CA2122670A1 - Absorbable block copolymers and surgical articles fabricated therefrom - Google Patents
Absorbable block copolymers and surgical articles fabricated therefromInfo
- Publication number
- CA2122670A1 CA2122670A1 CA002122670A CA2122670A CA2122670A1 CA 2122670 A1 CA2122670 A1 CA 2122670A1 CA 002122670 A CA002122670 A CA 002122670A CA 2122670 A CA2122670 A CA 2122670A CA 2122670 A1 CA2122670 A1 CA 2122670A1
- Authority
- CA
- Canada
- Prior art keywords
- block copolymers
- surgical articles
- fabricated therefrom
- articles fabricated
- absorbable block
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L17/00—Materials for surgical sutures or for ligaturing blood vessels ; Materials for prostheses or catheters
- A61L17/06—At least partially resorbable materials
- A61L17/10—At least partially resorbable materials containing macromolecular materials
- A61L17/12—Homopolymers or copolymers of glycolic acid or lactic acid
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B17/00—Surgical instruments, devices or methods, e.g. tourniquets
- A61B17/04—Surgical instruments, devices or methods, e.g. tourniquets for suturing wounds; Holders or packages for needles or suture materials
- A61B17/06—Needles ; Sutures; Needle-suture combinations; Holders or packages for needles or suture materials
- A61B17/06166—Sutures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/664—Polyesters containing oxygen in the form of ether groups derived from hydroxy carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B17/00—Surgical instruments, devices or methods, e.g. tourniquets
- A61B2017/00004—(bio)absorbable, (bio)resorbable, resorptive
Abstract
Block copolymers wherein one of the blocks is made from hard phase forming monomers and another of the blocks is made from soft phase forming monomers copolymerized with randomly intermingled units of other soft phase forming monomers. The copolymers are useful in forming surgical articles, including both monofilament and multifilament sutures.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US6881193A | 1993-05-27 | 1993-05-27 | |
US08/068,811 | 1993-05-27 | ||
US08/204,721 | 1994-03-02 | ||
US08/204,721 US5403347A (en) | 1993-05-27 | 1994-03-02 | Absorbable block copolymers and surgical articles fabricated therefrom |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2122670A1 true CA2122670A1 (en) | 1994-11-28 |
CA2122670C CA2122670C (en) | 2001-04-17 |
Family
ID=26749411
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002122670A Expired - Lifetime CA2122670C (en) | 1993-05-27 | 1994-05-02 | Absorbable block copolymers and surgical articles fabricated therefrom |
Country Status (7)
Country | Link |
---|---|
US (2) | US5403347A (en) |
EP (1) | EP0626404B1 (en) |
JP (1) | JP3251768B2 (en) |
AU (1) | AU675522B2 (en) |
CA (1) | CA2122670C (en) |
DE (1) | DE69408897T2 (en) |
ES (1) | ES2115802T3 (en) |
Families Citing this family (115)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5502159A (en) * | 1991-04-17 | 1996-03-26 | United States Surgical Corporation | Absorbable composition |
US5522841A (en) * | 1993-05-27 | 1996-06-04 | United States Surgical Corporation | Absorbable block copolymers and surgical articles fabricated therefrom |
US6315788B1 (en) | 1994-02-10 | 2001-11-13 | United States Surgical Corporation | Composite materials and surgical articles made therefrom |
CA2158420C (en) * | 1994-09-16 | 2007-05-01 | Mark S. Roby | Absorbable polymer and surgical articles fabricated therefrom |
US6206908B1 (en) | 1994-09-16 | 2001-03-27 | United States Surgical Corporation | Absorbable polymer and surgical articles fabricated therefrom |
US5618313A (en) * | 1994-10-11 | 1997-04-08 | United States Surgical Corporation | Absorbable polymer and surgical articles fabricated therefrom |
US5633343A (en) * | 1995-06-30 | 1997-05-27 | Ethicon, Inc. | High strength, fast absorbing, melt processable, gycolide-rich, poly(glycolide-co-p-dioxanone) copolymers |
US5747637A (en) * | 1995-09-07 | 1998-05-05 | Mitsui Toatsu Chemicals, Inc. | Bioabsorbable polymer and process for preparing the same |
US5639851A (en) * | 1995-10-02 | 1997-06-17 | Ethicon, Inc. | High strength, melt processable, lactide-rich, poly(lactide-CO-P-dioxanone) copolymers |
DE69728307T2 (en) * | 1996-01-19 | 2005-02-17 | United States Surgical Corp., Norwalk | Absorbable polymer mixtures and surgical articles made therefrom |
US6074673A (en) * | 1996-04-22 | 2000-06-13 | Guillen; Manuel | Slow-release, self-absorbing, drug delivery system |
DE19641335A1 (en) * | 1996-10-08 | 1998-04-09 | Inst Textil & Faserforschung | Triblock terpolymer, its use in surgical sutures and manufacturing methods |
US5718716A (en) * | 1996-09-20 | 1998-02-17 | Ethicon, Inc. | Process for manufacturing sutures from copolymers of glycolide and E-caprolactone |
ZA978537B (en) | 1996-09-23 | 1998-05-12 | Focal Inc | Polymerizable biodegradable polymers including carbonate or dioxanone linkages. |
DE19641334A1 (en) * | 1996-10-08 | 1998-04-09 | Inst Textil & Faserforschung | Triblock terpolymer, its use in medical products and manufacturing processes |
US6191236B1 (en) | 1996-10-11 | 2001-02-20 | United States Surgical Corporation | Bioabsorbable suture and method of its manufacture |
US5786022A (en) * | 1996-10-31 | 1998-07-28 | Ethicon, Inc. | Coating mixture for surgical articles |
US5817129A (en) | 1996-10-31 | 1998-10-06 | Ethicon, Inc. | Process and apparatus for coating surgical sutures |
US6007565A (en) * | 1997-09-05 | 1999-12-28 | United States Surgical | Absorbable block copolymers and surgical articles fabricated therefrom |
US5854383A (en) * | 1997-10-06 | 1998-12-29 | Ethicon, Inc. | Aliphatic polyesters of trimethylene carbonate epsilon-caprolactone and glycolide |
US6277927B1 (en) | 1997-11-26 | 2001-08-21 | United States Surgical Corporation | Absorbable block copolymers and surgical articles fabricated therefrom |
EP1045677A4 (en) | 1998-01-06 | 2005-01-12 | Aderans Res Inst Inc | Bioabsorbable fibers and reinforced composites produced therefrom |
EP1071480B1 (en) * | 1998-02-25 | 2010-11-10 | Tyco Healthcare Group LP | Sutures made from absorbable copolymers |
US6494898B1 (en) * | 1998-02-25 | 2002-12-17 | United States Surgical Corporation | Absorbable copolymers and surgical articles fabricated therefrom |
US6165202A (en) * | 1998-07-06 | 2000-12-26 | United States Surgical Corporation | Absorbable polymers and surgical articles fabricated therefrom |
US5971987A (en) * | 1998-09-18 | 1999-10-26 | Ethicon, Inc. | Biocompatible absorbable polymer fastener and driver for use in surgical procedures |
AU2003203627B2 (en) * | 1998-10-20 | 2005-05-19 | United States Surgical Corporation | Method of Manufacturing A Monofilament Suture From A Resin of A Random Copolymer |
AU762453B2 (en) * | 1998-10-20 | 2003-06-26 | United States Surgical Corporation | Absorbable polymers and surgical articles fabricated therefrom |
US6235869B1 (en) | 1998-10-20 | 2001-05-22 | United States Surgical Corporation | Absorbable polymers and surgical articles fabricated therefrom |
US6241732B1 (en) | 1998-11-03 | 2001-06-05 | David W. Overaker | Biocompatible absorbable rivets and pins for use in surgical procedures |
US6255408B1 (en) | 1998-11-06 | 2001-07-03 | Poly-Med, Inc. | Copolyesters with minimized hydrolytic instability and crystalline absorbable copolymers thereof |
US6551241B1 (en) * | 1999-12-17 | 2003-04-22 | Leonard S. Schultz | Instruments and methods for performing percutaneous surgery |
US6884427B1 (en) * | 1999-02-08 | 2005-04-26 | Aderans Research Institute, Inc. | Filamentary means for introducing agents into tissue of a living host |
US6462169B1 (en) * | 1999-11-30 | 2002-10-08 | Poly-Med, Inc. | Amorphous polymeric polyaxial initiators and compliant crystalline copolymers therefrom |
US7198641B2 (en) * | 2000-08-08 | 2007-04-03 | Aderans Research Institute, Inc. | Scaffolds for tissue engineered hair |
US6794485B2 (en) * | 2000-10-27 | 2004-09-21 | Poly-Med, Inc. | Amorphous polymeric polyaxial initiators and compliant crystalline copolymers therefrom |
US8299205B2 (en) * | 2000-10-27 | 2012-10-30 | Poly-Med, Inc. | Acetone-soluble, absorbable, crystalline polyaxial copolymers and applications thereof |
US7416559B2 (en) | 2000-10-27 | 2008-08-26 | Poly-Med, Inc. | Micromantled drug-eluting stent |
US20020161168A1 (en) * | 2000-10-27 | 2002-10-31 | Shalaby Shalaby W. | Amorphous polymeric polyaxial initiators and compliant crystalline copolymers therefrom |
US6575986B2 (en) | 2001-02-26 | 2003-06-10 | Ethicon, Inc. | Scaffold fixation device for use in articular cartilage repair |
US6743232B2 (en) | 2001-02-26 | 2004-06-01 | David W. Overaker | Tissue scaffold anchor for cartilage repair |
US6607548B2 (en) | 2001-05-17 | 2003-08-19 | Inion Ltd. | Resorbable polymer compositions |
US7901713B2 (en) * | 2001-06-20 | 2011-03-08 | Metaproteomics, Llc | Inhibition of COX-2 and/or 5-LOX activity by fractions isolated or derived from hops |
US6626950B2 (en) | 2001-06-28 | 2003-09-30 | Ethicon, Inc. | Composite scaffold with post anchor for the repair and regeneration of tissue |
US6498229B1 (en) | 2001-09-05 | 2002-12-24 | Poly-Med, Inc. | Direct synthesis of segmented glycolide copolymers and crystalline materials therefrom |
US20040068284A1 (en) * | 2002-01-29 | 2004-04-08 | Barrows Thomas H. | Method for stimulating hair growth and kit for carrying out said method |
US20030236319A1 (en) * | 2002-06-25 | 2003-12-25 | Hye-Sung Yoon | Block copolymers for surgical articles |
CA2500854C (en) * | 2002-10-04 | 2009-09-08 | Tyco Healthcare Group Lp | Process of making bioabsorbable filaments |
US8262963B2 (en) * | 2002-10-04 | 2012-09-11 | Tyco Healthcare Group Lp | Process of making bioabsorbable filaments |
US7148315B2 (en) * | 2002-10-23 | 2006-12-12 | Ethicon, Inc. | Monomer addition techniques to control manufacturing of bioabsorbable copolymers |
US7461574B2 (en) * | 2003-04-28 | 2008-12-09 | Biomet Microfixation, Llc | Multiple screw delivery apparatus |
US20040220534A1 (en) * | 2003-04-29 | 2004-11-04 | Martens Paul W. | Medical device with antimicrobial layer |
US7597885B2 (en) * | 2004-03-26 | 2009-10-06 | Aderans Research Institute, Inc. | Tissue engineered biomimetic hair follicle graft |
EP1763703A4 (en) * | 2004-05-12 | 2010-12-08 | Massachusetts Inst Technology | Manufacturing process, such as three-dimensional printing, including solvent vapor filming and the like |
AR050212A1 (en) * | 2004-08-13 | 2006-10-04 | Aderans Res Inst Inc | ORGANOGENESIS FROM DISCELLED CELLS |
AU2006270221B2 (en) | 2005-07-15 | 2012-01-19 | Micell Technologies, Inc. | Polymer coatings containing drug powder of controlled morphology |
WO2007011708A2 (en) | 2005-07-15 | 2007-01-25 | Micell Technologies, Inc. | Stent with polymer coating containing amorphous rapamycin |
US20070087061A1 (en) * | 2005-10-14 | 2007-04-19 | Medafor, Incorporated | Method and composition for creating and/or activating a platelet-rich gel by contact with a porous particulate material, for use in wound care, tissue adhesion, or as a matrix for delivery of therapeutic components |
TW200800240A (en) * | 2005-11-22 | 2008-01-01 | Aderans Res Inst Inc | Hair follicle graft from tissue engineered skin |
AR057628A1 (en) * | 2005-11-22 | 2007-12-05 | Aderans Res Inst Inc | CAPITAL DIVERTS DERIVED FROM EXTRACTED HAIR |
US20070205910A1 (en) * | 2006-02-22 | 2007-09-06 | Parker-Hannifin Corporation | Wireless motion control system |
WO2007127363A2 (en) * | 2006-04-26 | 2007-11-08 | Micell Technologies, Inc. | Coatings containing multiple drugs |
US8952123B1 (en) * | 2006-08-02 | 2015-02-10 | Abbott Cardiovascular Systems Inc. | Dioxanone-based copolymers for implantable devices |
US20080051833A1 (en) * | 2006-08-25 | 2008-02-28 | Vincent Gramuglia | Suture passer and method of passing suture material |
US8636767B2 (en) * | 2006-10-02 | 2014-01-28 | Micell Technologies, Inc. | Surgical sutures having increased strength |
EP2081694B1 (en) | 2006-10-23 | 2020-05-13 | Micell Technologies, Inc. | Holder for electrically charging a substrate during coating |
US11426494B2 (en) | 2007-01-08 | 2022-08-30 | MT Acquisition Holdings LLC | Stents having biodegradable layers |
JP5603598B2 (en) | 2007-01-08 | 2014-10-08 | ミセル テクノロジーズ、インコーポレイテッド | Stent with biodegradable layer |
US20100211164A1 (en) * | 2007-04-17 | 2010-08-19 | Mcclain James B | Stents having biodegradable layers |
EP2170418B1 (en) * | 2007-05-25 | 2016-03-16 | Micell Technologies, Inc. | Polymer films for medical device coating |
US7985537B2 (en) * | 2007-06-12 | 2011-07-26 | Aderans Research Institute, Inc. | Methods for determining the hair follicle inductive properties of a composition |
JP5330407B2 (en) * | 2007-12-21 | 2013-10-30 | スリーエム イノベイティブ プロパティズ カンパニー | Retroreflective pavement marking |
DE102008012620A1 (en) | 2008-02-28 | 2009-09-03 | Deutsche Institute Für Textil- Und Faserforschung Denkendorf | Absorbable block polymer, process for its preparation and use |
SG192523A1 (en) * | 2008-04-17 | 2013-08-30 | Micell Technologies Inc | Stents having bioabsorbable layers |
CN102159257B (en) | 2008-07-17 | 2015-11-25 | 米歇尔技术公司 | Drug delivery medical device |
WO2010042918A1 (en) | 2008-10-11 | 2010-04-15 | Rutgers, The State University Of New Jersey | Biocompatible polymers for medical devices |
US8834913B2 (en) * | 2008-12-26 | 2014-09-16 | Battelle Memorial Institute | Medical implants and methods of making medical implants |
US20100241220A1 (en) * | 2009-03-23 | 2010-09-23 | Mcclain James B | Peripheral Stents Having Layers |
CA2757276C (en) * | 2009-04-01 | 2017-06-06 | Micell Technologies, Inc. | Coated stents |
CA2759015C (en) | 2009-04-17 | 2017-06-20 | James B. Mcclain | Stents having controlled elution |
EP2453834A4 (en) | 2009-07-16 | 2014-04-16 | Micell Technologies Inc | Drug delivery medical device |
JP5944314B2 (en) | 2009-07-31 | 2016-07-05 | ラトガース,ザ ステート ユニバーシティ オブ ニュー ジャージー | Biocompatible polymers for medical devices |
AU2010303170B2 (en) | 2009-10-11 | 2015-02-26 | Rutgers, The State University Of New Jersey | Biocompatible polymers for medical devices |
EP2531140B1 (en) * | 2010-02-02 | 2017-11-01 | Micell Technologies, Inc. | Stent and stent delivery system with improved deliverability |
US8795762B2 (en) | 2010-03-26 | 2014-08-05 | Battelle Memorial Institute | System and method for enhanced electrostatic deposition and surface coatings |
CA2797110C (en) | 2010-04-22 | 2020-07-21 | Micell Technologies, Inc. | Stents and other devices having extracellular matrix coating |
DK2859887T3 (en) | 2010-07-09 | 2017-06-26 | Innocore Tech B V | BIODEGRADABLE PHASE Separated, SEGMENTED MULTIBLOCK COPOLYMERS AND RELEASE OF BIOLOGICALLY ACTIVE POLYPEPTIDES |
WO2012009684A2 (en) | 2010-07-16 | 2012-01-19 | Micell Technologies, Inc. | Drug delivery medical device |
PT3199126T (en) * | 2011-03-09 | 2020-01-28 | Tepha Inc | Systems for mastopexy |
US10464100B2 (en) | 2011-05-31 | 2019-11-05 | Micell Technologies, Inc. | System and process for formation of a time-released, drug-eluting transferable coating |
CA2841360A1 (en) | 2011-07-15 | 2013-01-24 | Micell Technologies, Inc. | Drug delivery medical device |
WO2013015685A1 (en) | 2011-07-22 | 2013-01-31 | Innocore Technologies B.V. | Biodegradable, semi-crystalline, phase separated, thermoplastic multi block copolymers for controlled release of biologically active compounds |
US10188772B2 (en) | 2011-10-18 | 2019-01-29 | Micell Technologies, Inc. | Drug delivery medical device |
US9416090B2 (en) | 2012-02-03 | 2016-08-16 | Rutgers, The State University Of New Jersey | Polymeric biomaterials derived from phenolic monomers and their medical uses |
US11472918B2 (en) | 2012-02-03 | 2022-10-18 | Rutgers, The State University Of New Jersey | Polymeric biomaterials derived from phenolic monomers and their medical uses |
US20130267972A1 (en) * | 2012-04-06 | 2013-10-10 | Poly-Med, Inc. | Polymeric mesh products, method of making and use thereof |
US9173655B2 (en) | 2012-12-13 | 2015-11-03 | Ethicon Endo-Surgery, Inc. | Needle driver and pawl mechanism for circular needle applier |
US9125645B1 (en) | 2013-03-11 | 2015-09-08 | Ethicon Endo-Surgery, Inc. | Reciprocating needle drive without cables |
WO2014165264A1 (en) | 2013-03-12 | 2014-10-09 | Micell Technologies, Inc. | Bioabsorbable biomedical implants |
USD771811S1 (en) | 2013-03-15 | 2016-11-15 | Ethicon Endo-Surgery, Llc | Suture tray |
US9375212B2 (en) | 2014-06-06 | 2016-06-28 | Ethicon Endo-Surgery, Llc | Circular needle applier with cleats |
US20150351749A1 (en) | 2014-06-06 | 2015-12-10 | Ethicon Endo-Surgery, Inc. | Needle Cartridge with Moveable Cover |
EP2996629B1 (en) | 2013-05-15 | 2021-09-22 | Micell Technologies, Inc. | Bioabsorbable biomedical implants |
US10004490B2 (en) | 2014-06-06 | 2018-06-26 | Ethicon Llc | Force limited needle driver |
USD745146S1 (en) | 2014-06-06 | 2015-12-08 | Ethicon Endo-Surgery, Inc. | Surgical suturing device |
US10774030B2 (en) | 2014-12-23 | 2020-09-15 | Rutgers, The State University Of New Jersey | Polymeric biomaterials derived from phenolic monomers and their medical uses |
AU2015370426B2 (en) | 2014-12-23 | 2019-09-12 | Rutgers, The State University Of New Jersey | Biocompatible iodinated diphenol monomers and polymers |
EP3085820B1 (en) | 2015-04-22 | 2017-12-20 | Sofradim Production | A method for forming a barbed suture and the barbed suture thus obtained |
EP3085332B1 (en) | 2015-04-23 | 2019-02-27 | Sofradim Production | Package for a surgical mesh |
US10022120B2 (en) | 2015-05-26 | 2018-07-17 | Ethicon Llc | Surgical needle with recessed features |
USD800306S1 (en) | 2015-12-10 | 2017-10-17 | Ethicon Llc | Surgical suturing device |
USD865964S1 (en) | 2017-01-05 | 2019-11-05 | Ethicon Llc | Handle for electrosurgical instrument |
EP3628698A1 (en) | 2018-09-26 | 2020-04-01 | Covidien LP | Biodegradable triblock copolymers and implantable medical devices made therefrom |
USD895112S1 (en) | 2018-11-15 | 2020-09-01 | Ethicon Llc | Laparoscopic bipolar electrosurgical device |
US11028222B2 (en) | 2018-11-28 | 2021-06-08 | Ethicon, Inc. | Advanced processing of absorbable poly(p-dioxanone) containing high level of p-dioxanone monomer |
Family Cites Families (77)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2683136A (en) * | 1950-10-25 | 1954-07-06 | Du Pont | Copolymers of hydroxyacetic acid with other alcohol acids |
US2703316A (en) * | 1951-06-05 | 1955-03-01 | Du Pont | Polymers of high melting lactide |
US2668162A (en) * | 1952-03-20 | 1954-02-02 | Du Pont | Preparation of high molecular weight polyhydroxyacetic ester |
US2758987A (en) * | 1952-06-05 | 1956-08-14 | Du Pont | Optically active homopolymers containing but one antipodal species of an alpha-monohydroxy monocarboxylic acid |
BE534967A (en) * | 1954-10-20 | |||
US3225766A (en) * | 1962-03-26 | 1965-12-28 | Grace W R & Co | Method of making absorbable surgical sutures from poly beta hydroxy acids |
NL294714A (en) * | 1963-06-28 | |||
US3297033A (en) * | 1963-10-31 | 1967-01-10 | American Cyanamid Co | Surgical sutures |
US3739773A (en) * | 1963-10-31 | 1973-06-19 | American Cyanamid Co | Polyglycolic acid prosthetic devices |
US3463158A (en) * | 1963-10-31 | 1969-08-26 | American Cyanamid Co | Polyglycolic acid prosthetic devices |
US3620218A (en) * | 1963-10-31 | 1971-11-16 | American Cyanamid Co | Cylindrical prosthetic devices of polyglycolic acid |
US3268487A (en) * | 1963-12-23 | 1966-08-23 | Shell Oil Co | Process for polymerization of lactides |
US3531561A (en) * | 1965-04-20 | 1970-09-29 | Ethicon Inc | Suture preparation |
US3442871A (en) * | 1966-05-04 | 1969-05-06 | American Cyanamid Co | Process for polymerizing a glycolide |
US3422181A (en) * | 1966-05-23 | 1969-01-14 | American Cyanamid Co | Method for heat setting of stretch oriented polyglycolic acid filament |
US3468853A (en) * | 1966-06-15 | 1969-09-23 | American Cyanamid Co | Process of polymerizing a glycolide |
US3597449A (en) * | 1967-11-16 | 1971-08-03 | American Cyanamid Co | Stable glycolide and lactide composition |
US3772420A (en) * | 1968-12-23 | 1973-11-13 | American Cyanamid Co | Method for improving the in-vivo strength of polyglycolic acid |
US3565869A (en) * | 1968-12-23 | 1971-02-23 | American Cyanamid Co | Extrudable and stretchable polyglycolic acid and process for preparing same |
US3626948A (en) * | 1968-12-23 | 1971-12-14 | American Cyanamid Co | Absorbable polyglycolic acid suture of enhanced in-vivo strength retention |
US3797499A (en) * | 1970-05-13 | 1974-03-19 | Ethicon Inc | Polylactide fabric graphs for surgical implantation |
BE758156R (en) * | 1970-05-13 | 1971-04-28 | Ethicon Inc | ABSORBABLE SUTURE ELEMENT AND ITS |
GB1332505A (en) * | 1970-10-16 | 1973-10-03 | Ethicon Inc | Sutures and other surgical aids |
US3846382A (en) * | 1971-02-25 | 1974-11-05 | American Cyanamid Co | Sterile medical dusting powder |
US3781349A (en) * | 1971-02-25 | 1973-12-25 | American Cyanamid Co | Preparation of polyglycolic acid in finely divided form |
US3987937A (en) * | 1971-05-06 | 1976-10-26 | Eppco | Powder feeder and methods for transporting particulate material |
US3878284A (en) * | 1971-08-12 | 1975-04-15 | American Cyanamid Co | Processes for making shaped articles such as filaments or films from solutions of polyglycolic acid |
US3733919A (en) * | 1971-09-20 | 1973-05-22 | Adjustable eccentric bearing mountings background | |
US3736646A (en) * | 1971-10-18 | 1973-06-05 | American Cyanamid Co | Method of attaching surgical needles to multifilament polyglycolic acid absorbable sutures |
US3867190A (en) * | 1971-10-18 | 1975-02-18 | American Cyanamid Co | Reducing capillarity of polyglycolic acid sutures |
US3784585A (en) * | 1971-10-21 | 1974-01-08 | American Cyanamid Co | Water-degradable resins containing recurring,contiguous,polymerized glycolide units and process for preparing same |
US3839297A (en) * | 1971-11-22 | 1974-10-01 | Ethicon Inc | Use of stannous octoate catalyst in the manufacture of l(-)lactide-glycolide copolymer sutures |
US3792010A (en) * | 1972-03-27 | 1974-02-12 | Ethicon Inc | Plasticized polyester sutures |
US3982543A (en) * | 1973-04-24 | 1976-09-28 | American Cyanamid Company | Reducing capillarity of polyglycolic acid sutures |
US4033938A (en) * | 1974-01-21 | 1977-07-05 | American Cyanamid Company | Polymers of unsymmetrically substituted 1,4-dioxane-2,5-diones |
GB1414600A (en) * | 1974-02-08 | 1975-11-19 | Ethicon Inc | Plasticised polyester sutures |
US3902497A (en) * | 1974-03-25 | 1975-09-02 | American Cyanamid Co | Body absorbable sponge and method of making |
US3937223A (en) * | 1974-04-19 | 1976-02-10 | American Cyanamid Company | Compacted surgical hemostatic felt |
US3896802A (en) * | 1974-04-19 | 1975-07-29 | American Cyanamid Co | Flexible flocked dressing |
US4045418A (en) * | 1975-01-28 | 1977-08-30 | Gulf Oil Corporation | Copolymers of D,L-lactide and epsilon caprolactone |
US4057537A (en) * | 1975-01-28 | 1977-11-08 | Gulf Oil Corporation | Copolymers of L-(-)-lactide and epsilon caprolactone |
US4060089A (en) * | 1975-09-03 | 1977-11-29 | United States Surgical Corporation | Surgical fastening method and device therefor |
US4052988A (en) * | 1976-01-12 | 1977-10-11 | Ethicon, Inc. | Synthetic absorbable surgical devices of poly-dioxanone |
US4300565A (en) * | 1977-05-23 | 1981-11-17 | American Cyanamid Company | Synthetic polyester surgical articles |
US4243775A (en) * | 1978-11-13 | 1981-01-06 | American Cyanamid Company | Synthetic polyester surgical articles |
US4137921A (en) * | 1977-06-24 | 1979-02-06 | Ethicon, Inc. | Addition copolymers of lactide and glycolide and method of preparation |
US4246904A (en) * | 1979-01-29 | 1981-01-27 | American Cyanamid Company | Surgical suture derived from segmented polyether-ester block copolymers |
FR2439003A1 (en) * | 1978-10-20 | 1980-05-16 | Anvar | NEW OSTEOSYNTHESIS PARTS, THEIR PREPARATION AND THEIR APPLICATION |
US4275831A (en) * | 1978-12-26 | 1981-06-30 | Sbs Corporation | Make up air system |
US4275813A (en) * | 1979-06-04 | 1981-06-30 | United States Surgical Corporation | Coherent surgical staple array |
US4273920A (en) * | 1979-09-12 | 1981-06-16 | Eli Lilly And Company | Polymerization process and product |
FR2510411B1 (en) * | 1981-07-30 | 1986-09-12 | Ethicon Inc | CROSSLINKED POLYDIOXANONE SURGICAL APPARATUS AND METHOD FOR THE PRODUCTION THEREOF |
US4429080A (en) * | 1982-07-01 | 1984-01-31 | American Cyanamid Company | Synthetic copolymer surgical articles and method of manufacturing the same |
US4643191A (en) * | 1985-11-29 | 1987-02-17 | Ethicon, Inc. | Crystalline copolymers of p-dioxanone and lactide and surgical devices made therefrom |
US4653497A (en) * | 1985-11-29 | 1987-03-31 | Ethicon, Inc. | Crystalline p-dioxanone/glycolide copolymers and surgical devices made therefrom |
US4744365A (en) * | 1986-07-17 | 1988-05-17 | United States Surgical Corporation | Two-phase compositions for absorbable surgical devices |
US4705820A (en) * | 1986-09-05 | 1987-11-10 | American Cyanamid Company | Surgical suture coating |
US4788979A (en) * | 1986-09-23 | 1988-12-06 | American Cyanamid Company | Bioabsorbable coating for a surgical article |
ES2040719T3 (en) * | 1986-09-23 | 1993-11-01 | American Cyanamid Company | BIO-ABSORBABLE COATING FOR A SURGICAL ARTICLE. |
US4916207A (en) * | 1987-12-17 | 1990-04-10 | Allied-Signal, Inc. | Polycarbonate homopolymer-based fiber compositions and method of melt-spinning same and device |
US5066772A (en) * | 1987-12-17 | 1991-11-19 | Allied-Signal Inc. | Medical devices fabricated totally or in part from copolymers of recurring units derived from cyclic carbonates and lactides |
US4891263A (en) * | 1987-12-17 | 1990-01-02 | Allied-Signal Inc. | Polycarbonate random copolymer-based fiber compositions and method of melt-spinning same and device |
US5120802A (en) * | 1987-12-17 | 1992-06-09 | Allied-Signal Inc. | Polycarbonate-based block copolymers and devices |
US4920203A (en) * | 1987-12-17 | 1990-04-24 | Allied-Signal Inc. | Medical devices fabricated from homopolymers and copolymers having recurring carbonate units |
US5145945A (en) * | 1987-12-17 | 1992-09-08 | Allied-Signal Inc. | Homopolymers and copolymers having recurring carbonate units |
US5152781A (en) * | 1987-12-17 | 1992-10-06 | Allied-Signal Inc. | Medical devices fabricated from homopolymers and copolymers having recurring carbonate units |
US5185408A (en) * | 1987-12-17 | 1993-02-09 | Allied-Signal Inc. | Medical devices fabricated totally or in part from copolymers of recurring units derived from cyclic carbonates and lactides |
US4916193A (en) * | 1987-12-17 | 1990-04-10 | Allied-Signal Inc. | Medical devices fabricated totally or in part from copolymers of recurring units derived from cyclic carbonates and lactides |
US4838267A (en) * | 1988-02-12 | 1989-06-13 | Ethicon, Inc. | Glycolide/p-dioxanone block copolymers |
US5007923A (en) * | 1990-01-31 | 1991-04-16 | Ethicon, Inc. | Crystalline copolyesters of amorphous (lactide/glycolide) and p-dioxanone |
US5133739A (en) * | 1990-02-06 | 1992-07-28 | Ethicon, Inc. | Segmented copolymers of ε-caprolactone and glycolide |
US5037950A (en) * | 1990-02-09 | 1991-08-06 | Ethicon, Inc. | Bioabsorbable copolymers of polyalkylene carbonate/RHO-dioxanone for sutures and coatings |
US5080665A (en) * | 1990-07-06 | 1992-01-14 | American Cyanamid Company | Deformable, absorbable surgical device |
US5252701A (en) * | 1990-07-06 | 1993-10-12 | American Cyanamid Company | Segmented absorbable copolymer |
US5225520A (en) * | 1991-04-17 | 1993-07-06 | United States Surgical Corporation | Absorbable composition |
US5236444A (en) * | 1992-10-27 | 1993-08-17 | United States Surgical Corporation | Absorbable polymers and surgical articles made therefrom |
US5322925A (en) * | 1992-10-30 | 1994-06-21 | United States Surgical Corporation | Absorbable block copolymers and surgical articles made therefrom |
-
1994
- 1994-03-02 US US08/204,721 patent/US5403347A/en not_active Expired - Lifetime
- 1994-05-02 CA CA002122670A patent/CA2122670C/en not_active Expired - Lifetime
- 1994-05-25 ES ES94108086T patent/ES2115802T3/en not_active Expired - Lifetime
- 1994-05-25 EP EP94108086A patent/EP0626404B1/en not_active Expired - Lifetime
- 1994-05-25 DE DE69408897T patent/DE69408897T2/en not_active Expired - Lifetime
- 1994-05-25 JP JP11114994A patent/JP3251768B2/en not_active Expired - Fee Related
- 1994-05-26 AU AU63361/94A patent/AU675522B2/en not_active Expired
-
1995
- 1995-01-26 US US08/378,754 patent/US5554170A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0626404A3 (en) | 1995-04-12 |
JPH072993A (en) | 1995-01-06 |
AU675522B2 (en) | 1997-02-06 |
DE69408897T2 (en) | 1998-07-30 |
EP0626404B1 (en) | 1998-03-11 |
US5554170A (en) | 1996-09-10 |
AU6336194A (en) | 1994-12-01 |
JP3251768B2 (en) | 2002-01-28 |
US5403347A (en) | 1995-04-04 |
DE69408897D1 (en) | 1998-04-16 |
ES2115802T3 (en) | 1998-07-01 |
CA2122670C (en) | 2001-04-17 |
EP0626404A2 (en) | 1994-11-30 |
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