CA2168405A1 - Polyurethane-based thickeners for aqueous compositions - Google Patents

Polyurethane-based thickeners for aqueous compositions

Info

Publication number
CA2168405A1
CA2168405A1 CA002168405A CA2168405A CA2168405A1 CA 2168405 A1 CA2168405 A1 CA 2168405A1 CA 002168405 A CA002168405 A CA 002168405A CA 2168405 A CA2168405 A CA 2168405A CA 2168405 A1 CA2168405 A1 CA 2168405A1
Authority
CA
Canada
Prior art keywords
mole
thickeners
aqueous compositions
optionally
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002168405A
Other languages
French (fr)
Other versions
CA2168405C (en
Inventor
Klaus Konig
Jurgen Schwindt
Jan Mazanek
Josef Pedain
Manfred Dietrich
Gerhard Klein
Karl-Roland Jerg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of CA2168405A1 publication Critical patent/CA2168405A1/en
Application granted granted Critical
Publication of CA2168405C publication Critical patent/CA2168405C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/43—Thickening agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyethers (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a process for the preparation of polyurethanes suitable for use as thickeners for aqueous compositions by reacting at an NCO/OH equivalent ratio of 0.9:1 to 1.2:1 a) a polyether component having an OH number of 10 to 30 mg KOH/g and obtained by the alkoxylation of a mixture of a1) 30 to 80 mole % of a monofunctional alcohol or alkylphenol having 8 to 30 carbon atoms, a2) 2 to 10 mole % of sodium hydroxide or potassium hydroxide, a3) 10 to 60 mole % of water and a4) 0 to 10 mole % of a trihydric to hexahydric alcohol having a molecular weight of 92 to 600, with ethylene oxide or a mixture of ethylene oxide with up to 20 mole %, based on the total moles of alkylene oxides, of propylene oxide, in which the percentages of a1) to a4) add up to 100, with b) a polyisocyanate component containing at least one organic diisocyanate, optionally in admixture with up to 20 mole %, based on the total moles of component b), of higher than difunctional polyisocyanates. The invention also relates to the polyurethanes obtainable by this method and their use, optionally in combination with other thickeners, for the thickening of aqueous systems.
CA002168405A 1995-02-02 1996-01-30 Polyurethane-based thickeners for aqueous compositions Expired - Fee Related CA2168405C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19503281.0 1995-02-02
DE19503281A DE19503281A1 (en) 1995-02-02 1995-02-02 Polyurethanes suitable as thickeners for aqueous systems

Publications (2)

Publication Number Publication Date
CA2168405A1 true CA2168405A1 (en) 1996-08-03
CA2168405C CA2168405C (en) 2007-08-28

Family

ID=7752939

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002168405A Expired - Fee Related CA2168405C (en) 1995-02-02 1996-01-30 Polyurethane-based thickeners for aqueous compositions

Country Status (7)

Country Link
US (1) US5612408A (en)
EP (1) EP0725097B1 (en)
JP (1) JP3673314B2 (en)
CA (1) CA2168405C (en)
DE (2) DE19503281A1 (en)
DK (1) DK0725097T3 (en)
ES (1) ES2137569T3 (en)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3581450B2 (en) * 1995-09-01 2004-10-27 旭電化工業株式会社 Emulsion paint composition
ES2191167T3 (en) * 1996-02-24 2003-09-01 Henkel Kgaa SOLID, ADHERENT MASS, THAT GETS REMOVED WITH SOFTNESS, IN THE FORM OF A GLUE BAR.
US5856285A (en) * 1997-10-31 1999-01-05 Nouveau Technologies, Inc. Polyurethane adhesive/sealant remover
AU770290B2 (en) * 1998-08-06 2004-02-19 National Starch And Chemical Investment Holding Corporation Novel associative thickeners for aqueous systems
DE19945574A1 (en) * 1999-09-23 2001-04-05 Basf Coatings Ag Use of associative thickeners based on polyurethane and / or dipropylene glycol monoalkyl ethers to suppress optical defects in color and / or effect multi-layer coatings or their refinish coatings
JP4650967B2 (en) * 2000-08-28 2011-03-16 株式会社Ａｄｅｋａ Water-based metallic base coating composition containing a thickener and viscosity modifier
DE10118268A1 (en) * 2001-04-12 2002-10-17 Cognis Deutschland Gmbh Production of polyetherurethane thickeners useful in cosmetic compositions, involves reacting an ethoxylated fatty alcohol with a diisocyanate
EP1541643B1 (en) * 2003-12-10 2013-03-13 Rohm And Haas Company Nonionic associative thickener containing condensation polymer backbone
DE102004008015A1 (en) * 2004-02-19 2005-09-08 Cognis Deutschland Gmbh & Co. Kg Thickener for polyurethane base
JP4904463B2 (en) * 2005-09-02 2012-03-28 サンノプコ株式会社 Viscosity improver
JP4904464B2 (en) * 2005-09-02 2012-03-28 サンノプコ株式会社 Viscosity improver
DE102006027490A1 (en) * 2006-06-14 2007-12-20 Borchers Gmbh Water-soluble or -dispersible polyurethane for use as a thickener for aqueous paint or adhesives, obtained by reacting polyether-polyol with di-isocyanate and an unsaturated mono-alcohol or mono-alcohol alkoxylate
EP2114365B1 (en) * 2007-01-31 2010-09-01 Basf Se Cationic conditioning agent
SG188159A1 (en) * 2008-02-26 2013-03-28 Cambrios Technologies Corp Methods and compositions for ink jet deposition of conductive features
JP2011523630A (en) * 2008-05-06 2011-08-18 ビーエーエスエフ ソシエタス・ヨーロピア Polyurethane as a means of modifying the rheology of cosmetic formulations
EP2184304A1 (en) 2008-05-06 2010-05-12 Basf Se Polyurethane thickener
AU2011298459A1 (en) 2010-09-01 2013-03-14 Basf Se Associative thickener for aqueous preparations
US8871817B2 (en) 2010-10-22 2014-10-28 Basf Se Polyurethane thickeners
AU2011317583A1 (en) 2010-10-22 2013-05-02 Basf Se Polyurethane thickener
US9175125B2 (en) 2010-10-22 2015-11-03 Basf Se Polyurethane thickeners
RU2013123091A (en) 2010-10-22 2014-11-27 Басф Се POLYURETHANE THICKENERS
KR101924770B1 (en) * 2011-01-20 2018-12-04 바스프 에스이 Dendritic polyether-polyurethane thickeners
US9066891B2 (en) 2011-01-20 2015-06-30 Base Se Dendritic polyether-polyurethane thickeners
FR2976579B1 (en) * 2011-06-14 2013-07-05 Coatex Sas NONIONIC ASSOCIATIVE THICKENERS CONTAINING ALKYLS CYCLOHEXYLOLS, FORMULATIONS CONTAINING SAME AND USES THEREOF
FR2976580B1 (en) * 2011-06-14 2013-05-31 Coatex Sas ASSOCIATIVE NONIONIC THICKENERS CONTAINING ALKYLS CYCLOHEXYLOLS, FORMULATIONS CONTAINING SAME AND USES THEREOF.
JP2014521797A (en) 2011-08-05 2014-08-28 ビーエイエスエフ・ソシエタス・エウロパエア Associative thickeners based on hyperbranched polymers
CA2878312C (en) * 2012-07-06 2019-04-30 Sumitomo Seika Chemicals Co., Ltd. Modified polyalkylene oxide
CN104211941A (en) * 2014-08-12 2014-12-17 安徽大学 Preparation method of linear and star polyethylene associated thickening agent
US20230108458A1 (en) 2020-03-13 2023-04-06 Adeka Corporation Oily composition and cosmetic composition containing said oily composition

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1444243A1 (en) 1963-03-16 1968-10-24 Bayer Ag Process for dyeing or printing textile materials
NL6504268A (en) * 1965-04-03 1966-10-04
US4079028A (en) 1975-10-03 1978-03-14 Rohm And Haas Company Polyurethane thickeners in latex compositions
US4155892A (en) 1975-10-03 1979-05-22 Rohm And Haas Company Polyurethane thickeners for aqueous compositions
CA1177988A (en) 1979-12-26 1984-11-13 Robert J. Knopf Production of high viscosity liquid polyether- urethane block copolymers
US4499233A (en) 1983-05-03 1985-02-12 Nl Industries, Inc. Water dispersible, modified polyurethane and a thickened aqueous composition containing it
DE3630319A1 (en) 1986-09-05 1988-03-10 Akzo Gmbh THICKENING AGENT
US5023309A (en) 1987-09-18 1991-06-11 Rheox, Inc. Water dispersible, modified polyurethane thickener with improved high shear viscosity in aqueous systems
DE4101239C1 (en) 1991-01-17 1992-04-02 Th. Goldschmidt Ag, 4300 Essen, De
AU662511B2 (en) * 1991-02-08 1995-09-07 Sherwin-Williams Company, The Silicon-containing, hydrophobically-modified polyurethane thickeners
DE4137247A1 (en) * 1991-11-13 1993-05-19 Henkel Kgaa THICKENERS ON POLYURETHANE BASE
DE4310702A1 (en) * 1993-04-01 1994-10-06 Bayer Ag Polyurethane-based thickener preparation and its use for thickening aqueous systems

Also Published As

Publication number Publication date
US5612408A (en) 1997-03-18
ES2137569T3 (en) 1999-12-16
JP3673314B2 (en) 2005-07-20
JPH08253548A (en) 1996-10-01
EP0725097A1 (en) 1996-08-07
DK0725097T3 (en) 2000-04-10
DE59603114D1 (en) 1999-10-28
EP0725097B1 (en) 1999-09-22
DE19503281A1 (en) 1996-08-08
CA2168405C (en) 2007-08-28

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Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20160201