CA2205027C - Diaper having a lotioned topsheet - Google Patents
Diaper having a lotioned topsheet Download PDFInfo
- Publication number
- CA2205027C CA2205027C CA002205027A CA2205027A CA2205027C CA 2205027 C CA2205027 C CA 2205027C CA 002205027 A CA002205027 A CA 002205027A CA 2205027 A CA2205027 A CA 2205027A CA 2205027 C CA2205027 C CA 2205027C
- Authority
- CA
- Canada
- Prior art keywords
- emollient
- absorbent article
- topsheet
- disposable absorbent
- lotion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/48—Surfactants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/51113—Topsheet, i.e. the permeable cover or layer facing the skin comprising an additive, e.g. lotion or odour control
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/84—Accessories, not otherwise provided for, for absorbent pads
- A61F13/8405—Additives, e.g. for odour, disinfectant or pH control
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4993—Derivatives containing from 2 to 10 oxyalkylene groups
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/22—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing macromolecular materials
- A61L15/34—Oils, fats, waxes or natural resins
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
- D21H21/24—Surfactants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
- A61F13/511—Topsheet, i.e. the permeable cover or layer facing the skin
- A61F13/51113—Topsheet, i.e. the permeable cover or layer facing the skin comprising an additive, e.g. lotion or odour control
- A61F2013/51117—Topsheet, i.e. the permeable cover or layer facing the skin comprising an additive, e.g. lotion or odour control the lotion having skin care properties
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/31—Anhydrous
Abstract
A diaper containing a liquid pervious topsheet coated with a lotion composition is disclosed. The lotion composition reduces the adherence of BM
to the skin of the wearer, thereby improving the ease of BM cleanup. The lotion composition comprises a plastic or fluid emollient such as mineral oil or petrolatum, an immobilizing agent such as a fatty alcohol or paraffin wax to immobilize the emollient on the surface of the diaper topsheet, and optionally a hydrophilic surfactant to improve wettability of the coated topsheet. Because the emollient is substantially immobilized on the surface of the topsheet, less lotion is required to impart the desired therapeutic or protective lotion coating benefits.
to the skin of the wearer, thereby improving the ease of BM cleanup. The lotion composition comprises a plastic or fluid emollient such as mineral oil or petrolatum, an immobilizing agent such as a fatty alcohol or paraffin wax to immobilize the emollient on the surface of the diaper topsheet, and optionally a hydrophilic surfactant to improve wettability of the coated topsheet. Because the emollient is substantially immobilized on the surface of the topsheet, less lotion is required to impart the desired therapeutic or protective lotion coating benefits.
Description
DIAPE,F2 HAVING A LOTIONED TOPSHEET
This application relates to absorbent articles such as diapers, training pants, adult incontinence devices, and the like. More particularly, the present invention relates to absorbent articles having a lotion coating on the outer surface of the topsheet that is transferable to the wearers skin by normal contact and wearer motion and/or body heat. The lotions disclosed in the present invention reduce the adherence of BM to the skin of the wearer, thereby improving the ease of BM clean up.
BACKGROUND OF THE INVENTION
Many types of disposable absorbent products, such as diapers, are available that have a high capacity for absorbing urine. Disposable pro~ta of this type generally comprise some sort of fluid-permeable topsheet material, an absorbent core, and a fluid-impermeable backsheet material. Although these types of absorbent structures may be highly efficier>Z for the absorption of fluids, they cannot absorb bowel movements i.e., hereinafter referred to as "BM"). Typically, the BM is Yapped between the outer surface of the fluid-permeable topsheet and the skin of the wearer, much of it adhering to the wearers skin.
To prevent BM from adhering to the wearers skin, the caregiver often applies protective or "repellent" products such as vasefine or mineral oil to the buttocks and anal region before placing the absorbent article on the wearer. This procedure usually involves the caregivers pouring of the oil or lotion, for example, in one of their hands, rubbing both hands together to distribute the substance thereon and then wiping the same on the skin of the infant. To eliminate the need for this wasteful, messy, and easily forgotten procedure, there have been numerous previous attempts to prepare absorbent articles which contain a protective or therapeutic skin care substance on the topsheet.
One substance that has been applied as a lotion to diaper products to impart a soothing, protective coating is mineral oil. Mineral oil (also known as liquid petrolatum) is a mixture of various liquid hydrocarbons obtained by distilling the high-boiling (i.e., 300°-390°C) fractions in petroleum. Mineral oil is liquid at ambient temperatures, e.g. 20°-25°C. As a result, mineral oil is relatively fluid and mobile, even when- applied to diaper topsheets.
Because mineral oil is fluid and mobile at ambient temperatures, it tends not to remain localized on the surface of the topsheet, but instead migrates through the topsheet into the interior of the diaper. Accordingly, relatively high levels of mineral oil need to be applied to the topsheet to provide the desired therapeutic or protective coating lotion benefits. This leads not only to increased costs for these lotioned diaper products, but other detrimental effects as well.
One of these detrimental effects is a decrease in the fluid handling properties as high levels of mineral oil tend to block the topsheet openings.
Atso, as mineral oil migrates to the interior of the diaper, it tends to act as a hydrophobic additive, thus decreasing the absorbency of the underlying absorbent core, if one is used. This decrease in absorbency becomes more pronounced as the level of mineral oil applied is increased.
Even without increasing its level, the tendency of mineral oil to migrate once applied has other detrimental effects. For example, the applied mineral oil can transfer to, into and through the packaging or wrapper material for the lotioned diaper product. This can create the need for ban-ier-type packaging or wrapper films to avoid smearing or other leakage of mineral oil from the diaper product.
Accordingly, it would be desirable to provide lotioned diaper products that: (1 ) have desirable therapeutic or protective coating lotion benefits (2) do not require relatively high levels of coatings that are liquid at room temperature (e.g., mineral oil) (3) do not adversely affect the absorbency of the diaper product; and (4) do not require special wrapping or barrier materials for packaging.
U.5. Patent 3,585,998 to Hayford et al. teaches a disposable baby diaper, an interior liner of which carnes an array of pressure-rupturable capsules containing S baby oil. The patent teaches that it is desirable to break the capsules prior to using the diaper by applying pressure with such household items as a rolling pin, hand iron, etc.
The same principle of pressure-rupturable capsules is used in U.S. Patent 3,464,413 to Goldfarb et al. for making bandages capable of delivering a medicinal material to an injury. Articles disclosed by both patents have a serious drawback. Namely, unless the capsules are ruptured by applying pressure prior to using the diaper or the bandage, the skin-care substance contained in the capsules is either not delivered at all or is delivered non-uniformly leaving some areas of skin uncoated.
U.5. Patent 3,896,807 to Buchaller teaches an article impregnated with a solid oil phase of cream formulation which forms a cream upon addition of moisture thereto. A major disadvantage of the article disclosed by the reference is that transfer of a beneficial substance from the absorbent substrate to skin is delayed and is only realized when body fluids are released.
U.S. Patent 3,489,148 to Duncan et al. teaches a baby diaper comprising a hydrophobic and oleophobic topsheet wherein a portion of the topsheet is coated with a discontinuous film of oleaginous material. A major disadvantage of the diapers disclosed in the Duncan et al. reference is that the hydrophobic and oleophobic topsheets are slow in promoting transfer of urine to the underlying aborbent cores.
Therefore, it is an object of an aspect of the present invention to provide a disposable diaper having a hydrophilic topsheet having superior fluid handing properties.
It is a further object of an aspect of the present invention to provide a hydrophilic diaper topsheet having a lotion coating on the outer surface of the topsheet that is transferable to the wearer's skin and is effective at reducing the adherence of BM to the skin, thereby improving the ease of BM cleanup.
It is yet a further object of an aspect of the present invention desirable to provide lotioned diaper products that: (1) have desirable BM release, cleaning, therapeutic or protective lotion coating benefits; (2) do not require relatively high levels of mineral oil; (3) do not adversely affect the fluid handling properties of the diaper; and (4) do not require special wrapping or barner materials for packaging.
These and other object of aspects are obtained using the present invention, as will become readily apparent from a reading of the following disclosure.
SUMMARY OF THE INVENTION
The present invention relates to a disposable diaper having a lotion coating on the outer surface of the topsheet that is semisolid or solid at ambient temperatures (i.e., at 20°C) and is adapted to be transferred to the wearer's skin, where it acts to reduce the adherence of BM to the skin of the wearer, thereby improving the ease of BM clean up.
Briefly, the disposable diapers of the present invention comprise:
A) a liquid impervious backsheet B) a liquid pervious, hydrophilic topsheet joined to said backsheet, said topsheet having an inner surface oriented toward the interior of said diaper and an outer surface oriented toward the skin of the wearer when said diaper is being worn, wherein at least a portion of said topsneet outer surface comprises an effective amount of a lotion coating which is semi-solid or solid at 20°C and which is partially transferable to the wearer's skin, said lotion coating comprising:
(i) from about 10 to about 95% of a substantially water free emollient having a plastic or fluid consistency at 20°C and comprising a member selected from the group consisting of petroleum-based emollients, fatty acid ester emollients, alkyl ethoxylate emollients, polysiloxane emollients, and mixtures thereof;
(ii) from about 5 to about 90% of an agent capable of immobilizing said emollient on said outer surface of the topsheet, said immobilizing agent having a melting point of at least about 35°C; and C) an absorbent core positioned between said topsheet and said backsheet.
The quantity of lotion coating on a least a portion of the diaper topsheets of S the present invention preferably ranges from about 0.1 mg/inz to about 25 mg/in2, more preferably from about 1 mg/in2 to about 10 mg/in2. Lotioned diaper topsheets according to the present invention provide desirable BM cleaning, therapeutic or protective lotion coating benefits. Because the emollient is substantially immobilized on the surface of the topsheet, less lotion composition is needed to impart the desired skin care benefits. In addition, special barrier or wrapping materials are unnecessary in packaging the lotioned diaper products of the present invention.
As will be discussed hereinafter, the lotion compositions of the present invention preferably have a melting profile such that they are relatively immobile and localized on the diaper topsheet at room temperature, are transferable to the wearer at body temperature, and yet are not completely liquid under exareme storage conditions.
Importantly, the lotion compositions of the present invention are easily transferable to the skin by way of normal contact, wearer motion, and/or body heat.
Without being bound by theory, it is believed that the lotion composition changes the surface energy of the skin, and/or fornis a "barrier" reducing the affinity of the skin for BM. The BM, therefore, has a reduced tendency to stick to the skin, and is easier to remove.
In accordance with one embodiment of the present invention, there is provided a disposable absorbent article comprising:
A) a liquid impervious backsheet;
B) a liquid pervious topsheet; and C) an absorbent core positioned between the topsheet and the backsheet, wherein at least a portion of the topsheet has applied thereto an effective amount of a lotion composition which is partially transferable to the wearer's skin, the lotion composition comprising:
(i) from about 10 to about 95% of a substantially water free emollient having a plastic or fluid consistency at 20°C, wherein Sa the emollient is selected from the group consisting of petroleum-based emollients, fatty acid ester emollients, alkyl ethoxylate emollients, fatty acid ester ethoxylates emollients, fatty alcohol emollients, polysiloxane emollients, and mixtures thereof; and (ii) from about 5 to about 90% of an immobilizing agent capable of immobilizing the emollient on the topsheet, the immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°(:, wherein the immobilizing agent is selected from the group consisting of polyhydroxy fatty acid esters, polyhydroxy fatty acid amides, Cia-C:ZZ fatty alcohols, C,z-CZZ fatty acids, C12-CZZ fatty alcohol ethoxylates, waxes, and mixtures thereof.
In accordance with a further embodiment of the present invention, there is provided a disposable absorbent article comprising:
A) a liquid impervious backsheet;
B) a liquid pervious topsheet; and C) an absorbent core positioned between the topsheet and the backsheet, wherein at least a portion of the topsheet comprises an effective amount of a lotion composition comprising a substantially water free emollient having a plastic or fluid consistency at 20°C and an immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°C, and wherein the lotion composition is applied in a non-uniform pattern to the topsheet.
In accordance with a further embodiment, there is provided a method for making an absorbent article having a lotion composition disposed on at least a portion of a topsheet, comprising the steps of the steps of (1) providing a topsheet; and (2) applying a lotion composition to the topsheet, the lotion composition comprising:
Sb (i) from about 10 to about 95% of a substantially water free emollient having a plastic or fluid consistency at 20°C, wherein the emollient is selected from the group consisting of petroleum-based emollient, fatty acid ester emollient, alkyl ethoxylate emollient, fatty acid ester ethoxylate emollient, fatty alcohol emollient, polysiloxane emollient, and mixtures thereof;
(ii) from about 5 to about 90% of an agent capable of immobilizing the emollient on the topsheet, the immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°C, wherein the immobilizing agent is selected from the group consisting of wax, polyhydroxy fatty acid ester, polyhydroxy fatty acid amide, C14-C22 fatty alcohol, C,2-Cz2 fatty acid, C,z-C22 fatty alcohol ethoxylate having an average degree of ethoxylation of about 2 to about 30, and mixtures thereof.
Figure 1 is a schematic representation illustrating a preferred process for applying the lotion composition of the present invention to diaper topsheets.
Figure 2 is a schematic representation illustrating an alternative process for applying the lotion composition of the present invention to diaper topsheets.
Figure 3 is an absorbent article in the form of a diaper according to the present invention.
DETAILED DESCRIPTION OF THE INVENTION
As used herein, the term "comprising" means that the various components, ingredients, or steps, can be conjointly employed in practicing the present invention. Accordingly, the term "comprising" encompasses the more restrictive terms "consisting essentially oP' and "consisting of."
All percentages, ratios and proportions used herein are by weight unless otherwise specified.
A. Absorbent Article As used herein, the term "absorbent article" refers to devices which absorb and contain body exudates, and more specifically, refers to devices which are placed against the skin of a wearer to absorb and contain the various exudates discharged from the body. The term "disposable" is used herein to describe absorbent articles which are not intended to be laundered or otherwise restored or reused as an absorbent article after a single use. Examples of disposable absorbent articles include feminine hygiene garments such as sanitary napkins and panti-liners, diapers, incontinence briefs, diaper holders, training pants, and the like.
Disposable absorbent articles typically comprise a liquid pervious topsheet, a liquid impervious backsheet joined to the topsheet and an absorbent core positioned between the topsheet and the backsheet.
Disposable absorbent articles and components thereof, including the topsheet, backsheet, absorbent core, and any individual layers of these components, have a body surface and a garment surface. As used herein, "body surface" means that surface of the article or component which is intended to be worn toward or adjacent to the body of the wearer, while the "garment surface" is on the opposite side and is intended to be worn toward or placed adjacent to the wearer's body or undergarments when the disposable absorbent article is worn.
' The following description generally discusses the absorbent core, topsheet, and backsheet materials that are useful in disposable absorbent ' 5 articles. It is to be understood that this general description applies to these components of the specific absorbent articles shown in Figure 3 and further described below, in addition to those of other disposable absorbent articles which are generally described herein.
In general, the absorbent core is capable of absorbing or retaining liquids (e.g., menses, urine, and/or other body exudates). The absorbent core is preferably compressible, conformable, and non-irritating to the wearer's skin. The absorbent core may be manufactured in a wide variety of sizes and shapes (e.g., rectangular, oval, hourglass, 'T' shaped, dog bone, asymmetric, etc.). In addition to the absorbent composites of the present invention, the absorbent core may include any of a wide variety of liquid-absorbent materials commonly used in absorbent articles, such as comminuted wood pulp, which is generally referred to as airfelt. Examples of other suitable absorbent materials for use in the absorbent core include creped cellulose wadding; meltblown polymers including coform; chemically stiffened, modified or cross-linked cellulosic fibers; synthetic fibers such as crimped polyester fibers; peat moss; tissue including tissue wraps and tissue laminates; absorbent foams; absorbent sponges; superabsorbent polymers; absorbent gelling materials; or any equivalent material or combinations of materials, or mixtures of these.
The configuration and construction of the absorbent core may also be varied (e.~., the absorbent core may have varying caliper zones and/or have a profile so as to be thicker in the center, hydrophilic gradients;
gradients of the absorbent composite of the present invention, superabsorbent gradients; or lower average density and lower average basis weight zones, e.g., acquisition zones; or may comprise one or more layers or structures). The total absorbent capacity of the absorbent core should, however, be compatible with the design loading and the intended use of the absorbent article. Further, the size and absorbent capacity of the absorbent core may be varied to accommodate different uses such as diapers, incontinence pads, pantiliners, regular sanitary napkins, and overnight sanitary napkins, and to accommodate wearers ranging from infants to adults.
The absorbent core can include other absorbent components that are often used in absorbent articles, for example, a dusting layer, a wicking or acquisition layer, or a secondary topsheet for increasing the wearer's comfort.
The topsheet is preferably compliant, soft feeling, and non-irritating to the wearer's skin. Further, the topsheet is liquid pervious, permitting liquids (e.g., menses and/or urine) to readily penetrate through its thickness. A suitable topsheet may be manufactured from a wide range of materials such as woven and nonwoven materials (e.g., a nonwoven web of fibers); polymeric materials such as apertured formed thermoplastic films, apertured plastic films, and hydrofonned thermoplastic films; porous foams;
reticulated foams; reticulated thermoplastic films; and thermoplastic scrims.
Suitable woven and nonwoven materials can be comprised of natural fibers (e.g., wood or cotton fibers), synthetic fibers (e.g., polymeric fibers such as polyester, polypropylene, or polyethylene fibers) or from a combination of natural and synthetic fibers. When the topsheet comprises a nonwoven web, the web may be manufactured by a wide number of known techniques.
For example, the web may be spunbonded, carded, wet-laid, melt-blown, hydroentangled, combinations of the above, or the like.
The backsheet is impervious to liquids (e.g., menses and/or urine) and is preferably manufactured from a thin plastic film, although other flexible liquid impervious materials may also be used. As used herein, the term "flexible" refers to materials which are compliant and will readily conform to the general shape and contours of the human body. The backsheet prevents the exudates absorbed and contained in the absorbent core from wetting articles which contact the absorbent article such as bedsheets, pants, pajamas and undergarments. The backsheet may thus comprise a woven or nonwoven material, polymeric films such as thermoplastic films of polyethylene or polypropylene, or composite materials such as a film~oated nonwoven material. A suitable backsheet is a polyethylene film having a thickness of from about 0.012 mm (0.5 mil) to about 0.051 mm (2.0 mils). Exemplary polyethylene films are manufactured by Clopay Corporation of Cincinnati, Ohio, under the designation P18-1401 and by Tredegar Film Products of Terre Haute, Indiana, under the designation XP-39385. The backsheet is preferably embossed and/or matte finished to provide a more clothlike appearance. Further, the backsheet may permit vapors to escape from the absorbent core (i.e., the backsheet is breathable) while still preventing exudates from passing through the backsheet. The size of the backsheet is dictated by the size of the absorbent core and the exact absorbent article design selected.
The backsheet and the topsheet are positioned adjacent the garment surface and the body surface, respectively, of the absorbent core. The absorbent core is preferably joined with the topsheet, the backsheet, or both in any manner as is known by attachment means (not shown in Figure 3) such as those well known in the art.
However, embodiments of the present invention are envisioned wherein portions of the entire absorbent core are unattached to either the topsheet, the backsheet or both.
For example, the backsheet an/or the topsheet may be secured to the absorbent core or to each other by a uniform continuous layer of adhesive, a patterned layer of adhesive, or an array of separate lines, spirals, or spots of adhesive.
Adhesives which have been found to be satisfactory are manufactured by H. B. Fuller Company of St.
Paul; Minnesota under the designation HL-1258 or H-2031. The attachment means will preferably comprise an open pattern network of filaments of adhesive as is disclosed in U.S. Patent 4,573,986, issued to Minetola, et al. on March 4, 1986. An exemplary attachment means of an open pattern network of filaments comprise:
several lines of adhesive filaments swirled into a spiral pattern such as illustrated by the apparatus and method shown in U.S. Patent 3,911,173 issued to Sprague, Jr.
on October 7, 1975; U.S. Patent 4,785,996 issued to Zwieker, et al. on November 22, 1978; and U.S. Patent 4,842,666 issued to Werenicz on June 27, 1989.
