CA2190249C - Laminated thermal transfer printable labels - Google Patents

Laminated thermal transfer printable labels Download PDF

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Publication number
CA2190249C
CA2190249C CA002190249A CA2190249A CA2190249C CA 2190249 C CA2190249 C CA 2190249C CA 002190249 A CA002190249 A CA 002190249A CA 2190249 A CA2190249 A CA 2190249A CA 2190249 C CA2190249 C CA 2190249C
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CA
Canada
Prior art keywords
substrate
face
ribbon
facestock
roll
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002190249A
Other languages
French (fr)
Other versions
CA2190249A1 (en
Inventor
Chauncey T. Mitchell, Jr.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Media Solutions International Inc
Original Assignee
Media Solutions Inc
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Filing date
Publication date
Application filed by Media Solutions Inc filed Critical Media Solutions Inc
Publication of CA2190249A1 publication Critical patent/CA2190249A1/en
Application granted granted Critical
Publication of CA2190249C publication Critical patent/CA2190249C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/382Contact thermal transfer or sublimation processes
    • B41M5/38207Contact thermal transfer or sublimation processes characterised by aspects not provided for in groups B41M5/385 - B41M5/395
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B31MAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER; WORKING PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER
    • B31DMAKING ARTICLES OF PAPER, CARDBOARD OR MATERIAL WORKED IN A MANNER ANALOGOUS TO PAPER, NOT PROVIDED FOR IN SUBCLASSES B31B OR B31C
    • B31D1/00Multiple-step processes for making flat articles ; Making flat articles
    • B31D1/02Multiple-step processes for making flat articles ; Making flat articles the articles being labels or tags
    • B31D1/027Multiple-step processes for making flat articles ; Making flat articles the articles being labels or tags involving, marking, printing or coding
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/02Forms or constructions
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42Intermediate, backcoat, or covering layers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/906Roll or coil
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/913Material designed to be responsive to temperature, light, moisture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1052Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1056Perforating lamina
    • Y10T156/1057Subsequent to assembly of laminae
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1052Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1084Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing of continuous or running length bonded web
    • Y10T156/1085One web only
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1476Release layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1481Dissimilar adhesives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1486Ornamental, decorative, pattern, or indicia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/149Sectional layer removable
    • Y10T428/1495Adhesive is on removable layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/15Sheet, web, or layer weakened to permit separation through thickness
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24826Spot bonds connect components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851Intermediate layer is discontinuous or differential
    • Y10T428/2486Intermediate layer is discontinuous or differential with outer strippable or release layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24893Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
    • Y10T428/24901Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material including coloring matter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree

Abstract

A label stock includes a thermal transfer facestock and a thermal transfer ribbon that are laminated together. The facestock has a front face for receiving thermal transfer ink and a back face covered by an adhesive. The ribbon has a front face covered by thermal transfer ink and a back face covered by a release. The facestock and ribbon are laminated and wound together into a roll so that the ribbon also functions as a conventional release liner.

Description

:: .. - 1 -TITLE

TECHNICAL FIELD -The invention relates to the fields of label making and printing. The fields are related by combining elements of thermal transfer printing with label making.
BACKGROUND
Thermal transfer printing is a type of non-impact printing in which controlled concentrations of heat are used to melt ink from a ribbon onto a print medium. The ribbon is a thin film or paper that readily transfersheat from its back face, which engages heating elements of a printing mechanism, to its front face, which is coated with a wax- or resin-bound ink. The print medium has a front face that is made to receive the melted ink.
One use of thermal transfer printing is for printing self-adhesive labels, which can be made with thermal transfer paper or film facestocks. The front face of the facestock must be absorptive to prevent the ink from smearing yet very smooth to prevent discontinuities in the printed image. Coating materials, such as calcium carbonate and calcinated clay pigments, are often used to increase absorptivity.
A back face of the facestock is coated with an adhesive for applying a length of the facestock to another ~ article. A liner having a release coating protects the adhesive and allows the facestock to be wound into a roll of label stock prior to use. The liner also allows the WO 95/31800 _ PCTIIJS95105248 2~.9~124~ ','.s....
z . .
facestock to be divided into individual labels that are carried by the liner.
The thermal transfer ribbon and the lined facestock are fed from different spools into a thermal transfer printer. The front face of the ribbon is registered in ' contact with the front face of the facestock between a thermal print head and a platen. Under light pressure, heat from the print head causes the ink to melt from the ribbon and be absorbed by the facestack. The ribbon is rewound onto a take-up spool for disposal. Individually printed labels can be dispensed either separately from or together with the liner. In the former case, the liner is rewound onto a take-up spool for disposal. In the latter case, sections of the liner must be discarded individually after the labels are removed.
However, the liners do not readily degrade, and disposal can be expensive. The liners are relatively costly to make and account for up to 60 percent of the size and weight of label stock rolls. The additional weight increases shipping costs, as well as the weight of portable thermal transfer printers. Also, many prihter dispensing failures occur because of difficulties separating labels from the liners.
SUMMARY OF INVENTION
My invention provides for replacing cohventional release liners of thermal transfer printable label stock with specially adapted thermal transfer ribbons. A release coating is applied to a back face of the thermal transfer ribbon, and the ribbon is laminated together with a self-adhesive facestock in place of the release liner. Thus, in addition to the function of carrying ink, the ribbon also functions as a release liner for protecting an adhesive layer of the facestock.

