CA2088743A1 - Absorption of hydrogen sulfide and absorbent composition therefor - Google Patents
Absorption of hydrogen sulfide and absorbent composition thereforInfo
- Publication number
- CA2088743A1 CA2088743A1 CA2088743A CA2088743A CA2088743A1 CA 2088743 A1 CA2088743 A1 CA 2088743A1 CA 2088743 A CA2088743 A CA 2088743A CA 2088743 A CA2088743 A CA 2088743A CA 2088743 A1 CA2088743 A1 CA 2088743A1
- Authority
- CA
- Canada
- Prior art keywords
- hydrogen sulfide
- absorption
- absorbent composition
- composition therefor
- therefor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/104—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/304—Linear dimensions, e.g. particle shape, diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/311—Porosity, e.g. pore volume
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
- B01D2257/304—Hydrogen sulfide
Abstract
Hydrogen sulfide is removed from a gas by contacting it with an absorbent composition consisting essentially of a mixed oxide of iron, zinc and nickel and an inorganic binder.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/874,908 | 1992-04-28 | ||
US07/874,908 US5244641A (en) | 1992-04-28 | 1992-04-28 | Absorption of hydrogen sulfide and absorbent composition therefor |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2088743A1 true CA2088743A1 (en) | 1993-10-29 |
CA2088743C CA2088743C (en) | 2000-01-18 |
Family
ID=25364841
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002088743A Expired - Fee Related CA2088743C (en) | 1992-04-28 | 1993-02-03 | Absorption of hydrogen sulfide and absorbent composition therefor |
Country Status (11)
Country | Link |
---|---|
US (2) | US5244641A (en) |
EP (1) | EP0568003B1 (en) |
JP (1) | JP3009309B2 (en) |
AU (1) | AU648955B2 (en) |
CA (1) | CA2088743C (en) |
DE (1) | DE69312559T2 (en) |
ES (1) | ES2104997T3 (en) |
MX (1) | MX9302386A (en) |
NO (1) | NO300160B1 (en) |
SG (1) | SG59961A1 (en) |
ZA (1) | ZA932765B (en) |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5858912A (en) * | 1997-04-02 | 1999-01-12 | The Sulfatreat Company | Non-aqueous liquids for moistening an oxide-bearing carrier in sulfur sweetening |
US5494879A (en) * | 1993-02-26 | 1996-02-27 | Regents, University Of California | Catalyst for the reduction of sulfur dioxide to elemental sulfur |
US5494880A (en) * | 1994-03-23 | 1996-02-27 | The United States Of America As Represented By The United States Department Of Energy | Durable zinc oxide-containing sorbents for coal gas desulfurization |
US5674463A (en) * | 1994-08-25 | 1997-10-07 | The Boc Group, Inc. | Process for the purification of carbon dioxide |
US5603913A (en) * | 1995-05-17 | 1997-02-18 | Azerbaidzhanskaya Gosudarstvennaya Neftianaya Academiya | Catalysts and process for selective oxidation of hydrogen sulfide to elemental sulfur |
US5891415A (en) * | 1995-05-17 | 1999-04-06 | Azerbaidzhanskaya Gosudarstvennaya Neftianaya Academiya | Process for selective oxidation of hydrogen sulfide to elemental sulfur |
US5710089A (en) * | 1995-06-07 | 1998-01-20 | Phillips Petroleum Company | Sorbent compositions |
US5710083A (en) * | 1996-08-14 | 1998-01-20 | Phillips Petroleum Company | Process to rejuvenate spent zinc oxide sorbents |
US5792438A (en) * | 1996-08-20 | 1998-08-11 | The Sulfatreat Company | Process and composition for increasing the reactivity of sulfur scavenging iron oxides |
US5882614A (en) * | 1998-01-23 | 1999-03-16 | Exxon Research And Engineering Company | Very low sulfur gas feeds for sulfur sensitive syngas and hydrocarbon synthesis processes |
US6887445B2 (en) * | 1998-08-04 | 2005-05-03 | M-I L.L.C. | Process for sulfur scavenging |
JP4197073B2 (en) * | 1999-08-27 | 2008-12-17 | 株式会社コスモ総合研究所 | Deep desulfurization catalyst, method for producing the same, and desulfurization method using the same |
US6271173B1 (en) * | 1999-11-01 | 2001-08-07 | Phillips Petroleum Company | Process for producing a desulfurization sorbent |
US6491884B1 (en) * | 1999-11-26 | 2002-12-10 | Advanced Technology Materials, Inc. | In-situ air oxidation treatment of MOCVD process effluent |
US6683024B1 (en) * | 2000-03-15 | 2004-01-27 | Conocophillips Company | Desulfurization and novel sorbents for same |
US6346190B1 (en) * | 2000-03-21 | 2002-02-12 | Phillips Petroleum Company | Desulfurization and novel sorbents for same |
JP4533515B2 (en) * | 2000-08-16 | 2010-09-01 | 三菱重工業株式会社 | Syngas production method |
US6428761B1 (en) * | 2000-09-29 | 2002-08-06 | Engelhard Corporation | Process for reduction of gaseous sulfur compounds |
JP2004515355A (en) | 2000-12-11 | 2004-05-27 | ユナイテッド・ステイツ・フィルター・コーポレイション | Activated carbon for odor control and its manufacturing method |
US7297655B2 (en) * | 2001-06-21 | 2007-11-20 | Shell Oil Company | Catalyst and its use in desulphurisation |
US6494153B1 (en) * | 2001-07-31 | 2002-12-17 | General Electric Co. | Unmixed combustion of coal with sulfur recycle |
US6544410B1 (en) | 2001-12-19 | 2003-04-08 | Phillips Petroleum Company | Desulfurization with improved sorbent regeneration |
US6649555B2 (en) | 2001-12-19 | 2003-11-18 | Conocophillips Company | Reactivation of deactivated sorbents |
US6635795B2 (en) | 2001-12-19 | 2003-10-21 | Conocophillips Company | Desulfurization with improved sorbent regeneration |
JP2006500202A (en) * | 2002-09-23 | 2006-01-05 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | Catalyst particles and their use for desulfurization |
KR20120065439A (en) * | 2002-10-17 | 2012-06-20 | 엔테그리스, 아이엔씨. | Method for purifying carbon dioxide |
AU2003293370A1 (en) * | 2002-12-05 | 2004-06-30 | Usfilter Corporation | Activated carbon for odor control and method for making same |
SE0301071D0 (en) * | 2003-04-11 | 2003-04-11 | Hoeganaes Ab | Gas purification |
SG117798A1 (en) * | 2003-06-23 | 2008-02-29 | Shell Int Research | Process to prepare a lubricating base oil |
CA2433277C (en) * | 2003-06-25 | 2008-02-26 | Clean-Flo Gas Filtration Systems (1987) Ltd. | Gas purification medium for removing sulfides from gaseous streams |
US20070272592A1 (en) * | 2003-06-27 | 2007-11-29 | Germaine Gilbert R B | Process to Prepare a Lubricating Base Oil |
US7351328B2 (en) * | 2003-07-23 | 2008-04-01 | China Petroleum & Chemical Corporation | Desulfurization and novel process for same |
EP1697258A4 (en) * | 2003-11-26 | 2010-03-10 | Cabot Corp | Particulate absorbent materials and methods for making same |
WO2006067176A1 (en) * | 2004-12-23 | 2006-06-29 | Shell Internationale Research Maatschappij B.V. | Process to prepare a lubricating base oil |
JP2008168228A (en) * | 2007-01-12 | 2008-07-24 | Okayama Univ | Catalyst for purifying nitrogen oxide in exhaust gas of diesel engine using unburnt carbon and nitrogen oxide purifying method |
US7682424B2 (en) * | 2008-01-31 | 2010-03-23 | Conocophillips Company | Contaminant removal from a gas stream |
US7951740B2 (en) * | 2008-09-11 | 2011-05-31 | China Petroleum & Chemical Corporation | Method of inhibiting in situ silicate formation in desulfurization sorbents |
US7935324B2 (en) * | 2008-12-04 | 2011-05-03 | Uop Llc | Integrated warm gas desulfurization and gas shift for cleanup of gaseous streams |
US8940660B2 (en) * | 2008-12-04 | 2015-01-27 | Uop Llc | Simultaneous warm gas desulfurization and complete CO-shift for improved syngas cleanup |
US7759282B2 (en) * | 2008-12-04 | 2010-07-20 | Uop Llc | Catalyst for removal of sulfer from a gaseous stream |
US7811474B2 (en) * | 2008-12-04 | 2010-10-12 | Uop Llc | Simultaneous warm gas desulfurization and CO-shift for improved syngas cleanup |
US8017545B2 (en) * | 2008-12-04 | 2011-09-13 | Uop Llc | Dynamic composition for the removal of sulfur from a gaseous stream |
US8404031B1 (en) * | 2009-10-06 | 2013-03-26 | Michael Callaway | Material and method for the sorption of hydrogen sulfide |
JP5547994B2 (en) * | 2010-03-08 | 2014-07-16 | 大阪瓦斯株式会社 | Desulfurization method, desulfurization apparatus and fuel cell power generation system |
JP2013537848A (en) * | 2010-09-13 | 2013-10-07 | フイリツプス66カンパニー | Low temperature sulfur tolerant tar and sulfur removal associated with syngas conditioning |
US8759252B1 (en) | 2010-10-06 | 2014-06-24 | Michael D. and Anita Kaye | Material and method for the sorption of hydrogen sulfide |
EP2439176A1 (en) | 2010-10-07 | 2012-04-11 | EnCana Corporation | Treatment of water for use in hydraulic fracture stimulation |
US9353026B2 (en) | 2013-07-19 | 2016-05-31 | Baker Hughes Incorporated | Oil soluble hydrogen sulfide scavenger |
US11311855B2 (en) | 2015-10-13 | 2022-04-26 | Regents Of The University Of Minnesota | Adsorbent material for removal of hydrogen sulfide |
CN105396454A (en) * | 2015-10-13 | 2016-03-16 | 中国石油化工股份有限公司 | Preparation method of hydrogen sulfide absorbent |
KR102001144B1 (en) | 2016-03-04 | 2019-07-17 | 주식회사 엘지화학 | Ferritic catalyst composite, method for preparing ferritic oxide catalyst composite and butadiene |
WO2020033500A1 (en) * | 2018-08-09 | 2020-02-13 | Ohio State Innovation Foundation | Systems, methods and materials for hydrogen sulfide conversion |
WO2020210396A1 (en) | 2019-04-09 | 2020-10-15 | Ohio State Innovation Foundation | Alkene generation using metal sulfide particles |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2551905A (en) * | 1946-04-29 | 1951-05-08 | Phillips Petroleum Co | Desulfurization of gases |
US2747968A (en) * | 1951-05-07 | 1956-05-29 | Pigache Pierre Gustave Adolphe | Dry process for the recovery of sulfur from gases |
DE1224282B (en) * | 1964-08-18 | 1966-09-08 | Chem Fab Hoesch K G | Process for the production of highly active addition products of zinc oxide on silicon dioxide |
FR2295782A1 (en) * | 1974-12-27 | 1976-07-23 | Inst Francais Du Petrole | PROCESS FOR DEPURING A GAS CONTAINING HYDROGEN SULFIDE AND CONTACT MASSES USABLE FOR THIS PURPOSE |
FR2295784A1 (en) * | 1974-12-27 | 1976-07-23 | Inst Francais Du Petrole | PROCESS FOR DEPURING A GAS CONTAINING SULFUR COMPOUNDS |
JPS5561926A (en) * | 1978-11-02 | 1980-05-10 | Shin Meiwa Ind Co Ltd | Removal of malodor |
EP0167206B1 (en) * | 1984-06-22 | 1991-10-23 | Mizusawa Industrial Chemicals Ltd. | Synthetic fraipontite and process for preparation thereof |
US4680806A (en) * | 1984-12-04 | 1987-07-14 | Koenig & Bauer Aktiengesellschaft | Edge location measuring head |
US4729889A (en) * | 1985-03-29 | 1988-03-08 | California Institute Of Technology | High temperature regenerative H2 S sorbents |
US4769045A (en) * | 1986-04-10 | 1988-09-06 | The United States Department Of Energy | Method for the desulfurization of hot product gases from coal gasifier |
US4690806A (en) * | 1986-05-01 | 1987-09-01 | Exxon Research And Engineering Company | Removal of sulfur from process streams |
US4732888A (en) * | 1986-05-15 | 1988-03-22 | Amax Inc. | Durable zinc ferrite sorbent pellets for hot coal gas desulfurization |
JPS63134028A (en) * | 1986-11-26 | 1988-06-06 | Mitsubishi Heavy Ind Ltd | Dry desulfurizing method |
US4857285A (en) * | 1987-06-04 | 1989-08-15 | General Electric Environmental Services, Inc. | Method and system for removal of sulfur compounds from gases and for regenerating spent sorbents |
US4895824A (en) * | 1987-09-08 | 1990-01-23 | W. R. Grace & Co.-Conn. | Add-on hydrogen sulfide trap |
US4916105A (en) * | 1989-02-07 | 1990-04-10 | W. R. Grace & Co.-Conn. | Catalyst and metal ferrites for reduction of hydrogen sulfide emissions from automobile exhaust |
CA2014560C (en) * | 1989-06-07 | 1999-02-16 | Dennis R. Kidd | Selective removal of hydrogen sulfide over a zinc oxide and silica absorbing composition |
US4990318A (en) * | 1989-06-07 | 1991-02-05 | Phillips Petroleum Company | Selective removal of hydrogen sulfide over a nickel-promoted absorbing composition |
US5094996A (en) * | 1989-06-07 | 1992-03-10 | Phillips Petroleum Company | Nickel-promoted absorbing compositions for selective removal of hydrogen sulfide |
US5045522A (en) * | 1990-03-27 | 1991-09-03 | Phillips Petroleum Company | Absorption composition comprising zinc titanate for removal of hydrogen sulfide from fluid streams |
US5077261A (en) * | 1990-06-25 | 1991-12-31 | Phillips Petroleum Company | Sulfur absorbants |
-
1992
- 1992-04-28 US US07/874,908 patent/US5244641A/en not_active Expired - Lifetime
-
1993
- 1993-02-03 CA CA002088743A patent/CA2088743C/en not_active Expired - Fee Related
- 1993-04-07 AU AU36811/93A patent/AU648955B2/en not_active Ceased
- 1993-04-20 ZA ZA932765A patent/ZA932765B/en unknown
- 1993-04-23 MX MX9302386A patent/MX9302386A/en unknown
- 1993-04-23 JP JP5097785A patent/JP3009309B2/en not_active Expired - Fee Related
- 1993-04-27 SG SG1996005868A patent/SG59961A1/en unknown
- 1993-04-27 EP EP93106803A patent/EP0568003B1/en not_active Expired - Lifetime
- 1993-04-27 DE DE69312559T patent/DE69312559T2/en not_active Expired - Fee Related
- 1993-04-27 ES ES93106803T patent/ES2104997T3/en not_active Expired - Lifetime
- 1993-04-27 NO NO931538A patent/NO300160B1/en unknown
- 1993-05-07 US US08/058,586 patent/US5306685A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0568003B1 (en) | 1997-07-30 |
DE69312559T2 (en) | 1997-12-04 |
NO931538L (en) | 1993-10-29 |
NO300160B1 (en) | 1997-04-21 |
US5244641A (en) | 1993-09-14 |
JP3009309B2 (en) | 2000-02-14 |
SG59961A1 (en) | 1999-02-22 |
ZA932765B (en) | 1993-11-16 |
AU648955B2 (en) | 1994-05-05 |
JPH06279774A (en) | 1994-10-04 |
CA2088743C (en) | 2000-01-18 |
US5306685A (en) | 1994-04-26 |
ES2104997T3 (en) | 1997-10-16 |
NO931538D0 (en) | 1993-04-27 |
EP0568003A2 (en) | 1993-11-03 |
DE69312559D1 (en) | 1997-09-04 |
AU3681193A (en) | 1993-11-11 |
EP0568003A3 (en) | 1993-12-29 |
MX9302386A (en) | 1993-10-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed | ||
MKLA | Lapsed |
Effective date: 20050203 |