CA2114147A1 - Film materials based on multi-layer blown microfibers - Google Patents
Film materials based on multi-layer blown microfibersInfo
- Publication number
- CA2114147A1 CA2114147A1 CA002114147A CA2114147A CA2114147A1 CA 2114147 A1 CA2114147 A1 CA 2114147A1 CA 002114147 A CA002114147 A CA 002114147A CA 2114147 A CA2114147 A CA 2114147A CA 2114147 A1 CA2114147 A1 CA 2114147A1
- Authority
- CA
- Canada
- Prior art keywords
- film materials
- materials based
- blown microfibers
- layer blown
- microfibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001410 Microfiber Polymers 0.000 title abstract 2
- 239000003658 microfiber Substances 0.000 title abstract 2
- 239000000463 material Substances 0.000 title 1
- 230000005540 biological transmission Effects 0.000 abstract 1
- 239000013536 elastomeric material Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/098—Melt spinning methods with simultaneous stretching
- D01D5/0985—Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/56—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/903—Microfiber, less than 100 micron diameter
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/914—Transfer or decalcomania
- Y10S428/915—Fraud or tamper detecting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/916—Fraud or tamper detecting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2738—Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith
- Y10T442/2754—Pressure-sensitive adhesive
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
- Y10T442/614—Strand or fiber material specified as having microdimensions [i.e., microfiber]
- Y10T442/625—Autogenously bonded
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
- Y10T442/614—Strand or fiber material specified as having microdimensions [i.e., microfiber]
- Y10T442/626—Microfiber is synthetic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/68—Melt-blown nonwoven fabric
Abstract
An extensible transparent film is provided having a continuous phase of a low modules or elastomeric material and an in-cluded affray of entangled microfibers. The film turns opaque and increases moisture vapor transmission when stretched.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/768,174 US5190812A (en) | 1991-09-30 | 1991-09-30 | Film materials based on multi-layer blown microfibers |
US07/768,174 | 1991-09-30 | ||
PCT/US1992/006672 WO1993007319A1 (en) | 1991-09-30 | 1992-08-11 | Film materials based on multi-layer blown microfibers |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2114147A1 true CA2114147A1 (en) | 1993-04-15 |
CA2114147C CA2114147C (en) | 2003-12-16 |
Family
ID=25081765
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002114147A Expired - Fee Related CA2114147C (en) | 1991-09-30 | 1992-08-11 | Film materials based on multi-layer blown microfibers |
Country Status (7)
Country | Link |
---|---|
US (1) | US5190812A (en) |
EP (1) | EP0606237B1 (en) |
JP (1) | JP3345418B2 (en) |
KR (1) | KR100220280B1 (en) |
CA (1) | CA2114147C (en) |
DE (1) | DE69207422T2 (en) |
WO (1) | WO1993007319A1 (en) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5514470A (en) * | 1988-09-23 | 1996-05-07 | Kimberly-Clark Corporation | Composite elastic necked-bonded material |
US5051241A (en) * | 1988-11-18 | 1991-09-24 | Pfefferle William C | Microlith catalytic reaction system |
US5238733A (en) * | 1991-09-30 | 1993-08-24 | Minnesota Mining And Manufacturing Company | Stretchable nonwoven webs based on multi-layer blown microfibers |
JP3134959B2 (en) * | 1992-03-17 | 2001-02-13 | チッソ株式会社 | Composite melt blow spinneret |
FR2704179B1 (en) * | 1993-04-19 | 1996-09-20 | Guial Sa | COMPOSITE PLANAR MATERIAL COMPRISING A PERFORATED FILM AND THERMOPLASTIC FIBERS, USE AND METHOD OF MANUFACTURE. |
FR2704244B1 (en) * | 1993-04-19 | 1995-07-13 | Guial | COMPOSITE PLANAR MATERIAL COMPRISING A FILM AND THERMOPLASTIC FIBERS, USE AND METHOD OF MANUFACTURE. |
CA2116081C (en) | 1993-12-17 | 2005-07-26 | Ann Louise Mccormack | Breathable, cloth-like film/nonwoven composite |
US5707468A (en) * | 1994-12-22 | 1998-01-13 | Kimberly-Clark Worldwide, Inc. | Compaction-free method of increasing the integrity of a nonwoven web |
WO1996026697A1 (en) | 1995-02-28 | 1996-09-06 | Tredegar Industries, Inc. | Three-dimensional film formed by melt bonding fibers on the surface of a polymeric film |
US6066221A (en) * | 1997-06-17 | 2000-05-23 | Kimberly-Clark Worldwide, Inc. | Method of using zoned hot air knife |
US6133173A (en) * | 1997-12-01 | 2000-10-17 | 3M Innovative Properties Company | Nonwoven cohesive wrap |
US6102039A (en) | 1997-12-01 | 2000-08-15 | 3M Innovative Properties Company | Molded respirator containing sorbent particles |
USH1927H (en) * | 1998-03-03 | 2000-12-05 | Tredegar Corporation | Embossed monolithic polymer film and process of forming the same |
US6395376B1 (en) | 1999-01-22 | 2002-05-28 | 3M Innovative Properties Company | Tamper indicating adhesive device |
US6273938B1 (en) | 1999-08-13 | 2001-08-14 | 3M Innovative Properties Company | Channel flow filter |
US6416857B1 (en) * | 2000-10-25 | 2002-07-09 | 3M Innovative Properties Company | Tamper indicating device |
JP2006524364A (en) * | 2003-04-21 | 2006-10-26 | スリーエム イノベイティブ プロパティズ カンパニー | Tamper indicating device and method for protecting information |
WO2005083240A1 (en) * | 2004-02-23 | 2005-09-09 | Donaldson Company, Inc. | Crankcase ventilation filter |
US8057567B2 (en) | 2004-11-05 | 2011-11-15 | Donaldson Company, Inc. | Filter medium and breather filter structure |
RU2389529C2 (en) * | 2004-11-05 | 2010-05-20 | Дональдсон Компани, Инк. | Filtration material (versions) and method of filtration (versions) |
US8021457B2 (en) | 2004-11-05 | 2011-09-20 | Donaldson Company, Inc. | Filter media and structure |
JP4642861B2 (en) * | 2004-12-20 | 2011-03-02 | エスセーアー・ハイジーン・プロダクツ・アーベー | Absorbent article with one or more patterns |
WO2006068542A1 (en) * | 2004-12-20 | 2006-06-29 | Sca Hygiene Products Ab | Absorbent article comprising one or several visible patterns |
WO2006084282A2 (en) | 2005-02-04 | 2006-08-10 | Donaldson Company, Inc. | Aerosol separator |
WO2006091594A1 (en) | 2005-02-22 | 2006-08-31 | Donaldson Company, Inc. | Aerosol separator |
EP2117674A1 (en) * | 2007-02-22 | 2009-11-18 | Donaldson Company, Inc. | Filter element and method |
WO2008103821A2 (en) * | 2007-02-23 | 2008-08-28 | Donaldson Company, Inc. | Formed filter element |
US8673040B2 (en) | 2008-06-13 | 2014-03-18 | Donaldson Company, Inc. | Filter construction for use with air in-take for gas turbine and methods |
US20100266824A1 (en) * | 2009-04-21 | 2010-10-21 | Alistair Duncan Westwood | Elastic Meltblown Laminate Constructions and Methods for Making Same |
US8664129B2 (en) * | 2008-11-14 | 2014-03-04 | Exxonmobil Chemical Patents Inc. | Extensible nonwoven facing layer for elastic multilayer fabrics |
US9168718B2 (en) | 2009-04-21 | 2015-10-27 | Exxonmobil Chemical Patents Inc. | Method for producing temperature resistant nonwovens |
US20100266818A1 (en) * | 2009-04-21 | 2010-10-21 | Alistair Duncan Westwood | Multilayer Composites And Apparatuses And Methods For Their Making |
US10161063B2 (en) * | 2008-09-30 | 2018-12-25 | Exxonmobil Chemical Patents Inc. | Polyolefin-based elastic meltblown fabrics |
US9498932B2 (en) * | 2008-09-30 | 2016-11-22 | Exxonmobil Chemical Patents Inc. | Multi-layered meltblown composite and methods for making same |
US8267681B2 (en) | 2009-01-28 | 2012-09-18 | Donaldson Company, Inc. | Method and apparatus for forming a fibrous media |
JP5650138B2 (en) * | 2009-02-27 | 2015-01-07 | エクソンモービル・ケミカル・パテンツ・インク | Multilayer nonwoven in situ laminate and method for producing the same |
US8668975B2 (en) * | 2009-11-24 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Fabric with discrete elastic and plastic regions and method for making same |
EP3161198A4 (en) * | 2014-06-27 | 2018-03-07 | 3M Innovative Properties Company | Thermally stable meltblown web comprising multilayer fibers |
US10676614B2 (en) | 2016-04-20 | 2020-06-09 | Clarcor Inc. | High molecular and low molecular weight fine fibers and TPU fine fibers |
US20170306563A1 (en) * | 2016-04-20 | 2017-10-26 | Clarcor Inc. | Fine fiber pulp from spinning and wet laid filter media |
EP3445670B1 (en) * | 2016-04-22 | 2020-04-08 | JX Nippon Anci, Inc. | Tamper-evident mesh material and methods of manufacture therefor |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3480502A (en) * | 1965-11-22 | 1969-11-25 | Dow Chemical Co | Method of making christmas tinsel |
US3487505A (en) * | 1967-08-21 | 1970-01-06 | Dow Chemical Co | Laminates |
US3557265A (en) * | 1967-12-29 | 1971-01-19 | Dow Chemical Co | Method of extruding laminates |
US3841953A (en) * | 1970-12-31 | 1974-10-15 | Exxon Research Engineering Co | Nonwoven mats of thermoplastic blends by melt blowing |
US3849241A (en) * | 1968-12-23 | 1974-11-19 | Exxon Research Engineering Co | Non-woven mats by melt blowing |
US3759647A (en) * | 1969-04-10 | 1973-09-18 | Turner Alfrey Us | Apparatus for the preparation of multilayer plastic articles |
US3684601A (en) * | 1969-12-29 | 1972-08-15 | Phillips Petroleum Co | Method of producing a soft outer surface of fine denier fiber on a nonwoven fabric |
US3687589A (en) * | 1970-07-20 | 1972-08-29 | Dow Chemical Co | Apparatus for the controlled extrusion of multi-component synthetic resinous bodies |
CA1007015A (en) * | 1971-09-27 | 1977-03-22 | Walter J. Schrenk | Coextrusion apparatus |
US3825379A (en) * | 1972-04-10 | 1974-07-23 | Exxon Research Engineering Co | Melt-blowing die using capillary tubes |
US3971373A (en) * | 1974-01-21 | 1976-07-27 | Minnesota Mining And Manufacturing Company | Particle-loaded microfiber sheet product and respirators made therefrom |
US4103058A (en) * | 1974-09-20 | 1978-07-25 | Minnesota Mining And Manufacturing Company | Pillowed web of blown microfibers |
US4197069A (en) * | 1976-05-21 | 1980-04-08 | Peter Cloeren | Variable thickness extrusion die |
CA1073648A (en) * | 1976-08-02 | 1980-03-18 | Edward R. Hauser | Web of blended microfibers and crimped bulking fibers |
DE2936905A1 (en) * | 1979-09-12 | 1981-04-02 | Toa Nenryo Kogyo K.K., Tokyo | Extrusion head for nonwoven fabrics - has triangular nozzle piece associated with slots for gas, contg. adjustable spacers |
US4375718A (en) * | 1981-03-12 | 1983-03-08 | Surgikos, Inc. | Method of making fibrous electrets |
US4429001A (en) * | 1982-03-04 | 1984-01-31 | Minnesota Mining And Manufacturing Company | Sheet product containing sorbent particulate material |
US4729371A (en) * | 1983-10-11 | 1988-03-08 | Minnesota Mining And Manufacturing Company | Respirator comprised of blown bicomponent fibers |
US4755178A (en) * | 1984-03-29 | 1988-07-05 | Minnesota Mining And Manufacturing Company | Sorbent sheet material |
US4720415A (en) * | 1985-07-30 | 1988-01-19 | Kimberly-Clark Corporation | Composite elastomeric material and process for making the same |
US4669163A (en) * | 1985-12-12 | 1987-06-02 | Minnesota Mining And Manufacturing Company | Polyolefin fiber roll |
US4818463A (en) * | 1986-04-26 | 1989-04-04 | Buehning Peter G | Process for preparing non-woven webs |
US4781296A (en) * | 1987-05-26 | 1988-11-01 | Minnesota Mining And Manufacturing Company | Method affording an easy opening device for nonwoven thermoplastic fiber envelopes |
US4929492A (en) * | 1987-07-24 | 1990-05-29 | Minnesota Mining And Manufacturing Company | Stretchable insulating fabric |
US4939016A (en) * | 1988-03-18 | 1990-07-03 | Kimberly-Clark Corporation | Hydraulically entangled nonwoven elastomeric web and method of forming the same |
AU609963B2 (en) * | 1988-05-13 | 1991-05-09 | Minnesota Mining And Manufacturing Company | Elastomeric adhesive and cohesive materials |
US4876123A (en) * | 1988-06-27 | 1989-10-24 | Minnesota Mining And Manufacturing Company | Tamper indicating tape and delaminating film therefore |
US4986743A (en) * | 1989-03-13 | 1991-01-22 | Accurate Products Co. | Melt blowing die |
US5073423A (en) * | 1990-01-04 | 1991-12-17 | Corning Incorporated | Decalcomania |
-
1991
- 1991-09-30 US US07/768,174 patent/US5190812A/en not_active Expired - Lifetime
-
1992
- 1992-08-11 JP JP50686593A patent/JP3345418B2/en not_active Expired - Fee Related
- 1992-08-11 WO PCT/US1992/006672 patent/WO1993007319A1/en active IP Right Grant
- 1992-08-11 KR KR1019940700990A patent/KR100220280B1/en not_active IP Right Cessation
- 1992-08-11 EP EP92917975A patent/EP0606237B1/en not_active Expired - Lifetime
- 1992-08-11 DE DE69207422T patent/DE69207422T2/en not_active Expired - Fee Related
- 1992-08-11 CA CA002114147A patent/CA2114147C/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP0606237A1 (en) | 1994-07-20 |
CA2114147C (en) | 2003-12-16 |
EP0606237B1 (en) | 1996-01-03 |
US5190812A (en) | 1993-03-02 |
JP3345418B2 (en) | 2002-11-18 |
JPH06511037A (en) | 1994-12-08 |
DE69207422T2 (en) | 1996-05-15 |
KR100220280B1 (en) | 1999-09-15 |
DE69207422D1 (en) | 1996-02-15 |
WO1993007319A1 (en) | 1993-04-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |