CA2129420A1 - Process for the production of molded products using internal mold release agents - Google Patents
Process for the production of molded products using internal mold release agentsInfo
- Publication number
- CA2129420A1 CA2129420A1 CA002129420A CA2129420A CA2129420A1 CA 2129420 A1 CA2129420 A1 CA 2129420A1 CA 002129420 A CA002129420 A CA 002129420A CA 2129420 A CA2129420 A CA 2129420A CA 2129420 A1 CA2129420 A1 CA 2129420A1
- Authority
- CA
- Canada
- Prior art keywords
- reaction product
- imr
- compound
- production
- mold release
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3253—Polyamines being in latent form
- C08G18/3259—Reaction products of polyamines with inorganic or organic acids or derivatives thereof other than metallic salts
- C08G18/3262—Reaction products of polyamines with inorganic or organic acids or derivatives thereof other than metallic salts with carboxylic acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2125/00—Compositions for processes using internal mould release agents
Abstract
The present invention is directed to an improved internal mold release system for the production of low density molded foam parts.
The process comprises reacting a reaction mixture of an isocyanate and at least one organic compound containing isocyanate-reactive hydrogens in the presence of a blowing agent, a catalyst, a surfactant, an IMR, and, optionally, a reinforcing agent, in a closed mold. The IMR comprises:
a) mixed esters comprising the reaction product of i) aliphatic dicarboxylic acids, ii) aliphatic polyols, and iii) monocarboxylic acids with 12 to 30 carbon atoms in the molecule.
The IMR may additionally comprise b) and/or c) wherein:
b) represents a compound comprising the reaction product of i) N,N-dimethylpropylene diamine with ii) a compound selected from the group consisting of tall oil, C8-20 monofunctional carboxylic acids, and mixtures of C8-20 monofunctional carboxylic acids; and c) represents a compound comprising the reaction product of oleic acid, adipic acid, and pentaerythritol; with the proviso that the reaction product of a) is different than the reaction product of c).
The process comprises reacting a reaction mixture of an isocyanate and at least one organic compound containing isocyanate-reactive hydrogens in the presence of a blowing agent, a catalyst, a surfactant, an IMR, and, optionally, a reinforcing agent, in a closed mold. The IMR comprises:
a) mixed esters comprising the reaction product of i) aliphatic dicarboxylic acids, ii) aliphatic polyols, and iii) monocarboxylic acids with 12 to 30 carbon atoms in the molecule.
The IMR may additionally comprise b) and/or c) wherein:
b) represents a compound comprising the reaction product of i) N,N-dimethylpropylene diamine with ii) a compound selected from the group consisting of tall oil, C8-20 monofunctional carboxylic acids, and mixtures of C8-20 monofunctional carboxylic acids; and c) represents a compound comprising the reaction product of oleic acid, adipic acid, and pentaerythritol; with the proviso that the reaction product of a) is different than the reaction product of c).
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12349193A | 1993-09-17 | 1993-09-17 | |
US08/123,491 | 1993-09-17 | ||
US08/275,468 US5389696A (en) | 1993-09-17 | 1994-07-14 | Process for the production of molded products using internal mold release agents |
US08/275,468 | 1994-07-14 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2129420A1 true CA2129420A1 (en) | 1995-03-18 |
CA2129420C CA2129420C (en) | 2004-06-22 |
Family
ID=26821611
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002129420A Expired - Lifetime CA2129420C (en) | 1993-09-17 | 1994-08-03 | Process for the production of molded products using internal mold release agents |
Country Status (2)
Country | Link |
---|---|
US (1) | US5389696A (en) |
CA (1) | CA2129420C (en) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5500176A (en) * | 1993-09-17 | 1996-03-19 | Bayer Corporation | Process for the production of molded products using internal mold release agents |
US5529739A (en) * | 1994-11-15 | 1996-06-25 | Bayer Corporation | Process for the production of molded products using internal mold release agents |
US5622777A (en) * | 1995-05-17 | 1997-04-22 | Bayer Corporation | Heat-resistant reinforced foam |
US5576409B1 (en) * | 1995-08-25 | 1998-09-22 | Ici Plc | Internal mold release compositions |
IT1280096B1 (en) * | 1995-10-06 | 1997-12-29 | Ediltec S R L | POLYURETHANE FOAM |
US5686526A (en) * | 1995-12-14 | 1997-11-11 | Basf Corporation | Process of making molded polyurethane articles |
US5700390A (en) * | 1995-12-14 | 1997-12-23 | Basf Corporation | Polyol compositions having internal mold release properties |
US5686187A (en) * | 1995-12-14 | 1997-11-11 | Basf Corporation | Molded polyurethane SRIM articles |
US5700869A (en) * | 1995-12-14 | 1997-12-23 | Basf Corporation | Polyurethane compositions having internal mold release properties |
US5716439A (en) * | 1995-12-14 | 1998-02-10 | Basf Corporation | Internal mold release compositions |
US5910515A (en) * | 1997-03-24 | 1999-06-08 | Ediltec S.R.L. | Polyurethane foam |
US7195726B1 (en) | 1998-08-26 | 2007-03-27 | Dow Global Technologies Inc. | Internal mold release for low density reaction injection molded polyurethane foam |
KR20010113747A (en) * | 1999-03-15 | 2001-12-28 | 추후제출 | Internal Mold Release Compositions |
US20040171784A1 (en) * | 1999-03-15 | 2004-09-02 | Shidaker Trent A. | Internal mold release compositions |
MXPA03006220A (en) * | 2001-01-24 | 2003-09-22 | Huntsman Int Llc | Molded foam articles prepared with reduced mold residence time and improved quality. |
US6448364B1 (en) | 2001-03-16 | 2002-09-10 | Bayer Corporation | IMR having synergistic effect with stabilizing system additives and catalyst package |
US20040112862A1 (en) * | 2002-12-12 | 2004-06-17 | Molecular Imprints, Inc. | Planarization composition and method of patterning a substrate using the same |
US7365103B2 (en) * | 2002-12-12 | 2008-04-29 | Board Of Regents, The University Of Texas System | Compositions for dark-field polymerization and method of using the same for imprint lithography processes |
US20040168613A1 (en) * | 2003-02-27 | 2004-09-02 | Molecular Imprints, Inc. | Composition and method to form a release layer |
US7396475B2 (en) | 2003-04-25 | 2008-07-08 | Molecular Imprints, Inc. | Method of forming stepped structures employing imprint lithography |
US7307118B2 (en) * | 2004-11-24 | 2007-12-11 | Molecular Imprints, Inc. | Composition to reduce adhesion between a conformable region and a mold |
US20050160934A1 (en) | 2004-01-23 | 2005-07-28 | Molecular Imprints, Inc. | Materials and methods for imprint lithography |
US20060108710A1 (en) * | 2004-11-24 | 2006-05-25 | Molecular Imprints, Inc. | Method to reduce adhesion between a conformable region and a mold |
US20050084804A1 (en) * | 2003-10-16 | 2005-04-21 | Molecular Imprints, Inc. | Low surface energy templates |
US7122482B2 (en) * | 2003-10-27 | 2006-10-17 | Molecular Imprints, Inc. | Methods for fabricating patterned features utilizing imprint lithography |
US8076386B2 (en) | 2004-02-23 | 2011-12-13 | Molecular Imprints, Inc. | Materials for imprint lithography |
US7906180B2 (en) | 2004-02-27 | 2011-03-15 | Molecular Imprints, Inc. | Composition for an etching mask comprising a silicon-containing material |
US7282550B2 (en) * | 2004-08-16 | 2007-10-16 | Molecular Imprints, Inc. | Composition to provide a layer with uniform etch characteristics |
US7939131B2 (en) | 2004-08-16 | 2011-05-10 | Molecular Imprints, Inc. | Method to provide a layer with uniform etch characteristics |
US20060062922A1 (en) | 2004-09-23 | 2006-03-23 | Molecular Imprints, Inc. | Polymerization technique to attenuate oxygen inhibition of solidification of liquids and composition therefor |
US7292326B2 (en) | 2004-11-30 | 2007-11-06 | Molecular Imprints, Inc. | Interferometric analysis for the manufacture of nano-scale devices |
US8808808B2 (en) | 2005-07-22 | 2014-08-19 | Molecular Imprints, Inc. | Method for imprint lithography utilizing an adhesion primer layer |
US7759407B2 (en) * | 2005-07-22 | 2010-07-20 | Molecular Imprints, Inc. | Composition for adhering materials together |
US8557351B2 (en) | 2005-07-22 | 2013-10-15 | Molecular Imprints, Inc. | Method for adhering materials together |
US8142703B2 (en) * | 2005-10-05 | 2012-03-27 | Molecular Imprints, Inc. | Imprint lithography method |
US20080110557A1 (en) * | 2006-11-15 | 2008-05-15 | Molecular Imprints, Inc. | Methods and Compositions for Providing Preferential Adhesion and Release of Adjacent Surfaces |
US20100109195A1 (en) | 2008-11-05 | 2010-05-06 | Molecular Imprints, Inc. | Release agent partition control in imprint lithography |
DE102014208353A1 (en) * | 2014-05-05 | 2015-11-05 | Henkel Ag & Co. Kgaa | Polyphase polyurethane composition with reduced foaming |
US10519273B2 (en) | 2017-12-07 | 2019-12-31 | Covestro Llc | Processes for producing filter cartridge assemblies and molded polyurethane elastomers |
EP4177287A1 (en) * | 2021-11-03 | 2023-05-10 | Covestro Deutschland AG | Method for the production of a polyurethane sandwich element |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE757939A (en) * | 1969-10-24 | 1971-04-01 | Bayer Ag | PROCESS FOR THE PREPARATION OF FOAM MATERIALS |
DE2121670C3 (en) * | 1971-05-03 | 1979-11-15 | Bayer Ag, 5090 Leverkusen | Process for the production of foams |
DE2262266C2 (en) * | 1972-12-20 | 1982-04-01 | Neynaber Chemie Gmbh, 2854 Loxstedt | Use of an ester mixture as a lubricant for the shaping processing of thermoplastic materials |
DE2307589C3 (en) * | 1973-02-16 | 1984-11-15 | Bayer Ag, 5090 Leverkusen | Process for the production of foams with excellent release properties |
US4201847A (en) * | 1973-02-16 | 1980-05-06 | Bayer Aktiengesellschaft | Process of preparing foams with internal mold-release agents |
US4058492A (en) * | 1974-01-10 | 1977-11-15 | Bayer Aktiengesellschaft | Process for molding polyurethane foams |
US4098731A (en) * | 1974-07-03 | 1978-07-04 | Bayer Aktiengesellschaft | Process for the production of foams |
GB1575205A (en) * | 1976-03-29 | 1980-09-17 | Ici Ltd | Process for the production of polyurethane foam mouldings |
US4111861A (en) * | 1976-09-24 | 1978-09-05 | Union Carbide Corporation | Method of molding polyurethanes having mold release properties |
BE893509A (en) * | 1981-07-06 | 1982-10-01 | Dart Ind Inc | INTERNAL RELEASE AGENTS AND THEIR USE |
US5182034A (en) * | 1983-02-16 | 1993-01-26 | The Dow Chemical Company | Internal mold release compositions |
US4499254A (en) * | 1984-02-13 | 1985-02-12 | Texaco Inc. | Reaction injection molded elastomers containing high molecular weight organic acids |
US4585803A (en) * | 1984-08-17 | 1986-04-29 | The Dow Chemical Company | Internal mold release compositions |
US4519965A (en) * | 1984-08-23 | 1985-05-28 | Mobay Chemical Corporation | Internal mold release agent for use in reaction injection molding |
US4581386A (en) * | 1985-05-23 | 1986-04-08 | Mobay Chemical Corporation | Internal mold release agent for use in reaction injection molding |
DE3631842A1 (en) * | 1986-09-19 | 1988-03-24 | Basf Ag | INNER MOLD RELEASE AGENTS, THE USE THEREOF FOR THE PRODUCTION OF MOLDED BODIES BY THE POLYISOCYANATE POLYADDITIONAL PROCESS AND METHOD FOR THE PRODUCTION OF THE MOLDED BODIES |
US4868224A (en) * | 1988-10-21 | 1989-09-19 | Mobay Corporation | Process for the production of molded products using internal mold release agents |
US5019317A (en) * | 1989-05-24 | 1991-05-28 | Mobay Corporation | Process for the production of molded products using internal mold release agents |
-
1994
- 1994-07-14 US US08/275,468 patent/US5389696A/en not_active Expired - Lifetime
- 1994-08-03 CA CA002129420A patent/CA2129420C/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US5389696A (en) | 1995-02-14 |
CA2129420C (en) | 2004-06-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKEX | Expiry |
Effective date: 20140804 |