CA2200759A1 - Polymers useful as ph responsive thickeners and monomers therefor - Google Patents

Polymers useful as ph responsive thickeners and monomers therefor

Info

Publication number
CA2200759A1
CA2200759A1 CA002200759A CA2200759A CA2200759A1 CA 2200759 A1 CA2200759 A1 CA 2200759A1 CA 002200759 A CA002200759 A CA 002200759A CA 2200759 A CA2200759 A CA 2200759A CA 2200759 A1 CA2200759 A1 CA 2200759A1
Authority
CA
Canada
Prior art keywords
aqueous
weight percent
ethylenically unsaturated
nonionic
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002200759A
Other languages
French (fr)
Other versions
CA2200759C (en
Inventor
Fred Robinson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvay USA Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23232859&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2200759(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Individual filed Critical Individual
Publication of CA2200759A1 publication Critical patent/CA2200759A1/en
Application granted granted Critical
Publication of CA2200759C publication Critical patent/CA2200759C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F20/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
    • C08F220/302—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety and two or more oxygen atoms in the alcohol moiety
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/932—Thickener or dispersant for aqueous system

Abstract

Novel aqueous thickener or thixotropic polymers are prepared by the copolymerization of (A) about 15-60 weight percent of a C3-C8 alpha, beta-ethylenically unsaturated carboxylic acid monomer, preferably acrylic or methacrylic acid or a mixture thereof with itaconic or fumaric acid, (B) about 15-80 weight percent of a nonionic copolymerizable C2-C12 alpha, beta-ethylenically unsaturated monomer, preferably a monovinyl ester such as ethyl acrylate or a mixture thereof with styrene, acrylonitrile, vinyl chloride or vinyl acetate, and (C) about 1-30 weight percent of a new and novel nonionic ethylenically unsaturated nonionic biphillic monomer such as tristyrylpoly(ethyleneoxy)x methyl acrylate, to provide a stable aqueous colloidal dispersion at an acid pH lower than about 5.0 but becoming an effective thickener for aqueous systems upon adjustment to a pH of about 5.5-10.5 or higher. These polymers adjusted to a pH of about 5.5 or higher are effective thickeners for a wide variety of aqueous systems including cosmetic products, drilling muds, aqueous coating compositions such as latex paint, and high solids compositions such as spackle, grouts, cements, and the like.
CA002200759A 1994-10-03 1995-09-29 Polymers useful as ph responsive thickeners and monomers therefor Expired - Lifetime CA2200759C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US31726194A 1994-10-03 1994-10-03
US08/317,261 1994-10-03
PCT/US1995/012601 WO1996010602A1 (en) 1994-10-03 1995-09-29 POLYMERS USEFUL AS pH RESPONSIVE THICKENERS AND MONOMERS THEREFOR

Publications (2)

Publication Number Publication Date
CA2200759A1 true CA2200759A1 (en) 1996-04-11
CA2200759C CA2200759C (en) 2008-04-22

Family

ID=23232859

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002200759A Expired - Lifetime CA2200759C (en) 1994-10-03 1995-09-29 Polymers useful as ph responsive thickeners and monomers therefor

Country Status (12)

Country Link
US (2) US5874495A (en)
EP (1) EP0705854B2 (en)
JP (1) JP4290761B2 (en)
AT (1) ATE165104T1 (en)
CA (1) CA2200759C (en)
DE (1) DE69502067T3 (en)
DK (1) DK0705854T3 (en)
ES (1) ES2118514T3 (en)
FI (1) FI954670A (en)
NO (1) NO953911L (en)
WO (1) WO1996010602A1 (en)
ZA (1) ZA958224B (en)

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NO953911L (en) 1996-04-09
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DE69502067D1 (en) 1998-05-20
NO953911D0 (en) 1995-10-02
DK0705854T3 (en) 1998-11-09
WO1996010602A1 (en) 1996-04-11
DE69502067T2 (en) 1999-02-04
JP4290761B2 (en) 2009-07-08
JPH10509467A (en) 1998-09-14
US5770760A (en) 1998-06-23
ATE165104T1 (en) 1998-05-15
US5874495A (en) 1999-02-23
FI954670A (en) 1996-04-04
ES2118514T3 (en) 1998-09-16
ZA958224B (en) 1997-02-06
DE69502067T3 (en) 2012-05-31

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