CA2176276A1 - Ketone-based surfactant and method for treating industrial, commercial, and institutional waste-water - Google Patents
Ketone-based surfactant and method for treating industrial, commercial, and institutional waste-waterInfo
- Publication number
- CA2176276A1 CA2176276A1 CA002176276A CA2176276A CA2176276A1 CA 2176276 A1 CA2176276 A1 CA 2176276A1 CA 002176276 A CA002176276 A CA 002176276A CA 2176276 A CA2176276 A CA 2176276A CA 2176276 A1 CA2176276 A1 CA 2176276A1
- Authority
- CA
- Canada
- Prior art keywords
- ketone
- surfactant
- hydrogen
- hydrophobic
- unsubstituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000002576 ketones Chemical class 0.000 title abstract 3
- 239000004094 surface-active agent Substances 0.000 title abstract 3
- 239000002351 wastewater Substances 0.000 title 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 2
- 239000002736 nonionic surfactant Substances 0.000 abstract 2
- 150000002894 organic compounds Chemical class 0.000 abstract 2
- VDFVNEFVBPFDSB-UHFFFAOYSA-N 1,3-dioxane Chemical compound C1COCOC1 VDFVNEFVBPFDSB-UHFFFAOYSA-N 0.000 abstract 1
- 125000006091 1,3-dioxolane group Chemical group 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000000356 contaminant Substances 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000000203 mixture Chemical group 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/547—Tensides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D17/00—Separation of liquids, not provided for elsewhere, e.g. by thermal diffusion
- B01D17/02—Separation of non-miscible liquids
- B01D17/04—Breaking emulsions
- B01D17/047—Breaking emulsions with separation aids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/32—Heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/42—Ethers, e.g. polyglycol ethers of alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
- C02F2001/425—Treatment of water, waste water, or sewage by ion-exchange using cation exchangers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
Abstract
A nonionic surfactant having cyclic 1,3-dioxane and/or 1,3-dioxolane functionality which is irreversibly splittable by lowering the pH of its aqueous solution is useful in various processes requiring the removal of emulsified hydrophobic contaminants or other hydrophobic materials from an aqueous stream. After splitting of the surfactant into its component ketone and polyol, the hydrophobic components phase-separate and can be removed from the aqueous stream by routine means. The non-ionic surfactant is represented by the formulas:
or, of which R and R' are the residue of an organic compound (substituted or unsubstituted) which does not contain a beta-alkoxy substituent or other moieties or linkages which significantly interfere with the performance of the surfactant for its intended purpose and derived from a ketone of the formula
or, of which R and R' are the residue of an organic compound (substituted or unsubstituted) which does not contain a beta-alkoxy substituent or other moieties or linkages which significantly interfere with the performance of the surfactant for its intended purpose and derived from a ketone of the formula
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/439,953 | 1995-05-12 | ||
US08/439,953 US5744064A (en) | 1995-05-12 | 1995-05-12 | Ketone-based surfactant and method for treating industrial, commerical, and institutional waste-water |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2176276A1 true CA2176276A1 (en) | 1996-11-13 |
CA2176276C CA2176276C (en) | 2001-07-03 |
Family
ID=23746800
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002176276A Expired - Fee Related CA2176276C (en) | 1995-05-12 | 1996-05-10 | Ketone-based surfactant and method for treating industrial, commercial, and institutional waste-water |
Country Status (9)
Country | Link |
---|---|
US (2) | US5744064A (en) |
EP (1) | EP0742178B1 (en) |
JP (1) | JPH09164385A (en) |
KR (1) | KR960041065A (en) |
CN (2) | CN1151332A (en) |
AU (1) | AU693341B2 (en) |
CA (1) | CA2176276C (en) |
DE (1) | DE69614029T2 (en) |
DK (1) | DK0742178T3 (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5744064A (en) * | 1995-05-12 | 1998-04-28 | Union Carbide Chemicals & Plastics Technology Corporation | Ketone-based surfactant and method for treating industrial, commerical, and institutional waste-water |
US5744065A (en) * | 1995-05-12 | 1998-04-28 | Union Carbide Chemicals & Plastics Technology Corporation | Aldehyde-based surfactant and method for treating industrial, commercial, and institutional waste-water |
US6110231A (en) * | 1998-06-01 | 2000-08-29 | Boehme Filatex, Inc. | Method of processing textile products utilizing decomposable emulsifiers |
US6623649B2 (en) * | 2000-06-06 | 2003-09-23 | Bp Koln Gmbh | Process for removing cyclic acetals from wastewater streams |
US7201227B2 (en) * | 2004-12-20 | 2007-04-10 | Bj Services Company | Method and composition for treating a subterranean formation with splittable foams |
US20080108522A1 (en) * | 2006-11-07 | 2008-05-08 | Bj Services Company | Use of anionic surfactants as hydration aid for fracturing fluids |
US7816305B2 (en) * | 2008-05-15 | 2010-10-19 | Halliburton Energy Services, Inc. | Reversible surfactants and methods of use in subterranean formations |
EP2905370A1 (en) * | 2008-06-19 | 2015-08-12 | Electrolux Home Products Corporation N.V. | Washing method and washing machine implementing this method |
US8349777B2 (en) * | 2010-11-22 | 2013-01-08 | Chevron Oronite Company Llc | Lubricating composition containing 1,3-dioxolane-4-methanol compounds as antiwear additives |
US8518267B2 (en) | 2011-12-15 | 2013-08-27 | General Electric Company | Treatment of surfactant laden wastewater |
US11230476B2 (en) | 2013-12-30 | 2022-01-25 | Total Marketing Services | Dissolved air flotation use with cationic metal processing fluids |
Family Cites Families (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2905719A (en) * | 1959-09-22 | Cxhzo | ||
US3244753A (en) * | 1966-04-05 | Process f-or manufacture cf acetals | ||
GB414772A (en) * | 1932-11-05 | 1934-08-07 | Ig Farbenindustrie Ag | Improvements in the manufacture and production of substances suitable as wetting, washing, dispersing and like agents |
NL89229C (en) * | 1952-11-29 | |||
US2786081A (en) * | 1954-01-08 | 1957-03-19 | Quaker Chemical Products Corp | Acetal condensation products |
US3058981A (en) * | 1958-11-14 | 1962-10-16 | Richardson Merrell Inc | 2-methyl-2-nonyl-4-hydroxymethyl-1, 3-dioxolane and carbamates thereof |
FR1302969A (en) * | 1960-06-25 | 1962-09-07 | Molins Y Puigarnau S R C | Process for obtaining a product endowed with great stability, with all the properties emanating from active chlorine at relatively high temperatures |
NL295816A (en) * | 1962-07-27 | |||
US3948953A (en) * | 1969-08-05 | 1976-04-06 | Texaco Inc. | Dioxolane derivatives having surfactant properties |
US3909460A (en) * | 1969-08-05 | 1975-09-30 | Texaco Inc | Detergent compositions containing dioxolanes as surfactants and their preparation |
US3725438A (en) * | 1970-10-16 | 1973-04-03 | Petro Tex Chem Corp | Production of cyclic acetals |
US4060532A (en) * | 1972-03-15 | 1977-11-29 | Ici United States Inc. | Halogenated dioxolane tranquilizers |
US3931337A (en) * | 1974-08-19 | 1976-01-06 | Basf Wyandotte Corporation | Multi-block polyacetal copolymer surfactants |
US4189609A (en) * | 1974-08-19 | 1980-02-19 | Basf Wyandotte Corporation | Multi-block coupled polyoxyalkylene copolymer surfactants |
FR2302969A1 (en) * | 1975-03-03 | 1976-10-01 | Mitsui Toatsu Chemicals | PROCESS FOR THE TREATMENT OF DEOILING RESIDUAL WATER CONTAINING OILY SUBSTANCES |
US4198294A (en) * | 1975-06-16 | 1980-04-15 | The Redux Corporation, Inc. | Water purification system |
CA1075718A (en) * | 1975-12-12 | 1980-04-15 | Gerhard W. H. Scherf | Acetals as enervatable surface-active organic compounds |
SE439505B (en) * | 1977-10-20 | 1985-06-17 | Montedison Spa | WASHING PROCEDURE FOR DEPARTMENT OF PRINTED RETURN PAPER AND DEPOSITION COMPOSITION |
