CA2136627A1 - Use of Zeolites in the Conversion of Oxygenates in Hydrocarbons - Google Patents

Use of Zeolites in the Conversion of Oxygenates in Hydrocarbons

Info

Publication number
CA2136627A1
CA2136627A1 CA 2136627 CA2136627A CA2136627A1 CA 2136627 A1 CA2136627 A1 CA 2136627A1 CA 2136627 CA2136627 CA 2136627 CA 2136627 A CA2136627 A CA 2136627A CA 2136627 A1 CA2136627 A1 CA 2136627A1
Authority
CA
Canada
Prior art keywords
oxygenates
zeolites
hydrocarbons
conversion
ecr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA 2136627
Other languages
French (fr)
Other versions
CA2136627C (en
Inventor
Marcel J. G. Janssen
David E. W. Vaughan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Marcel J. G. Janssen
David E. W. Vaughan
Exxon Chemical Patents Inc.
Exxon Chemical Patents, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Marcel J. G. Janssen, David E. W. Vaughan, Exxon Chemical Patents Inc., Exxon Chemical Patents, Inc. filed Critical Marcel J. G. Janssen
Publication of CA2136627A1 publication Critical patent/CA2136627A1/en
Application granted granted Critical
Publication of CA2136627C publication Critical patent/CA2136627C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Abstract

A process for converting an oxygenate feed to light olefins using a microporous zeolite catalyst such as ECR-1, mazmorites, and/or ECR-18 is provided. In a preferred embodiment, the process is conducted at 440 ° C to 460 ° C using a methanol:
water (approximately 1:4 molar ratio) feed.
CA002136627A 1992-05-27 1993-05-27 Use of zeolites in the conversion of oxygenates in hydrocarbons Expired - Fee Related CA2136627C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US888,668 1986-07-23
US07/888,668 US5278345A (en) 1992-05-27 1992-05-27 Use of ECR-1, mazmorite and ECR-18 in the conversion of oxygenates to hydrocarbons
PCT/US1993/005053 WO1993024429A1 (en) 1992-05-27 1993-05-27 Use of zeolites in the conversion of oxygenates to hydrocarbons

Publications (2)

Publication Number Publication Date
CA2136627A1 true CA2136627A1 (en) 1993-12-09
CA2136627C CA2136627C (en) 1999-11-02

Family

ID=25393626

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002136627A Expired - Fee Related CA2136627C (en) 1992-05-27 1993-05-27 Use of zeolites in the conversion of oxygenates in hydrocarbons

Country Status (9)

Country Link
US (1) US5278345A (en)
EP (1) EP0649394B1 (en)
JP (1) JP2628108B2 (en)
AU (1) AU678361B2 (en)
CA (1) CA2136627C (en)
DE (1) DE69308305T2 (en)
ES (1) ES2099956T3 (en)
SG (1) SG52772A1 (en)
WO (1) WO1993024429A1 (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6436869B1 (en) 1996-05-29 2002-08-20 Exxonmobil Chemical Patents Inc. Iron, cobalt and/or nickel containing ALPO bound SAPO molecular sieve catalyst for producing olefins
US6046372A (en) * 1996-10-02 2000-04-04 Mobil Oil Corporation Process for producing light olefins
US6444868B1 (en) 1999-02-17 2002-09-03 Exxon Mobil Chemical Patents Inc. Process to control conversion of C4+ and heavier stream to lighter products in oxygenate conversion reactions
US6613951B1 (en) 1999-09-23 2003-09-02 Mobil Oil Corporation Process for converting methanol to olefins
WO2001025150A1 (en) 1999-10-01 2001-04-12 Pop, Grigore Process for the synthesis of silicoaluminophosphate molecular sieves
AU2001236985A1 (en) 2000-02-16 2001-08-27 Exxonmobil Chemical Patents Inc Treatment of molecular sieves with silicon containing compounds
US6531639B1 (en) 2000-02-18 2003-03-11 Exxonmobil Chemical Patents, Inc. Catalytic production of olefins at high methanol partial pressures
US6743747B1 (en) 2000-02-24 2004-06-01 Exxonmobil Chemical Patents Inc. Catalyst pretreatment in an oxgenate to olefins reaction system
US6506954B1 (en) 2000-04-11 2003-01-14 Exxon Mobil Chemical Patents, Inc. Process for producing chemicals from oxygenate
US7102050B1 (en) 2000-05-04 2006-09-05 Exxonmobil Chemical Patents Inc. Multiple riser reactor
US6613950B1 (en) * 2000-06-06 2003-09-02 Exxonmobil Chemical Patents Inc. Stripping hydrocarbon in an oxygenate conversion process
US6441261B1 (en) 2000-07-28 2002-08-27 Exxonmobil Chemical Patents Inc. High pressure oxygenate conversion process via diluent co-feed
US6486219B1 (en) 2000-09-27 2002-11-26 Exxonmobil Chemical Patents, Inc. Methanol, olefin, and hydrocarbon synthesis process
US7122160B2 (en) * 2002-09-24 2006-10-17 Exxonmobil Chemical Patents Inc. Reactor with multiple risers and consolidated transport
US20040064007A1 (en) * 2002-09-30 2004-04-01 Beech James H. Method and system for regenerating catalyst from a plurality of hydrocarbon conversion apparatuses
US7083762B2 (en) * 2002-10-18 2006-08-01 Exxonmobil Chemical Patents Inc. Multiple riser reactor with centralized catalyst return
US7241716B2 (en) 2003-11-10 2007-07-10 Exxonmobil Chemical Patents Inc. Protecting catalytic sites of metalloaluminophosphate molecular sieves
US7199277B2 (en) * 2004-07-01 2007-04-03 Exxonmobil Chemical Patents Inc. Pretreating a catalyst containing molecular sieve and active metal oxide
KR101395454B1 (en) * 2007-09-20 2014-05-15 삼성전자주식회사 Optical film having a graded index of refraction and fabricating method thereof
EP2123736A1 (en) 2008-05-19 2009-11-25 C.E.-Technology Limited Method for producing diesel fuels and aviation fuels from C1-C5 alcohols
WO2013127006A1 (en) * 2012-02-29 2013-09-06 Raymond Le Van Mao Catalytic conversion of ligno-cellulosic biomass into fuels and chemicals
KR102262349B1 (en) 2013-07-04 2021-06-08 토탈 리서치 앤드 테크놀로지 펠루이 Catalyst compositions comprising small size molecular sieves crystals deposited on a porous material
CN113574038A (en) 2019-03-28 2021-10-29 埃克森美孚化学专利公司 Method for converting benzene and/or toluene via methylation
US11691933B2 (en) 2019-03-28 2023-07-04 Exxonmobil Chemical Patents Inc. Processes and systems for converting benzene and/or toluene via methylation
CN113574036A (en) 2019-03-28 2021-10-29 埃克森美孚化学专利公司 Method for converting benzene and/or toluene via methylation
WO2023044278A1 (en) 2021-09-16 2023-03-23 Exxonmobil Chemical Patents Inc. Xylene isomer separation processes
WO2023064684A1 (en) 2021-10-12 2023-04-20 Exxonmobil Chemical Patents Inc. Staged alkylation for producing xylene products
WO2023204947A1 (en) 2022-04-19 2023-10-26 Exxonmobil Chemical Patents Inc. Processes for oxidizing p-xylene or p-xylene-containing mixtures

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928483A (en) * 1974-09-23 1975-12-23 Mobil Oil Corp Production of gasoline hydrocarbons
US4025575A (en) * 1975-04-08 1977-05-24 Mobil Oil Corporation Process for manufacturing olefins
DE3006471A1 (en) * 1980-02-21 1981-08-27 Basf Ag, 6700 Ludwigshafen CRYSTALLINE ISOTACTIC ZEOLITES, METHOD FOR PRODUCING THE SAME AND THEIR USE AS CATALYSTS
DE3132024C2 (en) * 1981-08-13 1983-12-08 Basf Ag, 6700 Ludwigshafen Process for the production of olefins from methanol and / or dimethyl ether
FR2519335B1 (en) * 1982-01-04 1986-05-02 Azote & Prod Chim PRODUCTION OF HYDROCARBONS FROM METHANOL IN THE PRESENCE OF ZEOLITE TYPE CATALYSTS
US4499314A (en) * 1982-03-31 1985-02-12 Imperial Chemical Industries Plc Methanol conversion to hydrocarbons with zeolites and cocatalysts
AU562665B2 (en) * 1982-05-04 1987-06-18 Cosmo Oil Company Ltd Crystalline metal silicates
US4467133A (en) * 1982-06-21 1984-08-21 Mobil Oil Corporation Conversion of alcohols and ethers to distillate range hydrocarbons
US4677243A (en) * 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
JPS5997523A (en) * 1982-11-24 1984-06-05 Agency Of Ind Science & Technol Zeolite containing alkaline earth metal, its manufacture and manufacture of olefin
US4496786A (en) * 1983-09-30 1985-01-29 Chevron Research Company Selective conversion of methanol to low molecular weight olefins over high silica SSZ-13 zeolite
JPS6115848A (en) * 1984-06-30 1986-01-23 Agency Of Ind Science & Technol Production of lower olefin using zeolite catalyst modified with calcium phosphate
JPS6147421A (en) * 1984-08-15 1986-03-07 Satoyuki Inui Production of olefinic hydrocarbon from methanol
US4547616A (en) * 1984-12-28 1985-10-15 Mobil Oil Corporation Conversion of oxygenates to lower olefins in a turbulent fluidized catalyst bed
US4657748A (en) * 1985-03-18 1987-04-14 Exxon Research And Engineering Company Crystalline zeolite (ECR-1) and process for preparing it
US4661332A (en) * 1985-07-29 1987-04-28 Exxon Research And Engineering Company Zeolite (ECR-18) isostructural with paulingite and a method for its preparation
US5013536A (en) * 1988-08-22 1991-05-07 Exxon Research And Engineering Company ECR-18, method of its preparation, and uses for sorption and separation

Also Published As

Publication number Publication date
JP2628108B2 (en) 1997-07-09
US5278345A (en) 1994-01-11
CA2136627C (en) 1999-11-02
EP0649394B1 (en) 1997-02-26
ES2099956T3 (en) 1997-06-01
JPH08502025A (en) 1996-03-05
SG52772A1 (en) 1998-09-28
DE69308305T2 (en) 1997-08-28
EP0649394A1 (en) 1995-04-26
AU4394893A (en) 1993-12-30
AU678361B2 (en) 1997-05-29
DE69308305D1 (en) 1997-04-03
WO1993024429A1 (en) 1993-12-09

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