CA2079949A1 - Low temperature pressure swing adsorption with refrigeration - Google Patents
Low temperature pressure swing adsorption with refrigerationInfo
- Publication number
- CA2079949A1 CA2079949A1 CA2079949A CA2079949A CA2079949A1 CA 2079949 A1 CA2079949 A1 CA 2079949A1 CA 2079949 A CA2079949 A CA 2079949A CA 2079949 A CA2079949 A CA 2079949A CA 2079949 A1 CA2079949 A1 CA 2079949A1
- Authority
- CA
- Canada
- Prior art keywords
- refrigeration
- swing adsorption
- pressure swing
- low temperature
- temperature pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0462—Temperature swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
- B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/18—Noble gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/702—Hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/80—Water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0438—Cooling or heating systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0446—Means for feeding or distributing gases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S95/00—Gas separation: processes
- Y10S95/90—Solid sorbent
- Y10S95/902—Molecular sieve
Abstract
Pressure swing adsorption gas separation operations are enhanced by the retention and use of internal refrigeration effects, without the need for externally supplied refrigeration.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US772,336 | 1991-10-07 | ||
US07/772,336 US5169413A (en) | 1991-10-07 | 1991-10-07 | Low temperature pressure swing adsorption with refrigeration |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2079949A1 true CA2079949A1 (en) | 1993-04-08 |
CA2079949C CA2079949C (en) | 1993-04-08 |
Family
ID=25094730
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002079949A Expired - Fee Related CA2079949C (en) | 1991-10-07 | 1992-10-06 | Low temperature pressure swing adsorption with refrigeration |
Country Status (12)
Country | Link |
---|---|
US (1) | US5169413A (en) |
EP (1) | EP0537597B1 (en) |
JP (1) | JP2524292B2 (en) |
KR (1) | KR0153434B1 (en) |
CN (1) | CN1032848C (en) |
AR (1) | AR247708A1 (en) |
BR (1) | BR9203886A (en) |
CA (1) | CA2079949C (en) |
DE (1) | DE69215641T2 (en) |
ES (1) | ES2096001T3 (en) |
MX (1) | MX9205709A (en) |
TW (1) | TW203561B (en) |
Families Citing this family (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5174979A (en) | 1989-10-06 | 1992-12-29 | Uop | Mixed ion-exchanged zeolites and processes for the use thereof in gas separations |
US5624477A (en) * | 1991-05-09 | 1997-04-29 | The Boc Group Plc | Pressure swing adsorption plants |
FR2700276B1 (en) * | 1993-01-08 | 1995-02-10 | Air Liquide | Process and adsorption unit for the production of a gas by separation of a gaseous mixture. |
US5529610A (en) * | 1993-09-07 | 1996-06-25 | Air Products And Chemicals, Inc. | Multiple zeolite adsorbent layers in oxygen separation |
US5453112A (en) * | 1994-02-02 | 1995-09-26 | Praxair Technology, Inc. | Pressure swing adsorption heat recovery |
JPH07251023A (en) * | 1994-03-16 | 1995-10-03 | Sumitomo Seika Chem Co Ltd | Method for separating gas and apparatus therefor |
GB9422833D0 (en) * | 1994-11-11 | 1995-01-04 | Secr Defence | Pressure and temperature swing absorbtion |
US5837021A (en) | 1994-12-09 | 1998-11-17 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Installation for the treatment of at least one fluid, by passage through two adjacent masses of material |