WO 95Y31800 , , PCTJUS95I05248 ~1g0249 A single roll of laminated ribbon and facestock replaces separate rolls of ribbon and lined facestock. This reduces inventory items, packaging requirements, and shipping costs and makes planning easier because the required amount of ribbon is laminated together with the facestock.
Printer drive mechanisms can be simplified by eliminating one of two feed spools for conventional ribbons and facestock, as well as by eliminating a take-up spool for conventional liners. Operation of the printers is also simplified because only one feed spool requires loading, and the ribbon and facestock are used up together. Further, dispensing failures can be reducedbecause the adhesive layer of the facestock is separated from the release layer of the ribbon prior to printing.
In another respect, my invention can be understood to include two substrates. A first of the substrates, which forms the facestock, has a front face that is adapted for receiving thermal transfer ink and a back face that is covered with a layer of adhesive. A second of the substrates, which forms the thermal transfer ribbon, has a front face that is covered with a layer of the thermal transfer ink and a back face that is covered by a layer of release. The facestock and ribbon substrates are laminated and wound together into coils such that th,e adhesive layer of the facestock contacts the release layer of the ribbon.
The contact between the adhesive and release layers can take place either within each coil or between adjacent coils. For example, one version of my invention laminates the adhesive and release layers together prior to winding.
~ Another version laminates the front face of the facestock against the ink layer of the ribbon so that contact between ~ the~release and adhesive layers occurs only upon winding.
Regardless of-which way the two substrates are laminated together before winding, the front face of the facestock must be registered in contact with the ink layer of the ribbon during printing. Accordingly, the adhesive and release layers are separated either within each coil or between adjacent coils prior to printing. A binder such as fugitive adhesive or static cling can be used to tack the two substrates together for printing.
The facestock can be cut against the ribbon similar to cutting against conventional liners. Cutting divides the facestock into individual labels that are carried by the ribbon. The individual labels can be gripped by the fugitive adhesive to maintain their proper registration with the ribbon. Preferably, the fugitive adhesive is applied directly on the front face of the ribbon in strips that extend along outer edges of the ribbon. Gaps in the strip allow air to escape between the two substrates. The fugitive adhesive exhibits slightly higher bonding strength between the front faces of the substrates than is exhibited by the adhesive and release layers between the back faces of the substrates. This assures that individual labels will remain registered with the ribbon while being unwound into the printer.
In one particularly preferred embodiment there is provided a roll of thermal label stock comprising: a first substrate having front and back faces; said front face of the first substrate adapted for receiving thermal transfer ink; an adhesive layer covering at least a portion of said back face of the first substrate; a second substrate having front and back faces; a thermal transfer ink layer covering at least a portion of said front face of the second substrate; a release layer covering at least a portion of - 4a -said back face of the second substrate; and said first and second substrates being laminated and wound together into coils such that said adhesive layer of the first substrate contacts said release layer of the second substrate.
The invention also provides for a self-adhesive thermal transfer label prepared from the label stock just described and a method of making such labels.
DRAWINGS
FIG. 1 is a diagram of a system for making a roll of my new thermal transfer printable label stock.
FIG. 2 is a cross-sectional side view through one example of a roll of my label stock in which layers are drawn with exaggerated thickness.
FIG. 3 is a cross-sectional end view taken along line 3-3 of FIG 2.

WO 95131800 PCTlU595105248 FIG: 4 is a partially cut-away plan view of the same label stock showing a pattern of adhesive between the layers.
FIG. 5-is a cross-sectional side view of another example of a roll of my label stock, also drawn with layers of exaggerated thickness.
FIG. 6 is a cross-sectional end view taken along line 6-6 of FIG. 5.
FIG..7 is a diagram of a printing system for individually printing and dispensing labels from the label stock of FIGS. 2-4.
FIG. 8 is a diagram of a printing system for individually printing and dispensing labels from the label stock of FIGS. 5 and 6.
FIG. 9 is a diagram of an internal transport system for a thermal printer.
DETAILED DESCRIPTION
My new thermal transfer printable label stock can be made according to the system of FIG. 1 from starting materials such as a roll 10 of thermal transfer facestock 12 and a roll 14 of thermal transfer ribbon 16. A first embodiment of the new label stock is shown in FIGS. 2-4.
The facestock 12, which has front and back faces 26 and 28, is preferably a paper substrate that absorbs thermal transfer inks. The front face 26 of the facestock 12 can be coated to increase absorptivity or to improve appearance.
Other facestock substrates can be made from films, metals, ceramics, and glass.

. i:
W095/31800 ~ ~ PCT/US95105248 The thermal transfer ribbon 16, which has front and back faces 36 and 38, is preferably made from a polyester film substrate. The front face 36 of the ribbon 16 is coated with a resin- or wax-bound ink 18. Other ribbon or liner materials, including resin or paper materials having higher melting points than the bound ink 18, could also be used.
A printer 20, which can be either a variable or a static: information type printer but is preferably a press, operates ~~in line~~ on the facestock 12. In fact, either thermal or non-thermal printing could be performed. Ink 24 or other marking material can be applied by the printer 20 in various patterns and colors to the front or back faces 26 or 28 of the facestock 12. For example, logos, forms, or security markings can be applied in predetermined positions on the facestock 12. A water-based flexo ink that is heat and air dried is preferred. -A first adhesive coater 22 and a laminator 32 join the facestock 12 and the ribbon 16. The adhesive coater 22 is arranged to apply a fugitive adhesive 40 in a predetermined pattern to the front face 36 of the ribbon 16.
The predetermined pattern includes coatings that cover the entire front face 36. The laminator 32 aligns and presses the facestock 12 and ribbon 16 together.
According to the embodiment of FIGS. 2-4, the front face 26 of the facestock is laminated against the front face 36 of the ribbon. Preferably, the.fugitive adhesive 40 is applied in strips to edges of the ribbon 16 for providing a temporary bond between the front faces 26 and 36 of the ribbon and facestock. Gaps 42 allow trapped air to escape between the front faces 26 and 36. - The fugitive adhesive 40 can be cured by air or radiation.
A release coater 44, a cutter 46, and a second adhesive coater 48 complete the exemplary in-line operations. The release coater 44 applies a layer of release 21~0~~9 34 on the back face 38 of the ribbon. The cutter 46 divides the facestock 12 with cuts 54 into individual labels 50. The adhesive coater 48 applies a layer of adhesive 30 to the back face 28 of the facestock.
The release 34 is preferably a radiation curable, silicone-based material that exhibits little bonding to the adhesive 30 but bonds tightly to the ribbon 16. Other release materials including resins, waxes, and oils can be selected for use with particular adhesives.
The cutter 46 is preferably a die cutting tool for cutting the facestock 12 against the ribbon 16. To enhance the cutting action, the facestock 12 can be a paper that splits apart upon partial penetration of the cutter 46 according to a so-called ~~butt~~ cutting technique. On the other hand, the ribbon 16, which functions as a liner for transporting the individual labels 50, preferably resists splitting apart upon partial penetration of the cutter 46.
These cutting properties of the facestock 12 and the ribbon 16 widen tolerances for operating the cutter 46.
The adhesive 30 is preferably a pressure-sensitive adhesive that is applied as a hot melt. However, solvent- or water-based adhesives using acrylics, polymers, and rubber bases and which are dried by air or radiation could also be used. Other applications may require the adhesive 30 to be applied in a special pattern or to exhibit other properties such as co-adhesion, repositionability, removability, or resistance to cold.
The completed label stock 56 is wound into a roll 52 in which the layer of adhesive 30 in one coil of the roll contacts the layer of release 34 in another coil. The layer of release 34 also forms the outermost layer of the roll 52.
However, the completed label stock 56 could also be wound with the adhesive layer 30 forming the outermost layer.

W0 95Y31800 ~ ~ ~ ~ ~ ~ ~ PCZ'/US95I05248 _ g The fugitive adhesive 40 is preferably applied just prior-to laminating the facestock 12 and ribbon 16, and the adhesive 30 is preferably applied just prior to winding completed label stock 56 into the roll 52.- This minimizes exposure of the in-line system to the adhesives 40 and 30, which can contaminate moving parts of the system. Also, the fugitive adhesive 40 is formulated with respect to the adhesive 30 to form a temporary bond between the front faces 26 and 36 of the facestock and ribbon that is stronger than the releasable bond between the back faces 28 and 38 of the facestock and ribbon. This assures that the individual labels 5D remain attached to the ribbon 16 while the label stock 56 is unwound from the roll 52.-The system illustrated in FIG. 1 for making my new thermal transfer label stock admits many variations, including changes to the starting materials and changes to the order and number of the operations. For example, the facestock 12 could be preprinted on the roll 10, and the ribbon 16 could be precoated with the layer of release 34.
The fugitive adhesive 40 could be applied in advance to either the front face 26 of the facestock or the'front face 36 of the ribbon. The adhesive 3Dcould also be applied at various times including before or after the facestock 12 and the ribbon 16 are laminated together. The layers of adhesive 30 and- release 34 could also be applied in, matching patterns, and the fugitive adhesive 40 could be replaced by static cling.
The cutter 46 could be arranged to partially separate the labels 50 by a series-of perforations; and a binder, such as the fugitive adhesive 40, would no longer be needed to transport the labels 50 with the ribbon 16.
Cutting could also be performed along with subsequent thermal transfer printing operations on either fixed or variable , length labels.

W095/31800 PCTfi3S95105248 _ , . ~ t Another embodiment of my new label stock, manufacturable by a similar system, is shown in FIGS. 5 and 6. Similar to the preceding embodiment, the present label stock includes a facestock 60 having front and back faces 62 and 64 and a ribbon 66 having front and back faces 68 and 70. The front face 62 of the facestock is adapted for receiving thermal transfer ink, and the back face 64 of the facestock is covered by a layer of adhesive 72. The front face 68 of the ribbon is covered by alayer of thermal transfer ink 74, and the back face 70 of the ribbon is covered by a layer of release 76.
Also similar to the preceding embodiment, the front and back faces 62and 64 of the facestock can be printed with ink 78 in predetermined patterns or colors. The cutter 46 could also be used to divide the facestock 60 into individual labels separated by perforations.' However, in contrast to the preceding embodiment, the adhesive 72 of the facestock back face 64 is laminated to the release 76 of the ribbon back face 70. This simplifies manufacture by providing an immediate cover for the adhesive 72. When wound into a roll 80, the thermal transfer ink 74 on the ribbon front face 68 of one coil contacts the facestock front face 62 of another coil. The front face 62 of the facestock also forms the outermost layer of the roll 80. However, the completed label stock 82 could also be wound with the ink ,74 on the ribbon front face 68 forming the outermost layer.
FIGS_ 7 and 8 show how the two embodiments can be printed and dispensed. In FIG. 7, the roll 52 of new label stock 56 is unrolled into a thermal transfer printer 84 for printing unique information on the individual labels 50. The binder, e.g., fugitive adhesive 40 (see FIGS. 2-4), is strong enough to overcome any bonding between the layers of adhesive 30 and release 34 to insure that the labels 50 remain attached to the ribbon 16 for transport through the printer 84. However, if static cling is used as a binder, a static WO95131800 ~ PCT/US95/05248 remover may be required to limit static discharges that could damage the printer 84.
After printing, a dispenser 86 provzdes for separating the individual labels 5D from the ribbon 16, which is subsequently rewound into a roll 88 for disposal.
Although illustrated as separate processing stages, the functions of dispensing and rewinding are preferably incorporated into the printing device.
In FIG. 8, the facestock 60 of label stock 82 is -inverted with respect to'the ribbon 66 upon unwinding from the roll 80. This separates the adhesive layer 72 of the facestock from the release layer 76 of the ribbon and positions the front face 62 of the facestock against the thermal transfer ink 74 of the ribbon. In other words, the facestock 60 and the ribbon 66 are relaminated together similar to corresponding layers of the first embodiment. The relaminated label stock is appropriately ordered-far printing by thermal transfer printer 90.
After thermal transfer-printing on fixed or variable lengths of the facestock 60, a cutter 92 divides the facestock 60 into individual labels 94 of corresponding lengths. The ribbon 66 can be cut together with the facestock 60 for dispensing with the labelø or can be separately rewound onto a roll similar to the printing system of FIG: 7. Instead of cutting, the facestock 60 could be perforated or aligned with a tear bar for manually separating the facestock 60 into the individual labels 94.
FIG. 9 illustrates an internal transportation system for my new label stock 96 within a thermal printer 98. The new label stock 96 is guided within the printer 98 by a belt 100 that engages an adhesive layer 102 of the label , stock 96 with an endless release surface. The belt 100, which can be coated with a layer of release to prevent the adhesive from sticking, guides the new label stock 96 between a thermal transfer print head 104 and a platen 106. The print head 104 applies a controlled pattern of heat to the back face of the thermal transfer ribbon (see preceding embodiments) for transferring printed images onto the front face of the facestock.
The internal transportation system could also be used to transport other types of self-adhesive facestock through thermal printers, including thermal transfer printers and direct thermal printers. Another such facestock is a self-wound direct thermal printable stock disclosed in United States Patent No. 5,661,099 issued August 26, 1997.

Claims (56)

I CLAIM:
1. A roll of thermal transfer label stock comprising:
a first substrate having front and back faces;
said front face of the first substrate adapted for receiving thermal transfer ink;
an adhesive layer covering at least a portion of said back face of the first substrate;
a second substrate having front and back faces;
a thermal transfer ink layer covering at least a portion of said front face of the second substrate;
a release layer covering at least a portion of said back face of the second substrate; and said first and second substrates being laminated and wound together into coils such that said adhesive layer of the first substrate contacts said release layer of the second substrate.
2. The roll of claim 1 in which said first substrate is cut against said second substrate.
3. The roll of claim 2 in which said cut divides portions of said first substrate into individual labels that are carried by said second substrate.
4. The roll of claim 3 in which said second substrate is a film that resists splitting apart upon partial penetration of a cutting tool.
5. The roll of claim 3 in which said first substrate is a paper that promotes splitting apart upon partial penetration of a cutting tool.
6. The roll of claim 5 in which said first substrate is butt cut into the individual labels.
7. The roll of claim 1 in which said adhesive layer of the first substrate within one coil contacts said release layer of the second substrate within another coil.
8. The roll of claim 7 in which said release layer forms an outer surface of the roll.
9. The, roll of claim 7 further comprising a binder for tacking said first and second substrates together.
10. The roll of claim 9 in which said binder is a fugitive adhesive located between said front faces of the substrates.
11. The roll of claim 10 in which said fugitive adhesive exhibits greater bonding strength between said front faces of the substrates than is exhibited by said adhesive and release layers between said back faces of the substrates.
12. The roll of claim 10 in which said fugitive adhesive is applied in a pattern.
13. The roll of claim 12 in which said fugitive adhesive is applied in strips.
14. The roll of claim l3 in which gaps are formed in said strips of fugitive adhesive to release air between said front faces.
15. The roll of claim 14 in which said fugitive adhesive is applied to edges of said front face of the second substrate.
16. The roll of claim 1 in which said front face of the first substrate within one coil contacts said thermal transfer ink layer of the second substrate within another coil.
17. The roll of claim 16 in which said front face of the first substrate forms an outer surface of the roll.
18. In a self-adhesive thermal transfer label of the type comprising:
a substrate having first and second faces;
said first face of the substrate being receptive to thermal transfer ink;
an adhesive on said second face of the substrate;
a liner having first and second faces; and a release on said first face of the liner for protecting said adhesive prior to use;
the improvement wherein a thermal transfer ink is carried on said second face of the liner for transferring images onto said first face of the substrate.
19. The label of claim 18 in which said first face of the substrate is laminated against said second face of the liner.
20. The label of claim 19 further comprising a fugitive adhesive located between said first face of the substrate and said second face of the liner.
21. The label of claim 20 in which said fugitive adhesive is applied in strips to edges of said second face of the liner.
22. The label of claim 21 in which gaps are formed in said strips of fugitive adhesive to release air between said substrate and said liner.
23. The label of claim 18 in which said substrate is divided into individual labels carried by said liner.
24. The label of claim 23 further comprising a binder for tacking said substrate and said liner together.
25. The label of claim 24 in which said binder is a fugitive adhesive that is applied in a pattern between said first face of the substrate and said second face of the liner for attaching the individual labels to the liner.
26. The label of claim 25 in which said fugitive adhesive exhibits greater bonding strength between said first face of the substrate and said second face of the liner than is exhibited by said adhesive and release between said second face of the substrate and said first face of the liner.
27. The label of claim 23 in which said liner is a film that resists splitting apart upon partial penetration of a cutting tool.
28. The label of claim 18 in which said second face of the substrate is laminated against said first face of the liner.
29. The label of claim 28 in which said substrate is divided into individual labels by series of perforations.
30. The label of claim 18 in which said thermal transfer ink is made from a material that melts from said liner upon application of heat to said first face of the liner.
31. The label of claim 30 in which a non-thermal ink is also applied to one of said faces of the substrate.
32. A method of making labels comprising the steps of:
applying an adhesive to a back face of a thermal transfer facestock;
applying a release coating to a back face of a thermal transfer ribbon;

laminating said facestock and said ribbon together;
and winding said laminated facestock and ribbon into a roll.
33. The method of claim 32 including the further step of dividing the facestock into individual labels.
34. The method of claim 33 in which said step of dividing separates the individual labels by a series of perforations.
35. The method of claim 33 in which said step of dividing includes cutting the facestock against the ribbon.
36. The method of claim 35 in which said step of dividing cuts the facestock into individual labels that are carried by the ribbon.
37. The method of claim 36 in which said step of dividing includes butt cutting the facestock.
38. The method of claim 33 in which said step of laminating includes laminating a front face of the facestock against a front face of the ribbon.
39. The method of claim 38 including the further step of binding the facestock and the ribbon together.
40. The method of claim 39 in which said step of binding includes applying a fugitive adhesive between the front face of the facestock and the front face of the ribbon prior to said step of laminating.
41. The method of claim 40 in which the fugitive adhesive is applied in a pattern that adheres the individual labels to the ribbon.
42. The method of claim 41 in which the fugitive adhesive is applied in strips along edges of the ribbon.
43. The method of claim 32 including the further step of unwinding the roll of laminated web and ribbon into a printer.
44. The method of claim 43 including the further step of applying a controlled pattern of heat to the back face of the thermal transfer ribbon for transferring printed images onto a front face of the facestock.
45. The method of claim 44 including a further step of printing onto one of the front and back faces of the facestock before said step of unwinding the roll.
46. The method of claim 95 in which said further step of printing is performed with a press.
47. The method of claim 32 in which said laminating step includes laminating the back face of the facestock against the back face of the ribbon.
48. The method of claim 47 including the further steps of separating the laminated back faces of the facestock and ribbon and relaminating a front face of the facestock against a front face of the ribbon.
49. The method of claim 48 in which said further steps of separating and relaminating take place after said winding step.
50. The method of claim 49 including the further step of thermal transfer printing onto the front face of the facestock by applying heat to the ribbon following said further steps of separating and relaminating.
51. The method of claim 50 including the further step of dividing the facestock into individual labels.
52. The method of claim 51 in which said step of dividing separates individual labels by a series of perforations.
53. The method of claim 32 including the further step of applying a fugitive adhesive between a front face of the facestock and a front face of the ribbon.
54. The method of claim 53 in which the fugitive adhesive is applied in a pattern.
55. The method of claim 54 in which the fugitive adhesive is applied in strips along edges of the ribbon.
56. The method of claim 55 in which gaps are formed in the strips to release air between the facestock and the ribbon.
CA002190249A 1994-05-13 1995-04-26 Laminated thermal transfer printable labels Expired - Fee Related CA2190249C (en)

