CA2166091A1 - A hardwood floor cleaning composition comprising an alkyl pyrrolidone - Google Patents

A hardwood floor cleaning composition comprising an alkyl pyrrolidone

Info

Publication number
CA2166091A1
CA2166091A1 CA002166091A CA2166091A CA2166091A1 CA 2166091 A1 CA2166091 A1 CA 2166091A1 CA 002166091 A CA002166091 A CA 002166091A CA 2166091 A CA2166091 A CA 2166091A CA 2166091 A1 CA2166091 A1 CA 2166091A1
Authority
CA
Canada
Prior art keywords
copolymer
hardwood floor
methyl
vinylpyrrolidone
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002166091A
Other languages
French (fr)
Inventor
Frank Fusiak
Kolazi S. Narayanan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Verona Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2166091A1 publication Critical patent/CA2166091A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/28—Heterocyclic compounds containing nitrogen in the ring
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C11D17/0021—Aqueous microemulsions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam

Abstract

A hardwood floor cleaner composition is provided which is non-tacky, and cleans and shines in one-step, is free of silicones, does not dull the wood surface. The composition comprises (a) about 0.1-5 %, preferably 0.2-2 %, of a C6-C24 alkyl pyrrolidone, preferably N-octyl-pyrrolidone; (b) about 0.1-5 %, preferably 0.2-1 %, of an anionic or nonionic surfactant, preferably sodium dodecyl sulfate; (c) about 1-5 %, preferably 2-4 %, of a shine booster, preferably a vinylpyrrolidone copolymer, such as vinylpyrrolidone-dimethylaminoethyl methyacrylate (Gafquat? 755-N - ISP); and (d) about 05-2 %, preferably 0.8-15 %, of a film-former, for example, all acrylic emulsion, preferably Esi-Cryl? 405 (Emulsion Systems Inc.), which is 2-methyl-2-propenoic acid, copolymer with ethyl-2-propenoate, methyl-2-methyl propenoate and 2-propenoic acid, and (e) about 85-95 %, preferably 88-93 %, of water, or an alcohol or mixtures thereof, by weight of the composition. A concentrate and an aqueous microemulsion of the composition of the invention also is provided herein.

Description

C) 95/00611 t; ~ ~ ~ 3 PCT/US94/03999 A HARDWOOD FLOOR CLEANING COMPOSITION COMPRISING AN ALKYL
PYRROLIDONE
BACKGROUND OF THE INVENTION

1. Field of the Invention This invention relates to hardwood floor cleaner compositions, and, more particularly, to a composition for this use which is non-tacky, cleans and shines in one-step, is free of silicones, and does not dull the wood surface being cleaned.
2. Description of the Prior Art EPA 0467472A2 discloses a hard surface liquid cleAni~g composition with an anti-soiling polymer, which, however, is primarily used for bathroom porcelain and tiles. U.S. Patent 4,368,146 describes a light duty hand dishwashing liquid detergent composition for kitchen utensils and glasses.

DETAILED DESCRIPTION OF THE INVENTION

In the hardwood floor cleaner composition herein, component (a) is a C6-C24 alkyl pyrrolidone which functions effectively to clean the floor. Most preferred are alkyl pyrrolidones selected from N-octylpyrrolidone, N-dodecylpyrrolidone or mixtures thereof. Suitably component (a) is present in the composition in an amount of about 0.1-5~, preferably 0.2-2%, by weight of the composition.
Component (b) of the composition is a surfactant, and is preferably an anionic or nonionic surfactant. As representative of the anionic surfactant, alkali metal salts of C8-C22 aliphatic surfactants such as WO95/00611 2 ~ 9 1 2 PCT~S94/03999 -sodium dodecyl sulfate or sulfonate, alkali metal salts of alkyl aromatic sulfonates or sulfates, and ethoxylated derivatives of the above, such as the alkylphenyl ethoxylated phosphate esters, may be used. The anionic surfactants are believed to form pseudo salts or ion v pairs with the higher alkyl pyrrolidone component (a~, which can produce an advantageous synergistic effect on wetting and surface spreading for the composition.
Sodium dodecyl (lauryl) sulfate is a preferred anionic surfactant. Component (b) suitably is present in an amount of about 0.1-5%, preferably 0.2-1%, by weight of the composition.
In combination, components (a) and (b) of the composition of the invention in a solvent such as water or alcohol, or mixtures thereof, provide a clear to slightly hazy aqueous microemulsion.
Component (c) of the composition provides a shine booster function for the composition. Suitable shine boosters are copolymers of vinylpyrrolidone, such as a copolymer of vinylpyrrolidone-dimethylaminoethyl methacrylate (Gafquat~ 755-N - ISP); vinylpyrrolidone-vinyl acetate, vinylpyrrolidone-acrylic acid; and vinylpyrrolidone-methaminopropyl trimethyl ammonium chloride. The shine booster is present in the composition in an amount of about 1-5% as supplied, preferably 2-4%, of the composition; or 0.2 to 1.0% based on the solids content of the composition.
Component (d) of the composition provides a film-former function for the composition; it is present in an amount of about 0.5-2%, preferably 0.8-1.5%, of the composition. Suitable film-formers are acrylic emulsions, such as Esi-Cryl~ 405 sold by Emulsion Systems Inc., which is a copolymer of 2-methyl-2-propopenoic acid with ethyl-2-propenoate, methyl-2-methylpropenoate and 2-propenoic acid; styrene acrylic emulsion sold as Carboset0 (Union Carbide); acrylic emulsions sold as Conrez~ (Morton Int.); and Joncryl~ (S.C. Johnson).

95/~611 ~1 ~ G D 9 ~ PCT~S94/03999 The combination of components (c) and (d) in the compositions forms a barrier of a water-film on the hardwood surface which prevents or reduces contact of the surface with oil or dirt thus keeping the appearance of the surface shiny and clean-looking.
Component (e) of the composition is water, or alcohol, or mixtures thereof, in an amount of about 85-95%, preferably 88-93%, by weight of the composition.
Optional ingredients in the composition of the invention include a neutralizing agent for the acrylic em~lsion to make it clear; a plasticizer; a fragrance; a bittering agent; dyes; and auxiliary surfactants to improve leveling.
The composition may be applied to a wood surface by spraying, then damp mopping, or the concentrate may be added to a bucket of water, mixed, and then applied using a damp mop.

CQNCENTRAT~
Component 5uitable Preferred (a) Surfadone LP-100 1-50 6.12 (b) Stepanol WAC 1-50 10.20 (c) GAFQUAT 755-N 10-50 25.51 (d) Esi-Cryl 405 5-50 24.49 (e) Isopropanol or Water10-70 30.61 Lemon Fragrance 1.02 Zonyl FSo 2.04 Ammonium hydroxide 1.30 The microemulsion composition of the invention is made by a given amount of the concentrate with water, J' or alcohol, or mixtures thereof, in a 1:10 ratio. The resultant aqueous microemulsion composition is shown in Table 2 below.

WO95/00611 2 l ~ 1 PCT~S94/0399 Preferred (a) Surfadone LP-100 0.6 (b) Stepanol WAC 1.0 (c) GAFQUAT 755-N 2.5 (d) Esi-Cryl 405 2.4 (e) Deionized water 90.2 Isopropanol 3.0 Lemon Fragrance 0.1 Zonyl FSO 0.2 Ammonium Hydroxide Q.S. to pH = 8.5 The compositions listed in the Table below were prepared by mixing the several components of the composition at ambient conditions in the order listed until a clear, homogeneous solution was obtained. Then 5.0 g of each formulation was applied onto a clean glass plate, and wiped evenly with a damp sponge and allowed to air-dry. The resultant appearance of the film was evaluated for clarity and tackiness. Formulations that produced clear, non-tacky films were tested on hardwood floor t~les as follows: 5 ml of a given formulation was applied to a 6 inch by 6 inch prefi n; ~hed TopFlor Oak Grain Parquet Genuine Hardwood Floor Tile and wiped clean over the surface with a damp sponge. After air dyring, the 60 specular gloss was measured before and after cleaning using a BYK-Gardner micro-TRI-gloss gloss meter, and the change in gloss was calculated. The results are shown below in Table 3.

O 95/00611 ~ 7 9 1 PCT/US94/03999 ~o o o ~ ~ t~ o O ~1 U~ ~ O 1 u~ o o~ l co o ~
~D I I I I N ~1 O ~ ~ ~ O O

~O O O ~ ~ CO O
Itl I I I I N J.
O ~I t~ ~ O O ~ 1~ -- ~.0 0 11~ ~ N ~ O ~ ~1 .. ~, . . I I ,. . , . . a, - o ,~ ~ ~ o o ~ ~D O O ~ ~ ~ O ~t ~: o .1 u~ ~ o ~ r~ _ O
o ~

1~ . L
U~ O ~ ~ ~ D O 0 ~ m .. IIII ..... ~, O _I N O O

~o o In ~ ~ ~D O ~ oo ,,~ . . . I I I I UJ C~ -O ~I ~ O O ~ 1~7 --~ 1~') o _ O L
Z t) a a I ~
'J ~ - o o .~ O ` O
IJ 0 -~ ~ I I I 0 5 ~ ~
_ ~ n5 JJ e W w ~ n5 ~ 4 _~ t E~ 4 4 t` :2~ ~5 tq ~ ~ ~ ~ L~ ~ ~ a5 ~c5 : - ~ _ P p P P t.) ~ .C --I ~ ~ O
~ 5 ~ a ~ o c ~ 5 ~ O

I L ~ 4 ~ U 3 ~: P P ~3: tq o 0 ~ u 5 ~ ~ u '15 O :~ O ~ P~ W N ~ Ll r: ~ o n5 O t _ ~ r n5 ~2 V ~5 0 _ _ _ _ _ t,r WO95/00611 ~ ~ 6 ~ 6 - PCT~S94/03999 -While the invention has been described with particular reference to certain embodiments thereof, it will be understood that changes and modifications may be made which are within the skill of the art. Accordingly, it is intended to be bound only by the following claims, in which:

Claims (7)

WHAT IS CLAIMED IS:
1. A hardwood floor cleaner composition comprising, by weight of the composition, (a) about 0.1-5% of a C6-C24 alkyl pyrrolidone, (b) about 0.1-5% of a surfactant, (c) about 1-5% of a shine booster, (d) about 0.5-2% of a film-former, and (e) about 85-95% of water or alcohol, or mixtures thereof.
2 . A hardwood floor cleaner according to claim 1 wherein:
(a) is about 0.2-2%, (b) is about 0.2-1%, (c) is about 2-4%, (d) is about 0.8-1.5%, and (e) is about 88-93%.
3. A hardwood floor cleaner composition according to claim 1 wherein:
(a) is N-octylpyrrolidone, N-dodecylpyrrolidone, or mixtures thereof;
(b) is an anionic or nonionic surfactant;
(c) is a copolymer of vinylpyrrolidone and a polymerizable monomer; and (d) is an acrylic emulsion.
4. A hardwood floor cleaner according to claim 1 wherein:
(a) is N-octylpyrrolidone or N-dodecylpyrrolidone;
(b) is sodium dodecyl sulfate, sodium dodecyl sulfonate; a sodium salt of an alkyl aromatic sulfonate or sulfate, or ethoxylated derivatives thereof;
(c) is a copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate, a copolymer of vinylpyrrolidone and acrylic acid, a copolymer of vinylpyrrolidone and vinyl acetate; or a copolymer of vinylpyrrolidone and methaminopropyl trimethyl ammonium chloride;
(d) is an acrylic emulsion of 2-methyl-2-propenoic acid copolymer with ethyl-2-propenoate, methyl-2-methyl propenoate and 2-propenoic acid, or an acrylic-styrene emulsion and (e) is predominately water.
5. A hardwood floor cleaner according to claim 1 wherein:
(a) is N-octylpyrrolidone, (b) is sodium dodecyl sulfate, (c) is a copolymer of vinylpyrrolidone and dimethylaminoethyl methacrylate, (d) is an acrylic emulsion of 2-methyl-2-propenoic acid copolymer with ethyl-2-propenoate, methyl-2-methyl propenoate and 2-propenoic acid, and (e) is predominately water.
6. A concentrate of a hardwood floor cleaner composition according to claim 1 wherein (a) is about 1-50%, (b) is about 1-50%, (c) is about 10-50%, (d) is about 5-50%, and (e) is about 10-70.
7. A method of cleaning and shining a hardwood floor in one step to provide a cleaned and shiny wood surface which also is non-tacky, and free of silicones, which comprises applying the hardwood floor cleaner composition of claim 1 to a hardwood floor and wiping the applied surface cleaner after a predetermined period of application.
CA002166091A 1993-06-25 1994-04-12 A hardwood floor cleaning composition comprising an alkyl pyrrolidone Abandoned CA2166091A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/082,315 1993-06-25
US08/082,315 US5409639A (en) 1993-06-25 1993-06-25 Hardwood floor cleaner composition

Publications (1)

Publication Number Publication Date
CA2166091A1 true CA2166091A1 (en) 1995-01-05

Family

ID=22170442

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002166091A Abandoned CA2166091A1 (en) 1993-06-25 1994-04-12 A hardwood floor cleaning composition comprising an alkyl pyrrolidone

Country Status (3)

Country Link
US (1) US5409639A (en)
CA (1) CA2166091A1 (en)
WO (1) WO1995000611A1 (en)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5641742A (en) * 1993-04-14 1997-06-24 Colgate-Palmolive Co. Microemulsion all purpose liquid cleaning compositions
DE4335046A1 (en) * 1993-10-14 1995-04-20 Henkel Kgaa Aqueous floor cleaning agent
CA2200747A1 (en) * 1994-09-23 1996-03-28 Alfredo Vinci Aqueous metal cleaner
US5526320A (en) * 1994-12-23 1996-06-11 Micron Technology Inc. Burst EDO memory device
ES2163091T3 (en) * 1996-01-25 2002-01-16 Unilever Nv DETERGENT COMPOSITION.
HUP0001073A3 (en) * 1997-01-10 2003-02-28 Unilever Nv Detergent compositions and copolymers for inhibiting dye transfer
US6484735B1 (en) 1997-02-14 2002-11-26 The Procter & Gamble Company Alkaline liquid hard-surface cleaning compositions comprising N-vinylpyrrolidone copolymer
WO1998036046A1 (en) * 1997-02-14 1998-08-20 The Procter & Gamble Company Alkaline liquid hard-surface cleaning compositions comprising n-vinylpyrrolidone copolymer
US5981456A (en) * 1997-07-23 1999-11-09 Lever Brothers Company Automatic dishwashing compositions containing water soluble cationic or amphoteric polymers
DE69833506T2 (en) * 1997-11-21 2006-09-28 The Procter & Gamble Company, Cincinnati LIQUID DETERGENT COMPOSITIONS CONTAIN POLYMER FOAM IMAGES
PL340632A1 (en) 1997-11-21 2001-02-12 Procter & Gamble Detergent compositions containing polymeric froth generation enhancing agents and their application
NZ337058A (en) * 1997-12-12 2001-03-30 Church & Dwight Co Inc Composition for cleaning hard surfaces, comprising a synergistic blend of a surface tension reducing agent, a superwetting agent and an organic coupling and/or degreasing agent
AU2496599A (en) 1998-06-02 1999-12-20 Procter & Gamble Company, The Dishwashing detergent compositions containing organic diamines
US7241729B2 (en) 1999-05-26 2007-07-10 Rhodia Inc. Compositions and methods for using polymeric suds enhancers
EP1180130A1 (en) 1999-05-26 2002-02-20 The Procter & Gamble Company Liquid detergent compositions comprising polymeric suds enhancers
US7939601B1 (en) 1999-05-26 2011-05-10 Rhodia Inc. Polymers, compositions and methods of use for foams, laundry detergents, shower rinses, and coagulants
ATE410455T1 (en) 1999-05-26 2008-10-15 Rhodia BLOCK POLYMERS, COMPOSITIONS AND METHODS FOR USE IN FOAM, DETERGENT, SHOWER CLEANER AND COAGULANT
ATE374235T1 (en) 1999-05-26 2007-10-15 Procter & Gamble LIQUID DETERGENT COMPOSITIONS CONTAINING BLOCK POLYMERS FOAM FORMERS
US20030017960A1 (en) 1999-06-15 2003-01-23 The Procter & Gamble Company Cleaning compositions
WO2000077143A1 (en) * 1999-06-15 2000-12-21 The Procter & Gamble Company Cleaning compositions
US7264678B2 (en) 2000-06-14 2007-09-04 The Procter & Gamble Company Process for cleaning a surface
US6562142B2 (en) 2001-01-30 2003-05-13 The Procter & Gamble Company System and method for cleaning and/or treating vehicles and the surfaces of other objects
US6376631B1 (en) 2000-09-27 2002-04-23 Rhodia, Inc. Processes to control the residual monomer level of copolymers of tertiary amino monomer with a vinyl-functional monomer
AU2002220660A1 (en) * 2000-11-02 2002-05-15 Brunt, Thomas Alexander Composition for cleaning hard surfaces
GB2381531A (en) * 2001-11-02 2003-05-07 Reckitt Benckiser Inc Hard surface cleaning and disinfecting compositions
US6926745B2 (en) * 2002-05-17 2005-08-09 The Clorox Company Hydroscopic polymer gel films for easier cleaning
US7331355B2 (en) * 2003-10-30 2008-02-19 The Procter & Gamble Company Floor cleaning and gloss enhancing compositions
US20050101512A1 (en) * 2003-11-11 2005-05-12 Isp Investments Inc. Soil settling composition
GB0403008D0 (en) * 2004-02-11 2004-03-17 Reckitt Benckiser Uk Ltd Composition and method
US20120252713A1 (en) * 2010-09-24 2012-10-04 Invista North America S.A.R.L. Composition for surface treatment and process
JP6423789B2 (en) 2012-09-04 2018-11-14 ルブリゾル アドバンスド マテリアルズ， インコーポレイテッド Polyurethane-acrylic / styrene hybrid dispersions for glossing applications in home care
US9212987B2 (en) 2013-03-15 2015-12-15 Gojo Industries, Inc. Alcoholic compositions with improved properties and methods for evaluating interaction of the compositions with surfaces
CN103865675B (en) * 2014-03-19 2017-02-08 深圳市洁王精细化工科技有限公司 Composite wood floor cleaning agent
US20160053203A1 (en) * 2014-08-21 2016-02-25 Kolazi S. Narayanan Synergistic mixed solvents-based compositions for removal of paint, varnish and stain coatings
SI3204486T1 (en) * 2014-10-07 2020-07-31 Nuas Technology As Compact reactor for enzymatic treatment

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5010274A (en) * 1973-06-01 1975-02-01
US4230605A (en) * 1978-12-13 1980-10-28 Armstrong Cork Company Cleaning composition for no-wax vinyl composition floor covering
US4368146A (en) * 1979-01-12 1983-01-11 Lever Brothers Company Light duty hand dishwashing liquid detergent composition
LU83949A1 (en) * 1982-02-16 1983-09-02 Oreal COMPOSITION FOR THE TREATMENT OF KERATINIC MATERIALS CONTAINING AT LEAST ONE CATIONIC POLYMER AND AT LEAST ONE ANIONIC LATEX
LU85067A1 (en) * 1983-10-28 1985-06-19 Oreal COMPOSITION AND METHOD FOR TREATING KERATINIC MATERIALS WITH AT LEAST ONE ANIONIC POLYMER AND AT LEAST ONE QUATERNIZED PROTEIN
US5093031A (en) * 1986-06-27 1992-03-03 Isp Investments Inc. Surface active lactams
KR930007227B1 (en) * 1989-07-28 1993-08-04 인터내셔널 리서치 앤드 디벨롭먼트 코포레이션 Balanced newtral liquid detergent lotion emulsion formulation
US5041235A (en) * 1990-07-16 1991-08-20 Henkel Corporation Liquid hard surface cleaner for porous surfaces
CA2047085A1 (en) * 1990-07-16 1992-01-17 Karen L. Wisniewski Hard surface liquid cleaning composition with soil release polymer
US5252245A (en) * 1992-02-07 1993-10-12 The Clorox Company Reduced residue hard surface cleaner

Also Published As

Publication number Publication date
WO1995000611A1 (en) 1995-01-05
US5409639A (en) 1995-04-25

Similar Documents

Publication Publication Date Title
US5409639A (en) Hardwood floor cleaner composition
US6530383B1 (en) Agent for cleaning hard surfaces
CA2394626C (en) A cleaning wipe comprising low residue surfactant and hydrophilic polymer
AU2002361849B2 (en) Thickened toilet bowl cleaner
CA2007812C (en) Acidic disinfectant all-purpose liquid cleaning composition
US6521584B1 (en) Liquid multiphase detergents
CA2047085A1 (en) Hard surface liquid cleaning composition with soil release polymer
EP0804536A1 (en) Glass cleaner compositions
JPS6029760B2 (en) General purpose cleaning composition
WO2008153961A1 (en) Cleaning compositions containing a hydrophilic fragrance
EP0648834B1 (en) Carpet cleaner
US5395555A (en) Cleaning composition for animal urine removal
US6326344B1 (en) Carpet spot removal composition
MXPA97003154A (en) Hard surface cleaning compositions quecomprenden protonated amounts and amino oxide surgical agents
JPH10508056A (en) Hard surface cleaning composition containing a protonated amine and an amine oxide surfactant
GB2306499A (en) Hard surface cleaning compositions
JP2990578B2 (en) Cleaning composition for hard surfaces
AU712709B2 (en) Releasant for aqueous polymer-type floor polish
PL181424B1 (en) Stable microemulsion-type cleaning agent
JPH08504862A (en) Wiping neutral protection compound (▲ I ▼)
JPH08507319A (en) Floor protector
JP2602562B2 (en) Liquid detergent composition for floors
JPH08239691A (en) Detergent composition for hard surface
JP2021038324A (en) Wiping composition
KR20050102312A (en) Aqueous composition for glass cleaner

Legal Events

Date Code Title Description
FZDE Discontinued