CA2208818A1 - Methods and apparatus for liquid cryogen gasification utilizing cryoelectrics - Google Patents
Methods and apparatus for liquid cryogen gasification utilizing cryoelectricsInfo
- Publication number
- CA2208818A1 CA2208818A1 CA 2208818 CA2208818A CA2208818A1 CA 2208818 A1 CA2208818 A1 CA 2208818A1 CA 2208818 CA2208818 CA 2208818 CA 2208818 A CA2208818 A CA 2208818A CA 2208818 A1 CA2208818 A1 CA 2208818A1
- Authority
- CA
- Canada
- Prior art keywords
- cryogenic fluid
- gasification unit
- unit
- energy converter
- cryoelectronic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C7/00—Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass
- F17C7/02—Discharging liquefied gases
- F17C7/04—Discharging liquefied gases with change of state, e.g. vaporisation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C9/00—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure
- F17C9/02—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure with change of state, e.g. vaporisation
- F17C9/04—Recovery of thermal energy
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2203/00—Vessel construction, in particular walls or details thereof
- F17C2203/06—Materials for walls or layers thereof; Properties or structures of walls or their materials
- F17C2203/068—Special properties of materials for vessel walls
- F17C2203/0687—Special properties of materials for vessel walls superconducting
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/012—Hydrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/014—Nitrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/05—Applications for industrial use
- F17C2270/0509—"Dewar" vessels
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
Abstract
Methods and apparatus for gasification of liquid nitrogen and other cryogenic liquids are provided. The apparatus includes a gasification unit capable of refrigerating at least one cryoelectronics energy converter and utilizing the heat generated thereby to gasify a cryogenic fluid. Refrigeration is provided by the cryogenic fluid in the gasification unit.
The gasification unit is preferably capable of gasifying at least 1 liter/hour of cryogenic fluid.
The gasification unit can be coupled to a chemical processing unit such that gasified cryogenic fluid produced in the gasification unit can be introduced into the chemical processing unit for use therein. A secondary heat recovery unit can be provided upstream of the chemical processing unit to separate entrained liquid particles from the gasified cryogenic fluid produced by the gasification unit. Cryogenic fluid can be supplied to the gasification unit from an air liquefaction plant, a storage tank, a truck or the like. The gasification unit can be used to gasify nitrogen. liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or other cryogenic fluids.
The gasification unit is preferably capable of gasifying at least 1 liter/hour of cryogenic fluid.
The gasification unit can be coupled to a chemical processing unit such that gasified cryogenic fluid produced in the gasification unit can be introduced into the chemical processing unit for use therein. A secondary heat recovery unit can be provided upstream of the chemical processing unit to separate entrained liquid particles from the gasified cryogenic fluid produced by the gasification unit. Cryogenic fluid can be supplied to the gasification unit from an air liquefaction plant, a storage tank, a truck or the like. The gasification unit can be used to gasify nitrogen. liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or other cryogenic fluids.
Description
CA 02208818 1997-06-2~
METHODS AND APPARATUS FOR LIQUID CRYOGEN GASIFICATION
UTILIZING CRYOELECTRONICS
TECHNICAL ~IELD
S The present invention generally relates to methods and apparatus for liquid cryogen gasification and more particularly relates to liquid cryogen gasification lltili7ing cryoelectronic devices.
BACKGROUND OF THE INVENTION
Cryogenics relates to the production and maintenance of very low temperatures, often using cryogenic fluids such as hydrogen, helium, nitrogen, oxygen, air or methane. Various discussions concerning cryogenic systems can be found in literature. See e.g., Barron, Cr~vogenic Systems. 2d Ed., Oxford University Press (1985); Bell, Jr., Cr~ogenicEngineering, Prentice Hall Inc. (1963); Vance, Cr~ogenic Technology, John Wiley & Sons, Inc. (1963) and Timmerhaus et al., Cryogenic Process Engineering, Plenum Press (1989).
In addition, U.S. Patent Nos. 3,320,755; 3,714,796 and 3,728,868 disclose cryogenic refrigeration systems (i.e. cryostats). U.S. Patent No. 4,237,699 relates to cryostats for producing cryogenic refrigeration by expansion s~f a working fluid through a Joule-Thomson orifice. The cryostat disclosed in U.S. Patent No. 4 237,699 can be placed in a dewar so that the liquefied working fluid can be maintained to cool an object such as an infrared detector. Similarly, U.S. Patent Nos. 3,021,683 and 3,048,021 relate to gas liquefiers.
U.S. Patent No. 4,653,284 discloses a Joule Thomson heat exchanger and cryostat. U.S.
Patent No. 4,781,033 discloses a heat exchanger for a fast cooldown. The above-mentioned devices and apparatus are useful in liquefaction processes.
Air liquefaction is often utilized to provide liquid or gaseous oxygen for chemical processing and steel production plants. The remaining liquid nitrogen is used in food processing plants and the like. Liquid nitrogen is also converted to a gas for use as a protective blanket for reactive elements in chemical plants. Because of transportation costs and other factors, liquefled nitrogen is typically re-gasified after being liquefied in an air CA 02208818 1997-06-2~
liquefaction plant for use in such facilities. As discussed in greater detail herein, the liquefied nitrogen is transported from an air liquefaction plant, a tanker or the like through a pipe line to an evaporator where it is gasified. The gasified nitrogen is then transported to the chemical, steel or food processing plant for use.
The gaseous nitrogen blankets protect reactive elements used in various processing plants where explosion or cont~min~tion hazards are a significant concern. In addition, many reactive elements used in these plants will undergo oxidation if not adequately protected. In addition to reducing explosion and cont:~min~ion hazards, gaseous nitrogen blankets also reduce the possibilities of undesired oxidation. For example, gaseous nitrogen blankets are sometimes employed in plants where chlorine is produced from salt brine by electrochemical methods. Additionally, food processing plants may use gaseous nitrogen during food processing to preserve expensive foods. Liquid nitrogen is used to flash freeze shrimp or foods that cannot be processed with acceptable quality using norrnal freezing processes.
As mentioned above, prior art techniques for providing gaseous nitrogen blankets to these processing plants typically include the use of air liquefaction plants. In large industrial applications for example, a gas pipe line connects the air plant to the chemical processing plant. The gas pipeline length x is typically about S00-S000 meters. The liquid nitrogen is converted to a gas in an evaporator and transported through the gas pipe line. Heat input requirements to the evaporator must be equivalent to the latent heat of vaporization for the liquid nitrogen, i.e. about 43.6 W/liter/hour.
During the summertime and during periods of high humidity, the liquid nitrogen plant often cannot deliver sufficient gas to the chemical plant. This can be attributed in part to the high humidity causing ice formation on the evaporator. In addition to heat energy requirements to the evaporator, geographical location can thus be a limiting factor in designing such plants. Even if such plants can be constructed in areas where the climate is subject to frequent periods of high humidity, additional design and construction costs must be taken into account to protect the evaporator from the disadvantages associated with such icing.
Another disadvantage associated with the prior art is that separate cooling systems are utilized for power supplies and other large equipment requiring active cooling. For example, in situations where large power supplies are also used in the plant, they are typically either water or air cooled. Consequently, the regulation of nitrogen gas flow from the evaporator is separate from the process requirements in the plant.
It would therefore be desirable to provide methods and apparatus for improving liquid S cryogen gasification such that heat energy requirements and disadvantages caused by high humidity environments are reduced, thereby overcoming the shortcomings associated with the prior art. The resulting gasification will also improve the operation of large equipment requiring active cooling.
Sl~ll~lARY OF THE INVENTION
It is an object of the present invention to provide methods and apparatus for utilizing cryoelectronics systems for gas production systems.