US4360439A (en) * | 1977-10-20 | 1982-11-23 | Montedison S.P.A. | Composition for the de-inking of printed waste paper by the washing process |
EP0054366A3 (en) * | 1980-12-15 | 1982-08-11 | Imperial Chemical Industries Plc | Novel surface active agents and compositions comprising them |
US4408084A (en) * | 1981-01-09 | 1983-10-04 | Basf Wyandotte Corporation | Non-ionic surfactants containing acetal groups |
JPS5813530A (en) * | 1981-07-20 | 1983-01-26 | Kao Corp | 2,3-dialkoxypropyl glyceryl ether, its preparation, and cosmetic containing the same |
US4605773A (en) * | 1982-08-10 | 1986-08-12 | Diamond Shamrock Chemicals Company | Low-foaming, pH sensitive, alkylamine polyether surface active agents and methods for using |
US4483741A (en) * | 1982-08-10 | 1984-11-20 | Economics Laboratory, Inc. | Low-foaming, pH sensitive, alkylamine polyether surface active agents and methods for using |
DE3318592A1 (en) * | 1983-05-21 | 1984-11-22 | Hoechst Ag, 6230 Frankfurt | Surface-active polyglycol ether acetals |
US4675125A (en) * | 1984-07-02 | 1987-06-23 | Cincinnati-Vulcan Company | Multi-purpose metal cleaning composition containing a boramide |
DE3441542A1 (en) * | 1984-11-14 | 1986-05-15 | Hoechst Ag, 6230 Frankfurt | BORDER AREA ACTIVE POLYGLYCOLAETHERACETALE |
US4977281A (en) * | 1987-12-21 | 1990-12-11 | Milliken Research Corporation | Polyoxyalkylene amino alcohols and polyoxyalkylene amino 1,3-dioxanes and 1,3-dioxolanes |
US5076937A (en) * | 1990-07-26 | 1991-12-31 | Unitog Rental Services, Inc. | Method for removal of fat, oil and grease from laundry wash water |
US5114607A (en) * | 1990-08-08 | 1992-05-19 | Betz Laboratories, Inc. | Low foaming alkaline cleaner comprising a surfactant mixture of an EO-PO-EO block copolymer and a PO-ZO-PO block copolymer |
US5207922A (en) * | 1990-10-25 | 1993-05-04 | Diversey Corporation | Method for treating laundry waste water |
US5167829A (en) * | 1991-06-21 | 1992-12-01 | Harold Diamond | System for treating commercial waste effluents |
US5246590A (en) * | 1991-06-21 | 1993-09-21 | Dober Chemical Corporation | Water treatment to reduce fog levels controlled with streaming current detector |
US5137654A (en) * | 1991-10-17 | 1992-08-11 | Eaton Corporation | Process for reclaiming oil/water emulsion |
US5744064A (en) * | 1995-05-12 | 1998-04-28 | Union Carbide Chemicals & Plastics Technology Corporation | Ketone-based surfactant and method for treating industrial, commerical, and institutional waste-water |
US5744065A (en) * | 1995-05-12 | 1998-04-28 | Union Carbide Chemicals & Plastics Technology Corporation | Aldehyde-based surfactant and method for treating industrial, commercial, and institutional waste-water |
-
1995
- 1995-05-12 US US08/439,953 patent/US5744064A/en not_active Expired - Lifetime
-
1996
- 1996-05-10 DE DE69614029T patent/DE69614029T2/en not_active Expired - Fee Related
- 1996-05-10 EP EP96303261A patent/EP0742178B1/en not_active Expired - Lifetime
- 1996-05-10 DK DK96303261T patent/DK0742178T3/en active
- 1996-05-10 CA CA002176276A patent/CA2176276C/en not_active Expired - Fee Related
- 1996-05-10 JP JP8151458A patent/JPH09164385A/en active Pending
- 1996-05-10 AU AU52224/96A patent/AU693341B2/en not_active Ceased
- 1996-05-10 KR KR1019960015339A patent/KR960041065A/en active IP Right Grant
- 1996-05-11 CN CN96108424A patent/CN1151332A/en active Pending
-
1997
- 1997-11-26 US US08/978,920 patent/US5851434A/en not_active Expired - Fee Related
-
2001
- 2001-07-17 CN CN01123061A patent/CN1336423A/en active Pending
Also Published As
Publication number | Publication date |
---|---|
KR960041065A (en) | 1996-12-17 |
CN1336423A (en) | 2002-02-20 |
EP0742178A1 (en) | 1996-11-13 |
DE69614029D1 (en) | 2001-08-30 |
JPH09164385A (en) | 1997-06-24 |
US5744064A (en) | 1998-04-28 |
EP0742178B1 (en) | 2001-07-25 |
AU5222496A (en) | 1996-11-21 |
US5851434A (en) | 1998-12-22 |
AU693341B2 (en) | 1998-06-25 |
DK0742178T3 (en) | 2001-11-05 |
DE69614029T2 (en) | 2002-03-14 |
CN1151332A (en) | 1997-06-11 |
CA2176276C (en) | 2001-07-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |