CA2177225A1 - Method for preparing ultraviolet radiation absorbing contact lenses - Google Patents

Method for preparing ultraviolet radiation absorbing contact lenses

Info

Publication number
CA2177225A1
CA2177225A1 CA002177225A CA2177225A CA2177225A1 CA 2177225 A1 CA2177225 A1 CA 2177225A1 CA 002177225 A CA002177225 A CA 002177225A CA 2177225 A CA2177225 A CA 2177225A CA 2177225 A1 CA2177225 A1 CA 2177225A1
Authority
CA
Canada
Prior art keywords
ultraviolet radiation
radiation absorbing
contact lenses
absorbing agent
absorbing contact
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002177225A
Other languages
French (fr)
Other versions
CA2177225C (en
Inventor
Frank F. Molock
Ivan M. Nunez
James D. Ford
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson and Johnson Vision Care Inc
Original Assignee
Frank F. Molock
Ivan M. Nunez
James D. Ford
Johnson & Johnson Vision Products, Inc.
Johnson & Johnson Vision Care, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Frank F. Molock, Ivan M. Nunez, James D. Ford, Johnson & Johnson Vision Products, Inc., Johnson & Johnson Vision Care, Inc. filed Critical Frank F. Molock
Publication of CA2177225A1 publication Critical patent/CA2177225A1/en
Application granted granted Critical
Publication of CA2177225C publication Critical patent/CA2177225C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F9/00Methods or devices for treatment of the eyes; Devices for putting-in contact lenses; Devices to correct squinting; Apparatus to guide the blind; Protective devices for the eyes, carried on the body or in the hand
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/14Esterification
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12Chemical modification
    • C08J7/14Chemical modification with acids, their salts or anhydrides
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041Lenses
    • G02B1/043Contact lenses
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/20Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/30Chemical modification of a polymer leading to the formation or introduction of aliphatic or alicyclic unsaturated groups

Abstract

Disclosed is a process for producing an ultraviolet radiation absorbing contact lens from a lens shaped polymer having hydroxyl groups pendant therefrom and having dispersed therein a UV absorbing agent substituted with at least one anhydride group which is exposed to basic conditions such that the hydroxyl groups react with the anhydride groups on the UV absorbing agent. As a result the UV absorbing agent becomes fixed to the polymer through the formation of a covalent ester bond.
CA002177225A 1995-05-24 1996-05-23 Method for preparing ultraviolet radiation absorbing contact lenses Expired - Lifetime CA2177225C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/449,004 US5681871A (en) 1995-05-24 1995-05-24 Method for preparing ultraviolet radiation absorbing contact lenses
US08/449,004 1995-05-24

Publications (2)

Publication Number Publication Date
CA2177225A1 true CA2177225A1 (en) 1996-11-25
CA2177225C CA2177225C (en) 2008-01-29

Family

ID=23782485

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002177225A Expired - Lifetime CA2177225C (en) 1995-05-24 1996-05-23 Method for preparing ultraviolet radiation absorbing contact lenses

Country Status (17)

Country Link
US (1) US5681871A (en)
EP (1) EP0744632B1 (en)
JP (1) JP3894984B2 (en)
KR (1) KR960040331A (en)
CN (1) CN1078130C (en)
AT (1) ATE226324T1 (en)
AU (1) AU693676B2 (en)
BR (1) BR9602405A (en)
CA (1) CA2177225C (en)
DE (1) DE69624285T2 (en)
HU (1) HUP9601413A3 (en)
IL (1) IL118228A0 (en)
NO (1) NO962104L (en)
NZ (1) NZ286575A (en)
SG (1) SG81895A1 (en)
TW (1) TW326499B (en)
ZA (1) ZA964143B (en)