It is another object of the invention to provide methods and apparatus for utilizing waste heat from cryoelectronics energy converters to gasify a cryogenic fluid for subsequent 15 use.
It is a further object of the invention to provide methods and apparatus for providing refrigeration units for cryoelectronics systems in combination with gasification units.
It is still a further object of the invention to provide methods and apparatus for gas production proportional to load requirements in a processing plant.
It is still another object of the invention to provide methods and apparatus forimproving the cost effectiveness and efficiency of various processing plants such as chemical plants, steel plants and food processing plants.
These and other objects of the invention are provided by methods and apparatus that use the waste heat from cryoelectronics energy converters (i.e. cryoconverters or disipative active electrical devices) to gasify nitrogen (or other cryogenic fluid) for chemical or other plants requiring substantial amounts of clean nitrogen (or such other cryogenic fluid). This is accomplished by utilizing high temperature superconductor (HTS) bus bar stock to carry electricity, and cryogenically cooled power electronics for energy conversion and power factor correction to improve the cost effectiveness of chemical plants, steel plants and the like. The power electronic components can be positioned in a controlled cryogenically CA 02208818 1997-06-2~
cooled environment such as a liquid nitrogen environment~ which provides refrigeration to the components. Waste heat from the refrigeration process is used to produce nitrogen gas for the process plant. In an alternative embodiment of the invention, high current electrical switches can be installed in this liquid nitrogen environment to avoid the cost of cleaning and S maintenance.
The liquid nitrogen can be gasified at a rate directly proportional to the load requirements of the plant. Thus, the present invention utilizes the waste heat from cryoelectronics energy converters to gasify nitrogen for such plants and elimin~tes the need for separate refrigeration systems for power supplies to the plant.
The present invention can also be utilized to gasify other cryogenic liquids using the same process or with slight modifications. For example, the present invention can be used in connection with the gasification of liquefied natural gas. carbon dioxide~ oxygen, hydrogen, argom neon and the like.
The present invention employs a liquid air plant or another source of liquid nitrogen such as a tanker truck. a storage tank or the like. In a cryogenic power electronics apparatus, liquid cryogen will flow through a cryostat or gasifier. The cryostat or gasifier can be utilized to evaporate the liquid cryogen, such as liquid nitrogen. Appropriate piping, pipe lines, fittings, valves and the like can be used to connect the source of liquid nitrogen, the gasifier and the process plant.
For example, a liquid air plant can ship liquid nitrogen by tanker or through a pipe line. The power electronics for the plant is housed in the gasifier and operates as a nitrogen gasifier while the liquid nitrogen provides cooling for the power electronics. The optimization of the cryogenics design of the cryoelectronics is not penalized for the refrigeration system. In a synchronous rectifier design for example, 0.125 V forward drop at 75,000 A provides the energy available for gasification of 9.3 kW. This will gasify over 150,000 liters of gas per hour. The gas production rate can be directly proportional to the load in the electrochemical or other chemical plant.
The foregoing has outlined some of the more pertinent objects of the present invention. These objects should be construed to be merely illustrative of some of the more prominent features and applications of the invention. Many other beneficial results can be CA 02208818 1997-06-2~
attained by applying the disclosed invention in a different manner of modifying the invention as will be described. Accordingly, other objects and a fuller understanding of the invention may be had by referring to the following Detailed Description of the Preferred Embodiments.
BRIEF DESCRIPTION OF l~lE DRAWINGS
For a fuller understanding of the present invention, reference is had to the following description taken in conjunction with the accompanying drawings, in which:
Fig. 1 illustrates a flow diagram of prior art techniques utilized to provide gaseous oxygen or nitrogen to chemical processing plants;
Fig. 2 shows a flow diagram suitable providing cryogenic fluids to chemical processing plants in accordance with the present invention;
Fig. 3 illustrates a graph of enthalpy versus temperature for nitrogen;
Fig. 4 illustrates dewar and secondary heat recovery and gas separation units according to one embodiment of the present invention; and Figs. 5a-5c illustrate alternative configurations of dewars for use according to the present invention.
Similar reference characters refer to similar parts throughout the several views of the drawings.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIl\IENTS
As mentioned above, prior art techniques of providing gaseous nitrogen or oxygen to chemical processing plants have included the use of air liquefaction plants and an evaporator.
As illustrated in Fig. 1 for example, prior art systems 10 include air liquefaction plant 30 coupled to evaporator 40 by pipe line 32. Alternatively, liquid nitrogen can be provided to evaporator 40 by tanker 20 through pipe line 22.
Liquid nitrogen is converted to a gaseous state in evaporator 40 and pumped through pipe line 42 to chemical processing plant 50. The length ~c of pipe line 42 is typically 500-5000 m. As further shown in Fig. 1, energy requirements equivalent to the latent heat of vaporization for nitrogen (i.e. about 43.6 W/liter/hour) must be provided to evaporator 40.
CA 02208818 1997-06-2~
In addition to requiring input of the heat necessary to gasify the liquid nitrogen, another disadvantage associated with prior art techniques such as those shown in Fig. 1 include the problems discussed above in connection with ice formation on the evaporator during periods of high humidities. Consequently, construction of chemical processing plants in geographical areas subject to high humidity environments can be undesirable or impractical due to increased cost of construction and design to compensate for ice formation on the evaporator.
Further, prior art systems typically include separate cooling or refrigeration systems for power supplies to the processing plant. As a result, the regulation of gaseous nitrogen flow to the processing plant is separate and not necessarily proportional to the process requirements in the chemical plant.
The present invention overcomes these disadvantages by combining the use of cryoelectronics energy converters and the waste heat generated by refrigerating such converters to gasify nitrogen or other cryogenic fluids in a manner that can be directly lS proportional to the load requirements in a chemical processing facility. The use of cryoelectronics energy converters provide for high performance, thereby enhancing the overall performance of the system. Additionally, the use of the waste heat generated by refrigeration of the converters elimin;3tes or reduces the need to provide energy to an evaporator as practiced in accordance with prior art techniques.
A flow diagram for a system 100 suitable for use in accordance with the present invention is shown in Fig. 2. System 100 includes a gasifier unit 110. As discussed herein, gasifier unit 110 includes cryogenically cooled power electronic devices that provide power to a processing unit 126. Processing unit 126 can be a chemical processing plant, a steel plant, a cryogenic freezing plant or the like.
For purposes of illustration, liquid nitrogen is used to illustrate a cryogenic liquid capable of gasification in accordance with the present invention. It will be appreciated by those skilled in the art, however, that the present invention can also be utilized to gasify other cryogenic liquids using the same process or with slight modifications. For example, the present invention can be used in connection with the gasification of liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon and the like. In addition, any other fluid CA 02208818 1997-06-2~
that is capable of operating at temperatures below room temperature when the fluid is used with the cryoeleetronics energy converter is suitable for use in the present invention. Liquid nitrogen can be supplied to gasifier 110 using various techniques. For example, liquid nitrogen can be transported to gasifier 110 by a tanker 112, from a storage tank 114, from an 5 air liquefaction plant 116 or combinations thereof. As also shown in Fig. 2, nitrogen is transported to gasifier 110 through a pipe line 118, which is constructed of materials suitable for transporting liquid nitrogen. It will be appreciated by those skilled in the art however, that liquid nitrogen can be introduced directly into gasifer 110 from the liquid nitrogen source, thereby elimin~in~ pipe line 118.
