CA2055397A1 - Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers - Google Patents

Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers

Info

Publication number
CA2055397A1
CA2055397A1 CA002055397A CA2055397A CA2055397A1 CA 2055397 A1 CA2055397 A1 CA 2055397A1 CA 002055397 A CA002055397 A CA 002055397A CA 2055397 A CA2055397 A CA 2055397A CA 2055397 A1 CA2055397 A1 CA 2055397A1
Authority
CA
Canada
Prior art keywords
bulk polymerization
preparation
metallocene catalysts
specific metallocene
cycloolefin polymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CA002055397A
Other languages
French (fr)
Other versions
CA2055397C (en
Inventor
Michael-Joachim Brekner
Frank Osan
Juergen Rohrmann
Martin Antberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ticona GmbH
Original Assignee
Michael-Joachim Brekner
Frank Osan
Juergen Rohrmann
Martin Antberg
Hoechst Aktiengesellschaft
Ticona Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michael-Joachim Brekner, Frank Osan, Juergen Rohrmann, Martin Antberg, Hoechst Aktiengesellschaft, Ticona Gmbh filed Critical Michael-Joachim Brekner
Publication of CA2055397A1 publication Critical patent/CA2055397A1/en
Application granted granted Critical
Publication of CA2055397C publication Critical patent/CA2055397C/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/602—Component covered by group C08F4/60 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F32/08—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having two condensed rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Abstract of the disclosure Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers Polymers of polycyclic olefins, such as, for example, norbornene or tetracyclododecene, or copolymers of polycyclic olefins with cycloolefins and/or 1-olefins are obtained without ring opening, in high space-time yield, with a high cycloolefin incorporation rate and at in-dustrially favorable polymerization temperatures, by bulk polymerization in which a catalyst is used which comprises an aluminoxane and a stereorigid chiral metal-locene compound of an element from groups IVb to VIb, where the hydrocarbon radicals forming the sandwich structure are different.
CA002055397A 1990-11-14 1991-11-13 Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers Expired - Lifetime CA2055397C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4036264 1990-11-14
DE4036264.7 1990-11-14

Publications (2)

Publication Number Publication Date
CA2055397A1 true CA2055397A1 (en) 1992-05-15
CA2055397C CA2055397C (en) 2004-04-20

Family

ID=6418254

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002055397A Expired - Lifetime CA2055397C (en) 1990-11-14 1991-11-13 Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers

Country Status (13)

Country Link
EP (1) EP0485893B1 (en)
JP (1) JP3247130B2 (en)
KR (1) KR100230915B1 (en)
AT (1) ATE165372T1 (en)
AU (1) AU641291B2 (en)
CA (1) CA2055397C (en)
CS (1) CS344291A3 (en)
DE (1) DE59108971D1 (en)
ES (1) ES2117632T3 (en)
HU (1) HUT59429A (en)
NO (1) NO914439L (en)
TW (1) TW227005B (en)
ZA (1) ZA918990B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5602219A (en) * 1993-02-12 1997-02-11 Hoechst Aktiengesellschaft Process for preparing cycloolefin copolymers
US5637400A (en) * 1993-02-12 1997-06-10 Hoechst Aktiengesellschaft Cycloolefin copolymers having low melt viscosity and low optical attenuation
US5733991A (en) * 1993-02-12 1998-03-31 Hoechst Aktiengesellschaft Process for preparing cycloolefin polymer
US6214951B1 (en) 1993-02-12 2001-04-10 Hoechst Aktiengesellschaft Cycloolefin copolymers having high tear strength and low optical attenuation
US7205040B2 (en) 2003-11-10 2007-04-17 Mitsubishi Polyester Film Gmbh Peelable polyester film having improved oxygen barrier, process for its production and its use
US7829633B2 (en) 2002-09-13 2010-11-09 Ticona Gmbh Method for the production of a packaging made of thermoformable film having high thermal stability and a vapour barrier

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US5744664A (en) * 1990-07-05 1998-04-28 Hoechst Aktiengesellschaft Cycloolefin copolymers (COCS) as substrate material for liquid-crystal displays
DE59209568D1 (en) * 1991-02-27 1999-01-07 Ticona Gmbh Process for the preparation of cycloolefin (co) polymers with narrow molecular weight distribution
EP0594147A1 (en) * 1992-10-24 1994-04-27 Hoechst Aktiengesellschaft Cyclo-olefin copolymers as substrate material for liquid crystal displays
DE4304309A1 (en) * 1993-02-12 1994-08-18 Hoechst Ag Flexible cycloolefin copolymer film
DE4304308A1 (en) * 1993-02-12 1994-08-18 Hoechst Ag Rigid cycloolefin copolymer film
DE4304285A1 (en) * 1993-02-12 1994-08-18 Hoechst Ag Cycloolefin copolymers with high tear resistance and low optical attenuation
TW369545B (en) * 1993-02-12 1999-09-11 Hoechst Ag Process for preparing cycloolefin copolymers
EP0610850A1 (en) * 1993-02-12 1994-08-17 Hoechst Aktiengesellschaft Process for preparing cyclo-olefin polymers
TW274100B (en) 1993-02-12 1996-04-11 Hoechst Ag
DE4410559A1 (en) * 1994-03-26 1995-09-28 Hoechst Ag Oriented polyolefin film with amorphous polymer, process for its production and its use
DE4422157A1 (en) * 1994-06-24 1996-01-04 Hoechst Ag Process for the preparation of cycloolefin copolymers
DE4426185A1 (en) 1994-07-23 1996-01-25 Hoechst Ag Sealable oriented polyolefin multilayer film, process for its production and its use
DE4426184A1 (en) 1994-07-23 1996-01-25 Hoechst Ag Non-sealable oriented polyolefin multilayer film, process for its production and its use
DE19536043A1 (en) * 1995-09-28 1997-04-10 Hoechst Ag Polyolefin film with cycloolefin polymer, process for its production and its use
DE19539093A1 (en) 1995-10-20 1997-04-24 Hoechst Ag Metallized polyolefin film
DE19917790A1 (en) * 1999-04-20 2000-11-02 Hoechst Trespaphan Gmbh Biaxially oriented film for the production of ceramic capacitors
DE19929809A1 (en) 1999-06-30 2001-01-04 Ticona Gmbh Continuous process for the production of an amorphous polyolefin with a broad molar mass distribution and uniform glass temperature
DE10009646A1 (en) * 2000-03-01 2001-09-13 Ticona Gmbh Polymer mixture containing amorphous polyolefin, useful for preparing e.g. axially oriented films, has controllable relaxation and shrinkage properties
DE10012137A1 (en) 2000-03-13 2001-09-20 Mitsubishi Polyester Film Gmbh Translucent biaxially oriented polyester film, e.g. useful for food packaging or printing, includes a layer containing a cycloolefin copolymer
DE10022942A1 (en) 2000-05-11 2001-11-15 Mitsubishi Polyester Film Gmbh Mat white biaxially oriented polyester film, e.g. useful for food packaging, includes a cycloolefin copolymer
DE10026177A1 (en) 2000-05-26 2001-11-29 Mitsubishi Polyester Film Gmbh White, high-gloss polyester film containing cycloolefin copolymer (COC), process for its production and its use
DE10035328A1 (en) 2000-07-20 2002-01-31 Mitsubishi Polyester Film Gmbh Opaque polyester film containing cycloolefin copolymer (COC) with good surface adhesion, process for its production and its use
US6670423B2 (en) 2001-02-20 2003-12-30 E. I. Du Pont De Nemours And Company Polar ethylene-based polymer, cycloolefin polymer blends
US6696524B2 (en) 2001-02-20 2004-02-24 E. I. Du Pont De Nemours And Company Low Tg ethylene-based polymer, cycloolefin polymer blends
DE10137924B4 (en) 2001-08-07 2005-12-01 Ticona Gmbh Long fiber-reinforced polyolefin-plastic structure, process for its preparation and moldings produced therefrom
US6713582B2 (en) 2001-12-14 2004-03-30 Uniroyal Chemical Company, Inc. Process for the oligomerization of α-olefins having low unsaturation, the resulting polymers, and lubricants containing same
CN100475521C (en) * 2001-12-21 2009-04-08 纳幕尔杜邦公司 Multilayer film
DE10223662A1 (en) 2002-05-28 2003-12-11 Mitsubishi Polyester Film Gmbh Transparent polyester film with improved water vapor barrier, process for its production and its use
DE10223663A1 (en) 2002-05-28 2003-12-11 Mitsubishi Polyester Film Gmbh Transparent polyester film with improved water vapor barrier, process for its production and its use
US7141293B2 (en) 2003-04-22 2006-11-28 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film having high peeling resistance, process for its production and its use
US7442427B2 (en) 2003-04-22 2008-10-28 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film, process for its production and its use
US7288312B2 (en) 2003-04-22 2007-10-30 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film having low peeling resistance, process for its production and its use
US7186452B2 (en) 2003-04-22 2007-03-06 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film having high peeling resistance, process for its production and its use
US7144615B2 (en) 2003-04-22 2006-12-05 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film, process for its production and its use
US7223459B2 (en) 2003-04-22 2007-05-29 Mitsubishi Polyester Film Gmbh Coextruded, hot-sealable and peelable polyester film, process for its production and its use
DE10352431A1 (en) 2003-11-10 2005-06-09 Mitsubishi Polyester Film Gmbh Peelable polyester film with automatic venting, process for their preparation and their use
DE10352444A1 (en) 2003-11-10 2005-06-09 Mitsubishi Polyester Film Gmbh Adhesion-promoted, heat-sealable and peelable polyester film, process for its preparation and its use
DE10352432A1 (en) 2003-11-10 2005-06-09 Mitsubishi Polyester Film Gmbh White, heat-sealable, peelable polyester film, process for its preparation and its use
US7288316B2 (en) 2003-11-21 2007-10-30 Topas Advanced Polymers, Inc. Cycloolefin copolymer heat sealable films
JP2004195246A (en) * 2004-02-13 2004-07-15 Mitsunobu Miyagi Laser probe
US8231978B2 (en) 2006-10-05 2012-07-31 Treofan Germany Gmbh & Co. Kg Simultaneously drawn opaque film made of PLA
DE102007006825A1 (en) 2007-02-07 2008-08-14 Evonik Röhm Gmbh Plastic mold with anisotropic light scattering
DE102007055491A1 (en) 2007-11-21 2009-06-04 Mitsubishi Polyester Film Gmbh Low-density polyester film for polar substrates
KR101043657B1 (en) * 2008-09-23 2011-06-22 김명호 Apparatus for forming wire products
US9021611B2 (en) 2009-02-18 2015-04-28 Northwestern University Beam pen lithography
US9452593B2 (en) 2010-04-15 2016-09-27 Topas Advanced Polymers, Inc. Melt blends of amorphous cycloolefin polymers and partially crystalline cycloolefin elastomers with improved toughness
DE102010030074A1 (en) 2010-06-15 2011-12-15 Evonik Degussa Gmbh Plastic photovoltaic module and method for its production
CA2802097C (en) 2010-07-27 2014-06-03 Exxonmobil Oil Corporation Film composition and method of making the same
EP2744654A1 (en) 2011-08-19 2014-06-25 Avery Dennison Corporation Low noise flexible barrier films
EP2794266A1 (en) 2011-12-22 2014-10-29 Avery Dennison Corporation Flexible barrier films containing cyclic olefins
US9783352B2 (en) 2012-01-31 2017-10-10 E.I. Du Pont De Nemours And Company Multilayer film comprising cyclic olefin copolymer
WO2017155712A1 (en) 2016-03-11 2017-09-14 Topas Advanced Polymers, Inc. Injection stretch blow-molding (isbm) enhancement for semi-crystalline polyolefin containers utilizing alicyclic polyolefins
KR102325932B1 (en) 2016-05-12 2021-11-17 에스에이치피피 글로벌 테크놀러지스 비.브이. Capacitor film having high temperature performance, manufacturing method and article thereof
AR109065A1 (en) 2016-07-28 2018-10-24 Dow Global Technologies Llc MULTI-PAPER STRUCTURES, MULTI-PAPER FILMS AND FORMED CONTAINERS FROM THEM
US10951875B2 (en) 2018-07-03 2021-03-16 Raxium, Inc. Display processing circuitry
DE102018215422A1 (en) 2018-09-11 2020-03-12 Mitsubishi Polyester Film Gmbh Heat-sealable polyester film for the production of menu trays, processes for their production and their use
DE102019200365A1 (en) 2019-01-14 2020-07-16 Mitsubishi Polyester Film Gmbh Package made of polyester with a thermoformable bottom film and a sealable and peelable top film, process for their production and their use
US11710445B2 (en) 2019-01-24 2023-07-25 Google Llc Backplane configurations and operations
US11637219B2 (en) 2019-04-12 2023-04-25 Google Llc Monolithic integration of different light emitting structures on a same substrate
US11238782B2 (en) 2019-06-28 2022-02-01 Jasper Display Corp. Backplane for an array of emissive elements

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US5003019A (en) * 1987-03-02 1991-03-26 Mitsui Petrochemical Industries, Ltd. Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers
DE3726325A1 (en) * 1987-08-07 1989-02-16 Hoechst Ag METHOD FOR PRODUCING AN OLEFIN POLYMER
DE68911435T2 (en) * 1988-09-05 1994-04-28 Idemitsu Kosan Co Process for the production of a polymer.
DE3835044A1 (en) * 1988-10-14 1990-04-19 Hoechst Ag Process for the preparation of cycloolefin polymers
DE3922546A1 (en) * 1989-07-08 1991-01-17 Hoechst Ag METHOD FOR THE PRODUCTION OF CYCLOOLEFINPOLYMERS

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5602219A (en) * 1993-02-12 1997-02-11 Hoechst Aktiengesellschaft Process for preparing cycloolefin copolymers
US5637400A (en) * 1993-02-12 1997-06-10 Hoechst Aktiengesellschaft Cycloolefin copolymers having low melt viscosity and low optical attenuation
US5733991A (en) * 1993-02-12 1998-03-31 Hoechst Aktiengesellschaft Process for preparing cycloolefin polymer
US6214951B1 (en) 1993-02-12 2001-04-10 Hoechst Aktiengesellschaft Cycloolefin copolymers having high tear strength and low optical attenuation
US7829633B2 (en) 2002-09-13 2010-11-09 Ticona Gmbh Method for the production of a packaging made of thermoformable film having high thermal stability and a vapour barrier
US7205040B2 (en) 2003-11-10 2007-04-17 Mitsubishi Polyester Film Gmbh Peelable polyester film having improved oxygen barrier, process for its production and its use

Also Published As

Publication number Publication date
AU8777791A (en) 1992-05-21
NO914439L (en) 1992-05-15
AU641291B2 (en) 1993-09-16
JP3247130B2 (en) 2002-01-15
NO914439D0 (en) 1991-11-13
ATE165372T1 (en) 1998-05-15
DE59108971D1 (en) 1998-05-28
ZA918990B (en) 1992-07-29
EP0485893A1 (en) 1992-05-20
EP0485893B1 (en) 1998-04-22
KR100230915B1 (en) 1999-11-15
HU913539D0 (en) 1992-01-28
ES2117632T3 (en) 1998-08-16
KR920009859A (en) 1992-06-25
HUT59429A (en) 1992-05-28
CS344291A3 (en) 1992-09-16
TW227005B (en) 1994-07-21
JPH04268312A (en) 1992-09-24
CA2055397C (en) 2004-04-20

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