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US08/242,313 US5587214A (en) 1994-05-13 1994-05-13 Laminated thermal transfer printable labels
PCT/US1995/005248 WO1995031800A1 (en) 1994-05-13 1995-04-26 Laminated thermal transfer printable labels

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Families Citing this family (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3438447B2 (en) * 1994-12-28 2003-08-18 セイコーエプソン株式会社 Printing apparatus and printing method for tape-shaped recording medium, and tape-shaped recording medium
US5798161A (en) * 1995-01-20 1998-08-25 Dai Nippon Printing Co., Ltd. Optical disk, method of forming image on optical disk, image forming apparatus and adhesive layer transfer sheet
US5578352A (en) * 1995-04-04 1996-11-26 Moore Business Forms, Inc. Strip coated adhesive products
KR100407080B1 (en) * 1995-08-10 2004-03-26 세이코 엡슨 가부시키가이샤 Cartridge for ink jet printer and ink jet printer
US5766714A (en) * 1996-01-30 1998-06-16 Gold Eagle Co. Oil resistant label system
WO1998012053A1 (en) 1996-09-23 1998-03-26 Media Solutions, Inc. Direct thermal printable film and laminate
GB2319762B (en) 1996-11-28 2000-06-28 Instance Ltd David J Manufacture of self-adhesive labels
US6090747A (en) * 1996-12-17 2000-07-18 Labelon Corporation Thermosensitive direct image-recording material
JPH10181111A (en) * 1996-12-27 1998-07-07 Fujicopian Co Ltd Label printing mechanism
DE19704450C2 (en) * 1997-02-06 1999-07-08 Ritter & Co Method and device for producing printed sticky notes
JP3883264B2 (en) * 1997-09-08 2007-02-21 大日本印刷株式会社 Thermal transfer image receiving sheet for sealing and method for producing the same
US6423168B1 (en) * 1997-09-29 2002-07-23 Southern Imperial, Inc. Scanning hook overlays and method of manufacture of same
GB2330347A (en) * 1997-10-16 1999-04-21 Andreas Photiou Authentication by symbols visible when irradiated
GB2330329B (en) * 1997-10-16 2001-11-14 Trip Productions B V Pattern printing of adhesives
US6228486B1 (en) * 1998-10-06 2001-05-08 Avery Dennison Corporation Thermal transfer laminate
US6432528B1 (en) 1998-12-09 2002-08-13 3M Innovative Properties Company Variably printed tape and system for printing and applying tape onto surfaces
US6416835B1 (en) * 1999-04-30 2002-07-09 Grand Rapids Label Company Combination static cling and product label assembly
WO2001025100A1 (en) 1999-10-05 2001-04-12 Flynn Timothy J Envelope
US6220504B1 (en) 1999-10-11 2001-04-24 Timothy J. Flynn Envelope with a removable panel
US6367689B1 (en) 1999-10-05 2002-04-09 Timothy J. Flynn Envelope with a tab
US6383631B1 (en) 2000-04-17 2002-05-07 The Standard Register Company Release coating and barrier coating for linerless thermal labels and method of making
FR2807704A1 (en) * 2000-04-18 2001-10-19 Thomson Csf THERMAL PRINTING METHOD AND DEVICE
US6309498B1 (en) 2000-05-05 2001-10-30 Alfred Doi Self-contained thermal transfer label
US20040018322A1 (en) * 2000-05-08 2004-01-29 Alfred Doi Self-contained thermal transfer label and method of preparation
US6830795B1 (en) 2000-08-28 2004-12-14 The Standard Register Company Stripe coated linerless labels
US7434305B2 (en) 2000-11-28 2008-10-14 Knowles Electronics, Llc. Method of manufacturing a microphone
US6652172B2 (en) 2001-01-05 2003-11-25 3M Innovative Properties Company Method and apparatus for handling linerless label tape within a printing device
US6756095B2 (en) 2001-01-10 2004-06-29 Avery Dennison Corporation Heat-sealable laminate
US6758000B2 (en) 2001-01-10 2004-07-06 Avery Dennison Corporation Livestock security tag assembly
US6773653B2 (en) 2001-10-05 2004-08-10 Avery Dennison Corporation In-mold labeling method
US7716334B2 (en) * 2002-05-17 2010-05-11 Oracle America, Inc. Computer system with dynamically configurable capacity
US7137020B2 (en) * 2002-05-17 2006-11-14 Sun Microsystems, Inc. Method and apparatus for disabling defective components in a computer system
US20030217247A1 (en) * 2002-05-17 2003-11-20 Sun Microsystems, Inc. Method and system for storing field replaceable unit static and dynamic information
US7131030B2 (en) * 2002-05-17 2006-10-31 Sun Microsystems, Inc. Method and system for storing field replaceable unit repair history information
US20030217043A1 (en) * 2002-05-17 2003-11-20 Sun Microsystems, Inc. Method and system for storing field replaceable unit dynamic information using tagged data elements
US20030236998A1 (en) * 2002-05-17 2003-12-25 Sun Microsystems, Inc. Method and system for configuring a computer system using field replaceable unit identification information
US7168007B2 (en) * 2002-05-17 2007-01-23 Sun Microsystems, Inc. Field replaceable unit (FRU) identification system tool
US6716501B2 (en) 2002-07-18 2004-04-06 Avery Dennison Corporation Multilayered film
JP2006507962A (en) 2002-12-02 2006-03-09 エイベリィ デニスン コーポレイション Method for labeling fabric and thermal transfer label suitable for the method
US7309399B2 (en) * 2003-10-30 2007-12-18 Sfs Intec Ag System and method for manufacturing filling strips configured for use with a corrugated member
FR2864314B1 (en) * 2003-12-17 2006-06-09 Mc3 COIL TAPE LABEL HOLDER
US20060105203A1 (en) * 2004-11-15 2006-05-18 Seagate Technology Llc Head disc interface design
US8206543B2 (en) * 2005-05-23 2012-06-26 Ward Kraft Method of manufacturing pattern coated web configurations for use in producing shaped prime labels
GB2457185B (en) * 2006-05-13 2009-09-23 Filtrona United Kingdom Ltd Security laminates and documents
US8445104B2 (en) * 2006-05-18 2013-05-21 MAXStick Products Ltd. Thermally printable adhesive label
US7645355B2 (en) * 2006-11-17 2010-01-12 3M Innovative Properties Company Method of making a microsphere transfer adhesive
US7934531B2 (en) * 2008-04-18 2011-05-03 Brady Worldwide, Inc. Method and apparatus for applying heat activated transfer adhesives
JP5552673B2 (en) * 2009-07-21 2014-07-16 株式会社フジシール Bag-shaped label and method for manufacturing bag-shaped label
US8460774B2 (en) 2010-07-02 2013-06-11 Appleton Papers Inc. Splice tape for imprintable webs
US8800626B2 (en) 2010-11-29 2014-08-12 Klöckner Pentaplast Of America, Inc. System and method for making laminated sheets
US8882955B2 (en) 2011-07-07 2014-11-11 Superior Tape & Label Incorporated Automated labeling method and label supply therefor
FI20115764A0 (en) * 2011-07-20 2011-07-20 Upm Raflatac Oy Label laminates as well as the procedure and system for manufacturing a label laminate
CA2885047A1 (en) * 2012-10-01 2014-04-10 Outlook Group Corp. Method of manufacturing reverse-printed, pressure sensitive cut labels
WO2014165117A1 (en) * 2013-03-13 2014-10-09 Outlook Group Corp. Temporarily removable reverse-printed label assembly
JP2015087758A (en) * 2013-09-26 2015-05-07 サトーホールディングス株式会社 Roll state mount-less label
JP2015087757A (en) * 2013-09-26 2015-05-07 サトーホールディングス株式会社 Roll state mount-less label
JP6476793B2 (en) * 2014-11-27 2019-03-06 シヤチハタ株式会社 Label printing sheet structure
NL2014345B1 (en) 2015-02-24 2016-10-13 T T R Euroworks B V Thermal transfer printing spool, production method therefor, printing method, and use of a thermal transfer printer.
US10538116B2 (en) * 2018-01-31 2020-01-21 Postek Electronics Co., Ltd Thermal transfer printer, composite consumable thereof and method for supplying such composite consumable to thermal transfer printer
JP6683233B2 (en) * 2018-10-12 2020-04-15 シヤチハタ株式会社 Sheet structure for label printing
US10889423B2 (en) * 2019-01-22 2021-01-12 W/S Packaging Group, Inc. Bonding label
US11059646B2 (en) * 2019-01-22 2021-07-13 W/S Packaging Group, Inc. Bonding label
KR102040477B1 (en) * 2019-05-27 2019-11-27 (주)남양프린트 Method of manufacturing functional roll sticker labels with added security and sticker labels manufactured by them

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3332829A (en) * 1964-02-18 1967-07-25 Avery Adhesive Products Inc Article for multiplicate marking
US4104816A (en) * 1976-12-16 1978-08-08 Doring Labels, Inc. Multi-function label and carrier web
US4244605A (en) * 1977-10-25 1981-01-13 Minnesota Mining And Manufacturing Company Material for forming graphics
US4253899A (en) * 1979-03-08 1981-03-03 Avery International Corporation Method of making matrix free thin labels
JPS5635144A (en) * 1979-08-31 1981-04-07 Nippon Telegr & Teleph Corp <Ntt> Two-color recording paper and recording method using this
JPS5769091A (en) * 1980-10-17 1982-04-27 Ricoh Co Ltd Peel-off type heatsensitive recording paper
US4370370A (en) * 1981-06-08 1983-01-25 Ricoh Company, Ltd. Thermosensitive recording adhesive label
US4415615A (en) * 1982-01-15 1983-11-15 Minnesota Mining And Manufacturing Co. Cellular pressure-sensitive adhesive product and method of making
US4541340A (en) * 1982-07-02 1985-09-17 Markem Corporation Process for forming permanent images using carrier supported inks containing sublimable dyes
JPS59107264A (en) * 1982-12-11 1984-06-21 Sanko Junyaku Kk Measuring method of total bilirubin in blood
IT1160123B (en) * 1983-05-03 1987-03-04 Vibac Spa PRESSURE-SENSITIVE SELF-ADHESIVE TAPE PROVIDED WITH A PRINTABLE NON-STICKER LACQUER AND LACQUER COMPOSITION FOR THE DEPOSITION OF SUCH LAYER
JPS6054842A (en) * 1983-09-06 1985-03-29 日本製紙株式会社 Thermal-sensing color-developing tacky label and manufacturethereof
US4525566A (en) * 1984-03-02 1985-06-25 Dow Corning Corporation Coating method and silicone composition for PSA release coating
US4587156A (en) * 1984-03-02 1986-05-06 Minnesota Mining And Manufacturing Company Directly printable pressure-sensitive adhesive tape
IT1173584B (en) * 1984-05-04 1987-06-24 Boston Spa SELF-ADHESIVE TAPE OF WRITABLE TYPE
US4633276A (en) * 1984-05-25 1986-12-30 Ricoh Electronics, Inc. Thermosensitive recording label
US4577204A (en) * 1984-05-25 1986-03-18 Ricoh Electronics, Inc. Thermosensitive recording label
US4590497A (en) * 1984-11-05 1986-05-20 Ricoh Electronics, Inc. Heat insulated thermosensitive paper
US4784714A (en) * 1986-02-10 1988-11-15 Ricoh Electronics, Inc. Linerless thermal label printer and applicator
CA1323982C (en) * 1986-07-14 1993-11-09 Sadayuki Ohki Indication element with protective layer and process for producing the same
US4851383A (en) * 1987-06-08 1989-07-25 Ricoh Electronics, Inc. Non-laminate thermosensitive, pressure sensitive label and method of manufacture
FR2622146A1 (en) * 1987-10-26 1989-04-28 Duport Jean Claude COMPOSITE RIBBON FOR LABEL PRINTING MACHINES AND MACHINE USING SUCH A RIBBON
US4898849A (en) * 1987-12-29 1990-02-06 Nashua Corporation Coated thermally printable material and method of producing the same
US4886774A (en) * 1988-08-09 1989-12-12 Alfred Doi Ultraviolet protective overcoat for application to heat sensitive record materials
CA2001646C (en) * 1988-10-28 1996-05-28 Takeo Suzuki Thermo-transfer sheet and label and manufacturing method of the same
GB8829229D0 (en) * 1988-12-15 1989-01-25 Esselte Meto Int Gmbh Medium for printing and its use
JPH02165988A (en) * 1988-12-20 1990-06-26 Ricoh Co Ltd Label for thermal recording
US5264279A (en) * 1989-09-19 1993-11-23 Dai Nippon Insatsu Kabushiki Kaisha Composite thermal transfer sheet
EP0442823B1 (en) * 1990-02-16 1995-01-18 Tomoegawa Paper Co. Ltd. Thermal printing medium and label incorporating the same
IT1241569B (en) * 1990-09-24 1994-01-18 Vibac Spa REFINEMENTS MADE TO A SILENT PRINTABLE SELF-ADHESIVE TAPE
US5427840A (en) * 1990-11-29 1995-06-27 Dai Nippon Printing Co., Ltd. Thermal transfer sheet
US5242650A (en) * 1991-09-09 1993-09-07 Avery Dennison Corporation In-mold labelling a coextruded, stretched and annealed label
US5226994A (en) * 1992-03-05 1993-07-13 Rand Mcnally & Company Method of making improved baggage tag stock
US5674345A (en) * 1992-07-01 1997-10-07 Moore Business Forms, Inc. Linerless label printer applicator
US5292713A (en) * 1992-07-15 1994-03-08 Stenzel Herbert J Linerless thermal and thermal transfer labels
EP0600622A1 (en) * 1992-11-30 1994-06-08 Moore Business Forms, Inc. A linerless thermally printed baggage tag
CA2129068A1 (en) * 1993-08-02 1995-02-03 Karl Schroeder Printing system for linerless labels

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ES2123981T3 (en) 1999-01-16
EP0759200A1 (en) 1997-02-26
AU2367595A (en) 1995-12-05
DE69504498T2 (en) 1999-04-22
US5738748A (en) 1998-04-14
US5587214A (en) 1996-12-24
EP0759200B1 (en) 1998-09-02
WO1995031800A1 (en) 1995-11-23
DE69504498D1 (en) 1998-10-08
CA2190249A1 (en) 1995-11-23
JPH10500784A (en) 1998-01-20

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