Alternatively, the attachment means may comprise heat bonds, pressure bond, ultrasonic bonds, dynamic mechanical bond, or any other suitable attachment means or combinations of them attachment means as are known in the art.
A preferred disposable absorbent article in which the lotioned topsheets of the present invention may be used are diapers. As used herein, the term "diapers"
refers to an absorbent article generally worn by infants, and incontinent persons that is worn about the lower torso of the wearer. In other words, the term "diaper" includes infant diapers, training pants, adult incontinence devices, etc.
Figure 3 is a plan view of the diaper 50 of the present invention in its flat-out, uncontracted state (i.e., with elastic induced contraction pulled out) 5 with portions of the structure being cut-away to more clearly show the construction of the diaper 50 and with the portion of the diaper 50 which faces away from the wearer, the outer surface, oriented towards the viewer.
As shown in Figure 3, the diaper 50 preferably comprises a liquid pervious topsheet 520; a liquid impervious backsheet 530 joined with the topsheet 10 520; an absorbent core 540 positioned between the topsheet 520 and the backsheet 530, the absorbent core 540 having a garment facing surface 542, a body facing surface 544, side edges 546, waist edges 548, and ears 549. The diaper 50 preferably further comprises elasticized leg cuffs 550;
an elastic waist feature multiply designated as 560; and a fastening system generally multiply designated as 570.
The diaper 50 is shown in Figure 3 to have an outer surface 52, an inner surface 54 opposed to the outer surface 52, a first waist region 56, a second waist region 58, and a periphery 51 which is defined by the outer edges of the diaper 50 in which the longitudinal edges are designated 55 and the end edges are designated 57. (While the skilled artisan will recognize that a diaper is usually described in terms of having a pair of waist regions and a crotch region between the waist regions, in this application, for simplicity of terminology, the diaper 50 is described as having only waist regions including a portion of the diaper which would typically be designated as part of the aotch region). The inner surface 54 of the diaper 50 comprises that portion of the diaper 50 which is positioned adjacent to the wearer's body during use (i.e., the inner surface 54 generally is formed by at least a portion of the topsheet 520 and other components that may be joined to the topsheet 520). The outer surface 52 comprises that portion of the diaper 50 which is positioned away from the wearers body (i.e., the outer surface 52 generally is formed by at least a portion of the backsheet 530 and other components that may be joined to the backsheet 530). (As used herein, the portion of the diaper 50 or component thereof which faces the wearer is also referred to as the body facing surface. Similarly, the portion facing away from the wearer is also referred to herein as the garment facing surface.) The first waist region 56 and the second waist region 58 extend, respectively, from the end edges 57 of the periphery 51 to the lateral centerline 53 of the diaper 50. Figure 3 also shows the longitudinal centerline 59.
Figure 3 shows a preferred embodiment of the diaper 50 in which the topsheet 520 and the backsheet 530 have length and width dimensions generally larger than those of the absorbent core 540. The elasticized leg cuffs 550 and the backsheet 530 extend beyond the edges of the absorbent core 540 to thereby form the periphery 51 of the diaper 50.
Diapers of the present invention can have a number of well known configurations, with the absorbent cores thereof being adapted to the present invention. Exemplary configurations are described generally in U.S. Patent 3,860,003 issued to Buell on January 14,1975; U.S. Patent 5,151,092 issued to Buell et al. on September 29, 1992; U.S. Patent 5,221,274 issued to Buell et al. on June 22, 1993.
Another diaper configuration to which the present invention can be readily adapted are described in U.S. Patent No. 5,554,145 issued on September 10, 1996. The absorbent cores of diapers described in these patents can be adapted in light of the teachings herein to include the absorbent composite of the present invention as an absorbent gelling material described therein.
A topsheet 520 which is particularly suitable for use in the diaper 50, is carded and thermally bonded by means well known to those skilled in the fabrics art.
A
satisfactory topsheet for the present invention comprises staple length polypropylene fibers having a denier of about 2.2. As used herein, the term "staple length fibers"
refers to those fibers having a length of at least about 15.9 mm (0.625 inches).
Preferably, the topsheat has a basis weight from about 14 to about 25 grams per square meter. A suitable topsheet is manufactured by Veratec, Inc., a Division of International Paper Company, of Walpole, Mass. under the designation P-8.
The topsheet 520 of diaper 50 is preferably made of a hydrophilic material to promote rapid transfer of liquids (e.g., urine) through the tophseet. If the topsheet is made of a hydrophobic material, at least the upper surface of the topsheet is treated to be hydrophilic so that liquids will transfer through the topsheet more rapidly. This diminishes the likelihood that body exudates will flow off the topsheet rather than being drawn through the topsheet and being absorbed by the absorbent core. The topsheet can be rendered hydrophilic by treating it with a surfactant.
Suitable methods for treating the topsheet with a surfactant include spraying the topsheet material with the surfactant and immersing the material into the surfactant. A more detailed discussion of such a treatment and hydrophilicity is contained in U.S. Patents 4,988,344 entitled "Absorbent Articles with Multiple Layer Absorbent Layers"
issued to Reising, et al. on January 29, 1991 and U.S. Patent 4,988,345 entitled "Absorbent Articles with Rapid Acquiring Absorbent Cores" issued to Reising on January 29, 1991.
In a preferred embodiment of a diaper as described herein, the backsheet 530 has a modified hourglass shape extending beyond the absorbent core a minimum distance of about 1.3 cm to about 6.4 cm (about 0.5 to about 2.5 inch) around the entire diaper periphery.
The absorbent core 540 may take on any size or shape that is compatible with the diaper 50. One preferred embodiment of the diaper 50 has an asymmetric, modified T-shaped absorbent core 540 having ears in the first waist region but a generally rectangular shape in the second waist region. Exemplary absorbent structures for use as the absorbent core of the present invention that have achieved wide acceptance and commercial success are described in U.S. Patent 4,610,678 entitled "High-Density Absorbent Structures" issued to Weisman et al. on September 9, 1986; U. S. Patent 4,673,402 entitled "Absorbent Articles With Dual-Layered Cores" issued to Weisman et al. on June 16, 1987; U.S. Patent 4,888,231 entitled "Absorbent Core Having A Dusting Layer" issued to Angstadt on December 19, 1989;
and U.S. Patent 4,834,735, entitled "High Density Absorbent Members Having Lower Density and Lower Basis Weight Acquisition Zones" issued to Alemany et al. on May 30, 1989. The absorbent core may further comprise the dual core system containing an acquisition/distribution core of chemically stiffened fibers positioned over an absorbent storage core as detailed in U.S. Patent 5,234,423, entitled "Absorbent Article With Elastic Waist Feature and Enhanced Absorbency" issued to Alemany et al., on August 10, 1993; and in U.S. Patent 5,147,345, entitled "High Efficiency Absorbent Articles For Incontinence Management"
issued to Young, Lavon and Taylor on September 15,1992.
In a preferred embodiment, the diaper 50 further comprises elasticized leg cuffs 550 for providing improved containment of liquids and other body exudates; an elastic waist feature 560 that provides improved fit and containment; and a fastening system 570 which forms a side closure which maintains the first waist region 56 and the second waist region 58 in an overlapping configuration such that lateral tensions are maintained around the circumference of the diaper to maintain the diaper on the wearer. The diaper 50 may also comprise elasticized side panels (not shown) in the waist regions 56 and 58 to provide an elastically extensible feature that provides a more comfortable and contouring fit and more effective application of the diaper S0.
The elasticized leg cuffs 550 can be constructed in a number of different configurations, including those described in U.S. Patent No. 3,860,003; U.S.
Patent No.4,909,803, issued to Aziz et al. on March 20, 1990; U.S. Patent No.4,695,278, issued to Lawson on September 22, 1987; and U.S. Patent No.4,795,454, issued to Dragoo on January 3, 1989.
The elasticized waist feature preferably comprises an elasticized waistband (not shown) that may be constructed in a number of different configurations including those described in U.S. Patent No.4,515,595 issued to Kievit et al. on May 7, 1985;
U.S. Patent No. 5,026,364 issued to Robertson on June 25, 1991; and the above referenced U.S. Patent No. 5,151,092 issued to Buell et at. on Sep.29, 1992.
The elasticized side panels may be constructed in a number of configurations.
Examples of diapers with elasticized side panels positioned in the ears (ear flaps) of the diaper are disclosed in U.S. Patent No. 4,857,067, issued to Wood, et al.
on Aug.lS, 1989; U.S. Patent No. 4,381,781, issued to Sciaraffa, et al. on May 3, 1983;
U.S. Patent No. 4,938,753, issued to Van Gompell, et al. on July 3, 1990; and U.S.
Patent No. 5,1 S 1,092, issued to Buell et al. on September 29, 1992.
Exemplary fastening Systems 570 are disclosed in U. S Patent No. 4,846,815, issued to Scripps on July 11, 1989; U.S. Patent No. 4,894,060, issued to Nestegard on Jan.l6, 1990;
U.S. Patent No.4,946,527, issued to Battrell on Aug. 7, 1990; U.S. Patent No.3,848,594, issued to Buell on Nov. 19, 1974; U.S. Patent No. B 1 4,662,875, issued to Hirotsu et al. on May 5, 1987; and U.S. Patent No.5,151,092, issued to Buell et al.
on Sep.29, 1992.
The diaper 50 is preferably applied to a wearer by positioning one of the waist regions of the diaper, preferably the second waist region 58, under the wearer's back and drawing the remainder of the diaper between the wearer's legs so that the other waist region, preferably the first waist region 56, is positioned across the front of the wearer. The fastening system is then applied to effect a side closure.
The lotioned topsheets of the present invention are also useful in training pants. The term "training pants", as used herein, refers to disposable garments having fixed sides and leg openings. Training pants are placed in position on the wearer by inserting the wearers legs into the leg openings and sliding the training pant into position about the wearer's lower torso. Suitable training pants are disclosed in U.S.
Patent No. 5,246,433, issued to Hesse, et al. on September 21, 1993.
Another disposable absorbent article for which the lotioned topsheets of the present invention are useful are incontinence articles. The term "incontinence article"
refers to pads, undergarments (pads held in place by a suspension system of same type, such as a belt, or the like), inserts for absorbent articles, capacity boosters for absorbent articles, briefs, bed pads and the like regardless of whether they are worn by adults or other incontinent persons. Suitable incontinence articles are disclosed in U.S.
Patent No. 4,253,461 issued to Strickland, et al. on March 3, 1981; U.S.
Patent Nos.
4,597,760 and 4,597,761 issued to Buell; the above-mentioned U.S. Patent No.4,704,115; U.S. Patent No. 4,909,802 issued to Ahr, et al.; U.S. Patent No.4,964,860 issued to Gipson, at al. on October 23.1990; and in PCT
Publication No. WO 92/11830 published on July 23, 1992.
B. Lotion Composition.
The lotion compositions of the present invention are solid, or more often semisolid, at 20°C, i.e. at ambient temperatures. By "semisolid"
is meant that the lotion composition has a rheology typical of pseudopfastic or 5 plastic fluids. When no shear is applied, the lotion compositions can have the appearance of a semi-solid but can be made to flow as the shear rate is increased. This is due to the fact that, while the lotion composition contains primarily solid components, it also includes some minor liquid components.
The lotion compositions of the present invention are at least semi-1o solid at room temperature to minimize lotion migration. In addition, the lotion compositions preferably have a final melting point (100°r6 liquid) above potential "stressful" storage conditions that can be greater than 45°C
(e.g., warehouse in Arizona, car trunk in Florida, etc.).
Specifically, the lotion compositions of the present invention should have 15 the following melt profile:
Characteristic Preferred Ranae Most Preferred % liquid at 2-50 3-25 room temp. (20 °C) % liquid at 25-95 30-90 body temp. (37 °C) final melting point (°C) z38 >_45 By being solid or semisolid at ambient temperatures, these lotion compositions do not have a tendency to flow and migrate into the interior of the diaper topsheet to which they are applied. This means less lotion composition is required for imparting desirable therapeutic or protective coating lotion benefits.
When applied to outer surface of diaper topsheets, the lotion compositions of the present invention are transferable to the wearer's skin by normal contact, wearer motion, andlor body heat. Importantly, the lotions disclosed in the present invention reduce the adherence of BM to the skin of the wearer, thereby improving the ease of BM clean up.
The diaper topsheets of the present invention contain an effective amount of the lotion composition. As used herein, the term "effective amount of a lotion coating" refers to an amount of a particular lotion composition which, when applied to a diaper topsheet, will be effective in reducing the adherence of BM to the skin of the wearer. Of course, the effective amount of a lotion coating will depend, to a large extent, on the particular lotion composition used.
The lotion compositions of the present invention comprise: (1 ) an emollient(s); (2) an immobilizing agents) for the emollient; (3) optionally a hydrophilic surfactant(s); and (4) other optional components.
The viscosity of the formulated lotion compositions, including emollient, immobolizing agent, and optional components should be as high as possible to keep the lotion from flowing into the interior of the diaper.
Unfortunately, high viscosities can also lead to lotion compositions that are difficult to apply without processing problems. Therefore, a balance must be achieved so the viscosities are high enough to keep the lotion compositions localized on the surface of the diaper topsheet, but not so high as to cause processing problems. Suitable viscosities for the lotion compositions will typically range from about 5 to about 200 centipoises, preferably from about 15 to about 100 centipoises, measured at 60°C.
1. mollient The key active ingredient in these lotion compositions is one or more emollients. As used herein, an emollient is a material that softens, soothes, supples, coats, lubricates, moisturizes, or cleanses the skin. An emollient typically accomplishes several of these objectives such as soothing, moisturizing, and lubricating the skin. For the purposes of the present invention, these emollients have either a plastic or fluid consistency at 20°C, i.e., at ambient temperatures. This particular emollient consistency allows the lotion composition to impart a soft, lubricious, lotion-like feel.
The emollients useful in the present invention are also substantially free of water. By "substantially free of water' is meant that water is not intentionally added to the emollient. Addition of water to the emollient is not necessary in preparing or using the lotion compositions of the present invention and could require an additional drying step. However, minor or trace quantities of water in the emollient that are picked up as a result of, for example, ambient humidity can be tolerated without adverse effect.
Typically, the emollients used in the present invention contain about 5°r6 or less water, preferably about 1 °~ or less water, most preferably about 0.5°~
or less water.
Emollients useful in the present invention can be petroleum-based, fatty acid ester type, alkyl ethoxylate type, fatty acid ester ethoxylates, fatty alcohol type, polysiloxane type, or mixtures of these emollients. Suitable petroleum-based emollients include those hydrocarbons, or mixtures of hydrocarbons, having chain lengths of from 16 to 32 carbon atoms.
Petroleum based hydrocarbons having these chain lengths include mineral oil (also known as "liquid petrolatum") and petrolatum (also known as "mineral wax," "petroleum jelly" and "mineral jelly"). Mineral oil usually refers to less viscous mixtures of hydrocarbons having from 16 to 20 carbon atoms. Petrolatum usually refers to more viscous mixtures of hydrocarbons having from 16 to 32 carbon atoms. Petrolatum and mineral oil are particularly preferred emollients for lotion compositions of the present invention.
Suitable fatty acid ester type emollients include those derived from C12-C2g fatty acids, preferably C1g-C~ saturated fatty acids, and short chain (C1-Cg, preferably C1-C3) monohydric alcohols. Representative examples of such esters include methyl palmitate, methyl stearate, isopropyl laurate, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate and mixtures thereof. Suitable fatty acid ester emollients can also be derived from esters of longer chain fatty alcohols (C12-C2g, preferably C12-C16) and shorter chain fatty acids e.g., lactic acid, such as lauryl lactate and c;etyl lactate.
Suitable alkyl ethoxylate type emollients include C12-C~ fatty alcotwl ethoxylates having an average degree of ethoxylation of from about 2 to about 30. Preferably, the fatty alcohol ethoxylate emoliient is selected from the group consisting of lauryl, cetyl, and stearyl ethoxylates, and mixtures thereof, having an average degree of ethoxylation ranging from about 2 to about 23. Representative examples of such alkyl ethoxylates include laureth-3 (a lauryl ethoxylate having an average degree of ethoxylation of 3), laureth-23 (a lauryl ethoxylate having an average degree of ethoxylation of 23), ceteth-10 (a cetyl alcohol ethoxylate having an average degree of ethoxylation of 10) and steareth-10 (a stearyl alcohol ethoxylate having an average degree of ethoxylation of 10~. These alkyl ethoxylate emollients are typically used in combination with the petroleum based emollients, such as petrolatum, at a weight ratio of alkyl ethoxylate emollient to pstroleum~based emollient of from about 1:1 to about 1:5, preferably from about 1:2 to about 1:4.
Suitable fatty alcohol type etnollienta include C12-C22 tatty alcohols, preferably C1g-C1g tatty alcohols. Representative examples include cetyl alcohol and stearyl alcohol, and mixtures thereof. These fatty alcohol emollients are typically used in ' combination with the petroleum-based emollients, such as petrolatum, at a weight ratio of fatty alcohol emollient to petroleum-based emollient of from about 1:1 to about 1:5, preferably from about 1:1 to about 1:2.
Other suitable types of emollients for use in the present invention include polysiioxane compounds. In general suitable polysiloxane materials for u:. in the present invention include those having monomeric siloxane pits of the following structure:
R~
Si-O _ wherein, R1 and RZ, for each independent sitoxsne monomeric unit can each independently be hydrogen or any alkyl, aryl, slksnyl, alkaryl, arakyi, ~~ halogenated hydrocarbon, or other radical. Any of such radicals do be substituted or una~tituted. R1 and R2 radicals of any partiarlar ~c ~ ~y d;~~ fiom the corresponding functionalities of the next monomeric unit. A~itionalty, the polysiloxa~ can be either a ~;g~ chain, a brsrxhed chain or have a cyclic stru~o. The radicals R1 ~d RZ can sddidonally independently be other siliceous functionalities such as, but not limited to siloxsnes, polysiloxanss, silanes, and polysilanes. The radicals R1 and R2 may contain any of a variety of orpsnic tundionalities including, for ex~ur~ple, alcohol, carboxylic acid, phenyl, end amine fundionalities.
Exemplary alkyl radicals are methyl, ethyl, propyl, butyl, pentyl, hexyl, octyl, decyl, octadecyl, and the like. Exemplary alkenyl radicals are vinyl, allyl, and the like.
Exemplary aryl radicals are phenyl, diphenyl, naphthyl, and the like.
Exemplary alkaryl radicals are toyl, xylyl, ethylphenyl, and the like. Exemplary aralkyl radicals S are benzyl, alpha-phenylethyl, betaphenylethyl, aipha-phenylbutyl, and the like.
Exemplary cycloalkyl radicals are cyclobutyl, cyclopentyl, cyclohexyl, and the like.
Exemplary halogenated hydrocarbon radicals are chioromethyl, bromoethyl, tetrafluorethyl, fluorethyl, trifluorethyl, trifluorotloyl, hexafluoroxylyl, and the like.
Viscosity of polysiloxanes useful may vary as widely as the viscosity of polysiloxanes in general vary, so long as the polysiloxane is flowable or can be made to be flowable for application to the diaper topsheet. This includes, but is not limited to, viscosity as low as 5 centistokes (at 37 °C as measured by a glass viscometer) to about 20,000,000 centistokes. Preferably the polysiloxanes have a viscosity at 37 °C
ranging from about S to about 51000 centistokes, more preferably from about S
to about 2,000 centistokes, most preferably from about 100 to about 1000 centistokes.
High viscosity polysiloxanes which themselves are resistant to flowing can be effectively deposited upon the diaper topsheets by such methods as, for example, emulsifying the polysiloxane in surfactant or providing the polysiloxane in solution with the aid of a solvent, such as hexane, listed for exemplary purposes only.
Particular methods for applying polysiloxane emollients to diaper topsheets are discussed in more detail hereinafter.
