CA2124633A1 - Starch-based food enhancement - Google Patents

Starch-based food enhancement

Info

Publication number
CA2124633A1
CA2124633A1 CA002124633A CA2124633A CA2124633A1 CA 2124633 A1 CA2124633 A1 CA 2124633A1 CA 002124633 A CA002124633 A CA 002124633A CA 2124633 A CA2124633 A CA 2124633A CA 2124633 A1 CA2124633 A1 CA 2124633A1
Authority
CA
Canada
Prior art keywords
matrix
starch
food product
protein based
flash
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002124633A
Other languages
French (fr)
Inventor
Richard C. Fuisz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Biovail International Ltd USA
Original Assignee
Fuisz Technologies Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuisz Technologies Ltd filed Critical Fuisz Technologies Ltd
Publication of CA2124633A1 publication Critical patent/CA2124633A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/14Organic oxygen compounds
    • A21D2/18Carbohydrates
    • A21D2/186Starches; Derivatives thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G3/00Sweetmeats; Confectionery; Marzipan; Coated or filled products
    • A23G3/02Apparatus specially adapted for manufacture or treatment of sweetmeats or confectionery; Accessories therefor
    • A23G3/10Candy-pulling machines ; Processes or apparatus for making cotton candy or candy floss
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23JPROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
    • A23J3/00Working-up of proteins for foodstuffs
    • A23J3/22Working-up of proteins for foodstuffs by texturising
    • A23J3/225Texturised simulated foods with high protein content
    • A23J3/227Meat-like textured foods
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/40Meat products; Meat meal; Preparation or treatment thereof containing additives
    • A23L13/42Additives other than enzymes or microorganisms in meat products or meat meals
    • A23L13/426Addition of proteins, carbohydrates or fibrous material from vegetable origin other than sugars or sugar alcohols
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/40Meat products; Meat meal; Preparation or treatment thereof containing additives
    • A23L13/42Additives other than enzymes or microorganisms in meat products or meat meals
    • A23L13/428Addition of flavours, spices, colours, amino acids or their salts, peptides, vitamins, yeast extract or autolysate, nucleic acid or derivatives, organic acidifying agents or their salts or acidogens, sweeteners, e.g. sugars or sugar alcohols; Addition of alcohol-containing products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/40Meat products; Meat meal; Preparation or treatment thereof containing additives
    • A23L13/42Additives other than enzymes or microorganisms in meat products or meat meals
    • A23L13/43Addition of vegetable fats or oils; Addition of non-meat animal fats or oils; Addition of fatty acids
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/50Poultry products, e.g. poultry sausages
    • A23L13/52Comminuted, emulsified or processed products; Pastes; Reformed or compressed products from poultry meat
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/60Comminuted or emulsified meat products, e.g. sausages; Reformed meat from comminuted meat product
    • A23L13/67Reformed meat products other than sausages
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L17/00Food-from-the-sea products; Fish products; Fish meal; Fish-egg substitutes; Preparation or treatment thereof
    • A23L17/70Comminuted, e.g. emulsified, fish products; Processed products therefrom such as pastes, reformed or compressed products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L25/00Food consisting mainly of nutmeat or seeds; Preparation or treatment thereof
    • A23L25/10Peanut butter
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/70Fixation, conservation, or encapsulation of flavouring agents
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/212Starch; Modified starch; Starch derivatives, e.g. esters or ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/262Cellulose; Derivatives thereof, e.g. ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/30Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/30Foods or foodstuffs containing additives; Preparation or treatment thereof containing carbohydrate syrups; containing sugars; containing sugar alcohols, e.g. xylitol; containing starch hydrolysates, e.g. dextrin
    • A23L29/35Degradation products of starch, e.g. hydrolysates, dextrins; Enzymatically modified starches
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/125Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives containing carbohydrate syrups; containing sugars; containing sugar alcohols; containing starch hydrolysates
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/17Amino acids, peptides or proteins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/20Reducing nutritive value; Dietetic products with reduced nutritive value
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P10/00Shaping or working of foodstuffs characterised by the products
    • A23P10/20Agglomerating; Granulating; Tabletting
    • A23P10/25Agglomeration or granulation by extrusion or by pressing, e.g. through small holes, through sieves or between surfaces
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P10/00Shaping or working of foodstuffs characterised by the products
    • A23P10/20Agglomerating; Granulating; Tabletting
    • A23P10/28Tabletting; Making food bars by compression of a dry powdered mixture
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23PSHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P10/00Shaping or working of foodstuffs characterised by the products
    • A23P10/30Encapsulation of particles, e.g. foodstuff additives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00Medicinal preparations characterised by special physical form
    • A61K9/14Particulate form, e.g. powders, Processes for size reducing of pure drugs or the resulting products, Pure drug nanoparticles
    • A61K9/16Agglomerates; Granulates; Microbeadlets ; Microspheres; Pellets; Solid products obtained by spray drying, spray freeze drying, spray congealing,(multiple) emulsion solvent evaporation or extraction
    • A61K9/1605Excipients; Inactive ingredients
    • A61K9/1629Organic macromolecular compounds
    • A61K9/1652Polysaccharides, e.g. alginate, cellulose derivatives; Cyclodextrin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K9/00Medicinal preparations characterised by special physical form
    • A61K9/70Web, sheet or filament bases ; Films; Fibres of the matrix type containing drug

Abstract

ABSTRACT OF THE INVENTION

The present invention includes food products and a food ingredient. Both starch and a matrix prepared by flash-flow processing are part of the present invention.
They can be included in food products as separate ingredients or the starch can be a part of the matrix which is prepared by subjecting a carrier to flash-flow processing. Alternatively, starch can be added both as a part of the matrix and as a separate ingredient in the overall composition. Preferably the food product is protein based.

Description

-2- 21~63~
447~81 (F-124) 8TARC~-BA~BD FOOD ENaANCBMBNT

BACR~RO D OF TH~ INVENTION

This application is a continuation-part of U.S.
Application Serial No. 851,650 filed March 16, 1992, which is a continuation-in-part of U.S. Patent No. 5,096,492, which, in turn, is a continuation-in-part of U.S. Patent No. 4,855,326 which, in turn, is a continuation-in-part of U.S. Patent Application Serial No. 040,371, now abandoned. It is also a continuation-in-part application of U.S. Application Serial No. 847,595 filed March 5, 1992, which is a continuation~
in-part application of U.S. Application Serial No. 782,430 filed October 25, 1991. The disclosures of the '326 and '492 patents are incorporated herein by reference.

The present invention relates to new method and product for enhancing food products, and, in particular, to the use of starch and starch-based ingredients.

Food technology in recent years has focused on providing high quality food products which are low in calorie content and low in cost. To this end, ingredients are constantly being sought for their .. ___ __ _ _._ _ , _ . . . _ .. _ .. .... _ .. _... _ _ ~, . __ . .. _ _ . .. _ .. . . .. . .. _ __. __ _ ... . .
versatility and compatibility with major food products.

Carbohydrates have always been a major component of the human diet. Sugars, for example, have been used extensively as a food ingredient. Materials containing both simple sugars and polymers of saccharides have also ~
been used as ingredients in food products. ~ -Starch is a carbohydrate which is a homopolymer of .. , ,~.. . . . ~. .. , , : , ;, ~1 2li ~3 3 glucopyranoside. It is a polysaccharide found in many plant cells, and it consists of two (2) fractions:
amylose or ~-amylose, a straight chain of 1, 4, ~-glucopyranose units, and amylopectin or ~-amylose, a 1, 6, ~-branched form. The length of amylose chains averages between 500 and 2,000 glucose units, and is found in amounts of up to about 32% in grains and potatoes.

The present inventor, Dr. Fuisz, has discovered that processing sugars under flash-flow conditions alters the structure and behavior of the products during use. The processed sugars can be used for various puxposes.

In United States Patent No. 5,011,532, oleaginous substances, such as vegetable oil, mineral oil, baby oil, margarine, lanolin, cocoa butter and the like are disclosed as characteristically lacking affinity for water. The '532 patent explains how this characteristic is altered by mixing the oleaginous s~bstance with sugar and subjecting the mixture to a type of flash-flow processing in a cotton candy spinning machine or the equivalent. As so modified, the products disperse in water forming a colloidal or pseudo-colloidal dispersion.
Such modification enabled such widely disparate procedures as: (a) incorporating shortening oil in a cake mix containing flour but no egg to which water is added to produce a batter; and (b) producing a confection or .. _ . __ ._ _ . .. , . . . .. . . . _ .. ..... . .. .. .. ... . .. ...... . . . . .. . . . ~ . _ . . ._ _ _ .
medicated lozenge by dehydrating the dispersion and allowing the melted residue to solidify. The disclosure of the '532 patent is incorporated herein by reference.

Other disclosures dealing with substances processed with one or more sugars under flash-flow conditions will be found in United States Patent Nos. 4,873,085;
4,997,586; 5,028,632 and 5,034,421.

2 ~2~63t, More recently, Dr. Fuisz has discovered unexpected phenomena regarding maltodextrins. Maltodextrins contain a mix of sugars and polysaccharides which range from long-chain oligomers resulting from starch hydrolysis to sugars having a low number of monomeric units. Under FDA
guidelines maltodextrin consists of nonsweet, nutritive saccharide polymers having a D.E. of less than 20, while corn syrup solids is regarded by the FDA as having a D.E.
greater than 20. However, maltodextrins are referred to herein collectively as saccharide-based material consisting of nonsweet, nutritive saccharide polymers and other oligomers having six-carbon monomer units which collectively provide a carrier material capable of forming a matrix from flash-flow processing. In one parent case, U.S. Application Serial No. 847,595, maltodextrins were subjected to flash flow conditions and found to possess an unpredictably altered structure which can be used to enhance delivery of oleaginous material and active ingredients.

In U.S. parent Application Serial No. 851,650, a new protein-based food product is disclosed which includes a carrier and an oleaginous substance. The carrier is prsferably a saccharide or a cellulosic material. An acceptable ground meat product can be prepared in accordance with the invention set forth in the '650 application. Other protein products, such as a soyburger, can be prepared in accordance with the '650 , .. . . _ _ _ . . .. . .. . . .. , _ .. . .. .. . . . . . . _ . _ . ~ . .. . . . , . _ . _ _ _ . _ . _ _, ., application with acceptable results.

Other attempts to reduce fat in ground meat products include the use of a modified food starch, e.g., LEANBIND~ (a product of the National Starch and Chemical Company of Bridgewater, N.J.), which has an amylose ``
content of less than 20%, in beef patties to reduce the fat content. This combination has been found, however, to produce only moderate success. The product prepared 21 2~ 63.) with the modified food starch is not even comparable to the higher fat content product.

In order, therefore, to entice the consumer to choose healthier food products as alternative, it is an object of the present invention to overcome the shortcomings known in the art of reduced fat products and food enhancement ingredients.

Other and further ob;ects of the present invention will become apparent in the following description and its scope will be pointed out with the appended claims.

8UMMARY OF TH~ INVENTION

The present invention is a food enhancing ingredient and food products which incorporate the use of a matrix formed by subjecting a carrier material to flash-flow processing and a starch mixed with the matrix. In another embodiment, the starch can be combined with the carrier material prior to being subjected to flash-flow processing. Preferably, the matrix is in the form of a flake which exhibits bactericidal effects.

The primary ingredients in the compositions of the present invention include a matrix formed by subjecting the carrier material to flash-flow processing, and a __~ __ starch. The starch can be ~ixed with the matrix or-it can be combined with the carrier prior to being flash-flow processed into the matrix material.

Other ingredients which can be included in thecompositions of the present invention include an oleaginous substance, oleoresins, spices, and flavor oils.

The carrier material can be selected from 21 ~fifi3~

saccharides, cellulosics and mixtures thereof. When the carrier material is a maltodextrin, it is preferably a deionized maltodextrin.

The starch material can be modified starch or unmodified starch. In one preferred embodiment, the starch is a waxy starch which means that it has an amylose content of not greater than about 20%, the balance of the material being substantially amylopectin.

Finally, the compositions of the present invention are particularly useful in protein-based food products, and, in particular, as a fat replacement in protein based food products.

When starch is combined with a matrix material to form an ingredient for inclusion in a protein based food product, the amount of starch should not exceed 35% of the combination, and preferably does not exceed 25% of the combination. If starch is combined with a carrier prior to forming a matrix, it should be included in an amount not greater than 35%, and preferably not greater than 25% of the combined feedstock which is flash-flow processed to form the matrix.

Furthermore, the final product should contain no more than 1% starch, preferably no more than 0.75%
starch, and most preferably not more than 0.5% starch by weight. Thus, the total~starch~~contënt~~in and oùt~of~the - ~-~ -matrix shol~ld not exceed 1.0%, 0.75%, or, 0.5%, respectively, for the preferred embodiments.

The food enhancing ingredient of the present invention provides a safe, expedient means of bulking a comestible while retaining cohesiveness and texture and moisture. It is ideal as a replacement for fat or other ingredients which noticeably reduce the bulk of the _7_ 212~i63~
comestible when removed. It ~s particularly useful in protein based food products in which fat is an important ingredient Por cohesiveness, bulk, moisture and texture.

The present invention further provides a means by which a starch can be successfully used as a fat replacement in products especially protein based products.

As a result of the present invention, various edible protein compositions can be provided which have enhanced taste, texture, and moisture, all without loss of bulk.
This has been achieved by being able to include starch in a unique manner with a source of protein.

The present invention also enhances shelf life and reduces or inhibits microbial growth in food productsO

Another advantage of the present invention is that high intensity flavorants such as oleoresins can be incorporated in bulk food products without incurring unwanted "hot spots" due to inadequate mixing, and thorough mixing can be achieved without deterioration of the food product.

In one particular aspect of the invention, a commercial scale manufacturing process and composition for reducing fat has been promoted without loss of . ___ _ _ ~ _ _ .. .. . .. _ .. _ . . . .. _ _ ., _ . , _.. . , . .. . . .. . -- ,.. . . . ., . _ __. _ _ _ . _ .
product quality due to the reduction of fat in the product.

BRIEF DE:~3CRIPTION OF TH~: D~WINGS

Figure 1 is a graph which depicts the results of data collected from comparative testing conducted to demonstrate the efficacy of the present invention.

, : .

21 2l~ 63 ~) pETAIl:,ED DE8CRIPl':tON OF T~IE :lNVBNTION

The present invention concerns the use of starch as a key ingredient in the formation of food products and as an ingredient for enhancing food products. In the present invention a matrix which is formed by flash-flow processing can be combined with starch and added to a food product, especially a protein-based food product, in order to enhance the gustatory qualities thereof.

The present invention also includes the use of additional components in the food enhancing ingredient and the food products. In particular, an oleaginous substance can be combined with the carrier material, or the oleaginous can be combined with the carrier and/or starch prior to being subjected to flash-flow processing.
l'he oleaginous substance can be selected from the group consisting of animal fats, such as tallows and lards, fish oils and crustacean oils, vegetable oils, and mixtures thereof.

In one preferred embodiment, the carrier is corn syrup solds (a maltodextrin), and the resalting matrix is in the form of flakes. Surprisingly, it has been found that the flake form inhibits microbial growth, and possibly has a bactericidal effect in food products.

. _ _ _ , . . . _ .. , . .. , . . . . . _ . _ _ _ ~ _ . _ . . . .. _ . _ _ _ _ While applicant is not bound by theory, it appears that maltodextrins have an antioxidant and bactericidal effect on edible proteins when incorporated therein. The extended shelf-life is observed in ground meats such as ground chicken, ground turkey, and ground beef and is especially advantageous property when the bulk protein material has low salt levels. Consequently, growth of microorganisms such as E. Coli; choliform, et al. is controlled.

212~633 g Moreover, water can be added to and retained in meat products which have been prepared in accordance with the present invention. This is contrary to conventional practice in ground meat art. The result, however, is quite beneficial in that juiciness seems to be enhanced, and the meat appears to be steamed during cooking.

Another ingredient which has been found to be quite useful in the present invention is oleoresin. Oleoresin is a natural combination of resins and essential oils exuded from plants. Oleoresin extract includes the flavoring componen~s of the spice which are soluble in the solvent used in the extraction process. Flavor is due to both volatile and nonvolatile components in herbs and spices. Most constituents are hydrophobic and, consequently, are extracted with nonpolar solvents such as hydrocarbons. Other flavor components are hydrophilic, and require recovery with a polar solvent such as acetone. Water has also been used as a solvent to produce stable spice extracts of a fresh herb or spice, and is carried out on frozen comminuted material which has been treated with acetic acid before hydraulic expression.

Oleoresin as used herein also includes water/oil-dispersable oleoresins. Water/oil-dispersable spice oleoresins can be obtained from Kalsec~ Inc. of Kalamazoo, MI under the trademark AQUARESIN~.
_ . _ . .. . .. .. .. .. .. .. . ~ .. . .. . . . . . . _ . _ .. . . .. .. .. . _ .. _ _ _ . .. . _ _ . _ .. _ . . .. _ _ .
Kalsec~ Inc. claims such resins are covered by one or more of U.S. Patent Nos. 4,283,429; 4,315,947; 4,285,981;
and 4,343,823.

Oleoresins can deliver spices such as tarragon, thyme, sage, rosemary, oregano, nutmeg, basil, bay, cardamom flavor, celery (including sweet celery), cilantro, cinnamon, clove, coriander, cumin, fennel, ginger, mace, marjoram, capsicum, black pepper, white - . : : , --: ' .. :
- ' ~' :

212~633 pepper, annatto, papr~ka, turmeric, cajun, and mixtures thereof including allspice. The present invention also contemplates the use of spice, such as those set forth above. The oleoresins can be used in the enhanced food ingredient or in the products prepared herewith. Thus, the oleoresin or spice can be combined with the carrier material prior to being subjected to flash-flow conditions. In food products, the spice or oleoresin can also be incorporated in the food product as an ingredient separate from the matrix.

The present invention can also include a flavor oil such as peppermint oil, spearmint oil, cinnamon oil, oil of wintergreen, nut oil, licorice, vanilla, citrus oils, fruit essences and mixtures thereof. Citrus oils and fruit essences can be selected from apple, apricot, banana, blueberry, cherry, coconut, grape, grapefruit, lemon, lime, orange, pear, peaches, pineapple, plum, raspberry, strawberry, and mixtures thereof.

The carrier material of the present invention can be saccharide, cellulosics and mixtures thereof.
saccharide can be any one of, for example, sucrose, lactose, fructose, dextrose, sorbitol, mannitol, maltitol, maltose, polydextrose, maltodextrins, oligosaccharides derived from chicory root, and mixtures thereof. The maltodextrin feed stock of the present _ _ _ _ ~ _ . _ _ _ . _ . ~ . _ . _ _ _ . .. .. . _ . _ . .. _, _ , _ .. _ _ , , . . . .. . . _ . _ .. _ _ _ _ _ _ ~ _ invention is a saccharide based solid material consisting of nonsweet, nutritive saccharide polymers and other glucose bearing oligomers as well as glucose units, which collectively provide a carrier material capable of forming a matrix. The Dextrose Equivalent (D.E.) of the maltodextrin feedstock is less than forty (40). In a preferred ambodiment of the present invention the D.E.
can be between twenty (20) and forty (40), and yet another preferred embodiment the D.E. can be between ten (10) and twenty (20). Preferably, the maltodextrin used as a carrier in the present invention is deionized.
However, ionized maltodextrins can be used also.

The present invention also includes starch as a basic component. Starch is a carbohydrate or polysaccharide which is derived from plant cells. Starch basically includes two fractions, amylose which is a substantially straight chain polysaccharide and amylopectin which is a branched form of the polysaccharide. Generally speaking, starches contain up to about 32% amylose while the remainder is substantially amylopectin.

In a preferred embodiment, waxy starch is used in the present invention. Waxy starch is defined as a starch which has an amylose content of not more than about 20%, and in a most preferred embodiment not greater than about 17%. Waxy starches can be derived from, for example, tapioca.

The starches of the present invention can be modified or unmodified starches. Starches can be modified by acid treatment, bleaching, oxidizing, esterified, etherified, or modified with treatment by, for example, alpha-amylase, chlorine, and sodium hydroxide. The starch may also be modified by a combination of treatments set forth above. One food _ .___ _ _ ._ .. . . .. ._ .. _ .. .. . _ ~ .. . . . .. _ .. ... _ . . _ . . . _ . . .. ._ . __ _ ~ .
modified starch which can be used in the present invention is sold by National Starch and Chemical Co. of Bridgewater, New Jersey and is known by the trade name LEANBIND~, which has an amylose content of less than 20%.
The present invention has been found to be particularly useful in protein based food products and includes both the food enhancing ingredient as well as the food product itself. Protein based food products may : ~

2 1 ~ 3 have a source of protein which is derived from meat products, soy, vegetables, and can be in the form of, for example, ground meat products. Thus, such products can include hamburger products, turkey or seafood-based products, soy-based or vegetable-based products in the form of patties, steaks, and fillets.

The matrix is provided in the present invention by subjecting the carrier and any other materials previously combined therewith to a flash-flow process. "Flash-flow"
is referred to in the present invention as a phenomena which occurs when a solid carrier material is subjected to conditions of temperature and sheer sufficient to provide internal flow at a subparticle level. This condition produces a transformation of physical and/or chemical structure without degradation of the material.
Internal flow occurs when the infrastructure of the material breaks down sufficiently to permit movement of the material at a subparticle level, and probably at a molecular level. At a molecular level, internal flow contemplates the movement of molecules relative to each other. Flash-flow can be achieved by spinning the carrier material in a high speed spinner which has a spinning head having a conductive heat element on the -perimeter thereof. This apparatus is similar to "cotton candy" type machine. The spinning machine used to achieve flash flow processing can be a cotton candy type machine, such as the Econo-Floss Model 3017 manufactured _ _ by Goldmetal Products Company of Cincinnati, Ohio.

Another method of producing flash-flow is by a shearform process such as that disclosed in commonly owned U.S. Application Serial No. 965,804 which was filed on October 23, 1992O Tha contents of U.S. Application Serial No. 965,804 is incorporated herein by reference.

The matrix obtained in the flash heat process is in 212~ 3 the form of a floss, fiber, particle, flake, spicule, or any other generally nondescript amorphous aggregate. As a result of the unique combination of the matrix material and the starch, it has been found that the texture cohesiveness, and moisture retention of food products are significantly enhanced. This appears to be the case from experimentation even when the same starch product is used alone in the protein based food product.

Xt is also contemplated that food gums, such as carageenen, xanthan, and other gums can be included in the feedstock and processed to form the matrix of the present invention.

Suitable cellulosic materials include methyl cellulose, ethyl cellulose, hydroxyethylcellulose, alkali-metal salts of carboxymethylcelluloses and the like and mixtures thereof.

The starch and matrix combination as well as the starch bearing matrix are especially well suited for products containing at least 60~ edible protein. Such products include meat products, fish, crustacean based and/or protein based compositions such as soy or vegetable products. Meats can include beef, pork, lamb, chicken, turkey, horse meat, and the like and mixtures thereof to provide a wide array of enhanced products. In 25 ~ addition the matrix may be combined-with protein material such as soy or vegetable based products. Examples of such products include soy, soy burger additives or vegetablP byproducts.

It is also contemplated that the invention can be used with most processed meat products, especially those which normally include a substantial level of fat in order to obtain desired taste characteristics. For example hot dogs, sausages, wursts, beef jerky, pet foods ~12~l633 and the like ~ay be prepared in accordance with the present invention.

In one embodiment, it has been found that exceptionally tasty meat products can be prepared by exchanging a portion (or all) of the fat found in the meat or protein based product with the matrix and starch compositions of the present invention. Even when oleaginous material is included in the matrix, the overall content of the fat can be signi~icantly reduced.
For example, a typical beef hamburger product can be prepared which has as low as about 5% percent of overall fat, without losing the gustatory qualities of a 20% -30~ fat-containing burger.

Additional advantages include an extension of shelf life of the food products which contains the inventive combination, and the high efficiency in producing protein based products with presently available equipment.

Ancillary additives include other edible ingredients such as preservatives, colorants, dyes and so forth. It has been found that by using the present invention, cooked protein products retain the taste and texture as well as the juiciness of the product. Thus, the consumer will readily select the lower fat containing product because of its comparable destitory qualities.

Examples have been set forth herein which demonstrate the efficacy of the present invention. These examples are provided to show the present preferred embodiments and to explain the unique qualities of products prepared with the present invention, but are not intended to, in any way, limit the scope of the present invention.

: - . .

2 1 2 ~ 6 3 '3 EXI~IPLE9 OF THE~ ENTION

Three matrices were prepared in order to be tested with protein-based food product. The first matrix included 80~ maltodextrin having a D.E. of 36 (Hubinger Dri Sweet 36), and 20% cannola oil. The combination was spun in a spinning apparatus to provide a white flake aggregate.

A second matrix material was prepared which consisted of 91% maltodextrin having a D.E. of 36 and 9~
oleaginous. The ingredients were mixed and sub;ected to high speed spinning for two minutes to produce results similar to that set forth in B except that the flakes were somewhat smaller.

A third matrix was prepared which included 71%
maltodextrin having a ~.E. of 36, g% oleaginous material (Canola Oil) in the way of cannola oil, and 20% food modified starch sold by the National Starch and Chemical Company under the trademark LEANBIND~. The ingredients were mixed as in matrix A and subjected to spinning in the same high speed spinning machine for two minutes.
White flakes were produced after the process reached steady state.

The compositions for each of the three matrix _ _ __ materials have been set forth in summary fashion in Table 1.

,~12rl63 3 TA~B 1 _ INGREDIENT MATRIX MATRIX MATRIX
.. _ Maltodextrin 80% 91~ 71 Oleaginous 20% 9% 9%
lStarch _ _ 20%
.

These matrices were used in the examples set forth below to compare protein based food products without the inventive compositions.

It has been found from experimentation that a high quality matrix can be prepared with excellent yield, e.g., 85% to 95~, by processing corn syrup solids, a maltodextrin, LEANBIND~ starch and canola oil in a high speed spinning machine at a speed of about 3,600 r.p.m. A working range is from about 3,500 r.p.m. to about 3,700 r.p.m., and a preferred range is from about 3,550 r.p.m. to about 3,650 r.p.m. The temperature used to process the material was 135-C. A working temperature 2Q range for processing the ~altodextrin/canola oil/starch feedstock is fro~ about 130-C to about 140-C with a preferred range from about 130-C to about 138-C.

B~AMPLE ONE

Four different hamburger products were prepared in order to compare the results using the present invention with a low fat, high quality hamburger food product. A

control example was prepared using 100 grams of 90~ fat free ground beef. The 100% ground beef patty was cooked on a hot plate at 350 degrees for two minutes per side.
The resulting hamburger was subjected to a taste test with a five member panel. The panel members tested four primary qualities of the product: taste, texture, juiciness, and product homogeneity (i.e., consistency of the product throughout the patty). The 100% ground beef patty was used as the standard against which examples 2, 3 and 4 were compared. The results of the test have been set forth below a~ter a descrlption of each of the example patties.

A second example was prepared which included 89.5%
ground beef, 8% added water and 2.5% of matrix A. Thus, example 2 is a product prepared in accordance with parent application serial No. 847,595 filed on March 5, 1992.

All of the compositions used in the examples have been set forth in table 2 herein below.

The sample of example two was formed into a lO0 gram patty which was cooked at 350- on a hot plate for two minutes on each side. The sample was submitted to the _ five_member test p~anel for determining the quality_of _ _ taste, texture, homogeneity and juiciness or moisture retention.

}3~MPL~3 T}IRE~3 In example three, a composition was prepared which included 89.5% ground beef, 8% added water and 2.5% of matrix C. Thus, example 3 is a manifestation of the present invention wherein the starch material is incorporated in the matrix.

The composition was formed into a 100 gram patty and cooked two minutes on each side on a hot plate at 350-F.
The taste tests were conducted on the example three and compared to the other examples set forth herein. For comparison of the compositions in accordance with the examples see table two here and below.

BXAMP~B FOWR

A fourth sample was prepared which incorporated 89.5% ground beef, 8~ added water, 2% of matrix B and 0.5~ of modified food starch sold undex the trademark LEANBIND~. Thus, the composition of example four shows the use of the matrix material and the starch as a combination in the protein-based product, but the starch was not subjected to flash-flow processing and made part of the matrix.

The composition was formed into a 100 gram patty and cooked on a hot plate at 350F for two minutes on each side. Taste tests to determine the comparative taste, texture, homogeneity and juiciness wa~ made by the five member taste panel.

.. ~ . .. ... .

21 2l~633 TABL~ 2 . EXAMPLE~
j INGREDIENTS 1 2 3 4 I . ..... ... __ .
Ground Beef 100% 89.5% 89.5% 89.5 5 i 90% Fat Free l I
Added _ 8.0% 8.0% 8.0%
Water Starch _ _ _ 0.5% l Matrix A _ 2.5% _ _ ¦

Matrix B _ _ _ 2.0%

Matrix C ~ _ 2.5%

The products prepared were submitted to the test panel in a blind test. Thus, the tasters did not know the origin or composition of any o~ the samples which they tasted.

Upon analysis of the comparative examples set forth below, it can be seen that the low fat hamburger by itself, Example l, was the least deæired -- the rating was the lowest of all the samples. Example 2 which basically sets forth the previous invention of the parent application showed an improvement over the low fat hamburger patty.

~12~;33 TA~LB 3 EX~MPT.~S OF THE INVENTION

Taste + ++ +++ ++++
Homogeneity Product +++++ ~+~+ +++++ +++
Texture + ++ +++ ++++
10 1 ~O~S + ++ +++ ++++

However Examples 3 and 4 which included the starch in the matrix itself and then in the composition (outside the matrix), respectively, were far superior to Example 1 and Example 2 with respect to taste, texture and juiciness. The homogeneity or product consistency for Example 4, however, was not as highly rated as in Examples 2 and 3. ~The homogeneity of Example 1 by definition must have the highest rating since it was not mixed with any other components). The test panel determined that the products of Examples 3 and 4 were both of high quality, and both were superior to It is noted that for large volume manufacturing Example 3 is the most desirable since all of the essential ingredients are contained in the matrix delivery system thereby significantly streamlining the processing procedures.

212li63 ~, BxAMpLs FIVE
Finally, another control example was prepared in which the recommended amount of LEANBIND~, e.g.
l.Oi~ - 1.5%, was used in combi~ation with low fat ground beef (90% fat free) without starch. Example S was prepared to test the starch and matrix in a protein based product as defined herein. The product was prepared by mixing the LEANBIND~ starch and ground beef, and then ~ormed into a 100 gram patty which was cooked at 350-F on a hot plate for two minutes on each side. The product was tasted by independent tasters and awarded nominal ratings of taste, texture, juiciness, and homogeneity.
The comments with respect to the low fat be~f patty with starch alone were as follows.

With respect to taste, the testers indicated that the taste was a waxy flavor having a tapioca note which overpowered the beef flavor. They indicated that the taste was unacceptable for a beef patty product. :

With respect to texture, the testers indicated that the texture was mushy having an overly-soft-continuum feeling in the mouth which did not permit crisp detachment usually associated with maceration of a beef patty.

_ _ _ __ With respect to moisture retention, the testers noted that the product had an overall soggy appearance and presentation to the mouth. The moisture which was retained gave the impression of dissolving the base ;
product both in appearance and gustatory qualities.

Finally with respect to homogeneity, the tasters described the product as discontinuous based on, among other things, the moisture separating from the patty.

The tasters were unanimous in their assessment that the product prepared with starch plus the matrix material (as well as starch incorporated in the matrix material) was vastly superior to the LEANBIND~ product in combination with the low beef patty. They also assessed Examples 1 and 2 with the LEANBIND~ patty and rated Examples 1 and 2 superior to the product in which ground beef was combined with starch by itself.

The results of those tests have been entered in graph format in Figure 1 in order to depict the dramatic results achieved using the present invention. It is of particular interest that the inventive compositions of Example 3 and the previous invention of Example 2 achieved the same degree of product homogeneity as the beef-only example!

OLEORE8IN EXA~PL~8 An equally dramatic showing of the efficacy of the present invention pertains to enabling the artisan to incorporate intense-flavored oleoresins into a protein-based food product such as ground meat, e.g., ground beefand ground turkey. Oleoresins by their very nature are high intensity flavorants. Consequently, it is very difficult to use oleoresins in food products which are bulky. This is especially true of protein-based food _ 25 ~__products such~as SGy burgers, hamburgers, turkey burgers, _ _ etc. In fact, it has been found that it is quite difficult to obtain a uniform distribution of oleoresins by mixing in ground meat products.

EXAM~LB ~IX

once again, ground beef product (which is 90% fat free) was provided for mixing with an oleoresin. The oleoresin was mixed by use of a standard mixing 2~%'16~3 apparatus~ Oleoresin was gradually added to the ground beef during mixing in a Hobart mixer at a ratio of .075 oz. of oleoresin to 50 ounces of ground beef. The mixing apparatus was permited to continue until a thorough mixture of the oleoresin was provided in the ground beef.
When the oleoresin was finally thoroughly combined with the ground beef, the texture of the meat had deteriorated so greatly that it had become pasty and generally undesirable for cooking and consumption.

The same procedure was conducted usinq ground turkey as the source of protein. Once again the oleoresin was gradually added during mixing in a Hobart mixer in an amount of .075 oz. of oleoresin to 50 ounces of ground turkey. A standard mixing apparatus was used to combine the two ingredients. Before the oleoresin was completely mixed with the ground turkey, the texture of the meat had thoroughly deteriorated, thus making it undesirable for cooking and consumption. ' These examples are to be compared with Example 7 which employed the present invention to effect mixing of high intensity oleoresin flavors.

~AMPLB 8EVEN

A feedstock was prepared in accordance with the ,formula,,set forth,in Table 4. , _ ~

:: . ~; .. . .

2~2ll633 -2~-. . _ .

~ . . . _ I
¦ INGREDIENTS AMOUNT %
l . I
Oleoresin 1.5 lbs. 3%
(Cajun AQUARESIN~) ¦ Oleaginous Material1.5 lbs. 5~ ¦
(Canola Oil) Starch 10 lbs. 20%
~LEANBIND~) Carrier 36 lbs. 72%
(DriSweet 36~) ... _ ... _ _ - 50 lbs. 100%

The feedstock was delivered to a flash-flow process provided by a high speed spinning machine (at 3600 r.p.m.) It was run at temperature of about 130-C
for a time period of about 12 minutes. The spinning procedure provided a consistent flaXe ideal for combining with hamburgex.

Next the material was introduced to the same standard mixing apparatus which was used in Example 6 at a rate of 1.25 ounces amount matrix to 45 ounces of ground beef. The product was stirred very easily in a Hobart mixer at high speed for only about 30 seconds.
The resultant composition was a thoroughly mixed protein product having the matrix combined throughout. Four (4) ounces of water was then added while the mixture was mixed in the Hobart mixer for another 10 seconds to obtain a unifcrm mix.

Consequently, the product contained spice oleoresin :~' ,. .. . - : .

212~ 633 thoroughly mixed in the ground beef without any unwanted "hot spots". The product also had excellent texture and bulk for cooking and consumption. Patties were formed at sizes of 100 gms. and cooked on a hot plate at 350-F for two minutes on each side. Use of the unique "matrix-plus-starch" combination of the present invention enable the investigators to prepare a highly desirable meat patty which cooked nicely to a spiced hamburger product.

Thus, while there had been described what are presently believed to be the preferred embodiments of the present invention, those skilled in the art will appreciate that further modifications can be made to the invention without departing from the true scope thereof, and it is intended to include all such modifications within the claims as set forth here and below.

Claims (71)

1. A food enhancing ingredient comprising:
a matrix formed by subjecting a carrier material to flash-flow processing and a starch mixed with said matrix.
2. The food enhancing ingredient of claim 1 wherein said starch is included in an amount of not more than about 35% of said ingredient.
3. The food enhancing ingredient of claim 2 wherein said starch is present in an amount of not more than about 25% of said ingredient.
4. The food enhancing ingredient of claim 1 wherein said matrix further comprises an oleaginous substance combined with said carrier material prior to being subjected to said flash-flow processing.
5. The food enhancing ingredient of claim 4 wherein said oleaginous substance is selected from the group consisting of animal fats, tallows, lards, fish oils, crustacean oils, vegetable oils and mixtures thereof.
6. The food enhancing ingredient of claim 1 wherein said matrix further comprises oleoresin combined with said carrier material prior to being subjected to flash-flow processing.
7. The food enhancing ingredient of claim 1 wherein said matrix further comprises spice combined with said carrier material prior to being subjected to flash-flow processing.
8. The food enhancing ingredient of claim 1 wherein said matrix further comprises flavor oil combined with said carrier material prior to being subjected to flash-flow processing.
9. The food enhancing ingredient of claim 1 wherein said starch is a waxy starch having an amylose content of not greater than about 20%.
10. The food enhancing ingredient of claim 9 wherein said amylose content is not greater than 17%.
11. The food enhancing ingredient of claim 1 wherein said carrier material is selected from the group consisting of saccharides, cellulosics and mixtures thereof.
12. The food enhancing ingredient of claim 11 wherein said carrier material is a saccharide is selected from the group consisting of sucrose, lactose, fructose, dextrose, sorbitol, mannitol, maltose, polydextrose, and maltodextrins, and mixtures thereof.
13. The food enhancing ingredient of claim 12 wherein said saccharide is deionized maltodextrin.
14. The food enhancing ingredient of claim 11 wherein said carrier material is cellulosic selected from the group consisting of methyl cellulose, ethyl cellulose, hydroxymethylcellulose, hydroxyethylcellulose, alkali-metal salts of carboxymethylcellulose and mixtures thereof.
15. The food enhancing ingredient of claim 1 wherein said matrix is in the form of flakes which exhibits bactericidal effect in food.
16. A protein based food product, comprising:
a matrix formed by subjecting a carrier material to flash-flow processing, a starch, and a source of protein.
17. The protein based food product of claim 16 wherein said starch is included in an amount less than about 1.0% by weight of said food product.
18. The protein based food product of claim 17 wherein said starch is included in an amount less than about 0.75% by weight of said food product.
19. The protein based food product of claim 16 wherein said matrix further comprises an oleaginous substance which is combined with said carrier material prior to said flash-flow processing.
20. The protein based food product of claim 19 wherein said oleaginous substance is selected from the group consisting of animal fats, tallows, lards, fish oils, crustacean oils, vegetable oils, and mixtures thereof.
21. The protein based food product of claim 16 wherein said matrix further comprises a flavor oil combined with said carrier material prior to said flash-flow processing.
22. The protein based food product of claim 16 wherein said matrix further comprises oleoresin combined with said carrier material prior to being subjected to flash-flow processing.
23. The protein based food product of claim 16 wherein said matrix further comprises spice combined with said carrier material prior to being subjected to flash-flow processing.
24. The protein based food product of claim 16 wherein said starch is a waxy starch having an amylose content of not greater than 20%.
25. The protein based food product of claim 24 wherein said amylose content is not greater than 17%.
26. The protein based food product of claim 16 wherein said carrier material is selected from the group consisting of saccharides, cellulosics and mixtures thereof.
27. The protein based food product of claim 26 wherein said carrier material is a saccharide selected from the group consisting of sucrose, lactose, fructose, dextrose, sorbitol, mannitol, maltose, polydextrose, maltodextrins, and mixtures thereof.
28. The protein based food product of claim 27 wherein said saccharide is deionized maltodextrin.
29. The protein based food product of claim 26 wherein said carrier material is a cellulosic selected from the group consisting of methyl cellulose, ethyl cellulose, hydroxymethylcellulose, hydroxyethylcellulose, alkali-metal salts of carboxymethylcellulose, and mixtures thereof.
30. The protein based food product of claim 16 wherein said source of protein is selected from the group consisting of animal meats, soy-based products, vegetable-based products, fish products, crustacean products and mixtures thereof.
31. The protein based food product of claim 16 wherein said matrix is in the form of flakes which exhibits bactericidal effect in said food product.
32. A novel comestible matrix comprising:
a carrier combined with a starch and subjected to flash-flow processing.
33. The matrix of claim 32 wherein said starch is combined with said carrier in an amount of not more than about 35% by weight of said combination.
34. The matrix of claim 33 wherein said starch is combined in an amount of not more than about 25% weight of said combination.
35. The matrix of claim 32 wherein said carrier is selected from the group consisting of saccharides, cellulosic materials and mixtures thereof.
36. The matrix of claim 33 wherein said carrier is a saccharide selected from the group consisting of sucrose, lactose, fructose, dextrose, sorbitol, mannitol, maltose, polydextrose, maltodextrin, and mixtures thereof.
37. The matrix of claim 35 wherein said carrier is deionized maltodextrin.
38. The matrix of claim 35 wherein said carrier is a cellulosic selected from the group consisting of methyl cellulose, ethyl cellulose, hydroxymethylcellulose, hydroxyethylcellulose, alkali-metal salts of carboxymethylcellulose and mixtures thereof.
39. The matrix of claim 32 wherein said starch is a waxy starch having an amylose content of not greater than about 20%.
40. The matrix of claim 39 wherein said amylose content is not greater than about 17%.
41. The matrix of claim 32 which further comprises an oleaginous material combined with said carrier and said starch prior to being subjected to flash-flow processing.
42. The matrix of claim 41 wherein said oleaginous is selected from a group consisting of animal fats, tallows, lards, fish oils, crustacean oils, vegetable oils, soy-based products, and mixtures thereof.
43. The matrix of claim 32 which further comprises a flavor oil combined with said carrier and said starch prior to being subjected to flash-flow processing.
44. The matrix of claim 32 which further comprises an oleoresin combined with said carrier and said starch prior to being subjected to flash-flow processing.
45. The matrix of claim 32 which further comprises spice combined with said carrier and said starch prior to being subjected to flash-flow processing.
46. The matrix of claim 32 which is in the form of a flake which exhibits batericidal effect in food.
47. A protein based food product, comprising:
a novel comestible matrix comprising a carrier combined with a starch and subjected to flash-flow processing, and a source of protein.
48. The protein based food product of claim 47 wherein said starch is included with said carrier in an amount of not greater than about 35% of said combination.
49. The protein based food product of claim 48 wherein said starch is included in an amount not greater than about 25% of said combination.
50. The protein based food product of claim 47 which further comprises starch in addition to said starch in said matrix.
51. The protein based food product of claim 50 wherein the total starch content of said product is not greater than 1% by weight.
52. The protein based product of claim 51 wherein the total amount of starch is not greater than about 0.75% by weight of said food product.
53. The protein based food product of claim 47 wherein said matrix further comprises an oleaginous substance which is combined with said carrier material prior to said flash-flow processing.
54. The protein based food product of claim 53 wherein said oleaginous substance is selected from the group consisting of animal fats, tallows, lards, fish oils, crustacean oils, vegetable oils, and mixtures thereof.
55. The protein based food product of claim 47 wherein said matrix further comprises a flavor oil combined with said carrier material prior to said flash flow processing.
56. The protein based food product of claim 47 wherein said matrix further comprises oleoresin combined with said carrier material prior to being subjected to flash-flow processing.
57. The protein based food product of claim 47 wherein said matrix further comprises spice combined with said carrier material prior to being subjected to flash-flow processing.
58. The protein based food product of claim 47 wherein said starch is a waxy starch having an amylose content of not greater than 20%.
59. The protein based food product of 58 wherein said amylose content is not greater than 17%.
60. The protein based food product of claim 47 wherein said carrier material is selected from the group consisting of saccharides, cellulosics, and of mixtures thereof.
61. the protein based food product of claim 60 wherein said carrier material is a saccharide selected from the group consisting of sucrose, lactose, fructose, dextrose, sorbitol, mannitol, maltose, polydextrose, maltodextrins, and mixtures thereof.
62. The protein based food product of claim 60 wherein said saccharide is deionized maltodextrin.
63. The protein based food product of claim 60 wherein said carrier material is a cellulosic selected from the group consisting of methyl cellulose, ethyl cellulose, hydroxymethylcellulose, hydroxyethylcellulose, alkili-metal salts of carboxymethylcellulose, and mixtures thereof.
64. The protein based food product of claim 47 wherein said source of protein is selected from the group consisting of animal meats, soy-based products, vegetable-based products, fish products, crustacean products and mixtures thereof.
65. The protein based food product of claim 47 wherein said source of protein is ground beef and said matrix comprises oleoresin combined with said carrier prior to flash-flow processing.
66. The protein based food product of claim 65 wherein said carrier is a maltodextrin and said matrix is in the form of flakes.
67. The protein based food product of claim 47 wherein said source of protein is ground turkey and said matrix comprises oleoresin combined with said carrier prior to flash-flow processing.
68. The protein based food product of claim 67 wherein said carrier is maltodextrin and said matrix is in the form of flakes.
69. A method of stabilizing a protein based food product against loss of gustatory qualities during cooking comprising:
combining starch and a matrix formed by subjecting a carrier material to flash-flow processing with a source of protein prior to cooking.
70. The method of claim 69 further comprising adding starch to said carrier material prior to flash-flow processing.
71. A method of stabilizing a protein based food product against loss of gustatory qualities during cooking comprising:
combining a matrix formed by subjecting a carrier material and starch to flash-flow processing with a source of protein prior to cooking.
CA002124633A 1993-06-02 1994-05-30 Starch-based food enhancement Abandoned CA2124633A1 (en)

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Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5603976A (en) * 1993-12-07 1997-02-18 Lifewise Ingredients, Inc. Method of reducing the animal fat content of meat products
US5582855A (en) 1994-07-01 1996-12-10 Fuisz Technologies Ltd. Flash flow formed solloid delivery systems
US5587198A (en) 1995-05-31 1996-12-24 Fuisz Technologies Ltd. Positive hydration method of preparing confectionery and product therefrom
US5833757A (en) * 1995-12-22 1998-11-10 U.S. Tech, Inc. Process for conversion of bananas to sugar syrup
US5902622A (en) * 1996-06-04 1999-05-11 Konstantinos Poulgouras Natural heat stable flavorings for bakery applications
US5952033A (en) 1996-12-24 1999-09-14 Nestec S.A. Gelatinized cereal product containing oligosaccharide and processes of preparing and using same
GB9723059D0 (en) 1997-10-31 1998-01-07 Mars Uk Ltd Pet food
WO1999056567A1 (en) * 1998-05-05 1999-11-11 Abbott Deane Nz Limited Anti-microbial agents
EP1034705A3 (en) * 1999-03-10 2001-02-28 Haarmann & Reimer Gmbh Encapsulating medium and method for encapsulating perfumes and flavours
TWI329516B (en) * 2000-12-12 2010-09-01 Kaneka Corp Composition for preventing or ameliorating multiple risk factor syndromes and visceral fat-type obesity
US6613369B2 (en) 2001-03-29 2003-09-02 Kraft Foods Holdings, Inc. Vegetable sausage analogues
JP2002316941A (en) * 2001-04-16 2002-10-31 Jungman Yoon Atp synthesis activator
ES2365138T3 (en) * 2003-08-13 2011-09-23 Ceapro Inc. COMPOSITION OF DIAGNOSIS FOR TYPE 2 DIABETES AND GLUCOSE INTOLERANCE, AND METHODS OF USE.
US20050119222A1 (en) 2003-12-01 2005-06-02 The Iams Company Compositions comprising fermentable fiber which are adapted for use by a companion animal and kits and methods of their use
US9848634B2 (en) 2009-06-30 2017-12-26 Philip Morris Products S.A. Smokeless tobacco product
AR087159A1 (en) 2011-06-20 2014-02-26 Gen Biscuit GALLETITA FOR BREAKFAST WITH SLOW GLUCOSE AVAILABILITY
IT201700028503A1 (en) * 2017-03-16 2018-09-16 Adriano Podesta Food preparation of protein matrices, optimized for healthiness, palatability, desirability and industrial and commercial characteristics, including the absence of fumes and residues, geometric tolerance, low flame cooking temperature, suitability for individual personal use in socially frequented environments
US10966720B2 (en) 2017-09-01 2021-04-06 RevMedica, Inc. Surgical stapler with removable power pack
CN112423602A (en) * 2018-07-19 2021-02-26 联合利华知识产权控股有限公司 Savoury liquid concentrate

Family Cites Families (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2826169A (en) * 1954-01-21 1958-03-11 Veen Harry H Le Reflective heat insulating coating for animals
US2918404A (en) * 1956-07-30 1959-12-22 Ortho Pharma Corp Solid compressed amino acid spermicidal vehicle
US3067743A (en) * 1958-11-12 1962-12-11 Alginate Ind Ltd Alginic compounds
US3131428A (en) * 1958-12-19 1964-05-05 Celanese Corp Spinneret and spinning method
US3036532A (en) * 1960-06-28 1962-05-29 Bowe John Cotton candy machine with product of alternating colors
US3019745A (en) * 1960-10-03 1962-02-06 Bois Albert Du Sugar spinning machine
US3070045A (en) * 1961-04-24 1962-12-25 Bowe John Machine for spinning sugar
US3073262A (en) * 1961-08-16 1963-01-15 Bowe John Spinner head for candy cotton machine
NL287733A (en) * 1962-01-15
US3095258A (en) * 1962-06-22 1963-06-25 Du Pont Melt spinning process for producing hollow-core filament
US3308221A (en) * 1963-05-14 1967-03-07 Allied Chem Melt spinning of modified cross section yarn
US3482998A (en) * 1966-02-17 1969-12-09 Gen Mills Inc Process for preparing ground meat composition
US3766165A (en) * 1966-08-17 1973-10-16 Pfizer Polysaccharides and their preparation
US3595675A (en) * 1966-11-21 1971-07-27 Gen Mills Inc Gelatin composition
US3615671A (en) * 1968-04-19 1971-10-26 Gen Foods Corp Dry food products in spun filaments and method of making same
US3723134A (en) * 1968-05-17 1973-03-27 Gen Mills Inc Process for making candy floss
US3557717A (en) * 1968-05-17 1971-01-26 Gen Mills Inc Process for making candy floss
US3762846A (en) * 1968-05-17 1973-10-02 Gen Mills Inc Process and apparatus for making candy floss
US3676148A (en) * 1970-05-13 1972-07-11 Scm Corp Edible comestibles and process for making same
US3625214A (en) * 1970-05-18 1971-12-07 Alza Corp Drug-delivery device
US3686000A (en) * 1971-01-11 1972-08-22 Gen Foods Corp Moisture resistant sugar filaments
US3951821A (en) * 1972-07-14 1976-04-20 The Dow Chemical Company Disintegrating agent for tablets
US3875300A (en) * 1972-12-18 1975-04-01 Ortho Pharma Corp Composition for sustained release of a medicament and method of using same
US3876794A (en) * 1972-12-20 1975-04-08 Pfizer Dietetic foods
US3930043A (en) * 1973-07-19 1975-12-30 Tec Pak Corp Method for making cotton candy
US3856443A (en) * 1973-08-06 1974-12-24 Gen Properties Anstalt Apparatus for producing candyfloss
US3925525A (en) * 1973-08-10 1975-12-09 Celanese Corp Spinning method
US4136145A (en) * 1974-07-05 1979-01-23 Schering Aktiengesellschaft Medicament carriers in the form of film having active substance incorporated therein
US3967623A (en) * 1975-06-30 1976-07-06 Johnson & Johnson Disposable absorbent pad
US3992265A (en) * 1975-12-31 1976-11-16 American Cyanamid Company Antibiotic susceptibility testing
US4090920A (en) * 1976-02-19 1978-05-23 Fisher Scientific Company Disposable antibiotic susceptability test package
US4153512A (en) * 1976-04-07 1979-05-08 Fisher Scientific Company Storage stable antibiotic susceptibility test kit and method of testing
GB1548022A (en) * 1976-10-06 1979-07-04 Wyeth John & Brother Ltd Pharmaceutial dosage forms
US4293570A (en) * 1979-04-02 1981-10-06 Chimicasa Gmbh Process for the preparation of sweetener containing product
US4291015A (en) * 1979-08-14 1981-09-22 Key Pharmaceuticals, Inc. Polymeric diffusion matrix containing a vasodilator
US4303684A (en) * 1980-03-17 1981-12-01 General Foods Corporation Rapidly-soluble sweetener, process for its preparation and beverage mix employing it
US4348420A (en) * 1980-08-25 1982-09-07 Nutrisearch Company Process for binding comminuted meat
US4500546A (en) * 1980-10-31 1985-02-19 International Telephone And Telegraph Corporation Suspensions containing microfibrillated cellulose
US4585797A (en) * 1981-04-13 1986-04-29 Seton Company Cosmetic and pharmaceutical sheet material containing polypeptides
US4376743A (en) * 1981-06-12 1983-03-15 Fiber Industries, Inc. Melt spinning process
JPS5966841A (en) * 1982-10-05 1984-04-16 Meiji Seika Kaisha Ltd Preparation of conjugate fibrous chewing gum
GB2137470B (en) * 1983-04-08 1986-11-26 Meiji Seika Kaisha Fleecy confectionery producing machine
US4511584A (en) * 1983-05-31 1985-04-16 Scm Corporation Particulate food acidulant
DE3430809A1 (en) * 1984-08-22 1986-03-06 Merck Patent Gmbh, 6100 Darmstadt SUCRALFAT SUSPENSION
US4619833A (en) * 1984-12-13 1986-10-28 General Foods Inc. Process for producing a rapidly water-soluble, free-flowing, sugar-free dry beverage mix
US4879108A (en) * 1985-12-20 1989-11-07 Warner-Lambert Company Confectionery delivery system for antipyretics
US4772477A (en) * 1986-10-17 1988-09-20 Balchem Corporation Meat acidulant
US4793782A (en) * 1986-12-17 1988-12-27 Sells-Floto Inc. Cotton candy machine
US5236734A (en) * 1987-04-20 1993-08-17 Fuisz Technologies Ltd. Method of preparing a proteinaceous food product containing a melt spun oleaginous matrix
US5286513A (en) * 1987-04-20 1994-02-15 Fuisz Technologies Ltd. Proteinaceous food product containing a melt spun oleaginous matrix
US4997856A (en) * 1987-04-20 1991-03-05 Fuisz Pharmaceutical Ltd. Method of producing compacted dispersable systems
US5034421A (en) * 1988-12-13 1991-07-23 Fuisz Pharmaceutical Ltd. Moderated spun fibrous system and method of manufacture
US5096492A (en) * 1987-04-20 1992-03-17 Fuisz Technologies Ltd. Dispersed systems and method of manufacture
US4855326A (en) * 1987-04-20 1989-08-08 Fuisz Pharmaceutical Ltd. Rapidly dissoluble medicinal dosage unit and method of manufacture
US4873085A (en) * 1987-04-20 1989-10-10 Fuisz Pharmaceutical Ltd. Spun fibrous cosmetic and method of use
US5028632A (en) * 1987-04-20 1991-07-02 Fuisz Pharmaceutical Ltd. Taste masked medicated pharmaceutical
US5387431A (en) * 1991-10-25 1995-02-07 Fuisz Technologies Ltd. Saccharide-based matrix
US5011532A (en) * 1988-03-18 1991-04-30 Fuisz Pharmaceutical Ltd. Dispersed systems and method of manufacture
US5089606A (en) * 1989-01-24 1992-02-18 Minnesota Mining And Manufacturing Company Water-insoluble polysaccharide hydrogel foam for medical applications
US4978537A (en) * 1989-04-19 1990-12-18 Wm. Wrigley Jr. Company Gradual release structures for chewing gum
US5009900A (en) * 1989-10-02 1991-04-23 Nabisco Brands, Inc. Glassy matrices containing volatile and/or labile components, and processes for preparation and use thereof
JP2807298B2 (en) * 1989-12-05 1998-10-08 千代田食品株式会社 Sausage and method for producing the same
JPH03175955A (en) * 1989-12-05 1991-07-31 Chiyoda Shokuhin Kk Sausage and its preparation
JPH03206871A (en) * 1990-01-10 1991-09-10 Chiyoda Shokuhin Kk Hamburger and production thereof
KR100237733B1 (en) * 1991-11-04 2000-01-15 리차드 디. 슈미트 Water-soluble delivery systems for hydrophobic liquid

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US5422136A (en) 1995-06-06
DE69414460D1 (en) 1998-12-17
US5472731A (en) 1995-12-05
EP0627172A1 (en) 1994-12-07
EP0627172B1 (en) 1998-11-11
DK0627172T3 (en) 1999-07-26

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