CA2176277A1 - Aldehyde-based surfactant and method for treating industrial, commercial, and institutional waste-water - Google Patents

Aldehyde-based surfactant and method for treating industrial, commercial, and institutional waste-water

Info

Publication number
CA2176277A1
CA2176277A1 CA002176277A CA2176277A CA2176277A1 CA 2176277 A1 CA2176277 A1 CA 2176277A1 CA 002176277 A CA002176277 A CA 002176277A CA 2176277 A CA2176277 A CA 2176277A CA 2176277 A1 CA2176277 A1 CA 2176277A1
Authority
CA
Canada
Prior art keywords
hydrogen
aldehyde
dioxolane
hydrophobic
residue
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002176277A
Other languages
French (fr)
Other versions
CA2176277C (en
Inventor
Denise Christine Galante
Richard Charles Hoy
Albert Ferris Joseph
Stephen Wayne King
Charles Arnold Smith
Cheryl Marie Wizda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Publication of CA2176277A1 publication Critical patent/CA2176277A1/en
Application granted granted Critical
Publication of CA2176277C publication Critical patent/CA2176277C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
    • B01D17/02—Separation of non-miscible liquids
    • B01D17/04—Breaking emulsions
    • B01D17/047—Breaking emulsions with separation aids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/017—Mixtures of compounds
    • C09K23/018—Mixtures of two or more different organic oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/547—Tensides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
    • C09K23/42—Ethers, e.g. polyglycol ethers of alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
    • C08G2650/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group
    • C08G2650/44—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type containing oxygen in addition to the ether group containing acetal or formal groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C11D2111/12—
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S210/00—Liquid purification or separation
    • Y10S210/902—Materials removed
    • Y10S210/908—Organic

Abstract

A nonionic surfactant having cyclic 1,3-dioxane and/or 1,3-dioxolane functionality is irreversibly splittable by lowering the pH of its aqueous solution. The cyclic 1,3-dioxolane has the formula:

(see figure I) The 1,3-dioxolane has the formula:

(see figure II) of which R is hydrogen and R' has no alkoxy linkage and is the residue of an organic compound (substituted or unsubstituted) derived from an aldehyde of the formula (see figure III) wherein R is hydrogen and R' is the residue of an organic compound (substituted or unsubstituted) which contains a total of 8 to 20 carbon atoms and which contains no moieties or linkages which significantly interfere with the performance of the surfactant for its intended purpose; X is hydrogen or the residue of a hydrophobic end-cap; Y is hydrogen, methyl, ethyl, or mixtures thereof; Z is hydrogen, methyl, or ethyl; m is 0 or 1; and n is an integer of 1 to 40. After splitting of the surfactant into its components aldehyde and polyol, the hydrophobic components phase-separate and can be removed from the aqueous stream by routine means. The nonionic surfactant is useful in various processes requiring the removal of emulsified hydrophobic contaminants or other hydrophobic materials from an aqueous stream.
CA002176277A 1995-05-12 1996-05-10 Aldehyde-based surfactant and method for treating industrial, commercial, and institutional waste-water Expired - Fee Related CA2176277C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/439,964 1995-05-12
US08/439,964 US5744065A (en) 1995-05-12 1995-05-12 Aldehyde-based surfactant and method for treating industrial, commercial, and institutional waste-water

Publications (2)

Publication Number Publication Date
CA2176277A1 true CA2176277A1 (en) 1996-11-13
CA2176277C CA2176277C (en) 2001-07-03

Family

ID=23746857

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002176277A Expired - Fee Related CA2176277C (en) 1995-05-12 1996-05-10 Aldehyde-based surfactant and method for treating industrial, commercial, and institutional waste-water

Country Status (9)

Country Link
US (4) US5744065A (en)
EP (1) EP0742177B1 (en)
KR (1) KR100329452B1 (en)
CN (2) CN1143536A (en)
AU (1) AU708763B2 (en)
CA (1) CA2176277C (en)
DE (1) DE69612421T2 (en)
DK (1) DK0742177T3 (en)
MY (1) MY132307A (en)

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Also Published As

Publication number Publication date
DK0742177T3 (en) 2001-07-23
DE69612421T2 (en) 2001-11-22
KR960041066A (en) 1996-12-17
CA2176277C (en) 2001-07-03
US5744065A (en) 1998-04-28
MY132307A (en) 2007-10-31
KR100329452B1 (en) 2002-10-11
CN1385509A (en) 2002-12-18
CN1143536A (en) 1997-02-26
US6051035A (en) 2000-04-18
AU5222396A (en) 1996-11-21
US6306249B1 (en) 2001-10-23
EP0742177A1 (en) 1996-11-13
EP0742177B1 (en) 2001-04-11
AU708763B2 (en) 1999-08-12
US5919372A (en) 1999-07-06
DE69612421D1 (en) 2001-05-17

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