy/C
C-15* Pt-Co(50:50) alloy/C E-15* 91 52 C-16 Pt-Co(83:17) skeleton E-16 99 60 alloy/C
C-17* Pt-Co(83:17) alloy/C E-17* 88 53 C-18* Pt-Ni(50:50) alloy/C E-18* 88 58 C-19 Pt-Ni(75:25) skeleton E-l9 102 68 alloy/C
C-20* Pt-Ni(75:25) alloy/C E-20* 92 60 C-21* Pt-Cr(52:48) alloy/C E-21* 78 48 C-22 Pt-Cr(78:22) skeleton E-22 89 58 alloy/C
C-23* Pt-Cr(78:22) alloy/C E-23* 80 50 C-24* Pt-Mn(45:55) alloy/C E-24* 68 47 C-25 Pt-Mn(76:24) skeleton E-25 77 54 alloy/C
C-26* Pt-Mn(76:24) alloy/C E-26* 67 46 C-27* Pt-Ga-Co(51:24:25) E-27* 80 72 alloy/C
C-28 Pt-Ga-Co(79:9:12) E-28 89 80 skeleton alloy/C
C-29* Pt-Ga-Co(79:9:12) E-29* 81 68 alloy/C
C-30* Pt-V-Fe(50:25:25) E-30* 74 68 alloy/C
C-31 Pt-V-Fe(76:13:11) E-31 85 79 skeleton alloy/C
C-32* Pt-V-Fe(76:13:11) E-32* 75 66 alloy/C
C-33* Pt-Fe-Co(48:26:26) E-33* 82 84 alloy/C
C-34 Pt-Fe-Co(74:13:13) E-34 94 95 skeleton alloy/-C
C-35* Pt-Fe-Co(74:13:13) E-35* 84 82 alloy/C
Table 6 Catalyst Electrode EC.MSA Oxygen No. Constitution (m2/g) reduction mass activity (~ A/mgPt) C-36* 30% Pt/C E-36* 107 32 C-38* Pt-Co-Ni(50:25:25) E-38* 80 61 alloy/C
C-39 Pt-Co-Ni(74:13:13) E-39 89 68 skeleton alloy/C
C-40* Pt-Co-Ni(74:13:13) E-40* 81 62 alloy/C
Table 7 Catalyst Electrode EC.MSA Oxygen No. Constitution (m2/g) reduction mass activity (~ A/mgPt) C-37* 40% Pt/C E-37* 100 29 C-41* Pt-Cu(50:50) alloy/C E-41* 65 58 C-42 Pt-Cu(78:28) skeleton E-42 76 65 alloy/C
C-43* Pt-Cu(78:28) alloy/C E-43* 67 55 CA 022l4076 l997-08-2 As is seen from the above results, the electrodes E-ll, E-14, E-16, E-l9, E-22, E-25, E-28, E-31 and E-34 showed activities which are 1.4 times to 2.4 times higher than the electrode E-l* using the single platinum supported catalyst having the same platinum loading amount as these. In comparison with electrodes using conventionally known platinum-base metal solid solution alloy-supported catalysts, the electrodes of the present invention showed actlvities higher by about 10% to 26%.
(2) Single cell test of fuel cells:
The electrode E-l* was set as the anode and the electrode E-12*, E-13* or E-34 as the cathode, which were set face-to-face on their catalyst coated layer sides, and between which an electrolyte sheet comprising an SiC matrix sheet impregnated with 105% phosphoric acid was inserted. Thus, a small-size single cell having an electrode effective area of 7.4 cm x 7.4 cm was set up. The electrodes were maintained at 210~ at a current density of 200 mA/cmZ while feeding hydrogen gas to the anode side and air to the cathode side at flow rates of 100 ml/min and 600 ml/min, respectively, and the changes with time of IR-free terminal voltage were followed up.
Compared with cells employing as the cathode the electrode using the platinum-base metal solid solution alloy-supported catalyst or using the conventionally known single platinum supported catalyst, S the cell employing as the cathode the electrode produced using the catalyst of the present invention exhibited superior performances in that the cell had not only a higher initial terminal voltage for 1,000 to 2,000 hours, but also rather a very smaller rate of terminA1 voltage drop, which was as small as about 1/2 of the conventional catalysts, after 7,000 to 8,000 hours.
The changes with time of IR-free terminal voltages of the respective cells are shown in Fig. 2.
From these catalysts, Cr, Mn, Ga/Co, V/Fe and Fe/Co were respectively removed in the same manner as in Example l to obtain the corresponding platinum skeleton alloy supported catalysts C-22, C-25, C-28, C-31 and C-34, respectively. The lattice constants of these original base metal-rich platinum solid solution alloy-supported catalysts and platinum skeleton alloy-supported catalysts were given for comparison in Table 2, together with the lattice constants of alloy-supported catalysts C-23*, C-26*, IS C-29*, C-32* and C-35* separately produced, having the composition respectively corresponding to the skeleton catalysts.
Table 2 Solid Skeleton Solid solution alloy (B) solution alloy (A) alloy (C) with com-position of (B) Pt:Cr C-21* C-22 C-23*
Atomic ratio: 52:48 78:22 78:22 Crystal Disordered Disordered Disordered form: fcc fcc fcc Lattice constant: 3.849 3.857 3.879 Pt:Mn C-24* C-25 C-26*
Atomic ratio: 45:55 76:22 76:22 Crystal form: Tetragonal Tetragonal Ordered Lattice a=b=4.004 a=b=3.974 cubic constant: c=3.676 c=3.719 3.885 Pt:Ga:Co C-27* C-28 C-29*
Atomic ratio: 51:24:25 79:9:12 79:9:12 Crystal Disordered Disordered Disordered form: fcc fcc fcc Lattice constant: 3.840 3.856 3.885 Pt:V:Fe C-30* C-31 C-32*
Atomic ratio: 50:25:25 76:13:11 76:13:11 Crystal Disordered Disordered Disordered form: fcc fcc fcc Lattice constant: 3.854 3.863 3.889 Pt:Fe:Co C-33* C-34 C-35*
Atomic ratio: 48:26:26 74:13:13 74:13:13 Crystal Ordered Ordered Disordered form: cubic cubic fcc Lattice constant: 3.783 3.816 3.864 Comparative Example 8 (Production Examples 36 & 37) Production of platinum-supported catalysts:
CA 022l4076 l997-08-2 The procedure of Production Example 1 was repeated except that the heat-treated carbon black having a specific surface area of 110 m2/g was replaced with untreated carbon black (trade name: W LCAN XC- 72R, available from Cabot Corp.) having a specific surface area of 260 m2/g and the charging ratio of carbon:Pt was changed to follow Production Example 11. Thus, a 30% Pt/C catalyst (C-36*) and a 4096 Pt/C catalyst (C-37*) were produced.
Example 5 (Production Examples 38 & 39) Production of platinum skeleton alloy supported catalysts:
The procedure of Comparative Example 2 was repeated except that the 10% Pt-C catalyst (C-l*) used therein was replaced with 50 g of 30% Pt/C catalyst (C-36*), which was slurried in 3,000 ml of deionized water, and that an aqueous solution of a mixture of cobalt (II) nitrate containing 2.25 g of Co and nickel (II) nitrate containing 2.25 g of Ni, in place of Cu, was added. Thus, a Pt-CO-Ni solid solution alloy-supported catalyst (C-38*) was obtained. Subsequently, this was treated in the same manner as in Example 1 to obtain a platinum skeleton alloy supported catalyst (C-39) having the composition with a Pt:Co:Ni atomic ratio of 74:13:13.
Meanwhile, from C-36*, a solid solution alloy-supported catalyst (C-40*) ha~ing the same composition was directly produced.
Similarly, to 50 g of 40~ Pttc catalyst (C-37*), an aqueous solution of copper (II) nitrate containing 6.5 g of Cu was added to produce a Pt-Cu solid solution alloy-supported catalyst (C-41*). This was treated in the same manner as in Example 1 to produce a platinum skeleton alloy-supported catalyst (C-42) having the composition with a Pt:Cu atomic ratio of 72:28. Also, from C-37*, a solid solution alloy-supported catalyst (C-43*) having the same composition was directly produced.
The crystal forms and lattice constants of these alloy supported in the catalysts were given for comparison in Table 3.
Table 3 Solid Skeleton Solid solution alloy (B) solution alloy (A) alloy (C) with com-position of (B) Pt:Co:Ni C-38* C-39 C-40*
Atomic ratio: 50:25:25 74:13:13 74:13:13 Crystal Disordered Disordered Disordered form: fcc fcc fcc Lattice constant: 3.774 3.797 3.845 Pt:Cu C-41* C-42 C-43*
Atomic ratio: 50:50 72:28 72:28 Crystal Disordered Disordered Disordered form: fcc fcc fcc Lattice constant: 3.791 3.809 3.852 2. Production of electrode:
The catalysts C-l*, C-3*, C-9*, C-ll and C-12* to C-43* obtained in the foregoing Production Examples 1, 3, 9 and 11 to 43, respectively, were each ultrasonically dispersed in an aqueous polytetrafluoroethylene dispersion (trade name: TEFLON TFE-30, available from Du Pont) to obtain a uniform slurry containing the catalyst and the polytetrafluoroethylene in a dried-weight ratio of 50:50. To this mixture slurry, aluminum chloride was added to form a flocculent precipitate. This flocculent precipitate was deposited (built-up) on a carbon paper support substrate (trade name: TGP-H-12, available from Toray Industries, Inc.) having been made water-repellent with polytetrafluoroethylene, and was then pressed, followed by drying and thereafter baking in a stream of nitrogen at 350~ for 15 minutes to obtain an electrode. Electrodes produced using the catalysts C-l*, C-3*, C-9*, C-ll and C-12* to C-43* are called E-l*, E-3*, E-9*, E-ll and E-12* to E-43*, respectively. These electrodes were all produced so as to contain the catalyst in an amount of 5.0 mg (in terms of dry weight) per 1 cm2 of the electrode. The electrodes having the catalysts according to Examples and Comparative Examples, thus produced, were put to the following performance tests. -3. Performance Tests (1) Test for mass activity on oxygen reduction reaction:
A circular electrode test piece of 24 mm in diameter was, on its side coated with catalyst layer, brought into contact with a 105% phosphoric acid electrolyte kept at 200~, and, to the other gaseous diffusion layer side, oxygen (~2) was fed at a flow rate of 600 ml/min. This electrode was set as a working electrode, and a reference hydrogen electrode (RHE) was made of a Luggin tube subjected to bubbling with hydrogen gas along a platinum wire.
A counter electrode made of a platinum mesh was provided.
Electric currents were passed between the working electrode and the counter electrode at various current densities ranging from 0 to 600 mA/cm2, where their polarization potential was measured. Internal resistance (IR) was corrected by the current interruption method. With respect to the respective electrodes E-l*, E-3*, E-9*, E-11 and E-12* to E-43*, internal resistance-free (IR-free) electrode potentials to current densities were plotted on a semilogarithmic graph to determine the current density at plus 900 mV vs. the RHE, and the mass activity (mA/mg Pt) of each catalyst was determined from the values obtained. Results are given in Tables 4 to 7.
Table 4 Catalyst Electrode EC.MSA Oxygen No. Constitution (m2/g) reduction mass activity (~ A/mgPt) C-l* 10~ Pt/C E-l* 120 40 C-9* Pt-Cu(16:84) E-9* 72 70 alloy/C
C-ll Pt-Cu(16:24) E-ll 91 86 skeleton alloy/C
C-3* Pt-Cu(76:24) E-3* 75 68 alloy/C
Table 5 Catalyst Electrode EC.MSA Oxygen No. Constitution (mZ/g) reduction mass activity (~ A/mgPt) C-12* 20~ Pt/C E-12* 116 39 C-13* Pt-Cu(50:50) alloy/C E-13* 68 69 C-14 Pt-Cu(71:29) skeleton E-14 77 80 alloy/C
C-15* Pt-Co(50:50) alloy/C E-15* 91 52 C-16 Pt-Co(83:17) skeleton E-16 99 60 alloy/C
C-17* Pt-Co(83:17) alloy/C E-17* 88 53 C-18* Pt-Ni(50:50) alloy/C E-18* 88 58 C-19 Pt-Ni(75:25) skeleton E-l9 102 68 alloy/C
C-20* Pt-Ni(75:25) alloy/C E-20* 92 60 C-21* Pt-Cr(52:48) alloy/C E-21* 78 48 C-22 Pt-Cr(78:22) skeleton E-22 89 58 alloy/C
C-23* Pt-Cr(78:22) alloy/C E-23* 80 50 C-24* Pt-Mn(45:55) alloy/C E-24* 68 47 C-25 Pt-Mn(76:24) skeleton E-25 77 54 alloy/C
C-26* Pt-Mn(76:24) alloy/C E-26* 67 46 C-27* Pt-Ga-Co(51:24:25) E-27* 80 72 alloy/C
C-28 Pt-Ga-Co(79:9:12) E-28 89 80 skeleton alloy/C
C-29* Pt-Ga-Co(79:9:12) E-29* 81 68 alloy/C
C-30* Pt-V-Fe(50:25:25) E-30* 74 68 alloy/C
C-31 Pt-V-Fe(76:13:11) E-31 85 79 skeleton alloy/C
C-32* Pt-V-Fe(76:13:11) E-32* 75 66 alloy/C
C-33* Pt-Fe-Co(48:26:26) E-33* 82 84 alloy/C
C-34 Pt-Fe-Co(74:13:13) E-34 94 95 skeleton alloy/-C
C-35* Pt-Fe-Co(74:13:13) E-35* 84 82 alloy/C
Table 6 Catalyst Electrode EC.MSA Oxygen No. Constitution (m2/g) reduction mass activity (~ A/mgPt) C-36* 30% Pt/C E-36* 107 32 C-38* Pt-Co-Ni(50:25:25) E-38* 80 61 alloy/C
C-39 Pt-Co-Ni(74:13:13) E-39 89 68 skeleton alloy/C
C-40* Pt-Co-Ni(74:13:13) E-40* 81 62 alloy/C
Table 7 Catalyst Electrode EC.MSA Oxygen No. Constitution (m2/g) reduction mass activity (~ A/mgPt) C-37* 40% Pt/C E-37* 100 29 C-41* Pt-Cu(50:50) alloy/C E-41* 65 58 C-42 Pt-Cu(78:28) skeleton E-42 76 65 alloy/C
C-43* Pt-Cu(78:28) alloy/C E-43* 67 55 CA 022l4076 l997-08-2 As is seen from the above results, the electrodes E-ll, E-14, E-16, E-l9, E-22, E-25, E-28, E-31 and E-34 showed activities which are 1.4 times to 2.4 times higher than the electrode E-l* using the single platinum supported catalyst having the same platinum loading amount as these. In comparison with electrodes using conventionally known platinum-base metal solid solution alloy-supported catalysts, the electrodes of the present invention showed actlvities higher by about 10% to 26%.
(2) Single cell test of fuel cells:
The electrode E-l* was set as the anode and the electrode E-12*, E-13* or E-34 as the cathode, which were set face-to-face on their catalyst coated layer sides, and between which an electrolyte sheet comprising an SiC matrix sheet impregnated with 105% phosphoric acid was inserted. Thus, a small-size single cell having an electrode effective area of 7.4 cm x 7.4 cm was set up. The electrodes were maintained at 210~ at a current density of 200 mA/cmZ while feeding hydrogen gas to the anode side and air to the cathode side at flow rates of 100 ml/min and 600 ml/min, respectively, and the changes with time of IR-free terminal voltage were followed up.
Compared with cells employing as the cathode the electrode using the platinum-base metal solid solution alloy-supported catalyst or using the conventionally known single platinum supported catalyst, S the cell employing as the cathode the electrode produced using the catalyst of the present invention exhibited superior performances in that the cell had not only a higher initial terminal voltage for 1,000 to 2,000 hours, but also rather a very smaller rate of terminA1 voltage drop, which was as small as about 1/2 of the conventional catalysts, after 7,000 to 8,000 hours.
The changes with time of IR-free terminal voltages of the respective cells are shown in Fig. 2.
Claims (16)
1. An electrocatalyst comprising an alloy of platinum with a base metal selected from the group consisting of gallium, vanadium, chromium, manganese, iron, cobalt, nickel and copper, having a structure of vacant lattice site type lattice defects, and a conductive carbon powder on which said alloy is supported.
2. The electrocatalyst according to claim 1, wherein the platinum is supported in an amount of 1% by weight to 60% by weight based on the whole catalyst.
3. The electrocatalyst according to claim 1, wherein the atomic ratio of platinum to the base metal in said platinum skeleton alloy is in the range of 1:1 to 1:0.05.
4. The electrocatalyst according to claim 1, wherein said conductive carbon powder has a BET specific surface area of from 50 to 1,500 m2/g, a graphite (002) crystallite diameter of from 7 to 80 A, a graphite crystal interlattice distance dc (002) of from 3.40 to 3.79 A, and a DBP oil absorption of from 50 to 700 ml/100 gC.
5. The electrocatalyst according to claim 1, which is a cathode catalyst for a phosphoric acid type fuel cell.
6. The electrocatalyst according to claim 5, wherein platinum is supported in an amount of 5 to 30% by weight based on the whole catalyst.
7. The electrocatalyst according to claim 5, wherein said conductive carbon powder is an at least partially graphitized carbon black having a BET specific surface area of from 50 to 180 m2/g, a graphite (002) crystallite diameter of from 10 to 70 A.
8. The electrocatalyst according to claim 1, which is a cathode catalyst for a proton-exchange membrane type fuel cell.
9. The electrocatalyst according to claim 8, wherein platinum is supported in an amount of 20 to 50% by weight based on the whole catalyst.
10. The electrocatalyst according to claim 8, wherein said conductive carbon powder has a BET specific surface area of from 120 to 1,500 m2/g and a graphite (002) crystallite diameter of from 7 to 35 A.
11. An electrode comprising the electrocatalyst as claimed in claim 1 and a water-repellent binder which are bound to a conductive and gas-permeable support substrate.
12. The electrode according to claim 11, which is a cathode for a phosphoric acid type fuel cell.
13. The electrode according to claim 11, which is a cathode for a proton-exchange membrane type fuel cell.
14. A process for producing the electrocatalyst as claimed in claim 1, the process comprising;
the first step of bringing a solid solution alloy of platinum with a base metal selected from the group consisting of gallium, vanadium, chromium, manganese, iron, cobalt, nickel and copper into support in a highly dispersed state with a conductive carbon powder; and the second step of removing the base metal at least in part from the crystal lattice of the alloy while retaining the crystal form to form a structure of vacant lattice site type lattice defects.
the first step of bringing a solid solution alloy of platinum with a base metal selected from the group consisting of gallium, vanadium, chromium, manganese, iron, cobalt, nickel and copper into support in a highly dispersed state with a conductive carbon powder; and the second step of removing the base metal at least in part from the crystal lattice of the alloy while retaining the crystal form to form a structure of vacant lattice site type lattice defects.
15. The process according to claim 14, wherein 20 to 90% by weight of the base metal contained in the platinum solid solution alloy is removed in the second step.
16. The process according to claim 14, wherein the second step comprises suspending a platinum solid solution alloy-supported carbon powder in phosphoric acid heated to 100°C to 200°C or in an aqueous mineral acid solution kept at a temperature of room temperature to 100°C
in an atmosphere containing substantially no oxygen, and maintaining the resultant suspension with stirring for a certain time, followed by cooling, filtering, and washing with hot water until the filtrate has an electrical conductivity of 20 µ S/cm or less, and subsequently drying, whereby the base metal being removed.
in an atmosphere containing substantially no oxygen, and maintaining the resultant suspension with stirring for a certain time, followed by cooling, filtering, and washing with hot water until the filtrate has an electrical conductivity of 20 µ S/cm or less, and subsequently drying, whereby the base metal being removed.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24267796A JP3874380B2 (en) | 1996-08-26 | 1996-08-26 | Carbon-supported platinum skeleton alloy electrocatalyst with vacancy-type lattice defects |
| JP8-242677 | 1996-08-26 |
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| CA2214076A1 true CA2214076A1 (en) | 1998-02-26 |
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| CA002214076A Abandoned CA2214076A1 (en) | 1996-08-26 | 1997-08-25 | Platinum skeleton alloy-supported electrocatalyst, electrode using the electrocatalyst, and process for producing the electrocatalyst |
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| Country | Link |
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| US (1) | US5876867A (en) |
| EP (1) | EP0827225A3 (en) |
| JP (1) | JP3874380B2 (en) |
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| US5079107A (en) * | 1984-06-07 | 1992-01-07 | Giner, Inc. | Cathode alloy electrocatalysts |
| JPS618851A (en) * | 1984-06-07 | 1986-01-16 | ガイナー・インコーポレーテツド | Fuel battery and electrolyte catalyst therefor |
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| JPH0697615B2 (en) * | 1989-03-09 | 1994-11-30 | エヌ・イーケムキャット株式会社 | Platinum alloy electrode catalyst |
| JP2909166B2 (en) * | 1990-07-31 | 1999-06-23 | エヌ・イーケムキヤツト株式会社 | Supported platinum quaternary alloy electrode catalyst |
| DE4028916C2 (en) * | 1990-09-12 | 1994-05-05 | Heraeus Gmbh W C | Wire mesh catalytic converter mesh made from the precious metal alloys platinum / rhodium or platinum / rhodium / palladium |
| JPH05208135A (en) * | 1991-02-23 | 1993-08-20 | Tanaka Kikinzoku Kogyo Kk | Electrode catalyst for negative electrode |
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| US5759944A (en) * | 1993-04-20 | 1998-06-02 | Johnson Matthey Public Limited Company | Catalyst material |
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1996
- 1996-08-26 JP JP24267796A patent/JP3874380B2/en not_active Expired - Lifetime
-
1997
- 1997-08-25 CA CA002214076A patent/CA2214076A1/en not_active Abandoned
- 1997-08-26 US US08/917,620 patent/US5876867A/en not_active Expired - Lifetime
- 1997-08-26 EP EP97114738A patent/EP0827225A3/en not_active Withdrawn
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111554946A (en) * | 2020-04-23 | 2020-08-18 | 广东道氏云杉氢能科技有限公司 | Pt alloy with high HOR catalytic activity and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3874380B2 (en) | 2007-01-31 |
| US5876867A (en) | 1999-03-02 |
| JPH1069914A (en) | 1998-03-10 |
| EP0827225A3 (en) | 2001-11-07 |
| EP0827225A2 (en) | 1998-03-04 |
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