CA2142733A1 - Impact modification of thermoplastics - Google Patents

Impact modification of thermoplastics

Info

Publication number
CA2142733A1
CA2142733A1 CA002142733A CA2142733A CA2142733A1 CA 2142733 A1 CA2142733 A1 CA 2142733A1 CA 002142733 A CA002142733 A CA 002142733A CA 2142733 A CA2142733 A CA 2142733A CA 2142733 A1 CA2142733 A1 CA 2142733A1
Authority
CA
Canada
Prior art keywords
thermoplastics
alpha
compositions
impact modification
linear ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002142733A
Other languages
French (fr)
Other versions
CA2142733C (en
Inventor
H. Craig Silvis
Daniel J. Murray
Thomas R. Fiske
Stephen R. Betso
Robert R. Turley
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Global Technologies LLC
Original Assignee
H. Craig Silvis
Daniel J. Murray
Thomas R. Fiske
Stephen R. Betso
Robert R. Turley
The Dow Chemical Company
Dow Global Technologies Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by H. Craig Silvis, Daniel J. Murray, Thomas R. Fiske, Stephen R. Betso, Robert R. Turley, The Dow Chemical Company, Dow Global Technologies Inc. filed Critical H. Craig Silvis
Publication of CA2142733A1 publication Critical patent/CA2142733A1/en
Application granted granted Critical
Publication of CA2142733C publication Critical patent/CA2142733C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C19/00—Tyre parts or constructions not otherwise provided for
    • B60C19/002—Noise damping elements provided in the tyre structure or attached thereto, e.g. in the tyre interior
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S138/00—Pipes and tubular conduits
    • Y10S138/07—Resins

Abstract

Compositions having good low temperature impact performance made from a thermoplastic (e.g., a polyolefin such as polypropylene) and either at least one linear ethylene/C5-C20 .alpha.-olefin or at least one substantially linear ethylene/C3-C20 .alpha.-olefin polymer are disclosed. The compositions are easily molded and have particular utility in making automotive facia, parts and other household articles.
CA002142733A 1992-09-15 1993-09-15 Impact modification of thermoplastics Expired - Lifetime CA2142733C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US94503492A 1992-09-15 1992-09-15
US07/945,034 1992-09-15
US4533093A 1993-04-08 1993-04-08
US08/045,330 1993-04-08
PCT/US1993/008731 WO1994006859A1 (en) 1992-09-15 1993-09-15 Impact modification of thermoplastics

Publications (2)

Publication Number Publication Date
CA2142733A1 true CA2142733A1 (en) 1994-03-31
CA2142733C CA2142733C (en) 2005-02-08

Family

ID=26722651

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002142733A Expired - Lifetime CA2142733C (en) 1992-09-15 1993-09-15 Impact modification of thermoplastics

Country Status (8)

Country Link
US (5) US5576374A (en)
EP (2) EP0877050B1 (en)
JP (2) JP3373516B2 (en)
CA (1) CA2142733C (en)
DE (2) DE69322871T2 (en)
ES (2) ES2126002T3 (en)
FI (1) FI951192A (en)
WO (1) WO1994006859A1 (en)

Families Citing this family (185)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5525695A (en) * 1991-10-15 1996-06-11 The Dow Chemical Company Elastic linear interpolymers
US6270867B1 (en) 1993-06-24 2001-08-07 Pechiney Plastic Packaging, Inc. Structures of polymers made from single site catalysts
US5360648A (en) * 1993-06-24 1994-11-01 The Dow Chemical Company Pouch for packaging flowable materials
US5723507A (en) * 1996-03-11 1998-03-03 The Dow Chemical Company Foamed gaskets made from homogeneous olefin polymers
US6472042B1 (en) * 1994-02-10 2002-10-29 Dow Global Technologies Inc. Highly filled thermoplastic compositions
US6218470B1 (en) 1994-06-01 2001-04-17 The Dow Chemical Company Thermoplastic elastomeric blends
JP3191054B2 (en) * 1994-06-01 2001-07-23 ザ・ダウ・ケミカル・カンパニー Thermoplastic blend composition
US5773515A (en) * 1994-08-25 1998-06-30 Solvay Engineered Polymers Engineered polyolefin materials
US5763534A (en) * 1994-08-25 1998-06-09 Solvay Engineered Polymers Thermoplastic polypropylene blends with mixtures of ethylene/butene and ethylene/octene copolymer elastomers
US6403710B1 (en) 1994-08-29 2002-06-11 The Dow Chemical Company Block copolymer compositions containing substantially inert thermoelastic extenders
WO1996012765A1 (en) * 1994-10-24 1996-05-02 Asahi Kasei Kogyo Kabushiki Kaisha Polyoxymethylene resin composition
JP3375780B2 (en) * 1995-03-29 2003-02-10 三井化学株式会社 Polyethylene resin composition for heavy packaging bags and polyethylene resin film for heavy packaging bags comprising the composition
US5811494A (en) * 1995-04-06 1998-09-22 The Dow Chemical Company Impact modified thinwall polymer compositions
JPH11503193A (en) * 1995-04-07 1999-03-23 ザ ダウ ケミカル カンパニー Blends of polycarbonate and flocculent ethylene polymer
IT1274469B (en) 1995-05-11 1997-07-17 Spherilene Spa DYNAMICALLY VULCANIZABLE POLYOLEFINIC COMPOSITIONS
MY114719A (en) 1995-06-29 2002-12-31 Mitsui Chemicals Inc Olefin thermoplastic elastomer compositions
US6011091A (en) 1996-02-01 2000-01-04 Crane Plastics Company Limited Partnership Vinyl based cellulose reinforced composite
JP3327320B2 (en) * 1996-03-28 2002-09-24 豊田合成株式会社 Wheel cover
DE69722197T2 (en) * 1996-04-10 2003-12-04 Dow Chemical Co ETHYLENE POLYMER COMPOSITION FOR ELECTRICAL CABLES
US5844037A (en) * 1996-07-24 1998-12-01 The Dow Chemical Company Thermoplastic polymer compositions with modified electrical conductivity
DE19635503A1 (en) 1996-09-02 1998-03-05 Basf Ag Low-whitening, tough modified propylene polymers
US5866264A (en) 1996-10-22 1999-02-02 Crane Plastics Company Limited Partnership Renewable surface for extruded synthetic wood material
US6117924A (en) 1996-10-22 2000-09-12 Crane Plastics Company Limited Partnership Extrusion of synthetic wood material
US5827462A (en) 1996-10-22 1998-10-27 Crane Plastics Company Limited Partnership Balanced cooling of extruded synthetic wood material
US6180257B1 (en) 1996-10-29 2001-01-30 Crane Plastics Company Limited Partnership Compression molding of synthetic wood material
US6344504B1 (en) 1996-10-31 2002-02-05 Crane Plastics Company Limited Partnership Extrusion of synthetic wood material
US5861463A (en) * 1996-10-31 1999-01-19 The Dow Chemical Company Impact-modified thermoplastic polyolefins and articles fabricated therefrom
US6610408B1 (en) 1996-11-08 2003-08-26 Solvay Engineered Polymers TPO blends containing multimodal elastomers
WO1998021275A1 (en) * 1996-11-13 1998-05-22 Exxon Chemical Patents Inc. Modification of polypropylene impact copolymers with metallocene based polyethylenes
WO1998023684A1 (en) * 1996-11-27 1998-06-04 The Dow Chemical Company Polycarbonate blend compositions
US6245856B1 (en) 1996-12-17 2001-06-12 Exxon Chemical Patents, Inc. Thermoplastic olefin compositions
US6506842B1 (en) 1997-01-29 2003-01-14 Dupont Dow Elastomers L.L.C. Rheology-modified thermoplastic elastomer compositions and articles fabricated therefrom
US20030211280A1 (en) 1997-02-28 2003-11-13 Shaw Industries, Inc. Carpet, carpet backings and methods
WO1998038375A2 (en) 1997-02-28 1998-09-03 Shaw Industries, Inc. Carpet, carpet backings and methods
US7338698B1 (en) 1997-02-28 2008-03-04 Columbia Insurance Company Homogeneously branched ethylene polymer carpet, carpet backing and method for making same
CN1248986A (en) * 1997-02-28 2000-03-29 陶氏化学公司 Filled polyethylene compositions
US5973049A (en) * 1997-06-26 1999-10-26 The Dow Chemical Company Filled polymer compositions
IT1293757B1 (en) * 1997-07-23 1999-03-10 Pirelli Cavi S P A Ora Pirelli CABLES WITH RECYCLABLE COVERING WITH HOMOGENEOUS DISTRIBUTION
US6552112B1 (en) 1997-07-23 2003-04-22 Pirelli Cavi E Sistemi S.P.A. Cable with self-extinguishing properties and flame-retardant composition
IT1293759B1 (en) * 1997-07-23 1999-03-10 Pirelli Cavi S P A Ora Pirelli CABLES WITH LOW RESIDUAL RECYCLABLE LINING
US6372344B1 (en) 1997-07-23 2002-04-16 Pirelli Cavi E Sistemi S.P.A. Cables with a halogen-free recyclable coating comprising polypropylene and an ethylene copolymer having high elastic recovery
US6410651B1 (en) 1997-07-23 2002-06-25 Pirelli Cavi E Sistemi S.P.A. Cables with a halogen-free recyclable coating comprising polypropylene and an ethylene copolymer having high structural uniformity
US6025420A (en) * 1997-07-24 2000-02-15 The Dow Chemical Company Compositions for tough and easy melt processible polycarbonate/polyolefin blend resin
US6464913B1 (en) 1997-09-05 2002-10-15 Crane Plastics Company Limited Partnership In-line compounding and extrusion system
CA2305380A1 (en) * 1997-09-29 1999-04-22 National Research Council Of Canada Trivalent thrombin inhibitor
US6136923A (en) * 1997-10-15 2000-10-24 The Dow Chemical Company Thermoplastic compositions of interpolymers of ethylene with styrene blended with poly vinyl chloride
US6344268B1 (en) 1998-04-03 2002-02-05 Certainteed Corporation Foamed polymer-fiber composite
AR018359A1 (en) * 1998-05-18 2001-11-14 Dow Global Technologies Inc HEAT RESISTANT ARTICLE, CONFIGURED, IRRADIATED AND RETICULATED, FREE FROM A SILANAN RETICULATION AGENT
EP1112323B1 (en) * 1998-08-19 2006-09-27 ExxonMobil Chemical Patents Inc. Semicrystalline polymer blends
US6977115B1 (en) 1998-12-21 2005-12-20 Magna International Of America, Inc. Low pressure compression molded parts having nano-particle reinforced protrusions and method of making the same
US6454974B1 (en) * 1998-12-21 2002-09-24 Magna International Of America, Inc. Method for vacuum pressure forming reinforced plastic articles
US6166139A (en) * 1998-12-28 2000-12-26 Visteon Global Technologies, Inc. Paintable, surface-damage resistant compounded grade thermoplastic olefin (TPO)
AU2715100A (en) 1998-12-28 2000-07-31 Crane Plastics Company Limited Partnership Cellulosic, inorganic-filled plastic composite
US6107404A (en) * 1998-12-28 2000-08-22 Ford Motor Company Paintable, surface-damage resistant reactor grade thermoplastic olefin (TPO)
US6150442A (en) * 1998-12-31 2000-11-21 Ferro Corporation Flame retardant polypropylene composition
JP2000256520A (en) 1999-03-10 2000-09-19 Idemitsu Petrochem Co Ltd Propylene-based resin composition and interior automotive trim using the same
US6339128B1 (en) * 1999-03-30 2002-01-15 Idemitsu Petrochemical Co., Ltd. Polyolefin resin modifier, polyolefin resin composition and oriented polyolefin film
BE1012775A3 (en) * 1999-07-06 2001-03-06 Solvay Flexible polymer compositions propylene.
US6397425B1 (en) * 1999-08-31 2002-06-04 Gillette Canada Company Polypropylene brush body
US6641913B1 (en) * 1999-12-03 2003-11-04 Fina Technology, Inc. Heat-sealable films
US6329454B1 (en) 1999-12-08 2001-12-11 The Dow Chemical Company Filled propylene polymer composition
US6300419B1 (en) 1999-12-08 2001-10-09 The Dow Chemical Company Propylene polymer composition
US6988305B1 (en) 1999-12-17 2006-01-24 Magna International Of America, Inc. Method and apparatus for blow molding large reinforced plastic parts
JP2001234056A (en) * 2000-02-24 2001-08-28 Asahi Kasei Corp Urethane elastomer composition
US6662515B2 (en) 2000-03-31 2003-12-16 Crane Plastics Company Llc Synthetic wood post cap
GB0008690D0 (en) 2000-04-07 2000-05-31 Borealis Polymers Oy Process
US6821915B2 (en) * 2000-05-03 2004-11-23 Kimberly-Clark Worldwide, Inc. Film having high breathability induced by low cross-directional stretch
US6372847B1 (en) 2000-05-10 2002-04-16 Exxon Mobil Chemical Patents, Inc. Polyolefin compositions having improved low temperature toughness
US7439016B1 (en) * 2000-06-15 2008-10-21 Digene Corporation Detection of nucleic acids by type-specific hybrid capture method
US7601497B2 (en) * 2000-06-15 2009-10-13 Qiagen Gaithersburg, Inc. Detection of nucleic acids by target-specific hybrid capture method
US6384123B1 (en) 2000-07-14 2002-05-07 Rjf International Corporation Thermoplastic elastomer film composition
US6399707B1 (en) 2000-09-29 2002-06-04 Exxonmobil Chemical Patents Inc. Impact copolymer and plastomer blend
US6437035B1 (en) 2000-11-02 2002-08-20 Rjf International Corporation Flame retardant thermoplastic elastomer film composition
US6578368B1 (en) 2001-01-19 2003-06-17 Crane Plastics Company Llc Cryogenic cooling of extruded and compression molded materials
US6637213B2 (en) 2001-01-19 2003-10-28 Crane Plastics Company Llc Cooling of extruded and compression molded materials
US6998084B2 (en) 2001-02-16 2006-02-14 Daimlerchrysler Corporation Co-extruded pigmented/clear coated polymeric coating for an article such as automotive exterior body panels
WO2002085954A2 (en) * 2001-04-23 2002-10-31 Exxonmobil Chemical Patents Inc. Blends of epdm and metallocene plastomers for wire and cable applications
US7169467B2 (en) * 2001-06-21 2007-01-30 Magna International Of America, Inc. Structural foam composite having nano-particle reinforcement and method of making the same
US7220801B2 (en) 2001-06-22 2007-05-22 Exxonmobil Chemical Patents Inc. Metallocene-produced very low density polyethylenes or linear low density polyethylenes as impact modifiers
KR100849606B1 (en) * 2001-07-19 2008-07-31 가부시키가이샤 구라레 Vinyl chloride polymer composition
US6706815B2 (en) * 2001-09-06 2004-03-16 Dupont Dow Elastomers L.L.C. Impact resistant rigid PVC compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers
US20050070673A1 (en) * 2001-10-01 2005-03-31 Novak Leo R. Thermoformable propylene polymer compositions
DE10148658C1 (en) * 2001-10-02 2003-02-06 Sgl Carbon Ag Production of hollow bodies made from fiber-reinforced ceramic materials used in the production of brake and clutch disks comprises forming cores, forming a green body
US6632863B2 (en) 2001-10-25 2003-10-14 Crane Plastics Company Llc Cellulose/polyolefin composite pellet
US20030144423A1 (en) * 2001-12-14 2003-07-31 Marchand Gary R. Impact resistant rigid PVC compositions using hydrocarbon rubbers and chlorinated polyethylene as impact modifiers
US6849694B2 (en) 2002-01-17 2005-02-01 Dupont Dow Elastomers, Llc Impact modifier compositions for rigid PVC compositions of hydrocarbon rubbers and chlorinated polyethylene
US6780359B1 (en) 2002-01-29 2004-08-24 Crane Plastics Company Llc Synthetic wood composite material and method for molding
US6734253B2 (en) * 2002-07-19 2004-05-11 Dow Global Technologies, Inc. Scratch and mar resistant propylene polymer composition
CA2492839C (en) 2002-08-12 2011-02-01 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
US7531594B2 (en) 2002-08-12 2009-05-12 Exxonmobil Chemical Patents Inc. Articles from plasticized polyolefin compositions
US8003725B2 (en) 2002-08-12 2011-08-23 Exxonmobil Chemical Patents Inc. Plasticized hetero-phase polyolefin blends
US7271209B2 (en) 2002-08-12 2007-09-18 Exxonmobil Chemical Patents Inc. Fibers and nonwovens from plasticized polyolefin compositions
US7998579B2 (en) 2002-08-12 2011-08-16 Exxonmobil Chemical Patents Inc. Polypropylene based fibers and nonwovens
TW200422333A (en) * 2002-09-30 2004-11-01 Sunoco Inc R&M Polyolefin compositions exhibiting enhanced stain resistance
US8389634B2 (en) 2002-10-02 2013-03-05 Dow Global Technologies Llc Polymer compositions comprising a low-viscosity, homogeneously branched ethylene α-olefin extender
KR20050055015A (en) * 2002-10-15 2005-06-10 다우 글로벌 테크놀로지스 인크. Articles comprising a fiber-reinforced thermoplastic polymer composition
AU2003302033A1 (en) 2002-10-15 2004-06-15 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
BR0314562B1 (en) * 2002-10-17 2013-11-19 Polymeric composition.
US6803421B2 (en) 2002-11-12 2004-10-12 Equister Chemicals, Lp High flow filled propylene polymer compositions having improved impact and dimensional properties
US7226880B2 (en) * 2002-12-31 2007-06-05 Kimberly-Clark Worldwide, Inc. Breathable, extensible films made with two-component single resins
US7199191B2 (en) * 2003-03-14 2007-04-03 Dow Global Technologies Inc. Impact modifier compositions with improved flowability
US7741408B2 (en) * 2003-03-28 2010-06-22 Dow Global Technologies, Inc. Low gloss thermoformable flooring structure
US6967225B2 (en) * 2003-05-05 2005-11-22 Honda Motor Co., Ltd. Scratch-resistant polypropylene composition
US7375162B2 (en) * 2003-05-29 2008-05-20 Equistar Chemicals, Lp Filled propylene polymer compositions having improved melt strength
US20040242776A1 (en) * 2003-05-29 2004-12-02 Strebel Jeffrey J. Propylene polymer compositions having improved melt strength
US7122601B2 (en) * 2003-07-28 2006-10-17 Fina Technology, Inc. Properties of polyolefin blends and their manufactured articles
US8192813B2 (en) 2003-08-12 2012-06-05 Exxonmobil Chemical Patents, Inc. Crosslinked polyethylene articles and processes to produce same
US7932196B2 (en) 2003-08-22 2011-04-26 Kimberly-Clark Worldwide, Inc. Microporous stretch thinned film/nonwoven laminates and limited use or disposable product applications
US7270723B2 (en) * 2003-11-07 2007-09-18 Kimberly-Clark Worldwide, Inc. Microporous breathable elastic film laminates, methods of making same, and limited use or disposable product applications
US20070244228A1 (en) * 2004-02-10 2007-10-18 Dow Global Technologies Inc. Electrically-Dissipative Propylene Polymer Composition
EP1727841B1 (en) 2004-03-17 2010-03-17 Dow Global Technologies Inc. Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
US7582716B2 (en) 2004-03-17 2009-09-01 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack
US7514517B2 (en) 2004-03-17 2009-04-07 Dow Global Technologies Inc. Anti-blocking compositions comprising interpolymers of ethylene/α-olefins
US7863379B2 (en) 2004-03-17 2011-01-04 Dow Global Technologies Inc. Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers
JP4879882B2 (en) 2004-03-17 2012-02-22 ダウ グローバル テクノロジーズ エルエルシー Catalyst composition comprising a shuttling agent for forming higher order olefin multi-block copolymers
AR053693A1 (en) 2004-03-17 2007-05-16 Dow Global Technologies Inc COMPOSITIONS OF ETHYLENE / ALFA-OLEFINE INTERPOLIMERO MULTIBLOCK SUITABLE FOR FILMS
US7622179B2 (en) 2004-03-17 2009-11-24 Dow Global Technologies Inc. Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof
US7671106B2 (en) 2004-03-17 2010-03-02 Dow Global Technologies Inc. Cap liners, closures and gaskets from multi-block polymers
US7741397B2 (en) 2004-03-17 2010-06-22 Dow Global Technologies, Inc. Filled polymer compositions made from interpolymers of ethylene/α-olefins and uses thereof
US7803728B2 (en) 2004-03-17 2010-09-28 Dow Global Technologies Inc. Fibers made from copolymers of ethylene/α-olefins
US7622529B2 (en) 2004-03-17 2009-11-24 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility
US7671131B2 (en) 2004-03-17 2010-03-02 Dow Global Technologies Inc. Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom
US7897689B2 (en) 2004-03-17 2011-03-01 Dow Global Technologies Inc. Functionalized ethylene/α-olefin interpolymer compositions
US8273838B2 (en) 2004-03-17 2012-09-25 Dow Global Technologies Llc Propylene/α-olefins block interpolymers
US7355089B2 (en) 2004-03-17 2008-04-08 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US7714071B2 (en) 2004-03-17 2010-05-11 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom
US7666918B2 (en) 2004-03-17 2010-02-23 Dow Global Technologies, Inc. Foams made from interpolymers of ethylene/α-olefins
US7579408B2 (en) 2004-03-17 2009-08-25 Dow Global Technologies Inc. Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins
US7662881B2 (en) 2004-03-17 2010-02-16 Dow Global Technologies Inc. Viscosity index improver for lubricant compositions
US7687442B2 (en) 2004-03-17 2010-03-30 Dow Global Technologies Inc. Low molecular weight ethylene/α-olefin interpolymer as base lubricant oils
US7795321B2 (en) 2004-03-17 2010-09-14 Dow Global Technologies Inc. Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom
ATE450570T1 (en) * 2004-05-05 2009-12-15 Dow Global Technologies Inc SCRATCH RESISTANT PROPYLENE POLYMER COMPOSITION
EP1753811A1 (en) * 2004-05-14 2007-02-21 Dow Gloval Technologies Inc. Low gloss thermoplastic polyolefin composition
JP4875613B2 (en) * 2004-05-26 2012-02-15 ダウ グローバル テクノロジーズ エルエルシー Coaxial cable with foam insulation
AU2005279786B2 (en) * 2004-08-31 2012-01-19 Dow Global Technologies Llc Composition suitable for thermoformable sheets and articles made therefrom
US8074339B1 (en) 2004-11-22 2011-12-13 The Crane Group Companies Limited Methods of manufacturing a lattice having a distressed appearance
US8389615B2 (en) 2004-12-17 2013-03-05 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin
US8084537B2 (en) 2005-03-17 2011-12-27 Dow Global Technologies Llc Polymer blends from interpolymers of ethylene/α-olefin with improved compatibility
MX2007011323A (en) 2005-03-17 2007-11-07 Dow Global Technologies Inc Fibers made from copolymers of ethylene/alpha-olefins.
BRPI0609841B1 (en) 2005-03-17 2022-09-27 Dow Global Technologies Inc COMPOSITION OF ETHYLENE/A-OLEFIN INTERPOLYMER AND ARTICLE
CA2601296A1 (en) * 2005-03-17 2006-09-28 Dow Global Technologies Inc. Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers
US7737061B2 (en) 2005-03-17 2010-06-15 Dow Global Technologies Inc. Compositions of ethylene/alpha-olefin multi-block interpolymer for elastic films and laminates
ATE555166T1 (en) 2005-07-15 2012-05-15 Exxonmobil Chem Patents Inc ELASTOMERIC COMPOSITIONS
JP2007056145A (en) * 2005-08-25 2007-03-08 Asahi Kasei Chemicals Corp Thermoplastic resin composition
TW200716700A (en) * 2005-09-12 2007-05-01 Dow Global Technologies Inc Automotive parts prepared from ethylene/ α -olefins compositions
TW200722441A (en) 2005-09-15 2007-06-16 Dow Global Technologies Inc Catalytic olefin block copolymers via polymerizable shuttling agent
CA2622599A1 (en) 2005-09-15 2007-03-29 Dow Global Technolgies Inc. Control of polymer architecture and molecular weight distribution via multi-centered shuttling agent
US8167275B1 (en) 2005-11-30 2012-05-01 The Crane Group Companies Limited Rail system and method for assembly
RU2008127854A (en) 2005-12-09 2010-01-20 Дау Глобал Текнолоджиз Инк. (Us) METHODS FOR REGULATING MOLECULAR MASS DISTRIBUTION IN ETHYLENE / ALPHA-OLEPHIN COMPOSITIONS
US8153243B2 (en) 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
US7743567B1 (en) 2006-01-20 2010-06-29 The Crane Group Companies Limited Fiberglass/cellulosic composite and method for molding
JP2007231136A (en) 2006-02-28 2007-09-13 Kyoraku Co Ltd Blow molded panel composed of propylene-based resin composition, blow molded panel composed of the composition and deck board for automobile composed of the blow molded panel
BRPI0709294A2 (en) * 2006-03-17 2011-07-05 Dow Global Technologies Inc impact resistant rigid vinyl chloride polymer composition, process for preparing an impact resistant rigid vinyl chloride polymer composition and article
KR20150052338A (en) * 2006-08-04 2015-05-13 아르끄마 프랑스 Photovoltaic modules having a polyvinylidene fluoride surface
TW200835737A (en) 2006-11-01 2008-09-01 Dow Global Technologies Inc Polyurethane compositions and articles prepared therefrom, and methods for making the same
WO2008067538A2 (en) 2006-11-30 2008-06-05 Dow Global Technologies Inc. Stretch fabrics with wrinkle resistance and garment
EP2087155B1 (en) 2006-11-30 2017-04-26 Dow Global Technologies LLC Fabric comprising elastic fibres of cross-linked ethylene polymer
EP2084313A1 (en) 2006-11-30 2009-08-05 Dow Global Technologies Inc. Olefin block compositions for heavy weight stretch fabrics
US8460797B1 (en) 2006-12-29 2013-06-11 Timbertech Limited Capped component and method for forming
EP2052857A1 (en) 2007-10-22 2009-04-29 Dow Global Technologies Inc. Multilayer films
WO2009114275A1 (en) * 2008-03-12 2009-09-17 Dow Global Technologies Inc. Clarified polypropylene and ethylene alpha olefin blend
WO2010062546A1 (en) * 2008-10-27 2010-06-03 Qiagen Gaithersburg Inc. Fast results hybrid capture assay on an automated platform
JP6108661B2 (en) * 2009-01-28 2017-04-05 キアジェン ゲイサーズバーグ インコーポレイテッド Sequence-specific mass sample preparation and assay methods
US9018310B2 (en) * 2009-04-06 2015-04-28 Polyone Designed Structures And Solutions Llc Polymer blend composition for automotive flooring applications
CN102414327B (en) * 2009-05-01 2015-04-08 奇亚根盖瑟斯堡股份有限公司 A non-target amplification method for detection of RNA splice-forms in a sample
CA2773320C (en) 2009-09-14 2018-02-20 Qiagen Gaithersburg, Inc. Compositions and methods for recovery of nucleic acids or proteins from tissue samples fixed in cytology media
US20110104342A1 (en) * 2009-11-03 2011-05-05 Kevin David Glaser Chlorine-Free Packaging Sheet with Tear-Resistance Properties
US8574694B2 (en) 2009-11-03 2013-11-05 Curwood, Inc. Packaging sheet with improved cutting properties
WO2011066194A1 (en) * 2009-11-25 2011-06-03 Dow Global Technologies Llc Molded polymeric article with low haze and high clarity
US9689047B2 (en) 2010-01-29 2017-06-27 Qiagen Gaithersburg Inc. Methods and compositions for sequence-specific purification and multiplex analysis of nucleic acids
CN102822353A (en) 2010-01-29 2012-12-12 奇亚根盖瑟斯堡股份有限公司 Method of determining and confirming the presence of an HPV in a sample
AU2011255638B2 (en) 2010-05-19 2016-08-25 Qiagen Gaithersburg, Inc. Methods and compositions for sequence-specific purification and multiplex analysis of nucleic acids
AU2011258501B2 (en) 2010-05-25 2016-07-07 Qiagen Gaithersburg, Inc. Fast results hybrid capture assay and associated strategically-truncated probes
TW201231279A (en) * 2011-01-19 2012-08-01 Ming-Yu Chen Composite composition and polymer indoor decorative material
US9885092B2 (en) 2011-02-24 2018-02-06 Qiagen Gaithersburg Inc. Materials and methods for detection of HPV nucleic acids
WO2014039490A1 (en) * 2012-09-07 2014-03-13 Dow Global Technologies Llc Injection-moldable sound-deadening filled thermoplastic polyolefin composition
EP2970646B1 (en) * 2013-03-14 2020-08-19 Braskem America, Inc. Polypropylene impact copolymers with low haze
US9475928B2 (en) 2013-06-24 2016-10-25 Dow Global Technologies Llc Reinforced polypropylene composition
SG11201510299TA (en) 2013-06-24 2016-01-28 Dow Global Technologies Llc Reinforced polypropylene composition
US20150155072A1 (en) * 2013-12-02 2015-06-04 Cerro Wire Llc Polymer formulations for use in cable jacketing and insulation
TWI490108B (en) 2013-12-20 2015-07-01 Ind Tech Res Inst Composite and method for preparing the same
CN105694432A (en) * 2016-03-19 2016-06-22 龚灿锋 Multifunctional cable for building construction
ES2899349T3 (en) 2017-09-18 2022-03-11 Dow Global Technologies Llc Compositions Containing Coated Polymeric Particles and TPO Compositions Formed Therefrom
TW202020037A (en) 2018-08-29 2020-06-01 美商陶氏全球科技有限責任公司 Silicone enhanced ethylene/alpha-olefin interpolymers for improved stiffness-toughness balance

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA684471A (en) * 1964-04-14 The Dow Chemical Company Polypropylene rubber blends
NL274843A (en) * 1961-02-17
JPS4822335B1 (en) * 1962-09-05 1973-07-05
FR1456359A (en) * 1964-12-28 1966-10-21 Dow Chemical Co Polypropylene compositions of improved impact resistance and their preparation
CA849081A (en) * 1967-03-02 1970-08-11 Du Pont Of Canada Limited PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES
JPS52109580A (en) * 1976-03-10 1977-09-13 Gunze Kk Polypropylene bi axial oriented composite films having good low temperature heat seal property
JPS5913202B2 (en) * 1978-04-26 1984-03-28 三井化学株式会社 ski shoes
AU533447B2 (en) * 1978-12-18 1983-11-24 Asahi Kasei Kogyo Kabushiki Kaisha Stretching multi layer film
US4395519A (en) * 1979-04-18 1983-07-26 Mitsui Petrochemical Industries, Ltd. Physically blended propylene polymer composition
JPS57202336A (en) * 1981-06-03 1982-12-11 Showa Denko Kk Shock absorber
US4525257A (en) * 1982-12-27 1985-06-25 Union Carbide Corporation Low level irradiated linear low density ethylene/alpha-olefin copolymers and film extruded therefrom
JPS6088016A (en) * 1983-10-21 1985-05-17 Mitsui Petrochem Ind Ltd Ethylene copolymer
JPS60212443A (en) * 1984-04-09 1985-10-24 Toa Nenryo Kogyo Kk Polypropylene composition
JPS6198756A (en) * 1984-10-20 1986-05-17 Mitsui Petrochem Ind Ltd Polypropylene composition having improved low-temperature impact resistance
FI86878C (en) * 1984-11-02 1992-10-26 Mitsui Petrochemical Ind Crystalline random propylene copolymer blend and composite laminate containing the blend
JPS62112644A (en) * 1985-11-11 1987-05-23 Nippon Petrochem Co Ltd Non-rigid polyolefin composition
JPH06820B2 (en) * 1985-11-21 1994-01-05 三井石油化学工業株式会社 Low crystalline ethylene random copolymer and its use
US4764404A (en) * 1985-11-29 1988-08-16 American National Can Company Films having a polypropylene blend layer
US5071686A (en) * 1985-11-29 1991-12-10 Genske Roger P Films of polypropylene blends and polyethylene blends and articles made therewith
US5011719A (en) * 1985-11-29 1991-04-30 American National Can Company Polymeric compositions and films
AU601381B2 (en) * 1985-11-29 1990-09-13 American National Can Company Blends of polypropylene and sheet structures made from the blends
US4843129A (en) * 1985-12-27 1989-06-27 Exxon Research & Engineering Company Elastomer-plastic blends
US5011891A (en) * 1985-12-27 1991-04-30 Exxon Research & Engineering Company Elastomer polymer blends
KR900004932B1 (en) * 1987-05-26 1990-07-12 주식회사 럭키 Prepration of olefinic thermoplastic resin composition
US4812526A (en) * 1987-06-08 1989-03-14 Union Carbide Corporation Impact polypropylene
CA1333308C (en) * 1987-07-08 1994-11-29 Tadashi Hikasa Olefinic thermoplastic elastomer composition
JPH07103280B2 (en) * 1987-07-10 1995-11-08 日本合成ゴム株式会社 Polypropylene resin composition for automobile interior and exterior parts
JPH01166954A (en) * 1987-12-23 1989-06-30 Idemitsu Petrochem Co Ltd Polyolefin group resin laminate
JP2600829B2 (en) * 1988-08-04 1997-04-16 三井石油化学工業株式会社 Polypropylene resin composition
FR2645541B1 (en) * 1989-04-06 1993-07-30 Norsolor Sa COMPOSITION AND METHOD FOR REDUCING THE STOCKING CHARACTER OF ETHYLENE / ALPHA-OLEFIN COPOLYMERS
JP2571964B2 (en) * 1989-04-19 1997-01-16 豊田合成株式会社 Reinforced polypropylene resin composition
US5268220A (en) * 1989-05-11 1993-12-07 Nippon Petrochemicals Company, Limited Polypropylene film
US5272236A (en) * 1991-10-15 1993-12-21 The Dow Chemical Company Elastic substantially linear olefin polymers
CA2048296C (en) * 1990-08-13 2002-09-24 Henry G. Schirmer Blends of polypropylene and ethylene copolymer and films made from the blend
MX9200724A (en) * 1991-02-22 1993-05-01 Exxon Chemical Patents Inc HEAT SEALABLE MIX OF POLYETHYLENE OR PLASTOMER OF VERY LOW DENSITY WITH POLYMERS BASED ON POLYPROPYLENE AND THERMAL SEALABLE FILM AS WELL AS ARTICLES MADE WITH THOSE.
AU658608B2 (en) * 1991-03-25 1995-04-27 Astellas Pharma Europe B.V. Topical preparation containing a suspension of solid lipid particles
US5266392A (en) * 1991-09-16 1993-11-30 Exxon Chemical Patents Inc. Plastomer compatibilized polyethylene/polypropylene blends
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5206075A (en) * 1991-12-19 1993-04-27 Exxon Chemical Patents Inc. Sealable polyolefin films containing very low density ethylene copolymers
US5414040A (en) * 1992-09-15 1995-05-09 The Dow Chemical Company Formulated ethylene/α-olefin elastomeric compounds
EP0593221B1 (en) * 1992-10-15 1998-08-05 Mitsubishi Chemical Corporation Propylene resin compositions
JP2618169B2 (en) * 1992-12-22 1997-06-11 三井石油化学工業株式会社 Polypropylene composition
US5571864A (en) * 1993-03-23 1996-11-05 Regents Of The University Of Minnesota Miscible polyolefin blends with modifying polyolefin having matching segment lengths
US5654364A (en) * 1993-03-23 1997-08-05 Regents Of The University Of Minnesota Miscible blend of polyolefin and polyolefin block copolymer
US5763534A (en) * 1994-08-25 1998-06-09 Solvay Engineered Polymers Thermoplastic polypropylene blends with mixtures of ethylene/butene and ethylene/octene copolymer elastomers
US5416148B1 (en) * 1994-09-09 1999-03-02 Dow Chemical Co Blends of polycarbonate and ethylene polymers
US5468808A (en) * 1994-09-12 1995-11-21 Exxon Chemical Patents Inc. Reduction of flow marks in rubber modified polypropylene
US5484838A (en) * 1994-12-22 1996-01-16 Ford Motor Company Thermoplastic compositions with modified electrical conductivity

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US5688866A (en) 1997-11-18
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US5681897A (en) 1997-10-28
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