Preferred polysiloxanes compounds for use in the present invention are disclosed in U.S. Patent 5,059,282 (Ampulski et al), issued October 22, 1991.
Particularly preferred polysiloxane compounds for use as emollients in the lotion compositions of the present invention include phenyl-functional polymethylsiloxane compounds (e.g., Dow Coming 556 Cosmetic-Grade Fluid:
polyphenylmethylsiloxane) and cetyl or stearyl functionalized dimethicones such as Dow 2502 and Dow 2503 polysiloxane fluids, respectively. In addition to such substitution with phenyl-functional or alkyl groups, effective substitution may be made with amino, carboxyl, hydroxyl, ether, polyether, aldehyde, ketone, amide, ester, and thiol groups. Of these effective substituent groups, the family of groups comprising phenyl, amino, alkyl, carboxyl, and hydroxyl groups are more prefer-ed than the others;
and phenyl-functional groups are most preferred.
Besides petroleum-based emollients, fatty acid ester emollients, fatty acid ester ethoxylates, alkyl ethoxylate emollients fatty alcohol emollients, 5 and polysiloxanes, the emollients useful in the present invention can include minor amounts (e.g., up to about 10% of the total emollient) of other, conventional emollients. These other, conventional emollients include propylene glycol, glycerine, triethylene glycol, spermaceti or other waxes, fatty acids, and fatty alcohol ethers having from 12 to 28 carbon 10 atoms in their fatty chain, such as stearic acid, propoxylated fatty alcohols;
glycerides, acetoglycerides, and ethoxylated gfycerides of C12-C2g fatty acids; other fatty esters of polyhydroxy alcohols; lanolin and its derivatives.
These other emollients should be included in a manner such that the sobd or semisolid characteristics of the lotion composition are maintained.
15 The amount of emollient that can be included in the lotion composition will depend on a variety of factors; including the particular emollient involved, the lotion-like benefits desired, the other components in the lotion composition and like factors. The lotion composition can comprise from about 10 to about 95°~ of the emollient. Preferably, the 20 lotion composition comprises from about 20 to about 80°r6, most preferably from about 40 to about 75°~, of the emollient.
2. immobilizing Agent An especially key component of the lotion compositions of the present invention is an agent capable of immobilizing the emollient on the diaper topsheet to which the lotion composition is applied. Because the emollient in the composition has a plastic or fluid consistency at 20°C, it tends to flow or migrate, even when subjected to modest shear. When applied to a diaper topsheet, especially in a melted or molten state, the emollient will not remain primarily on the surface of the topsheet. Instead, the emollient will tend to migrate and flow into the interior of the diaper.
This migration of the emollient into the interior of the diaper can cause undesired effects on the absorbency of the diaper core due to the hydrophobic characteristics of many of the emollients used in the lotion compositions of the present invention. It also means that much more emollient has to be applied to the diaper topsheet to get the desired therapeutic or protective lotion benefits. Increasing the level of emollient not only increases the cost, but also exacerbates the undesirable effect on the absorbency of the diaper core.
The immobilizing agent counteracts this tendency of the emollient to migrate or flow by keeping the emollient primarily localized on the surface of the diaper topsheet to which the lotion composition is applied. This is believed to be due, in part, to the fact that the immobilizing agent raises the melting point of the lotion composition above that of the emollient. Since the immobilizing agent is also miscible with the emollient (or solubilized in the emollient with the aid of an appropriate emulsifier), it entraps the emollient on the surface of the diaper topsheet as well.
It is also advantageous to "lock" the immobilizing agent on the surface of the diaper topsheet. This can be accomplished by using immobilizing agents which quickly crystallize (i.e., solidify) at the surface of the topsheet. In addition, outside cooling of the treated diaper topsheet via blowers, fans, etc. can speed up crystallization of the immobilizing agent.
In addition to being miscible with (or solubilized in) the emollient, the immobilizing agent needs to have a melting point of at least about 35°C.
This is so the immobilizing agent itself will not have a tendency to migrate or flow. Preferred immobilizing agents will have melting points of at least about 40°C. Typically, the immobilizing agent will have a melting point in the range of ftom about 50° to about 150°C.
Suitable immobilizing agents for the present invention can comprise a member selected from the group consisting of C14-C~ fatty alcohols, C12-C~ fatty acids, and C12-C~ fatty alcohol ethoxylates having an average degree of ethoxylation ranging from 2 to about 30, and mixtures thereof. Preferred immobilizing agents include C1g-C18 fatty alcohols, most preferably selected from the group consisting of cetyl alcohol, stearyl alcohol, and mixtures thereof. Mixtures of cetyl alcohol and stearyl alcohol are particularly preferred. Other preferred immobilizing agents include C1g-C1g fatty acids, most preferably selected from the group consisting of palmitic acid, stearic acid, and mixtures thereof. Mixtures of palmitic acid and stearic acid are particularly preferred. Still other preferred immobilizing agents include C1g-C1g fatty alcohol ethoxylates having an average degree of ethoxylation ranging from about 5 to about 20. Preferably, the fatty alcohols, fatty acids and fatty alcohols are linear.
Importantly, these preferred immobilizing agents such as the Cog -C~g fatty alcohols increase the rate of crystallization of the lotion causing the lotion to crystallize rapidly onto the surface of the substrate. Lower lotion levels can therefore be utilized or a superior lotion feel can be delivered. Traditionally, greater amounts of lotion were needed to generate softness because of the flow of these liquids into the diaper core.
Other types of immobilizing agents can be used either alone or in combination with the fatty alcohols, fatty acids, and fatty alcohol ethoxylates described above. Examples of these other types of immobilizing agents includes polyhydroxy fatty acid esters, polyhydroxy fatty acid amides, and mixtures thereof. Preferred esters and amides will have three or more free hydroxy groups on the polyhydroxy moiety and are typically nonionic in character. Because of the possible skin sensitivity of those using diaper topsheets to which the lotion composition is applied, these esters and amides should also be relatively mild and non-irritating to the skin.
Suitable polyhydroxy fatty acid esters for use in the present invention will have the formula:
II
R-C-O Y
n wherein R is a C5-C3~ hydrocarbyl group, preferably straight chain C7-Cog alkyl or alkenyl, more preferably straight chain Cg-C~7 alkyl or alkenyl, most preferably straight chain C~ ~-C~7 alkyl or alkenyl, or mixture thereof;
Y is a polyhydroxyhydrocarbyl moiety having a hydrocarbyl chain with at least 2 flee hydroxyls directly connected to the chain; and n is at least 1.
Suitable Y groups can be derived from polyols such as glycerol, pentaerythritol; sugars such as raffinose, maltodextrose, galactose, sucrose, glucose, xylose, fructose, maltose, lactose, mannose and WO 96I16a8Z PCZ'/US95113809 erythrose; sugar ~alcohols such as erythritoi, xylitol, malitol, mannitol and sorbitol; and anhydrides of sugar alcohols such as sorbitan.
Ores class of suitable polyhydroxy fatty acid esters for use in the present invention comprises certain sorbitan esters, preferably the sorbitan esters of Cog-C~ saturated fatty acids. Because of the manner in which they are typically manufactured, these sorbitan esters usually comprise mixtures of mono-, dl-, tri-, etc. esters. Representative examples of suitable *
sorbitsn esters include sorbitan palmitates (e.g., SPAN 40), sorbitan atsarates (e.g., SPAN 60y, and sorbitan behenates, that comprise one or more of the mono-, dl- and tri-ester versions of these sorbitan esters, e.g., sorbitan mono-, dl- and tri-palmitate, sorbitan mono-, dl- and tri-stearate, sorbitan mono-, dl and tti-behenate, as well as mixed tallow fatty acid sorbitan mono-, dl- and tri-esters. Mixtures of different sorbitan esters can also be used, such as sorbitan patmitates with sorbitan stearates.
t 5 Partiwlarly preferrod sorbitan esters are the sorbitan stearates, typically as a mixture of mono-, dl- and tri-esters (plus some tstraester) such as SPAN
60, and sorbitan stearates sold under the trade name GLYCOMUL-S by Lonza, Inc. Although these sorbitan esters typically contain mixtures of mono-, dl- and tri-esters, plus some tetraester, the mono- and di-esters are usually the predominant species in these mixtures.
Another Gas: of suitable polyhyc~oxy fatty aad esters for use in the preset invention comprises certain glyceryl monoesters, preferably _ gtyCeryl monoe:ters of Ctg-C~ satursted fatty cads such as glyceryl morrostarate, Qiycyryl monopalmitats, and glyceryt monobehenate. Again, like the sorbitan esters, gtycsryl monosster mixtures will typically contain some dl- end triester. Hovwwsr, such mixtures should contain pr~0ominantty the plyceryl monoester species' to be useful in the present inversion.
Another das: of suitable polyhydroxy fatty sad esters for use in the present invention comprise cartsin sucrose fatty acid esters, preferably the C~Z.C~ sattxated fstty acid esters of suaose.. Suaoae monoesters and dissters an paniartarly preferred and include suaose mono- and di-stearate and suaose mono- and dl- laurate.
Suitable polyhydroxy fatty acid amides for use in the present invention will haw the formula:
* = Trade-mark R' RZ-~-N-Z
wherein R~ is H, C1-C4 hydrocarbyl, 2fiydroxyethyl, 2-hydroxypropyl, melho~cyethyi, methoxypropyl or a mixture thereof, preferably C 1-C4 alkyl, methoxyethyl or methoxypropyl, more preferably C1 or C2 alkyl or methoxypropyl , most preiersbly C~ .alkyl (i.e., methyl) or methoxypropyl;
and R2 is a C5-C31 hydroc~srbyi gn~up, preferably straight chain CT-C19 alkyl or slkenyi, more preferably straight chain Cg-C ~ ~ alkyl or alkenyl, most preferably straight chain C11-C1~ alkyl or slkenyl, or mixture thereof;
and Z is a polyhydroxyhydrocarbyl moiety having a linen hydrocarbyi chain with a3 fist 3 hydroxyls directly comeded to the chain. See U.S. patent 5,174,927 (Hones), issued December 29,1992 which discloses these polyhydroary fatty acid amides, as well as their preparation.
Ttte Z moiety preferably will be derived Trom a reducing sugar in a radudivb amination reaction; most ~efersbly glyatyl. Suitable reduung sugar include gluco:e, fnrctose, maltose, lactose, galactose, mannose, and xylose. High dextrose cram syrup, high fructose cam syrup, and high maltose com syrup can be utilized, as welt as the individual sugars listed . ~ cprn syrups can yield mad~ees of sugar components for the Z
The Z ntoity Prefe~y X11 be selected 'from t~ 9~P consisting of .CHZ.(CHOH~-CHZOH, -CH(CHZOHy-((CHOH~.1]-CHZOH, -CH20H~
CHZ.(CHOH~(CHOR3xCHOH)-CH20H, where n is an integeC from 3 to 5, ~ R3 is H or a cydk a aliphatic monosaa~aride. Most preferred are the ~ity~ wt~s n is 4, partiarlarly -CH2-(CHOH~-CHZOH.
In the above forr>xrla. R~ ~ ~~ for example, N-methyl, N.~thyl, N-~pyl, N~p~yl~ N.p~yl, N-2-hydroxYethyl, N-methoxyproPYl or N-2-hy~xypropyl,. R2 can be selected to provide, for example, cocamides, 3p stesramides, oleamides, Isursmides, myristsmides, capricamides, palmitamides, talk~rsmides, etc. The Z moiety an be 1 ~eoXyglucityl, 2-deoxyfructityl, 1-deoxymaltityl, 1-deoxylactityl, 1-deoxygalactityl, 1-deoxymannityl, 1-deoxymaltotriotityl, etc.
The most preferred polyhydroxy fatty acid amides have the general formula:
O R~ OH
II I I
wherein R1 is methyl or methoxypropyl; R2 is a C11-C17 straight-chain alkyl or alkenyl group. These include N-lauryl-N-methyl glucamide, N-10 lauryl-N-methoxypropyl glucamide, N-cocoyl-N-methyl glucamide, N~ocoyl-N-methoxypropyl glucamide, N-palmityl-N-methoxypropyl glucamide, N-tallowyl-N-methyl glucamide, or N-tallowyl-N-methoxypropyl glucamide.
As previously noted, some of the immobilizing agents require an emulsifier for solubilization in the emollient. This is particularly the case for 15 certain of the glucamides such as the N-alkyl-N-methoxypropyl glucamides having HLB values of at least about 7. Suitable emulsifiers will typically include those having HLB values below about 7. In this regard, the sorbitan esters previously described, such as the sorbitan stearates, having HLB
values of about 4.9 or less have been found useful in solubilizing these 20 glucamide immobilizing agents in petrolatum. Other suitable emulsifiers inGude steareth-2 (polyethylene glycol ethers of stearyt alcohol that conform to the formula CHg(CH2)1~(OCH2CH2)nOH, where n has an average value of 2), sorbitan tristearate, isosorbide laurate, and glyceryl monostearate. The emulsifier can be included in an amount sufficient to 25 solubilize the immobilizing agent in the emollient such that a substantially homogeneous mixture is obtained. For example, an approximately 1:1 mixture of N-cocoyl-N-methyl glucamide and petrolatum that will normally not melt into a single phase mixture, will melt into a single phase mixture upon the addition of 20°~ of a 1:1 mixture of Steareth-2 and sorbitan tristearate as the emulsifier.
Other types of ingredients that can be used as immobilizing agents, either alone, or in combination with the above-mentioned immobilizing agents, include waxes such as carnauba, beeswax, candelilla, paraffin, ceresin, esparto, ouricuri, rezowax, and other known waxes. Preferably the wax is a paraffin wax. An example of a particularly preferred paraffin wax is Parrafin S.P. 434 from Strahl and Pitsch Inc. PØ Box 1098 West Babylon, NY 11704.
The amount of immobilizing agent that should be included in the lotion composition will depend on a variety of factors, including the particular emollient involved, the particular immobilizing agent involved, whether an emulsifier is required to solubilize the immobilizing agent in the emollient, the other components in the lotion composition and like factors.
The lotion composition can comprise from about 5 to about 90% of the immobilizing agent. Preferably, the lotion composition comprises from about 5 to about 50%, most preferably from about 10 to about 40°~, of the immobilizing agent.
3. Optional Hydrophilic Surfactant As mentioned above, it is highly desirable that the diaper topsheet is made of a hydrophilic material to promote rapid transfer of liquids (e.g., urine) through the topsheet. Similarly, it is important that the lotion composition also be sufficiently wettable to ensure that liquids will transfer through the topsheet more rapidly. This diminishes the likelihood that body exudates will flow off the lotion coating rather than being drawn through the topsheet and being absorbed by the absorbent core. Depending upon the particular immobilizing agent used in the lotion composition of the present invention, an additional hydrophilic surfactant (or a mixture of hydrophilic surtactants) may, or may not, be required to improve wettability. For example, some immobilizing agents, such as N-cocoyi-N-methoxypropyl glucamide have HLB values of at least about 7 and are sufficiently wettable without the addition of hydrophilic surfactant. Other immobilizing agents such as the C1g - C1g fatty alcohols having HLB values below about 7 will require addition of hydrophilic surfactant to improve wettability when the lotion composition is applied to diaper topsheets. Similarly, a hydrophobic emollient such as petrolatum will require the addition of a hydrophilic surtactant.
wo 9t~m pc~rms9snsao9 Suitable hydrophilic surfactants wilt be miscible with the emollient and the immobilizing agent so as to form homogeneous mixtures. Because of possible skin sensitivity of those using disposable absorbent products to which the Potion composition is applied, these surfactants should also be relatively mild and non-irritating to the skin. Typically, these hydrophilic surfactants are nonionic to be rest only non-irritating to the skin, but also to avoid other undesirable effects on any underlying tissue laminate structure, e.g., reductions in tensile strength.
Suitable nonionic surfactants may be substantially nonmigratory after the lotion composition is applied to the diaper topsheets and will typically have HLB values in the range of from about 4 to about 20, preferably from about 7 to about 20. To be nonmigratory, these nonionic surfactants wilt typically have melt temperatures greater than the temperatures commonly eared during storage; shipping, merd~andising, and use of disposable absorbent products, e.g., at least about 30'C tn this regard, these nonionic surfactants will preferably have making points similar to those of the immobilizing agent: previously described.
Suitable nonionic surfactants for use in lotion compositions of the present invention inducts alkylgtycosides; alkylglycoside ethers as described in U.S. patent 4,011,389 (Langdon. et al), issued March 8, 1977;
alkyipolyethoxylated estsn such as Pegospsrse 1000MS (available from Lonza, Inc.. Fair Lawn, New Jersey), ethoxylsted :orbitan mono-, di- andlor tri-sstlrs of C12-C18 fatty acids having an average degree of ethoxylation of from about 2 to shout 20, preferably from about 2 to about 10, such as TWEEN*60 (:orbitan esters of stsaric acid having an average degree of ethoxylation of about 20) and TWEEN 81 (sorbitan esters of stearic acid t~tvnnp an avtrage degree of ethoxytation of shout 4), and the condensation prodaras d aliphstic sloohols with from shout 1 to about 54 moles of ~yler~ oxide. The slkyl ch~sin of the aliphatic alcohol is typically in a straight chsin (linear) oonfigurstion and contains from about 8 to about 22 carbon atoms. Particularly pnfetred an the sation products of aloohola having an alkyl group containing from about 11 to about 22 carbon stoma with from about 2 to about 30 moles of ethylene oxide per mole of alcohol, Examples of such ethoxylated alcohols indude the condensation . products of myristyl alcohol with 7 moles of ethylene oxide per mole of alcohol, the c~dsnsation products of donut alcohol (a mixture of fatty * = Trade-mark WO 9b116682 PCfNS95/13809 alcohols having alkyl chains varying in length from 10 to 14 carbon atoms) with about fi moles of ethylene oxide. A number of suitable ethoxylated alcohols are commercially available, including TERGITOL~ 15-S-9 (the condensation product of C11-C15 linear alcohois with 9 moles of ethylene oxide), marketed by Union Carbide Corporation; KYRO E08*(condensation product of C13-C15 linear alcohols with S moles of ethylene oxide), marketed by The Procter 8 Gamble Co., the NEODOL* brand name surfactants marketed by Shall Chemical Co., in particular NEODOL 25-12 (condensation product of C12-C15 linear afcohols with 12 males of ethylene oxide) and NEODOt 23-6.5T (condensation product of C12-C13 linear akx~hols with 6.5 moles of ethylene oxide that has been distil *ed (topped) to remove certain impurities), and especially the PLURAFAC brand name surfactants marketed Dy BASF Corp., in particular PLURAFAC A-38 (a condensation product of a C 18 straight chain alcohol with 27 moles ~ot ethylene oxide). (Certain of the hydrophilic surfactants, in particular ethoxylated slcohois such ss NEODOL 25-12, can also function as alkyl ethoxylats emollients). Other examples of preferred sthoxylated alcohol swfadsnts include ICPa Gass of 8rij surfactants and mixtures thereof, with 8rij 72 (i.e., Stearoth-2) and 8rij*76 ( i.e., Stearoth-10) being especially preferred. Also, mixtixes of cety! alcohol and stearyf alcohol ethoxylated to an average degree .of ethox)rlation of from about 10 to about 20 may also be used as the hydrophilic surfactant.
Another type al auitsbie surface for use in the present invention includes Aerosol OT, a dioctyl ester of sodium sutfosuocinic acid marketed by Art>.rian Cyanamid Company.
Still anot~r type of suitable surfa~t for use in the present irnrenbon includes silicone copolymers such as General Electric SF 1188 (a of s potydimethylsitoxane and a polyoxyslkylene ether) and General Electric SF 1228 (a siliaor» polyether copolymer). These silicone surfaasrns can be used in combination with the other types of hydrophilic surtaaaras disarssed above, such as the ~d slcotlols. These silicone surfactants haw bran found ~ ~ ~~w at concsnVations as low as 0.19, more preferably from about 0,25 to about 1.0%, by weight of the lotion sition.
3S The amount of hydrophilic surfactant . required to increase the wettabiiity of the lotion composition to a desired level will depend upon the = Trade-mark HLB value and level of immobilizing agent used, the HLB value of the surfactant used and like factors. The lotion composition can comprise from about 1 to about 50°~ of the hydrophilic surfactant when needed to increase the wettability properties of the composition. Preferably, the lotion composition comprises from about 1 to about 25%, most preferably from about 10 to about 20°r6, of the hydrophilic surfactant when needed to increase wettability.
4. Other Optional Components Lotion compositions can comprise other optional components typically present in emollient, creams, and lotions of this type. These optional components include water, viscosity modifiers, perfumes, disinfectant antibacterial actives, pharmaceutical actives, film formers, deodorants, opacifiers, astringents, solvents and the like. In addition, stabilizers can be added to enhance the shelf life of the lotion composition such as cellulose derivatives, proteins and lecithin. All of these materials are well known in the art as additives for such formulations and can be employed in appropriate amounts in the lotion compositions of the present invention.
C. Treating Diaper Toosheets With Lotion Composition In preparing lotioned diaper products according to the present invention, the lotion composition is applied to the outer surface (i.e., body facing surface) of a diaper topsheet. Any of a variety of application methods that evenly distribute lubricious materials having a molten or liquid consistency can be used. Suitable methods include spraying, printing (e.g., flexographic printing), coating (e.g., gravure coating), extrusion, or combinations of these application techniques, e.g. spraying the lotion composition on a rotating surface, such as a calender roll, that then transfers the composition to the outer surface of the diaper topsheet.
The manner of applying the lotion composition to the diaper topsheet should be such that the topsheet does not become saturated with the lotion composition. tf the topsheet becomes saturated with the lotion composition, there is a greater potential for the lotion to block the topsheet openings, reducing the ability of the topsheet to transmit fluid to the underlying absorbent core. Also, saturation of the topsheet is not required to obtain the therapeutic and/or protective lotion benefits. Particularly suitable application methods will apply the lotion composition primarily to the outer surface of the diaper topsheet.
The minimum level of lotion to be applied to the diaper topsheets is 5 an amount effective for reducing the adherence of BM to the skin of the wearer. The lotion composition is preferably applied to the diaper topsheets of the present invention in an amount ranging from about 0.1 mg/in2 to about 25 mg/in2 more preferably from about 1 mg/in2 to about 10 mg/in2 (mg of lotion per square inch of coated topsheet). Because the 10 emollient is substantially immobilized on the surface of the topsheet, less lotion composition is needed to impart the desired skin care benefits. Such relatively low levels of lotion composition are adequate to impart the desired therapeutic and/or protective lotion benefits to the topsheet, yet do not saturate the topsheet's absorbency and/or wettability properties.
15 The lotion composition may be applied to the entire surface of the topsheet or portions thereof. Preferably, the lotion composition is applied in a stripe aligned with and centered on the longitudinal centerline of the disposable absorbent article. Most preferably, as described in the Examples hereinafter, the lotion composition is applied to a discrete version 20 of the topsheet, e.g., a 3.75 inch wide (diaper lateral direction) and 7 inch long (diaper longitudinal direction) patch generally disposed toward the second waist region.
The lotion composition can also be applied nonuniformly to the outer surface of the diaper topsheet. By "nonuniform" is meant that the amount, 25 pattern of distribution, etc. of the lotion composition can vary over the topsheet surface. For example, some portions of the treated surface of the topst~eet can have greater or lesser amounts of lotion composition, including portions of the surface that do not have any lotion composition on it.
The lotion composition can be applied to the topsheet at any point 30 during assembly. For example, the lotion composition can be applied to the topsheet of the finished disposable absorbent product before it has been packaged. The lotion composition can also be applied to the topsheet before it is combined with the other raw materials to form a finished disposable absorbent product.
WO 96!16682 PCT/US95/13809 The lotion composition is typically applied from a melt thereof to the diaper topsheet. Since the lotion composition melts at significantly above ambient temperatures, it is usually applied as a heated coating to the topsheet. Typically, the lotion composition is heated to a temperature in the range from about 35° to about 100°C, preferably from 40°
to about 90°C, prior to being applied to the diaper topsheet. Once the melted lotion composition has been applied to the diaper topsheet, it is allowed to cool and solidify to form solidified coating or film on the surface of the topsheet.
Preferably, the application process is designed to aid in the cooling/set up of the lotion.
In applying lotion compositions of the present invention to diaper topsheets, spraying, gravure coating and extrusion coating methods are preferred. Figure 1 illustrates one such preferred method involving spraying of the coating on the diaper topsheet before the topsheet is assembled with the other raw materials into a finished product. Referring to Figure 1, a nonwoven topsheet web 1 is unwound from parent topsheet roll 2 (rotating in the direction indicated by arrow 2a) and advanced to spray station 6 where one side of the web is sprayed with a hot, molten (e.g., 65°C) lotion composition. After leaving spray station 6, nonwoven topsheet web 1 becomes a lotioned topsheet web indicated by 3. Lotioned topsheet web 3 is then advanced around turning roll 4 and turning roll 8, and then wound up on lotioned topsheet parent roll 10 (rotating in the direction indicated by arrow 10a).
Figure 2 illustrates an alternative preferred method involving continuous or intermittent spraying of the lotion composition on to a diaper topsheet during the converting operation. Referring to Figure 2, conveyor belt 1 advances in the direction shown by the arrows on turning rolls 3 and 4 and becomes returning conveyor belt 2. Conveyor belt 1 carries nonlotioned diaper 5 to spray station 6 where topsheet patch 7 is sprayed with a hot, molten (e.g., 65°C) lotion composition. After leaving spray station 6, nonlotioned diaper 5 becomes lotioned diaper 8 having a lotioned topsheet. The amount of lotion composition transferred to topsheet patch 7 is controlled by: (1 ) the rate at which the molten lotion composition is sprayed ftom spray station 6; andlor (2) the speed at which conveyor belt 1 travels under spray station 6.
W096I16681 cA o220502~ 2002-o5-os p~~7g95t13809 DIAPER TOPSHEETS A~C~II~tG TO THE PRESENT INV NTI(",~N
The following are specific illusVations of treating diaper topsheets 5 with lotion compositions in accordance with the present invention:
m I t A. Preparation of Lotion CQmoos--itions A water free lotion composition (Lotion A) is made by mixing the following melted (i.e., liquid) components together Mineral Oil 10 (Carnation White Mineral Oil, USP made by Witco Corp.), Cetearyl Alcohol (a mixed linear C ~ g-C ~ 8 primary alcohol made by the Procter 3 Gamble Company under the name TA-1618); Steareth-2 (Brij T2, a C~8 linear alcohol ethoxylate having an average degree of ethoxylation of 2, made by ICI America). The weight percentages of 15 these componsnta are shown in Table 1 below:
Compote Weigh %
Mineral Oil 50 Cetesryl Alcohol35 ~
Stear~th-2 15 8. narration of Lotioned Q_Zo_oshl t bV Hot Meit Soravina L.otiort Con~positior~ A is placed iMa s heated tank operating at ~ a Z0 temperahxe of 125'F. The co~osition is subseqwntly sprayed (using a Dynatec''E84B1T58 spray head, operating at a temperature of 185'F and an atomisation pressure of 2.40 paig) onto the topsheet of a diaper in s 3.T5 inch wide (diaper lateral direction) and T inch long (diaper longitudinal d~e~ia~) uea, the patch beginning 1 inch ZS forward of the lateral centerline and extending toward the rear of the per. Add-on level = 0.006 ~n2 (9.3 gtm2).
* = Trade-maxk Examale 2 The lotion composition A (prepared in accordance with the procedure in Example I) is subsequently sprayed onto the topsheet of a diaper in a 3.75 inch wide (diaper lateral direction) stripe centered on the longitudinal centerline and extending the entire length of the product.
Add-on level = 0.006 g/in2 (9.3 g/m2).
Example 3 The lotion composition A (prepared in accordance with the procedure in Example I) is subsequently sprayed onto the topsheet of a diaper in a 3.75 inch wide (diaper lateral direction) stripe centered on the longitudinal centerline and 7 inch long (diaper longitudinal direction) area, the patch beginning 1 inch forward of the lateral centerline arid extending toward the rear of the product. Add-on level = 0.003 g/in2 (4.65 glm2).
Example 4 A. Preparation of Lotion Compositions A water free lotion composition (Lotion B) is made by mixing the following melted (i.e., liquid) components together: Mineral Oil (Carnation White Mineral Oil, USP made by Witco Corp.), and Cetearyl Alcohol (a mixed linear C16-C18 primary alcohol made by the Procter 8 Gamble Company under the name TA-1618). The weight percentages of these components are shown in Table II
below:
Table II
Component Weight ~
Mineral Oil 65 Cetearyl Alcohol35 B. Preparation of Lotioned Tissue by Hot Melt Soravin4 Lotion Composition B is placed into a heated tank operating at a temperature of 125°F. The composition is subsequently sprayed (using a Dynatec E84B1758 spray head, operating at a temperature of 165°F and an atomization pressure of 2.40 psig) onto the topsheet of a diaper in a 3.75 inch wide (diaper lateral direction) and 7 inch long (diaper longitudinal direction) area, the patch beginning 1 inch forward of the lateral centerline and extending toward the rear of the product. Add-on level = 0.006 g/in2 (9.3 g/m2).
Example 5 A. Preparation of Lotion Composition A water free lotion composition (Lotion C) is made by mixing the following melted (i.e., liquid) components together: White Protopet~
1 S (white petrolatum made by Witco Corp.), Cetearyl Alcohol (a mixed linear C16-C1g primary alcohol made by the Procter ~ Gamble Company under the name TA-1618); Steareth-2 (Brij 762, a C18 linear alcohol ethoxylate having an average degree of ethoxylation of 2 made by ICI America). The weight percentages of these components are shown in Table I below:
A water free lotion composition (Lotion C) is made by mixing together the following melted (i.e., liquid) components in the weight percentages shown in the Table III below according to the procedure of Example 2:
Table III
Component Weight ~
WhiteProtopet~ 50 Cetearyl Alcohol35 Steareth-2 15 B. Preparation of Lotioned Tissue by Hot Melt Spravina Lotion Composition C is placed into a heated tank operating at a temperature of 125°F. The composition is subsequently sprayed (using a Dynatec E84B1758 spray head, operating at a temperature 5 of 165°F and an atomization pressure of 2.40 psig) onto the topsheet of a diaper in a 3.75 inch wide (diaper lateral direction) and 7 inch long (diaper longitudinal direction) area, the patch beginning 1 inch forward of the lateral centerline and extending toward the rear of the product. Add-on level = 0.006 glint (9.3 glm2).
Example 6 A. Preparation of Lotion Composition A water free lotion composition (Lotion D) is made by mixing the following melted (i.e., liquid) components together: White Protopet~
1 S (white petrolatum made by Witco Corp. ); Dow Coming 556 Cosmetic Grade Fluid(a polyphenylmethylsiloxane made by the Dow Coming Corporation), An example of a particularly preferred paraffin wax is Parrafin S.P. 434 (a paraffin wax made by Strahl and Pitsch Inc.); Cetearyl Alcohol (a mixed linear C16-C1g primary alcohol made by the Procter ~ Gamble Company under the name TA-1618);
PEG 2000 ( a polyethylene glycol having a MW of 2000 made by Sigma-Aldrich Corp). The weight percentages of these components are shown in Table IV below:
Table IV
Component Weight ~
WhiteProtopet~ 52 Polyphenyimethyl- 20 siloxane Paraffin Wax 15 Cetearyl Alcohol 10 WO 96!16682 PCT/US95/13809 B. Preparation of Lotioned Tissue by Hot Melt SDrayinQ
Lotion Composition D is placed into a heated tank operating at a temperature of 150°F. The composition is subsequently sprayed (using a Dynatec E84B1758 spray head, operating at a temperature of 170°F and an atomization pressure of 2.40 psig) onto the topsheet of a diaper in a 3.75 inch wide (diaper lateral direction) and 7 inch long (diaper longitudinal direction) area, the patch beginning 1 inch forward of the lateral centerline and extending toward the rear of the product. Add-on level = 0.006 glint (9.3 g/m2).
This application relates to absorbent articles such as diapers, training pants, adult incontinence devices, and the like. More particularly, the present invention relates to absorbent articles having a lotion coating on the outer surface of the topsheet that is transferable to the wearers skin by normal contact and wearer motion and/or body heat. The lotions disclosed in the present invention reduce the adherence of BM to the skin of the wearer, thereby improving the ease of BM clean up.
BACKGROUND OF THE INVENTION
Many types of disposable absorbent products, such as diapers, are available that have a high capacity for absorbing urine. Disposable pro~ta of this type generally comprise some sort of fluid-permeable topsheet material, an absorbent core, and a fluid-impermeable backsheet material. Although these types of absorbent structures may be highly efficier>Z for the absorption of fluids, they cannot absorb bowel movements i.e., hereinafter referred to as "BM"). Typically, the BM is Yapped between the outer surface of the fluid-permeable topsheet and the skin of the wearer, much of it adhering to the wearers skin.
To prevent BM from adhering to the wearers skin, the caregiver often applies protective or "repellent" products such as vasefine or mineral oil to the buttocks and anal region before placing the absorbent article on the wearer. This procedure usually involves the caregivers pouring of the oil or lotion, for example, in one of their hands, rubbing both hands together to distribute the substance thereon and then wiping the same on the skin of the infant. To eliminate the need for this wasteful, messy, and easily forgotten procedure, there have been numerous previous attempts to prepare absorbent articles which contain a protective or therapeutic skin care substance on the topsheet.
One substance that has been applied as a lotion to diaper products to impart a soothing, protective coating is mineral oil. Mineral oil (also known as liquid petrolatum) is a mixture of various liquid hydrocarbons obtained by distilling the high-boiling (i.e., 300°-390°C) fractions in petroleum. Mineral oil is liquid at ambient temperatures, e.g. 20°-25°C. As a result, mineral oil is relatively fluid and mobile, even when- applied to diaper topsheets.
Because mineral oil is fluid and mobile at ambient temperatures, it tends not to remain localized on the surface of the topsheet, but instead migrates through the topsheet into the interior of the diaper. Accordingly, relatively high levels of mineral oil need to be applied to the topsheet to provide the desired therapeutic or protective coating lotion benefits. This leads not only to increased costs for these lotioned diaper products, but other detrimental effects as well.
One of these detrimental effects is a decrease in the fluid handling properties as high levels of mineral oil tend to block the topsheet openings.
Atso, as mineral oil migrates to the interior of the diaper, it tends to act as a hydrophobic additive, thus decreasing the absorbency of the underlying absorbent core, if one is used. This decrease in absorbency becomes more pronounced as the level of mineral oil applied is increased.
Even without increasing its level, the tendency of mineral oil to migrate once applied has other detrimental effects. For example, the applied mineral oil can transfer to, into and through the packaging or wrapper material for the lotioned diaper product. This can create the need for ban-ier-type packaging or wrapper films to avoid smearing or other leakage of mineral oil from the diaper product.
Accordingly, it would be desirable to provide lotioned diaper products that: (1 ) have desirable therapeutic or protective coating lotion benefits (2) do not require relatively high levels of coatings that are liquid at room temperature (e.g., mineral oil) (3) do not adversely affect the absorbency of the diaper product; and (4) do not require special wrapping or barrier materials for packaging.
U.5. Patent 3,585,998 to Hayford et al. teaches a disposable baby diaper, an interior liner of which carnes an array of pressure-rupturable capsules containing S baby oil. The patent teaches that it is desirable to break the capsules prior to using the diaper by applying pressure with such household items as a rolling pin, hand iron, etc.
The same principle of pressure-rupturable capsules is used in U.S. Patent 3,464,413 to Goldfarb et al. for making bandages capable of delivering a medicinal material to an injury. Articles disclosed by both patents have a serious drawback. Namely, unless the capsules are ruptured by applying pressure prior to using the diaper or the bandage, the skin-care substance contained in the capsules is either not delivered at all or is delivered non-uniformly leaving some areas of skin uncoated.
U.5. Patent 3,896,807 to Buchaller teaches an article impregnated with a solid oil phase of cream formulation which forms a cream upon addition of moisture thereto. A major disadvantage of the article disclosed by the reference is that transfer of a beneficial substance from the absorbent substrate to skin is delayed and is only realized when body fluids are released.
U.S. Patent 3,489,148 to Duncan et al. teaches a baby diaper comprising a hydrophobic and oleophobic topsheet wherein a portion of the topsheet is coated with a discontinuous film of oleaginous material. A major disadvantage of the diapers disclosed in the Duncan et al. reference is that the hydrophobic and oleophobic topsheets are slow in promoting transfer of urine to the underlying aborbent cores.
Therefore, it is an object of an aspect of the present invention to provide a disposable diaper having a hydrophilic topsheet having superior fluid handing properties.
It is a further object of an aspect of the present invention to provide a hydrophilic diaper topsheet having a lotion coating on the outer surface of the topsheet that is transferable to the wearer's skin and is effective at reducing the adherence of BM to the skin, thereby improving the ease of BM cleanup.
It is yet a further object of an aspect of the present invention desirable to provide lotioned diaper products that: (1) have desirable BM release, cleaning, therapeutic or protective lotion coating benefits; (2) do not require relatively high levels of mineral oil; (3) do not adversely affect the fluid handling properties of the diaper; and (4) do not require special wrapping or barner materials for packaging.
These and other object of aspects are obtained using the present invention, as will become readily apparent from a reading of the following disclosure.
SUMMARY OF THE INVENTION
The present invention relates to a disposable diaper having a lotion coating on the outer surface of the topsheet that is semisolid or solid at ambient temperatures (i.e., at 20°C) and is adapted to be transferred to the wearer's skin, where it acts to reduce the adherence of BM to the skin of the wearer, thereby improving the ease of BM clean up.
Briefly, the disposable diapers of the present invention comprise:
A) a liquid impervious backsheet B) a liquid pervious, hydrophilic topsheet joined to said backsheet, said topsheet having an inner surface oriented toward the interior of said diaper and an outer surface oriented toward the skin of the wearer when said diaper is being worn, wherein at least a portion of said topsneet outer surface comprises an effective amount of a lotion coating which is semi-solid or solid at 20°C and which is partially transferable to the wearer's skin, said lotion coating comprising:
(i) from about 10 to about 95% of a substantially water free emollient having a plastic or fluid consistency at 20°C and comprising a member selected from the group consisting of petroleum-based emollients, fatty acid ester emollients, alkyl ethoxylate emollients, polysiloxane emollients, and mixtures thereof;
(ii) from about 5 to about 90% of an agent capable of immobilizing said emollient on said outer surface of the topsheet, said immobilizing agent having a melting point of at least about 35°C; and C) an absorbent core positioned between said topsheet and said backsheet.
The quantity of lotion coating on a least a portion of the diaper topsheets of S the present invention preferably ranges from about 0.1 mg/inz to about 25 mg/in2, more preferably from about 1 mg/in2 to about 10 mg/in2. Lotioned diaper topsheets according to the present invention provide desirable BM cleaning, therapeutic or protective lotion coating benefits. Because the emollient is substantially immobilized on the surface of the topsheet, less lotion composition is needed to impart the desired skin care benefits. In addition, special barrier or wrapping materials are unnecessary in packaging the lotioned diaper products of the present invention.
As will be discussed hereinafter, the lotion compositions of the present invention preferably have a melting profile such that they are relatively immobile and localized on the diaper topsheet at room temperature, are transferable to the wearer at body temperature, and yet are not completely liquid under exareme storage conditions.
Importantly, the lotion compositions of the present invention are easily transferable to the skin by way of normal contact, wearer motion, and/or body heat.
Without being bound by theory, it is believed that the lotion composition changes the surface energy of the skin, and/or fornis a "barrier" reducing the affinity of the skin for BM. The BM, therefore, has a reduced tendency to stick to the skin, and is easier to remove.
In accordance with one embodiment of the present invention, there is provided a disposable absorbent article comprising:
A) a liquid impervious backsheet;
B) a liquid pervious topsheet; and C) an absorbent core positioned between the topsheet and the backsheet, wherein at least a portion of the topsheet has applied thereto an effective amount of a lotion composition which is partially transferable to the wearer's skin, the lotion composition comprising:
(i) from about 10 to about 95% of a substantially water free emollient having a plastic or fluid consistency at 20°C, wherein Sa the emollient is selected from the group consisting of petroleum-based emollients, fatty acid ester emollients, alkyl ethoxylate emollients, fatty acid ester ethoxylates emollients, fatty alcohol emollients, polysiloxane emollients, and mixtures thereof; and (ii) from about 5 to about 90% of an immobilizing agent capable of immobilizing the emollient on the topsheet, the immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°(:, wherein the immobilizing agent is selected from the group consisting of polyhydroxy fatty acid esters, polyhydroxy fatty acid amides, Cia-C:ZZ fatty alcohols, C,z-CZZ fatty acids, C12-CZZ fatty alcohol ethoxylates, waxes, and mixtures thereof.
In accordance with a further embodiment of the present invention, there is provided a disposable absorbent article comprising:
A) a liquid impervious backsheet;
B) a liquid pervious topsheet; and C) an absorbent core positioned between the topsheet and the backsheet, wherein at least a portion of the topsheet comprises an effective amount of a lotion composition comprising a substantially water free emollient having a plastic or fluid consistency at 20°C and an immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°C, and wherein the lotion composition is applied in a non-uniform pattern to the topsheet.
In accordance with a further embodiment, there is provided a method for making an absorbent article having a lotion composition disposed on at least a portion of a topsheet, comprising the steps of the steps of (1) providing a topsheet; and (2) applying a lotion composition to the topsheet, the lotion composition comprising:
Sb (i) from about 10 to about 95% of a substantially water free emollient having a plastic or fluid consistency at 20°C, wherein the emollient is selected from the group consisting of petroleum-based emollient, fatty acid ester emollient, alkyl ethoxylate emollient, fatty acid ester ethoxylate emollient, fatty alcohol emollient, polysiloxane emollient, and mixtures thereof;
(ii) from about 5 to about 90% of an agent capable of immobilizing the emollient on the topsheet, the immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°C, wherein the immobilizing agent is selected from the group consisting of wax, polyhydroxy fatty acid ester, polyhydroxy fatty acid amide, C14-C22 fatty alcohol, C,2-Cz2 fatty acid, C,z-C22 fatty alcohol ethoxylate having an average degree of ethoxylation of about 2 to about 30, and mixtures thereof.
Figure 1 is a schematic representation illustrating a preferred process for applying the lotion composition of the present invention to diaper topsheets.
Figure 2 is a schematic representation illustrating an alternative process for applying the lotion composition of the present invention to diaper topsheets.
Figure 3 is an absorbent article in the form of a diaper according to the present invention.
DETAILED DESCRIPTION OF THE INVENTION
As used herein, the term "comprising" means that the various components, ingredients, or steps, can be conjointly employed in practicing the present invention. Accordingly, the term "comprising" encompasses the more restrictive terms "consisting essentially oP' and "consisting of."
All percentages, ratios and proportions used herein are by weight unless otherwise specified.
A. Absorbent Article As used herein, the term "absorbent article" refers to devices which absorb and contain body exudates, and more specifically, refers to devices which are placed against the skin of a wearer to absorb and contain the various exudates discharged from the body. The term "disposable" is used herein to describe absorbent articles which are not intended to be laundered or otherwise restored or reused as an absorbent article after a single use. Examples of disposable absorbent articles include feminine hygiene garments such as sanitary napkins and panti-liners, diapers, incontinence briefs, diaper holders, training pants, and the like.
Disposable absorbent articles typically comprise a liquid pervious topsheet, a liquid impervious backsheet joined to the topsheet and an absorbent core positioned between the topsheet and the backsheet.
Disposable absorbent articles and components thereof, including the topsheet, backsheet, absorbent core, and any individual layers of these components, have a body surface and a garment surface. As used herein, "body surface" means that surface of the article or component which is intended to be worn toward or adjacent to the body of the wearer, while the "garment surface" is on the opposite side and is intended to be worn toward or placed adjacent to the wearer's body or undergarments when the disposable absorbent article is worn.
' The following description generally discusses the absorbent core, topsheet, and backsheet materials that are useful in disposable absorbent ' 5 articles. It is to be understood that this general description applies to these components of the specific absorbent articles shown in Figure 3 and further described below, in addition to those of other disposable absorbent articles which are generally described herein.
In general, the absorbent core is capable of absorbing or retaining liquids (e.g., menses, urine, and/or other body exudates). The absorbent core is preferably compressible, conformable, and non-irritating to the wearer's skin. The absorbent core may be manufactured in a wide variety of sizes and shapes (e.g., rectangular, oval, hourglass, 'T' shaped, dog bone, asymmetric, etc.). In addition to the absorbent composites of the present invention, the absorbent core may include any of a wide variety of liquid-absorbent materials commonly used in absorbent articles, such as comminuted wood pulp, which is generally referred to as airfelt. Examples of other suitable absorbent materials for use in the absorbent core include creped cellulose wadding; meltblown polymers including coform; chemically stiffened, modified or cross-linked cellulosic fibers; synthetic fibers such as crimped polyester fibers; peat moss; tissue including tissue wraps and tissue laminates; absorbent foams; absorbent sponges; superabsorbent polymers; absorbent gelling materials; or any equivalent material or combinations of materials, or mixtures of these.
The configuration and construction of the absorbent core may also be varied (e.~., the absorbent core may have varying caliper zones and/or have a profile so as to be thicker in the center, hydrophilic gradients;
gradients of the absorbent composite of the present invention, superabsorbent gradients; or lower average density and lower average basis weight zones, e.g., acquisition zones; or may comprise one or more layers or structures). The total absorbent capacity of the absorbent core should, however, be compatible with the design loading and the intended use of the absorbent article. Further, the size and absorbent capacity of the absorbent core may be varied to accommodate different uses such as diapers, incontinence pads, pantiliners, regular sanitary napkins, and overnight sanitary napkins, and to accommodate wearers ranging from infants to adults.
The absorbent core can include other absorbent components that are often used in absorbent articles, for example, a dusting layer, a wicking or acquisition layer, or a secondary topsheet for increasing the wearer's comfort.
The topsheet is preferably compliant, soft feeling, and non-irritating to the wearer's skin. Further, the topsheet is liquid pervious, permitting liquids (e.g., menses and/or urine) to readily penetrate through its thickness. A suitable topsheet may be manufactured from a wide range of materials such as woven and nonwoven materials (e.g., a nonwoven web of fibers); polymeric materials such as apertured formed thermoplastic films, apertured plastic films, and hydrofonned thermoplastic films; porous foams;
reticulated foams; reticulated thermoplastic films; and thermoplastic scrims.
Suitable woven and nonwoven materials can be comprised of natural fibers (e.g., wood or cotton fibers), synthetic fibers (e.g., polymeric fibers such as polyester, polypropylene, or polyethylene fibers) or from a combination of natural and synthetic fibers. When the topsheet comprises a nonwoven web, the web may be manufactured by a wide number of known techniques.
For example, the web may be spunbonded, carded, wet-laid, melt-blown, hydroentangled, combinations of the above, or the like.
The backsheet is impervious to liquids (e.g., menses and/or urine) and is preferably manufactured from a thin plastic film, although other flexible liquid impervious materials may also be used. As used herein, the term "flexible" refers to materials which are compliant and will readily conform to the general shape and contours of the human body. The backsheet prevents the exudates absorbed and contained in the absorbent core from wetting articles which contact the absorbent article such as bedsheets, pants, pajamas and undergarments. The backsheet may thus comprise a woven or nonwoven material, polymeric films such as thermoplastic films of polyethylene or polypropylene, or composite materials such as a film~oated nonwoven material. A suitable backsheet is a polyethylene film having a thickness of from about 0.012 mm (0.5 mil) to about 0.051 mm (2.0 mils). Exemplary polyethylene films are manufactured by Clopay Corporation of Cincinnati, Ohio, under the designation P18-1401 and by Tredegar Film Products of Terre Haute, Indiana, under the designation XP-39385. The backsheet is preferably embossed and/or matte finished to provide a more clothlike appearance. Further, the backsheet may permit vapors to escape from the absorbent core (i.e., the backsheet is breathable) while still preventing exudates from passing through the backsheet. The size of the backsheet is dictated by the size of the absorbent core and the exact absorbent article design selected.
The backsheet and the topsheet are positioned adjacent the garment surface and the body surface, respectively, of the absorbent core. The absorbent core is preferably joined with the topsheet, the backsheet, or both in any manner as is known by attachment means (not shown in Figure 3) such as those well known in the art.
However, embodiments of the present invention are envisioned wherein portions of the entire absorbent core are unattached to either the topsheet, the backsheet or both.
For example, the backsheet an/or the topsheet may be secured to the absorbent core or to each other by a uniform continuous layer of adhesive, a patterned layer of adhesive, or an array of separate lines, spirals, or spots of adhesive.
Adhesives which have been found to be satisfactory are manufactured by H. B. Fuller Company of St.
Paul; Minnesota under the designation HL-1258 or H-2031. The attachment means will preferably comprise an open pattern network of filaments of adhesive as is disclosed in U.S. Patent 4,573,986, issued to Minetola, et al. on March 4, 1986. An exemplary attachment means of an open pattern network of filaments comprise:
several lines of adhesive filaments swirled into a spiral pattern such as illustrated by the apparatus and method shown in U.S. Patent 3,911,173 issued to Sprague, Jr.
on October 7, 1975; U.S. Patent 4,785,996 issued to Zwieker, et al. on November 22, 1978; and U.S. Patent 4,842,666 issued to Werenicz on June 27, 1989.
Alternatively, the attachment means may comprise heat bonds, pressure bond, ultrasonic bonds, dynamic mechanical bond, or any other suitable attachment means or combinations of them attachment means as are known in the art.
A preferred disposable absorbent article in which the lotioned topsheets of the present invention may be used are diapers. As used herein, the term "diapers"
refers to an absorbent article generally worn by infants, and incontinent persons that is worn about the lower torso of the wearer. In other words, the term "diaper" includes infant diapers, training pants, adult incontinence devices, etc.
Figure 3 is a plan view of the diaper 50 of the present invention in its flat-out, uncontracted state (i.e., with elastic induced contraction pulled out) 5 with portions of the structure being cut-away to more clearly show the construction of the diaper 50 and with the portion of the diaper 50 which faces away from the wearer, the outer surface, oriented towards the viewer.
As shown in Figure 3, the diaper 50 preferably comprises a liquid pervious topsheet 520; a liquid impervious backsheet 530 joined with the topsheet 10 520; an absorbent core 540 positioned between the topsheet 520 and the backsheet 530, the absorbent core 540 having a garment facing surface 542, a body facing surface 544, side edges 546, waist edges 548, and ears 549. The diaper 50 preferably further comprises elasticized leg cuffs 550;
an elastic waist feature multiply designated as 560; and a fastening system generally multiply designated as 570.
The diaper 50 is shown in Figure 3 to have an outer surface 52, an inner surface 54 opposed to the outer surface 52, a first waist region 56, a second waist region 58, and a periphery 51 which is defined by the outer edges of the diaper 50 in which the longitudinal edges are designated 55 and the end edges are designated 57. (While the skilled artisan will recognize that a diaper is usually described in terms of having a pair of waist regions and a crotch region between the waist regions, in this application, for simplicity of terminology, the diaper 50 is described as having only waist regions including a portion of the diaper which would typically be designated as part of the aotch region). The inner surface 54 of the diaper 50 comprises that portion of the diaper 50 which is positioned adjacent to the wearer's body during use (i.e., the inner surface 54 generally is formed by at least a portion of the topsheet 520 and other components that may be joined to the topsheet 520). The outer surface 52 comprises that portion of the diaper 50 which is positioned away from the wearers body (i.e., the outer surface 52 generally is formed by at least a portion of the backsheet 530 and other components that may be joined to the backsheet 530). (As used herein, the portion of the diaper 50 or component thereof which faces the wearer is also referred to as the body facing surface. Similarly, the portion facing away from the wearer is also referred to herein as the garment facing surface.) The first waist region 56 and the second waist region 58 extend, respectively, from the end edges 57 of the periphery 51 to the lateral centerline 53 of the diaper 50. Figure 3 also shows the longitudinal centerline 59.
Figure 3 shows a preferred embodiment of the diaper 50 in which the topsheet 520 and the backsheet 530 have length and width dimensions generally larger than those of the absorbent core 540. The elasticized leg cuffs 550 and the backsheet 530 extend beyond the edges of the absorbent core 540 to thereby form the periphery 51 of the diaper 50.
Diapers of the present invention can have a number of well known configurations, with the absorbent cores thereof being adapted to the present invention. Exemplary configurations are described generally in U.S. Patent 3,860,003 issued to Buell on January 14,1975; U.S. Patent 5,151,092 issued to Buell et al. on September 29, 1992; U.S. Patent 5,221,274 issued to Buell et al. on June 22, 1993.
Another diaper configuration to which the present invention can be readily adapted are described in U.S. Patent No. 5,554,145 issued on September 10, 1996. The absorbent cores of diapers described in these patents can be adapted in light of the teachings herein to include the absorbent composite of the present invention as an absorbent gelling material described therein.
A topsheet 520 which is particularly suitable for use in the diaper 50, is carded and thermally bonded by means well known to those skilled in the fabrics art.
A
satisfactory topsheet for the present invention comprises staple length polypropylene fibers having a denier of about 2.2. As used herein, the term "staple length fibers"
refers to those fibers having a length of at least about 15.9 mm (0.625 inches).
Preferably, the topsheat has a basis weight from about 14 to about 25 grams per square meter. A suitable topsheet is manufactured by Veratec, Inc., a Division of International Paper Company, of Walpole, Mass. under the designation P-8.
The topsheet 520 of diaper 50 is preferably made of a hydrophilic material to promote rapid transfer of liquids (e.g., urine) through the tophseet. If the topsheet is made of a hydrophobic material, at least the upper surface of the topsheet is treated to be hydrophilic so that liquids will transfer through the topsheet more rapidly. This diminishes the likelihood that body exudates will flow off the topsheet rather than being drawn through the topsheet and being absorbed by the absorbent core. The topsheet can be rendered hydrophilic by treating it with a surfactant.
Suitable methods for treating the topsheet with a surfactant include spraying the topsheet material with the surfactant and immersing the material into the surfactant. A more detailed discussion of such a treatment and hydrophilicity is contained in U.S. Patents 4,988,344 entitled "Absorbent Articles with Multiple Layer Absorbent Layers"
issued to Reising, et al. on January 29, 1991 and U.S. Patent 4,988,345 entitled "Absorbent Articles with Rapid Acquiring Absorbent Cores" issued to Reising on January 29, 1991.
In a preferred embodiment of a diaper as described herein, the backsheet 530 has a modified hourglass shape extending beyond the absorbent core a minimum distance of about 1.3 cm to about 6.4 cm (about 0.5 to about 2.5 inch) around the entire diaper periphery.
The absorbent core 540 may take on any size or shape that is compatible with the diaper 50. One preferred embodiment of the diaper 50 has an asymmetric, modified T-shaped absorbent core 540 having ears in the first waist region but a generally rectangular shape in the second waist region. Exemplary absorbent structures for use as the absorbent core of the present invention that have achieved wide acceptance and commercial success are described in U.S. Patent 4,610,678 entitled "High-Density Absorbent Structures" issued to Weisman et al. on September 9, 1986; U. S. Patent 4,673,402 entitled "Absorbent Articles With Dual-Layered Cores" issued to Weisman et al. on June 16, 1987; U.S. Patent 4,888,231 entitled "Absorbent Core Having A Dusting Layer" issued to Angstadt on December 19, 1989;
and U.S. Patent 4,834,735, entitled "High Density Absorbent Members Having Lower Density and Lower Basis Weight Acquisition Zones" issued to Alemany et al. on May 30, 1989. The absorbent core may further comprise the dual core system containing an acquisition/distribution core of chemically stiffened fibers positioned over an absorbent storage core as detailed in U.S. Patent 5,234,423, entitled "Absorbent Article With Elastic Waist Feature and Enhanced Absorbency" issued to Alemany et al., on August 10, 1993; and in U.S. Patent 5,147,345, entitled "High Efficiency Absorbent Articles For Incontinence Management"
issued to Young, Lavon and Taylor on September 15,1992.
In a preferred embodiment, the diaper 50 further comprises elasticized leg cuffs 550 for providing improved containment of liquids and other body exudates; an elastic waist feature 560 that provides improved fit and containment; and a fastening system 570 which forms a side closure which maintains the first waist region 56 and the second waist region 58 in an overlapping configuration such that lateral tensions are maintained around the circumference of the diaper to maintain the diaper on the wearer. The diaper 50 may also comprise elasticized side panels (not shown) in the waist regions 56 and 58 to provide an elastically extensible feature that provides a more comfortable and contouring fit and more effective application of the diaper S0.
The elasticized leg cuffs 550 can be constructed in a number of different configurations, including those described in U.S. Patent No. 3,860,003; U.S.
Patent No.4,909,803, issued to Aziz et al. on March 20, 1990; U.S. Patent No.4,695,278, issued to Lawson on September 22, 1987; and U.S. Patent No.4,795,454, issued to Dragoo on January 3, 1989.
The elasticized waist feature preferably comprises an elasticized waistband (not shown) that may be constructed in a number of different configurations including those described in U.S. Patent No.4,515,595 issued to Kievit et al. on May 7, 1985;
U.S. Patent No. 5,026,364 issued to Robertson on June 25, 1991; and the above referenced U.S. Patent No. 5,151,092 issued to Buell et at. on Sep.29, 1992.
The elasticized side panels may be constructed in a number of configurations.
Examples of diapers with elasticized side panels positioned in the ears (ear flaps) of the diaper are disclosed in U.S. Patent No. 4,857,067, issued to Wood, et al.
on Aug.lS, 1989; U.S. Patent No. 4,381,781, issued to Sciaraffa, et al. on May 3, 1983;
U.S. Patent No. 4,938,753, issued to Van Gompell, et al. on July 3, 1990; and U.S.
Patent No. 5,1 S 1,092, issued to Buell et al. on September 29, 1992.
Exemplary fastening Systems 570 are disclosed in U. S Patent No. 4,846,815, issued to Scripps on July 11, 1989; U.S. Patent No. 4,894,060, issued to Nestegard on Jan.l6, 1990;
U.S. Patent No.4,946,527, issued to Battrell on Aug. 7, 1990; U.S. Patent No.3,848,594, issued to Buell on Nov. 19, 1974; U.S. Patent No. B 1 4,662,875, issued to Hirotsu et al. on May 5, 1987; and U.S. Patent No.5,151,092, issued to Buell et al.
on Sep.29, 1992.
The diaper 50 is preferably applied to a wearer by positioning one of the waist regions of the diaper, preferably the second waist region 58, under the wearer's back and drawing the remainder of the diaper between the wearer's legs so that the other waist region, preferably the first waist region 56, is positioned across the front of the wearer. The fastening system is then applied to effect a side closure.
The lotioned topsheets of the present invention are also useful in training pants. The term "training pants", as used herein, refers to disposable garments having fixed sides and leg openings. Training pants are placed in position on the wearer by inserting the wearers legs into the leg openings and sliding the training pant into position about the wearer's lower torso. Suitable training pants are disclosed in U.S.
Patent No. 5,246,433, issued to Hesse, et al. on September 21, 1993.
Another disposable absorbent article for which the lotioned topsheets of the present invention are useful are incontinence articles. The term "incontinence article"
refers to pads, undergarments (pads held in place by a suspension system of same type, such as a belt, or the like), inserts for absorbent articles, capacity boosters for absorbent articles, briefs, bed pads and the like regardless of whether they are worn by adults or other incontinent persons. Suitable incontinence articles are disclosed in U.S.
Patent No. 4,253,461 issued to Strickland, et al. on March 3, 1981; U.S.
Patent Nos.
4,597,760 and 4,597,761 issued to Buell; the above-mentioned U.S. Patent No.4,704,115; U.S. Patent No. 4,909,802 issued to Ahr, et al.; U.S. Patent No.4,964,860 issued to Gipson, at al. on October 23.1990; and in PCT
Publication No. WO 92/11830 published on July 23, 1992.
B. Lotion Composition.
The lotion compositions of the present invention are solid, or more often semisolid, at 20°C, i.e. at ambient temperatures. By "semisolid"
is meant that the lotion composition has a rheology typical of pseudopfastic or 5 plastic fluids. When no shear is applied, the lotion compositions can have the appearance of a semi-solid but can be made to flow as the shear rate is increased. This is due to the fact that, while the lotion composition contains primarily solid components, it also includes some minor liquid components.
The lotion compositions of the present invention are at least semi-1o solid at room temperature to minimize lotion migration. In addition, the lotion compositions preferably have a final melting point (100°r6 liquid) above potential "stressful" storage conditions that can be greater than 45°C
(e.g., warehouse in Arizona, car trunk in Florida, etc.).
Specifically, the lotion compositions of the present invention should have 15 the following melt profile:
Characteristic Preferred Ranae Most Preferred % liquid at 2-50 3-25 room temp. (20 °C) % liquid at 25-95 30-90 body temp. (37 °C) final melting point (°C) z38 >_45 By being solid or semisolid at ambient temperatures, these lotion compositions do not have a tendency to flow and migrate into the interior of the diaper topsheet to which they are applied. This means less lotion composition is required for imparting desirable therapeutic or protective coating lotion benefits.
When applied to outer surface of diaper topsheets, the lotion compositions of the present invention are transferable to the wearer's skin by normal contact, wearer motion, andlor body heat. Importantly, the lotions disclosed in the present invention reduce the adherence of BM to the skin of the wearer, thereby improving the ease of BM clean up.
The diaper topsheets of the present invention contain an effective amount of the lotion composition. As used herein, the term "effective amount of a lotion coating" refers to an amount of a particular lotion composition which, when applied to a diaper topsheet, will be effective in reducing the adherence of BM to the skin of the wearer. Of course, the effective amount of a lotion coating will depend, to a large extent, on the particular lotion composition used.
The lotion compositions of the present invention comprise: (1 ) an emollient(s); (2) an immobilizing agents) for the emollient; (3) optionally a hydrophilic surfactant(s); and (4) other optional components.
The viscosity of the formulated lotion compositions, including emollient, immobolizing agent, and optional components should be as high as possible to keep the lotion from flowing into the interior of the diaper.
Unfortunately, high viscosities can also lead to lotion compositions that are difficult to apply without processing problems. Therefore, a balance must be achieved so the viscosities are high enough to keep the lotion compositions localized on the surface of the diaper topsheet, but not so high as to cause processing problems. Suitable viscosities for the lotion compositions will typically range from about 5 to about 200 centipoises, preferably from about 15 to about 100 centipoises, measured at 60°C.
1. mollient The key active ingredient in these lotion compositions is one or more emollients. As used herein, an emollient is a material that softens, soothes, supples, coats, lubricates, moisturizes, or cleanses the skin. An emollient typically accomplishes several of these objectives such as soothing, moisturizing, and lubricating the skin. For the purposes of the present invention, these emollients have either a plastic or fluid consistency at 20°C, i.e., at ambient temperatures. This particular emollient consistency allows the lotion composition to impart a soft, lubricious, lotion-like feel.
The emollients useful in the present invention are also substantially free of water. By "substantially free of water' is meant that water is not intentionally added to the emollient. Addition of water to the emollient is not necessary in preparing or using the lotion compositions of the present invention and could require an additional drying step. However, minor or trace quantities of water in the emollient that are picked up as a result of, for example, ambient humidity can be tolerated without adverse effect.
Typically, the emollients used in the present invention contain about 5°r6 or less water, preferably about 1 °~ or less water, most preferably about 0.5°~
or less water.
Emollients useful in the present invention can be petroleum-based, fatty acid ester type, alkyl ethoxylate type, fatty acid ester ethoxylates, fatty alcohol type, polysiloxane type, or mixtures of these emollients. Suitable petroleum-based emollients include those hydrocarbons, or mixtures of hydrocarbons, having chain lengths of from 16 to 32 carbon atoms.
Petroleum based hydrocarbons having these chain lengths include mineral oil (also known as "liquid petrolatum") and petrolatum (also known as "mineral wax," "petroleum jelly" and "mineral jelly"). Mineral oil usually refers to less viscous mixtures of hydrocarbons having from 16 to 20 carbon atoms. Petrolatum usually refers to more viscous mixtures of hydrocarbons having from 16 to 32 carbon atoms. Petrolatum and mineral oil are particularly preferred emollients for lotion compositions of the present invention.
Suitable fatty acid ester type emollients include those derived from C12-C2g fatty acids, preferably C1g-C~ saturated fatty acids, and short chain (C1-Cg, preferably C1-C3) monohydric alcohols. Representative examples of such esters include methyl palmitate, methyl stearate, isopropyl laurate, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate and mixtures thereof. Suitable fatty acid ester emollients can also be derived from esters of longer chain fatty alcohols (C12-C2g, preferably C12-C16) and shorter chain fatty acids e.g., lactic acid, such as lauryl lactate and c;etyl lactate.
Suitable alkyl ethoxylate type emollients include C12-C~ fatty alcotwl ethoxylates having an average degree of ethoxylation of from about 2 to about 30. Preferably, the fatty alcohol ethoxylate emoliient is selected from the group consisting of lauryl, cetyl, and stearyl ethoxylates, and mixtures thereof, having an average degree of ethoxylation ranging from about 2 to about 23. Representative examples of such alkyl ethoxylates include laureth-3 (a lauryl ethoxylate having an average degree of ethoxylation of 3), laureth-23 (a lauryl ethoxylate having an average degree of ethoxylation of 23), ceteth-10 (a cetyl alcohol ethoxylate having an average degree of ethoxylation of 10) and steareth-10 (a stearyl alcohol ethoxylate having an average degree of ethoxylation of 10~. These alkyl ethoxylate emollients are typically used in combination with the petroleum based emollients, such as petrolatum, at a weight ratio of alkyl ethoxylate emollient to pstroleum~based emollient of from about 1:1 to about 1:5, preferably from about 1:2 to about 1:4.
Suitable fatty alcohol type etnollienta include C12-C22 tatty alcohols, preferably C1g-C1g tatty alcohols. Representative examples include cetyl alcohol and stearyl alcohol, and mixtures thereof. These fatty alcohol emollients are typically used in ' combination with the petroleum-based emollients, such as petrolatum, at a weight ratio of fatty alcohol emollient to petroleum-based emollient of from about 1:1 to about 1:5, preferably from about 1:1 to about 1:2.
Other suitable types of emollients for use in the present invention include polysiioxane compounds. In general suitable polysiloxane materials for u:. in the present invention include those having monomeric siloxane pits of the following structure:
R~
Si-O _ wherein, R1 and RZ, for each independent sitoxsne monomeric unit can each independently be hydrogen or any alkyl, aryl, slksnyl, alkaryl, arakyi, ~~ halogenated hydrocarbon, or other radical. Any of such radicals do be substituted or una~tituted. R1 and R2 radicals of any partiarlar ~c ~ ~y d;~~ fiom the corresponding functionalities of the next monomeric unit. A~itionalty, the polysiloxa~ can be either a ~;g~ chain, a brsrxhed chain or have a cyclic stru~o. The radicals R1 ~d RZ can sddidonally independently be other siliceous functionalities such as, but not limited to siloxsnes, polysiloxanss, silanes, and polysilanes. The radicals R1 and R2 may contain any of a variety of orpsnic tundionalities including, for ex~ur~ple, alcohol, carboxylic acid, phenyl, end amine fundionalities.
Exemplary alkyl radicals are methyl, ethyl, propyl, butyl, pentyl, hexyl, octyl, decyl, octadecyl, and the like. Exemplary alkenyl radicals are vinyl, allyl, and the like.
Exemplary aryl radicals are phenyl, diphenyl, naphthyl, and the like.
Exemplary alkaryl radicals are toyl, xylyl, ethylphenyl, and the like. Exemplary aralkyl radicals S are benzyl, alpha-phenylethyl, betaphenylethyl, aipha-phenylbutyl, and the like.
Exemplary cycloalkyl radicals are cyclobutyl, cyclopentyl, cyclohexyl, and the like.
Exemplary halogenated hydrocarbon radicals are chioromethyl, bromoethyl, tetrafluorethyl, fluorethyl, trifluorethyl, trifluorotloyl, hexafluoroxylyl, and the like.
Viscosity of polysiloxanes useful may vary as widely as the viscosity of polysiloxanes in general vary, so long as the polysiloxane is flowable or can be made to be flowable for application to the diaper topsheet. This includes, but is not limited to, viscosity as low as 5 centistokes (at 37 °C as measured by a glass viscometer) to about 20,000,000 centistokes. Preferably the polysiloxanes have a viscosity at 37 °C
ranging from about S to about 51000 centistokes, more preferably from about S
to about 2,000 centistokes, most preferably from about 100 to about 1000 centistokes.
High viscosity polysiloxanes which themselves are resistant to flowing can be effectively deposited upon the diaper topsheets by such methods as, for example, emulsifying the polysiloxane in surfactant or providing the polysiloxane in solution with the aid of a solvent, such as hexane, listed for exemplary purposes only.
Particular methods for applying polysiloxane emollients to diaper topsheets are discussed in more detail hereinafter.
Preferred polysiloxanes compounds for use in the present invention are disclosed in U.S. Patent 5,059,282 (Ampulski et al), issued October 22, 1991.
Particularly preferred polysiloxane compounds for use as emollients in the lotion compositions of the present invention include phenyl-functional polymethylsiloxane compounds (e.g., Dow Coming 556 Cosmetic-Grade Fluid:
polyphenylmethylsiloxane) and cetyl or stearyl functionalized dimethicones such as Dow 2502 and Dow 2503 polysiloxane fluids, respectively. In addition to such substitution with phenyl-functional or alkyl groups, effective substitution may be made with amino, carboxyl, hydroxyl, ether, polyether, aldehyde, ketone, amide, ester, and thiol groups. Of these effective substituent groups, the family of groups comprising phenyl, amino, alkyl, carboxyl, and hydroxyl groups are more prefer-ed than the others;
and phenyl-functional groups are most preferred.
Besides petroleum-based emollients, fatty acid ester emollients, fatty acid ester ethoxylates, alkyl ethoxylate emollients fatty alcohol emollients, 5 and polysiloxanes, the emollients useful in the present invention can include minor amounts (e.g., up to about 10% of the total emollient) of other, conventional emollients. These other, conventional emollients include propylene glycol, glycerine, triethylene glycol, spermaceti or other waxes, fatty acids, and fatty alcohol ethers having from 12 to 28 carbon 10 atoms in their fatty chain, such as stearic acid, propoxylated fatty alcohols;
glycerides, acetoglycerides, and ethoxylated gfycerides of C12-C2g fatty acids; other fatty esters of polyhydroxy alcohols; lanolin and its derivatives.
These other emollients should be included in a manner such that the sobd or semisolid characteristics of the lotion composition are maintained.
15 The amount of emollient that can be included in the lotion composition will depend on a variety of factors; including the particular emollient involved, the lotion-like benefits desired, the other components in the lotion composition and like factors. The lotion composition can comprise from about 10 to about 95°~ of the emollient. Preferably, the 20 lotion composition comprises from about 20 to about 80°r6, most preferably from about 40 to about 75°~, of the emollient.
2. immobilizing Agent An especially key component of the lotion compositions of the present invention is an agent capable of immobilizing the emollient on the diaper topsheet to which the lotion composition is applied. Because the emollient in the composition has a plastic or fluid consistency at 20°C, it tends to flow or migrate, even when subjected to modest shear. When applied to a diaper topsheet, especially in a melted or molten state, the emollient will not remain primarily on the surface of the topsheet. Instead, the emollient will tend to migrate and flow into the interior of the diaper.
This migration of the emollient into the interior of the diaper can cause undesired effects on the absorbency of the diaper core due to the hydrophobic characteristics of many of the emollients used in the lotion compositions of the present invention. It also means that much more emollient has to be applied to the diaper topsheet to get the desired therapeutic or protective lotion benefits. Increasing the level of emollient not only increases the cost, but also exacerbates the undesirable effect on the absorbency of the diaper core.
The immobilizing agent counteracts this tendency of the emollient to migrate or flow by keeping the emollient primarily localized on the surface of the diaper topsheet to which the lotion composition is applied. This is believed to be due, in part, to the fact that the immobilizing agent raises the melting point of the lotion composition above that of the emollient. Since the immobilizing agent is also miscible with the emollient (or solubilized in the emollient with the aid of an appropriate emulsifier), it entraps the emollient on the surface of the diaper topsheet as well.
It is also advantageous to "lock" the immobilizing agent on the surface of the diaper topsheet. This can be accomplished by using immobilizing agents which quickly crystallize (i.e., solidify) at the surface of the topsheet. In addition, outside cooling of the treated diaper topsheet via blowers, fans, etc. can speed up crystallization of the immobilizing agent.
In addition to being miscible with (or solubilized in) the emollient, the immobilizing agent needs to have a melting point of at least about 35°C.
This is so the immobilizing agent itself will not have a tendency to migrate or flow. Preferred immobilizing agents will have melting points of at least about 40°C. Typically, the immobilizing agent will have a melting point in the range of ftom about 50° to about 150°C.
Suitable immobilizing agents for the present invention can comprise a member selected from the group consisting of C14-C~ fatty alcohols, C12-C~ fatty acids, and C12-C~ fatty alcohol ethoxylates having an average degree of ethoxylation ranging from 2 to about 30, and mixtures thereof. Preferred immobilizing agents include C1g-C18 fatty alcohols, most preferably selected from the group consisting of cetyl alcohol, stearyl alcohol, and mixtures thereof. Mixtures of cetyl alcohol and stearyl alcohol are particularly preferred. Other preferred immobilizing agents include C1g-C1g fatty acids, most preferably selected from the group consisting of palmitic acid, stearic acid, and mixtures thereof. Mixtures of palmitic acid and stearic acid are particularly preferred. Still other preferred immobilizing agents include C1g-C1g fatty alcohol ethoxylates having an average degree of ethoxylation ranging from about 5 to about 20. Preferably, the fatty alcohols, fatty acids and fatty alcohols are linear.
Importantly, these preferred immobilizing agents such as the Cog -C~g fatty alcohols increase the rate of crystallization of the lotion causing the lotion to crystallize rapidly onto the surface of the substrate. Lower lotion levels can therefore be utilized or a superior lotion feel can be delivered. Traditionally, greater amounts of lotion were needed to generate softness because of the flow of these liquids into the diaper core.
Other types of immobilizing agents can be used either alone or in combination with the fatty alcohols, fatty acids, and fatty alcohol ethoxylates described above. Examples of these other types of immobilizing agents includes polyhydroxy fatty acid esters, polyhydroxy fatty acid amides, and mixtures thereof. Preferred esters and amides will have three or more free hydroxy groups on the polyhydroxy moiety and are typically nonionic in character. Because of the possible skin sensitivity of those using diaper topsheets to which the lotion composition is applied, these esters and amides should also be relatively mild and non-irritating to the skin.
Suitable polyhydroxy fatty acid esters for use in the present invention will have the formula:
II
R-C-O Y
n wherein R is a C5-C3~ hydrocarbyl group, preferably straight chain C7-Cog alkyl or alkenyl, more preferably straight chain Cg-C~7 alkyl or alkenyl, most preferably straight chain C~ ~-C~7 alkyl or alkenyl, or mixture thereof;
Y is a polyhydroxyhydrocarbyl moiety having a hydrocarbyl chain with at least 2 flee hydroxyls directly connected to the chain; and n is at least 1.
Suitable Y groups can be derived from polyols such as glycerol, pentaerythritol; sugars such as raffinose, maltodextrose, galactose, sucrose, glucose, xylose, fructose, maltose, lactose, mannose and WO 96I16a8Z PCZ'/US95113809 erythrose; sugar ~alcohols such as erythritoi, xylitol, malitol, mannitol and sorbitol; and anhydrides of sugar alcohols such as sorbitan.
Ores class of suitable polyhydroxy fatty acid esters for use in the present invention comprises certain sorbitan esters, preferably the sorbitan esters of Cog-C~ saturated fatty acids. Because of the manner in which they are typically manufactured, these sorbitan esters usually comprise mixtures of mono-, dl-, tri-, etc. esters. Representative examples of suitable *
sorbitsn esters include sorbitan palmitates (e.g., SPAN 40), sorbitan atsarates (e.g., SPAN 60y, and sorbitan behenates, that comprise one or more of the mono-, dl- and tri-ester versions of these sorbitan esters, e.g., sorbitan mono-, dl- and tri-palmitate, sorbitan mono-, dl- and tri-stearate, sorbitan mono-, dl and tti-behenate, as well as mixed tallow fatty acid sorbitan mono-, dl- and tri-esters. Mixtures of different sorbitan esters can also be used, such as sorbitan patmitates with sorbitan stearates.
t 5 Partiwlarly preferrod sorbitan esters are the sorbitan stearates, typically as a mixture of mono-, dl- and tri-esters (plus some tstraester) such as SPAN
60, and sorbitan stearates sold under the trade name GLYCOMUL-S by Lonza, Inc. Although these sorbitan esters typically contain mixtures of mono-, dl- and tri-esters, plus some tetraester, the mono- and di-esters are usually the predominant species in these mixtures.
Another Gas: of suitable polyhyc~oxy fatty aad esters for use in the preset invention comprises certain glyceryl monoesters, preferably _ gtyCeryl monoe:ters of Ctg-C~ satursted fatty cads such as glyceryl morrostarate, Qiycyryl monopalmitats, and glyceryt monobehenate. Again, like the sorbitan esters, gtycsryl monosster mixtures will typically contain some dl- end triester. Hovwwsr, such mixtures should contain pr~0ominantty the plyceryl monoester species' to be useful in the present inversion.
Another das: of suitable polyhydroxy fatty sad esters for use in the present invention comprise cartsin sucrose fatty acid esters, preferably the C~Z.C~ sattxated fstty acid esters of suaose.. Suaoae monoesters and dissters an paniartarly preferred and include suaose mono- and di-stearate and suaose mono- and dl- laurate.
Suitable polyhydroxy fatty acid amides for use in the present invention will haw the formula:
* = Trade-mark R' RZ-~-N-Z
wherein R~ is H, C1-C4 hydrocarbyl, 2fiydroxyethyl, 2-hydroxypropyl, melho~cyethyi, methoxypropyl or a mixture thereof, preferably C 1-C4 alkyl, methoxyethyl or methoxypropyl, more preferably C1 or C2 alkyl or methoxypropyl , most preiersbly C~ .alkyl (i.e., methyl) or methoxypropyl;
and R2 is a C5-C31 hydroc~srbyi gn~up, preferably straight chain CT-C19 alkyl or slkenyi, more preferably straight chain Cg-C ~ ~ alkyl or alkenyl, most preferably straight chain C11-C1~ alkyl or slkenyl, or mixture thereof;
and Z is a polyhydroxyhydrocarbyl moiety having a linen hydrocarbyi chain with a3 fist 3 hydroxyls directly comeded to the chain. See U.S. patent 5,174,927 (Hones), issued December 29,1992 which discloses these polyhydroary fatty acid amides, as well as their preparation.
Ttte Z moiety preferably will be derived Trom a reducing sugar in a radudivb amination reaction; most ~efersbly glyatyl. Suitable reduung sugar include gluco:e, fnrctose, maltose, lactose, galactose, mannose, and xylose. High dextrose cram syrup, high fructose cam syrup, and high maltose com syrup can be utilized, as welt as the individual sugars listed . ~ cprn syrups can yield mad~ees of sugar components for the Z
The Z ntoity Prefe~y X11 be selected 'from t~ 9~P consisting of .CHZ.(CHOH~-CHZOH, -CH(CHZOHy-((CHOH~.1]-CHZOH, -CH20H~
CHZ.(CHOH~(CHOR3xCHOH)-CH20H, where n is an integeC from 3 to 5, ~ R3 is H or a cydk a aliphatic monosaa~aride. Most preferred are the ~ity~ wt~s n is 4, partiarlarly -CH2-(CHOH~-CHZOH.
In the above forr>xrla. R~ ~ ~~ for example, N-methyl, N.~thyl, N-~pyl, N~p~yl~ N.p~yl, N-2-hydroxYethyl, N-methoxyproPYl or N-2-hy~xypropyl,. R2 can be selected to provide, for example, cocamides, 3p stesramides, oleamides, Isursmides, myristsmides, capricamides, palmitamides, talk~rsmides, etc. The Z moiety an be 1 ~eoXyglucityl, 2-deoxyfructityl, 1-deoxymaltityl, 1-deoxylactityl, 1-deoxygalactityl, 1-deoxymannityl, 1-deoxymaltotriotityl, etc.
The most preferred polyhydroxy fatty acid amides have the general formula:
O R~ OH
II I I
wherein R1 is methyl or methoxypropyl; R2 is a C11-C17 straight-chain alkyl or alkenyl group. These include N-lauryl-N-methyl glucamide, N-10 lauryl-N-methoxypropyl glucamide, N-cocoyl-N-methyl glucamide, N~ocoyl-N-methoxypropyl glucamide, N-palmityl-N-methoxypropyl glucamide, N-tallowyl-N-methyl glucamide, or N-tallowyl-N-methoxypropyl glucamide.
As previously noted, some of the immobilizing agents require an emulsifier for solubilization in the emollient. This is particularly the case for 15 certain of the glucamides such as the N-alkyl-N-methoxypropyl glucamides having HLB values of at least about 7. Suitable emulsifiers will typically include those having HLB values below about 7. In this regard, the sorbitan esters previously described, such as the sorbitan stearates, having HLB
values of about 4.9 or less have been found useful in solubilizing these 20 glucamide immobilizing agents in petrolatum. Other suitable emulsifiers inGude steareth-2 (polyethylene glycol ethers of stearyt alcohol that conform to the formula CHg(CH2)1~(OCH2CH2)nOH, where n has an average value of 2), sorbitan tristearate, isosorbide laurate, and glyceryl monostearate. The emulsifier can be included in an amount sufficient to 25 solubilize the immobilizing agent in the emollient such that a substantially homogeneous mixture is obtained. For example, an approximately 1:1 mixture of N-cocoyl-N-methyl glucamide and petrolatum that will normally not melt into a single phase mixture, will melt into a single phase mixture upon the addition of 20°~ of a 1:1 mixture of Steareth-2 and sorbitan tristearate as the emulsifier.
Other types of ingredients that can be used as immobilizing agents, either alone, or in combination with the above-mentioned immobilizing agents, include waxes such as carnauba, beeswax, candelilla, paraffin, ceresin, esparto, ouricuri, rezowax, and other known waxes. Preferably the wax is a paraffin wax. An example of a particularly preferred paraffin wax is Parrafin S.P. 434 from Strahl and Pitsch Inc. PØ Box 1098 West Babylon, NY 11704.
The amount of immobilizing agent that should be included in the lotion composition will depend on a variety of factors, including the particular emollient involved, the particular immobilizing agent involved, whether an emulsifier is required to solubilize the immobilizing agent in the emollient, the other components in the lotion composition and like factors.
The lotion composition can comprise from about 5 to about 90% of the immobilizing agent. Preferably, the lotion composition comprises from about 5 to about 50%, most preferably from about 10 to about 40°~, of the immobilizing agent.
3. Optional Hydrophilic Surfactant As mentioned above, it is highly desirable that the diaper topsheet is made of a hydrophilic material to promote rapid transfer of liquids (e.g., urine) through the topsheet. Similarly, it is important that the lotion composition also be sufficiently wettable to ensure that liquids will transfer through the topsheet more rapidly. This diminishes the likelihood that body exudates will flow off the lotion coating rather than being drawn through the topsheet and being absorbed by the absorbent core. Depending upon the particular immobilizing agent used in the lotion composition of the present invention, an additional hydrophilic surfactant (or a mixture of hydrophilic surtactants) may, or may not, be required to improve wettability. For example, some immobilizing agents, such as N-cocoyi-N-methoxypropyl glucamide have HLB values of at least about 7 and are sufficiently wettable without the addition of hydrophilic surfactant. Other immobilizing agents such as the C1g - C1g fatty alcohols having HLB values below about 7 will require addition of hydrophilic surfactant to improve wettability when the lotion composition is applied to diaper topsheets. Similarly, a hydrophobic emollient such as petrolatum will require the addition of a hydrophilic surtactant.
wo 9t~m pc~rms9snsao9 Suitable hydrophilic surfactants wilt be miscible with the emollient and the immobilizing agent so as to form homogeneous mixtures. Because of possible skin sensitivity of those using disposable absorbent products to which the Potion composition is applied, these surfactants should also be relatively mild and non-irritating to the skin. Typically, these hydrophilic surfactants are nonionic to be rest only non-irritating to the skin, but also to avoid other undesirable effects on any underlying tissue laminate structure, e.g., reductions in tensile strength.
Suitable nonionic surfactants may be substantially nonmigratory after the lotion composition is applied to the diaper topsheets and will typically have HLB values in the range of from about 4 to about 20, preferably from about 7 to about 20. To be nonmigratory, these nonionic surfactants wilt typically have melt temperatures greater than the temperatures commonly eared during storage; shipping, merd~andising, and use of disposable absorbent products, e.g., at least about 30'C tn this regard, these nonionic surfactants will preferably have making points similar to those of the immobilizing agent: previously described.
Suitable nonionic surfactants for use in lotion compositions of the present invention inducts alkylgtycosides; alkylglycoside ethers as described in U.S. patent 4,011,389 (Langdon. et al), issued March 8, 1977;
alkyipolyethoxylated estsn such as Pegospsrse 1000MS (available from Lonza, Inc.. Fair Lawn, New Jersey), ethoxylsted :orbitan mono-, di- andlor tri-sstlrs of C12-C18 fatty acids having an average degree of ethoxylation of from about 2 to shout 20, preferably from about 2 to about 10, such as TWEEN*60 (:orbitan esters of stsaric acid having an average degree of ethoxylation of about 20) and TWEEN 81 (sorbitan esters of stearic acid t~tvnnp an avtrage degree of ethoxytation of shout 4), and the condensation prodaras d aliphstic sloohols with from shout 1 to about 54 moles of ~yler~ oxide. The slkyl ch~sin of the aliphatic alcohol is typically in a straight chsin (linear) oonfigurstion and contains from about 8 to about 22 carbon atoms. Particularly pnfetred an the sation products of aloohola having an alkyl group containing from about 11 to about 22 carbon stoma with from about 2 to about 30 moles of ethylene oxide per mole of alcohol, Examples of such ethoxylated alcohols indude the condensation . products of myristyl alcohol with 7 moles of ethylene oxide per mole of alcohol, the c~dsnsation products of donut alcohol (a mixture of fatty * = Trade-mark WO 9b116682 PCfNS95/13809 alcohols having alkyl chains varying in length from 10 to 14 carbon atoms) with about fi moles of ethylene oxide. A number of suitable ethoxylated alcohols are commercially available, including TERGITOL~ 15-S-9 (the condensation product of C11-C15 linear alcohois with 9 moles of ethylene oxide), marketed by Union Carbide Corporation; KYRO E08*(condensation product of C13-C15 linear alcohols with S moles of ethylene oxide), marketed by The Procter 8 Gamble Co., the NEODOL* brand name surfactants marketed by Shall Chemical Co., in particular NEODOL 25-12 (condensation product of C12-C15 linear afcohols with 12 males of ethylene oxide) and NEODOt 23-6.5T (condensation product of C12-C13 linear akx~hols with 6.5 moles of ethylene oxide that has been distil *ed (topped) to remove certain impurities), and especially the PLURAFAC brand name surfactants marketed Dy BASF Corp., in particular PLURAFAC A-38 (a condensation product of a C 18 straight chain alcohol with 27 moles ~ot ethylene oxide). (Certain of the hydrophilic surfactants, in particular ethoxylated slcohois such ss NEODOL 25-12, can also function as alkyl ethoxylats emollients). Other examples of preferred sthoxylated alcohol swfadsnts include ICPa Gass of 8rij surfactants and mixtures thereof, with 8rij 72 (i.e., Stearoth-2) and 8rij*76 ( i.e., Stearoth-10) being especially preferred. Also, mixtixes of cety! alcohol and stearyf alcohol ethoxylated to an average degree .of ethox)rlation of from about 10 to about 20 may also be used as the hydrophilic surfactant.
Another type al auitsbie surface for use in the present invention includes Aerosol OT, a dioctyl ester of sodium sutfosuocinic acid marketed by Art>.rian Cyanamid Company.
Still anot~r type of suitable surfa~t for use in the present irnrenbon includes silicone copolymers such as General Electric SF 1188 (a of s potydimethylsitoxane and a polyoxyslkylene ether) and General Electric SF 1228 (a siliaor» polyether copolymer). These silicone surfaasrns can be used in combination with the other types of hydrophilic surtaaaras disarssed above, such as the ~d slcotlols. These silicone surfactants haw bran found ~ ~ ~~w at concsnVations as low as 0.19, more preferably from about 0,25 to about 1.0%, by weight of the lotion sition.
3S The amount of hydrophilic surfactant . required to increase the wettabiiity of the lotion composition to a desired level will depend upon the = Trade-mark HLB value and level of immobilizing agent used, the HLB value of the surfactant used and like factors. The lotion composition can comprise from about 1 to about 50°~ of the hydrophilic surfactant when needed to increase the wettability properties of the composition. Preferably, the lotion composition comprises from about 1 to about 25%, most preferably from about 10 to about 20°r6, of the hydrophilic surfactant when needed to increase wettability.
4. Other Optional Components Lotion compositions can comprise other optional components typically present in emollient, creams, and lotions of this type. These optional components include water, viscosity modifiers, perfumes, disinfectant antibacterial actives, pharmaceutical actives, film formers, deodorants, opacifiers, astringents, solvents and the like. In addition, stabilizers can be added to enhance the shelf life of the lotion composition such as cellulose derivatives, proteins and lecithin. All of these materials are well known in the art as additives for such formulations and can be employed in appropriate amounts in the lotion compositions of the present invention.
C. Treating Diaper Toosheets With Lotion Composition In preparing lotioned diaper products according to the present invention, the lotion composition is applied to the outer surface (i.e., body facing surface) of a diaper topsheet. Any of a variety of application methods that evenly distribute lubricious materials having a molten or liquid consistency can be used. Suitable methods include spraying, printing (e.g., flexographic printing), coating (e.g., gravure coating), extrusion, or combinations of these application techniques, e.g. spraying the lotion composition on a rotating surface, such as a calender roll, that then transfers the composition to the outer surface of the diaper topsheet.
The manner of applying the lotion composition to the diaper topsheet should be such that the topsheet does not become saturated with the lotion composition. tf the topsheet becomes saturated with the lotion composition, there is a greater potential for the lotion to block the topsheet openings, reducing the ability of the topsheet to transmit fluid to the underlying absorbent core. Also, saturation of the topsheet is not required to obtain the therapeutic and/or protective lotion benefits. Particularly suitable application methods will apply the lotion composition primarily to the outer surface of the diaper topsheet.
The minimum level of lotion to be applied to the diaper topsheets is 5 an amount effective for reducing the adherence of BM to the skin of the wearer. The lotion composition is preferably applied to the diaper topsheets of the present invention in an amount ranging from about 0.1 mg/in2 to about 25 mg/in2 more preferably from about 1 mg/in2 to about 10 mg/in2 (mg of lotion per square inch of coated topsheet). Because the 10 emollient is substantially immobilized on the surface of the topsheet, less lotion composition is needed to impart the desired skin care benefits. Such relatively low levels of lotion composition are adequate to impart the desired therapeutic and/or protective lotion benefits to the topsheet, yet do not saturate the topsheet's absorbency and/or wettability properties.
15 The lotion composition may be applied to the entire surface of the topsheet or portions thereof. Preferably, the lotion composition is applied in a stripe aligned with and centered on the longitudinal centerline of the disposable absorbent article. Most preferably, as described in the Examples hereinafter, the lotion composition is applied to a discrete version 20 of the topsheet, e.g., a 3.75 inch wide (diaper lateral direction) and 7 inch long (diaper longitudinal direction) patch generally disposed toward the second waist region.
The lotion composition can also be applied nonuniformly to the outer surface of the diaper topsheet. By "nonuniform" is meant that the amount, 25 pattern of distribution, etc. of the lotion composition can vary over the topsheet surface. For example, some portions of the treated surface of the topst~eet can have greater or lesser amounts of lotion composition, including portions of the surface that do not have any lotion composition on it.
The lotion composition can be applied to the topsheet at any point 30 during assembly. For example, the lotion composition can be applied to the topsheet of the finished disposable absorbent product before it has been packaged. The lotion composition can also be applied to the topsheet before it is combined with the other raw materials to form a finished disposable absorbent product.
WO 96!16682 PCT/US95/13809 The lotion composition is typically applied from a melt thereof to the diaper topsheet. Since the lotion composition melts at significantly above ambient temperatures, it is usually applied as a heated coating to the topsheet. Typically, the lotion composition is heated to a temperature in the range from about 35° to about 100°C, preferably from 40°
to about 90°C, prior to being applied to the diaper topsheet. Once the melted lotion composition has been applied to the diaper topsheet, it is allowed to cool and solidify to form solidified coating or film on the surface of the topsheet.
Preferably, the application process is designed to aid in the cooling/set up of the lotion.
In applying lotion compositions of the present invention to diaper topsheets, spraying, gravure coating and extrusion coating methods are preferred. Figure 1 illustrates one such preferred method involving spraying of the coating on the diaper topsheet before the topsheet is assembled with the other raw materials into a finished product. Referring to Figure 1, a nonwoven topsheet web 1 is unwound from parent topsheet roll 2 (rotating in the direction indicated by arrow 2a) and advanced to spray station 6 where one side of the web is sprayed with a hot, molten (e.g., 65°C) lotion composition. After leaving spray station 6, nonwoven topsheet web 1 becomes a lotioned topsheet web indicated by 3. Lotioned topsheet web 3 is then advanced around turning roll 4 and turning roll 8, and then wound up on lotioned topsheet parent roll 10 (rotating in the direction indicated by arrow 10a).
Figure 2 illustrates an alternative preferred method involving continuous or intermittent spraying of the lotion composition on to a diaper topsheet during the converting operation. Referring to Figure 2, conveyor belt 1 advances in the direction shown by the arrows on turning rolls 3 and 4 and becomes returning conveyor belt 2. Conveyor belt 1 carries nonlotioned diaper 5 to spray station 6 where topsheet patch 7 is sprayed with a hot, molten (e.g., 65°C) lotion composition. After leaving spray station 6, nonlotioned diaper 5 becomes lotioned diaper 8 having a lotioned topsheet. The amount of lotion composition transferred to topsheet patch 7 is controlled by: (1 ) the rate at which the molten lotion composition is sprayed ftom spray station 6; andlor (2) the speed at which conveyor belt 1 travels under spray station 6.
W096I16681 cA o220502~ 2002-o5-os p~~7g95t13809 DIAPER TOPSHEETS A~C~II~tG TO THE PRESENT INV NTI(",~N
The following are specific illusVations of treating diaper topsheets 5 with lotion compositions in accordance with the present invention:
m I t A. Preparation of Lotion CQmoos--itions A water free lotion composition (Lotion A) is made by mixing the following melted (i.e., liquid) components together Mineral Oil 10 (Carnation White Mineral Oil, USP made by Witco Corp.), Cetearyl Alcohol (a mixed linear C ~ g-C ~ 8 primary alcohol made by the Procter 3 Gamble Company under the name TA-1618); Steareth-2 (Brij T2, a C~8 linear alcohol ethoxylate having an average degree of ethoxylation of 2, made by ICI America). The weight percentages of 15 these componsnta are shown in Table 1 below:
Compote Weigh %
Mineral Oil 50 Cetesryl Alcohol35 ~
Stear~th-2 15 8. narration of Lotioned Q_Zo_oshl t bV Hot Meit Soravina L.otiort Con~positior~ A is placed iMa s heated tank operating at ~ a Z0 temperahxe of 125'F. The co~osition is subseqwntly sprayed (using a Dynatec''E84B1T58 spray head, operating at a temperature of 185'F and an atomisation pressure of 2.40 paig) onto the topsheet of a diaper in s 3.T5 inch wide (diaper lateral direction) and T inch long (diaper longitudinal d~e~ia~) uea, the patch beginning 1 inch ZS forward of the lateral centerline and extending toward the rear of the per. Add-on level = 0.006 ~n2 (9.3 gtm2).
* = Trade-maxk Examale 2 The lotion composition A (prepared in accordance with the procedure in Example I) is subsequently sprayed onto the topsheet of a diaper in a 3.75 inch wide (diaper lateral direction) stripe centered on the longitudinal centerline and extending the entire length of the product.
Add-on level = 0.006 g/in2 (9.3 g/m2).
Example 3 The lotion composition A (prepared in accordance with the procedure in Example I) is subsequently sprayed onto the topsheet of a diaper in a 3.75 inch wide (diaper lateral direction) stripe centered on the longitudinal centerline and 7 inch long (diaper longitudinal direction) area, the patch beginning 1 inch forward of the lateral centerline arid extending toward the rear of the product. Add-on level = 0.003 g/in2 (4.65 glm2).
Example 4 A. Preparation of Lotion Compositions A water free lotion composition (Lotion B) is made by mixing the following melted (i.e., liquid) components together: Mineral Oil (Carnation White Mineral Oil, USP made by Witco Corp.), and Cetearyl Alcohol (a mixed linear C16-C18 primary alcohol made by the Procter 8 Gamble Company under the name TA-1618). The weight percentages of these components are shown in Table II
below:
Table II
Component Weight ~
Mineral Oil 65 Cetearyl Alcohol35 B. Preparation of Lotioned Tissue by Hot Melt Soravin4 Lotion Composition B is placed into a heated tank operating at a temperature of 125°F. The composition is subsequently sprayed (using a Dynatec E84B1758 spray head, operating at a temperature of 165°F and an atomization pressure of 2.40 psig) onto the topsheet of a diaper in a 3.75 inch wide (diaper lateral direction) and 7 inch long (diaper longitudinal direction) area, the patch beginning 1 inch forward of the lateral centerline and extending toward the rear of the product. Add-on level = 0.006 g/in2 (9.3 g/m2).
Example 5 A. Preparation of Lotion Composition A water free lotion composition (Lotion C) is made by mixing the following melted (i.e., liquid) components together: White Protopet~
1 S (white petrolatum made by Witco Corp.), Cetearyl Alcohol (a mixed linear C16-C1g primary alcohol made by the Procter ~ Gamble Company under the name TA-1618); Steareth-2 (Brij 762, a C18 linear alcohol ethoxylate having an average degree of ethoxylation of 2 made by ICI America). The weight percentages of these components are shown in Table I below:
A water free lotion composition (Lotion C) is made by mixing together the following melted (i.e., liquid) components in the weight percentages shown in the Table III below according to the procedure of Example 2:
Table III
Component Weight ~
WhiteProtopet~ 50 Cetearyl Alcohol35 Steareth-2 15 B. Preparation of Lotioned Tissue by Hot Melt Spravina Lotion Composition C is placed into a heated tank operating at a temperature of 125°F. The composition is subsequently sprayed (using a Dynatec E84B1758 spray head, operating at a temperature 5 of 165°F and an atomization pressure of 2.40 psig) onto the topsheet of a diaper in a 3.75 inch wide (diaper lateral direction) and 7 inch long (diaper longitudinal direction) area, the patch beginning 1 inch forward of the lateral centerline and extending toward the rear of the product. Add-on level = 0.006 glint (9.3 glm2).
Example 6 A. Preparation of Lotion Composition A water free lotion composition (Lotion D) is made by mixing the following melted (i.e., liquid) components together: White Protopet~
1 S (white petrolatum made by Witco Corp. ); Dow Coming 556 Cosmetic Grade Fluid(a polyphenylmethylsiloxane made by the Dow Coming Corporation), An example of a particularly preferred paraffin wax is Parrafin S.P. 434 (a paraffin wax made by Strahl and Pitsch Inc.); Cetearyl Alcohol (a mixed linear C16-C1g primary alcohol made by the Procter ~ Gamble Company under the name TA-1618);
PEG 2000 ( a polyethylene glycol having a MW of 2000 made by Sigma-Aldrich Corp). The weight percentages of these components are shown in Table IV below:
Table IV
Component Weight ~
WhiteProtopet~ 52 Polyphenyimethyl- 20 siloxane Paraffin Wax 15 Cetearyl Alcohol 10 WO 96!16682 PCT/US95/13809 B. Preparation of Lotioned Tissue by Hot Melt SDrayinQ
Lotion Composition D is placed into a heated tank operating at a temperature of 150°F. The composition is subsequently sprayed (using a Dynatec E84B1758 spray head, operating at a temperature of 170°F and an atomization pressure of 2.40 psig) onto the topsheet of a diaper in a 3.75 inch wide (diaper lateral direction) and 7 inch long (diaper longitudinal direction) area, the patch beginning 1 inch forward of the lateral centerline and extending toward the rear of the product. Add-on level = 0.006 glint (9.3 g/m2).
Claims (44)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A disposable absorbent article comprising:
A) a liquid impervious backsheet;
B) a liquid pervious topsheet; and C) an absorbent core positioned between the topsheet and the backsheet, wherein at least a portion of the topsheet has applied thereto an effective amount of a lotion composition which is partially transferable to the wearer's skin, the lotion composition comprising:
(i) from about 10 to about 95% of a substantially water free emollient having a plastic or fluid consistency at 20°C, wherein the emollient is selected from the group consisting of petroleum-based emollients, fatty acid ester emollients, alkyl ethoxylate emollients, fatty acid ester ethoxylates emollients, fatty alcohol emollients, polysiloxane emollients, and mixtures thereof; and (ii) from about 5 to about 90% of an immobilizing agent capable of immobilizing the emollient on the topsheet, the immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°C, wherein the immobilizing agent is selected from the group consisting of polyhydroxy fatty acid esters, polyhydroxy fatty acid amides, C14-C22 fatty alcohols, C12-C22 fatty acids, C12-C22 fatty alcohol ethoxylates, waxes, and mixtures thereof.
A) a liquid impervious backsheet;
B) a liquid pervious topsheet; and C) an absorbent core positioned between the topsheet and the backsheet, wherein at least a portion of the topsheet has applied thereto an effective amount of a lotion composition which is partially transferable to the wearer's skin, the lotion composition comprising:
(i) from about 10 to about 95% of a substantially water free emollient having a plastic or fluid consistency at 20°C, wherein the emollient is selected from the group consisting of petroleum-based emollients, fatty acid ester emollients, alkyl ethoxylate emollients, fatty acid ester ethoxylates emollients, fatty alcohol emollients, polysiloxane emollients, and mixtures thereof; and (ii) from about 5 to about 90% of an immobilizing agent capable of immobilizing the emollient on the topsheet, the immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°C, wherein the immobilizing agent is selected from the group consisting of polyhydroxy fatty acid esters, polyhydroxy fatty acid amides, C14-C22 fatty alcohols, C12-C22 fatty acids, C12-C22 fatty alcohol ethoxylates, waxes, and mixtures thereof.
2. The disposable absorbent article of Claim 1 wherein the emollient contains a bout 5% or less water.
3. The disposable absorbent article of Claim 1 wherein the emollient comprises a petroleum-based emollient comprising a mixture of hydrocarbons with chain length from 16 to 32 carbon atoms, selected from the group consisting of mineral oil, petrolatum, and mixtures thereof.
4. The disposable absorbent article of Claim 1 wherein the emollient comprises a fatty acid ester emollient selected from the group consisting of methyl palmitate, methyl stearate, isopropyl laurate, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, lauryl lactate and cetyl lactate, and mixtures thereof.
5. The disposable absorbent article of Claim 1 wherein the emollient comprises an alkyl ethoxylate emollient selected from the group consisting of C12-C18 fatty alcohol ethoxylate having an average degree of ethoxylation ranging from about 2 to about 30.
6. The disposable absorbent article of Claim 1 wherein the lotion composition comprises from about 5 to about 50% of the immobilizing agent, the immobilizing agent having a melting point of at least about 40°C.
7. The disposable absorbent article of Claim 6 wherein the immobilizing agent comprises a C14-C22 fatty alcohol.
8. The disposable absorbent article of Claim 7 wherein the immobilizing agent comprises a C16-C18 fatty alcohol selected from the group consisting of cetyl alcohol, stearyl alcohol, and mixtures thereof.
9. The disposable absorbent article of Claim 6 wherein the immobilizing agent comprises a polyhydroxy fatty acid ester having the formula:
wherein R is a C5-C31 hydrocarbyl group; Y is a polyhydroxyhydrocarbyl moiety having a hydrocarbyl chain with at least 2 free hydroxyls directly connected to the chain; and n is at least 1.
wherein R is a C5-C31 hydrocarbyl group; Y is a polyhydroxyhydrocarbyl moiety having a hydrocarbyl chain with at least 2 free hydroxyls directly connected to the chain; and n is at least 1.
10. The disposable absorbent article of Claim 9 wherein the immobilizing agent comprises a polyhydroxy fatty acid ester selected from the group consisting of sorbitan ester of C16-C22 saturated fatty acid, glyceryl monoester of C16-C22 saturated fatty acid, and sucrose ester of C12-C22 saturated fatty acid,
11. The disposable absorbent article of Claim 10 wherein the immobilizing agent comprises a polyhydroxy fatty acid ester selected from the group consisting of sorbitan palmitate, sorbitan stearate, sorbitan behenate, glyceryl monostearate, glyceryl monopalmitate, glyceryl monobehenate, sucrose mono- and di-stearate, and sucrose mono- and di-laurate.
12. The disposable absorbent article of Claim 11 wherein the immobilizing agent comprises sorbitan stearate.
13. The disposable absorbent article of Claim 6 wherein the immobilizing agent comprises a polyhydroxy fatty acid amide having the formula:
wherein R1 is H, C1-C4 hydrocarbyl, 2-hydroxyethyl, 2-hydroxypropyl, methoxyethyl, methoxypropyl or a mixture thereof; R2 is a C5-C31 hydrocarbyl group; and Z is a polyhydroxyhydrocarbyl moiety having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain.
wherein R1 is H, C1-C4 hydrocarbyl, 2-hydroxyethyl, 2-hydroxypropyl, methoxyethyl, methoxypropyl or a mixture thereof; R2 is a C5-C31 hydrocarbyl group; and Z is a polyhydroxyhydrocarbyl moiety having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain.
14. The disposable absorbent article of Claim 13 wherein R1 is N-methyl, N-ethyl, N-propyl, N-isopropyl, N-butyl, N-2-hydroxyethyl, N-methoxypropyl or N-2-hydroxypropyl; R2 is straight chain C11-C17 alkyl or alkenyl, or mixture thereof; and Z is glycityl.
15. The disposable absorbent article of Claim 13 wherein the immobilizing agent comprises a polyhydroxy fatty acid amide selected from the group consisting of N-lauryl-N-methyl glucamide, N-lauryl-N-methoxypropyl glucamide, N-cocoyl-N-methyl glucamide, N-cocoyl-N-methoxypropyl glucamide, N-palmityl-N-methoxypropyl glucamide, N-tallowyl-N-methyl glucamide, and N-tallowyl-N-methoxypropyl glucamide.
16. The disposable absorbent article of Claim 6 wherein the immobilizing agent comprises a material selected from the group consisting of carnuba wax, beeswax, candelilla wax, paraffin wax, ceresin wax, esparto, ouricuri, rezowax; and mixtures thereof:
17. The disposable absorbent article of Claim 6 wherein said immobilizing agent comprises a fatty acid selected from the group consisting of palmitic acid, stearic acid, and mixtures thereof.
18. The disposable absorbent article of Claim 1 wherein the lotion composition further comprises fiom about 1 to about 50% of a hydrophilic surfactant, the hydrophilic surfactant having an HLB value of at least about 4.
19. The disposable absorbent article of Claim 18 wherein the hydrophilic surfactant is nonionic and has an HLB value of from about 4 to about 20.
20. The disposable absorbent article of Claim 19 wherein the hydrophilic surfactant comprises an ethoxylated alcohol having an alkyl chain of from about 8 to about 22 carbon atoms and having an average degree of ethoxylation ranging from about 1 to about 54.
21. The disposable absorbent article of Claim 20 wherein the ethoxylated alcohol has an alkyl chain of from about 11 to about 22 carbon atoms and having an average degree of ethoxylation ranging from about 2 to about 30.
22. The disposable absorbent article of Claim 18 wherein the hydrophilic surfactant comprises an ethoxylated sorbitan ester of a C12-C18 fatty acid having an average degree of ethoxylation of from about 2 to about 20.
23. The absorbent article of Claim 1 wherein said emollient further comprises up to about 10% of the total emollient of an emollient selected from the group consisting of polypropylene glycol, glycerine, triethylene glycol, spermaceti or other waxes, fatty acids, fatty alcohol ethers having from 12 to 28 carbon atoms in the fatty chain, fatty esters of polyhydroxy alcohols, lanolin and its derivatives, and mixtures thereof.
24. The absorbent article of Claim 1 wherein said lotion composition further comprises a stabilizer selected from the group consisting of a cellulose derivative, protein, lecithin, and mixtures thereof.
25. The absorbent article of Claim 1 wherein said lotion composition further comprises at least one material selected from the group consisting of water, viscosity modifier, perfume, disinfectant, antibacterial active, pharmaceutical active, film former, deodorant, opacifier, astringent, solvent, and mixtures thereof.
26. The disposable absorbent article of Claim 1 wherein the quantity of lotion composition on the topsheet ranges from about 0.1 mg/in2 to about 25 mg/in2.
27. The disposable absorbent article of Claim 26 wherein the quantity of lotion composition on the topsheet ranges from about 1 mg/in2 to about 10 mg/in2.
28. The disposable absorbent article of Claim 1 wherein the lotion coating is applied non-uniformly to the topsheet.
29. The disposable absorbent article of Claim 28 wherein the lotion is applied in a stripe aligned with and centered on the longitudinal centerline of the disposable absorbent article.
30. The disposable absorbent article of Claim 28 wherein the lotion has been applied on some portions of the topsheet, and the other portions have no lotion applied.
31. The disposable absorbent article of Claim 1 wherein the absorbent article is a diaper, an incontinence article, a diaper holder, or a training pant.
32. The disposable absorbent article of Claim 1 wherein the absorbent article is a sanitary napkin, or a pantiliner.
33. A disposable absorbent article comprising:
A) a liquid impervious backsheet;
B) a liquid pervious topsheet; and C) an absorbent core positioned between the topsheet and the backsheet, wherein at least a portion of the topsheet comprises an effective amount of a lotion composition comprising a substantially water free emollient having a plastic or fluid consistency at 20°C and an immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°C, and wherein the lotion composition is applied in a non-uniform pattern to the topsheet.
A) a liquid impervious backsheet;
B) a liquid pervious topsheet; and C) an absorbent core positioned between the topsheet and the backsheet, wherein at least a portion of the topsheet comprises an effective amount of a lotion composition comprising a substantially water free emollient having a plastic or fluid consistency at 20°C and an immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°C, and wherein the lotion composition is applied in a non-uniform pattern to the topsheet.
34. The disposable absorbent article of Claim 33 wherein the lotion composition is applied on some portions of the topsheet, and the other portions have no lotion applied.
35. The disposable absorbent article of Claim 33 wherein the lotion is applied in a stripe aligned with and centered on the longitudinal centerline of the disposable absorbent article.
36. The disposable absorbent article of Claim 33 wherein the emollient is selected from the group consisting of petroleum-based emollient, fatty acid ester emollient, alkyl ethoxylate emollient, fatty acid ester ethoxylate emollient, fatty alcohol emollient, polysiloxane emollient, and mixtures thereof.
37. The disposable absorbent article of Claim 36 wherein the emollient contains about 5% or less water.
38. The disposable absorbent article of Claim 35 wherein the quantity of lotion composition on the topsheet ranges from about 0.1 mg/in2 to about 25 mg/in2.
39. A method for making an absorbent article having a lotion composition disposed on at least a portion of a topsheet, wherein the method comprising the steps of:
(1) providing a topsheet; and (2) applying a lotion composition to the topsheet, the lotion composition comprising:
(i) from about 10 to about 95% of a substantially water free emollient having a plastic or fluid consistency at 20°C, wherein the emollient is selected from the group consisting of petroleum-based emollient, fatty acid ester emollient, alkyl ethoxylate emollient, fatty acid ester ethoxylate emollient, fatty alcohol emollient, polysiloxane emollient, and mixtures thereof;
(ii) from about 5 to about 90% of an agent capable of immobilizing the emollient on the topsheet, the immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°C, wherein the immobilizing agent is selected from the group consisting of wax, polyhydroxy fatty acid ester, polyhydroxy fatty acid amide, C14-C22 fatty alcohol, C12-C22 fatty acid, C12-C22 fatty alcohol ethoxylate having an average degree of ethoxylation of about 2 to about 30, and mixtures thereof.
(1) providing a topsheet; and (2) applying a lotion composition to the topsheet, the lotion composition comprising:
(i) from about 10 to about 95% of a substantially water free emollient having a plastic or fluid consistency at 20°C, wherein the emollient is selected from the group consisting of petroleum-based emollient, fatty acid ester emollient, alkyl ethoxylate emollient, fatty acid ester ethoxylate emollient, fatty alcohol emollient, polysiloxane emollient, and mixtures thereof;
(ii) from about 5 to about 90% of an agent capable of immobilizing the emollient on the topsheet, the immobilizing agent being miscible with the emollient, the immobilizing agent having a melting point of at least 35°C, wherein the immobilizing agent is selected from the group consisting of wax, polyhydroxy fatty acid ester, polyhydroxy fatty acid amide, C14-C22 fatty alcohol, C12-C22 fatty acid, C12-C22 fatty alcohol ethoxylate having an average degree of ethoxylation of about 2 to about 30, and mixtures thereof.
40. The method of Claim 39 wherein the method is selected from the group consisting of spraying, printing, coating, extruding, or a combination thereof.
41. The method of Claim 40 wherein the application step is extruding.
42. The method of Claim 39 wherein the lotion composition is at least semi-solid when applied to the topsheet.
43. The method of Claim 42 further comprising the step of cooling the lotion composition to a temperature sufficiently low such that the lotion composition solidifies.
44. The method of Claim 43 wherein the immobilizing agent crystallizes upon cooling.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/345,159 US5643588A (en) | 1994-11-28 | 1994-11-28 | Diaper having a lotioned topsheet |
US08/345,159 | 1994-11-28 | ||
PCT/US1995/013809 WO1996016682A1 (en) | 1994-11-28 | 1995-10-26 | Diaper having a lotioned topsheet |
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CA2205027A1 CA2205027A1 (en) | 1996-06-06 |
CA2205027C true CA2205027C (en) | 2003-12-23 |
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Application Number | Title | Priority Date | Filing Date |
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CA002205027A Expired - Lifetime CA2205027C (en) | 1994-11-28 | 1995-10-26 | Diaper having a lotioned topsheet |
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US (7) | US5643588A (en) |
EP (1) | EP0794804B1 (en) |
JP (7) | JP3222470B2 (en) |
CN (1) | CN1127987C (en) |
AR (1) | AR000203A1 (en) |
AU (1) | AU4135496A (en) |
BR (1) | BR9509774A (en) |
CA (1) | CA2205027C (en) |
CZ (1) | CZ297874B6 (en) |
DE (1) | DE69524630T2 (en) |
ES (1) | ES2164783T3 (en) |
FI (1) | FI972237A0 (en) |
HK (1) | HK1005654A1 (en) |
HU (1) | HU226312B1 (en) |
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SA (1) | SA96160533B1 (en) |
TR (1) | TR199501494A2 (en) |
TW (1) | TW299226B (en) |
WO (1) | WO1996016682A1 (en) |
ZA (1) | ZA9510061B (en) |
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-
1994
- 1994-11-28 US US08/345,159 patent/US5643588A/en not_active Expired - Lifetime
-
1995
- 1995-10-26 CZ CZ0161197A patent/CZ297874B6/en not_active IP Right Cessation
- 1995-10-26 BR BR9509774A patent/BR9509774A/en not_active IP Right Cessation
- 1995-10-26 CA CA002205027A patent/CA2205027C/en not_active Expired - Lifetime
- 1995-10-26 DE DE69524630T patent/DE69524630T2/en not_active Revoked
- 1995-10-26 WO PCT/US1995/013809 patent/WO1996016682A1/en not_active Application Discontinuation
- 1995-10-26 CN CN95196627A patent/CN1127987C/en not_active Expired - Lifetime
- 1995-10-26 AU AU41354/96A patent/AU4135496A/en not_active Abandoned
- 1995-10-26 JP JP51877696A patent/JP3222470B2/en not_active Expired - Lifetime
- 1995-10-26 ES ES95939598T patent/ES2164783T3/en not_active Expired - Lifetime
- 1995-10-26 MX MX9703881A patent/MX9703881A/en unknown
- 1995-10-26 EP EP95939598A patent/EP0794804B1/en not_active Revoked
- 1995-10-26 HU HU9800546A patent/HU226312B1/en not_active IP Right Cessation
- 1995-11-10 MY MYPI95003418A patent/MY114905A/en unknown
- 1995-11-16 TW TW084112157A patent/TW299226B/zh active
- 1995-11-24 AR AR33438295A patent/AR000203A1/en unknown
- 1995-11-27 ZA ZA9510061A patent/ZA9510061B/en unknown
- 1995-11-27 PE PE1995285720A patent/PE1897A1/en not_active Application Discontinuation
- 1995-11-27 TR TR95/01494A patent/TR199501494A2/en unknown
-
1996
- 1996-01-16 SA SA96160533A patent/SA96160533B1/en unknown
-
1997
- 1997-05-26 NO NO972394A patent/NO972394L/en unknown
- 1997-05-27 FI FI972237A patent/FI972237A0/en unknown
- 1997-06-27 US US08/884,575 patent/US5968025A/en not_active Expired - Lifetime
- 1997-06-27 US US08/884,069 patent/US6118041A/en not_active Expired - Lifetime
-
1998
- 1998-03-17 HK HK98102242A patent/HK1005654A1/en not_active IP Right Cessation
-
1999
- 1999-06-24 US US09/339,144 patent/US6586652B1/en not_active Expired - Fee Related
- 1999-07-20 US US09/358,007 patent/US6627787B1/en not_active Expired - Fee Related
-
2001
- 2001-05-28 JP JP2001158986A patent/JP4083395B2/en not_active Expired - Lifetime
-
2003
- 2003-03-12 US US10/386,959 patent/US6825393B2/en not_active Expired - Fee Related
-
2004
- 2004-06-07 JP JP2004168848A patent/JP4255883B2/en not_active Expired - Lifetime
-
2007
- 2007-06-25 US US11/821,612 patent/US20080249491A1/en not_active Abandoned
-
2008
- 2008-12-05 JP JP2008310942A patent/JP2009137964A/en active Pending
-
2009
- 2009-12-21 JP JP2009289641A patent/JP2010063921A/en active Pending
- 2009-12-21 JP JP2009289666A patent/JP2010075733A/en active Pending
- 2009-12-21 JP JP2009289656A patent/JP2010075732A/en not_active Withdrawn
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