CA2099936A1

CA2099936A1 - Linerless labels with a silica/polyvinyl alcohol tie coat

Info

Publication number: CA2099936A1
Application number: CA 2099936
Authority: CA
Inventors: Nancy G. Mitchell; Joseph W. Langan; Adele C. Shipston; Timothy J. Russ; Douglas M. Smith
Original assignee: Moore Business Forms Inc
Current assignee: Moore Wallace North America Inc
Priority date: 1992-07-13
Filing date: 1993-07-06
Publication date: 1994-01-14
Also published as: US6129965A; JPH06222719A; AU4185993A; EP0579423B1; US5651852A; US5354588A; EP0579423A1; US5547738A; DE69309797D1; DE69309797T2; NZ248116A; JP2713856B2; AU662987B2

Abstract

ABSTRACT OF THE DISCLOSURE

Linerless label stock is produced from a single substrate utilizing a coating machine by moving the substrate through the coating machine and applying a tie coating to the substrate first face, a release coating to the substrate second face, and a pressure sensitive adhesive to the tie coating. The tie coating comprises a dispersion of a pigment, such as silica, with a binder, such as polyvinyl alcohol.
The substrate is cut to form individual labels, and is rolled up into a roll with the release coated second face on the outside of the roll. Printing may be applied to the substrate prior to coating, or to the release coating.

Description

-~` 2~9~3~

LlNERLESS LABELS WIT~I TIE COAT

BACKGROUND AND SUMMARY OF Th~ INVENTION

Linerless labels, such as shown in U.S. patents 3,051,588, 3,285,771, and 4,851,383, and in Canadian patent 1,248,412, are known to have advantages over conventional pressure sensitive labels which are mounted on a liner which has been coated with a release coating. In the conventional labels the liner acts as a support for transport, printing and storage, and after the label is removed from the liner it must be disposed of. A linerless label, on the other hand has the face coated with a release coating, and the back with a pressure sensitive adhesive (PSA), and is wound in a roll configuration so that the PSA is in contact with the release coating, and the release coating faces outwardly.
The linerless construction offers advantages and lower costs due to substantial material reduction, elimination of disposal concerns and costs associated with release coated liners, and in providing approximately twice as many labels per roll.
While linerless labels have numerous advantages, they have not had widespread commercial acceptance, perhaps due in part to impediments to easy and clean peeling off of the PSA from the release coating in the roll format. If the adhesion of the PSA to the substrate iF- not strong enough (and this Adhesion can degrade under time under some environmental conditions and materials), adhesive 2 ~

may stick to the release coating, or the substrate may be torn.
According to the present invention, a linerless label stock, and a method of ma~ing linerless labels, are provided which enhance the viability of linerless labels by providing a more secure adhesion of the PSA to the substrate than is typically provided in the prior art. According to the present invention a tie coat is provided which facilitates adherence of the PSA to a first face (the "back" ) of the substrate, the tie coat adhering to both the substrate first face and the PSA. The tie coat preferably comprises a dispersion of a pigment, such as æilica, with a binder, such as PVA. For example, the tie coat may consist essentially of about 30-40 parts silica dispersion, about 20-35 parts PVA, and about 30-40 water. Printing may be provided on the substrate first face, or may be applied onto the release coating by certain techniques.
According to the method of ma~ing linerless labels of the invention, a coating machine is utilized with a substrate having first and second faces. The method comprises the steps of: (a) Continuously moving the substrate in a first direction through the coating machine, and substantially sequentially: (b) ~ith the coating machine, applying in a predetermined sequence to the moving substrate a tie coating to the substrate first face, a release coating to the substrate second face, and a pressure sensitive adhesive to the tie coating. (c) Cutting the substrate to form individual labels. And, (d) rolling the substrate ~` 2 ~ 3 ~

into a roll, with the release coated second face on the outside of the roll.
In the practice of the method set forth above, the predetermined sequence of step (bj is preferably to apply the tie coating first, then the release coating, and then the pressure sensitive adhesive.
The cutting step may be die cutting, and drying at a rate much faster than ambient air drying may be practiced before steps (c) and (d), by hot air, infrared, or like drying technique.
It is the primary object of the present invention to provide an advantageous linerless label stock, and a simple yet effective method for making the stock. This and other objects of the invention will become clear from an inspection of the detailed description of the invention and from the appended claims.

BRIE~ DESCRIPTION O~ T~E DR~WINGS

FIGURE . is a cross-sectional view of exemplary linerless label ~tock according to the present invention showing each of the layers (with greatly exaggerated thickness);

FIGURE 2 is a side scllematic view showing exemplary apparatus for practicing an exemplary method of producing linerless 'abels according to the present invention: and FIGURES 3 and 4 are perspective views of exemplary rolls of linerless label stock of FIGURE
1, produced utilizing the appa-atus in FIGURE 2.

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,. .

An exemplary section of linerless label stock is shown generally by reference numeral 10 in FIGVRE
1. The stock l0 according to the invention comprise~ a substrate 11 having a first face 12 and a second face 13, The substrate may be any conventional substrate used in label applications, such as bond paper, latex-impregnated paper, vinyl, or polyester. The substrate is not a thermally sen~itive one.
Associated with the substrate 11 is a coating of pressure sensitive adhesive 14. The PSA may comprise any conventional formulation used in pressure sensitive adhesive applications, including solvent-base, water-base, hot melt or radiation curable formulations. Typical adhesive formulations are listed in the "HandbooX of Pressure-Sensitive Technology" by Donatas Satas, Van Nostrand Reinhold Company, 1983. Particularly desirable PSA comprises a water-based acrylic adhesive prepared by free radical polymerization of acrylic monomers ~either a homopolymer or a copolymer). For example the polymer may be made 70-100% of a soft monomer such as 2-ethylhexyl acrylate, 0-6% of functional monomer such as acrylic acid, and 0 to 30% of a hard monomer SUC}l a vinyl acetate.
According to the invention, adherence of the PSA 14 to th~ substrate 11 first face 12 is provided hy a tie coa.ing 15. The tie coating 1~ adheres to both the PSA and the substrate ll. It may comprise, or consist essentially of, a dispersion of a pigment, preferably silica, with a binder material, 2 ~ 3 ~

such as polyvinyl alcohol (PVA). For example the tie coating may comprise or consist essentially of about 30-40 parts silica dispersion, about 20-35 parts PVA, and 30-40 parts water.
On the second face 13 of the substrate 11, which may have printing thereon (see FIGURE 3), a release coat 16 is provided. The release coating 16 is of any suitable material that imparts a lower fiurface energy to the face 13, and has properties with respect to the PSA 14 so that it will release easily from the PSA 14; that is the PSA 14 will not stick to the release coating 16, while it has great affinity for the tie coating 1~. Typical release coatings are listed in chapters 17 and 18 of the Handbook of Pressure-Sensitive Adhesive Technology by Satas, referenced above. Preferred formulations include silicone resins and chrome complexes of fatty acids.
FIGURE 2 illustrates exemplary apparatus for producing linerless labels according to an exemplary method of the present invention. The substrate 11 is continuously moved in the direction of arrows 18. Printing may be applied to the second face 13, as with the conventional printer 20, which may be located prior to a coating machine 21, and drives for the substrate ll may be any conventional driving means, such as drive rollers 22.
In the single, conventional coating machine 21, all three of the coatings l~-16 are provided. For example a first roller or like applicator 24 applies the tie coating 15 to the first face 12, while shortly thereafter a second roller or applicator 2S
applies the release coating 16 to the second face : 6 13. A dryer 26, for effecting drying of the tie coating 15 much more quickly than by ambient air (e.g. a hot air dryer) so that the tie coat is dry by the time it reaches the third roller or other applicator 27, which applies the pressure sensitive adhesive 14 over the tie coat 15, on the face 12, is also provided. The preferred location of the printer 20 is after the dryer 26 but before the second applicator 27.
Drying of the PSA 14 and/or the release coat 16 may be provided by dryers 29, 30 downstream of the coating machine 21 in the direction of arrows 18, and after drying by the dryers 29, 30 (which effect drying m~lch quicker than ambient air, and may be hot air, infrared, or like conventional dryers depending upon the particular coatings); and after the stock 10 is dried, it is cut into labels by a conventional cutter 32. Then the stock is taken up in roll format 33 by take up mechanism 34, with the release coating 16 and second face 13 on the outside of the roll 33 that is being taken up, with the PSA 14 in contact with the release coating 16 in the spiral configuration of the roll 33.
Printing can also be performed (not shown) on the release ccat 16 (e.g. a hot melt ink, ink jet printer).
The labels can be formed from a web which, just prior to take up 34, is slit into the rolls 33, or the rolls 33 can be formed later, after take up.
~ IGURES 3 and 4 illustrate two different construction~ of rolls of linerless label. The roll 33 of FIGURE 3 has individual labels 36 thereof which have been cut, with less than complete 2 ~

severing ~e.g. by very fine perforations, or die cuts, indicated by cut lines 37 in FIGURE 3), generally transverse to the direction of elongation of the substrate 11 of the roll 33, with the sides 3~ of each la~el corresponding to the sides of the substrate 11. Each label 36 has a width and length typically less than one foot. In this construction there is no waste whatsoever but rather each label 36 is merely detached along a line 37 from the next quadrate label 36 in sequence.
FIGURE 4 illustrates a modified form of a roll 33' of linerless labels according to the invention.
In this embodiment, the cutter 32 effects complete die cutting of individual labels 36' out of the substrate, BO that the edges 38' thereof do not correspond to the side edges of the substrate. The labels 36' may have any shape (they need not be quadrate), but in this embodiment there is some waste material provided by the skeletal structure 40 of the substrate outside of the labels 36'.
The invention having been described in general terms, one specific example of a linerless label producible according to the invention is as follows:
Example A tie coat 15 was prepared according to the following formulation:
36 parts - 20% Cab-0-Sperse Il dispersion, Cabot Corp.
28 parts - 10% Polyvinyl Alcohol, Air Products & Chemicals (Partially Hydrolyzed) 36 parts - Water 9 ~ 3 PSA 14 was prepared according to the following formulation:
51 2 parts - 2% PVA 523, Air Products &
Chemicals 48.7 parts - 2-ethylhexyl acrylate (monomer) BASF
.002 parts - Benzoyl Peroxide (BP0), Lucidol division of Pennwalt A release coating 16 was prepared according to the following formulation:
15 parts - Qu lon C, Valcon 85 parts - Wa.er The tie coat i5 was applied to first face 12 with the applicato~ 24, the release coat 16 was applied to face 13 with the applicator 25, the tie coat was dried by .he dryer 26, the PSA was applied over the tie coat ~ with the applicator 27, and the entlre stock 10 wae dried by dryers 29, 30, and after cutting into labels 32 was self-wound in roll form 33 by winder ~.

It will thlls -~ seen that according to the present invention :inerless label stock, and a method of producti-n thereof, have been provided which in a simple .-et effective way provide easy to use labels, with n^ or little waste. While the invention has been :~erein shown and described in what is presently _onceived to be the moqt practical and preferred embo~iment, it will be apparent to those of ordinary ~Xill in the art that many modifications may .e made thereof within the scope 2~9~3~

of the invention, which scope is to be accorded the broadest interpretation of the appended claims so as to encompass all equivalent products and processes.

Claims

1. Linerless label stock, comprising:
a substrate having first and second faces;
a pressure sensitive adhesive;
a tie coat facilitating adherence of said pressure sensitive adhesive to said first face of said substrate, said tie coat adhering to both said substrate first face and said pressure sensitive adhesive; and a release coat, of material that has a low adherence to said pressure sensitive adhesive, on said second face of said substrate.

2. Stock as recited in claim 1 in a continuous, roll configuration, portions of said pressure sensitive adhesive rolled on top of portions of said release coating, with said release coating on the outside of the roll.

3. Stock as recited in claim 2 wherein said tie coating comprises a dispersion of a pigment with a binder.

4. Stock as recited in claim 3 wherein the pigment is silica.

5. Stock as recited in claim 4 wherein the binder is polyvinyl alcohol.

6. Stock as recited in claim 5 wherein said tie coating consists essentially of about 30-40 parts silica dispersion, about 20-35 parts polyvinyl alcohol, and about 30-40 parts water.

7. Stock as recited in claim 1 wherein said substrate is cut into individual quadrate labels having a width and length each less than one foot, the side edge of the substrate forming the side edges of the labels.

8. Stock as recited in claim 1 consisting essentially of said substrate, adhesive, tie coat, and release coat.

9. Stock as recited in claim 1 including printing on said substrate second face and/or said substrate.

10. Stock as recited in claim 1 wherein said tie coating comprises a dispersion of a pigment with a binder.

11. Stock as recited in claim 10 wherein the pigment is silica.

12. Stock as recited in claim 10 wherein the binder is polyvinyl alcohol.

13. Stock as recited in claim 10 wherein said tie coating consists essentially of about 30-40 parts silica dispersion, about 20-35 parts polyvinyl alcohol, and about 30-40 parts water.

14. A method of making linerless labels using a coating machine, and a substrate having first and second faces, comprising the steps of:
(a) continuously moving the substrate in a first direction through the coating machine; and substantially sequentially:
(b) with the coating machine, applying in a predetermined sequence to the moving substrate a tie coating to the substrate first face, a release coating to the substrate second face, and a pressure sensitive adhesive to the tie coating;
(c) cutting the substrate to form individual labels; and (d) rolling the substrate into a roll, with the release coated second face on the outside of the roll.

15. A method as recited in claim 14 wherein the predetermined sequence of step (b) is to apply the tie coating first, then the release coating, and then the pressure sensitive adhesive.

16. A method as recited in claim 14 comprising the further step of printing the second face of substrate prior to step (b).

17. A method as recited in claim 14 wherein step (c) is practiced by die cutting.

18. A method as recited in claim 14 wherein step (b) is practiced by applying a tie coat comprising a dispersion of a pigment with a binder.

19. A method as recited in claim 14 wherein step (b) is practiced by applying a tie coat consisting essentially of about 30-40 parts silica dispersion, about 20-35 parts polyvinyl alcohol, and about 30-40 parts water.

20. A method as recited in claim 14 comprising the further step of effecting drying of the coatings applied in step (b) much more quickly than the ambient air drying, and prior to step (c).