Nitrogen is gasified in unit 110 and transported to a secondary heat recovery and gas separation unit 120 through pipe line 122. Secondary heat recovery and gas separation unit 120 can be utilized to prevent choke by further separating liquid particles entrained in the gaseous nitrogen flow. If the gasification process in unit 110 is sufficient, it may not be necessary or desirable to employ unit 120. Nitrogen gas exiting unit 110 or unit 120 is then transported to processing unit 126 through pipe line 122 or 124, respectively. Because the cryoelectronic energy converters that power plant 126 are cryogenically cooled in gasifler 110, nitrogen gasified in unit 110 can be produced at a rate sufficient to supply the plant. In preferred embodiments, nitrogen can be gasified in unit 110 at a rate directly proportional to the load requirements in plant 126. As described in greater detail herein, the present invention utilizes the waste heat from cryoelectronics energy converters to gasify the nitrogen for such plants.
The lengths of pipe lines 118, 122 and 124 (e, f and g respectively) can be varied depending on design parameters and the like. System 100 can be operated in a batch or continuous mode.
Referring now to Fig. 3, a graph of enthalpy versus temperature for nitrogen is illustrated. Cryogenic cooling of an object in a cryogenic fluid such as nitrogen produces an amount of waste heat. As shown in Fig. 2, nitrogen is liquid during phase a and gaseous at phase b. The enthalpy of the vapor, ~ICd~ between points c and d is generated during cryogenic cooling of an object. This enthalpy typically remains unused and is often wasted.
CA 02208818 1997-06-2~
The present invention utilizes the enthalpy generated during cryogenic cooling of cryoelectronics energy converters to gasify a cryogenic fluid such as nitrogen, thereby reducing energy requirements for the overall operation of processing facilities. This represents a significant improvement over prior art systems which require an amount of heat 5 at least equal to the latent heat of vaporization for nitrogen being introduced into an evaporator.
Referring now to Fig. 4, a gasifier unit 110 and secondary heat recovery and gasseparation unit 120 suitable for use in the present invention are shown. Gasifier unit 110 can be a liquid nitrogen manifold and heat sink. Unit 110 functions as a cryostat for the 10 cryoelectronic energy converters. Liquid nitrogen is introduced into unit 110 from pipe line 118 (from a source such as those illustrated in Fig. 2) at a rate that is suf~lcient to refrigerate the cryoelectronics energy converters and replace gaseous nitrogen removed from unit 110 via pipe line 122. Alternatively, liquid nitrogen can be introduced directly into unit 110 or a liquid air plant can be used to transport liquid nitrogen by tanker instead of transporting gas lS or liquid through a pipe line. In addition. pipe lines. fittings and valves connecting the gasifier to the process plant are employed.
Gasifier unit 110 includes at least one disipative active electrical device 130.Disipative active electrical device(s), as that term is used herein, refers to cryoelectronic energy converters, i.e. cryoconverters. These devices include power supplies and power 20 sinks in a controlled cryogenically cooled environment such that high performance of the device(s) can be achieved. Preferably, unit 110 includes a plurality of disipative active electrical devices 130a, 130b...130n, as shown in Fig. 4. Cryogenic electronics power supplies and power sinks suitable for use in accordance with the present invention include those disclosed in commonly owned U.S. Patent No. 5,347,168 and those disclosed in commonly owned copending U.S. application Serial No. 08/384,780, filed February 6, 1995.
The entire contents of both U.S. Patent No. 5,347,168 and U.S. application Serial No.
08/384,780 are incorporated herein by reference. The disipative active electrical devices, i.e. cryoconverters, can include MOSFETS and/or diodes. High temperature superconductor (HTS) bus bar stock that carry electricity, and cryogenically cooled power electronics for CA 02208818 1997-06-2~
energy conversion and power factor correction can improve the cost effectiveness of chemical plantsj steel plants,-foDd processing plants and the like.
The power electronics thus operate as nitrogen gasifiers while providing cooling for the disipative active electrical devices. The optimization of the cryogenics design of the 5 cryoelectronics is not penalized for the refrigeration system. In a synchronous recti~ler design for example, 0.125 V forward drop at 75,000 A provides the energy available for gasification of roughly 9.3 kW. This will gasify over 100,000 liters of gas per hour. In addition, the gas production rate can be directly proportional to the load in the electrochemical or other chemical plant. In preferred embodiments, the gasifier unit 110 will 10 be capable of producing several hundred thousand liters of gas per hour depending on the electrical load of the disipative active electrical devices(s). It will be appreciated by those skilled in the art that more than one gasifier unit can be employed in accordance with the present invention.
As mentioned above, cryogenic power electronics with cryogen flow through a lS cryostat can be used for evaporating liquid nitrogen or another cryogenic fluid. As shown in Fig. 4, devices 130a..130n can be on the surface of gasifier unit 110, external to the controlled liquid nitrogen environment. Alternatively, disipative active electrical devices 130a..130n and other components can be positioned within the controlled liquid nitrogen environment (see Fig. Sa), above the liquid nitrogen surface level (see Fig. 5c), or a combination of above and within the liquid nitrogen (see Fig. Sb). The controlled liquid nitrogen environment protects the devices from corrosion and the like. Switches can also be installed in the liquid nitrogen environment to avoid the cost of cleaning and maintenance.
Lines 140 provide connection for power source 144 to disipative active electrical device 130 in gasifier unit 110. Lines 142 provide connections for delivering power to a load 146 in the plant 126. In situations where multiple cryogenic devices operate, interconnections of lines 140 and 142 with the multiple devices 130a...130n can be accomplished within unit 110 at cryogenic temperatures. Oftentimes, high current electrical switches can be placed in the cryogen fluid to change the configuration of the power converters and/or to isolate the power converters from the load.
CA 02208818 1997-06-2~
The liquid nitrogen in unit 110 cools or refrigerates the cryogenic devices. During this process, the heat evolved is utilized to gasify the nitrogen, which is subsequently transported to the processing unit 126. Because the cryogenic devices provide power to the plant 126, the amount of nitrogen gasified is directly proportional to the load demands of the S plant. This is advantageous over the prior art in that prior art systems include separate cooling systems for power supplies and the regulation of gas flow is separate from the process requirements.
As further shown in Fig. 4, gaseous nitrogen exiting gasifier unit 110 through pipe line 122 may be introduced into a secondary heat recovery and gas separation unit 120. This 10 may be desirable or necessary to prevent choking in the event that entrained liquid particles are contained in the gaseous nitrogen. Unit 120 separates the entrained particles such that liquid is removed from the gaseous nitrogen and removed from unit 120 through pipe line 128. In some circumstances, it may desirable to recycle liquid nitrogen exiting unit 120 via pipe line 128 through gasifier unit 110. Gaseous nitrogen is then transported through pipe lS line 124 to processing plant 126. It should be appreciated that subsequent heat recovery and gas separation in unit 120 may not always be necessary or desirable. In situations where the nitrogen exiting unit 110 is sufficiently gasified, the nitrogen can be transported directly through pipe line 122 to processing unit 126. Thus, the system can be configured such that pipe line 122 is directly connected to processing unit 126. Alternatively, the system can be 20 configured such that a bypass pipe line 122a or the like (see Fig. 2) allows selective utilization of unit 120. Flow control equipment, e.g. a flow control valve 122b or the like, can be included in this embodiment of the invention.
As described above, nitrogen has been used to illustrate a cryogenic liquid capable of gasification in accordance with the present invention. It will be appreciated by those skilled 25 in the art, however, that the present invention can also be utilized to gasify other cryogenic liquids using the same process or with slight modifications. For example, the present invention can be used in connection with the gasification of liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon and the like. In addition, any other fluid that is CA 02208818 1997-06-2~
capable of operating at temperatures below room temperature when the fluid is used with the cryoelectronics energy converter is suitable for use in the present invention.
Figs. 5a-5c show alternative embodiments of the gasifier unit 110. In particular, the embodiment shown in Figs. 5a-Sc include a dewar vessel 136 or other similar vessel. Dewar 5 vessels, which are double walled tanks having evacuated space between the walls of the vessel, are sealed from the atmosphere. Liquid nitrogen can be introduced into vessel 136 through pipeline 118a, above the level of liquid nitrogen 132 in vessel 136. Alternatively, liquid nitrogen can be introduced through pipeline 118b, such that nitrogen enters vessel 136 below the level of liquid nitrogen 132 in vessel 136. In addition, liquid nitrogen can be introduced into vessel 136 through both pipelines 118a and 118b simultaneously. Valves 138a and 138b or other flow control devices can be employed to regulate the flow of nitrogen through pipelines 118a and 118b, respectively. Other alternative arrangements for introducing the nitrogen into vessel 136 can be employed. For example and while not to be construed as limiting, several pipe lines could be disposed around the circumference of vessel lS 136 and used selectively to introduce liquid nitrogen at predetermined positions and at predetermined times into vessel 136.
As discussed above in connection with Fig. 4, vessel 136 also includes a plurality of disipative active electrical devices 130. As shown in Fig. 5a, these devices can be positioned such that all or substantially all of the disipative active electrical devices are below 20 the liquid nitrogen level 132. Alternatively, if the liquid nitrogen is being used to cool another device (e.g. high temperature superconducting coil) and nitrogen gas and/or mist evolves above the liquid nitrogen, the cryogenic devices can be configured to operate both within the liquid nitrogen and above the liquid nitrogen surface level 132 in the cold gas stream (which may contain liquid particles entrained therein) as shown in Fig. Sb. The 25 cryogenic devices further can be configured to operate above the liquid level of cryogen fluid 132 in the cold gas stream (which may contain liquid particles entrained therein) as also shown in Fig. 5c.
Expansion area 134 is provided to allow nitrogen gas to rise above liquid level 132.
Nitrogen gas then exits vessel 136 through pipeline 122 and is transported to secondary heat recovery and gas separation unit 120 or processing plant 126.
As discussed above in connection with Fig. 4, the gasifier unit 110 shown in Figs.
5 5a-5c is also preferably capable of producing several hundred thousand liters of gas per hour depending on the electrical load of the disipative active electrical device(s). It will be appreciated by those skilled in the art that more than one gasifier unit can be employed in accordance with the present invention. In addition, the embodiments shown in Figs. 5a-Sc can also be utilized to gasify other cryogenic liquids using the same process or with slight lO modifications. For example, the present invention can be used to gasify liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid capable of operating at temperatures below room temperature when the cryogenic fluid is used with thecryoelectronic energy converter.
It should be appreciated by those skilled in the art that the specific embodiments 15 disclosed above may readily be utilized as a basis for modifying or designing other methods or structures for carrying out the same purpose of the present invention. It should also be realized by those skilled in the art that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims
METHODS AND APPARATUS FOR LIQUID CRYOGEN GASIFICATION
UTILIZING CRYOELECTRONICS
TECHNICAL ~IELD
S The present invention generally relates to methods and apparatus for liquid cryogen gasification and more particularly relates to liquid cryogen gasification lltili7ing cryoelectronic devices.
BACKGROUND OF THE INVENTION
Cryogenics relates to the production and maintenance of very low temperatures, often using cryogenic fluids such as hydrogen, helium, nitrogen, oxygen, air or methane. Various discussions concerning cryogenic systems can be found in literature. See e.g., Barron, Cr~vogenic Systems. 2d Ed., Oxford University Press (1985); Bell, Jr., Cr~ogenicEngineering, Prentice Hall Inc. (1963); Vance, Cr~ogenic Technology, John Wiley & Sons, Inc. (1963) and Timmerhaus et al., Cryogenic Process Engineering, Plenum Press (1989).
In addition, U.S. Patent Nos. 3,320,755; 3,714,796 and 3,728,868 disclose cryogenic refrigeration systems (i.e. cryostats). U.S. Patent No. 4,237,699 relates to cryostats for producing cryogenic refrigeration by expansion s~f a working fluid through a Joule-Thomson orifice. The cryostat disclosed in U.S. Patent No. 4 237,699 can be placed in a dewar so that the liquefied working fluid can be maintained to cool an object such as an infrared detector. Similarly, U.S. Patent Nos. 3,021,683 and 3,048,021 relate to gas liquefiers.
U.S. Patent No. 4,653,284 discloses a Joule Thomson heat exchanger and cryostat. U.S.
Patent No. 4,781,033 discloses a heat exchanger for a fast cooldown. The above-mentioned devices and apparatus are useful in liquefaction processes.
Air liquefaction is often utilized to provide liquid or gaseous oxygen for chemical processing and steel production plants. The remaining liquid nitrogen is used in food processing plants and the like. Liquid nitrogen is also converted to a gas for use as a protective blanket for reactive elements in chemical plants. Because of transportation costs and other factors, liquefled nitrogen is typically re-gasified after being liquefied in an air CA 02208818 1997-06-2~
liquefaction plant for use in such facilities. As discussed in greater detail herein, the liquefied nitrogen is transported from an air liquefaction plant, a tanker or the like through a pipe line to an evaporator where it is gasified. The gasified nitrogen is then transported to the chemical, steel or food processing plant for use.
The gaseous nitrogen blankets protect reactive elements used in various processing plants where explosion or cont~min~tion hazards are a significant concern. In addition, many reactive elements used in these plants will undergo oxidation if not adequately protected. In addition to reducing explosion and cont:~min~ion hazards, gaseous nitrogen blankets also reduce the possibilities of undesired oxidation. For example, gaseous nitrogen blankets are sometimes employed in plants where chlorine is produced from salt brine by electrochemical methods. Additionally, food processing plants may use gaseous nitrogen during food processing to preserve expensive foods. Liquid nitrogen is used to flash freeze shrimp or foods that cannot be processed with acceptable quality using norrnal freezing processes.
As mentioned above, prior art techniques for providing gaseous nitrogen blankets to these processing plants typically include the use of air liquefaction plants. In large industrial applications for example, a gas pipe line connects the air plant to the chemical processing plant. The gas pipeline length x is typically about S00-S000 meters. The liquid nitrogen is converted to a gas in an evaporator and transported through the gas pipe line. Heat input requirements to the evaporator must be equivalent to the latent heat of vaporization for the liquid nitrogen, i.e. about 43.6 W/liter/hour.
During the summertime and during periods of high humidity, the liquid nitrogen plant often cannot deliver sufficient gas to the chemical plant. This can be attributed in part to the high humidity causing ice formation on the evaporator. In addition to heat energy requirements to the evaporator, geographical location can thus be a limiting factor in designing such plants. Even if such plants can be constructed in areas where the climate is subject to frequent periods of high humidity, additional design and construction costs must be taken into account to protect the evaporator from the disadvantages associated with such icing.
Another disadvantage associated with the prior art is that separate cooling systems are utilized for power supplies and other large equipment requiring active cooling. For example, in situations where large power supplies are also used in the plant, they are typically either water or air cooled. Consequently, the regulation of nitrogen gas flow from the evaporator is separate from the process requirements in the plant.
It would therefore be desirable to provide methods and apparatus for improving liquid S cryogen gasification such that heat energy requirements and disadvantages caused by high humidity environments are reduced, thereby overcoming the shortcomings associated with the prior art. The resulting gasification will also improve the operation of large equipment requiring active cooling.
Sl~ll~lARY OF THE INVENTION
It is an object of the present invention to provide methods and apparatus for utilizing cryoelectronics systems for gas production systems.
It is another object of the invention to provide methods and apparatus for utilizing waste heat from cryoelectronics energy converters to gasify a cryogenic fluid for subsequent 15 use.
It is a further object of the invention to provide methods and apparatus for providing refrigeration units for cryoelectronics systems in combination with gasification units.
It is still a further object of the invention to provide methods and apparatus for gas production proportional to load requirements in a processing plant.
It is still another object of the invention to provide methods and apparatus forimproving the cost effectiveness and efficiency of various processing plants such as chemical plants, steel plants and food processing plants.
These and other objects of the invention are provided by methods and apparatus that use the waste heat from cryoelectronics energy converters (i.e. cryoconverters or disipative active electrical devices) to gasify nitrogen (or other cryogenic fluid) for chemical or other plants requiring substantial amounts of clean nitrogen (or such other cryogenic fluid). This is accomplished by utilizing high temperature superconductor (HTS) bus bar stock to carry electricity, and cryogenically cooled power electronics for energy conversion and power factor correction to improve the cost effectiveness of chemical plants, steel plants and the like. The power electronic components can be positioned in a controlled cryogenically CA 02208818 1997-06-2~
cooled environment such as a liquid nitrogen environment~ which provides refrigeration to the components. Waste heat from the refrigeration process is used to produce nitrogen gas for the process plant. In an alternative embodiment of the invention, high current electrical switches can be installed in this liquid nitrogen environment to avoid the cost of cleaning and S maintenance.
The liquid nitrogen can be gasified at a rate directly proportional to the load requirements of the plant. Thus, the present invention utilizes the waste heat from cryoelectronics energy converters to gasify nitrogen for such plants and elimin~tes the need for separate refrigeration systems for power supplies to the plant.
The present invention can also be utilized to gasify other cryogenic liquids using the same process or with slight modifications. For example, the present invention can be used in connection with the gasification of liquefied natural gas. carbon dioxide~ oxygen, hydrogen, argom neon and the like.
The present invention employs a liquid air plant or another source of liquid nitrogen such as a tanker truck. a storage tank or the like. In a cryogenic power electronics apparatus, liquid cryogen will flow through a cryostat or gasifier. The cryostat or gasifier can be utilized to evaporate the liquid cryogen, such as liquid nitrogen. Appropriate piping, pipe lines, fittings, valves and the like can be used to connect the source of liquid nitrogen, the gasifier and the process plant.
For example, a liquid air plant can ship liquid nitrogen by tanker or through a pipe line. The power electronics for the plant is housed in the gasifier and operates as a nitrogen gasifier while the liquid nitrogen provides cooling for the power electronics. The optimization of the cryogenics design of the cryoelectronics is not penalized for the refrigeration system. In a synchronous rectifier design for example, 0.125 V forward drop at 75,000 A provides the energy available for gasification of 9.3 kW. This will gasify over 150,000 liters of gas per hour. The gas production rate can be directly proportional to the load in the electrochemical or other chemical plant.
The foregoing has outlined some of the more pertinent objects of the present invention. These objects should be construed to be merely illustrative of some of the more prominent features and applications of the invention. Many other beneficial results can be CA 02208818 1997-06-2~
attained by applying the disclosed invention in a different manner of modifying the invention as will be described. Accordingly, other objects and a fuller understanding of the invention may be had by referring to the following Detailed Description of the Preferred Embodiments.
BRIEF DESCRIPTION OF l~lE DRAWINGS
For a fuller understanding of the present invention, reference is had to the following description taken in conjunction with the accompanying drawings, in which:
Fig. 1 illustrates a flow diagram of prior art techniques utilized to provide gaseous oxygen or nitrogen to chemical processing plants;
Fig. 2 shows a flow diagram suitable providing cryogenic fluids to chemical processing plants in accordance with the present invention;
Fig. 3 illustrates a graph of enthalpy versus temperature for nitrogen;
Fig. 4 illustrates dewar and secondary heat recovery and gas separation units according to one embodiment of the present invention; and Figs. 5a-5c illustrate alternative configurations of dewars for use according to the present invention.
Similar reference characters refer to similar parts throughout the several views of the drawings.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIl\IENTS
As mentioned above, prior art techniques of providing gaseous nitrogen or oxygen to chemical processing plants have included the use of air liquefaction plants and an evaporator.
As illustrated in Fig. 1 for example, prior art systems 10 include air liquefaction plant 30 coupled to evaporator 40 by pipe line 32. Alternatively, liquid nitrogen can be provided to evaporator 40 by tanker 20 through pipe line 22.
Liquid nitrogen is converted to a gaseous state in evaporator 40 and pumped through pipe line 42 to chemical processing plant 50. The length ~c of pipe line 42 is typically 500-5000 m. As further shown in Fig. 1, energy requirements equivalent to the latent heat of vaporization for nitrogen (i.e. about 43.6 W/liter/hour) must be provided to evaporator 40.
CA 02208818 1997-06-2~
In addition to requiring input of the heat necessary to gasify the liquid nitrogen, another disadvantage associated with prior art techniques such as those shown in Fig. 1 include the problems discussed above in connection with ice formation on the evaporator during periods of high humidities. Consequently, construction of chemical processing plants in geographical areas subject to high humidity environments can be undesirable or impractical due to increased cost of construction and design to compensate for ice formation on the evaporator.
Further, prior art systems typically include separate cooling or refrigeration systems for power supplies to the processing plant. As a result, the regulation of gaseous nitrogen flow to the processing plant is separate and not necessarily proportional to the process requirements in the chemical plant.
The present invention overcomes these disadvantages by combining the use of cryoelectronics energy converters and the waste heat generated by refrigerating such converters to gasify nitrogen or other cryogenic fluids in a manner that can be directly lS proportional to the load requirements in a chemical processing facility. The use of cryoelectronics energy converters provide for high performance, thereby enhancing the overall performance of the system. Additionally, the use of the waste heat generated by refrigeration of the converters elimin;3tes or reduces the need to provide energy to an evaporator as practiced in accordance with prior art techniques.
A flow diagram for a system 100 suitable for use in accordance with the present invention is shown in Fig. 2. System 100 includes a gasifier unit 110. As discussed herein, gasifier unit 110 includes cryogenically cooled power electronic devices that provide power to a processing unit 126. Processing unit 126 can be a chemical processing plant, a steel plant, a cryogenic freezing plant or the like.
For purposes of illustration, liquid nitrogen is used to illustrate a cryogenic liquid capable of gasification in accordance with the present invention. It will be appreciated by those skilled in the art, however, that the present invention can also be utilized to gasify other cryogenic liquids using the same process or with slight modifications. For example, the present invention can be used in connection with the gasification of liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon and the like. In addition, any other fluid CA 02208818 1997-06-2~
that is capable of operating at temperatures below room temperature when the fluid is used with the cryoeleetronics energy converter is suitable for use in the present invention. Liquid nitrogen can be supplied to gasifier 110 using various techniques. For example, liquid nitrogen can be transported to gasifier 110 by a tanker 112, from a storage tank 114, from an 5 air liquefaction plant 116 or combinations thereof. As also shown in Fig. 2, nitrogen is transported to gasifier 110 through a pipe line 118, which is constructed of materials suitable for transporting liquid nitrogen. It will be appreciated by those skilled in the art however, that liquid nitrogen can be introduced directly into gasifer 110 from the liquid nitrogen source, thereby elimin~in~ pipe line 118.
Nitrogen is gasified in unit 110 and transported to a secondary heat recovery and gas separation unit 120 through pipe line 122. Secondary heat recovery and gas separation unit 120 can be utilized to prevent choke by further separating liquid particles entrained in the gaseous nitrogen flow. If the gasification process in unit 110 is sufficient, it may not be necessary or desirable to employ unit 120. Nitrogen gas exiting unit 110 or unit 120 is then transported to processing unit 126 through pipe line 122 or 124, respectively. Because the cryoelectronic energy converters that power plant 126 are cryogenically cooled in gasifler 110, nitrogen gasified in unit 110 can be produced at a rate sufficient to supply the plant. In preferred embodiments, nitrogen can be gasified in unit 110 at a rate directly proportional to the load requirements in plant 126. As described in greater detail herein, the present invention utilizes the waste heat from cryoelectronics energy converters to gasify the nitrogen for such plants.
The lengths of pipe lines 118, 122 and 124 (e, f and g respectively) can be varied depending on design parameters and the like. System 100 can be operated in a batch or continuous mode.
Referring now to Fig. 3, a graph of enthalpy versus temperature for nitrogen is illustrated. Cryogenic cooling of an object in a cryogenic fluid such as nitrogen produces an amount of waste heat. As shown in Fig. 2, nitrogen is liquid during phase a and gaseous at phase b. The enthalpy of the vapor, ~ICd~ between points c and d is generated during cryogenic cooling of an object. This enthalpy typically remains unused and is often wasted.
CA 02208818 1997-06-2~
The present invention utilizes the enthalpy generated during cryogenic cooling of cryoelectronics energy converters to gasify a cryogenic fluid such as nitrogen, thereby reducing energy requirements for the overall operation of processing facilities. This represents a significant improvement over prior art systems which require an amount of heat 5 at least equal to the latent heat of vaporization for nitrogen being introduced into an evaporator.
Referring now to Fig. 4, a gasifier unit 110 and secondary heat recovery and gasseparation unit 120 suitable for use in the present invention are shown. Gasifier unit 110 can be a liquid nitrogen manifold and heat sink. Unit 110 functions as a cryostat for the 10 cryoelectronic energy converters. Liquid nitrogen is introduced into unit 110 from pipe line 118 (from a source such as those illustrated in Fig. 2) at a rate that is suf~lcient to refrigerate the cryoelectronics energy converters and replace gaseous nitrogen removed from unit 110 via pipe line 122. Alternatively, liquid nitrogen can be introduced directly into unit 110 or a liquid air plant can be used to transport liquid nitrogen by tanker instead of transporting gas lS or liquid through a pipe line. In addition. pipe lines. fittings and valves connecting the gasifier to the process plant are employed.
Gasifier unit 110 includes at least one disipative active electrical device 130.Disipative active electrical device(s), as that term is used herein, refers to cryoelectronic energy converters, i.e. cryoconverters. These devices include power supplies and power 20 sinks in a controlled cryogenically cooled environment such that high performance of the device(s) can be achieved. Preferably, unit 110 includes a plurality of disipative active electrical devices 130a, 130b...130n, as shown in Fig. 4. Cryogenic electronics power supplies and power sinks suitable for use in accordance with the present invention include those disclosed in commonly owned U.S. Patent No. 5,347,168 and those disclosed in commonly owned copending U.S. application Serial No. 08/384,780, filed February 6, 1995.
The entire contents of both U.S. Patent No. 5,347,168 and U.S. application Serial No.
08/384,780 are incorporated herein by reference. The disipative active electrical devices, i.e. cryoconverters, can include MOSFETS and/or diodes. High temperature superconductor (HTS) bus bar stock that carry electricity, and cryogenically cooled power electronics for CA 02208818 1997-06-2~
energy conversion and power factor correction can improve the cost effectiveness of chemical plantsj steel plants,-foDd processing plants and the like.
The power electronics thus operate as nitrogen gasifiers while providing cooling for the disipative active electrical devices. The optimization of the cryogenics design of the 5 cryoelectronics is not penalized for the refrigeration system. In a synchronous recti~ler design for example, 0.125 V forward drop at 75,000 A provides the energy available for gasification of roughly 9.3 kW. This will gasify over 100,000 liters of gas per hour. In addition, the gas production rate can be directly proportional to the load in the electrochemical or other chemical plant. In preferred embodiments, the gasifier unit 110 will 10 be capable of producing several hundred thousand liters of gas per hour depending on the electrical load of the disipative active electrical devices(s). It will be appreciated by those skilled in the art that more than one gasifier unit can be employed in accordance with the present invention.
As mentioned above, cryogenic power electronics with cryogen flow through a lS cryostat can be used for evaporating liquid nitrogen or another cryogenic fluid. As shown in Fig. 4, devices 130a..130n can be on the surface of gasifier unit 110, external to the controlled liquid nitrogen environment. Alternatively, disipative active electrical devices 130a..130n and other components can be positioned within the controlled liquid nitrogen environment (see Fig. Sa), above the liquid nitrogen surface level (see Fig. 5c), or a combination of above and within the liquid nitrogen (see Fig. Sb). The controlled liquid nitrogen environment protects the devices from corrosion and the like. Switches can also be installed in the liquid nitrogen environment to avoid the cost of cleaning and maintenance.
Lines 140 provide connection for power source 144 to disipative active electrical device 130 in gasifier unit 110. Lines 142 provide connections for delivering power to a load 146 in the plant 126. In situations where multiple cryogenic devices operate, interconnections of lines 140 and 142 with the multiple devices 130a...130n can be accomplished within unit 110 at cryogenic temperatures. Oftentimes, high current electrical switches can be placed in the cryogen fluid to change the configuration of the power converters and/or to isolate the power converters from the load.
CA 02208818 1997-06-2~
The liquid nitrogen in unit 110 cools or refrigerates the cryogenic devices. During this process, the heat evolved is utilized to gasify the nitrogen, which is subsequently transported to the processing unit 126. Because the cryogenic devices provide power to the plant 126, the amount of nitrogen gasified is directly proportional to the load demands of the S plant. This is advantageous over the prior art in that prior art systems include separate cooling systems for power supplies and the regulation of gas flow is separate from the process requirements.
As further shown in Fig. 4, gaseous nitrogen exiting gasifier unit 110 through pipe line 122 may be introduced into a secondary heat recovery and gas separation unit 120. This 10 may be desirable or necessary to prevent choking in the event that entrained liquid particles are contained in the gaseous nitrogen. Unit 120 separates the entrained particles such that liquid is removed from the gaseous nitrogen and removed from unit 120 through pipe line 128. In some circumstances, it may desirable to recycle liquid nitrogen exiting unit 120 via pipe line 128 through gasifier unit 110. Gaseous nitrogen is then transported through pipe lS line 124 to processing plant 126. It should be appreciated that subsequent heat recovery and gas separation in unit 120 may not always be necessary or desirable. In situations where the nitrogen exiting unit 110 is sufficiently gasified, the nitrogen can be transported directly through pipe line 122 to processing unit 126. Thus, the system can be configured such that pipe line 122 is directly connected to processing unit 126. Alternatively, the system can be 20 configured such that a bypass pipe line 122a or the like (see Fig. 2) allows selective utilization of unit 120. Flow control equipment, e.g. a flow control valve 122b or the like, can be included in this embodiment of the invention.
As described above, nitrogen has been used to illustrate a cryogenic liquid capable of gasification in accordance with the present invention. It will be appreciated by those skilled 25 in the art, however, that the present invention can also be utilized to gasify other cryogenic liquids using the same process or with slight modifications. For example, the present invention can be used in connection with the gasification of liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon and the like. In addition, any other fluid that is CA 02208818 1997-06-2~
capable of operating at temperatures below room temperature when the fluid is used with the cryoelectronics energy converter is suitable for use in the present invention.
Figs. 5a-5c show alternative embodiments of the gasifier unit 110. In particular, the embodiment shown in Figs. 5a-Sc include a dewar vessel 136 or other similar vessel. Dewar 5 vessels, which are double walled tanks having evacuated space between the walls of the vessel, are sealed from the atmosphere. Liquid nitrogen can be introduced into vessel 136 through pipeline 118a, above the level of liquid nitrogen 132 in vessel 136. Alternatively, liquid nitrogen can be introduced through pipeline 118b, such that nitrogen enters vessel 136 below the level of liquid nitrogen 132 in vessel 136. In addition, liquid nitrogen can be introduced into vessel 136 through both pipelines 118a and 118b simultaneously. Valves 138a and 138b or other flow control devices can be employed to regulate the flow of nitrogen through pipelines 118a and 118b, respectively. Other alternative arrangements for introducing the nitrogen into vessel 136 can be employed. For example and while not to be construed as limiting, several pipe lines could be disposed around the circumference of vessel lS 136 and used selectively to introduce liquid nitrogen at predetermined positions and at predetermined times into vessel 136.
As discussed above in connection with Fig. 4, vessel 136 also includes a plurality of disipative active electrical devices 130. As shown in Fig. 5a, these devices can be positioned such that all or substantially all of the disipative active electrical devices are below 20 the liquid nitrogen level 132. Alternatively, if the liquid nitrogen is being used to cool another device (e.g. high temperature superconducting coil) and nitrogen gas and/or mist evolves above the liquid nitrogen, the cryogenic devices can be configured to operate both within the liquid nitrogen and above the liquid nitrogen surface level 132 in the cold gas stream (which may contain liquid particles entrained therein) as shown in Fig. Sb. The 25 cryogenic devices further can be configured to operate above the liquid level of cryogen fluid 132 in the cold gas stream (which may contain liquid particles entrained therein) as also shown in Fig. 5c.
Expansion area 134 is provided to allow nitrogen gas to rise above liquid level 132.
Nitrogen gas then exits vessel 136 through pipeline 122 and is transported to secondary heat recovery and gas separation unit 120 or processing plant 126.
As discussed above in connection with Fig. 4, the gasifier unit 110 shown in Figs.
5 5a-5c is also preferably capable of producing several hundred thousand liters of gas per hour depending on the electrical load of the disipative active electrical device(s). It will be appreciated by those skilled in the art that more than one gasifier unit can be employed in accordance with the present invention. In addition, the embodiments shown in Figs. 5a-Sc can also be utilized to gasify other cryogenic liquids using the same process or with slight lO modifications. For example, the present invention can be used to gasify liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid capable of operating at temperatures below room temperature when the cryogenic fluid is used with thecryoelectronic energy converter.
It should be appreciated by those skilled in the art that the specific embodiments 15 disclosed above may readily be utilized as a basis for modifying or designing other methods or structures for carrying out the same purpose of the present invention. It should also be realized by those skilled in the art that such equivalent constructions do not depart from the spirit and scope of the invention as set forth in the appended claims
Claims (53)
1. A gasification unit for gasification of a cryogenic fluid, the unit comprising:
a cryostat capable of refrigerating cryoelectronics energy converters to predetermined temperatures;
at least one cryoelectronic energy converter at a predetermined position in the cryostat; and input/output means for supplying power to the at least one cryoelectronics energy converter and receiving power from the at least one cryoelectronics energy converter;
wherein the refrigeration of the at least one cryoelectronics energy converter is capable of gasifying a cryogenic fluid at a predetermined rate.
a cryostat capable of refrigerating cryoelectronics energy converters to predetermined temperatures;
at least one cryoelectronic energy converter at a predetermined position in the cryostat; and input/output means for supplying power to the at least one cryoelectronics energy converter and receiving power from the at least one cryoelectronics energy converter;
wherein the refrigeration of the at least one cryoelectronics energy converter is capable of gasifying a cryogenic fluid at a predetermined rate.
2. The gasification unit of claim 1, further including a cryogenic fluid.
3. The gasification unit of claim 2, wherein the cryogenic fluid is nitrogen, liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid capable of operating at temperatures below room temperature when the cryogenic fluid is used with the cryoelectronic energy converter.
4. The gasification unit of claim 1, wherein the position of the at least one cryoelectronics energy converter in the cryostat is such that the at least one cryoelectronic energy converter is above a surface level of a cryogenic fluid in the cryostat.
5. The gasification unit of claim 4, wherein the position of the at least one cryoelectronics energy converter is at a level where gasified cryogenic fluid is present.
6. The gasification unit of claim 5, wherein the gasified fluid contains liquid particulates entrained therein.
7. The gasification unit of claim 1, wherein the at least one cryoelectronic energy converter includes a MOSFET.
8. The gasification unit of claim 7, further including a cryogenic fluid.
9. The gasification unit of claim 8, wherein the cryogenic fluid is nitrogen, liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid capable of operating at temperatures below room temperature when the cryogenic fluid is used with the cryoelectronic energy converter.
10. The gasification unit of claim 1, wherein a plurality of cryoelectronic energy converters are arranged in predetermined positions in the cryostat.
11. The gasification unit of claim 10, further including a cryogenic fluid.
12. The gasification unit of claim 11, wherein the cryogenic fluid is nitrogen, liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid capable of operating at temperatures below room temperature when the cryogenic fluid is used with the cryoelectronic energy converter.
13. The gasification unit of claim 1, wherein the unit is capable of gasifying at least 1 liter/hour of cryogenic fluid.
14. The gasification unit of claim 13, further including a cryogenic fluid.
15. The gasification unit of claim 14, wherein the cryogenic fluid is nitrogen, liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid capable of operating at temperatures below room temperature when the cryogenic fluid is used with the cryoelectronic energy converter.
16. The gasification unit of claim 1, further including a secondary heat recovery unit coupled to the gasification unit.
17. The gasification unit of claim 16, wherein the secondary heat recovery unit is capable of separating entrained liquid particles from the gasified cryogenic fluid produced by the gasification unit.
18. The gasification unit of claim 1, further including a cryogenic fluid in the unit and wherein the at least one cryoelectronic energy converter is positioned below the surface level of the cryogenic fluid.
19. A system for providing a gasified cryogenic fluid to a processing plant, thesystem comprising:
a gasification unit for gasification of a cryogenic fluid, the unit comprising:
a cryostat capable of refrigerating cryoelectronics energy converters to predetermined temperatures;
at least one cryoelectronic energy converter at a predetermined position in the cryostat;
input/output means for supplying power to the at least one cryoelectronics energy converter and receiving power from the at least one cryoelectronic energy converter;
wherein the refrigeration of the at least one cryoelectronic energy converter iscapable of gasifying a cryogenic fluid at a predetermined rate; and a chemical processing plant coupled to the gasification unit.
a gasification unit for gasification of a cryogenic fluid, the unit comprising:
a cryostat capable of refrigerating cryoelectronics energy converters to predetermined temperatures;
at least one cryoelectronic energy converter at a predetermined position in the cryostat;
input/output means for supplying power to the at least one cryoelectronics energy converter and receiving power from the at least one cryoelectronic energy converter;
wherein the refrigeration of the at least one cryoelectronic energy converter iscapable of gasifying a cryogenic fluid at a predetermined rate; and a chemical processing plant coupled to the gasification unit.
20. The system of claim 19, wherein the chemical processing unit is coupled to the gasification unit by a pipe line.
21. The system of claim 20, wherein the pipe line is capable of transporting gasified cryogenic fluid therethrough.
22. The system of claim 21, further including a predetermined amount of cryogenic fluid in the gasification unit.
23. The system of claim 22, wherein the cryogenic fluid is nitrogen, liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid capable of operating at temperatures below room temperature when the cryogenic fluid is used with the cryoelectronic energy converter.
24. The system of claim 19, wherein the position of the at least one cryoelectronics energy converter in the cryostat is such that the at least one cryoelectronic energy converter is above a surface level of a cryogenic fluid in the cryostat.
25. The gasification unit of claim 24, wherein the position of the at least one cryoelectronic energy converter is at a level where gasified cryogenic fluid is present.
26. The gasification unit of claim 25, wherein the gasified fluid contains liquid particulate entrained therein.
27. The system of claim 19, wherein the at least one cryoelectronic energy converter is capable of providing power to the chemical processing plant.
28. The system of claim 27, wherein the gasification unit is capable of providing gasified cryogenic fluid to the chemical processing plant.
29. The system of claim 28, wherein the rate of providing gasified cryogenic fluid is proportional to the power provided to the chemical processing plant.
30. The system of claim 29, further including a predetermined amount of cryogenic fluid in the gasification unit.
31. The system of claim 30, wherein the cryogenic fluid is nitrogen, liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid-capable of operating at temperatures below room temperature when the cryogenic fluid is used with the cryoelectronic energy converter.
32. The system unit of claim 19, wherein the at least one cryoelectronics energyconverter includes a MOSFET.
33. The system of claim 19, wherein a plurality of cryoelectronic energy converters are arranged in predetermined positions in the cryostat.
34. The system of claim 33, further including a cryogenic fluid.
35. The system of claim 34, wherein the cryogenic fluid is nitrogen, liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid capable of operating at temperatures below room temperature when the cryogenic fluid is used with the cryoelectronic energy converter.
36. The system of claim 19, wherein the gasification unit is capable of gasifying at least 1 liter/hour of cryogenic fluid.
37. The system of claim 19, further including a secondary heat recovery unit coupled to the gasification unit upstream of the chemical processing unit.
38. The system of claim 37, wherein the secondary heat recovery unit is capable of separating entrained liquid particles from the gasified cryogenic fluid produced by the gasification unit.
39. The system of claim 19, further including a cryogenic fluid in the gasification unit and wherein the at least one cryoelectronic energy converter is positioned below the surface level of the cryogenic fluid.
40. The system of claim 19, further including a source of cryogenic fluid.
41. The system of claim 19, wherein the source of cryogenic fluid is an air liquefaction plant.
42. The system of claim 19, wherein the source of cryogenic fluid is a storage tank.
43. The system of claim 19, wherein the source of cryogenic fluid is a vehicle.
44. The system of claim 40, 41, 42, or 43, wherein the cryogenic fluid is nitrogen, liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid capable of operating at temperatures below room temperature when the cryogenic fluid is used with the cryoelectronic energy converter.
45. A method for gasifying a cryogenic fluid, comprising:
introducing a predetermined amount of cryogenic fluid into a gasification unit, the gasification unit having at least one cryoelectronic energy converter at a predetermined position therein; and allowing the cryogenic fluid to refrigerate the at least one cryoelectronic energy converter under conditions sufficient for heat generated during the refrigeration to gasify the cryogenic fluid.
introducing a predetermined amount of cryogenic fluid into a gasification unit, the gasification unit having at least one cryoelectronic energy converter at a predetermined position therein; and allowing the cryogenic fluid to refrigerate the at least one cryoelectronic energy converter under conditions sufficient for heat generated during the refrigeration to gasify the cryogenic fluid.
46. The method of claim 45, further including introducing the gasified cryogenicfluid to a chemical processing plant.
47. The method of claim 46, wherein the chemical processing plant is a chlorine manufacturing plant.
48. The method of claim 46, wherein the chemical processing plant is a food processing plant.
49. The method of claim 46, wherein the chemical processing plant is a steel manufacturing plant.
50. The method of claim 45, 46, 47, 48, or 49, wherein the cryogenic fluid is nitrogen, liquefied natural gas, carbon dioxide, oxygen, hydrogen, argon, neon or any other fluid capable of operating at temperatures below room temperature when the cryogenic fluid is used with the cryoelectronic energy converter.
51. The method of claim 45, 46, 47, 48, or 49, wherein the gasification unit is capable of gasifying at least 1 liter/hour of cryogenic fluid.
52. The method of claim 45, further including introducing the gasified cryogenicfluid to secondary heat recovery unit coupled to the gasification unit.
53. The method of claim 52, further including separating entrained liquid particles from the gasified cryogenic fluid produced by the gasification in the secondary heat recovery unit.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/671,860 US5787713A (en) | 1996-06-28 | 1996-06-28 | Methods and apparatus for liquid cryogen gasification utilizing cryoelectronics |
| US08/671,860 | 1996-06-28 |
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| CA2208818A1 true CA2208818A1 (en) | 1997-12-28 |
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| CA 2208818 Abandoned CA2208818A1 (en) | 1996-06-28 | 1997-06-25 | Methods and apparatus for liquid cryogen gasification utilizing cryoelectrics |
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| CA (1) | CA2208818A1 (en) |
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| CN101118028B (en) * | 2007-08-03 | 2011-06-22 | 自贡鸿鹤化工股份有限公司 | Liquid chlorine gasification device and gasification method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| US6257329B1 (en) * | 1998-08-17 | 2001-07-10 | Alfiero Balzano | Thermal management system |
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| US20040118144A1 (en) * | 2002-12-20 | 2004-06-24 | Hsu John S. | Hermetic inverter/converter chamber with multiple pressure and cooling zones |
| US7087804B2 (en) * | 2003-06-19 | 2006-08-08 | Chevron U.S.A. Inc. | Use of waste nitrogen from air separation units for blanketing cargo and ballast tanks |
| US20070023169A1 (en) * | 2005-07-29 | 2007-02-01 | Innovative Fluidics, Inc. | Synthetic jet ejector for augmentation of pumped liquid loop cooling and enhancement of pool and flow boiling |
| US20080173427A1 (en) * | 2007-01-23 | 2008-07-24 | Richard Schumacher | Electronic component cooling |
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| KR102224079B1 (en) * | 2020-08-31 | 2021-03-05 | 한국화학연구원 | Carbon monoxide recovery system and recovery method from industrial by-product gas |
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| US3048021A (en) * | 1959-02-17 | 1962-08-07 | Itt | Joule-thomson effect gas liquefier |
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| US3320755A (en) * | 1965-11-08 | 1967-05-23 | Air Prod & Chem | Cryogenic refrigeration system |
| SU403927A1 (en) * | 1969-12-12 | 1973-10-26 | CRYOSTAT | |
| US3714796A (en) * | 1970-07-30 | 1973-02-06 | Air Prod & Chem | Cryogenic refrigeration system with dual circuit heat exchanger |
| US3728868A (en) * | 1971-12-06 | 1973-04-24 | Air Prod & Chem | Cryogenic refrigeration system |
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| US4970868A (en) * | 1989-06-23 | 1990-11-20 | International Business Machines Corporation | Apparatus for temperature control of electronic devices |
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| DE4445183A1 (en) * | 1994-03-02 | 1995-09-07 | Daimler Benz Aerospace Ag | Refuelling aircraft with liquefied hydrogen or natural gas |
-
1996
- 1996-06-28 US US08/671,860 patent/US5787713A/en not_active Expired - Fee Related
-
1997
- 1997-06-25 CA CA 2208818 patent/CA2208818A1/en not_active Abandoned
-
1998
- 1998-08-04 US US09/128,883 patent/US6092372A/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101118028B (en) * | 2007-08-03 | 2011-06-22 | 自贡鸿鹤化工股份有限公司 | Liquid chlorine gasification device and gasification method |
Also Published As
| Publication number | Publication date |
|---|---|
| US5787713A (en) | 1998-08-04 |
| US6092372A (en) | 2000-07-25 |
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| Date | Code | Title | Description |
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| FZDE | Discontinued |