CA2105119A1 - Solid titanium catalyst component for olefin polymerization, process forpreparing the same, catalyst for olefin polymerization and process for olefin polymerization - Google Patents

Solid titanium catalyst component for olefin polymerization, process forpreparing the same, catalyst for olefin polymerization and process for olefin polymerization

Info

Publication number
CA2105119A1
CA2105119A1 CA2105119A CA2105119A CA2105119A1 CA 2105119 A1 CA2105119 A1 CA 2105119A1 CA 2105119 A CA2105119 A CA 2105119A CA 2105119 A CA2105119 A CA 2105119A CA 2105119 A1 CA2105119 A1 CA 2105119A1
Authority
CA
Canada
Prior art keywords
olefin polymerization
catalyst component
catalyst
solid titanium
olefin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA2105119A
Other languages
French (fr)
Other versions
CA2105119C (en
Inventor
Tetsuya Toida
Tetsunori Shinozaki
Mamoru Kioka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Tetsuya Toida
Tetsunori Shinozaki
Mamoru Kioka
Mitsui Petrochemical Industries, Ltd.
Mitsui Chemicals, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tetsuya Toida, Tetsunori Shinozaki, Mamoru Kioka, Mitsui Petrochemical Industries, Ltd., Mitsui Chemicals, Inc. filed Critical Tetsuya Toida
Publication of CA2105119A1 publication Critical patent/CA2105119A1/en
Application granted granted Critical
Publication of CA2105119C publication Critical patent/CA2105119C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

A solid titanium catalyst component comprising (a) magnesium, (b) titanium, (c) a halogen, (d) a polyether, (e) a hydrocarbon and (f) an electron donor other than the polyether (d) as essential components is provided. Also a process for preparing a solid titanium catalyst component for olefin polymerization, comprising the steps of contacting a halogenated magnesium compound with a compound selected from the group consisting of an alcohol, an ether and an ester in a hydrocarbon solvent to obtain a magnesium compound solution, contacting the magnesium compound solution with a polyether and contacting the resultant solution with a liquid titanium compound is provided.
Further, a catalyst for olefin polymerization comprising the above-mentioned solid titanium catalyst component, an organoaluminum compound catalyst component and an electron donor, and a process for polymerizing an olefin using the catalyst for olefin polymerization are also disclosed. By the use of the catalyst for olefin polymerization, an olefin (co) polymer having uniform particle size, less dust quantity, high bulk density and high stereoregularity can be obtained with excellent polymerization activity.
CA002105119A 1992-08-31 1993-08-30 Solid titanium catalyst component for olefin polymerization, process forpreparing the same, catalyst for olefin polymerization and process for olefin polymerization Expired - Fee Related CA2105119C (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP23173292 1992-08-31
JP231732/1992 1992-08-31
JP75513/1993 1993-04-01
JP7551393 1993-04-01
JP206345/1993 1993-08-20
JP20634593A JP3280477B2 (en) 1992-08-31 1993-08-20 Method for preparing solid titanium catalyst component for olefin polymerization

Publications (2)

Publication Number Publication Date
CA2105119A1 true CA2105119A1 (en) 1994-03-01
CA2105119C CA2105119C (en) 1998-08-25

Family

ID=27301856

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002105119A Expired - Fee Related CA2105119C (en) 1992-08-31 1993-08-30 Solid titanium catalyst component for olefin polymerization, process forpreparing the same, catalyst for olefin polymerization and process for olefin polymerization

Country Status (12)

Country Link
US (2) US5780378A (en)
EP (1) EP0585869B1 (en)
JP (1) JP3280477B2 (en)
KR (1) KR0142072B1 (en)
CN (1) CN1036344C (en)
CA (1) CA2105119C (en)
CZ (1) CZ281529B6 (en)
DE (1) DE69311033T2 (en)
HU (1) HU217647B (en)
RO (1) RO112185B1 (en)
TW (1) TW280823B (en)
YU (1) YU48557B (en)

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KR100387734B1 (en) 2000-06-17 2003-06-18 삼성종합화학주식회사 Catalyst and process for polymerization of olefin
CN1519263A (en) * 2000-07-03 2004-08-11 三井化学株式会社 Solid Ti catalyst, process for prepn. of alpha-olefine polymer or copolyer and polymer or copolymer made therefrom
KR100389475B1 (en) 2000-11-09 2003-06-27 삼성종합화학주식회사 Preparation method of catalyst for ethylene polymeration or copolymeration
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BRPI0416482B1 (en) 2003-11-14 2020-12-01 Polimeri Europa S.P.A. solid catalyst component for the (co) polymerization of ethylene, process for the preparation of a solid component, and, catalyst and process for the (co) polymerization of ethylene
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Also Published As

Publication number Publication date
HU9302459D0 (en) 1993-11-29
EP0585869B1 (en) 1997-05-28
DE69311033T2 (en) 1997-10-16
CN1087094A (en) 1994-05-25
YU57193A (en) 1996-02-19
CZ281529B6 (en) 1996-10-16
TW280823B (en) 1996-07-11
US5877265A (en) 1999-03-02
US5780378A (en) 1998-07-14
CN1036344C (en) 1997-11-05
JP3280477B2 (en) 2002-05-13
EP0585869A1 (en) 1994-03-09
KR0142072B1 (en) 1998-07-01
KR940003972A (en) 1994-03-14
RO112185B1 (en) 1997-06-30
JPH06336503A (en) 1994-12-06
HUT68333A (en) 1995-06-28
DE69311033D1 (en) 1997-07-03
CA2105119C (en) 1998-08-25
YU48557B (en) 1998-11-05
CZ179093A3 (en) 1994-03-16
HU217647B (en) 2000-03-28

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