Families Citing this family (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5856661A (en) * 1993-02-12 1999-01-05 Universal Magnifier Llc Credit card with magnifying lens formed with a radiation-curable resin
US6817532B2 (en) * 1992-02-12 2004-11-16 Lenscard U.S., Llc Wallet card with built-in light
US6769618B1 (en) 1992-02-12 2004-08-03 Lenscard U.S., Llc Wallet card with a magnifying lens and light
US6176430B1 (en) 1992-02-12 2001-01-23 Lenscard U.S. Llc Method for making a wallet card with an integral magnifying lens
US6022498A (en) * 1996-04-19 2000-02-08 Q2100, Inc. Methods for eyeglass lens curing using ultraviolet light
US6280171B1 (en) 1996-06-14 2001-08-28 Q2100, Inc. El apparatus for eyeglass lens curing using ultraviolet light
KR100218315B1 (en) * 1996-09-17 1999-09-01 구본준 Level shift circuit
US5989462A (en) 1997-07-31 1999-11-23 Q2100, Inc. Method and composition for producing ultraviolent blocking lenses
JP4541540B2 (en) * 1997-08-28 2010-09-08 ノバルティス アーゲー Methods and compositions for introducing radiation absorbers into polymers
US5891932A (en) * 1997-11-24 1999-04-06 Benz Research And Development Corporation Terpolymer for contact lens
US6149692A (en) * 1998-08-27 2000-11-21 Novartis Ag Method and composition for incorporating radiation-absorbing agents into polymers
US6478990B1 (en) 1998-09-25 2002-11-12 Q2100, Inc. Plastic lens systems and methods
US7879288B2 (en) 1999-03-01 2011-02-01 Johnson & Johnson Vision Care, Inc. Method and apparatus of sterilization using monochromatic UV radiation source
US6419873B1 (en) 1999-03-19 2002-07-16 Q2100, Inc. Plastic lens systems, compositions, and methods
US6271281B1 (en) * 1999-08-26 2001-08-07 Medennium, Inc. Homopolymers containing stable elasticity inducing crosslinkers and ocular implants made therefrom
JP3547662B2 (en) * 1999-09-20 2004-07-28 Hoya株式会社 Plastic spectacle lens excellent in ultraviolet absorption and method of manufacturing the same
JP3676138B2 (en) 1999-09-20 2005-07-27 Hoya株式会社 Plastic spectacle lens excellent in ultraviolet absorption and manufacturing method thereof
JP2001255498A (en) * 2000-03-09 2001-09-21 Menicon Co Ltd Method for manufacturing ultraviolet absorptive low hydrous soft contact lens
US6716375B1 (en) 2000-03-30 2004-04-06 Q2100, Inc. Apparatus and method for heating a polymerizable composition
US6698708B1 (en) 2000-03-30 2004-03-02 Q2100, Inc. Gasket and mold assembly for producing plastic lenses
US6723260B1 (en) 2000-03-30 2004-04-20 Q2100, Inc. Method for marking a plastic eyeglass lens using a mold assembly holder
US6632535B1 (en) 2000-06-08 2003-10-14 Q2100, Inc. Method of forming antireflective coatings
US6709257B2 (en) 2001-02-20 2004-03-23 Q2100, Inc. Eyeglass lens forming apparatus with sensor
US6790024B2 (en) 2001-02-20 2004-09-14 Q2100, Inc. Apparatus for preparing an eyeglass lens having multiple conveyor systems
US6726463B2 (en) 2001-02-20 2004-04-27 Q2100, Inc. Apparatus for preparing an eyeglass lens having a dual computer system controller
US6790022B1 (en) 2001-02-20 2004-09-14 Q2100, Inc. Apparatus for preparing an eyeglass lens having a movable lamp mount
US6712331B2 (en) 2001-02-20 2004-03-30 Q2100, Inc. Holder for mold assemblies with indicia
US6758663B2 (en) 2001-02-20 2004-07-06 Q2100, Inc. System for preparing eyeglass lenses with a high volume curing unit
US6612828B2 (en) 2001-02-20 2003-09-02 Q2100, Inc. Fill system with controller for monitoring use
US6655946B2 (en) 2001-02-20 2003-12-02 Q2100, Inc. Apparatus for preparing an eyeglass lens having a controller for conveyor and curing units
US6752613B2 (en) 2001-02-20 2004-06-22 Q2100, Inc. Apparatus for preparing an eyeglass lens having a controller for initiation of lens curing
US6702564B2 (en) 2001-02-20 2004-03-09 Q2100, Inc. System for preparing an eyeglass lens using colored mold holders
US6808381B2 (en) 2001-02-20 2004-10-26 Q2100, Inc. Apparatus for preparing an eyeglass lens having a controller
US6676399B1 (en) 2001-02-20 2004-01-13 Q2100, Inc. Apparatus for preparing an eyeglass lens having sensors for tracking mold assemblies
US6676398B2 (en) 2001-02-20 2004-01-13 Q2100, Inc. Apparatus for preparing an eyeglass lens having a prescription reader
US6783721B2 (en) * 2001-10-30 2004-08-31 Howmedica Osteonics Corp. Method of making an ion treated hydrogel
US6464484B1 (en) 2002-03-30 2002-10-15 Q2100, Inc. Apparatus and system for the production of plastic lenses
US20030223954A1 (en) * 2002-05-31 2003-12-04 Ruscio Dominic V. Polymeric materials for use as photoablatable inlays
US6899866B2 (en) * 2002-09-06 2005-05-31 Cph Innovations Corporation Photostabilization of a sunscreen composition with a combination of an α-cyano-β, β-diphenylacrylate compound and a dialkyl naphithalate
US6919473B2 (en) * 2002-09-17 2005-07-19 Cph Innovations Corporation Photostabilizers, UV absorbers, and methods of photostabilizing a sunscreen composition
US7544350B2 (en) * 2002-11-22 2009-06-09 Hallstar Innovations Corp. Method of decreasing the UV light degradation of polymers
US20050070661A1 (en) * 2003-09-30 2005-03-31 Frank Molock Methods of preparing ophthalmic devices
US7534420B2 (en) * 2004-02-25 2009-05-19 Hallstar Innovations Corp. Compounds derived from polyanhydride resins with film-forming, UV-absorbing, and photostablizing properties, compositions containing same, and methods of using the same
US7235587B2 (en) * 2004-07-01 2007-06-26 Cph Innovations Corporation Diesters containing two crylene or fluorene moieties, sunscreen compositions containing the same, and methods of photostabilizing a sunscreen compositions containing the same
US20060069178A1 (en) * 2004-09-24 2006-03-30 Bausch & Lomb Incorporated Method for polymerizing ophthalmic devices
US7887882B2 (en) * 2005-02-09 2011-02-15 Essilor International (Compagnie Generale D'optique) Stabilized ultra-violet absorbers
US8158678B2 (en) * 2005-04-07 2012-04-17 Cph Innovations Corp. Photoabsorbing, highly conjugated compounds of cyanoacrylic esters, sunscreen compositions and methods of use
US20060252850A1 (en) * 2005-05-04 2006-11-09 Bausch & Lomb Incorporated Radiation-absorbing polymeric materials and ophthalmic devices comprising same
US7438411B2 (en) * 2005-05-07 2008-10-21 Nanospectra Biosciences, Inc. Plasmon resonant based eye protection
JP5675647B2 (en) 2009-01-19 2015-02-25 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se Organic black pigment and its production
BR112012005626A2 (en) * 2009-09-15 2016-08-02 Novartis Ag Suitable prepolymers for making ultraviolet absorption contact lenses
CN101824748B (en) * 2010-04-06 2012-12-26 广东名鼠股份有限公司 Finishing method using anti-ultraviolet finishing agent
KR101564490B1 (en) * 2010-07-30 2015-10-29 노파르티스 아게 Method for making uv-absorbing ophthalmic lenses
JP5784119B2 (en) 2010-07-30 2015-09-24 ノバルティス アーゲー Amphiphilic polysiloxane prepolymers and their use
WO2012047961A1 (en) 2010-10-06 2012-04-12 Novartis Ag Polymerizable chain-extended polysiloxanes with pendant hydrophilic groups
US8835525B2 (en) 2010-10-06 2014-09-16 Novartis Ag Chain-extended polysiloxane crosslinkers with dangling hydrophilic polymer chains
EP2625218B1 (en) 2010-10-06 2018-04-25 Novartis AG Water-processable silicone-containing prepolymers and uses thereof
US9395468B2 (en) 2012-08-27 2016-07-19 Ocular Dynamics, Llc Contact lens with a hydrophilic layer
TW201940393A (en) * 2013-05-27 2019-10-16 日商參天製藥股份有限公司 Sealing label having identification function and container wrapped in the sealing label
WO2015073758A1 (en) 2013-11-15 2015-05-21 Ocular Dynamics, Llc Contact lens with a hydrophilic layer
EP3229851A4 (en) 2014-12-09 2018-08-01 Tangible Science LLC Medical device coating with a biocompatible layer
CN105599329B (en) * 2015-12-28 2018-01-30 哈尔滨工业大学 A kind of preparation method of antibacterial ultraviolet-resistannanofiber light contact lenses
JP2019520966A (en) * 2016-06-23 2019-07-25 メディセム インスティテュート エス.アール.オー. Photo-adjustable hydrogel and bioanalogous intraocular lens
CA3096600A1 (en) 2018-05-01 2019-11-07 Bausch & Lomb Incorporated Ophthalmic devices containing uv blocker and methods for their preparation
US11046636B2 (en) * 2018-06-29 2021-06-29 Johnson & Johnson Vision Care, Inc. Polymerizable absorbers of UV and high energy visible light

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2976576A (en) * 1956-04-24 1961-03-28 Wichterle Otto Process for producing shaped articles from three-dimensional hydrophilic high polymers
DE1065621B (en) * 1970-08-05 1959-09-17 Prag Dr Otto Wichterle Process for the production of hydrophilic, swollen or strongly swellable molded structures
US4157892A (en) * 1973-02-21 1979-06-12 Toyo Contact Lens Company, Limited Method of coloring water-absorbable plastics and colored water-absorbable plastics
US4304895A (en) * 1973-06-20 1981-12-08 Wesley-Jessen, Inc. Ultraviolet absorbing corneal contact lenses
USRE33477E (en) * 1973-06-20 1990-12-04 Wesley-Jessen, Inc. Ultraviolet absorbing hydrophilic corneal contact lenses
US4390676A (en) * 1976-11-15 1983-06-28 Schering Corporation Ultraviolet absorbing lenses
US4565348A (en) * 1981-04-30 1986-01-21 Mia-Lens Production A/S Mold for making contact lenses, the male mold member being more flexible than the female mold member
US4495313A (en) * 1981-04-30 1985-01-22 Mia Lens Production A/S Preparation of hydrogel for soft contact lens with water displaceable boric acid ester
US4379893A (en) * 1981-08-26 1983-04-12 Diamond Shamrock Corporation Surface-treated soft contact lenses
US4426492A (en) * 1981-09-03 1984-01-17 Plastomedical Sciences, Inc. Disposable, hydrogel soft contact lenses
US4486577A (en) * 1982-10-12 1984-12-04 Ciba-Geigy Corporation Strong, silicone containing polymers with high oxygen permeability
US4891046A (en) * 1984-03-15 1990-01-02 Coopervision, Inc. Tinted contact lens and method for preparation with dichlorotriazine reactive dye
US4680336A (en) * 1984-11-21 1987-07-14 Vistakon, Inc. Method of forming shaped hydrogel articles
US4687816A (en) * 1985-08-14 1987-08-18 Sola U.S.A. Inc. Surface treatment of soft contact lenses
US4803254A (en) * 1987-03-11 1989-02-07 Iolab Corporation Vinylsilylalkoxy arylbenzotriazole compounds and UV absorbing compositions made therefrom
JPH0761357B2 (en) * 1988-03-28 1995-07-05 ホーヤ株式会社 Intraocular lens
AU631190B2 (en) * 1989-03-14 1992-11-19 Novartis Ag Ultraviolet absorbing lenses and methods of making the same
US5298033A (en) * 1989-03-14 1994-03-29 Ciba-Geigy Corporation Ultraviolet absorbing lenses and methods of manufacturing thereof
US4963160A (en) * 1989-03-14 1990-10-16 Ciba-Geigy Corporation Reactive uv absorbing compositions and method of preparing lenses therefrom
US5376737A (en) * 1991-04-25 1994-12-27 Allergan, Inc. Methods for benefitting polymers
US5292350A (en) * 1992-04-24 1994-03-08 Vistakon, Inc. Method for preparing tinted contact lens
US5457140A (en) * 1993-07-22 1995-10-10 Johnson & Johnson Vision Products, Inc. Method of forming shaped hydrogel articles including contact lenses using inert, displaceable diluents
US5480927A (en) * 1994-05-20 1996-01-02 Ciba Geigy Corporation Method of increasing the concentration of radiation-absorbing agents in optical and ophthalmic lenses
WO1999009042A2 (en) * 1997-08-13 1999-02-25 Cepheid Microstructures for the manipulation of fluid samples

Also Published As

Publication number Publication date
SG81895A1 (en) 2001-07-24
ATE226324T1 (en) 2002-11-15
NO962104L (en) 1996-11-25
JPH09120042A (en) 1997-05-06
EP0744632A1 (en) 1996-11-27
JP3894984B2 (en) 2007-03-22
NO962104D0 (en) 1996-05-23
DE69624285T2 (en) 2003-07-03
AU693676B2 (en) 1998-07-02
KR960040331A (en) 1996-12-17
ZA964143B (en) 1997-11-24
AU5243096A (en) 1996-12-05
HUP9601413A2 (en) 1997-01-28
TW326499B (en) 1998-02-11
CA2177225C (en) 2008-01-29
CN1144738A (en) 1997-03-12
IL118228A0 (en) 1996-09-12
EP0744632B1 (en) 2002-10-16
CN1078130C (en) 2002-01-23
US5681871A (en) 1997-10-28
HUP9601413A3 (en) 1998-07-28
HU9601413D0 (en) 1996-07-29
DE69624285D1 (en) 2002-11-21
BR9602405A (en) 1998-04-22
NZ286575A (en) 1997-10-24

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Effective date: 20160524