CA2169596A1 - Storage-stable dual polymerizable composition comprising a peroxide and monomer component - Google Patents

Storage-stable dual polymerizable composition comprising a peroxide and monomer component

Info

Publication number
CA2169596A1
CA2169596A1 CA002169596A CA2169596A CA2169596A1 CA 2169596 A1 CA2169596 A1 CA 2169596A1 CA 002169596 A CA002169596 A CA 002169596A CA 2169596 A CA2169596 A CA 2169596A CA 2169596 A1 CA2169596 A1 CA 2169596A1
Authority
CA
Canada
Prior art keywords
peroxide
storage
composition
weight
percent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002169596A
Other languages
French (fr)
Other versions
CA2169596C (en
Inventor
Joachim E. Klee
Uwe Walz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dentsply GmbH
Original Assignee
Dentsply GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dentsply GmbH filed Critical Dentsply GmbH
Publication of CA2169596A1 publication Critical patent/CA2169596A1/en
Application granted granted Critical
Publication of CA2169596C publication Critical patent/CA2169596C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/891—Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • A61K6/893—Polyurethanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/20—Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K6/00—Preparations for dentistry
    • A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
    • A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
    • A61K6/891—Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds

Abstract

The invention provides a polymerizabie composition formed by mixing a liquid and a powder composition. The liquid composition includes a peroxide, which decomposes by at most fifty percent by weight of the peroxide within 10 hours at a temperature of at least 75 °C, and a polymerizable monomer. The powder composition comprising a proton donor, and a metal containing compound. The polymerizable composition has from 0.2 to 5 percent by weight of the peroxide, from 5 to 99 percent by weight of the polymerizable monomer, and from 0.1 to 3 percent by weight of the proton donor, and from 0.02 to 3 percent by weight of the metal containing compound. The polymerizable composition has an initial setting time and a storage setting time after storage of the first (liquid) composition for at least 12 months at a temperature of at least 23°C. The initial setting time is within 2 minutes of the storage setting time.
CA002169596A 1995-03-14 1996-02-15 Storage-stable dual polymerizable composition comprising a peroxide and monomer component Expired - Fee Related CA2169596C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/404,402 US5688883A (en) 1995-03-14 1995-03-14 Polymerizable composition
US08/404,402 1995-03-14

Publications (2)

Publication Number Publication Date
CA2169596A1 true CA2169596A1 (en) 1996-09-15
CA2169596C CA2169596C (en) 2007-05-01

Family

ID=23599460

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002169596A Expired - Fee Related CA2169596C (en) 1995-03-14 1996-02-15 Storage-stable dual polymerizable composition comprising a peroxide and monomer component

Country Status (4)

Country Link
US (1) US5688883A (en)
EP (1) EP0732098B1 (en)
CA (1) CA2169596C (en)
DE (1) DE69621500T2 (en)

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US20020068771A1 (en) * 1997-02-21 2002-06-06 Dentsply Detrey Gmbh. Low shrinking polymerizable dental material
DE69942571D1 (en) * 1998-04-23 2010-08-26 Dentsply Detrey Gmbh Storage-resistant polymerizable composition
DE19928238A1 (en) * 1999-06-21 2000-12-28 Espe Dental Ag Polymerizable dental composition, useful for e.g. filling, temporary crown or bridge, cement, technical material or facing, contains barbituric acid derivative or malonylsulfamide and peroxycarboxylic ester
DE10124029B4 (en) * 2001-05-16 2004-08-26 3M Espe Ag Initiator system for acidic dental formulations
DE10339557A1 (en) * 2003-08-26 2005-04-07 Heraeus Kulzer Gmbh Dental filling material
US20070100019A1 (en) * 2005-08-02 2007-05-03 Fuming Sun Catalyst system for dental compositions
DE102005039590B4 (en) * 2005-08-19 2008-05-21 Heraeus Kulzer Gmbh Polymerizable dental composition with a 2-component initiator system
EP1872767A1 (en) * 2006-06-30 2008-01-02 Ernst Mühlbauer GmbH & Co.KG Polymérisable dental material
US20080286724A1 (en) * 2007-05-18 2008-11-20 Ormco Corporation Orthodontic adhesives
DE102007050762B3 (en) * 2007-10-22 2009-05-07 Heraeus Medical Gmbh Paste polymethyl methacrylate bone cement and its use
DE102007050763A1 (en) 2007-10-22 2009-04-23 Heraeus Medical Gmbh Self-curing resin initiator system, its use, and bone cement compositions containing it
DE102009058638A1 (en) * 2009-12-16 2011-06-22 Ernst Mühlbauer GmbH & Co. KG, 25870 Multi-component system for producing a dental material
DE102010024653B4 (en) 2010-06-22 2012-06-21 Heraeus Medical Gmbh Kit for making bone cement and using this kit
DE102012003117A1 (en) * 2012-02-16 2013-08-22 Heinrich-Heine-Universität Düsseldorf Antimicrobial filler mixture
US10932994B2 (en) * 2014-07-10 2021-03-02 3M Innovative Properties Company Two-component self-adhesive dental composition, process of production and use thereof
US10470981B2 (en) 2015-08-28 2019-11-12 Gc Corporation Dental cement
CN108366911A (en) 2015-12-08 2018-08-03 3M创新有限公司 Two component autoadhesion dental compositions, the initiator system and their purposes of stable storing
US11510851B2 (en) 2016-10-05 2022-11-29 3M Innovative Properties Company Application device with redox initiator system, method of production and use thereof
CN112996472A (en) 2018-11-14 2021-06-18 3M创新有限公司 Storage stable two-part dual cure dental composition

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FR1089198A (en) * 1952-12-12 1955-03-15 Bayer Ag Plastic materials for dental use
US3200142A (en) * 1963-02-01 1965-08-10 Rafael L Bowen Surface-active comonomer and method of preparation
US3293233A (en) * 1963-04-09 1966-12-20 Rexall Drug Chemical Process for polymerizing ethylene at high pressures in the presence of a mixture of peroxides having different half lives
CA878004A (en) * 1968-06-14 1971-08-10 Ii Henry L. Lee Dental filling package
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JPS5774369A (en) * 1980-10-28 1982-05-10 Mitsui Petrochem Ind Ltd Coating composition
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JPS59137404A (en) * 1983-01-27 1984-08-07 Kuraray Co Ltd Dental adhesive
JPS59140276A (en) * 1983-01-31 1984-08-11 Kuraray Co Ltd Novel adhesive
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US4547531A (en) * 1984-08-02 1985-10-15 Pentron Corporation Two component (paste-paste) self-curing dental restorative material
DE3536076A1 (en) * 1985-10-09 1987-04-09 Muehlbauer Ernst Kg POLYMERIZABLE CEMENT MIXTURES
JP2677994B2 (en) * 1986-10-06 1997-11-17 株式会社クラレ adhesive
DE3730921A1 (en) * 1987-09-15 1989-03-23 Degussa HITZEHAERTBARE DENTAL MASSES
JP2690138B2 (en) * 1988-03-28 1997-12-10 株式会社トクヤマ Adhesive composition
DE3928987A1 (en) * 1989-09-01 1991-03-28 Siegfried Reiss METHOD AND SHAPE FORM FOR PRODUCING SHAPINGS FOR THE DENTAL AREA
JPH0819173B2 (en) * 1990-09-14 1996-02-28 テルモ株式会社 Polymerization initiator composition for controlling polymerization at interface and curable composition containing the same
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Also Published As

Publication number Publication date
EP0732098A3 (en) 1997-01-22
EP0732098A2 (en) 1996-09-18
EP0732098B1 (en) 2002-06-05
DE69621500D1 (en) 2002-07-11
US5688883A (en) 1997-11-18
DE69621500T2 (en) 2003-01-23
CA2169596C (en) 2007-05-01

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Legal Events

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MKLA Lapsed

Effective date: 20160215