CA2079535A1 - Poly hydroxybutyrate/hydroxy-valerate based hot melt adhesive - Google Patents
Poly hydroxybutyrate/hydroxy-valerate based hot melt adhesiveInfo
- Publication number
- CA2079535A1 CA2079535A1 CA2079535A CA2079535A CA2079535A1 CA 2079535 A1 CA2079535 A1 CA 2079535A1 CA 2079535 A CA2079535 A CA 2079535A CA 2079535 A CA2079535 A CA 2079535A CA 2079535 A1 CA2079535 A1 CA 2079535A1
- Authority
- CA
- Canada
- Prior art keywords
- weight
- hot melt
- melt adhesive
- valerate
- hydroxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
Abstract
Hot melt adhesive compositions are prepared from 20 to 90% by weight of a linearpolyester of 3-hydroxybutyric and 3-hydroxyvaleric acids containing 9 to 35% of the hydroxyvalerate component; 10 to 80% by weight of a polar tackifier having a Ring and Ball softening point (as described by ASTM E-26) greater than about 60°C; 0 to 50% by weight of a plasticizer; 0 to 30% by weight of a wax diluent and 0-3% by weight of a stabilizer; 0-20%
of a compatible polymer. But utilizing a naturally occurring, thermoplastic, biodegradable copolymer as the base polymer, these adhesives advance the state of the art of hot melt adhesives by alleviating the dependence on petroleum based materials and by allowing for the development of hot melt adhesives which either degrade naturally after coming in contact with the soil or which can be composted.
of a compatible polymer. But utilizing a naturally occurring, thermoplastic, biodegradable copolymer as the base polymer, these adhesives advance the state of the art of hot melt adhesives by alleviating the dependence on petroleum based materials and by allowing for the development of hot melt adhesives which either degrade naturally after coming in contact with the soil or which can be composted.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US826,571 | 1992-01-27 | ||
US07/826,571 US5169889A (en) | 1992-01-27 | 1992-01-27 | Poly hydroxybutyrate/hydroxyvalerate based hot melt adhesive |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2079535A1 true CA2079535A1 (en) | 1993-07-28 |
CA2079535C CA2079535C (en) | 1998-03-31 |
Family
ID=25246926
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002079535A Expired - Fee Related CA2079535C (en) | 1992-01-27 | 1992-09-30 | Poly hydroxybutyrate/hydroxy-valerate based hot melt adhesive |
Country Status (8)
Country | Link |
---|---|
US (1) | US5169889A (en) |
EP (1) | EP0553394B1 (en) |
JP (1) | JPH0662928B2 (en) |
AU (1) | AU643154B2 (en) |
CA (1) | CA2079535C (en) |
DE (2) | DE553394T1 (en) |
DK (1) | DK0553394T3 (en) |
ES (1) | ES2067437T3 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013162059A1 (en) * | 2012-04-26 | 2013-10-31 | Henkel Japan Ltd. | Hot melt adhesive |
Families Citing this family (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5502158A (en) * | 1988-08-08 | 1996-03-26 | Ecopol, Llc | Degradable polymer composition |
US5939467A (en) * | 1992-06-26 | 1999-08-17 | The Procter & Gamble Company | Biodegradable polymeric compositions and products thereof |
WO1994010257A1 (en) * | 1992-10-29 | 1994-05-11 | National Starch And Chemical Investment Holding Corporation | Polylactide containing hot melt adhesive |
US5312850A (en) * | 1993-01-04 | 1994-05-17 | National Starch And Chemical Investment Holding Corporation | Polylactide and starch containing hot melt adhesive |
US5252646A (en) * | 1992-10-29 | 1993-10-12 | National Starch And Chemical Investment Holding Corporation | Polylactide containing hot melt adhesive |
US5910520A (en) * | 1993-01-15 | 1999-06-08 | Mcneil-Ppc, Inc. | Melt processable biodegradable compositions and articles made therefrom |
GB9311399D0 (en) * | 1993-06-02 | 1993-07-21 | Zeneca Ltd | Polyester composition |
GB9314577D0 (en) * | 1993-07-14 | 1993-08-25 | Zeneca Ltd | Adhesion process |
JPH09505615A (en) * | 1993-10-15 | 1997-06-03 | エイチ.ビイ.フラー ライセンシング アンド ファイナンシング インク | Biodegradable / fertilizable hot melt adhesive containing lactic acid polyester |
SG47812A1 (en) * | 1994-01-28 | 1998-04-17 | Procter & Gamble | Biodegradable copolymers and plastic articles comprising biodegradable copolymers of 3-hydroxyhexanoate |
US5747573A (en) * | 1994-02-07 | 1998-05-05 | H. B. Fuller Licensing & Financing, Inc. | High heat resistant hot melt adhesive |
US5656367A (en) * | 1994-04-29 | 1997-08-12 | National Starch And Chemical Investment Holding Corporation | Poly(hydroxybutyrate/hydroxyvalerate) copolymers for fiber bonding |
BR9508583A (en) * | 1994-08-12 | 1998-07-14 | Minnesota Mining & Mfg | Pressure sensitive adhesive composition of pressure sensitive adhesive article and process of adhering two substrates |
DE4430415A1 (en) * | 1994-08-26 | 1996-03-14 | Buna Gmbh | Poly:hydroxy-butyric acid used as permanent contact adhesive |
US5583187A (en) * | 1995-05-03 | 1996-12-10 | National Starch And Chemical Investment Holding Corporation | Hot melt adhesives based on hydroxy-functional polyesters |
US5574076A (en) * | 1995-05-03 | 1996-11-12 | National Starch And Chemical Investment Holding Corporation | Sucrose benzoate as a tackifier for water sensitive or biodegradable hot melt adhesives |
US5750605A (en) * | 1995-08-31 | 1998-05-12 | National Starch And Chemical Investment Holding Corporation | Hot melt adhesives based on sulfonated polyesters |
EP0832165B1 (en) * | 1996-04-23 | 1999-07-14 | Uzin Utz Aktiengesellschaft | Resin-based dispersion glues |
FI963935A (en) * | 1996-10-01 | 1998-04-02 | Upm Kymmene Oy | polymer Composition |
US5945375A (en) * | 1997-03-31 | 1999-08-31 | Kimberly-Clark Worldwide, Inc. | Thermal dye diffusion coating and substrate |
US6281166B1 (en) | 1998-02-20 | 2001-08-28 | Kimberly-Clark Worldwide | Thermal dye diffusion coating and substrate |
US6022947A (en) * | 1998-09-18 | 2000-02-08 | Union Camp Corporation | Light-colored, low molecular weight phenolic-modified rosin esters |
US6479145B1 (en) * | 1999-09-09 | 2002-11-12 | Regents Of The University Of Minnesota | Biopolymers and biopolymer blends, and method for producing same |
US6767972B1 (en) * | 2000-09-15 | 2004-07-27 | Eastman Chemical Company | Methods for slowing the degradation rate of biodegradable polymers and biodegradable polymer compositions and compositions thereof |
AU2002225827A1 (en) * | 2000-10-27 | 2002-05-06 | Metabolix, Inc. | Compositions comprising low molecular weight polyhydroxyalkanoates and methods employing same |
DE10104004A1 (en) * | 2001-01-31 | 2002-08-08 | Walcher Ulrich | Environmentally friendly composition for the production of film products, as use in the fields of packaging, agricultural films and disposable packaging |
EP1236753A1 (en) * | 2001-03-02 | 2002-09-04 | Hycail B.V. | Environmentally degradable polymeric compounds, their preparation and use as hot melt adhesive |
WO2004076582A1 (en) * | 2003-02-21 | 2004-09-10 | Metabolix Inc. | Pha blends |
US7781539B2 (en) * | 2003-02-21 | 2010-08-24 | Metabolix Inc. | PHA blends |
JP2007517126A (en) * | 2003-12-30 | 2007-06-28 | メタボリックス インコーポレイティッド | Nucleator |
BRPI0600782A (en) * | 2006-02-24 | 2007-11-20 | Phb Ind Sa | composition for preparing degradable polyester polyol, process for obtaining polyester, elastomer, foam, paint and adhesive polyols, and degradable foam of a polyester polyol |
FR2927629B1 (en) * | 2008-02-14 | 2011-07-29 | Bostik Sa | BIODEGRADABLE THERMOFUSIBLE ADHESIVE COMPOSITION. |
EP2321368B1 (en) * | 2008-09-05 | 2014-01-22 | The Procter and Gamble Company | Hot melt adhesive composition |
US20110111012A1 (en) * | 2009-11-12 | 2011-05-12 | Hemcon Medical Technologies, Inc. | Nanomaterial wound dressing assembly |
US8002399B2 (en) * | 2009-12-02 | 2011-08-23 | Xerox Corporation | Solid inks incorporating a polyhydroxyalkanoate compound for enhanced properties |
JP5921946B2 (en) | 2012-04-26 | 2016-05-24 | ヘンケルジャパン株式会社 | Hot melt adhesive |
CN109054254B (en) | 2012-08-17 | 2021-02-02 | Cj第一制糖株式会社 | Bio-based rubber modifiers for polymer blends |
JP5925094B2 (en) | 2012-09-27 | 2016-05-25 | ヘンケルジャパン株式会社 | Hot melt adhesive for labels |
DE102013205144A1 (en) | 2013-03-22 | 2014-09-25 | Novamelt GmbH Klebstofftechnologie | Adhesive composition based on optionally modified polylactide, process for their preparation and use of the adhesive composition |
DE102013004909A1 (en) | 2013-03-22 | 2014-10-09 | Jowat Ag | New adhesive compositions based on renewable raw materials and their use |
JP2014234399A (en) * | 2013-05-30 | 2014-12-15 | ヘンケルジャパン株式会社 | Hot melt adhesive |
US10669417B2 (en) | 2013-05-30 | 2020-06-02 | Cj Cheiljedang Corporation | Recyclate blends |
JP6057837B2 (en) * | 2013-05-30 | 2017-01-11 | ヘンケルジャパン株式会社 | Hot melt adhesive |
JP6154725B2 (en) * | 2013-10-24 | 2017-06-28 | ヘンケルジャパン株式会社 | Hot melt adhesive |
WO2015149029A1 (en) | 2014-03-27 | 2015-10-01 | Metabolix, Inc. | Highly filled polymer systems |
BR112017004350A2 (en) | 2014-09-05 | 2017-12-05 | Henkel IP & Holding GmbH | hot melt adhesive compositions and their use |
US11890384B2 (en) | 2016-02-12 | 2024-02-06 | Tricol Biomedical, Inc. | Chitosan superfine fiber systems |
WO2018007548A1 (en) | 2016-07-07 | 2018-01-11 | Repsol, S.A. | Compositions of polyhydroxyalkanoates and polar polymers |
GB201718470D0 (en) * | 2017-11-08 | 2017-12-20 | Provost Fellows Found Scholars And The Other Members Of Board Of The College Of The Holy And Undivid | Adhesive formulations |
JP7368475B2 (en) | 2018-12-21 | 2023-10-24 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | Hot melt adhesives and their use |
AT523099B1 (en) * | 2019-10-21 | 2023-02-15 | Zampetti Max | membrane film |
AU2022299275A1 (en) * | 2021-06-21 | 2024-01-18 | Beiersdorf Ag | Biodegradable pressure-sensitive adhesive |
WO2023223689A1 (en) * | 2022-05-16 | 2023-11-23 | 株式会社カネカ | Composition for hot-melt adhesive |
ES2942331B2 (en) * | 2022-12-29 | 2023-11-15 | Asociacion Investig De Industria Textil Aitex | PROCEDURE FOR THE MANUFACTURE OF A HOT FUSE ADHESIVE AND HOT FUSE ADHESIVE OBTAINED BY SUCH PROCEDURE |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3959062A (en) * | 1972-08-10 | 1976-05-25 | E. I. Du Pont De Nemours And Company | Method of joining surfaces using segmented copolyester adhesive |
US4156676A (en) * | 1978-03-27 | 1979-05-29 | Chevron Research Company | Hot melt adhesives having improved thermal stability |
US4477654A (en) * | 1981-07-07 | 1984-10-16 | Imperial Chemical Industries Plc | 3-Hydroxybutyrate polymers |
AU560653B2 (en) * | 1981-07-07 | 1987-04-16 | Monsanto Company | 3-hydroxybutyrate polymers |
EP0288908B1 (en) * | 1987-04-28 | 1992-10-21 | Mitsubishi Gas Chemical Company, Inc. | Process for production of a random copolymer comprising d-(-)-3-hydroxybutyrate units and d-(-)-3-hydroxyvalerate |
US4900299A (en) * | 1987-05-11 | 1990-02-13 | Mcneil-Ppc, Inc. | Biodegradable tampon application comprising poly(3-hydroxybutyric acid) |
NZ224549A (en) * | 1987-05-29 | 1990-04-26 | Ici Australia Operations | Controlled release polymer microspheres containing at least one active agent |
US4876331A (en) * | 1987-08-18 | 1989-10-24 | Mitsubishi Kasei Corporation | Copolyester and process for producing the same |
-
1992
- 1992-01-27 US US07/826,571 patent/US5169889A/en not_active Expired - Fee Related
- 1992-08-27 DE DE0553394T patent/DE553394T1/en active Pending
- 1992-08-27 EP EP92114636A patent/EP0553394B1/en not_active Expired - Lifetime
- 1992-08-27 DE DE69203713T patent/DE69203713T2/en not_active Expired - Fee Related
- 1992-08-27 ES ES92114636T patent/ES2067437T3/en not_active Expired - Lifetime
- 1992-08-27 AU AU21344/92A patent/AU643154B2/en not_active Ceased
- 1992-08-27 DK DK92114636.1T patent/DK0553394T3/en active
- 1992-09-18 JP JP4249107A patent/JPH0662928B2/en not_active Expired - Lifetime
- 1992-09-30 CA CA002079535A patent/CA2079535C/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013162059A1 (en) * | 2012-04-26 | 2013-10-31 | Henkel Japan Ltd. | Hot melt adhesive |
EP2841522A4 (en) * | 2012-04-26 | 2015-12-16 | Henkel Ag & Co Kgaa | Hot melt adhesive |
Also Published As
Publication number | Publication date |
---|---|
ES2067437T3 (en) | 1995-11-01 |
DE69203713D1 (en) | 1995-09-07 |
JPH05271638A (en) | 1993-10-19 |
DE553394T1 (en) | 1995-08-03 |
AU2134492A (en) | 1993-07-29 |
EP0553394A1 (en) | 1993-08-04 |
ES2067437T1 (en) | 1995-04-01 |
AU643154B2 (en) | 1993-11-04 |
JPH0662928B2 (en) | 1994-08-17 |
DK0553394T3 (en) | 1995-09-11 |
CA2079535C (en) | 1998-03-31 |
US5169889A (en) | 1992-12-08 |
EP0553394B1 (en) | 1995-07-26 |
DE69203713T2 (en) | 1996-01-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |