CA2113261A1 - Chemical Treating Composition for Glass Fibers Having Emulsified Epoxy with Good Stability and the Treated Glass Fibers - Google Patents

Chemical Treating Composition for Glass Fibers Having Emulsified Epoxy with Good Stability and the Treated Glass Fibers

Info

Publication number
CA2113261A1
CA2113261A1 CA2113261A CA2113261A CA2113261A1 CA 2113261 A1 CA2113261 A1 CA 2113261A1 CA 2113261 A CA2113261 A CA 2113261A CA 2113261 A CA2113261 A CA 2113261A CA 2113261 A1 CA2113261 A1 CA 2113261A1
Authority
CA
Canada
Prior art keywords
surfactant
glass fibers
utilized
static
sizing composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2113261A
Other languages
French (fr)
Other versions
CA2113261C (en
Inventor
Michael W. Klett
Kenneth D. Beer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Ohio Inc
Original Assignee
Michael W. Klett
Kenneth D. Beer
Ppg Industries, Inc.
Ppg Industries Ohio, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michael W. Klett, Kenneth D. Beer, Ppg Industries, Inc., Ppg Industries Ohio, Inc. filed Critical Michael W. Klett
Publication of CA2113261A1 publication Critical patent/CA2113261A1/en
Application granted granted Critical
Publication of CA2113261C publication Critical patent/CA2113261C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24S—SOLAR HEAT COLLECTORS; SOLAR HEAT SYSTEMS
    • F24S80/00—Details, accessories or component parts of solar heat collectors not provided for in groups F24S10/00-F24S70/00
    • F24S80/50—Elements for transmitting incoming solar rays and preventing outgoing heat radiation; Transparent coverings
    • F24S80/52—Elements for transmitting incoming solar rays and preventing outgoing heat radiation; Transparent coverings characterised by the material
    • F24S80/525—Elements for transmitting incoming solar rays and preventing outgoing heat radiation; Transparent coverings characterised by the material made of plastics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/2938—Coating on discrete and individual rods, strands or filaments

Abstract

A simplified aqueous sizing composition utilizing a variety of components achieves improved stability, wettability and strength characteristics. The composition utilizes one or more aqueous, soluble, dispersible or emulsifiable bisphenol A type polyester film forming polymers with an epoxy containing film forming copolymer compatible with and soluble in the matrix polymer. One or more organo-silane coupling agents are also utilized. The sizing composition preferably includes a single nonionic surfactant in conjunction with a cationic amidated polyamine lubricant. One or more anti-static agents, generally cationic organic quaternary ammonium salts having one or more alkoxy moieties, are utilized in an effective anti-static amount. An anti-foaming agent may also be utilized for the prevention or suppression of foam during the mixing process. The improved stability and wettability characteristics of the aqueous sizing composition are preferably achieve through the use of a single epoxidized surfactant.
Compositions formed from this surfactant are effective at one-half the surfactant level and retain their static emulsion stability for 48 hours or more. This is accompanied by a 50 percent improvement in dry sliver abrasion with no apparent negative effects on the mechanical properties of the resultant glass fiber. Figure shows the particle size of four sizing compositions each with a different epoxy emulsion having a given amount of the surfactant.
CA002113261A 1991-07-12 1992-07-09 Chemical treating composition for glass fibers having emulsified epoxy with good stability and the treated glass fibers Expired - Fee Related CA2113261C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/729,255 US5242958A (en) 1991-07-12 1991-07-12 Chemical treating composition for glass fibers having emulsified epoxy with good stability and the treated glass fibers
US729,255 1991-07-12
PCT/US1992/005762 WO1993001235A1 (en) 1991-07-12 1992-07-09 Chemical treating composition for glass fibers having emulsified epoxy with good stability and the treated glass fibers

Publications (2)

Publication Number Publication Date
CA2113261A1 true CA2113261A1 (en) 1993-01-21
CA2113261C CA2113261C (en) 2000-03-14

Family

ID=24930235

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002113261A Expired - Fee Related CA2113261C (en) 1991-07-12 1992-07-09 Chemical treating composition for glass fibers having emulsified epoxy with good stability and the treated glass fibers

Country Status (7)

Country Link
US (2) US5242958A (en)
EP (1) EP0593647B1 (en)
JP (1) JP2872407B2 (en)
CA (1) CA2113261C (en)
DE (1) DE69222771T2 (en)
ES (1) ES2110005T3 (en)
WO (1) WO1993001235A1 (en)

Families Citing this family (35)

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FR2686828A1 (en) * 1992-01-30 1993-08-06 Vetrotex France Sa PROCESS FOR OBTAINING A COMPOSITE PRODUCT BY MOLDING.
US5605757A (en) * 1994-01-27 1997-02-25 Ppg Industries, Inc. Glass fiber sizing compositions, sized glass fibers and methods of reinforcing polymeric materials using the same
US5672641A (en) * 1995-01-23 1997-09-30 Ppg Industries, Inc. Secondary coating compositions for glass fibers, glass fibers coated with the same and composites reinforced therewith
US5919331A (en) * 1997-04-25 1999-07-06 Federal-Mogul World Wide, Inc. Adhesive for bonding elastomers to metals
US6225389B1 (en) * 1998-08-20 2001-05-01 Henkel Corp. Screen coating composition and method for applying same
GB9902976D0 (en) * 1999-02-11 1999-03-31 Giltech Ltd Composite
TR200103402T2 (en) * 1999-05-28 2002-04-22 Bayer Aktiegesellscheft Sizing composition, boiled glass fibers and their use
US6365272B1 (en) 1999-12-29 2002-04-02 Owens Corning Fiberglas Technology, Inc. System for preparing glass fiber pellets having low discoloration
JP4576692B2 (en) * 2000-10-02 2010-11-10 日東紡績株式会社 Glass fiber sizing agent, glass fiber bundle coated with the sizing agent, and phenol resin containing the glass fiber bundle
FR2826359B1 (en) 2001-06-21 2004-05-07 Saint Gobain Vetrotex SIZED GLASS WIRES, SIZING COMPOSITION AND COMPOSITES COMPRISING SAID WIRES
US7291390B2 (en) * 2003-11-07 2007-11-06 Ppg Industries Ohio, Inc. Sizing composition for glass fibers and sized fiber glass products
FR2864073B1 (en) * 2003-12-17 2006-03-31 Saint Gobain Vetrotex QUICK-IMPREGNATED ENSIMES GLASS YARNS FOR REINFORCING POLYMERIC MATERIALS
US8129018B2 (en) * 2004-06-18 2012-03-06 Ocv Intellectual Capital, Llc Sizing for high performance glass fibers and composite materials incorporating same
US20070082199A1 (en) * 2005-10-11 2007-04-12 Schweizer Robert A Fiber size, sized reinforcements, and articles reinforced with such reinforcements
US7709599B2 (en) * 2005-10-12 2010-05-04 Ppg Industries Ohio, Inc. Compounds, rosins, and sizing compositions
WO2007050467A1 (en) * 2005-10-24 2007-05-03 Ocv Intellectual Capital, Llc Long fiber thermoplastic process for conductive composites and composites formed thereby
WO2007074743A1 (en) * 2005-12-28 2007-07-05 Ocv Intellectual Capital, Llc Chopped strand and fiber-reinforced crystalline polyester resin molding material containing the same
US20120100784A1 (en) * 2006-09-15 2012-04-26 Saint-Gobain Abrasifs Microfiber Reinforcement for Abrasive Tools
US8808412B2 (en) * 2006-09-15 2014-08-19 Saint-Gobain Abrasives, Inc. Microfiber reinforcement for abrasive tools
CN101100355B (en) * 2007-06-12 2011-07-06 巨石集团有限公司 Soaking agent capable of increasing glass fiber acid resistance
US8791203B2 (en) * 2011-12-22 2014-07-29 Johns Manville Sizing compositions and sized products for thermoplastic composites
CN101659781A (en) * 2008-08-27 2010-03-03 东丽纤维研究所（中国）有限公司 Epoxy resin micro-particle, dispersion liquid and method for preparing same
JP5747696B2 (en) * 2011-07-08 2015-07-15 セントラル硝子株式会社 Unsaturated polyester resin moldings reinforced with glass fiber
JP5533850B2 (en) * 2011-12-05 2014-06-25 東レ株式会社 Prepreg and carbon fiber reinforced composites
JP5578164B2 (en) * 2011-12-05 2014-08-27 東レ株式会社 Molding material, carbon fiber reinforced composite material, and method for producing molding material
MX349437B (en) 2011-10-04 2017-07-28 Toray Industries Carbon fiber-reinforced thermoplastic resin composition, molding material, prepreg, and methods for producing same.
JP5316618B2 (en) * 2011-10-04 2013-10-16 東レ株式会社 Carbon fiber reinforced thermoplastic resin composition and molded article
JP5578163B2 (en) * 2011-12-05 2014-08-27 東レ株式会社 Molding material, carbon fiber reinforced composite material, and method for producing molding material
JP5533849B2 (en) * 2011-12-05 2014-06-25 東レ株式会社 Molding materials and carbon fiber reinforced composite materials
DE102013018088B4 (en) * 2013-02-10 2017-01-26 Karim El Kudsi Epoxy-based coatings and a process for their preparation and their uses
JP5327405B1 (en) * 2013-05-17 2013-10-30 東レ株式会社 Carbon fiber reinforced thermoplastic resin composition and molded article
JP5327406B2 (en) * 2013-05-17 2013-10-30 東レ株式会社 Carbon fiber reinforced thermoplastic resin composition and molded article
KR102190010B1 (en) * 2013-09-27 2020-12-11 마쓰모토유시세이야쿠 가부시키가이샤 Sizing agent for reinforcing fiber and application therefor
MX2017010964A (en) * 2015-02-27 2017-10-20 3M Innovative Properties Co Polyamide composition including hollow glass microspheres and articles and methods relating to the same.
EP3700872B1 (en) 2017-10-27 2024-02-07 Owens Corning Intellectual Capital, LLC Sizing compositions including weakly-coordinating anion salts and uses thereof

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3827230A (en) * 1970-04-13 1974-08-06 Owens Corning Fiberglass Corp Glass fiber size
JPS5319713B2 (en) * 1973-06-27 1978-06-22
US3983056A (en) * 1973-09-27 1976-09-28 Dai Nippon Toryo Co., Ltd. Aqueous epoxy resin paint composition
US4049597A (en) * 1974-10-09 1977-09-20 Ppg Industries, Inc. Glass fiber sizing composition
US4315044A (en) * 1980-11-05 1982-02-09 Celanese Corporation Stable aqueous epoxy dispersions
US4394418A (en) * 1981-12-24 1983-07-19 Ppg Industries, Inc. Aqueous sizing composition and glass fibers made therewith for reinforcing thermosetting polymers
US4436848A (en) * 1983-04-12 1984-03-13 Owens-Corning Fiberglas Corporation Aqueous co-emulsions of epoxy resin and mineral oil
US4487797A (en) * 1983-12-01 1984-12-11 Ppg Industries, Inc. Glass fibers to reinforce polymeric materials
US4752527A (en) * 1985-06-25 1988-06-21 Ppg Industries, Inc. Chemically treated glass fibers for reinforcing polymeric materials processes
US4808478A (en) * 1986-09-05 1989-02-28 Ppg Industries, Inc. Chemically treated glass fibers for reinforcing thermosetting polymers
US4981754A (en) * 1988-06-20 1991-01-01 Owens-Corning Fiberglas Corporation Glass fibers having a size composition containing the reaction product of an acid and/or alcohol with the terminal epoxy groups of a diglycidyl ether of a bisphenol
US4990549A (en) * 1989-10-16 1991-02-05 General Electric Company Glass fiber reinforced polyester molding compound with improved physical strength properties

Also Published As

Publication number Publication date
CA2113261C (en) 2000-03-14
WO1993001235A1 (en) 1993-01-21
EP0593647A1 (en) 1994-04-27
DE69222771D1 (en) 1997-11-20
EP0593647A4 (en) 1995-06-14
JPH07505658A (en) 1995-06-22
DE69222771T2 (en) 1998-04-23
US5242958A (en) 1993-09-07
EP0593647B1 (en) 1997-10-15
ES2110005T3 (en) 1998-02-01
JP2872407B2 (en) 1999-03-17
US5604270A (en) 1997-02-18

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