CA2196164A1 - Syntactic foam sheet material - Google Patents

Syntactic foam sheet material

Info

Publication number
CA2196164A1
CA2196164A1 CA002196164A CA2196164A CA2196164A1 CA 2196164 A1 CA2196164 A1 CA 2196164A1 CA 002196164 A CA002196164 A CA 002196164A CA 2196164 A CA2196164 A CA 2196164A CA 2196164 A1 CA2196164 A1 CA 2196164A1
Authority
CA
Canada
Prior art keywords
microspheres
resin
layer
mixture
syntactic foam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002196164A
Other languages
French (fr)
Inventor
Charles L. Meteer
Thomas E. Philipps
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ISORCA Corp
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2196164A1 publication Critical patent/CA2196164A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/18Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/08Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
    • B29C70/086Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers and with one or more layers of pure plastics material, e.g. foam layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/58Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/58Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
    • B29C70/66Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres the filler comprising hollow constituents, e.g. syntactic foam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D99/00Subject matter not provided for in other groups of this subclass
    • B29D99/001Producing wall or panel-like structures, e.g. for hulls, fuselages, or buildings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/42Layered products comprising a layer of synthetic resin comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/04Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the partial melting of at least one layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/046Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0085Use of fibrous compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/32Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16Fillers
    • B29K2105/165Hollow fillers, e.g. microballoons or expanded particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/106Carbon fibres, e.g. graphite fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/30Fillers, e.g. particles, powders, beads, flakes, spheres, chips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/72Density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2315/00Other materials containing non-metallic inorganic compounds not provided for in groups B32B2311/00 - B32B2313/04
    • B32B2315/08Glass
    • B32B2315/085Glass fiber cloth or fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2361/00Phenoplast, aminoplast
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/06Molding microballoons and binder
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S264/00Plastic and nonmetallic article shaping or treating: processes
    • Y10S264/07Binding and molding cellular particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1043Subsequent to assembly
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249971Preformed hollow element-containing
    • Y10T428/249972Resin or rubber element
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249971Preformed hollow element-containing
    • Y10T428/249974Metal- or silicon-containing element
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component
    • Y10T428/249953Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249986Void-containing component contains also a solid fiber or solid particle
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/26Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/269Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/647Including a foamed layer or component
    • Y10T442/652Nonwoven fabric is coated, impregnated, or autogenously bonded
    • Y10T442/653Including particulate material other than fiber

Abstract

A syntactic structural foam product (10) in flat sheet form or curved three-dimensional form adaptable to such uses as a light weight structural core for composite laminates, is made of a mixture of hollow ceramic microspheres (11, 12) and dry resin powder (14), of either thermosetting or a high-temperature thermoplastic resin, distributed in the interstices of the mass of microspheres for integration of the mixture into desired form upon heating and cooling. Resin powder collected as a waste by-product from resin coating materials can be recycled in the production of the desired product. The foam product is produced by first intermixing the microspheres and powdered resin by physical agitation of the mixture and depositing the mixture as a layer over a surface having a release agent thereover within a dimension defining region between boundary members and then supplying heat with or without pressure to the layer at a temperature and for a time period sufficient to effect a melting of the resin powder and thereafter cooling the resin in a hardened condition to integrate the mixture into the product desired after which the product is withdrawn from the forming zone. Reinforcing elements such as glass or carbon fibers (15) can be selectively included in the mixture for predetermined desired physical and mechanical properties.

Description

~ WO96/04132 21 961 64 r~ s ~ ll SYNT~rTIC F~M S~T~TeT ~TT.~TT~T.

This invention i5 generally related to a syntacticfoam core material and a method of forming same, and, more particularly, to a syntactic foam core made of a mixture of hollow ceramic microspheres and a dry resin powder intermixed therewith. The hollow microspheres are =~
joined together by heating the mixture to integrate the combination as a foam core material usable for example as a core for composite laminates, having preselectable strength, density and weight properties engineered therein.
R1~rT~r.T OTr"-l Syntactic foam layers and products have been conventionally made by intermixing glass microspheres with a heated liquid binding resin, and at times including reinforcing elements such as fibers. The use of resin in a fluid state heated to effect a cure, however, results in a considerable release of fumes and liquid vapors which can interrupt or destroy the integrity of the material and often must be treated as enviL, ~lly objec~;~n~hl~
In contrast heat curing or setting of heated powdered resin in a mixture with microspheres results in little effluent of fumes or liquid vapor. In other words, phenolic resins, for example, during heating to a liquid phase and curing give off vapors in.a considerable amount whereas dry phenolic powders during heat curing give off little vapor. In addition, resin in a fluid condition is less adaptable to providing a syntactic foam microsphere~
mixture capable of the wide range of light densities, SlJBSrITUTE SHEET (RULE 261 W096/04132 2 1 9 6 1 6 4 ~ s ~

weights and strength properties possible by use of resin powder according to the present invention A number of product properties can be imparted to a product by use of a reactive resin in powdered form that cannot be ~comrl; Rh~ with resin in a liquid form. For example, the bulk density of powdered resin is much less than the bulk density of solid resin of the same composition or liquid formed of the resin by heating it to a melted condition. An important advantage of using powdered resin mixed with ceramic microspheres to form a syntactic foam layer according to the present invention is that the bulk density of the final product can be the same as that of the initial , , Ct~ mixture During heating of the mixture, the powdered resin is converted to melted droplets which can flow over and join the microspheres of the mixture sacs may be aided by an adhesion promoting coating, for example a coupling agent, on the microspherec.~ The mixture is thus in a sense coalesced into a mass which upon hardening provides a light weight solid foam layer. The foam layer includes closea voids ~nt~;n;ng evolved gas and air. The bulk density of syntactic foam material as in the present invention can be half that of a conventional material made from liquid resin with intermixed microspheres. Additionally, the present invention eliminates the problems of high viscosity when many microspheres are added to a liquid resin, and ~l~m;n~t~ the process problem of getting microspheres ~which tend to float) wetted out and incorporated into a liquid resin.

SUBSTITUTE SHEET (RULE 261 ~ WO96/04132 2 1 9 6 1 64 F~~ 5 ,,1l It has been found that finer powder resin~ function much more effectively to produce the desired results than coarse powders. When the powders included are too coarse, the melting and dispersion of the material between the microspheres become more difficult and are much less effective in providing a uniformly integrated syntactic foam product.
The mixture can be heated by a number of techniques including induction heating with high frequency energy or conductive heating such as with heated platens on opposite ma~or surfaces of the layer of microspheres and resin powder. During heating of a platen in contact with a layer of intermixed powdered resin and microspheres, a skin layer can be formed at the surfaces of the foam. To prevent the mixture from sticking to such platens a layer t of separator material, a material which will not bond or unite with the syntactic foam layer, is provided between each of the platen surfaces and the surfaces of the =
microsphere mixture.
When it is desired that the density of the product be greater than that attained with the pressureless application of heat, the mixture can be compacted by bringing the heating platens closer together to establish a predetermined th; ~kn~. The thickness can be es~hl; Chpd by placing spacer members of the prP~t~rm;n~
desired thickness between the platens which will limit the ~ closeness to which the platens can be moved and thereby establish the desired thickness of the product produced.
The spacers can also function to limit the area over which the microsphere-resin powder mixture can spread. In other ~-SUSSTITUTE SHEET IRULE 26) WO96104132 2 1 9 6 1 6 4 ~ , , S ~

words, they can be used to confine the area of the mixture, such as in a tray, to establish the predetermined dimensions o~ the product to be produced.
As described herein the invention is used to form a stratum or core for structural laminate panels, but variations of the mixture of glass microspheres and resin powder can be engineered for a wide range of products as well, such as flooring, ducts, and three dimensional products useable for aircraft, trucks, automobiles, ships, boats, industrial tanks and the like. The desired light weight and strength properties of the foam are attained in part by ~ ;7;ng microspheres or bubbles, preferably hollow ceramic microspheres such as of glass commercially available in various diameters and wall thicknesses. The microsphere diameters and wall thick~esses are selected to impart specific predeterminable shear and compression strengths as ~well as desired weights and densities when integrated with the resin intermixed therewith. The powdered resin ;nt~rm;~ with the microspheres or bubbles is o~ substantially finer ~;m~nq;~n than the bubbles thereby enabling thorough distribution of the powder and filling of the interstices between the bubbles.
The term ~cured" or "curing" as applied to thermosetting resin herein refers to heat processing to a fluid then tQ a more stable hardened or set condition, but to facilitate description of the invention also refers herein to hardening of thermoplastic resins to a set condition upon cooling after being heated to a fluid condition according to the concepts of the present invention.

SUBSTITUTE SHEEt (RULE 26)
2~ 961 64 ~ WO96/04132 P~~ S, The bubbles of the mass may be of different sizes which permits their close compaction into an intimate mass for strength, while the finer resin powder _ills the interstices more readily to effect an inter-bonding of the bubbles and resin. The amount of resin incorporated in the core can be just sufficient to effect the desired inter-bonded relation between rn~, nn~ntc of the mixture, which with a light concentration of the powder in the mixture can result in the cured syntactic layer being porous and permeable. More desirably, however, for most applications the concentration of powder in the mixture is such that the cured integrated mass is subst~nt;~11y impermeable to moisture beside having high shear and compression strengths.
The foam mixture can optionally include reinforcing elements such as glass or carbon fibers or fibers of other high strength material. In this regard the fibers may be incorporated in the mixture as individual fibers, as bundles of chopped strands, or as contiuuous fi1 ~ in nonwoven mats or woven fabrics. Other reinforcing elements such as honeycomb structures can also be incorporated in the core material as well.
An object of the invention is to provide a mixture of components for formation of a syntactic foam material capable of being engineered and ~nllf~t1lred economically into products having a wide range of predeterminable ~ structural properties.
Another more specific object of the invention is to provide a basic, easily processed, ec-- 'r~lly producible, light weight core material capable of SUBSTITUTE SHEET (RULE 26i providing structural properties in layer form adaptable to use in sandwich structure composites. A feature of the invention is that the ' ;n~t;on of powdered phenolic material and glass microspheres gives off little or no volatiles or fumes during cure.
Another important feature is that the mixture can, within a wide range, be pre=engineered for a desired density, shear strength, compression strength~ low fl h;l;ty and low smoke and high moisture resistance while at the same time being capable of production at a low cost.
A further feature is that a syntactic foam core layer for laminar structures can be produced with no r~..rt;r,n in thickness dimension of the layer during heat processing.
Strength and density of the sheet can be modified by appropriate selection of the size and wall thickness of commercially available microspheres and the size and type of powder resin particles The microspheres can be provided with_a coating of a coupling agent such as silane to facilitate their coverage and inter-bonding by the melted resin powder. As pointed out the resin powders are of finer size than the small microspheres and fit in the interstices o~ the mass of microspheres to effect an inter-bonding upon heating and hardening. As the amount of resin present increases as part of the mixture the greater the weight of the microsphere foam product becomes.
The process of producing the syntactic sheet or core material involves first combining the microspheres and SUBSrITUTE SHEET (RULE 2~

~ WO96/04132 2 1 9 6 1 6 4 r~ l "

powdered resin. The combination i8 preferably deposited as a layer on a base having a release agent or commercial release film over its surface to prevent bonding to the final foam product. The base also is provided with boundary means to define the dimensions of the product.
The , ;n~ti~n is first vibrated for thorough intermixture of the resin powder in the microsphere interstices, and the mixture is then heated to melt the resin particles for inter-bonding with the microspheres.
Although pressure is not necessary to effect the inter-bonding of microspheres and resin, pressure can be applied to the mixture as an assist in effecting its ccm?~t;~n when a more dense product is desired. Such compaction of the mixture can be effected by bringing the overlying and =
underlying heated platens to a preselected spacing for a desired thickness of the layer. The thickness of a given deposited layer as well as its density and mechanical properties of the final product can thus be predetermined.
As indicated, in addition to a mixture of microspheres and resin powder alone providing the base mixture for the product, structural reinforcement elements such as fibers (hollow or solid) or fiber bundles can also be selectively in~ Other reinf~l~ q for example can be mats of random reinforcing fibers or reinforcing fiber fabrics, both woven and non-woven, rods, glass flakes and honeycomb structures which in appropriate locations can improve mechanical properties such as shear strength and shear modulus of the sheet product.
Resin in powder form such as can be formed by grinding down solid resin, is selected for its f;n~n~cq to SUBSrlTlJTE SHEET (RU~E 26) W096/04132 2 1 q 6 1 64 .~ . "

fill the interstices of the microspheres which can be ac~ h~ more readily than with coarser powders. To provide the binding relation for integration of the mixture, the powders are also selected for their chemical reactivity and heat softenable adhesive affinity for the glass microspheres. They can also be selected for low flame and smoke properties. In this regard, the invention iB quite versatile in permitting trial and error establishment of the engineered properties desired.
The resulting syntactic foam product is corrosion resistant, electrically and thermally relatively non-conductive, non-magnetic, electromagnetically transparent, light weight, much less than the weight of steel, has high strength and dimensional stability, and is adaptable to providing a wide range of physical and ~ -h~nir~l properties.
Any of a number of reactive resin powders may be used to provide the specific desired properties inrln~;ng, but not limited to, phenolic resins af~L, ;onG~ as well as epoxy and epoxy-modified phenolic resin, polyester resin powders, polyurethane, and polyphenylene sulphide. In addition powder resin from waste dust collection devices, such as in a resin manufacturing plant, can be used ln the present invention. Disposal of these waste materials is particularly an environmental problem because they are most frequently reactive powders. The present invention is thus additionally advantageous in that it can frequently ~;min~t~ envi.~ ~- problems by providing a value-added use for waste materials.

SUBSrlTUrE SHEET (~ULE 261 2196164 ~T/U~ 95/09977 ~ iPEA/US 2 9 FEB 1996 E~RT~ DE~.q('RTPTI(')N OE TM~ l~Rl~WTN~
Figure 1 is a broken away perspective view of a rigid syntactic foam core made according to the concepts of the present invention;
Figure 2A is an illustration representative of a magnified broken away view of a portion of the product of Figure 1 as taken on line 2-2 illustrating a mixture of ~ =
hollow microspheres of different sizes and cured resin powder intermixed therewith;
Figure 2B is an illustration representative of a magnified broken away view of a product like that of Figure 2A including bundles of reinforcing fibers;
Figure 3 is a representation of a layer of the :~
mixture of the invention i~ a vibrating tray;
Figure 4 is a schematic illustration of a layer of=
syntactic core material of the present invention in a press for heat cure and ~elective pressurization of the material of the present invention to an integrated condition;
Figure 5 is a schematic perspective view of a laminate product having top and bottom surface layers shown with an inbetween core layer of syntactic foam material of the present invention;
Figure 6 is a schematic illustration of a laminate including a core material of the pre~ent invention faced with opposite surface layers in a press in which the assembly can be heat cured and selectively~ pressurized to an integrated condition;
Figure 7 is a broken away perspective view of syntactic core material of the present invention including ~:

4MENDED SHE~I

2 1 ~6 1 64 ~ W09~4132 P~

11~
reinforcing elements in the form of fiber bundles distributed through the resin-microsphere structure; and Figure 8 is a schematic illustration of a portion of a ~nntinnmlc production line for producing a syntactic foam material according to the principles of the present invention.
DET~TT.T.'n L~ vL~
The beginning material of this invention is a particle mixture of hollow ceramic microspheres, preferably of glass, which are frequently referred to conv~n~inn~lly as bubbles, and resin powder of diameter finer than the microspheres which is heat softenable and curable or hardenable to effect inter-bonding of the mass into an integrated form. The beginning mixture may also include reinforcing elements such as chopped strands forming dispersed bundles of reinforcing fibers such as of glass or carbon. By way of example the powdered resin can be a thermosetting resin powder such as phenolic powders or powders of a high temperature thermoplastic resin such as polyphenylene sulfide reactor powder so that upon the mixture being heated, the mass of resin powders will soften and flow to effect the desired inter-bonding of the particles of the mass.
A coating of an adhesion promoting material can be provided on the microspheres, such as a silane coating, to facilitate wet out of the microspheres which results in better ~hGc;~n Alternately an adhesion ~n~n~ing material and the resin powder or a catalyst might be ;nnl~ in a thermosetting powdered resin. For example, when the resin is a phenolic resin a catalyst such as SUBSTITUlE SHEET ~RULE 261 ~ W096/04132 P~

hexamethylenetetramine can be ; nrl n~ which can be cured in an oven at a temperature in the order of 350 degrees F.
The resin powder can be present in the mass of microspheres in an amount just adequate to effect the desired inter-bonding but at the high end of the volume spectrum can be present in an amount more than that which is adequate to fill interstices in the microsphere mass to form a solid integrated material of the mass. A range of densities of the microsphere mixture can thus be provided d~ d~llL upon the amount of resin incorporated therein.
An important aspect to understanding the principles of the present invention is that when hollow microspheres of given uniform size are perfectly packed, resulting in a minimum of void space between microspheres, it has been determined that the theoretically minimum amount of void space is about 26% of the total volume. Another important aspect is that powdered resin will ~;m;n;ch in volume when heated to a melted condition. The bulk volume of the melted resin will ~;m;n; ch in practice to about 35-50% of the bulk volume of the powder. Accordingly when microspheres are closely packed with the voids therebetween being filled with fine resin powder, heating of the mixture to melt the resin powder results in the resin ~Im;n;.ah;nr in volume to lts liquid state and leaving voids r~n~;n;nr air and some gas vapors given off from the resin during melting. The amount of void space is generally about half the volume of resin powder originally added to the mixture.
The melted resin flows over the surface of the microspheres into their points of close proximity so that SUSSTITUTE SHEET (RIJLE 261 WO96104132 2 1 q 6 1 6 4 P~

upon ~nl;~ifi~t;~n the microspheres are solidly fused together leaving a generally predet~rm;n~ amount of void space inbetween. Thus a syntactic foam product o~ ~
predet~rmin~hle density can be produced. In this regard, if the volume of resin powder is less than or just fills the interstices of the layer of miuLu~he~s, the density of the mass can be ~';nt~;n~ ~ixed throughout the heat processing to the final product.
If the amount of powdered resin addea to the hollow microsphere mass fills the entire void space between the microspheres in its dry unheated state, after melting of the powder voids between microspheres will still result because of the lower bulk density of the powder resin. By way of example, if the amount of resin powder by bulk volume is about 26~, upon contraction to a melted state, in a perfectly packed mass, an internal void space of about 13 to 17~ in the final product results.
If on the other hand the amount of powdered resin originally added to the mixture is less than about 26~ for a theoretically perfectly packed mass of microspheres, such amount being just adequate to effect coverage and joinder of the microspheres, the void space " ;~;n~
would be greater than 17~ and result in a still lighter density syntactic foam.
Inter-bonding of particles can be effected by mere deposition of the mixture lightly packed as a layer without application of pressure and mere supply of curing heat thereto such as by contact of a hot platen surface to one side thereof. I~ has been found desirable, however, to selectively apply pressure for compaction of the mass SU~STITUTE SHEET (RULE 261 J a, fJ 7 l - 2 1 9 61 6 4 IP~A/~ 2 9 ~3 l99~

mixture to provide a desired density and thickness in the final product. It will be understood 'hat although the product as herein described is a planar core material for sandwich structure laminates, the concept of the invention lends itselE to forming layers of different thicknesses in different regions as well as to form products of three dimensional shapes such as by deposition on a curved surface or in an intricately shaped mold type heating unit with or without the pre~ence of surface layers of a laminate product.
Figure 1 shows a rigid heat cured syntactic foam sheet 10 formed of microspheres and resin to which surface skins or surface panel layers can be supplied to form a structural laminate. The thickness of the layer can be -~
selected to provide the desired physical and mechanical properties of the finished composite laminate sandwich structure.
Figure 2A shows a portion of the body 10 of the syntactic foam material of Figure 1 as taken on line 2-Q
after being heated and set illustrating in detail the base particles of the integrated product wherein hollow microspheres 11, 12 and 13 of three different sizes with resin 14, originally in powdered condition, intermixed therewith as they appear in the cured body or sheet with voids 19 distributed therethrough. The resin powder used in forming the sheet product is of much finer size than the microspheres and is thoroughly intermixed therewith and is present in an amount adequate to effect the desired inter-bonding of the microspheres but, in some products of the invention, the resin powder is present in an amount ~ t;JS~ J

l / ~

~ 2 1 9 6 1 6 4 IPEA~S 2 9 FEa t9~6 l~a selected to establish a predetermined buik densi~y as ~ell as the desired shear and compression WO96/04132 1~l/~ ,, strengths of the sheet product which results and at the same time leaving open voids 19 within the body.
Figure 2B illustratec a syntactic foam material like that of Figure 2A with glass fiber bundles 15 distributed therethrough to impart a greater shear strength to the core sheet to permit formation of higher strength lAm;n~t~
structures.
Figure 3 is representative of a mixture 16 of microspheres and resin powder in a tray 17 mounted on a vibrator 18 typically at about 600 vibrations per minute for about 10-15 seconds to thoroughly ;n~rm;~ the components of the mixture prior to being heated. The tray 17 is made to provide the desired peripheral ~;mon~;nn~ Of the syntactic layer and thickness of boundary members for insertion in a heating unit. The tray 17 is provided with a layer of separator material at its bottom to avoid bonding of the mixture thereto and permit removal of the core material after heating to a resin melt stage and hardening. An overlayer of separator material is also provided over the top surface prior to insertion in a press type heating unit.
Figure 4 illustrates a heating press 20 on pedestals ~~~
22 in which the syntactic foam core sheet 10 of Figure 1 can be produced having a base platen 24 and a moveable upper platen 21 both of which can be heated with the mixture of microspheres and resin located within a cnnf;n~ space determined by boundary mem~bers 28 of predetermined thickness and location in the presc which determine the thickness to which the upper platen 21 can precs the uncured mass as well as the boundary ~i ~; nn~

SUBSTITUTE StlEET ~RULE 26) ~W0 96104132 2 1 9 6 1 6 4 P~ 'C~

of the sheet 10 which finally results. The upper platen 21 can be lowered on guide rods 23 to a level of the thickness of the b~-ullda~y members 28 and the mass of microspheres and resin particles can be deposited within the confines of the boundary members 28 to provide the degree of compaction which will result in the desired density of the final core sheet 10 determined by trial and error in forming the foam material.
Figure 5 shows a laminate 40 incorporating a syntactic core 30 of the invention having panels or sheets 41 at its base and 42 over its upper surface. The lower and upper surfaces 41 and 42 respectively can be resin panels or metal sheets bonded to the core 30 as a sandwich structure designed to have the strength properties as determined by calculation and trial and error construction of the structure. The lower and upper panels 41 and 42 respectively can be bonded together with the core 30 of the type described in relation to Pigure 1 by separate bonding of the faces to the core 30 after the core 30 has been cured as in a press 20 illustrated in Figure 6. The surface sheets, however, can also be bonded to the core in a press as shown in Figure 6 wherein the lower panel 41 and upper panel 42 are placed in the press over the core material 40 as it is being heated to a cured condition.
Boundary members 48 on opposite sides o~ the composite determine the thickness to which the upper platen 21 can press the ' ;n~t;nn If one or both of the surface sheets are of pre-impregnated skin in an uncured condition, they can be combined with the syntactic foam core 40 while it is in an uncured state and the SUBSTITUTE SHEET ~RULE 26) PCT/~S 95/~9977 2 ~ 9 6 1 6 4 ~ V la~

combination can then be cured in one cycle to effect a cure of both the skin layers as the core layer is being cured.
As a further variation of the invention the two skin layers 41 and 42 can be subjected to a partial cure, such as by being brought to a B-stage cure prior to combination with the uncured core material and then in a single cycle ~= :
of final cure the complete assembly can be cured. ~nder such conditions since the skins are in a conformable B-stage cured condition, the assembly can be shaped in a die or mold positioned in the press to provide a desired shape for the final product. In this regard both surface layers 41 and 42 sandwiching the core can be made of sheet --molding compound (SMC) layers in which the final cure is - -accomplished under heat and pressure. ~he sheet molding compound being an entrapped jell material will become solidified under heat and pressure when cured to provide - -the final surface layers.
As still another variation of the invention, an uncured prepreg layer on one side of the core and a sheet molding compound layer can be assembled on the other side of the core as the outer layers of the laminate either before or while the laminate cure is effected.
Figure 7 illustrates another form of the invention in which the syntactic foam layer 60 includes additional reinforcing elements such as glass fibers or carbon fibers in individual form or as chopped strand bundles or in the form of continuous strand mats or stacked non-woven or woven fabrics. Such foam material can be made substantially as represented in Figure 4.

t ~ ~'096/04132 P~ ,7 Flgure 8 illustrates a continuous cullv~yur line rocess for production of syntactic foam sheet material according to the invention in which glass microspheres and resin powder, and optionally reinforcing elements, are introduced into a hopper 72 to which the components are supplied in nnnt;mlmlqly metered form or in batch form in predetermined percentage amounts by weight or volume to produce a mixture 71. The mixture 71 is supplied from the hopper through an end spout 73 to a conveyor belt 74 over an underlying vibrator 76 by which the mixture is sufficiently agitated to effect uniform distribution of the resin, and any included reinforcing-elements uniformly thLuuylluuL the mass of microspheres. The vibrated mixture then is conveyed by the continuously moving conveyor belt 74 having associated moveable side walls 75 on opposite ==
edges of the C~1~V~YUL belt which move in unison therewith to limit the breadth of distribution of the mixture deposited on the ~U~ yuL. The side walls 75 might optionally be stationary side walls but are preferably arranged to move in unison with the conveyor as a raised edge nnnfin;ng the particulate mixture to the width of the belt.
The conveyor belt 74 is made of a high-temperature flexible material such as a high-temperature polymer material or can be a flexible metal belt such as a steel band. The conveyor with the uncured syntactic foam ; material deposited thereon is passed through a curing oven 77 having an overlying belt 7a arranged to mate with the ~ yuL belt 74 to compact the ioam material 70 to the thickness determined by the height of the side walls 75 as SUBSTITIJTE SHEET ~RVLE 26) 21 96~ 64 WO96/04132 P~ll- ' ,.ll lG
well as to apply pressure to a degree called for to establish a desired density in the sheet material as it is being cured in the oven. The temperature and the rate of m~v of the conveyor belt 74 through the oven are selected to provide the cure cycle matching the material 71 supplied irom the hopper 72 by way of the channel 73.
soth the conveyor belt 74 and the overlying belt 78 are surfaced with a separator material to avoid sticking or bonding of the foam material to the belts during the cure cycle. As a-continuous sheet of syntactic foam material moves from the oven 77 it is passed onto a se,ulldaLy CJll~ey~L 81 where the length of the sheet is detrrm;nr~ by cutting it with means such as a chopper 79. Alternatively, cutting means such as a saw, a laser, or~a water jet cutter may be used to provide a syntactic foam sheet 80 meeting pr~rt~rm;n~ desired length spPr;f;rat;r,nq Microspheres of glass ;nrln~d to ~;ghten the weight of the foam mater:ial, by way of example7 can have a bulk density in the order of Q.2 pounds ~-er cubic foot. The density of the solid resin in contrast would be about 80 pounds per c~bic foot. When the microspheres and powder in addition to reinforcing elemênts are inter~ixed, a final product can be made in a density range of from 6 to 45 pounds per cubic foot. The sheet material can be made to any thickness such as in the range of from about 1/16 inch to 6 inches or more.
A mixture ;nrln~;ng phenolic resin as the matrix binder and a~catalyst therefor along with the microspheres and ~;t;~n~l reinforcing elements can be cured at a temperature In the order of 325-350 degrees F. with the SUSSrlTL~E SHEET (RULE 26) ~ W096/04132 2 1 9 6 1 6 4 P~

heating surface in contact with the mixture for a period in the order of 10 minutes. No post cure of the product has been found necessary. The resulting foam material is formed practically without volitization of any components.
Little or no water or 301vents are given off. That is, the process is a dry system rather than a liquid system.
During heat processing of the raw material, the resin powder during heating goes through a transition stage in which it is in a semi-sticky li~uid stage which ultimately becomes solid in ~nn~ol i ~AtP~ relation with the glass microspheres and reinforcing elemente. The foam character --of the material results from the voids provided by both the hollow microspheres and the voids left by reason of melting of the powdered resin which solidi$ies to a much lesser volume than the bulk powdered resin. By varying the ratio of the , nnPnt~ it is found that a shear modulus of the resulting sheet can be provided generally in the range of 500 to 25,000 psi with a compression strength generally in the range of 100 to 4,000 psi.
For a layer of resin powder ;nt~rm;Y~d with microspheres having a thickness of about 1 inch conductively heated by ~nnt~t; ng hot platens above and below without pressure applied to the layer, a syntactic foam product having a density of about 6 pounds can be formed in a cycle time in the range of 10-15 minutes.
When the mixture is thicker than th~ surrounding spacer --~ members in a press, the upper platen can be closed slowly to compact the mixture without rupturing the microspheres.
By so following the changes in dimensions of a mixture of sufficient thickness as it is heated, it has been found SUBSTITUTE SHEET (RULE 261 2~ 961 64 that a foam layer having a density of about 9 lbs. per cubic foot can be produced. For a mixture layer of 2 inches thick the cure time i8 about 22 minutes. When the mixture i5 greater than 1-2 inches thick it can be effectively microwave heated.
Following are other example~ of syntactic foam cores of different densities which have been made according to the present invention:
~ Volume Weight 1. 9 lhs/cu ft fo~m Phenolic resin powder 2.38 20 Glass bubbles 97.62 80 2. lS lh5/cu ft fo5m Phenolic resin powder 4.27 22.20 Glass bubbles 95.73 77.80
3. 19 lhs/cu ft fo~m Phenolic resin powder 4.96 20.34 Glass bubbles 92.54 59.32 1/2" Chopped bundles of 17 micron glass fibers (1000 ~ibers per bundle)2.50 20.34
4. 22 1h5/cu ft foam Phenolic resin powder 13.51 50.0 Glass bubbles 86 49 50.0
5. 28 lhs/cu ft fo~m SU9STITLITE SHEET (RULE 26 2~ 961 64 WO96/04132 F~

Phenolic resin powder 30.67 60.48 Glass bubbleE 64.30 19.81 Glass fiber mat 1.5 oz/sq ft5.04 19.71 The resin particle size in each of the above examples was in the order of 20 microns. A particle size of 50 microns is judged to be the upper desireable limit of the resin powder for satisfactory production of a foam according to the invention. The finer the resin powder -the better the product properties that are attained, down to as low as one micron size particle. The glass bubbles in each of the examples above had a US 80 mesh particle ---size (177 microns).
A coupling agent, although not npc~ ry on the microspheres, when present assists in wetting and adherence of the resin to the microsphere surfaces and by reason of its surface tension acts to interconnect the ~ =
adjacent microspheres in the mass The resin powder can be a reactive reein such as is produced as a waste byproduct from powdered resin coating materials. In other words the small diameter dust powder collected as waste, in a powdered coating production facility and which is usually air borne and collected as waste during manufacture of the powdered coating has been found to be ~Y~13~nt in providing syntactic foam according to the present invention.
If the reinforcement material for the syntactic foam layer is provided in the form of carbon fiber or glass fiber mats or high strength glass fiber mats or hollow glass fiber mats to increase the flex strength of the SUBSTITUTE SHEET (RUEE 26~

Wo96/04132 2 l 9 6 1 6 4 P~ " -composite, a mat of suf~icient thickness can be provided so that the resin powder and microspheres can be deposited and sifted into the mat by agitation. Such a process can provide a foam which when cured has improved physical and mechanical properties compared to a three component foam sheet which includes chopped fibers onIy as reinforcing elements.
Any number of skin materials can be bonded or molded to the core eo made, ;n~ ;ng composite resin sheets of di~ferent material or metal eheets such as aluminum sheets.
In forming a three ~;m~nc;~ncl article of the syntactic foam, a layer of the mixture of basic components, that is the bubbles, reinforcing media and powdered resin along with its catalyst if it is a thermosetting resin, can be pre-heated to a sticky integrated conformable stage which can then be draped over a three dimensional form for a final cure or hardening to the three dimensional article of desired shape. Microwave energy can be utilized for pre-heating and for cure of such a product, whether in planar or three dimensional form. The three ~; -; on~l shaping can result from use of a mold or tray having a contoured three dimensional shape in which the mold or tray is filled with a mixture of the powdered resin, reinforcing elements and glass microspheres which are pre-heated to a prepreg sticky condition and then further shaped into the three dimensional form.
As still another variation of the invention, the ~oam material can be cured into a thick block or a thick layer SUE~STITUTE SHEET (PlJLE 261 ~ W096/04132 2 1 9 6 1 6 4 r~

which can be machined or passed through a router for a desired three dimensional shape By way of example as illustration of the flexability of properties obtainable for densities of unreinforced syntactic foam core layers in the range of 6 to 45 pounds per cubic foot, typical properties produced in samples tested according to ASTM standards fall within the following ranges: compressive strength (pci) 100-over 4000; shear strength (psi) 74-1100; shear modulus (psi) 1500-over 24,000 Ideally when a composite in the form of a sandwich structure i6 formed with two faces of high strength material on opposite sides of the syntactic foam core, the core is desirably engineered 80 that in actual use when stressed to the breaking point a non-preferential rupture will occur either in the core or a face of the composite.
That is, it is desired ideally that the face sheet strength and the core strength be substantially equal ==
against rupture in the stressed sandwich ~LLU~LUL~. By way of example, if a face material has a flexural modulus in the order of 5.2 million psi and the shear modulus of the core is in the order of 20,000 pounds per square inch, the rupture strength of the composite or flexural modulus has been ~P~r~;n~ in the order of 4.3 million psi If the thickness of the composite is set, then the core shear strength and the face modulus can be de~rm;n~d in order to engineer the product for the maximum strength which it must sustain.
In view of the foregoing it will be understood that many variations of the dLLdll~. ~ of the invention can be SUBSTtTUTE SHEET (RULE 26) Wo96/~4132 2 1 9 6 1 6 4 r~Jl~ - s ~

provided within the broad scope of principles embodied therein. Thus while particular preferred embodiments of the invention have been shown and described, it is ;n~n~ by the appended Claims to cover all such modifications which fall within the true spirit and scope of the invention.

SUSSTlllJTE SHEET (WJLE 26)

Claims (22)

1. A syntactic foam core material adaptable to provide a low density rigid foam core layer for composite layered sandwich structures comprising a layer of hollow ceramic microspheres, dry resin powder particles finer in dimension than the diameter of said microspheres thoroughly intermixed with said layer of microspheres to provide a uniform mixture of said powder particles and microspheres, said microspheres being present in a percentage by volume amount of at least 60%, said mixture of microspheres and resin powder having been processed through a cycle of heat melting and setting of said resin particles in interbonded relationship with said microspheres, said resin particles being present in quantity to interbond said mixture into an integrated rigid syntactic foam layer while leaving void spaces within said layer upon setting of said melted resin, said rigid foam layer having a density less than 45 pounds per cubic foot, said layer having opposite major surfaces for combination with layers of material on opposite sides thereof in layered sandwich structures.
2. The syntactic foam core material of claim 1 in which said microspheres are glass microspheres and said core material includes reinforcing elements in the form of fibers intermixed throughout and interbonded with said mixture of glass microspheres and resin.
3. The syntactic foam core material of claim 2 in which the reinforcing elements are of glass fibers.
4. The syntactic foam core material of claim 3 in which said reinforcing elements are fibers of chopped glass strands.
5. The syntactic foam core material of claim 2 in which the reinforcing elements are fibers in the form of a mat of fibers.
6. The syntactic foam core material of claim 2 in which the reinforcing elements are carbon fibers.
7. The syntactic foam core material of Claim 1 in sheet form in which said resin powder particles have a dimension less than 50 microns.
3. The syntactic foam core material of claim 1 in which the diameter of the microspheres is in the order of 170 microns and the size of the resin powder particles is in the order of 20 microns.
9. The syntactic foam core material of claim 1 wherein said powdered resin is a phenolic resin.
10. The syntactic foam core material of claim 9 in which hexamethylenetetramine is present as a catalyst to enhance adhesion of said resin to said microspheres.
11. A syntactic foam material for producing a light weight rigid layer for multilayered composite articles, comprising a mass of hollow microspheres of glass in a layer, particles of a dry powdered resin distributed throughout said mass of hollow microspheres, said particles being finer in dimension than the dimension of said microspheres, said particles of powdered resin being present in said material in an amount to effect an interbonding of the combination in integrated relation in a rigid layer with void spaces in said layer upon heat cycling and setting of said resin powder, said microspheres being present in said material in a percentage by volume amount of at least 60%.
said rigid layer having a density less than 45 pounds per cubic foot and having opposite major surfaces for accommodation of surfaces of adjacent layers in said multilayered composite articles.
12. A method of forming a syntactic foam layer adaptable to use in composite products comprising intermixing a mass of hollow ceramic microspheres and an interbonding resin in dry powdered form, physically agitating said mixture to establish a uniformity of distribution of the resin powder throughout the mass of microspheres, depositing said uniform mixture as a layer on a base surface having a layer of separator material thereover, processing the layer of said mixture through a cycle of heating to melt said resin powder and setting said melted resin to fuse the resin and microspheres into a rigid integrated layer, the amount of dry resin powder intermixed with the microspheres being an amount which is effective to interbond the resin and microspheres and form void spaces in the layer.
13. A method as set forth in Claim 12 including providing relatively thin surface layers for a composite sandwich structure in overlying and underlying relation with said layer as a core and subjecting said surface layers and core layer together to said heating cycle to bond said surface layers to said core layer as said core layer is being integrated during said heating cycle
14. A method as set forth in Claim 13 in which at least one of said surface layers applied to said core layer comprises a resin sheet material in an uncured condition and curing the uncured surface layer in bonded relation with said core layer simultaneously during the cycle of heating and setting the resin to integrate said core layer.
15. A method as set forth in Claim 12 in which a three dimensional article is made by draping said layer while it is in a heated sticky conformable stage over a three dimensional form and setting the resin of the layer on said form as an integrated three dimensional article matched in shape to said form.
16. A method of making a rigid low density syntactic foam layer for producing light weight articles comprising providing a mass of hollow ceramic microspheres, combining a quantity of dry resin powder with said microspheres, the dimension of the particles of said powder being substantially finer than the diameters of said microspheres, vibrating the combination of said microspheres and resin powder to form a thorough mixture thereof, heating said mixture in a layer to a temperature at which the resin powder particles are converted to a melted condition and, setting said melted resin to a hardened condition, said quantity of dry resin powder being adequate to interbond said microspheres and resin into a rigid syntactic foam layer.
17. A method as set forth in Claim 16 wherein said quantity of resin powder is adequate to fill the spaces between said microspheres yet forms voids in said mixture upon setting of said resin.
18. A method as set forth in Claim 17 in which said quantity of resin powder is sufficient to effectively space at least a portion of said microspheres from contact with each other.
19. A method as set forth in Claim 16 in which said mass of microspheres include microspheres of a plurality of diameters.
20. A method as set forth in Claim 16 including compacting said mixture before being heated.
21. A method as set forth in Claim 16 in which said heating is effected conductively by providing heating means having at least one heated contact surface in communication with a surface of said mixture.
22. A method as set forth in Claim 16 in which said heating is effected by providing a high frequency energy heating means in close relation with said mixture and inductively heating said mixture.
CA002196164A 1994-07-29 1995-07-27 Syntactic foam sheet material Abandoned CA2196164A1 (en)

Applications Claiming Priority (2)

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US08/282,371 1994-07-29
US08/282,371 US5587231A (en) 1994-07-29 1994-07-29 Syntactic foam core material and method of manufacture

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EP (1) EP0772516A4 (en)
JP (1) JPH10503801A (en)
KR (1) KR970704573A (en)
AU (1) AU708635B2 (en)
CA (1) CA2196164A1 (en)
MX (1) MX9700745A (en)
WO (1) WO1996004132A1 (en)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USD953709S1 (en) 1985-08-29 2022-06-07 Puma SE Shoe
USD855953S1 (en) 2017-09-14 2019-08-13 Puma SE Shoe sole element
US5773121A (en) * 1994-07-29 1998-06-30 Isorca Inc. Syntactic foam core incorporating honeycomb structure for composites
KR19980703761A (en) * 1996-02-13 1998-12-05 캣츠 스티븐 지. Syntactic Foam Core Materials for Composite Structural Materials
JP3876491B2 (en) * 1997-02-27 2007-01-31 三菱電機株式会社 Vacuum insulation panel, method for manufacturing the same, and refrigerator using the same
US6043769A (en) * 1997-07-23 2000-03-28 Cuming Microware Corporation Radar absorber and method of manufacture
US6451231B1 (en) 1997-08-21 2002-09-17 Henkel Corporation Method of forming a high performance structural foam for stiffening parts
US6068915A (en) 1997-11-06 2000-05-30 Mcdonnell Douglas Corporation Thermosetting syntactic foams and their preparation
US6032300A (en) 1998-09-22 2000-03-07 Brock Usa, Llc Protective padding for sports gear
US6231961B1 (en) * 1998-12-09 2001-05-15 Henry Sperber Layered structures comprising particles, a dry binder and a foamable substance
US6171688B1 (en) * 1999-02-08 2001-01-09 Board Of Trustees Operating Michigan State University Material and method for the preparation thereof
US7037865B1 (en) * 2000-08-08 2006-05-02 Moldite, Inc. Composite materials
US7662468B2 (en) 2000-10-06 2010-02-16 Brock Usa, Llc Composite materials made from pretreated, adhesive coated beads
US6649002B2 (en) * 2000-11-09 2003-11-18 Patent Holding Company Method of manufacturing articles utilizing a composite material having a high density of small particles in a matrix material
DE10213753A1 (en) * 2002-03-26 2003-10-16 Basf Ag composite elements
FR2885144B1 (en) * 2005-04-27 2007-06-15 Saint Gobain Vetrotex FIBROUS STRUCTURE BONDED LOAD
TW200812793A (en) * 2006-09-13 2008-03-16 Tiong Liong Ind Co Ltd Foam laminated material made of a number of materials
US8623265B2 (en) * 2007-02-06 2014-01-07 World Properties, Inc. Conductive polymer foams, method of manufacture, and articles thereof
GB2458066B (en) * 2007-02-06 2011-10-05 World Properties Inc Conductive polymer foams, method of manufacture, and uses thereof
US20090226696A1 (en) * 2008-02-06 2009-09-10 World Properties, Inc. Conductive Polymer Foams, Method of Manufacture, And Uses Thereof
ITUD20070117A1 (en) * 2007-06-27 2008-12-28 Design Manufactoring S P A In AIRCRAFT COMPONENT AND PROCEDURE FOR ITS REALIZATION
US20090149284A1 (en) * 2007-12-11 2009-06-11 Isaac Garcia Hockey Stick Blade Having Fiber-Reinforced High Density Foam Core
US8110132B2 (en) * 2008-02-13 2012-02-07 James Hardie Technology Limited Process and machine for manufacturing lap siding and the product made thereby
US7824591B2 (en) * 2008-03-14 2010-11-02 Bauer Hockey, Inc. Method of forming hockey blade with wrapped, stitched core
US9802369B2 (en) 2008-03-14 2017-10-31 Bauer Hockey, Llc Epoxy core with expandable microspheres
WO2010016834A1 (en) * 2008-08-05 2010-02-11 World Properties, Inc. Conductive polymer foams, method of manufacture, and articles thereof
FR2939077B1 (en) 2008-12-03 2013-01-11 Ateca MATERIAL OF AME.
US20110104473A1 (en) * 2009-06-01 2011-05-05 Tippur Hareesh V Light weight interpenetrating phase composite foam and methods for making and using the same
US8815408B1 (en) 2009-12-08 2014-08-26 Imaging Systems Technology, Inc. Metal syntactic foam
EP2335899A1 (en) * 2009-12-17 2011-06-22 EUROCOPTER DEUTSCHLAND GmbH A method of fabricating an improved mold core and a mold core obtained by said method
CN102686652A (en) * 2009-12-29 2012-09-19 罗杰斯公司 Conductive polymer foams, method of manufacture, and uses thereof
US8251174B2 (en) * 2010-03-26 2012-08-28 Spirit Aerosystems, Inc. Method for bonding honeycomb cores
US8677599B2 (en) 2010-09-20 2014-03-25 Bauer Hockey, Inc. Blade constructs and methods of forming blade constructs
WO2013042611A1 (en) * 2011-09-20 2013-03-28 東海ゴム工業株式会社 Urethane foam molding and method for manufacturing same
US20130251924A1 (en) * 2012-03-21 2013-09-26 Majdi Haddad Macrosphere carbon fiber reduction
US10352059B2 (en) * 2012-08-24 2019-07-16 The Uab Research Foundation Modular shelters comprising composite panels
JP2016171636A (en) * 2015-03-11 2016-09-23 ファナック株式会社 Stator and manufacturing method of the same
EP3307978B1 (en) * 2015-06-12 2020-04-01 3M Innovative Properties Company Buoyancy module and method of making such a module
DE102016204775A1 (en) * 2016-03-23 2017-09-28 Sandvik Tps Zweigniederlassung Der Sandvik Materials Technology Deutschland Gmbh Structural body and method for its production
NL2016945B1 (en) * 2016-06-10 2018-01-24 Lantor Bv Flexible core for machine processing or production of composite parts or materials
US10226099B2 (en) * 2016-08-26 2019-03-12 Reebok International Limited Soles for sports shoes
USD850766S1 (en) 2017-01-17 2019-06-11 Puma SE Shoe sole element
FR3070306B1 (en) * 2017-08-22 2020-11-27 Eco Technilin Sas SANDWICH-TYPE STRUCTURAL MATERIAL FOR THERMOCOMPRESSING AND ASSOCIATED MANUFACTURING PROCESSES
USD975417S1 (en) 2017-09-14 2023-01-17 Puma SE Shoe
CN108202486B (en) * 2018-03-13 2023-05-16 远东电缆有限公司 Composite core production line and production process thereof
CN112074205A (en) * 2018-04-27 2020-12-11 彪马欧洲股份公司 Shoe, in particular sports shoe
IT201800010223A1 (en) * 2018-11-09 2020-05-09 Persico Spa PRODUCTION PROCESS OF A COMPOSITE PRODUCT
US20220402238A1 (en) * 2019-08-27 2022-12-22 Inoac Corporation Fiber-reinforced-resin composite molded article and method for producing same, antibacterial composite molded article and method for producing same, antibacterial fiber-reinforced resin composite molded article and method for producing same, and fiber-reinforced-resin laminated molded article and method for producing same