US5538544A (en) * | 1994-12-27 | 1996-07-23 | Praxair Technology, Inc. | Adsorption flow distribution |
US5632802A (en) * | 1995-03-03 | 1997-05-27 | Grgich; George R. | Apparatus and method of regenerating adsorbers for drying air |
US5807422A (en) * | 1995-03-03 | 1998-09-15 | Grgich; George R. | Divided radial and spherical desiccant bed adsorption units |
US5672196A (en) * | 1995-08-01 | 1997-09-30 | The Boc Group, Inc. | Process and apparatus for the separation of gases |
DE19529094A1 (en) * | 1995-08-08 | 1997-02-13 | Bayer Ag | Process for the adsorption of nitrogen from gas mixtures by means of pressure swing adsorption with zeolites |
US5989314A (en) * | 1995-09-26 | 1999-11-23 | Praxair Technology, Inc. | Pressure swing adsorption air prepurifier |
BR9603874A (en) * | 1995-09-26 | 1998-06-02 | Praxair Technology Inc | Air pre-cleaner with oscillating pressure adsorption |
US5674311A (en) * | 1995-10-20 | 1997-10-07 | Praxair Technology, Inc. | Adsorption process and system using multilayer adsorbent beds |
SE517561C2 (en) * | 1996-03-04 | 2002-06-18 | Aga Ab | Process and apparatus for producing a gas by separation from a gas mixture |
US5917140A (en) * | 1996-05-21 | 1999-06-29 | Advanced Technology Materials, Inc. | Sorbent-based fluid storage and dispensing vessel with enhanced heat transfer means |
US5766311A (en) * | 1996-07-03 | 1998-06-16 | Praxair Technology, Inc. | Multi-thermal pulse PSA system |
FR2753108B1 (en) * | 1996-09-06 | 1998-10-16 | Air Liquide | PROCESS FOR THE SEPARATION OF GASEOUS MIXTURES CONTAINING OXYGEN AND NITROGEN |
US6027548A (en) * | 1996-12-12 | 2000-02-22 | Praxair Technology, Inc. | PSA apparatus and process using adsorbent mixtures |
US5769928A (en) * | 1996-12-12 | 1998-06-23 | Praxair Technology, Inc. | PSA gas purifier and purification process |
US6152991A (en) | 1997-04-17 | 2000-11-28 | Praxair Technology, Inc. | Multilayer adsorbent beds for PSA gas separation |
FR2764522B1 (en) * | 1997-06-12 | 1999-07-16 | Air Liquide | METHOD AND INSTALLATION FOR AIR SEPARATION BY ADSORPTION |
FR2766384B1 (en) * | 1997-07-25 | 1999-09-03 | Air Liquide | REGULATION OF A PSA PROCESS |
US6238460B1 (en) | 1997-09-26 | 2001-05-29 | The Boc Group, Inc. | Air purification process |
DE19807225A1 (en) * | 1998-02-20 | 1999-08-26 | Linde Ag | Air preconditioning for fractionation, reducing costs and energy consumption |
WO1999042773A1 (en) * | 1998-02-20 | 1999-08-26 | Linde Aktiengesellschaft | Air purification with regenerators and adsorption bed for water |
US6106593A (en) * | 1998-10-08 | 2000-08-22 | Air Products And Chemicals, Inc. | Purification of air |
US6541159B1 (en) | 1999-08-12 | 2003-04-01 | Reveo, Inc. | Oxygen separation through hydroxide-conductive membrane |
US6284021B1 (en) * | 1999-09-02 | 2001-09-04 | The Boc Group, Inc. | Composite adsorbent beads for adsorption process |
US7122073B1 (en) * | 2000-09-18 | 2006-10-17 | Praxair Technology, Inc. | Low void adsorption systems and uses thereof |
SE523278C2 (en) * | 2001-10-11 | 2004-04-06 | Ifoe Ceramics Ab | Method and apparatus for producing oxygen or oxygen enriched air |
US6817614B2 (en) * | 2002-04-12 | 2004-11-16 | Sterling Gaming, Llc | Method of conducting a wagering game |
US7264651B2 (en) * | 2004-07-02 | 2007-09-04 | Praxair Technology, Inc. | Adsorption process and system using multilayer adsorbent beds containing regenerator section |
EP1907098A4 (en) * | 2005-06-27 | 2011-03-23 | Wearair Oxygen Inc | A process and apparatus for generating and delivering an enriched gas fraction |
KR100711237B1 (en) * | 2006-06-09 | 2007-04-25 | 한국에너지기술연구원 | Membranes embedded with adsorbents and method of separating carbon dioxide with the membranes |
FR2906160B1 (en) * | 2006-09-25 | 2009-06-05 | Air Liquide | PSA METHOD WITH COMPOSITE ADSORPTION BED FORMED OF ADSORBENT AND AGGLOMERATS OF MCP |
US7740690B2 (en) * | 2007-03-29 | 2010-06-22 | Praxair Technology, Inc. | Methods and systems for purifying gases |
JP4374393B1 (en) * | 2008-05-27 | 2009-12-02 | ダイナエアー株式会社 | Humidity control device |
TW201043327A (en) * | 2009-03-30 | 2010-12-16 | Taiyo Nippon Sanso Corp | Pressure swing adsorbing type gas separating method and separation device |
JP5708121B2 (en) * | 2011-02-25 | 2015-04-30 | 栗田工業株式会社 | Secondary battery gas ejection prevention material, gas ejection prevention system, and secondary battery system using the same |
JP5884877B2 (en) * | 2013-10-03 | 2016-03-15 | ダイキン工業株式会社 | Container refrigeration equipment |
CN105233619A (en) * | 2015-11-13 | 2016-01-13 | 无锡清杨机械制造有限公司 | Oil and water removal purifying system for great deal of gas used in mechanical industry |
US9925514B2 (en) | 2016-02-22 | 2018-03-27 | Air Products And Chemicals, Inc. | Modified chabazite adsorbent compositions, methods of making and using them |
US9708188B1 (en) * | 2016-02-22 | 2017-07-18 | Air Products And Chemicals, Inc. | Method for argon production via cold pressure swing adsorption |
US11420869B2 (en) * | 2019-02-22 | 2022-08-23 | Uop Llc | Process for removing oxygen from a hydrogen stream |
CN112495137B (en) * | 2020-11-12 | 2022-04-19 | 杭州汉德空分设备有限公司 | Pressure swing adsorption oxygen generating equipment |
CN113251699B (en) * | 2021-05-12 | 2022-08-16 | 四川零碳工程科技有限公司 | Heat recovery type heat pump oxygen-making air conditioning unit |
CN113251700B (en) * | 2021-05-12 | 2022-08-16 | 四川零碳工程科技有限公司 | Frostless type heat pump oxygen-making air conditioning unit |
CN113663469B (en) * | 2021-08-13 | 2022-08-02 | 广东省迅怡净化科技有限公司 | Molecular sieve gas separation device and control method thereof |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2223588A (en) * | 1936-06-25 | 1940-12-03 | Stewart Warner Corp | Drying refrigerating units and like apparatus |
US2359660A (en) * | 1941-05-12 | 1944-10-03 | J F Pritchard & Company | System for reactivating adsorbents |
BE500169A (en) * | 1950-01-05 | |||
US2790505A (en) * | 1954-08-02 | 1957-04-30 | United Gas Corp | Methods of and means for dehydrating and processing fluid streams |
US2910139A (en) * | 1957-04-03 | 1959-10-27 | Phillips Petroleum Co | Drying of gases |
US2995208A (en) * | 1958-08-15 | 1961-08-08 | Phillips Petroleum Co | Adsorption process and apparatus |
BE605131A (en) * | 1960-06-23 | |||
DE1544022B2 (en) * | 1963-02-15 | 1969-10-30 | Linde Ag, 6200 Wiesbaden | Process for the enrichment of a component in gas mixtures |
US3323288A (en) * | 1964-05-27 | 1967-06-06 | Union Carbide Corp | Selective adsorption process and apparatus |
US3490205A (en) * | 1967-11-30 | 1970-01-20 | Nasa | High pressure gas filter system |
US3734293A (en) * | 1970-03-04 | 1973-05-22 | Air Prod & Chem | Thermoelectric adsorber |
US3674429A (en) * | 1971-01-06 | 1972-07-04 | Union Carbide Corp | Adsorption process for water and nitrogen oxides |
US3712027A (en) * | 1971-01-22 | 1973-01-23 | Continental Oil Co | Vapor adsorption process for recovering selected components from a multi-component gas stream |
FR2135388B1 (en) * | 1971-05-03 | 1973-05-11 | Air Liquide | |
US3850592A (en) * | 1972-11-24 | 1974-11-26 | Deltech Eng Inc | Heat pump dryer |
GB1449864A (en) * | 1973-10-24 | 1976-09-15 | Boc International Ltd | Adsorption system |
US3973931A (en) * | 1974-10-30 | 1976-08-10 | Union Carbide Corporation | Air separation by adsorption |
US4026680A (en) * | 1974-10-30 | 1977-05-31 | Union Carbide Corporation | Air separation by adsorption |
US4329158A (en) * | 1980-06-13 | 1982-05-11 | Air Products And Chemicals, Inc. | Air fractionation by pressure swing adsorption |
US4499208A (en) * | 1983-05-13 | 1985-02-12 | Union Carbide Corporation | Activated carbon adsorbent with increased heat capacity and the production thereof |
DE3319664A1 (en) * | 1983-05-31 | 1984-12-06 | Bergwerksverband Gmbh, 4300 Essen | Process and apparatus for purifying gas mixtures |
US4472178A (en) * | 1983-07-05 | 1984-09-18 | Air Products And Chemicals, Inc. | Adsorptive process for the removal of carbon dioxide from a gas |
DE3336427A1 (en) * | 1983-10-06 | 1985-04-18 | Linde Ag, 6200 Wiesbaden | METHOD AND DEVICE FOR REGENERATING ADSORBERS |
JPS60246205A (en) * | 1984-05-22 | 1985-12-05 | Mitsubishi Heavy Ind Ltd | Method of dehumidification and cold heat recovery of o2 production unit |
US4696681A (en) * | 1986-10-01 | 1987-09-29 | The Boc Group, Inc. | PSA assembly |
US4783432A (en) * | 1987-04-28 | 1988-11-08 | Pall Corporation | Dryer regeneration through heat of compression and pressure swing desorption |
JP2870913B2 (en) * | 1990-01-12 | 1999-03-17 | 東京電力株式会社 | Gas turbine power generation method using poorly fueled gasified gas as fuel |
-
1991
- 1991-10-07 US US07/772,336 patent/US5169413A/en not_active Expired - Fee Related
-
1992
- 1992-10-06 DE DE69215641T patent/DE69215641T2/en not_active Expired - Fee Related
- 1992-10-06 AR AR92323356A patent/AR247708A1/en active
- 1992-10-06 JP JP4290957A patent/JP2524292B2/en not_active Expired - Lifetime
- 1992-10-06 TW TW081107928A patent/TW203561B/zh active
- 1992-10-06 CA CA002079949A patent/CA2079949C/en not_active Expired - Fee Related
- 1992-10-06 CN CN92112845A patent/CN1032848C/en not_active Expired - Fee Related
- 1992-10-06 EP EP92117041A patent/EP0537597B1/en not_active Expired - Lifetime
- 1992-10-06 BR BR929203886A patent/BR9203886A/en not_active IP Right Cessation
- 1992-10-06 ES ES92117041T patent/ES2096001T3/en not_active Expired - Lifetime
- 1992-10-06 MX MX9205709A patent/MX9205709A/en not_active IP Right Cessation
- 1992-10-06 KR KR1019920018297A patent/KR0153434B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CN1071850A (en) | 1993-05-12 |
JP2524292B2 (en) | 1996-08-14 |
CA2079949C (en) | 1993-04-08 |
JPH05220320A (en) | 1993-08-31 |
DE69215641T2 (en) | 1997-06-12 |
DE69215641D1 (en) | 1997-01-16 |
EP0537597B1 (en) | 1996-12-04 |
EP0537597A1 (en) | 1993-04-21 |
KR0153434B1 (en) | 1998-11-16 |
US5169413A (en) | 1992-12-08 |
ES2096001T3 (en) | 1997-03-01 |
CN1032848C (en) | 1996-09-25 |
MX9205709A (en) | 1993-05-01 |
KR930008422A (en) | 1993-05-21 |
BR9203886A (en) | 1993-04-27 |
TW203561B (en) | 1993-04-11 |
AR247708A1 (en) | 1995-03-31 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |