CA2208232A1 - High molecular weight high density polyethylene with improved tear resistance - Google Patents

High molecular weight high density polyethylene with improved tear resistance

Info

Publication number
CA2208232A1
CA2208232A1 CA002208232A CA2208232A CA2208232A1 CA 2208232 A1 CA2208232 A1 CA 2208232A1 CA 002208232 A CA002208232 A CA 002208232A CA 2208232 A CA2208232 A CA 2208232A CA 2208232 A1 CA2208232 A1 CA 2208232A1
Authority
CA
Canada
Prior art keywords
styrene
molecular weight
tear resistance
component
high molecular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002208232A
Other languages
French (fr)
Other versions
CA2208232C (en
Inventor
Thomas Samyon Daniluk
Steven Arthur Best
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents, Inc.
Thomas Samyon Daniluk
Steven Arthur Best
Exxonmobil Chemical Patents, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents, Inc., Thomas Samyon Daniluk, Steven Arthur Best, Exxonmobil Chemical Patents, Inc. filed Critical Exxon Chemical Patents, Inc.
Publication of CA2208232A1 publication Critical patent/CA2208232A1/en
Application granted granted Critical
Publication of CA2208232C publication Critical patent/CA2208232C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/02—Ziegler natta catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1397—Single layer [continuous layer]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/24992—Density or compression of components
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

Abstract

Articles fabricated from certain high molecular weight high density polyethylenes (HMW-HDPE) combined with a second component, exhibit superior puncture propagation tear resistance and puncture propagation tear length. The second component may be an elastomer such as styrene-butadiene-styrene, styrene-isoprene-styrene, EPR, EPDM, butyl rubber, metallocene-calatyzed polyethylene, and combinations thereof. The second component or components will be present in a fabricated article from 1 to 15 weight percent. Articles include films, bags made from films, and extrusion blow-molded articles.
CA 2208232 1994-12-12 1995-12-12 High molecular weight high density polyethylene with improved tear resistance Expired - Fee Related CA2208232C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/354,393 US5635262A (en) 1994-12-12 1994-12-12 High molecular weight high density polyethylene with improved tear resistance
US08/354,393 1994-12-12
PCT/US1995/015960 WO1996018678A1 (en) 1994-12-12 1995-12-12 High molecular weight high density polyethylene with improved tear resistance

Publications (2)

Publication Number Publication Date
CA2208232A1 true CA2208232A1 (en) 1996-06-20
CA2208232C CA2208232C (en) 2001-04-24

Family

ID=23393140

Family Applications (1)

Application Number Title Priority Date Filing Date
CA 2208232 Expired - Fee Related CA2208232C (en) 1994-12-12 1995-12-12 High molecular weight high density polyethylene with improved tear resistance

Country Status (6)

Country Link
US (1) US5635262A (en)
EP (1) EP0797622B1 (en)
AT (1) ATE177460T1 (en)
CA (1) CA2208232C (en)
DE (1) DE69508278T2 (en)
WO (1) WO1996018678A1 (en)

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US5897941A (en) * 1996-04-12 1999-04-27 Cryovac, Inc. High modulus film
KR980002138A (en) * 1996-06-17 1998-03-30 성재갑 Standing Pouch, Material Composition of Attachment and How to Use Pouch
US5733628A (en) 1996-10-10 1998-03-31 Tredegar Industries, Inc. Breathable elastic polymeric film laminates
DE69821358T2 (en) * 1997-06-25 2004-07-22 Eastman Chemical Co., Kingsport SINGLE LAYER FILM
US6017615A (en) * 1997-08-25 2000-01-25 Huntsman Polymers Corporation Film product comprising novel polyolefins
US6070394A (en) * 1997-09-12 2000-06-06 Eastman Chemical Company Lownoise stretch wrapping process
US6204335B1 (en) 1997-09-12 2001-03-20 Eastman Chemical Company Compositions of linear ultra low density polyethylene and propylene polymers and films therefrom
US6197887B1 (en) 1997-09-12 2001-03-06 Eastman Chemical Company Compositions having particular utility as stretch wrap cling film
US6153702A (en) * 1997-09-12 2000-11-28 Eastman Chemical Company Polymers, and novel compositions and films therefrom
US6045882A (en) * 1998-07-16 2000-04-04 Viskase Corporation Multilayer thin plastic film, useful for shrink overwrap packaging
AUPP591998A0 (en) 1998-09-15 1998-10-08 Anthony Smith Australasia Pty Ltd Closure
US6298984B1 (en) 1999-01-22 2001-10-09 Einstone, Inc. Packaging for deactivated cement and cement activator and procedure for mixing deactivated cement and cement activator therein
US6680265B1 (en) 1999-02-22 2004-01-20 Kimberly-Clark Worldwide, Inc. Laminates of elastomeric and non-elastomeric polyolefin blend materials
US6391411B1 (en) 1999-06-03 2002-05-21 Printpack Illinois, Inc. Machine direction oriented high molecular weight, high density polyethylene films with enhanced water vapor transmission properties
EP1214373A1 (en) * 1999-08-12 2002-06-19 Baxter International Inc. Thermoplastic composition
US6602593B1 (en) * 1999-08-30 2003-08-05 Celgard Inc. Battery separators with reduced splitting propensity
WO2001058681A1 (en) * 2000-02-11 2001-08-16 Denglas Technologies, Llc. Antireflective uv blocking multilayer coatings wherin film has cerium oxide
US6432586B1 (en) 2000-04-10 2002-08-13 Celgard Inc. Separator for a high energy rechargeable lithium battery
US6998157B2 (en) * 2001-03-30 2006-02-14 E.I. Du Pont De Nemours And Company, Inc. Thermoformable packaging film
US6814914B2 (en) * 2001-05-30 2004-11-09 Konica Corporation Cellulose ester film, its manufacturing method, optical retardation film, optical compensation sheet, elliptic polarizing plate, and image display
CN1315919C (en) * 2001-07-19 2007-05-16 尤尼威蒂恩技术有限责任公司 Polyethylene films with improved physical properties
US6936675B2 (en) 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
US20030104236A1 (en) * 2001-12-03 2003-06-05 Celgard Inc. Diffusion membrane
US20030113496A1 (en) * 2001-12-17 2003-06-19 Harris Michael G. Polyethylene melt blends for high density polyethylene applications
US6822051B2 (en) * 2002-03-29 2004-11-23 Media Plus, Inc. High density polyethylene melt blends for improved stress crack resistance in pipe
US6670035B2 (en) * 2002-04-05 2003-12-30 Arteva North America S.A.R.L. Binder fiber and nonwoven web
TW200504093A (en) * 2003-05-12 2005-02-01 Dow Global Technologies Inc Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom
US6870010B1 (en) 2003-12-01 2005-03-22 Univation Technologies, Llc Low haze high strength polyethylene compositions
US7288596B2 (en) * 2003-12-22 2007-10-30 Univation Technologies, Llc Polyethylene compositions having improved tear properties
US8440125B2 (en) * 2004-06-28 2013-05-14 Equistar Chemicals, Lp Polyethylene films having high resistance to deformation or elongation
US7193017B2 (en) * 2004-08-13 2007-03-20 Univation Technologies, Llc High strength biomodal polyethylene compositions
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US7473473B2 (en) * 2004-12-01 2009-01-06 Cryovac, Inc. Tear resistant shrink film
US20060115613A1 (en) * 2004-12-01 2006-06-01 Cryovac, Inc. Patch bag and barrier bag
US7312279B2 (en) * 2005-02-07 2007-12-25 Univation Technologies, Llc Polyethylene blend compositions
US8053048B2 (en) * 2005-04-25 2011-11-08 Baxter International Inc. Overpouch film and container and method of making same
CN1325553C (en) * 2005-05-19 2007-07-11 洛阳石化聚丙烯有限责任公司 Metallocene tribasic ethylene propylene rubber-polyethylene crosslinking substance in low density, preparation method and application
US8202001B1 (en) * 2006-01-26 2012-06-19 Chunhua Zhang Self-opening bag pack and method thereof
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US8263198B2 (en) * 2007-09-26 2012-09-11 Chevron Phillips Chemical Company Lp System and method for creating high gloss plastic items via the use of styrenic copolymers as a coextruded layer
US8215803B2 (en) 2009-08-19 2012-07-10 Gregg Singer Cover sleeve for CFL bulb
US8993681B2 (en) 2011-07-14 2015-03-31 Exxonmobil Research And Engineering Company Dendritic ethylene polymers and processes for making
US8915623B1 (en) * 2012-02-01 2014-12-23 St. Albert Innovations, LLC Cover for a light bulb
GB2580929B (en) 2019-01-30 2021-11-17 Innovia Films Ltd Film
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Also Published As

Publication number Publication date
DE69508278T2 (en) 1999-09-30
DE69508278D1 (en) 1999-04-15
EP0797622A1 (en) 1997-10-01
US5635262A (en) 1997-06-03
WO1996018678A1 (en) 1996-06-20
CA2208232C (en) 2001-04-24
EP0797622B1 (en) 1999-03-10
ATE177460T1 (en) 1999-03-15

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