CA2157465C - Absorbent articles for odor control with positive scent signal - Google Patents

Abstract

The present invention comprises compositions and articles such as catamenials, diapers, pantiliners, adult incontinence garments, and underarm sbields which minimize odor caused by body fluids and whicb provide a pleasant scent signal to indicate that the odor is being removed. This scent signal. provided by cyclodextrin/perfume inclusion complexes and/or matrix perfume microcapsules, assures the wearer that the product is working.

Description

WO 94/22500 _ ,~ ~ ~ ~ ~ PCT/US94/02857 ABSORBENT ARTICLES FOR ODOR CONTROL WITH
POSITIVE SCENT SIGNAL

TECHNICAL FIELD

The present invention relates to an improvement in absorbent articles such as catamenials, diapers, and adult incontinence garments, with a means for malodor control and a means to provide a "scent signal" in the form of a pleasant odor which signals the removal of odor during use of the product. The odor-controlling agents herein are designed to combat a broad spectrum of odorif-erous materials, including sour "ammonia-type" odors.
The scent signal materials release a fleeting perfume in use, e.g, in the presence of body fluids.

BACKGROUND OF THE INVENTION

A wide variety of fluid absorbent structures known in the art absorb body fluids such as blood, urine, menses, and the like, and are sanitary and comfortable in use. Disposable products of this type generally comprise fluid-permeable topsheet material, fluid absorbent core, and fluid-impermeable backsheet material.
Various shapes, sizes and thicknesses of such articles have been explored in an attempt to make their use more comfortable and convenient.

Odor control in sanitary products has been under investigation for many years. Many body fluids have an unpleasant odor, or develop such odors when in contact with air and/or bacteria for prolonged periods.

Various odor-controlling agents have been disclosed in the literature. For example, U.S. Pat. No. 4,525,410, Hagiwara et ' al., issued June 25, 1985, teaches zeolite particles (doped with bactericidal cations) assertedly stably held in a fibrous web by incorporating some portion of meltable fibers in the web, and applying heat. These compositions can be used as the "outside cover layer" in, e.g., "general sanitary goods."

SF.IVT BY~ 3-18-99 : 7~12P111 : SIM & McBURiVEY-'451#2237#637#1819953:# 7126 WO 94!1.2500 PC?ltJS94I01,55~

-2-U.S. Pat. Ho. 2,690,415, F. A. Shuler, issued Sept. 28, 1954, teaches particles of odor-absorbing materials uniformly affixed at the interstices of a pe neeable web by adhesive to provide an odor absorbent ~nadium for, e.g., catamenials. Particulate carbon, silica gel and activated alu~nina are noted. Shlfting/displacement of the particulates is assertedly avoided and the sheet is flexible.
ABSCEI~1T5 (odor-control molecular sieve froze Union Carbide) for use in diapers and cata~nenials are specifically noted in Union Carbide brochure (A. J. Gioffre 1988). The brochure indicates that UC's market research shows potential benefits in such _ products. U.S. Pat. Nos. 4,795,482 and 4,826,497, relate to ABSCENTS used as an odor-controlling agent, generally, and in sanitary products, in particular.
Zeolltic materials ire generally quite safe, and while they do effectively control eany odors associated with body fluids, unfortunately, they do not provide optimal control for ammonia odor and sieilar odors, presumably associated with short-chain amines and/or urea. This is particularly true of the so-called Zp "high ratio" (S102:A102) odor-Controlling zeolttes. Certain "intermediate raa o' (Si0~:A102) zeolites are score effective for adscrbing swine-type odors.
Sore consumers prefer cataniental and diaper products, etc., that have a scent signal' in addition to odor control. A "scent signal' is a positive perfume odor which signals the reaoval of odor during use of the product. This scent signal is normally difficult-to provide because odor absorbents can react with and/or deplete the perfume in the article prior to use, and the absorb-ents themselves can become inactive.
A consumer's ability to notice their own body odor, both good and bad, d~creases after prolonged exposure to the odor, making it difficult for theca to evaluate the efficacy of odor removal products. In other words, consuaaers becoex habituated to constant odors. Therefore, the positive odor is preferably fleeting and is delivered in "bursts' during use t~ avoid habituation to the WO 94/22500 _ ~ ~ ~ PCTlUS94/02857

-3-positive signal. The "scent signal" signifies the removal of odor so the consumer can feel greater self-confidence.
SUMMARY OF THE INVENTION
Accordingly, the present invention provides an improvement to the art by incorporating odor-absorbing agents for malodor control and moisture-activated encapsulated perfumes for an in-use "burst of fragrance" or "scent signal," into absorbent compositions and articles of manufacture.
Therefore, the present invention relates to compositions which minimize the odor that can be caused by bodily fluids and which provide a scent signal indicating that the odor is being removed, comprising:
I. an effective amount of moisture-activated encapsulated perfume;
II. an effective amount of odor-controlling agent selected from the group consisting of:
A. zeolite;
B. activated carbon;
C. kieselguhr;
D. water-soiuble antibacterial compound; and E. mixtures thereof; and III. an effective amount of fluid absorbing material.
The present invention also relates to consumer articles of manufacture containing the above compositions, such as diapers, catamenials, pantiliners, adult incontinence garments, and underarm shields, which decrease odors associated with bodily fluids such as blood, urine, and the like, and which provide a pleasant scent signal. Moisture-activated encapsulated perfume includes any encapsulated perfume system which will release the perfume when wetted by water. Preferably, moisture-activated perfume includes cyclodextrin/perfume inclusion complexes, poly-saccharide matrix perfume microcapsules, and mixtures thereof.
The odor controlling agent and the moisture-activated encapsulated perfume can be present in the fluid-retaining absorbent core or the fluid-receiving front face (topsheet) of these articles.

04-10-00 05:31pm From-SIM MCBURNEY 4165951163 T-522 P.OT/22 F-54T
3a In accordance with one embody-merit of the invention, a composition comprises:
I. an effective amount of moisture-activated encapsulated perfume;
II. an effective amount of odor-controlling agent Selected from the group consisting of:
A. an intermediate sil~.cate/aluminate zeolite riavltlg 8 SiOz/A102 molar ratio of less than ],p;
8. a mixture of activated carbon and zeolite wherein the caxbon is coated with the zeolite;
C. kiesalgurir; and D. ittlxtures thereof: and III. an effective amount of fluid absorbing material.
In accordance with another embodiment of the invention, an article of manufacture selected from the group consisting of:
Sa> catamenials;
tb) pantiliners;
tc1 diapers;
(d) acEalt incontinence garments; and te) underaru shields;
comprises:
I. an effective amount of moisture-activated encapsulated perfume;
II. an effective amount of odor-controlling agent selected from the group consisting of:
A. art intermediate silicate/aluminate 2eolite ham ng a SiO~~/A102 molar ratio of less than ~.0;
B. a mixture of activated carbon and 2eolite where~t~ the carbon ss coated wrth the zeolite;
C. kieseiguhr; and 04-10-00 05:32am Frvm-SIM MCBURNEY 4166951163 T-522 P.08/22 F-541 3b D. mixtures thereof; and I~r. an effective amount of fluid absorbing material.
In accordance with another embodiment of the invention, a method for decreasing odors assooiatea with bodily fluids such as blood, and urine, anG for providing a scent signal, comprises contacting said fluids with:
I_ an effective amount of moisture-activated encapsulaxed perfume;
II. an effective amount of odor-contro~.J.ing agent selected from the group consisting of:
A_ intermediate silicaLe/aluminate zeolite having a sio2/RIQz molar ratio of less than 10;
B, a mixture of activated carbon and zeolite wherein the carbon is coated with the zeolite;
C. kieselgahr; and D. mixtares Lherebf; and III. an effective amount of fluid absorbing maC~r~al.

WO 94/22500 PCT/US94/02857 t

-4-Cyclodextrin/perfume inclusion complexes are very stable in the dry state. Even the very volatile perfume molecules are bound in the cavity of the cyclodextrin molecules and do not provide perceptible odor. Upon wetting by an aqueous fluid such as a body fluid, the perfume is released to provide a burst of fragrance. A
greater variety of perfumes can be used to accommodate a variety of consumer preferences.
In polysaccharide matrix perfume microcapsules, the perfume is dispersed as minute droplets in, e.g., a starch/dextrin solid cellular matrix. Moisture swells and softens the polysaccharide matrix to release the encapsulated perfume.
Preferably, cyclodextrin/perfume inclusion complexes and the polysaccharide matrix perfume microcapsules contain volatile perfume.
DETAILED DESCRIPTION OF THE INVENTION
The compositions and methods for odor control and pleasant scent signal in the manner of this invention involve the use of odor-controlling agents, and moisture-activated encapsulated perfumes, as described more fully hereinafter.
The articles which employ said compositions of odor-control-ling agents and moisture-activated encapsulated perfumes can be prepared using constituents that are well-known in current com-mercial practice, and reference is made to the general sanitary products patent literature and trade catalogues for such items.
Such items typically comprise a moisture absorbent "core" (e. g., pad) interposed between a "topsheet" and a "backsheet." Likewise, methods and apparatus for assembling disposable diapers, cata-menials, and the like are known in the art.
While the constituents used in the assembly of catamenials, disposable diapers, and the like, are well-known, the following may be mentioned by way of example. The present invention relates to the novel combination of odor-controlling agents and matrix perfume microcapsules into the matrix of these articles, rather than in the constituents of the articles, per se.

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-5-I. hoi~ture-Activated Encapsulated Perfume The compositions and articles of this invention contain an effective amount of various eioisture-activated encapsulated perfume particles, as an essential ingredient. Such materials include, for example, cyclodextrin/perfume inclusion complexes, polysaccharide cellular matrix perfuaK ~nicrocapsules, and the like. Encapsulation of perfu~e sinimizes interaction with, and/or depletion by, odor-absorbing materials before use of the product.
Perfume is released when the oaterials are wetted, to provide a pleasant odor signal in a:e. Especially preferred are cyclo-dextrin inclusion cve~plexes of volatile perfumes, with a particlt site of less than about 12 microns. -I. A. Perfume The perfumes and compositions of this invention are the conventional ones known in the art. Selection of any perfuse component, or aaaunt of perfume, is based on functional and aesthetic considerations. Preferred perfuiae components useful in the present invention are the highly volatile, and the moderately volatile perfume ingredients, iaore preferably the highly volatile, low boiling perfumes.
The highly volatile, iow boiling, perfume ingredients typic-ally have bon ing points of about 250'C or lower. These highly volatile perfumes are fleeting and are quickly lost as they are released. Many of the yore iaoderately volatile perfume ingre-dients are also quickly lost. The aoderately volatile perfume ingredients are those having boiling points of frog about 250'C to about 30D'C. Many of the perfume ingredients as discussed here-inafter, along with their odor characters, and their physical and chesical properties, such as boiling point and solecular weight, are given in 'Perfume and Flavor Cheaicals (Aroma Che~aicsls),' 5teffen Arctander, publi:hed by the author, 1969.
ExaAples of the highly volatile, low boiling, perfume ingre-dients are: anethole, benzaldehyde, benty) acetate, benZyl alco-hol, benzyl formats, iso-bornyl acetate, ca~nphene, cis-citral (neral), citronellal, citronfllol, citrone11y1 acetate, para~

WO 94/22500 - ~ ~ ~ PCT/US94/02857

- 6 -cymene, decanal, dihydrolinalool, dihydromyrcenol, dimethyl phenyl carbinol, eucalyptol, geranial, geraniol, geranyl acetate, geranyl nitrile, cis-3-hexenyl acetate, hydroxycitronellal, d-limonene, ' linalool, linalaol oxide, linalyl acetate, linalyl propionate, methyl anthranilate, alpha-methyl, ionone, methyl nonyl acetalde-hyde, methyl phenyl carbinyl acetate, laevo-menthyl acetate, menthone, iso-menthone, myrcene, myrcenyl acetate, myrcenol, nerol, neryl acetate, nonyl acetate, phenyl ethyl alcohol, alpha-pinene, beta-pinene, gamma-terpinene. alpha-terpineol, beta-ter-pineol, terpinyl acetate, and vertenex (para-tertiary-butyl cyclohexyl acetate). Some natural oils also contain large per-centages of highly volatile perfume ingredients. For example, lavandin contains as major components: linalool; linalyl acetate;
geraniol; and citronellol. Lemon oil and orange terpenes both contain about 95% of d-limonene.
Examples of moderately volatile perfume ingredients are: amyl cinnamic aldehyde, iso-amyl salicylate, beta-caryophyllene, cedrene, cinnamic alcohol, coumarin, dimethyl benzyl carbinyl acetate, ethyl vanillin, eugenol, iso-eugenol, flor acetate, heliotropine, 3-cis-hexenyl salicylate, hexyl salicylate, lilial (para-tertiarybutyl-alpha-methyl hydrocinnamic aldehyde), gamma-methyl ionone, nerolidol, patchouli alcohol, phenyl hexanol, beta-selinene, trichloromethyl phenyl carbinyl acetate, triethyl citrate, vanillin, and veratraldehyde. Cedarwood terpenes are composed mainly of alpha-cedrene, beta-cedrene, and other C15H24 sesquiterpenes.
I. B. Gvclodextrin As used herein, the term "cyclodextrin" includes any of the known cyclodextrins such as unsubstituted cyclodextrins containing from six to twelve glucose units, especially, alpha-, beta-, and gamma-cyclodextrins, and/or their derivatives, and/or mixtures , thereof. The alpha-cyclodextrin consists of 6, the beta-cyclo-dextrin 7, and the gamma-cyclodextrin 8, glucose units arranged in a donut-shaped ring. The specific coupling and conformation of the glucose units give the cyclodextrins a rigid, conical molecular structure with a hollow interior of a specific volume.

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The "lining' of the internal cavity is formed by hydrogen atoms and glycosidic bridging oxygen atoms, therefore this surface is fairly hydrophobic. These cavities can be filled rith all or a portion of an organic molecule rith suitable size to form an "inclusion complex.' Alpha-, beta-, and gaahna-cyclodextrins can be obtained from, among others, American Maize-Products Company (Amaizo), Haarnond, Indiana.
Cyclodextrin derivatives are disclosed in U.S. Pat. Nas:
3,426,011, Parmerter et al., issued Feb. 4, 1969; 3,453,257, 3,453,258, 3,453,259, and 3,453,260, all in the naiaes of Parmerter et al., and ill also issued July 1, 1969; 3,459,731, Gramera et _ al., issued Aug. 5, 1969; 3,553,191. Parmerter et al., issued Jan.
5, 1971; 3,565,887, Parmerter et al., issued Feb. 23, 1971:
4,535,152, Sze~tli et al., issued Aug. 13, 1985; 4,616,008, Hir~i et al., issued Oct. 7, 1986; 4,638,058, Brandt et al., issued Jan. 20, 1987; 4,746,73~, Tsuchiyama et al., issued May 24, 1988;
and 4,678,598, Ogino et al., issued Jul. 7, 1982 Examples of cyclodextrin derivatives suitable for use herein are methyl-beta-cyclodextrln, hydroxyethyl-beta-cyclodextrin, and hydroxypropyl-beta-cyclodextrln of different degrees of substitution (O.S.), available from Aa~aizo; taacker Chemicals (USA), Inc.; and Atdrich Chemical Corpany. water-soluble derivatives are also highly desirable.
The individual cyclodextrins can also be linked together, e.g., using eultifunctional agents to forty oligomers, polymers, etc. Exarpl es of such uateri al s are avai 1 able coa~nerci al ly from llmtizo and froe Aldrich Cheeiical Coepany (bet:-cyclodextrin/epi-chlorohydrin copolymers).
The preferred cyclodextrin is beta-cyclodextrin. It 1s also desirable to use mixtures of cyclodextrins. Preferably at least a ma3or portion of the cyclodextrins are alpha-, beta- and/or ganma-cyclodextrins, riore preferably alpha- and beta-cyclodextrins.
Some cyclodextrin mixtures are cotamercially available from, e.g., Enauiko Sugar Refining Company, Yokohama, Japan.

SfNT BY~ 3-18-99 r 7~14PM : SIM & McBURNEY~451#2237~k637#1819953:#11/26 WO 94!12500 PCf NS9dI0Z857 I. C. Formation ofCvclodp'trin/~ Perfumyj2r,~lusion Comalexes The perfume/cyclodextrin inclusion complexes of this in~~an-lion are fot~ed in any of the ways known in the art. Typically, the complexes are formed either by bringing the perfume and the cyclodextrin together in a suitable solvent, e.g., water, or, preferably, by kneadlng/slurrying the ingredients together in the presence of a suitable, preferably minimal, amount of solvent, preferably water. The kneading/slurrying method is particularly desirable because it produces sAall~r complex particles and requires the use of less solvent, eliminating or reducing the need to further reduce particle size and separate excess solvent.
Disclosures of complex formation can b~ found in Atwoad, J.L., J.E.D. Davies A D.D. NacNichol, (Ed.): Inclusion Camuounds. Yol.
j,lj, Academic Press (1984), especially Chapter 11, Atwood, J.l.
and J.E.D. Davias (Ed.): Proceedtnas of the Second Intern-ational Srmaosj~ of Cvclodextrins Tokyo, Japan, (July, 1984), and J.
Sze3 tl i , Cyc; Qd ri n _j~c~p~ol oav, K1 wwr Academi c Pub1 i shers ( 1988).
In general, perfume/cyclodextrin complexes have a molar ratio of perfume compound to cyclodextrin of about 1:1. However, the molar ratio can be either higher or loner, depending on the size of the perfume compound and the identity of the cyclodextrin compound. The molar ratio can be determined by forming a satu rated solution of the cyclodextrin and adding the perfume to form the complex. In general the coplex will precipitate readily. If not, the~complex can usually be precipitated by the addition of electrollrte; change of pH, cooling, etc. The complex can then be analyzed to determine the ratio of perfume to cyclod~xtrin.
As stated hereinbafora, the actual complexes are deter~nin'd by the size of the cavity in the cyclodextrin and the size of-the parfuae molecule. Desirable complexes can be formed using mix lures of cyclodextrins since perfumes are normally rt:~xtures of materials that vary widely in size. It is usually dem ruble that at toast a majority of the material be alpha-, beta-, and/or gan~aa-cyclodextrin, more preferably beta-cyclodextr;n. The SF1VT BY~ 3-18-99 : 7~14PM : S(M & McBURNEY-'451#2237637#1819953:#12/26 WO 94IZ2500 PCTNS94IOZA.S7 _g_ content of the perfume in the beta-cyclodextrin complex is typic-ally frog about 5% to about 15%, more normally from about 7% to about 12%.
Continuous compltxation operation usually involves the use of supersaturated solutions, kneading/slurrying method, and/or teeeperature manipulation, e.g., heating and then either cooling, freeze-drying, etc. The complexes are dried to a dry powder to make the desired composition. In general, the fewest possible process steps are preferred to avoid loss of perfume.
I. D. Complex Part~le Size Complexes of this invention having a particle site of less thin about 12 microns, preferably less than about 10 microns, more preferably less than about 8 microns, and even more preferably less than about 5 microns, improve the release, especially the speed of release of the perfume when the complexes are wetted.
The particle size is typically between about 0.001 and 10 microns, Preferably between about 0.05 and S microns. It is highly desirable that at least an effective amount of the perfume be in complexes having the said particle sizes. It is desirable that at least about 75X, preferably at last about 80%, more areferably at least about 90X, and even more preferably at least about 100'x, of the complex that is present have the said particle sties.
These small particles of the invention are conveniently prepared. by kneading methods and/or grinding techniques. Cyclo dextrin complexes with large particle sizes can be pulverized to obtain the desired smaller particles of less than about 12 microns by using, e.g., a fluid energy. mill. ,Examples of fluid energy mills are the Trost Air Impact P~lverizers, sold by Garlock Inc., Plastomer zProducts, Neirtown, Pennsylvania; the Ilicronlzer fluid energy mills sold ~,b~r Sturtevant, Inc., Boston, Massachusetts; and the Spiral Jat Hill sold by Alpine Division, hicroPul Corporation (Hosokawa Micron International, Inc.), Summit, New Jersey.
As used herein, the particle size refers to the largest dimension of the particle and to the ultimata (or primary) par ticles. The size of these primary particles can be directly S~1T BY~ 3-18-99 : 7~14PM : SIM & McBURIVEY-'451#2237:k637#1819953:#13/26 w0 9arZU0o PCTrt.rS9aroZ857 determined with optical or scanning electron microscopes. The slides must be carefully prepared so that each contains a repre~
sentative simple of the bulk cyclodextrin complexes. The par-ticles sizes can also be measured by my of the other well-known methods, o.g., wet sieving (non-aqueous), sedimentation, light scattering, etc. A convenient instrusent that can be used to determine the particle size distribution of the dry complex powder directly (without having to awke a liquid susp~lsion or disper-sion) is the Halvern Particle and Droplet Size~M Model 2600C, sold by Malvern Instruments, Inc., Seuthbarough, Massachusetts. Some caution should be observed 1n that some of the dry particles may remain aggloa~rated. The presence of agglomerates can be further _ determined by microscopic analyst s Some other suitable methods for particle site analysis are descrioed in the article "Selecting a particle size analyzer: Factors to consider,' by Michael Pohl, published in Powder and Bulk Engineering, Ilolu~ne 4 (1990), pp.
26-Z9. It is recognized that the very small particles of the invention can readily aggregate to form loose agglomerates that are easily broken apart by either some mechanical action or by the action of water. Accordingly, particles should be measured after they are broken apart, e.g., by agitation or sonication. The method, of course, should be selected to acconraodate the particle size and maintain the integ-rity of the complex particles, with iterative measurements being made 1f the original method selected proves to be inappropriate.
It 13 essential that it least an effective aaaunt of the cyclodextrin/perfwne complex be applied to the article. Effective mounts aye typically tn the range of free about 0.005 g to about 10 g, preferably from about 0.01 g to about 3 g, more preferably from about O.OZ g to about. 1 g per article.
I. E. Matrix Perfwne liicrocaosules Water-soluble cellular matrix perfume microcapsules are solid particles containing perfume stably held in the cells. The water-soluble matrix material comprises mainly polysaccharide and polyhydroxy compounds. The polysaccharides are preferably higher polysaccharides of the non-sweet, colloidally-soluble types, such SENT BY~ 3-18-99 ; 7~14PM : SIM & McBURNEY-'451#2237.637#1819953:#14/26 Wp 9a~2Z5p0 pCTIUS94lo2e57 as natural gums, e.g., gum arabic, starch derivatives, dextrinized and hydrolyzed starches, and the like. The polyhydroxy compounds are preferably alcohols, plant-type sugars, lactones, monoethers, and acotals. The cellular matrix microcapsules useful in the present invention are prepared by, e.g., (1) forming an aqueous phase of the polysaccharide and polyhydroxy compound in proper proportions, with added emulsifier if necessary or desirable; (2) emulsifying the perfumes in the aqueous phase; and (3) removing moisture while the mass is plastic or flowable, e.g., by spray drying droplets of the eMUlsion. The matrix materials and process details are disclosed in, e.g., U.S. Pat. No. 3,971,952, Brenner et al., issued July 27, 1916 The present invention preferably has einimal non-encapsulated surface perfume, preferably less than about lx.
Moisture-activated perfuew ~nicrocapsules can be obtained commercially, e.g., as IN-CAPS from Polak's Frutal Works, Inc., hiddletown, New York; and as Optilok System encapsulated perfumes from Encapsulated Technology, Inc., Nyack, New York.
Water-soluble matrix perfume microcapsules preferably have size of from about 0.5 micron to about 300 microns, more prefer-ably from about 1 micron to about 200 microns, most preferably from about 2 microns to about 100 microns.
It is essential that at least an effective amount of the Z5 water-activated matrix perfume microcapsules be applied to the article. Effective mounts are typically in the range of from about 0.001 g to about 5 g, preferably froe~ about 0.005 g to about I g, ~or~ preferably from about 0.01 g to about 0.5 g, per article.
II. Odor-Controlling Material The ca~posltions and articles of this invention contain an effective, i.e., odor-controlling, aea unt of various odor-con-trolling materials. Such materials include, for example, zeo-lites, activated carbon, kieseiguhr, and water-soluble antibac-terial coopounds, such as cetyl pyridinlum chloride, zinc chloride, copper salts, copper ions, chlorhexidine, quaternary ammonium compounds, chelating agents, parabens, chitin, pH buf-fered materials, and the like. Especially preferred is zeolite .
material having "intermediate" silicate/aluminate ratios (vide infra). Such materials typically are present at a level of from about 0.01 g to about 15 g, more preferably from about 0.1 g to about 10.0 g, in fluid absorbent articles of the type disclosed herein to provide odor control benefits. Some partially neu-tralized hydrogel-forming absorbent gelling materials, such as polyacrylate gelling material and acrylate grafted starch gelling material (vide infra), are also useful in the present invention to control certain ammonia-type odors. These materials are discussed in III. Fluid Absorbent Material because they also function as fluid absorbent materials.
Surprisingly, the moisture-activated encapsulated perfume (I) does not interfere with the efficacy of the odor controlling matErial (II).
II. A. Zeolite Odor-Controlling Aaent In general terms, traditional zeolites comprise an aluminate/
silicate framework, with associated cations, M, providing overall electrical neutrality. Empirically, the zeolite framework can be represented as x A102 . y Si02 and the electrically neutral zeolite as x/n M . x A102 . y Si02 . z H20 wherei n: x and y are each i ntegers, M i s a cati on and n i s the charge on the cation. As noted by the empirical formula, zeolites may also comprise waters of hydration (z H20). M can be a wide variety of cations, e.g., Na+, K+, NH4T, alkylammonium, heavy metals, and the like.
A preferred class of zeolites useful in the present invention is characterized as "intermediate" silicate/aluminate zeolites.
The "intermediate" zeolites are characterized by Si02/A102 molar ratios of less than about 10. Typically, the molar ratio of Si02/A102 will range from about 2 to about 10. The intermediate zeolites have three advantages over "high" zeolites, disclosed in SF1VT BY: 3-18-99 ; 7:15PM : SIM & McBURNE1f-'451#2237637#1819953:#15/26 WO 942~.i00 PCTNS94107,~5~

U.S. Pat. Hos. 4,795,482 and 1,826,497.
First, the intermediate zeolites have a higher capacity for amine-type odors which is important for controlling urine and menses odors. Second, the interniediate zeolites have z larger surface area (about 700-800 ~/g) than high zeolites (about 400 n~/g). Therefore, less intermediate zeolite is needed to absorb a given amount of odor on a weight to weight basis. Third, intermediate zeolites are more moisture tolerant and retain more odor-absorbing capacity in the presence of water.
A wide variety of inter~dlata zeolite~ suitable for use herein are co~n~ercially available as YALFOR CP301-68, YALFOR
300-63, YAIFOR CP300-35 and VAIFOR CP300-56, from PQ Corporation,-and the C8V100 series (other thah hordenite, as noted below) of zeolites from Conteka.
The zeolites used herein are not of the fibrous type, e.g., various liordenites, and same types of Y zeolltes, since these may be subject to safety issues. Accordingly, the tern 'zeolite' as used herein is intended to encompass only tht nonfibrous zeolites.
While some naturally-occurring zeolites ieeet the objectives of this invention, the synthetic zeolites of the types available in commerce are generally more preferred.
Even though intermediate zeolites are preferred, high zeo-lites can be optionally eaployed in the practice of this invention in combination with the interasediate ratio zaolites. High zeo-lites include, for example, the well-knorn "molecular sieve' zeolltes of the lSh, Deta zeollte, etc., type (generally in the 1-10 micron particle size range) and the zeollte materials mar-keted under the trade name ABSCENTS by the Union Carbide Corpo-ration and UOP. ABSCENTS are typically available as a white powder in the 3-5 micron particle size range (See: ABSCEHTS, A New Approach for Odor Control by A. J. Giaffre, copyright 1988 by the Union Carbide Corporation). Such materials are preferred over the 'intermediate' zeolites for control of odors associated with sulfur compounds, e.g., thiols, mercaptans.
Various other modified zeolite-type iaater.ials which can be used in the present inventloa, such as the oanganese-aluminum-SF~VT BY: 3-18-99 : 7:15PM : SIM & McBURiVEY-'451#2237:k637#1819953,#16/26 WO 9a~2f80 PCTIUS9410ZBSl phosphorus-silicon-oxide molecular sieves and ether zeolite odor-controlling compositions are described in U.S. Pat. Nos.
4,793,833, Lok et al.; 4.604,110; 4,437,429: and 4,648,977.
II. B, tryl~ina Avent The carbon material employed herein is the material ~e11 known in commercial practice as an adsorbent for organic molecules and/or for air purification purposes. Carbon suitable for use herein is available from ~ variety of commercial sources under trade names such as CALGON Type "CPG', Type 'PCB", Type "SGL", TypR 'CAl', and Type "OL.' Often, such carbon material is _ referred to simply as 'activated' carbon or 'activated' charcoal.
Typically, it is available in the form of extremely fine, dusty particles (e. g., 0.1-300 microns) having large surface areas (about 200 to several thousand m2/g). It is to be understood that any of the "air purifying" or 'activated" carbons of commerce can be used in the practice of this invention.
If the z~olttes herein are optionally used in conjunction with the activated carbon, it is preferred (for aesthetics rea sons) to coat the carbon with the zenlite using a binder_ II. C. 9ther for-Controlling Agents Other odor-controlling agents include kieselguhr, and water-soluble antibacterial coepounds, such as cetyl pyridinium chloride, zinc chloride, copper salts, copper ions, chlorhexidine, quaternary amsoniua coapounds, chelating agents, parabens, chitin, pH buffered wterials, and the like.
III. Flui~ d Absorbent Material Fluid absorbent material can be any material which is gen erally compressible, conforwable, non-irritating to the wearer's skin, and which is capable of absorbing and retaining fluids.
The fluid absorbent material can be constructed from any of a variety of materials conmonly used in disposable absorbent articles. These materials are described in U.S. Pat. Nos.:
3,905,863, Ayers, issued .Sept. 16, 1975; 3,974,025; Ayers, issued Aug. 10, 1976; 4,191,609, Trokhan, issued Mar. 4, 1980; 4,440,597, Wells et al., issued Apr. 3, 1984; 4,529,480; Trokhan, issued SENT BY: 3-18-99 : 7:15PM : SIM & McBURNEY-451#2237:k637#1819953:#17/26 w0 9aIZZ500 PCTIUS9ai0?.a57 July 16, 1985; and 4,637,859, Trokhan, issued Jan. 20, 1987. Examples of suitable absorbent materials include creped cellulose wadding, cotton fluff, chemithermomechanical pulp, and citric acid cross-linked cellulose pulp dis-closed in U.S. Pat. Nos.: 5,190,563, issued Mar. Z, 1993, 5,183,707, issued Fab. 2, 1993; and 5,137,537, issued Aug. I1.
1992, all issued to Herron et al.; synthetic fibers disclosed in U.S. Pat. No. 4,578,414, Saryer, issued liar. Z5, 1986; absorbent foals, absorbent sponges, superabsorbent co~posites, superabsorb-ent foal, and super absorbent polymers. A preferred fluid absor-bent maters al i s colltni muted and ai rl a ~ d rood pul p f i hers con~non 1 y referred to as absorbent fluff. An absorbent fluff having a-density of froel about 0.05 g to about 0.175 g per cm3 is generally acceptable.
i5 More preferred fluid absorbent materials are the absorbent gelling materials. As is cell knorn in the art, fluid absorbent gelling materials (soieetiees referrtd to as 'AGli' or 'super-sorbers') are broadly used in fluid absorbent articles. In general, such AGl1's have been used only for their fluid-absorbing properties. Such materials fore) hydrogels on contact rith cater (e. g., rith urine, blood, and the like). One highly preferred type of hydrogel-forming, absorbent gelling material is based on the hydrolyed polyacids, especially neutralized polyacrylic acid.
Hydrogel-for~aiing polyiaeric 4aterlals of this type are those rhich, upon contact rith fluids (i.e., liquids) such as cater or body fluids, iebibe such fluids and thereby fore hydrogels. In this Banner,, fluid discharged into the fluid absorbent structures herein can be acquired and held. These preferred fluid absorbent gelling sat~rials rill generally coaprise substantially rater-insoluble, slightly cross-linked, partially neutralized, hydro-gel-foreting polyiaer uterials prepared from polylearizable, unsatu-rated, acid-containing monomers. In such slaterials, t!he polymeric coeponant forced froo unsaturated, acid-containing awnoexrs may comprise the entire gelling agent or may be grafted onto other types of polye~er soieties such as starch or cellulose. The hydrolyzed polyacrylic acid grafted starch Aaterials are of this WO 94122500 PC'T/US94/02857 latter type. Thus the preferred fluid absorbent gelling materials include hydrolyzed polyacrylonitrile grafted starch, hydrolyzed polyacrylate grafted starch, polyacrylates, malefic anhydride-iso-butylene copolymers and combinations thereof. Especially pre-y ferred fluid absorbent gelling materials are the hydrolyzed polyacrylates and hydrolyzed polyacrylate grafted starch.
Whatever the nature of the polymer components of the pre-ferred fluid absorbent gelling materials, such materials will in general be slightly cross-linked. Cross-linking serves to render these preferred hydrogel-forming absorbent materials substantially water-insoluble, and cross-linking also in part determines the gel volume and extractable polymer characteristics of the hydrogels formed therefrom. Suitable cross-linking agents are well known in the art and include, for example: (1) compounds having at least two polymerizable double bonds; (2) compounds having at least one polymerizable double bond and at least one functional group reactive with the acid-containing monomer material; (3) compounds having at least two functional groups reactive with the acid-con-taining monomer material; and (4) polyvalent metal compounds which can form ionic cross-linkages. Cross-linking agents of the forego i ng types are descri bed i n greater detai 1 i n U . S . Pat . No .
4,076,663, Masuda et al., issued Feb. 28, 1978. Preferred cross-linking agents are the di- or polyesters of unsaturated mono- or polycarboxylic acids with polyols, the bisacrylamides and the di-or triallyl amines. Especially preferred cross-linking agents are N,N'-methylenebisacrylamide, trimethylol propane triacrylate and triallyl amine. The cross-linking agent will generally comprise from about 0.001 mole percent to about 5 mole percent of the preferred materials. More preferably, the cross-linking agent will comprise from about 0.01 mole percent to about 3 mole percent of the absorbent gelling materials used herein.
The preferred, slightly cross-linked, hydrogel-forming absorbent gelling materials will generally be employed in their partially neutralized form. For purposes described herein, such materials are considered partially neutralized when at least about 25 mole percent, preferably at least about 50 mole percent, and WO 94/22500 _ ~ ~ ~~ ~,~ ~ J PCTIUS94/02857 more preferably at least about 75 mole percent, of monomers used to form the polymer are acid group-containing monomers which have been neutralized with a salt-forming cation. Suitable salt-forming cations include alkali metal, ammonium, substituted ammonium and amines. This percentage of the total. monomers utilized which are neutralized acid group-containing monomers is referred to as the "degree of neutralization." Typically, commer-cial fluid absorbent gelling materials have a degree of neutrali-zation somewhat less than about 90X.
The preferred fluid absorbent gelling materials used herein are those which have a relatively high capacity for imbibing fluids encountered in the fluid absorbent articles; this capacity can be quantified by referencing the "gei volume" of said fluid absorbent gelling materials. Gel volume can be defined in terms of the amount of synthetic urine absorbed by any given fluid absorbent gelling agent buffer and is specified as grams of synthetic urine per gram of gelling agent.
Gel volume in synthetic urine (see Brandt et al., below) can be determined by forming a suspension of about 0.1-0.2 parts of dried fluid absorbent gelling material to be tested with about 20 parts of synthetic urine. This suspension is maintained at ambient temperature under gentle stirring for about 1 hour so that swelling equilibrium is attained. The gel volume (grams of synthetic urine per gram of fluid absorbent gelling material) is then calculated from the weight fraction of the gelling agent in the suspension and the ratio of the liquid volume excluded from the formed hydrogel to the total volume of the suspension. The preferred fluid absorbent geiling materials useful in this inven-tion will have a gel volume of from about 20 to 70 grams, more preferably from about 30 to 60 grams, of synthetic urine per gram of absorbent gelling material.
Another feature of the most highly preferred fluid absorbent gelling materials relates to the level of extractable polymer material present in said materials. Extractable polymer levels can be determined by: (1) contacting a sample of preferred fluid absorbent gelling material with a synthetic urine solution for a WO 94/22500 - ~ ~ ~ PCT/US94/0285?

substantial period of time (e.g., at least 16 hours) to reach ex-traction equilibrium; (2) filtering the formed hydrogel from the supernatant liquid; and (3) determining the polymer content of the .
filtrate. The particular procedure used to determine extractable polymer content of the preferred fluid absorbent gelling agent , buffers herein is set forth in U.S. Pat. No. 4,654,039, Brandt, Goldman and Inglin, issued Mar. 31, 1987, Reissue No. 32,649. The fluid absorbent gelling materials which are especially useful in the fluid absorbent articles herein are those which have an equilibrium extractables content in synthetic urine of no more than about 17%, preferably no more than about 10% by weight of the fluid absorbent gelling material.
The fluid absorbent gelling materials hereinbefore described are typically used in the form of discrete particles. Such fluid absorbent gelling materials can be of any desired shape, e.g., spherical or semi-spherical, cubic, rod-like polyhedral, etc.
Shapes having a large greatest dimension/smallest dimension ratio, like needles and flakes, are also contemplated for use herein.
Agglomerates of fluid absorbent gelling material particles may also be used.
The size cf the fluid absorbent gelling material particles may vary over a wide range. For reasons of industrial hygiene, average particle sizes smaller than about 30 microns are less desirable. Particles having a smallest dimension larger than about 2 mm may also cause a feeling of grittiness in the absorbent article, which is undesirable from a consumer aesthetics stand-point. Furthermore, rate,of fluid absorption can be affected by particle size. Larger particles have very much reduced rates of absorption. Fluid absorbent gelling material particles preferably have a particle size of from about 30 microns to about 2 mm for substantially all of the particles. "Particle Size" as used herein means the weighted average of the smallest dimension of the individual particles.
The amount of fluid absorbent gelling material particles used ' in fluid absorbent cores will depend upon the degree of fluid SENT BY: 3-18-99 : 7:16PM : SIM & McBURNEY-451#2237:k637#1819953:#18/26 WO 9422500 PCTIUS9a~07~'7 absorbent capacity desired, and will generally comprise from about 2x to about 50x by weight of the fluid absorbent core, more typically from about 5x to about 20x by weight of the fluid absorbent tore.
When fluid absorbent gelling material particles are to be used in the cores of the fluid absorbent articles herein, such cores can ba prepared by any process or techniQue which provides a web comprising a combination of the fibers and the gelling material particles. For example, web cores can be formed by air-laying a substantially dry mixture of hydrophilic fibers and fluid absorbent galling material particles and, if desired or necessary, by densifying the resulting web. Such a procedure is descriDed more fully in U.S. Pat. No. 4,610,678, Weisman and Goldman, issued Sept. 9, 1986. As indicated in this U.S. Pat. No.
1'S 4,610,678, the air-laid webs fonAed by such a procedure will preferably comprise substantially unhanded fibers and will pref-erably have a moisture content of about 10% ~r less.
Another example combining the fibers and the gelling material particles is a tissue laminate. Such a fluid absorbent core is described more fully in U.S. Pat. Hos: 4,950,264, Osborn, issued Aug. 21, 1990; 5,009,653, Osborn, issued Apr. Z3, 1991; WO
93/01785, Osborn et al., published Feb. 4, 1993, "Stretchable Absorbent Articles;' and HO 93/01781, Johnson et al., published Feb. 4, 1993, 'Curving Shaped Absorbent Articles 23 AS indicated in these references, glue 1s tpplied to an air-laid, latex-bonded tissue and absorbent gelling material is added and then the tissue is folded over.
The density of the fluid absorbent cores which comprise webs of hydrophilic fibers and fluid absorbent gelling material par ticles can be of i~ortance in determining the fluid absorbent properties of the cores and of the fluid absorbent articles in which such cores are employed. The density of such fluid absor bent cores herein will preferably be in the range of from about 0.06 to about 0.3 g/c~, ~ and more preferably within the range of from about 0.09 to about 0.22 g/ce3. Typically the basis weight S)=1VT BY: 3-18-99 : 7:16PM : SIM & McBURIVEY~451#2237~k637#1819953:#19/26 WO 9dlZZ500 PLTI~(759W02857 - ZO -of the fluid absorbent cores herein tan range from about 0.02 to 0.12 g/cm2.
Density values for Cores of this type can be calculated froe basis weight and caliper. Caliper is measured under a confining pressure of O.I37 psi (0.94 kPa). Density and basis weight values include the weight of the fluid absorbent gelling materials and the odor-control material. Donsity of the cores herein need not be unifone throughout the core. within the density ranges set forth above, the cores can contain regions or zones of reiatively l0 higher or relatively lower density.
The size of the fluid absorbent element is dictated by the exact product design selected. -IV. Front-Face ~;Zterial-(Tonsheet Material) The finished articles herein will typically be provided with a fluid-receiving facing Material. Tho front-face ('topsheet') material used h~re~n can be any coapiiant, soft~feeling, non~
irrigating (to the wearer's skin) planar eaterial. It functions to contact the wearer's skin, to receive fluid discharges, to allow the discharges to pass readily therethrough into the ZO absorbent elueent, and to isolate the wearer's skin from the fluids in the absorbent element.
The topsheet can be porous paper made from natural or syn thetic fibers or mixtures thereof, non-woven fabric made from natural or synthetic fibers or mixtures thereof, aportured plastic Z5 file, porous foa~, or the like.
A preferred topsheet is spun bonded non-woven polyester fabric ode from fibers of free about 2.2 to about 2.5 denier, Raving a basis weight of about I7 g par square meter (~nz), Another pnferrad topsheat Aaterial has a basis weight of 22 g 30 Per ~ 4nd comprises about 65~r weight staple length, 1.~5 denier polyester fibers (such as Kodel type 411 polyester fibers as sold by Tennessee Eastaan Corporation, Kingsport, Tennessee); about 15%
crimped, staple length 1.5 denier rayon fibmrs: and about 20x acrylic copolyrer binder (such as CelaneseM CPE 8335 as sold by 35 Celanese Corporation, Charlotte, North Carolina). 'Staple length' refers to fibers having a length of at least about 15 mm.

SENT BY: 3-18-99 : 7:16PM : SIM & McBURNEY~451#2237:k637#1819953:#20/26 WO 9421500 YCrIUS9d~02a57 Still another preferred topsheet is constructed from poly-propylen~ fibers rhich have been carded and thermally bonded in a spaced-apart pattern. Fibers about 3.8 cm long and of from about 1.5 to about 3.0 denier are suitable. A preferred topsheet of this type his a basis reight of about 24 g per ~n2.
Suitable topsheets can also be constructed from apertured plastic files such as those described in U.S. Pat. Nos.:
4,342,314, Radel and Thoepson, issued Aug. 3, 1982: 4,341,217, Ferguson and landrigan, issued July 27, 1982; 4,324,246, ~lullane and S~ntth, issued April 13, 1982; and 3,9?9,135, Tho~pson, issued Dec. 30, 1975.
For example, according to the process of U.S. Pat. No.
4,324,24b, supra, a sa~ople of thereoplastic material such as 0.0038 cn~ thick polyethylene film is heated above its softening point. (The softening point is the temperature at rhich the thermoplastic material can be formed or owldad and is less than the melting point of the ~natarial.) The heated thermoplastic material in sheet form is then brought into contact rith a heated forming screen. The foroing screen is preferably an apertured rite mesh screen having the desired aperture size, pattern and configuration. A vacuum is used to draw the heated film against the forging screen, thereby fonaing the filA into the desired pattern and having the desired hole sizes. Ilhile the vacuum is still being applied to the file, a jet of hot air is passed over the file. The hot air jet perforates the filA in a pattern corresponding to the pattern and size of apertures tn the foraying screen.
Fluid-perseable sheets prepared in the wanner of U.S. Pat.
No. 4,324,246, supra, are conveniently referred to as 'fon~ed films.' The caliper of such fibs is i~aportant since. if the caliper is too great, liquid nay accumulate in the apertures and not readily piss therethrou9h. For the ~tnufactura of fluid absorbent articles such as diapers, cata~enials, incontinence article;, and the like, the sheets typically have a caliper of less than about O.OTS ce, or preferably less than about 0.064 can.

WO 94/22500 E,,, ,~ ~ PCT/US94/02857 Another formed-film sheet material useful herein is the resilient, 3-dimensional web exhibiting a fiber-like appearance and tactile impression, comprising a fluid-impervious plastic .
material, with said web having a multiplicity of apertures, the apertures being defined by a multiplicity of intersecting fiber-like elements, 311 as disclosed in U.S. Pat. No. 4,342,314, supra.
The Radel and Thompson sheet materials can be prepared using hydrophobic plastics such as polyethylene, polypropylene, PVC, and the 1 i ke, and are wel 1-known for use in fl uid absorbent products such as catamenials, and the like.
Yet another type of sheet material useful herein is described in U.S. Pat. No. 3,929,135, supra, and consists of hydrophobic polymer films having holes which are in the form of tapered capillaries. These "tapered capillary" sheets are also known for use in fluid absorbent articles, including adult incontinence articles. They may be prepared from various hydrophobic polymers, as mentioned hereinabove; typically, low density polyethylene having thickness of from 0.0025 to 0.0051 cm is employed.
Reference to U.S. Pat. No. 3,929,135, supra, can be made in order to further visualize tapered capillary sheets. In use, the apices of the capillaries in such tapered capillary topsheets are in contact with the underlying fluid absorbent core material.
Generally, tapered capillaries are in the form of a frustrum of a conical surface, but it is to be understood that any generally tapered structure, such as a frustrum of a pyramid or the like wi th a tri angul ar, square, or polygonal base, i s wi th i n the term "tapered capillary"; circular tapered capillaries, however, are used in this description for convenience. It is also to be understood that the tapered capillaries can be asymmetric (i.e., the angle of taper on one side can be different from that on another side) and that the angle of taper can change continuously (i.e., be curved) over the distance from base to apex. In the latter case, the angle of taper is defined as the angle of the tangent to the side of the capillary at its point of minimum apex opening dimension. The angle of taper suitable for use in top-sheets accordi ng to the practi ce of th i s i nventi on i s from about 10° to about 60°.

WO 94/22500 ~ PCT/IJS94/02857 Base opening dimension of the capillaries s defined as the maximum open measurement in the plane of topsheet at said tapered capillary. Apex opening dimension is defined as the maximum open measurement in the apex of said tapered capillary, which apex is remote from the plane of the topsheet. When the tapered capillary is in the form of a frustrum of a conical surface, the base and apex opening dimensions are, respectively, the base diameter and the apex diameter. Base diameter and apex diameter are herein-after used interchangeably with, respectively, base opening dimension and apex opening dimension.
The tapered capillary apex diameter is a diameter which will allow liquid to readily pass from the surface of the topsheet to the underlying fluid absorbent core. The apex diameter is from about 0.004 to about 0.100 inch (0.010 to 0.254 centimeter), preferably from about 0.005 to about 0.020 inch (0.013 to 0.051 centimeter).
The tapered capillary base diameter is selected to satisfy two criteria. The first of these is the subjective feel of the surface of the topsheet which contacts the skin of the user. It has been discovered that polyethylene can be made to exhibit pleasing, clothlike, non-waxy attributes when the base diameter is within the range from about 0.006 to about 0.250 inch (0.015 to 0.635 centimeter). Preferably, the base diameter should be within the range of from about 0.030 to about 0.060 inch (0.076 to 0.152 centimeter). The second criterion is that the capillary base diameter be small enough to allow an expected liquid droplet to bridge across at least one capillary. This criterion is satisfied by the above dimensions for disposable diapers and sanitary items.
The height of the tapered capillary is defined as the distance between the outermost surface of the topsheet (i.e., that surface which normally contacts the skin of the user) and the apex of the tapered capillary. This height, of course, depends upon apex diameter, base diameter, and angle of taper which have been selected as hereinbefore described. The height of the tapered capillary should provide a structure with a minimum tendency to collapse in use. The characteristics of the material of con-struction of the topsheet in large measure determine suitable WO X4122500 ~ ~ ~ ~ PCT/LTS94102857 ranges for the height. When the topsheet is low density poly-ethylene of from 0.001 to 0.002 inch (0.003 to 0.005 cm) thickness and apex diameter and base diameter are in the preferred range, , and angle of taper a is in its critical range, the height of the tapered capillary can be from about 0.003 to about 0.159 inch (0.008 to 0.404 centimeter).
A state of relative dryness on the surface of the topsheet implies that most of the liquid which contacts the topsheet is transferred through it to the fluid absorbent element. This in turn impl i es that each i sol ated dropl et of fl ui d i n contact wi th the topsheet must be in contact with the base diameter of a tapered capillary. This state of affairs can best be achieved if the land area (the area of the topsheet that exists between the bases of the tapered capillaries) is maintained at a minimum. The minimum limiting value is the case where conical tapered capil-laries or pyramidal tapered capillaries are provided in close packed array (where the periphery of the base of each capillary is in contact on all sides with the periphery of the base of adjacent capillaries). The preferred arrangement of minimum land area tends to insure that an individual droplet will contact at least one tapered capillary. A preferred arrangement in disposable diapers is where the tapered capillaries as hereinbefore described are in ordered arrangement with from about 30 to about 1500 tapered capillaries per square inch of topsheet (5 to 231 per square centimeter).
U.S. Pat. No. 4,629,643, Curro and Linman, issued Dec. 16, 1986, discloses a microapertured polymeric film with improved tactile impression, which can also be used in the practice of this invention.
A highly-preferred fluid-permeable formed-film sheet material which can be employed in the practice of this invention is disclosed in U.S. Pat. No. 4,463,045, Ahr et al., issued July 31, 1984, and reference can be made to that patent to further ass i st visualization of the Ahr et al. structures. ' In general terms, the sheets provided by U.S. Pat. ho.
4,463,045, supra, are designed not only to provide a desirable WO 94/22500 _ ~ ~ '~ ~ ~ ~ '~ PCT/US94/02857 cloth-like tactile impression, but also to substantially eliminate surface gloss. Thus, sheets made of plastic do not have an undesirably shiny, "plasticky" appearance.
"One-way" sheets whose back faces are treated with hydro philic latex are described in U.S. Pat. No. 4,735,843, Noda, issued April 5, 1988, and these'can also be employed herein.
In addition to the sophisticated apertured materials men tioned hereinabove, the practice of the present invention may also be undertaken with hydrophobic sheet materials having simple holes punched therethrough.
It will be understood from the foregoing that the aforesaid, preferred, "sheet" or "film" materials used in the practice of this invention are substantially different from fibrous nonwoven materials, which are characterized by a large number of fibers which overlap each other throughout the thickness of the material.
Moreover, such sheet materials are made from materials (prefer-ably, hydrophobic thermoplastic polymeric materials) which provide a clean-appearing, stain-resistant or "non-staining" surface, in use.
Other topsheet materials which can be used herein include, for example, various nonabsorbent fibrous or filamentous network sheets which are aqueous-fluid-permeable by virtue of a multi-plicity of holes or channels passing therethrough. Such sheet materials can be prepared by methods well-described in the patent literature. For example, according to the process of U.S. Pat.
No. 4,636,419, Madsen et al., issued Jan. 13, 1987, sheets com-prising a network of ribboned filaments of two dissimilar chemical types, and with two dissimilar melting or softening points, are contacted and cooled to allow the formation of a network sheet characterized by said different transverse and longitudinal polymer materials. Such sheets can be used in the practice of this invention.
Another sheet material useful herein is the formaminous net comprising a reticular network of polymeric filaments, said net comprising two arrays of filaments oriented at a displacement angle of about 20-90 degrees. Reference can be made to European SFaVf BY: 3-18-99 ; 7:16PM ; SIM & McBURNEI'-451#2237637#1819953;#21/26 wo 9or~soo Pcrr<rs9.aroass~
-2s-Patent Application 0215411, filed 5ept. 6, 1986, Sneyd et al., to further assist visualization of this sheet. The aforesaid sheet materials can be prepared using hydrophobic plastics such as polyethylene, polypropylene, PVC, and the like, and are well~known for use in absorbent products such as catamenial s, and the 1 i ke.
Such sheet materials typically have a basis weight of about 0. 5-5. 0 ounces/yd2 ( about 0.0016 ~g/ceiZ ~ 0.016 g/cm2) , a cal i per of 5-25 mils, an open area of about 30-gOX and a Mesh of 20-40.
The size of topsheet is dictated by the product design and the size of the wearer. It can be ascertained by those skilled in the ~rt.~
V. Basking Shg~
One na,)or function of the backing sheet (or backsheet) is to prevent body fluids from escaping from, e.g., disposable diaper or catamenial products, and soiling the wearer's outer garments and other surfaces in contact: with said products. Any compliant, non-irritating, planar material which is impermeable to body fluids can be used as backsheet.
A preferred backsheet is formed from poly-ethylene film having a thickness of from about 0.001 to about 0.5 nm, preferably from about 0.012 tv about 0.031 an.
Flushable or biodegradable backing sheets can also be used, e.g., wlth pantiliner devices herein.
The size of the backsheet is dictated by the exact product design selected and the size of the intended wearer; it can be readily ~'scartalned by those skilled in the art.
YI. Dntional Retains g heap the fluid absorbent structures herein can optionally, but preferably, be provided with means to hold them in place on or near the user's body to allow the structures to perfone their intended function. For example, diapers and incontinence gar,eents can be provided with well-known coauercially-available tape fasteners. Sanitary napkins can be provided rith glue strives facing outward on their backsheet in well-known fashion. Various pins, clips and fasteners of well-known types can optionally tie WO 94/22500 - ~ PCT/LJS94l02857 _ 27 _ employed. The retaining means also provide an additional benefit in that they can contain the body fluids in a more enclosed space.
As a consequence, the malodor is also contained and more readily absorbed and removed by the odor controlling agents.
VII. Incorporation of Encapsulated Perfume into Absorbent Articles Small particle size cyclodextrin/perfume complexes can be applied to the fluid absorbent articles by uniformly sprinkling, mixing, or distributing the cyclodextrin/perfume complex powder onto the fluid absorbent materials.
However, it is commonly known that when in use, the body fluid is not normally distributed to the whole fluid absorbent article, e.g., diaper, but usually localized in a portion of the article. Actually, modern disposable diapers are designed with a concentration of the fluid absorbent materials at different loca-ti ons dependi ng on the sex of the wearers . Simi 1 arly, i t i s not necessary to apply the cyclodextrin/perfume complex powder to the entire fluid absorbent article. Preferably, cyclodextrin/perfume complex powder is applied to areas most likely to be wetted by ZO body fluids to avoid waste in the areas which do not normally receive the body fluids.
Furthermore, when distributed as a dry powder, the cyclo-dextrin/perfume complex particles may shift away from the pre-ferred locations, and move to the areas where they have less chance to be solubilized by the body fluids, and become less effective. The shifting happens both during the manufacturing processes, e.g., folding, and packaging of the articles, and during later steps, e.g., transportation, and unfolding and refolding of the fluid absorbent article in use. Therefore, it is preferred to provide a means to immobilize the cyclodextrin/per-fume complex powder on the preferred locations in the fluid absorbent articles.
Immobilization can be accomplished by a variety of methods, i.e., hot-melt adhesives, thermoplastic binder fibers, thermo plastic binder particles, or other methods known to those skilled in the art.

A preferred method is to use a water-soluble binder to attach the cyclodextrin/perfume complex powder to the fluid absorbent core and/or topsheets. The water-soluble binders are preferably -polymeric. They can be low melting polymers such as polyethylene glycols (PEG), polyethylene glycol) methyl ethers, or mixtures -thereof. Preferred low melting water-soluble PEG materials have the general formula RO-(CH2CH20)n-R wherein each R is a hydrogen radical, a C1-C4 alkyl radical, or mixtures of such radicals, and have an average molecular weight (MW) of from about 600 to about 20,000 (n is from about 13 to about 450). More preferred PEG
materials are polyethylene glycols, polyethylene glycol) methyl ethers, or mixtures thereof, with MW of from about 1,000 to about 9,000 (n from about 20 to about 200), more preferably from about 1,400 to about 4,500 (n from about 30 to about 100). The weight ratio of the cyclodextrin/perfume complex to the PEG material is from about 3:1 to about 1:5, preferably from about 2:1 to about 1:3.
A preferred process of attaching cyclodextrin/perfume complex powder involves admixing solid small-particle-sized cyclodex-trin/perfume complex powder with a molten hydrophilic PEG
materi al . The mol ten mi xture can be sprayed di rectly to the dry fluid absorbent materials or topsheets, then letting the droplets solidify on said materials or nonwoven topsheets. Another pre-ferred method is to pulverize the solidified cyclodextrin com-plex/binder mixture into small particles first. Said particles can then be attached and immobilized to the surface of the fluid absorbent materials or the nonwoven topsheets by distributing the particles on said surface, melting said particles by, e.g., a heat source, and then resolidifying to bind said particles to said surface. At the cyclodextrin/perfume complex to the PEG material weight ratio of from about 3:1 to about 1:3, the molten mixture can be solidified to room temperature then pulverized at room temperature or cryogenically. At the cyclodextrin/perfume complex to the PEG material weight ratio of from about 1:2 to about 1:5, the molten mixture can be grilled by, e.g., spray drying, marumar-izing, etc., into solid grills. The solid cyclodextrin/perfume complex/PEG material mixture particles preferably have sizes of PCTlUS94/02857 from about 10 microns to about 1,000 microns, more preferably from about 20 microns to about 600 microns.
Another preferred method is to apply the cyclodextrin/perfume complex slurry to the fluid absorbent material and/or nonwoven y 5 topsheet. Upon drying, the small particles of the cyclodextrin complex adhere to the absorbent material and are immobilized on said material. This can be done, e.g., by spraying the cyclo-dextrin/perfume complex slurry onto the already formed and dry absorbent fiber web.
It is also preferred to incorporate a water-soluble polymer, such as PEG, polyvinyl alcohols, polyacrylic acids, and polyvinyl-pyrrolidone into the aqueous cyclodextrin/perfume complex slurry after the complex has been formed. The aqueous mixture is dis-tributed, e.g., by spraying, to the fluid absorbent materials or the nonwoven topsheets, then the resulting combination is dried, and thus attaching the cyclodextrin to said fluid absorbent materials or topsheets. Preferred MW of said polymers are from about 1,000 to about 200,000; more preferred are from about 2,000 to about 100,000.
A perfume used in the following examples is as follows:
Volatile Perfume Composition Component Wt.%
Alpha Pinene 5.0 Cedarwood Terpenes 20.0 Dihydro Myrcenol 10.0 Eugenol 5.0 Lavandin 15.0 Lemon Oil CP 10.0 Orange Terpenes 15.0 Phenyl Ethyl Alcohol 20.0 Total 100.0 Following are non-limiting examples of moisture-activated encapsulated perfumes (cyclodextrin/perfume inclusion complexes and matrix perfume microcapsules) that can be incorporated in the articles of this invention.

SENT BY: 3-18-99 : 7:17PM : SlM & McBURNEY~451#2237:k637#1819953.#22/26 WO 94/u500 PCrIUS9alp2857 A mobile slurry is prepared by mixing about I kg of beta-cyclodextrin and about 1,000 ml of water in a stainless steel mixing bowl of a KitchenAid mixer using a plastic coated heavy-duty mixing blade. Nixing is continued while about 175 g of the perfume is slowly added. The liquid-like slurry ia~nediately starts to thicken and becooks a creamy paste. Stirring is continued for about 30 minutes. The paste is now dough-like in appearance, About 500 ml of water is added to the paste and blended well. Stirring is then resuaed for about an additional 30 minutes. During this time the complex again thickens, although not to the same degree as before the additional cater is added.
The resulting creamy complex is spread in a thin layer on a tray and allowed to air dry. This produces about II00 g of granular solid which is ground to a fine power. The complex retains some free perfua~e and still has a residual perfume odor.
"~~o °1ex The last traces of cater in Complex 1 are removed by freeze drying, after which Complex 1 loses about lx of its weight.
Examination of the complex particles by scanning electron mitro scopy shows that practically all of the ultimate (primary) par-ticles of the complex have particle sizes less than about 5 ~oicrons. The resulting solid is washed with diethyl ether to remove the residual unco~nplexed perfume. The last traces of ether are rasoved in vacuo to give Coa~plex 2 as a white powder rhich is odorless then dry but produces the fragrance of the perfume Then added to cater.
A ieobi 1 a sl urry i s prepared by ~nixi ng about 600 g of beta cyclodextrin and 600 ml of water in a stainless steel mixing bowl of a Kitchen Aiclm mixer using a plastic coated heavy duty mixing blade. Mixing is continued rhila about 105 g of the perfume is slowly added. The liquid-like slurry i~ediately starts to thicken and becomes a creamy paste. Stirring is continued for about 30 minutes. About 1,200 ml of water is slowly added to the slurry with stirring. The stirring continues for about an addi-tional 30 minutes to give a liquid Slurry 1.

WO 94/22500 ~ ~ ~ J PCT/US94/02857 lurr A mobile slurry is prepared similarly to that of Slurry 1, except that the additional 1,200 ml of water contains about 20 g of dissolved polyethylene glycol with molecular weight of about 3,400.
Complex Particles 1 Solid cyclodextrin/perfume ~complex/polyethylene glycol par-ticles are prepared as follows. One part of Complex 1 is mixed thoroughly with about 1 part of molten polyethylene glycol with an average MW of about 3,400, at about 70'. The composition solidi-fies upon cooling, and is cryogenically ground with dry ice. The resulting solid cyclodextrin/perfume complex/polyethylene glycol parti cl es are sorted to get parti cl a s i ze of 1 ess than about 500 microns.
Complex Particles Solid cyclodextrin/perfume complex/polyethylene glycol par-ticles are prepared as follows. One part of Complex 1 is mixed thoroughly with about 3 parts of molten polyethylene glycol with an average MW of about 1,450, at about 80'. The molten compo-sition is atomized in a spray drying tower to obtain solid par-ticles. Solid particles solidify on the wall of the tower and are removed for particle size classification. Particles larger than about 500 mi Irons are ground further to reduce the part i cl a s i ze by cryogenic grinding with dry ice.
Matrix Perfume Microcansules Water-activated matrix perfume microcapsules can be applied to the fluid absorbent articles by uniformly sprinkling, mixing, or distributing the microcapsules onto the fluid absorbent materials. It is preferred to have the perfume microcapsules applied to areas most likely to be wetted by body fluids.
An example of water-activated matrix perfume microcapsules is an IN-CAP microcapsule sample (hereinafter called "Microcapsule 1") obtainable from Polak's Frutal Works, Inc., having about 50%
- perfume loading and particle size range of from about 3 microns to about 100 microns. Major components of the perfume are highly volatile components, such as citral and d-limonene.

SENT BY~ 3-18-99 : 7~17PM : SIM & McBURNEY-'451#2237:k637#1819953:#23/26 WO 94~Z25D0 PCTIU594102857 All percentages, ratios, and parts herein, in the Specifi-cation, Examples, and Claims, are by weight and ire approximations unless otherwise stated.
The following are non-limiting examples of the instant coepositions, articles, and methods.
,(AMPLE 1 A composition of muter suitable for use as an absorbent pad in diapers, sanitary napkins, and the like, comprises a substantially homogeneous blend of the following.
I n~;tr_Pdi ent Southern Softwood Kraft Cellulose Fibers 79 Valfore CP300~56 Intermediate Zeolite 20 Complex 2 1 ~jAMP~E 2 A composition of atatter suitable for use as an absorbent pad in diapers, sanitary napkins, and the like, is prepared as follows. About 2 parts of Slurry 1 is sprayed on about 20 parts of Kraft cellulose fibers, and let dry. About 5 parts of Valfor~
CP300-35 is blended in to forth the structure.
EXAhIP~E 3 A composition of matter suitable for use as an absorbent pad in diapers, sanitary napkins, and the like, is prepared as follows. One part of Complex Particles 1 is dry mixed vith about 20 parts of Kraft cellulose fibers and about 4 parts of zeolite (C8V400). The resulting mixture is placed in an 80'C oven for about 5 atinutes to attach said Complex Particles 1 onto said fibers.
~9nP~.E.~
A lightweight pantiliner suitable for use betvsen menstrual periods, and which can be disposed of in a toilet (i.e., 'flush-abl e' ) contpri see a pad of Exarnpl a 1 ( surface area about 117 ctn~ ;
with about 3 g Southern Softwood Kraft Cellulose Fibers air felt;
about 1 g zeollte; and about 40 ag cyclodextrin/perfume complex), said pad being interposed between the topsheet of U.S. Pat. No.
4,163,045, supra, and a fibrous, nonwoven, flushable backsheet.

WO 94/22500 _ ~ ~ ~ PCT/US94/02857 1=XAMPLE 5 A catamenial product in the form of a sanitary napkin having r two flaps extending outward from its absorbent core is prepared using the pad of Example 2 (surface area about 117 cm2; about 8.5 g Southern Softwood Kraft Cellulose Fibers air felt; about 2.13 g zeolite, and about 0.24 g cyclodextrin/perfume complex), per the design of U.S. Pat. No. 4,687,478, Van Tillburg, issued Aug. 18, 1987. The nonglossy sheet of U.S. Pat. No. 4,463,045, supra, is used as the topsheet.

A disposable baby diaper using the odor-control pad of Example I is prepared as follows. The dimensions listed are for a diaper intended for use with a child in the 6-10 kilogram size range. These dimensions can be modified proportionately for different size children, or for adult incontinence briefs, accord-ing to standard practice.
1. Backsheet: about 0.025-0.070 mm polyethylene; width at top and bottom about 33 cm; notched inwardly on both sides to a width-at-center of about 28.5 cm; length about 50.2 cm.
2. Topsheet: tapered capillary polyethylene topsheet, per U.S. Patent 3,929,135, described hereinabove; width at top and bottom about 33 cm; notched inwardly on both sides to a width-at-center of about 28.5 cm; length about 50.2 cm.
3. Absorbent core: air-laid wood pulp fibers per Example 3;
Taber stiffness range about 7-9.5, about 8.4 mm thick, calendered;
width at top and bottom about 28.6 cm; notched inwardly at both sides to a width-at-center of about 10.2 cm; length about 44.5 cm;
about 3.2 g of zeolite powder and about 0.8 g of Complex Par ticle 1 dispersed in said core.
4. Elastic leg bands: four individual rubber strips (2 per side); width about 4.77 mm; length about 370 mm; thickness about 0.178 mm (all the foregoing dimensions being in the relaxed state).
The diaper of Example 6 is prepared in standard fashion by positioning the core-plus-odor control material and scent signal covered with the topsheet on the backsheet and gluing.

The elastic bands (designated "inner" and "outer," corres-ponding to the bands closest to, and farthest from, the core, respectively) are stretched to about 50.2 cm and positioned between the topsheet/backsheet along each longitudinal side (2 bands per side) of the core. The inner bands along each side are .
positioned about 55 mm from the narrowest width of the core (measured from the inner edge of the elastic band). This provides a spacing element along each side of the diaper comprising the flexible topsheet/ backsheet material between the inner elastic and the curved edge of the core. The inner bands are glued down along their length in the stretched state. The outer bands are positioned about 13 mm from the inner bands, and are glued down along their length in the stretched state. Since the top-sheet/backsheet assembly is flexible, the glued-down bands con-tract to elasticize the sides of the diaper.

The preparation of a thin sanitary napkin is as follows.
A commercially available trifold wet-laid tissue containing approximately 5 g of absorbent gelling material particles per square foot (which yields about 0.68 g absorbent gelling material per sanitary napkin pad) is used to prepare the core. The trifold tissue laminate is sprayed with a fine mist of water and opened to expose the absorbent gelling material. About 1.0 g of Ilalfor CP300-56 is sprinkled onto the AGM. The two sides of the tissue are folded back to their original position, thereby sealing the absorbent gelling material and zeolite inside. The still moist core is resealed by using a hot iron, pressing firmly. About 0.2 g of Complex Particles 2 is sprinkled onto the dry core, with higher concentration at the central area of the core surface. An additional piece of tissue is positioned on top of the core. A
hot i ron i s pressed on top of the ti ssue to mel t the PEG of the cyciodextrin/perfume complex so that upon cooling the complex particles are bound to (immobilized on) the core surface and the tissue. ' An absorbent core prepared in the foregoing manner (about 20 cm x 7 cm) is placed on top of a slightly larger piece of poly-ethylene backsheet, with the piece of tissue exposed on top. A
microns.
Complex Particles Solid cyc WO 94/22500 - ~ ~ ~ ~ ~ ~ ~ PCT/US94/02857 formed-film topsheet of the type disclosed in U.S. Pat. No.
4,463,045 is coated evenly on its underside with about 0.03 g of a latex adhesive, and excess adhesive is wiped off. The topsheet is rol 1 ed wi th a gl ass rod to ensure good contact and proper appl i -, 5 cation of adhesive. The topsheet is then placed on top of the above-prepared core assembly. ~To ensure good core bonding, the topsheet is weighted with a piece of Plexiglas.
The assembly is sealed together to provide the overall product: topsheet/tissue/cyclodextrin complex/absorbent core with odor-controlling components/backsheet. Optionally, adhesive can be applied on the outside of the backsheet of the pad for affixing the article to undergarments. The topsheet of the product is sprayed with about 0.03 g of Pegosperse~ nonionic surfactant (PEG
200) to hydrophilize the fluid-receiving surface of the topsheet.
While the foregoing illustrates the preparation of a sanitary napkin in the manner of this invention, an entirely similar operation can be employed to prepare a pantiliner (generally of the dimensions approximately 14 cm x 5 cm) with appropriate modifications of the amounts of the ingredients, as noted here inabove.

A composition of matter suitable for use as an absorbent pad comprises a homogeneous blend of the following:
Ingredient Wt,~
Southern Softwood Kraft Cellulose Fibers 79.5 Valfor~ CP300-56 Zeolite 20.0 Microcapsule 1 0.5 A pantiliner is prepared similarly to that of Example 4, except that a pad of Example 8 is used.
When the zeolites are optionally to be used in conjunction with activated carbon, it is preferred (for aesthetics reasons) to coat the carbon with the zeolite using a binder. The following illustrates this in detail.
Preparation of Carbon/Zeolite/Binder Particles - A simple, yet effective, method for preparing the particles herein employs a SENT BY: 3-18-99 ; 7:17PM ; SIM & McBURNEY-451#2237~k637#1819953:#24/26 w0 9a225oo PCiNS94lOZ857 fluidized bed coating apparatus.
Fly He CQ~~tina - 6attom spray fluid bed (Wurster) is the preferred method: This is an effective tray to get a good coating onto an individual particle, because of the ordered flow up the center draft tube and because the flow of the spray and particle are in the same direction. Using bottom spray without the tube with charcoal/zeolite provides a' desirable agglomerated particle in the manner of this invention. The lower limit of this process is nominally 100 microns.
Using the llurster process a preferred particle is made using about 300-500 micron size carbon (CALGON PCB30x140) and about 1-90 micron size inter~di~te tango zeolite (VALFOR; Philadelphia -Quartz) with lIETHOCEL E5 as the binder. This provides the follow-ing advantages. Starting with a larger size core particle gives a bigger 'target' for the coating spray to hit. The particle flow in the draft tube is normally more regular. t4oreowr, for the same reight percent of coating, the wall is thicker on a larger tore particle. (The surface to area ratio is smaller for a larger particle.) A thicker wall means better masking. In addition, 2o METHOCEL E5 is somewhat tacky and has . high viscosity. While a higher viscosity can limit the ability co atomize and pump-on the coating, it also can mean a stickier coating. Other coatings that are less viscous do not appear to duplicate this effect.
In a representative exempla, about 100 g of METHOCEL SE
binder are dissolved in about 1900 ml deionized water. Zealite {YALFOR CP300-56; about 398 g) is added to the hETHOCEI solution (abouT 19.9x dispersion). A high shear mixer (Tekmar High Shear llixer~del 5045) is used to create a dispersion of the zaolite.
Typical shtar time is about 15 minutes.
About 996 g of ~mn~ercial carbon ponder are placed in a Wurstar Fluid Bed Coater (about 10 cm Ascoat llrit hadel 101, Lasko Co., Leominster, llassathusetts). The carbon material is fluidized in the bed at an air flow of about 18 scf~ (standard cubic ft./min.); the inlet temperature is brought to about 138'F (about 59'C).
The flow of YALFOR/hETHOCEL coating solution into the spray nozzle is begun (1/4-Round Spray Nozzle made by The Spray~n9 WO 94/22500 ~ ! ~ ~ PCTIUS94102857 Systems Co.; 0.40/0.100 fluid cap.; 0.120 air cap.). The flow rate i s set at 7 . 7 g/mi n . Exi t ai r temperature i s about 77-84' F
(25' to about 29'C).
In a typical run, particles prepared in the foregoing manner . 5 comprise from about 20% to about 50% carbon; from about 20% to about 40% zeolite, the balance comprising the binder. Particle sizes range from about 90 to about 300 microns.
These carbon-containing, zeolite-coated, odor-controlling particles are especially adapted for use in catamenials, especi ally sanitary napkins, as well as in other disposable sanitary products. The preferred particles herein are of an off-white to gray or light bluish color, and are, thus, rather unobtrusive in the product. The mixture of zeolite-coated carbon particles and particulate absorbent gelling material (especially polyacrylates or starch/acrylates) is easily added to disposable articles. The particle mixture is spread or sprinkled onto a water-permeable paper or nonwoven tissue and covered with a second tissue to form a tissue/particles/tissue laminate structure that is quite thin.
The tissue laminate is then placed in the article, generally as a layer directly under the topsheet. (Optionally, an absorbent core can underlie the tissue layer, e.g., in a sanitary napkin. For pantiliners, the additional fluid absorbent capacity afforded by the absorbent core is optional, and may not be needed for most uses.) The zeolite/carbon particles control odor and the absorbent gelling material both helps control some odor, plus absorbs body fluids.
The following Example 10 illustrates a preferred tissue/par-ticles/tissue laminate and its use in a sanitary napkin or panti-liner, using the following preferred materials.
1. Carbon - available from Calgon as PCB30x140; average particle size (sieve analysis) ranging from about 100 to about 600 microns, preferably from about 200 to about 500 microns.
2. Zeolite - available as any of the 11ALFOR series; or Zeolite Y (Conteka); average particle size (X-ray analysis) ranging from about 0.2 to about 90 microns.
3. Coating method - Wurster fluidized bed, using METHOCEL
E5/water at from about 4% to about 10~, preferably from about 4.5%

to about 8.5X, by weight METHOCEL.
4. Weight ratio of zeolite:carbon from about 0.8 to about 1.25, preferably about 1:1.
5. Color - off-white to gray or gray/bluish.
6. Size of zeolite/METHOCEL/carbon particle (sieve analy-sis, average size) from about 125 to about 825 microns, although particles up to about 1,000 microns are satisfactory.

7. Absorbent gelling material - polyacrylate or starch/
polyacrylate/available as L-74 from Shokubai or as 1180 from NALCO. Average particle sizes range from about 100 to about 350 microns, preferably from about 150 to about 300 microns.

8. Weight ratio of zeolite-coated carbon particles to absorbent gelling material particles - in the range of from about 10:1 to about 1:10, preferably from about 3:1 to about 1:3, most preferably about 1:1.

9. Amount of zeolite-coated carbon particles used per tissue laminate - for sanitary napkins ranging from about 0.1 g to about 1.5 g, preferably at least about 0.24 g. For pantiliners, somewhat less can be used; typically from about 0.1 g to about ZO 0.5 g.

10. Amount of absorbent gelling material used per tissue laminate - for sanitary napkins ranging from about 0.2 g to about 1.0 g, preferably at least about 0.5 g. For pantiliners, somewhat less can be used; typically from about 0.1 g to about 0.5 g.

11. Amount of cyclodextrin/perfume complex used per tissue laminate - from about 0.01 g to about 0.5 g.

The preparation of a thin sanitary napkin is similar to that of Example 7.
A commercially-available trifold wet-laid tissue containing approximately 5 g of absorbent gelling material particles per square foot (which yields approximately 0.68 g absorbent gelling material per sanitary napkin pad) is used to prepare the core.
The tri fol d ti slue 1 ami pate i s sprayed wi th a f i ne mi st of water and opened to expose the absorbent gelling material. About 1.2 g of IIALFOR-coated charcoal, prepared by the Wurster coating process (noted above) is sprinkled onto the AGM. The two sides of the tissue are folded back to their original position, thereby sealing the absorbent gelling material and zeolite-coated charcoal inside.
The still moist core is resealed by using a hot iron, pressing firmly.
. 5 An absorbent core prepared in the foregoing manner (about 20 cm x 7 cm) is placed on top of a slightly larger piece of poly-ethylene backsheet. About 0.2 g of Complex Particles 2 is sprinkled onto the dry core, with higher concentration at the central area of the core surface. An additional piece of tissue i s then posi ti oned on top of the Compl ex Parti cl es and the core .
A hot i ron i s pressed on top of the ti ssue to mel t and bond the cyclodextrin/perfume complex to the core surface and the tissue.
A formed-film topsheet is treated and placed on top of the above-prepared core assembly in the same manner as in Example 7.
It will be understood that the practice of the present invention applies not only to human odors, but also to animal odors.
WHAT IS CLAIMED IS:

Claims (34)

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS;

1. A composition comprising:
I. an effective amount of moisture-activated encapsulated perfume;
II. an effective amount of odor-controlling agent selected from the group consisting of:
A. an intermediate silicate/aluminate zeolite having a SiO2/AlO2 molar ratio of less than 10:
B. a mixture of activated carbon and zeolite wherein the carbon is coated with the zeolite;
C. kieselguhr; and D. mixtures thereof; and III. an effective amount of fluid adsorbing material.

2. The composition of Claim 1 wherein the perfume is selected from the group consisting of highly volatile perfume, moderately volatile perfume, and mixtures thereof.

3. The composition of Claim 2 wherein the perfume is highly volatile perfume.

4. The composition of Claim 1 wherein the moisture-activated encapsulated perfume is selected from the group consisting of cyclodextrin/perfume inclusion complexes, solid cellular matrix perfume microcapsules, and mixtures thereof.

5. The composition of Claim 4 wherein the moisture-activated encapsulated perfume is cyclodextrin/perfume inclusion complex of which a major portion has a particle site of less than about 10 microns.

6. The composition of Claim 5 wherein a major portion of the cyclodextrin/perfume inclusion complex has a particle size of less than about 8 microns.

7. The composition of claim 6 wherein a mayor portion of the cyclodextrin/perfume inclusion complex has a particle size of less than about 5 microns.

8. The composition of Claim 5 wherein the cyclodextrin is a mixture of alpha-, beta-, and gamma-cyclodextrin.

9. The composition of Claim 8 wherein a major portion of the cyclodextrin is beta-cyclodextrin.

10. The composition of Claim 1 wherein the fluid absorbing material is selected from the group consorting of fibrous absorbent material, absorbent gelling material, absorbent foam, absorbent sponge, anti mixtures thereof.

11. The composition of Claim 10 wherein the fibrous absorbent material is selected from the group consisting of cotton fluff, cellulose pulp, chemithermomechanical pulp, citric acid cross-linked cellulose pulp, synthetic fibers, and mixtures thereof.

12. The composition of Claim 10 wherein the absorbent gelling material is selected from the group consisting off:
(a) hydrolyzed polyacrylate gelling material;

(b) hydrolyzed polyacrylate grafted starch gelling material;
(c) hydrolyzed polyacrylonitrile grafted starch;
(d) maleic anhydride-isobutylene copolymers; and (e) mixtures thereof.

13. The composition of Claim 12 wherein the absorbent gelling material is (a), (b), and mixtures thereof.

14. An article of manufacture selected from the group consisting of:
(a) catamenials;
(b) pantiliners;
(c) diapers;
(d) adult incontinence garments; and (e) underarm shields;
comprising:
I. an effective amount of moisture-activated encapsulated perfume:
II. an effective amount of odor-controlling agent selected from the group consisting of:
A. an intermediate silicate/aluminate zeolite having a SiO2/AlO2 molar ratio of less than 10;
B. a mixture of activated carbon and zeolite wherein the carbon is coated with the zeolite;
C. kieselguhr; and D. mixtures thereof; and III. an effective amount of fluid absorbing material.

15. The article of Claim 14 wherein the perfume is selected from the group consisting of highly volatile perfume, moderately volatile perfume, and mixtures thereof.

16. The article of Claim 15 wherein the perfume is highly volatile perfume.

17, The article of Claim 14 comprising:
I. from about 0.001 g to about 10 g of moisture-activated encapsulated perfume; and II. from about 0.01 g to about 15 g odor-controlling agent.

18. The article of Claim 17 wherein the moisture-activated encapsulated perfume is selected from the group consisting of cyclodextrin/perfume inclusion complexes, solid cellular matrix perfume microcapsules, and mixtures thereof.

19. The article of Claim 18 wherein the moisture-activated encapsulated perfume is cyclodextrin/perfume inclusion complex having a level of from about 0.01 g to about 3 g and a major portion having a particle size of less than about 12 microns.

20. The article of Claim 19 wherein the level of inclusion complex is from about 0.02 g to about 1 g and a mayor portion has a particle size of less than about 10 microns.

21. The article of Clam 20 wherein a mayor portion of the inclusion complex has a particle size of less than about 6 microns.

22. The article of Claim 21 wherein a mayor portion of the inclusion complex has a particle size of less than about 5 microns.

23. The article of Claim 19 wherein the cyclodextrin is a mixture of alpha-, beta-, and gamma-cyclodextrin.

24. The article of Claim 23 wherein a major portion of the cyclodextrin is beta-cyclodextrin.

25. The article of Claim 17 wherein the level of odor-controlling agent is from about 0.1 g to about 10.0 g per article.

26. The article of Claim 14 wherein the fluid absorbing material is selected from the group consisting of fibrous absorbent material, absorbent gelling material, absorbent foam, absorbent sponge, and mixtures thereof.

21, The article of Claim 26 wherein the fibrous absorbent material is selected from the group consisting of cotton fluff, cellulose pulp, chemithermomechanical pulp, citric acid cross-linked cellulose pulp, synthetic fibers, and mixtures thereof.

28. The article of Claim 26 wherein the absorbent gelling material is selected from the group consisting of:
(a) hydrolyzed polyacrylate gelling material;
(b) hydrolyzed polyacrylate grafted starch gelling material;
(c) hydrolyzed polyacrylonitrile grafted starch;
(d) maleic anhydride-isobutylene copolymers; and (e) mixtures thereof.

29. The article of Claim 28 wherein the absorbent gelling maternal is (a), (b), and mixtures thereof.

30. The article of claim 14 wherein the article comprises:
(a) a flexible, fluid-receiving front face;
(b) a fluid-retaining absorbent care beneath the front face comprising fluid-absorbing material;
(c) a backsheet beneath the core: and (d) optionally, a retaining means for keeping the article in a position to perform its absorbency function.

31. The article of Claim 30 wherein the moisture-activated encapsulated perfume is located in the central area of (a), (b), and mixtures thereof.

32. The article of Claim 31 wherein the article additionally comprises a means for immobilising the moisture-activated encapsulated perfume.

33. The article of Claim 32 wherein the article has less than about 1% non-encapsulated surface perfume,

34. A method for decreasing odors associated with bodily fluids such as blood, and urine, and for providing a scent signal, comprising contacting said fluids with:
I. an effective amount of moisture-activated encapsulated perfume;
II. an effective amount of odor-controlling agent selected from the group consisting of:

A. intermediate silicate/aluminate zeolite having a SiO2/AlO2 molar ratio of less than 10;
B. a mixture of activated carbon and zeolite wherein the carbon is coated with the zeolite:
C. kieselguhr; and D. mixtures thereof: and an effective amount of fluid absorbing material.