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2806509A (en) * 1956-06-11 1957-09-17 Goodyear Aircraft Corp Sandwich structures
US2985411A (en) * 1957-06-25 1961-05-23 Jr Baxter C Madden Structural element having sphericallike filling
US3429955A (en) * 1965-09-23 1969-02-25 Pittsburgh Corning Corp Method of making a shaped article from coated multicellular glass nodules
US3855160A (en) * 1970-10-27 1974-12-17 Leben Utility Co Thermosetting foamable resinous composition
JPS515836B1 (en) * 1971-06-30 1976-02-23
JPS5634864B2 (en) * 1973-05-30 1981-08-13
US4111713A (en) * 1975-01-29 1978-09-05 Minnesota Mining And Manufacturing Company Hollow spheres
US4025686A (en) * 1975-06-26 1977-05-24 Owens-Corning Fiberglas Corporation Molded composite article and method for making the article
US4095008A (en) * 1975-08-13 1978-06-13 Rogers Corporation Syntactic foam matrix board
US4193829A (en) * 1977-03-16 1980-03-18 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Process for the manufacture of low density bis-maleimide-carbon microballoon composites
FR2386409A2 (en) * 1977-04-05 1978-11-03 Saunier Jean Pierre Cellular thermosetting resin prods. mfr. - for construction elements imparting heat- and sound-insulating properties, and flame-resistance
US4132755A (en) * 1977-07-22 1979-01-02 Jay Johnson Process for manufacturing resin-impregnated, reinforced articles without the presence of resin fumes
US4201823A (en) * 1977-12-29 1980-05-06 Rohm And Haas Company Method for making fiber reinforced articles
US4178406A (en) * 1977-12-29 1979-12-11 Rohm And Haas Company Three-layered fiberglass construction
US4447565A (en) * 1981-12-07 1984-05-08 The United States Of America As Represented By The United States Department Of Energy Method and composition for molding low density desiccant syntactic foam articles
DE3424474A1 (en) * 1984-02-08 1986-01-16 Siemens AG, 1000 Berlin und 8000 München METHOD FOR PRODUCING A LIGHT MATERIAL
JPS61246237A (en) * 1985-04-25 1986-11-01 Sumitomo Deyurezu Kk Production of phenolic resin composite foam
FR2586215B1 (en) * 1985-08-13 1988-09-02 Hutchinson THERMAL INSULATION MATERIAL OF THE SYNTACTIC TYPE, MACHINE AND METHOD FOR THE PRODUCTION THEREOF, AND INSULATION MEANS COMPRISING SUCH A MATERIAL
GB8702847D0 (en) * 1987-02-09 1987-03-18 Ici Plc Shaping of syntactic foam
US4861649A (en) * 1987-11-02 1989-08-29 Browne James M Impact resistent composites
US5030488A (en) * 1988-11-23 1991-07-09 Chemical And Polymer Technology, Inc. Laminates, panels and means for joining them
US5034256A (en) * 1989-08-28 1991-07-23 United Technologies Corporation Closeout configuration for honeycomb core composite sandwich panels
JPH06157808A (en) * 1992-11-25 1994-06-07 Yokohama Rubber Co Ltd:The Production of syntactic foam

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US5587231A (en) 1996-12-24
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