CA2038209C - Low-temperature bleaching compositions - Google Patents
Low-temperature bleaching compositionsInfo
- Publication number
- CA2038209C CA2038209C CA002038209A CA2038209A CA2038209C CA 2038209 C CA2038209 C CA 2038209C CA 002038209 A CA002038209 A CA 002038209A CA 2038209 A CA2038209 A CA 2038209A CA 2038209 C CA2038209 C CA 2038209C
- Authority
- CA
- Canada
- Prior art keywords
- benzenesulfonamide
- composition according
- acid
- group
- sulf
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
- A61Q11/02—Preparations for deodorising, bleaching or disinfecting dentures
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/392—Heterocyclic compounds, e.g. cyclic imides or lactames
Abstract
A bleaching composition is described that includes a peroxygen compound such as sodium perborate, an oxygen transfer agent, suchas sulfonimine, and a bleach precursor such as TAED.
These sulfonimines at relatively low concentration enhance the activity of the precursor.
A method for bleaching substrates is also provided, especially a method for cleaning fabrics.
These sulfonimines at relatively low concentration enhance the activity of the precursor.
A method for bleaching substrates is also provided, especially a method for cleaning fabrics.
Description
2~3~2~
C 6115 (R) LOW--TEMPERATURE BLEAC~IING COMPOSITIONS
1~ ~ield of the Invention The invention relates to a new type of low-temperature bleaching system and a method for cleaning substrates therewith.
2. The Related Art Many household and personal care products are formulated with an active oxygen-releasing material to effect ~ ~dl of stain and soil. Oxygen-releasing materials have an important limitation; their activity is exL~ -ly temperature-dependent. Temperatures in excess of 60~C are n~ lly required to achieve any bleach effectiveness in an aqueous wash system. Esp~cially for cleaning fabrics, high-temperature operation is both econo~ically and practically disadvantageous.
The art has partially solved the aforementioned problem through the use of activators. These activators, also known as bleach precursors, often appear in the form of carboxylic acid esters or amides. In an aqueous liquor, anions of hy~r oyen peroxide react with the ester or amide to generate a corresponding peroxyacid which oxidizes the stained substrate.
C~ -rcial application of this technology is found in certain ~abric bleaching detergent powders incorporating tetraacetylethylen~ ine (T~ED) and sodium nonanoyloxyben~ene sulfonate (SNOBS).
~AED is ef~ective only under warm-hot wash conditions, i.e above 30~C. Although this material is widely employed in Europe with laundry detergent, cold-water ~382~
C 6115 (R) consumer w~hin~ habits have not permitted use in the United States. SNOBS can operate at lower temperatures than TA~D. For this reason it has been ~ ~rcialized in the United States but its performance could still be improved.
Another problem with carboxylic acid ester or amide bleach precursors such as TAED and SNOBS is that conversion to peracid is inefficient. A further difficulty is that they are not catalytic. Once the ester or amide has been pell,y~lolyzed~ it can no longer be recycled. Accordingly, relatively large amounts of precursor are necessary. ~mounts as high as 8% may be n~ces~ry in a detergent formulation for bleaching fabrics. Cost for these relatively expensive chemicals is of major concern at such high use levels.
Outside the context of consumer products, there have been reports of catalytic oxidizing agents. F.A. Davis and co-workers, in a series of articles, reported preparation of a new class of stable oxidizing agents, namely 2-ar~n~llfonyl-3-aryl-oxaziridines. See Davis, Nadir, and ~luger, J.C.S. Chem Comm., 1977, 25; Davis, T~ -~ola Jr., Nadir, Kluger, Sederjarn, Panunto, Rill -rS~ JPnk;n~ Jr., Turchi, Watson, Chen and Kimura, J. Amer. ~hem. Soc., 1980, 102, 2000; and Davis, Chattopadhay, T~wson, Lal and Reedy, J.Orq. chem., 198~, S3, 2087. These oxaziridines were prepared by peracid or monopersulfate oxidation of a corresponding sulfonimine under alkaline conditions. In late lg88, Davis published a paper entitled "Selective Catalytic Oxidation of Sulfides to Sulfoxides Using N-sulfonyloxaziridines", J. Orq. Chem., 1988, 53, 5004. Therein described is a system ~here sulfonimine reacts with monopersulfate to generate an in situ toluene-water biphasic mixture.
Oxaziridine then coverts the sulfide to a sulfoxide and 2~382~
C 6115 (R) generates starting sulfonamine, thereby rendering the process catalytic in nature. Beyond use as a synthetic tool, there is no suggestion of any possible application for sulfonimine chemistry to the problem of removing stain in consumer applications, such as in cleaning fabrics.
It is an object of the present invention to provide an improved bleaching system and detergent composition containing such system that operates over a wide temperature range including that of under 60~C.
It is another object of the present invention to improve the performance of bleach precuraors that normally would be inoperative under low-temperature wash conditions~
A further object of the present invention is to provide bleach improvement through catalysts effective in relatively small amounts so as to avoid any substantial incremental costs.
A still further object of the present invention is to provide a method for bleaching stained substrates such as clothes, household hard surfaces including sinXs, toilets and the like, and even dentures.
other objects of the present invention will become apparent through the following summary, detailed discussion and examples.
~38~
C 6115 (R) SUMMARY OF THE INVENTION
A bleaching composition is provided comprising:
( i3 from about 1 to about 60% by weight of a peroxygen compound;
( ii) from about 0.05 to about 10% of an oxygen transfer agent whose structure is:
RlR2 C=NSo2R3 wherein:
Rl may be a substituted or unsubstituted radical selected from the group consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl and cycloalkyl radicals;
R2 may be a substituted or unsubstituted radical selected from the group consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl, cycloalkyl, RlC=NSo2R3, nitro, halo, cyano, alkoxy, keto, carboxylic ! and carboalkoxy radicals;
R3 may be a substituted or unsubstituted radical selected from the group consisting of phenyl, aryl, heterocyclic ring, alkyl, cycloalkyl, nitro, halo and cyano radicals;
Rl with R2 and R2 with R3 may respectively together form a cycloalkyl, heterocyclic, and aromatic ring system; and (iii) from about 0.1 to about 40% of a bleach precursor that reacts with peroxide anion and forms therewith a peracid, percarbonic acid or perimidic acid.
2~2~3 C 6115 (R) Additionally, there is provided a method for bleaching a stained substrate comprising treating the stained substrate with a peroxygen compound, an oxygen transfer agent whose structure is RlR2C=NSo2R3, with radical groups as defined above, and a bleach precursor.
2~382~
C 6115 (R) DETAILED DESCRIPTION
Now it has been found that relatively small amounts of sulfonimines can boost the performance of bleach precursor-peroxygen compound systems. Increased effectiveness has been noted on consumer and industrial articles whose stains can be removed even at relatively low temperatures. Thus, sulfonimine chemistry is more than a synthetic curiosity as in the conversion of sulfides to sulfoxides reported by Davis et al. Unlike the Davis et al biphasic system that requires an organic solvent, sulfonimines can be devised for use in completely aqueous wash systems.
Sulfonimines covered by the present invention are those whose structure is:
RlR2 C=NSo2R3 wherein:
Rl may be a suhstituted or unsubstituted radical selected from the group consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl, and cycloalkyl radicals;
R2 may be a substituted or unsubstituted radical selected from the group consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl, cycloalkyl/ RlC=NSo2R3 nitro, halo, cyano, alkoxy, keto, carboxylic and carboalkoxy radicals;
R3 may be a substituted or unsubstituted radical selected from the group consisting of phenyl, aryl, heteroeyelic rirlg, alkyl, cycloalkyl, nitro, halo, and cyano radieals; and R~ with R2 and R2 with R3 may respectively together form a cycloalkyl, heterocyclie or aromatic ring system.
20382~
C 6115 (R) Most advantageous are sulfonimines having at least one of Rl, R2, R3 substituted with a water-solubilizing functional group. These functional groups may be selected from carboxylates, phosphates, phosphonates, sulfates, sulfonates in acid or salt form. Suitable salts include those whose counter-ions are selected from alkali metal, ammonium, and C2-C6 alkanolammonium anlons.
Amine functional groups may also be incorporated into Rl, R2 or R3 to provide water-solubilization of the sulfonimines. An example combining the amine and heterocyclic structure is that of pyridine.
A water-solubilizing functional group is one which renders the sulfonimines soluble to the extent of at least 2 mg/l, preferably at least 25 mg/l, optimally at least 250 mg/l by weight in water at 25~C.
Heterocyclic rings according to this invention include cycloaliphatic and cycloaromatic type radicals incorporating an oxygen, sulfur and/or nitrogen atom within the ring system.
Representative nitrogen heterocycles include pyridine, pyrrole, imidazole, triazole, tetrazole, morpholine, pyrrolidine, piperidine and piperazine. Suitable oxygen heterocycles include furan, tetrahydrofuran and dioxane.
Sulfur heterocycles may include thiophene and tetrahydrothiophene. Among the various heterocycles, it has been found that those incorporating nitrogen are the most active.
The term "substituted" is defined in relation to Rl, R2, R3 as a substituent which is a nitro, halo, cyano, C1-C20 alkyl, amino, aminoalkyl, thioalkyl, sulfoal~yl, ~382~9 C 6115 (R) carboxyester, hydroxy, Cl-C20 alkoxy, polyalkoxy and Cl-C40 quaternary di- or tri-alkylammonium function.
Novel sulfonimine compounds are described below wherein Rl ifi hydrogen, R2 is phenyl with an X substituent, and R3 is phenyl with an Y substituent. Very often X and Y
groups are water-solubilizing groups, most commonly being carboxylic acid or salts thereof. Representative structures are as follows:
H\ / S02Ph-Y
X-Ph ~ NS02Ph-p-C02H
X Y
SULF 1 4-CO2H 4-Cl SULF 2 4-CO2H H ~
SULF 3 4-C1 4--C02H ~y SULF 10 SULF 6 4--C02H 3--N02 NS02Ph--p-C02H
SULF 8 4-OMo 4--CO2H
SULF 9 3-OH 4-Cl 2~382~9 C 6115 (R) Illustrative of cycloaromatic and of heterocyclic nitrogen ring sulfonimines are the respective SULF ll and SULF 12 whose structures are outlined below.
S~2 Ph-p~C1 S~2 N
The following further compounds are illustrative of sulfonimines within the present invention.
N-Benzylidenebenzenesulfonamide N-(4-Methylsulfinylbenzylidene)benzenesulfonamide N-~4-Methylsulfonylbenzylidene)benzenesulfonamide N-(3-Pyridinylmethylene)benzenesulfonamide N-(4-Pyridinylmethylene)benzenesulfonamide N-(2-Pyridinylmethylene)benzenesulfonamide N-Benzylidene-3-pyridinesulfonamide
C 6115 (R) LOW--TEMPERATURE BLEAC~IING COMPOSITIONS
1~ ~ield of the Invention The invention relates to a new type of low-temperature bleaching system and a method for cleaning substrates therewith.
2. The Related Art Many household and personal care products are formulated with an active oxygen-releasing material to effect ~ ~dl of stain and soil. Oxygen-releasing materials have an important limitation; their activity is exL~ -ly temperature-dependent. Temperatures in excess of 60~C are n~ lly required to achieve any bleach effectiveness in an aqueous wash system. Esp~cially for cleaning fabrics, high-temperature operation is both econo~ically and practically disadvantageous.
The art has partially solved the aforementioned problem through the use of activators. These activators, also known as bleach precursors, often appear in the form of carboxylic acid esters or amides. In an aqueous liquor, anions of hy~r oyen peroxide react with the ester or amide to generate a corresponding peroxyacid which oxidizes the stained substrate.
C~ -rcial application of this technology is found in certain ~abric bleaching detergent powders incorporating tetraacetylethylen~ ine (T~ED) and sodium nonanoyloxyben~ene sulfonate (SNOBS).
~AED is ef~ective only under warm-hot wash conditions, i.e above 30~C. Although this material is widely employed in Europe with laundry detergent, cold-water ~382~
C 6115 (R) consumer w~hin~ habits have not permitted use in the United States. SNOBS can operate at lower temperatures than TA~D. For this reason it has been ~ ~rcialized in the United States but its performance could still be improved.
Another problem with carboxylic acid ester or amide bleach precursors such as TAED and SNOBS is that conversion to peracid is inefficient. A further difficulty is that they are not catalytic. Once the ester or amide has been pell,y~lolyzed~ it can no longer be recycled. Accordingly, relatively large amounts of precursor are necessary. ~mounts as high as 8% may be n~ces~ry in a detergent formulation for bleaching fabrics. Cost for these relatively expensive chemicals is of major concern at such high use levels.
Outside the context of consumer products, there have been reports of catalytic oxidizing agents. F.A. Davis and co-workers, in a series of articles, reported preparation of a new class of stable oxidizing agents, namely 2-ar~n~llfonyl-3-aryl-oxaziridines. See Davis, Nadir, and ~luger, J.C.S. Chem Comm., 1977, 25; Davis, T~ -~ola Jr., Nadir, Kluger, Sederjarn, Panunto, Rill -rS~ JPnk;n~ Jr., Turchi, Watson, Chen and Kimura, J. Amer. ~hem. Soc., 1980, 102, 2000; and Davis, Chattopadhay, T~wson, Lal and Reedy, J.Orq. chem., 198~, S3, 2087. These oxaziridines were prepared by peracid or monopersulfate oxidation of a corresponding sulfonimine under alkaline conditions. In late lg88, Davis published a paper entitled "Selective Catalytic Oxidation of Sulfides to Sulfoxides Using N-sulfonyloxaziridines", J. Orq. Chem., 1988, 53, 5004. Therein described is a system ~here sulfonimine reacts with monopersulfate to generate an in situ toluene-water biphasic mixture.
Oxaziridine then coverts the sulfide to a sulfoxide and 2~382~
C 6115 (R) generates starting sulfonamine, thereby rendering the process catalytic in nature. Beyond use as a synthetic tool, there is no suggestion of any possible application for sulfonimine chemistry to the problem of removing stain in consumer applications, such as in cleaning fabrics.
It is an object of the present invention to provide an improved bleaching system and detergent composition containing such system that operates over a wide temperature range including that of under 60~C.
It is another object of the present invention to improve the performance of bleach precuraors that normally would be inoperative under low-temperature wash conditions~
A further object of the present invention is to provide bleach improvement through catalysts effective in relatively small amounts so as to avoid any substantial incremental costs.
A still further object of the present invention is to provide a method for bleaching stained substrates such as clothes, household hard surfaces including sinXs, toilets and the like, and even dentures.
other objects of the present invention will become apparent through the following summary, detailed discussion and examples.
~38~
C 6115 (R) SUMMARY OF THE INVENTION
A bleaching composition is provided comprising:
( i3 from about 1 to about 60% by weight of a peroxygen compound;
( ii) from about 0.05 to about 10% of an oxygen transfer agent whose structure is:
RlR2 C=NSo2R3 wherein:
Rl may be a substituted or unsubstituted radical selected from the group consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl and cycloalkyl radicals;
R2 may be a substituted or unsubstituted radical selected from the group consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl, cycloalkyl, RlC=NSo2R3, nitro, halo, cyano, alkoxy, keto, carboxylic ! and carboalkoxy radicals;
R3 may be a substituted or unsubstituted radical selected from the group consisting of phenyl, aryl, heterocyclic ring, alkyl, cycloalkyl, nitro, halo and cyano radicals;
Rl with R2 and R2 with R3 may respectively together form a cycloalkyl, heterocyclic, and aromatic ring system; and (iii) from about 0.1 to about 40% of a bleach precursor that reacts with peroxide anion and forms therewith a peracid, percarbonic acid or perimidic acid.
2~2~3 C 6115 (R) Additionally, there is provided a method for bleaching a stained substrate comprising treating the stained substrate with a peroxygen compound, an oxygen transfer agent whose structure is RlR2C=NSo2R3, with radical groups as defined above, and a bleach precursor.
2~382~
C 6115 (R) DETAILED DESCRIPTION
Now it has been found that relatively small amounts of sulfonimines can boost the performance of bleach precursor-peroxygen compound systems. Increased effectiveness has been noted on consumer and industrial articles whose stains can be removed even at relatively low temperatures. Thus, sulfonimine chemistry is more than a synthetic curiosity as in the conversion of sulfides to sulfoxides reported by Davis et al. Unlike the Davis et al biphasic system that requires an organic solvent, sulfonimines can be devised for use in completely aqueous wash systems.
Sulfonimines covered by the present invention are those whose structure is:
RlR2 C=NSo2R3 wherein:
Rl may be a suhstituted or unsubstituted radical selected from the group consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl, and cycloalkyl radicals;
R2 may be a substituted or unsubstituted radical selected from the group consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl, cycloalkyl/ RlC=NSo2R3 nitro, halo, cyano, alkoxy, keto, carboxylic and carboalkoxy radicals;
R3 may be a substituted or unsubstituted radical selected from the group consisting of phenyl, aryl, heteroeyelic rirlg, alkyl, cycloalkyl, nitro, halo, and cyano radieals; and R~ with R2 and R2 with R3 may respectively together form a cycloalkyl, heterocyclie or aromatic ring system.
20382~
C 6115 (R) Most advantageous are sulfonimines having at least one of Rl, R2, R3 substituted with a water-solubilizing functional group. These functional groups may be selected from carboxylates, phosphates, phosphonates, sulfates, sulfonates in acid or salt form. Suitable salts include those whose counter-ions are selected from alkali metal, ammonium, and C2-C6 alkanolammonium anlons.
Amine functional groups may also be incorporated into Rl, R2 or R3 to provide water-solubilization of the sulfonimines. An example combining the amine and heterocyclic structure is that of pyridine.
A water-solubilizing functional group is one which renders the sulfonimines soluble to the extent of at least 2 mg/l, preferably at least 25 mg/l, optimally at least 250 mg/l by weight in water at 25~C.
Heterocyclic rings according to this invention include cycloaliphatic and cycloaromatic type radicals incorporating an oxygen, sulfur and/or nitrogen atom within the ring system.
Representative nitrogen heterocycles include pyridine, pyrrole, imidazole, triazole, tetrazole, morpholine, pyrrolidine, piperidine and piperazine. Suitable oxygen heterocycles include furan, tetrahydrofuran and dioxane.
Sulfur heterocycles may include thiophene and tetrahydrothiophene. Among the various heterocycles, it has been found that those incorporating nitrogen are the most active.
The term "substituted" is defined in relation to Rl, R2, R3 as a substituent which is a nitro, halo, cyano, C1-C20 alkyl, amino, aminoalkyl, thioalkyl, sulfoal~yl, ~382~9 C 6115 (R) carboxyester, hydroxy, Cl-C20 alkoxy, polyalkoxy and Cl-C40 quaternary di- or tri-alkylammonium function.
Novel sulfonimine compounds are described below wherein Rl ifi hydrogen, R2 is phenyl with an X substituent, and R3 is phenyl with an Y substituent. Very often X and Y
groups are water-solubilizing groups, most commonly being carboxylic acid or salts thereof. Representative structures are as follows:
H\ / S02Ph-Y
X-Ph ~ NS02Ph-p-C02H
X Y
SULF 1 4-CO2H 4-Cl SULF 2 4-CO2H H ~
SULF 3 4-C1 4--C02H ~y SULF 10 SULF 6 4--C02H 3--N02 NS02Ph--p-C02H
SULF 8 4-OMo 4--CO2H
SULF 9 3-OH 4-Cl 2~382~9 C 6115 (R) Illustrative of cycloaromatic and of heterocyclic nitrogen ring sulfonimines are the respective SULF ll and SULF 12 whose structures are outlined below.
S~2 Ph-p~C1 S~2 N
The following further compounds are illustrative of sulfonimines within the present invention.
N-Benzylidenebenzenesulfonamide N-(4-Methylsulfinylbenzylidene)benzenesulfonamide N-~4-Methylsulfonylbenzylidene)benzenesulfonamide N-(3-Pyridinylmethylene)benzenesulfonamide N-(4-Pyridinylmethylene)benzenesulfonamide N-(2-Pyridinylmethylene)benzenesulfonamide N-Benzylidene-3-pyridinesulfonamide
3-Trimethylammoniomethyl-1,2-benzisothiazole-1,1-dioxide chloride salt 1,2-Benzisothiazole-1,1-dioxide N-(N-Methyl~3-pyridinylmethylene)benzenesulfonamide chloride salt N-(4-Trimethylammoniobenzylidene)benzenesulfonamine chloride salt N-Benzylidene-4-trimethylammoniobenzenesulfonamide chloride salt N-(4-Cholyloxycarbonylbenzylidene)benzenesulfonamide chloride salt N-Benzylidene-4-cholyloxycarbonylbenzenesulfonamide chloride salt N-(4-Sulfoethylcarbonylbenzylidene)benzenesulfonamide sodium salt 2~38299 C 6115 (R) Methyl N-(p-tolylsulfonyl)iminoacetate Phenylsulfonyliminoacetic acid N-(~-Methylbenzylidene)benzenesulfonamide N-Isopropylidenebenzenesulfonamide N~Benzylidenemethanesulfonamide N-(4-Carboxybenzylidene)methanesulfonamide N-Benzylidenetrifluoromethanesulfonamide N-(2,2,3,3,4,4,4 Heptafluorobutylidene)benzene sulfonamide N-(4-Dimethylsulfoniumbenzylidene)benzenesulfonamide chloride salt N-(2-Furfurylidene)-4-carboxybenzenesulfonamide N-(2-Pyrrolylmethylene)benzenesulfonamide N-(4-Phenoxycarbonylbenzylidene)benzene sulfonamide N-(2,6-Dicarboxy-4-pyridinylmethylene)benzene sulfonamide disodium salt The foregoing oxygen transfer agents may be incorporated into detergent bleach compositions along with a further essential component which is a peroxygen compound capable of yielding peroxide anion in an aqueous solution.
Amounts of oxygen transfer agent suitable for the present invention may range from about 0~05 to 10%, preferably from about 0.2 to 5%, optimally between about 0.5% and 1.5% by weight of the composition.
The peroxygen compound may be present from about 1% to 65%, preferably from about 1.5% to 25%, optimally between about 2% and 10% by weight.
The molar ratio of peroxide anion (or a peroxygen compound yenerating the equivalent amount of peroxide anion) to oxygen transfer agent will range from about 2~8~
11 C 6115 (R) 1500:1 to 1:2, preferably about lS0:1 to 1:1, optimally between about 60:1 to 3:1.
Amounts of bleach precursor relative to oxygen transfer agent will be present in the molar ratio from about 250:1 to about 1:20, preferably from about 100:1 to about 1:1, optimally between about 25:1 to 2:1.
Peroxide anion sources are well known in the art. They include the alkali metal peroxides, organic peroxides such as urea peroxide, and inorganic persalts, such as the alkali metal perborates, percarbonates, perphosphates, persilicates and persulfates. Mixtures of two or more such compounds may also be suitable.
Particularly preferred are sodium perborate tetrahydrate and, especially, sodium perborate monohydrate. Sodium perborate monohydrate is preferred because it has excellent storage stability while also dissolving very quickly in aqueous solutions.
Alkylhydroperoxides are another suitable class of peroxygen compounds. Examples of these materials include cumene hydroperoxide and t-butyl hydroperoxide.
Organic peroxy acids may also be suitable as the peroxygen compound. Such materials have a general formula:
o HO-O-C-R-Y
wherein R is an alkylene or substituted alkylene group containing from 1 to about 22 carbon atoms or a phenylene or substituted phenylene group, and Y is hydrogen, halogen, alkyl, aryl or ~382~9 C 6115 (R) O O
u 11 ~C-OH or -C-O-OH
The organic peroxy acids usable in the present invention can contain either or two peroxy groups and can be either aliphatic or aromatic. When the organic peroxy acid is aliphatic, the unsubstituted acid has the general formula:
o HO-O-C-(CH2)n~Y
wher~ Y can be, for example, H, CH3, CH2Cl, COOH, or COOOH; and n is an integer from 1 to 20.
When the organic peroxy acid is aromatic, the unsubstituted acid has the general formula:
o wherein Y is hydrogen, alkyl, alkylhalogen, halogen, or COOH or COOOH.
Typical monoperoxy acids useful herein include alkyl peroxy acids and aryl peroxy acids such as:
( i) peroxybenzoic acid and ring-substituted peroxybenzoic acids, e.g. peroxy-~-naphthoic acid;
( ii) aliphatic, substituted aliphatic and arylalkyl monoperoxy acids, e.g. peroxylauric acid, peroxystearic acid, and N,N-phthaloylaminoperoxycaproic acid.
Typical diperoxy acids useful herein include alkyl diperoxy acids and aryldiperoxy acids, such as:
2~3~2~
C 6115 (~) tiii) 1,12 diperoxydodecanedioic acid;
( iv) l,9-diperoxyazelaic acid;
( v) diperoxybrassylic acid; diperoxysebacic acid and diperoxyisophthalic acid;
( vi) 2-decyldiperoxybutane-1,4-dioic acid;
(vii) 4,4'-sulfonylbisperoxybenzoic acid.
Particularly preferred organic acids are peracetic acid, monoperoxyphthalic acid (magnesium salt hexahydrate), and diperoxydodecanedioic acid. Under certain circumstances, hydrogen peroxide itself may directly be employed as the peroxygen compound.
A third critical element in the composition of this invention is a bleach precursor that reacts with peroxide anion and forms therewith a peracid, percarbonic acid or perimidic acid. Precursors of this invention are water-soluble materials, being soluble generally to an extent of at least 1%, preferably at least about 5% by weight at 25~C and pH 7. Certain precursors of this invention may further be defined by the Per-Acid Formation Test wherein the precursor will have a titre of at least 1.5 ml of 0.1 N sodium thiosulphate. This test may be found in US 3,177,148 (Bright et al) herein incorporated by reference.
Precursors which may be utilized for purposes of the present invention include :
(a) N-diacylated and N'N'-polyacylated amines, such as N,N,N',N'-tetraacetyl methylene diamine and N,N,N',N'-tetraacetyl ethylene diamine, N,N-2~3~9 C S115 (R) diacetylaniline, N,N-diacetyl-p-toluidine; 1,3-diacylated hydantoins such as, for example, 1,3-diacetyl-5, 5-dimethyl hydantoin and 1,3-dipropionyl hydantoin; acetoxy-(N,N,N')-polyacylmalonamide, for example acetoxy-(N,N')-diacetylmalonamide;
(b) N-alkyl-N-sulphonyl carbonamides, for example the compounds N-metyl-N-mesyl-acetamide, N-methyl-N-mesylbenzamide, N-methyl-N-mesyl-p-nitrobenzamide, and N-methyl-N-mesyl-p-methoxybenzamide;
(c) N-acylated cyclic hydrazides, acylated triazones or urazoles, for example monoacetylmaleic acid hydrazide;
(d) O,N,N-trisubstituted hydroxylamines, such as O-benzoyl-N,N-succinyl hydroxylamine, O-acetyl-N,N-succinylhydroxylamine, O-p-methoxybenzoyl-N,N-succinylhydroxylamine, O-p-nitrobenzoyl-N,N-succinylhydroxylamine and O,N,N-triacetyl hydroxylamine;
(e~ N,N'-diacyl-sulphurylamides, for example N,N'-dimethyl-N,N'-diacetyl-sulphurylamide and N,N'-diethyl-N,N'-dipropionyl sulphurylamide;
(f) Triacyanurates, for example triacetyl cyanurate and tribenzoyl cyanurate;
(g) Car~oxylic acid anhydrides, such as benzoic anyhride, m-chloro-benzoic anhydride, phthalic an~ydride, 4-chloro phthalic anhydride;
(h) Esters, for example glycose pentaacetate, xylose tetraacetate, sodium acetyloxybenzene sulfonate, sodium nanoyloxybenzene sulfonate and sodium benzoyloxybenzenesulfonate;
(i) 1,3-Diacyl-4,5-diacyloxy-imidazolidine, for example 1,3~diformyl-4,5-diacetoxy-imidazoline, 1,3-diacetyl-4,5-diacetoxy-imidazoline, 1,3-diacetyl-4,5-dipropionyloxy-imidazoline;
(j) Tetraacetylglycoluril and tetrapropionyl glycoluril;
2 ~ ~
C 6115 (R) (k) Diacylated 2,5-diketopiperazine, such as 1,4-diacetyl-2,5-diketopiperazine, 1,4-dipropionyl-2,5-diketopiperazine and 1,4-dipropionyl-3,6-dimethyl-2,5-diketopiperazine;
(l) Acylation products of propylenediurea or 2,2-dimethylpropylenediurea ~2,4,6,8-tetraaza-bicyclo-(3,3,1)-nonane~3,7~dione or its 9,9-dimethyl derivative), especially the tetraacetyl- or the tetrapropionylpropylenediurea or their dimethyl derivatives;
(m~ Carbonic acid esters, for example the sodium salts of p-(ethoxycarbonyloxy)-benzoic acid and p-(propoxycarbonyloxy)-benzenesulphonic acid;
(n) Acyloxy-(N,N')polyacyl malonamides, auch as alpha-acetoxy(N,N')diacetyl malonamide; and (o) Quaternary ammonium substituted peroxycarbonic or carboxylic acid esters such as 2-(N,N,N-trimethyl ammonium) ethyl sodium 4-sulphophenyl carbonate.
The precursors mentioned under (a), (h) and (j) are of special interest, particularly N,N,N',N'-tetraacetyl-ethylene-diamine (TAED), tetraacetyl-glycoluril (TAGU), glucose pentaacetate, xylose tetraacetate, sodium acetyloxybenzene sulfonate (SABS) and sodium nonanoyloxybenzene sulfonate (SNOBS).
Bleach systems of the present invention may be employed for a wide variety of purposes, but are especially useful in the cleaning of laundry. When intended for such purpose, the peroxygen compound, oxygen transfer agent and precursor of the present invention will usually also be combined with surface-active materials, detergency builders and other known ingredients of laundry detergent formulations.
~3~9 C 6115 (R) The surface-active mater.ial may be naturally derived, or synthetic material selected from anionic, nonionic, amphoteric, zwitterionic, cationic actives and mixtures thereof. Many suitable actives are commercially available and are fully described in the literature, for example in "Surface Active Agents and Detergents", Volumes I and II, by Schwartz, Perry and Berch. The total level of the surface-active material may range up to 50% by weight, preferably being from about 0.5 to 40% by weight of the composition, most preferably 4 to 25%.
Synthetic anionic surface-actives are usually water-soluble alkali metal salts of organic sulphates and sulphonates having alkyl radicals containing from about 8 to about 22 carbon atoms.
Examples of suitable synthetic anionic detergent compounds are sodium and ammonium alkyl sulphates, especially those obtained by sulphating higher (C8-C18) alcohols produced, for example, from tallow or coconut oil; sodium and ammonium alkyl (Cg-C20) benzene sulphonates, sodium alkyl glyceryl ether sulphates, especially those ethers of the higher alcohols derived from tallow or coconut oil and synthetic alcohols derived from petroleum; sodium coconut oil fatty acid monoglycerîde sulphates and sulphonates; sodium and ammonium salts of sulphuric acid esters of higher (Cg-C18) fatty alcohol alkylene oxide, particularly ethylene oxide, reaction products; the reaction products of fatty acids such as coconut fatty acids esterified with isethionic acid and neutralized with sodium hydroxide; sodium and ammonium salts of fatty acid amides of methyl taurine; alkane monosulphonates such as those derived by reacting alpha-olefins (C8-C20) with sodium bisulphite and those derived by reacting 2~382~
17 C 6115 (R) paraffins with S02 and C12 and then hydrolyzing with a base to produce a random sulphonate; sodium and ammonium C7-C12 dialkyl sulfosuccinates; and olefin sulphonates, which term is used to describe the material made by reacting olefins, particularly C10-C20 alpha-olefins, with SO3 and then neutralizing and hydrolyzing the reaction product. The preferred anionic detergent compounds are sodium (Cl1-C15) alkylbenzene sulphonates, sodium ~Cl6-C18) alkyl sulphates and sodium ~Cl6-C18) alkyl ether sulphates.
Examples of suitable nonionic surface-active compounds which may be used, preferably together with the anionic surface-active compounds, include in particular the reaction products of alkylene oxides t usually ethylene oxide, with alkyl (C6-C22) phenols, generally 5-25 EO, i.e. 5-25 units of ethylene oxide per molecule; the condensation products of aliphatic (C8-Cl8) primary or secondary linear or branched alcohols with ethylene oxide, generally 2-30 EO, and prsducts made by condensation of ethylene oxide with the reaction products of propylene oxide and ethylene diamine. Other so-called nonionic surface-actives include alkyl polyglycosides, long chain tertiary amine oxides, long chain tertiary phosphine oxides and dialkyl sulphoxides.
Amphoteric or zwitterionic surface-active compounds can also be used in the compositions of the invention but this is not normally desired owing to their relatively high cost. If any amphoteric or zwittexionic detergent compounds are used, it is generally in small amounts in compositions based on the much more commonly used synthetic anionic and nonionic actives.
Soaps may also be incorporated into the compositions of the invention, preferably at a level of less than 30~ by ~2~3~2~
C 6115 (R) weight. They are particularly useful at low levels in binary (soap/anionic) or ternary mixtures together with nonionic or mixed synthetic anionic and nonionic compounds. Soaps which are used are preferably the sodium, or less desirably potassium, salts of saturated or unsaturated C10-C24 fatty acids or mixtures thereof.
The amount of such soaps can be varied between about 0.5% and about 25% by weight, with lower amounts of about 0.5% to about 5% being generally sufficient for lather control. Amounts of soap between about 2% and about 20%, especially between about 5% and about 15%, are used to give a beneficial effect on detergency. This is particularly valuable in compositions used in hard water when the soap acts as a supplementary builder.
The detergent compositions of the invention will normally also contain a detergency builder. Builder materials may be selected from (1) calcium sequestrant materials, (2) precipitating materials, (3~ calcium ion-exchange materials and (4) mixtures thereof.
In particular, the compositions of the invention may contain any one of the organic or inorganic builder materials, such as sodium or potassium tripolyphosphate, sodium or potassium pyrophosphate, sodium or potassium orthophosphate, sodium carbonate, the sodium salt of nitrilotriacetic acid, sodium citrate, carboxymethyl malonate, carboxymethyloxysuccinate, tartrate mono- and di-succinates, oxydisuccinate, crystalline or amorphous aluminosilicates and mixtures thereof.
Polycarboxylic homo- and co-polymers may also be included as builders and to function as powder structurants or processing aids. Particularly preferred are polyacrylic acid (available under the trademark Acrysol from the Rohm and Haas Company) and acrylic-2~382~
C 6115 (R) maleic acid co-polymers (available under the trademark Sokalan from the BASF Corporation) and alkali metal or other salts thereof.
These builder materials may be present at a level of, for example, from about l to 80% by weight, preferably from 10 to 60% by weight.
Upon dispersal in a wash water, the initial amount of peroxygen compound should range anywhere from about 0.05 to about 250 ppm active oxygen per liter of water, preferably between about 1 to 50 ppm. Within the wash media, the amount of oxygen transfer agent initially present should be from about 0.01 to about 300 ppm, preferably from about 5 to 100 ppm. Bleach precursor may be present in the wash media in an amount from about 0.05 to 20 ppm, preferably from about 5 to about 100 ppm. Surfactant should be present in the wash water from about 0.05 to 1.0 grams per liter, preferably from 0.15 to 0.20 grams per liter. When present, the builder amount will range from about 0.1 to 3.0 grams per liter.
Apart from the components already mentioned, the detergent compositions of the invention can contain any of the conventional additives in the amounts in which such materials are normally employed in fabric washing detergent compositions. Examples of these additives include lather boosters such as alkanolamides, particularly the monoethanolamides derived from palmkernel fatty acids and coconut fatty acids~ lather depressants such as alkyl phosphates and silicones, anti-redeposition agents such as sodium carboxymethylcellulose and alkyl or substituted alkylcellulose ethers, other stabilizers such as ethylene diamine tetraacetic acid and phosphonic acid derivatives (Dequest ~ , fabric softening agents, 2~1382~
C 6115 (R) inorganic salts such as sodium sulphate, and, usually present in very small amounts, fluorescent agents, perfumes, enzymes such as proteases, cellulases, lipases and amylases, germicides and colorants.
The oxygen transfer agents in combination with a peroxygen compound may be useful for removing stains both in consumer type products and for industrial applications. ~mong consumer products incorporating this invention are laundry detergents, laundry bleaches, hard surface cleaners, toilet bowl cleaners, automatic dishwashing compositions and even denture cleaners.
Stained consumer products benefiting from treatment with compositions of this invention may include clothes and other fabrics; household fixtures and appliances such as sinks, toilet bowls and oven ranges; tableware such as drinking glasses, dishes, cookware and utensils; and even dentures. ~air colorants may also be fGrmulated with the bleach composition of this invention.
The bleaching system of this invention may also be applied to industrial uses such as for the bleaching of wood pulp.
The system of the present invention may be delivered in a variety of product forms including powders, on sheets or other substrates, in pouches, in tablets, in aqueous liquids, or in non-aqueous liquids such as liquid nonionic detergents.
The following examples will more fully illustrate the embodiments of this invention. All parts, percentages and proportions referred to herein and in the appended claims are by weight unless otherwise illustrated.
~382~
C 6115 (R) Synthesis of N-Sulfonimines Sulfonimines used for the present invention were prepared by a modified version of procedures set forth by Davis et al~ Synthesis of the imines was accomplished by condensing commercially available aromatic aldehydes and sulfonamides. Thus, sulfonimines were prepared by heating equimolar amounts of the requisite sulfonamide and aldehyde in either toluene or chlorobenzene containing a catalytic amount of toluenesulfonic acid.
Reaction vessels were either fitted with a drying tube (calcium sulfate) or with a nitrogen flow system. Any water formed from these condensations was removed by equipping the reaction vessels with a Soxhlet extractor cont~;ning 3A molecular sieves. Formation of product sulfonimines was monitored by TLC and lH NMR analyses.
Complete reaction times varied from 1.5 hours to 2 days.
The carboxysulfonimine products were isolated by filtering the reaction mixtures at room temperature.
Specific syntheses are outlined in the following examples which focus upon product yield and spectroscopic analyses.
N-Benzylidenebenzenesulfonamide was prepared by reacting an equimolar mixture of benzenesulfonamide and benzaldehyde diethyl acetal as described by Davis et al.
in J. Amer. Chem. Soc., 1980, 102, 2000.
~382~
C 6115 (R) N-(4~Carboxybenzylidene)-4--chlorobenzenesulfonamide (SULF-l) A well-stirred slurry consisting of 4.64 g (31 mmol) of
Amounts of oxygen transfer agent suitable for the present invention may range from about 0~05 to 10%, preferably from about 0.2 to 5%, optimally between about 0.5% and 1.5% by weight of the composition.
The peroxygen compound may be present from about 1% to 65%, preferably from about 1.5% to 25%, optimally between about 2% and 10% by weight.
The molar ratio of peroxide anion (or a peroxygen compound yenerating the equivalent amount of peroxide anion) to oxygen transfer agent will range from about 2~8~
11 C 6115 (R) 1500:1 to 1:2, preferably about lS0:1 to 1:1, optimally between about 60:1 to 3:1.
Amounts of bleach precursor relative to oxygen transfer agent will be present in the molar ratio from about 250:1 to about 1:20, preferably from about 100:1 to about 1:1, optimally between about 25:1 to 2:1.
Peroxide anion sources are well known in the art. They include the alkali metal peroxides, organic peroxides such as urea peroxide, and inorganic persalts, such as the alkali metal perborates, percarbonates, perphosphates, persilicates and persulfates. Mixtures of two or more such compounds may also be suitable.
Particularly preferred are sodium perborate tetrahydrate and, especially, sodium perborate monohydrate. Sodium perborate monohydrate is preferred because it has excellent storage stability while also dissolving very quickly in aqueous solutions.
Alkylhydroperoxides are another suitable class of peroxygen compounds. Examples of these materials include cumene hydroperoxide and t-butyl hydroperoxide.
Organic peroxy acids may also be suitable as the peroxygen compound. Such materials have a general formula:
o HO-O-C-R-Y
wherein R is an alkylene or substituted alkylene group containing from 1 to about 22 carbon atoms or a phenylene or substituted phenylene group, and Y is hydrogen, halogen, alkyl, aryl or ~382~9 C 6115 (R) O O
u 11 ~C-OH or -C-O-OH
The organic peroxy acids usable in the present invention can contain either or two peroxy groups and can be either aliphatic or aromatic. When the organic peroxy acid is aliphatic, the unsubstituted acid has the general formula:
o HO-O-C-(CH2)n~Y
wher~ Y can be, for example, H, CH3, CH2Cl, COOH, or COOOH; and n is an integer from 1 to 20.
When the organic peroxy acid is aromatic, the unsubstituted acid has the general formula:
o wherein Y is hydrogen, alkyl, alkylhalogen, halogen, or COOH or COOOH.
Typical monoperoxy acids useful herein include alkyl peroxy acids and aryl peroxy acids such as:
( i) peroxybenzoic acid and ring-substituted peroxybenzoic acids, e.g. peroxy-~-naphthoic acid;
( ii) aliphatic, substituted aliphatic and arylalkyl monoperoxy acids, e.g. peroxylauric acid, peroxystearic acid, and N,N-phthaloylaminoperoxycaproic acid.
Typical diperoxy acids useful herein include alkyl diperoxy acids and aryldiperoxy acids, such as:
2~3~2~
C 6115 (~) tiii) 1,12 diperoxydodecanedioic acid;
( iv) l,9-diperoxyazelaic acid;
( v) diperoxybrassylic acid; diperoxysebacic acid and diperoxyisophthalic acid;
( vi) 2-decyldiperoxybutane-1,4-dioic acid;
(vii) 4,4'-sulfonylbisperoxybenzoic acid.
Particularly preferred organic acids are peracetic acid, monoperoxyphthalic acid (magnesium salt hexahydrate), and diperoxydodecanedioic acid. Under certain circumstances, hydrogen peroxide itself may directly be employed as the peroxygen compound.
A third critical element in the composition of this invention is a bleach precursor that reacts with peroxide anion and forms therewith a peracid, percarbonic acid or perimidic acid. Precursors of this invention are water-soluble materials, being soluble generally to an extent of at least 1%, preferably at least about 5% by weight at 25~C and pH 7. Certain precursors of this invention may further be defined by the Per-Acid Formation Test wherein the precursor will have a titre of at least 1.5 ml of 0.1 N sodium thiosulphate. This test may be found in US 3,177,148 (Bright et al) herein incorporated by reference.
Precursors which may be utilized for purposes of the present invention include :
(a) N-diacylated and N'N'-polyacylated amines, such as N,N,N',N'-tetraacetyl methylene diamine and N,N,N',N'-tetraacetyl ethylene diamine, N,N-2~3~9 C S115 (R) diacetylaniline, N,N-diacetyl-p-toluidine; 1,3-diacylated hydantoins such as, for example, 1,3-diacetyl-5, 5-dimethyl hydantoin and 1,3-dipropionyl hydantoin; acetoxy-(N,N,N')-polyacylmalonamide, for example acetoxy-(N,N')-diacetylmalonamide;
(b) N-alkyl-N-sulphonyl carbonamides, for example the compounds N-metyl-N-mesyl-acetamide, N-methyl-N-mesylbenzamide, N-methyl-N-mesyl-p-nitrobenzamide, and N-methyl-N-mesyl-p-methoxybenzamide;
(c) N-acylated cyclic hydrazides, acylated triazones or urazoles, for example monoacetylmaleic acid hydrazide;
(d) O,N,N-trisubstituted hydroxylamines, such as O-benzoyl-N,N-succinyl hydroxylamine, O-acetyl-N,N-succinylhydroxylamine, O-p-methoxybenzoyl-N,N-succinylhydroxylamine, O-p-nitrobenzoyl-N,N-succinylhydroxylamine and O,N,N-triacetyl hydroxylamine;
(e~ N,N'-diacyl-sulphurylamides, for example N,N'-dimethyl-N,N'-diacetyl-sulphurylamide and N,N'-diethyl-N,N'-dipropionyl sulphurylamide;
(f) Triacyanurates, for example triacetyl cyanurate and tribenzoyl cyanurate;
(g) Car~oxylic acid anhydrides, such as benzoic anyhride, m-chloro-benzoic anhydride, phthalic an~ydride, 4-chloro phthalic anhydride;
(h) Esters, for example glycose pentaacetate, xylose tetraacetate, sodium acetyloxybenzene sulfonate, sodium nanoyloxybenzene sulfonate and sodium benzoyloxybenzenesulfonate;
(i) 1,3-Diacyl-4,5-diacyloxy-imidazolidine, for example 1,3~diformyl-4,5-diacetoxy-imidazoline, 1,3-diacetyl-4,5-diacetoxy-imidazoline, 1,3-diacetyl-4,5-dipropionyloxy-imidazoline;
(j) Tetraacetylglycoluril and tetrapropionyl glycoluril;
2 ~ ~
C 6115 (R) (k) Diacylated 2,5-diketopiperazine, such as 1,4-diacetyl-2,5-diketopiperazine, 1,4-dipropionyl-2,5-diketopiperazine and 1,4-dipropionyl-3,6-dimethyl-2,5-diketopiperazine;
(l) Acylation products of propylenediurea or 2,2-dimethylpropylenediurea ~2,4,6,8-tetraaza-bicyclo-(3,3,1)-nonane~3,7~dione or its 9,9-dimethyl derivative), especially the tetraacetyl- or the tetrapropionylpropylenediurea or their dimethyl derivatives;
(m~ Carbonic acid esters, for example the sodium salts of p-(ethoxycarbonyloxy)-benzoic acid and p-(propoxycarbonyloxy)-benzenesulphonic acid;
(n) Acyloxy-(N,N')polyacyl malonamides, auch as alpha-acetoxy(N,N')diacetyl malonamide; and (o) Quaternary ammonium substituted peroxycarbonic or carboxylic acid esters such as 2-(N,N,N-trimethyl ammonium) ethyl sodium 4-sulphophenyl carbonate.
The precursors mentioned under (a), (h) and (j) are of special interest, particularly N,N,N',N'-tetraacetyl-ethylene-diamine (TAED), tetraacetyl-glycoluril (TAGU), glucose pentaacetate, xylose tetraacetate, sodium acetyloxybenzene sulfonate (SABS) and sodium nonanoyloxybenzene sulfonate (SNOBS).
Bleach systems of the present invention may be employed for a wide variety of purposes, but are especially useful in the cleaning of laundry. When intended for such purpose, the peroxygen compound, oxygen transfer agent and precursor of the present invention will usually also be combined with surface-active materials, detergency builders and other known ingredients of laundry detergent formulations.
~3~9 C 6115 (R) The surface-active mater.ial may be naturally derived, or synthetic material selected from anionic, nonionic, amphoteric, zwitterionic, cationic actives and mixtures thereof. Many suitable actives are commercially available and are fully described in the literature, for example in "Surface Active Agents and Detergents", Volumes I and II, by Schwartz, Perry and Berch. The total level of the surface-active material may range up to 50% by weight, preferably being from about 0.5 to 40% by weight of the composition, most preferably 4 to 25%.
Synthetic anionic surface-actives are usually water-soluble alkali metal salts of organic sulphates and sulphonates having alkyl radicals containing from about 8 to about 22 carbon atoms.
Examples of suitable synthetic anionic detergent compounds are sodium and ammonium alkyl sulphates, especially those obtained by sulphating higher (C8-C18) alcohols produced, for example, from tallow or coconut oil; sodium and ammonium alkyl (Cg-C20) benzene sulphonates, sodium alkyl glyceryl ether sulphates, especially those ethers of the higher alcohols derived from tallow or coconut oil and synthetic alcohols derived from petroleum; sodium coconut oil fatty acid monoglycerîde sulphates and sulphonates; sodium and ammonium salts of sulphuric acid esters of higher (Cg-C18) fatty alcohol alkylene oxide, particularly ethylene oxide, reaction products; the reaction products of fatty acids such as coconut fatty acids esterified with isethionic acid and neutralized with sodium hydroxide; sodium and ammonium salts of fatty acid amides of methyl taurine; alkane monosulphonates such as those derived by reacting alpha-olefins (C8-C20) with sodium bisulphite and those derived by reacting 2~382~
17 C 6115 (R) paraffins with S02 and C12 and then hydrolyzing with a base to produce a random sulphonate; sodium and ammonium C7-C12 dialkyl sulfosuccinates; and olefin sulphonates, which term is used to describe the material made by reacting olefins, particularly C10-C20 alpha-olefins, with SO3 and then neutralizing and hydrolyzing the reaction product. The preferred anionic detergent compounds are sodium (Cl1-C15) alkylbenzene sulphonates, sodium ~Cl6-C18) alkyl sulphates and sodium ~Cl6-C18) alkyl ether sulphates.
Examples of suitable nonionic surface-active compounds which may be used, preferably together with the anionic surface-active compounds, include in particular the reaction products of alkylene oxides t usually ethylene oxide, with alkyl (C6-C22) phenols, generally 5-25 EO, i.e. 5-25 units of ethylene oxide per molecule; the condensation products of aliphatic (C8-Cl8) primary or secondary linear or branched alcohols with ethylene oxide, generally 2-30 EO, and prsducts made by condensation of ethylene oxide with the reaction products of propylene oxide and ethylene diamine. Other so-called nonionic surface-actives include alkyl polyglycosides, long chain tertiary amine oxides, long chain tertiary phosphine oxides and dialkyl sulphoxides.
Amphoteric or zwitterionic surface-active compounds can also be used in the compositions of the invention but this is not normally desired owing to their relatively high cost. If any amphoteric or zwittexionic detergent compounds are used, it is generally in small amounts in compositions based on the much more commonly used synthetic anionic and nonionic actives.
Soaps may also be incorporated into the compositions of the invention, preferably at a level of less than 30~ by ~2~3~2~
C 6115 (R) weight. They are particularly useful at low levels in binary (soap/anionic) or ternary mixtures together with nonionic or mixed synthetic anionic and nonionic compounds. Soaps which are used are preferably the sodium, or less desirably potassium, salts of saturated or unsaturated C10-C24 fatty acids or mixtures thereof.
The amount of such soaps can be varied between about 0.5% and about 25% by weight, with lower amounts of about 0.5% to about 5% being generally sufficient for lather control. Amounts of soap between about 2% and about 20%, especially between about 5% and about 15%, are used to give a beneficial effect on detergency. This is particularly valuable in compositions used in hard water when the soap acts as a supplementary builder.
The detergent compositions of the invention will normally also contain a detergency builder. Builder materials may be selected from (1) calcium sequestrant materials, (2) precipitating materials, (3~ calcium ion-exchange materials and (4) mixtures thereof.
In particular, the compositions of the invention may contain any one of the organic or inorganic builder materials, such as sodium or potassium tripolyphosphate, sodium or potassium pyrophosphate, sodium or potassium orthophosphate, sodium carbonate, the sodium salt of nitrilotriacetic acid, sodium citrate, carboxymethyl malonate, carboxymethyloxysuccinate, tartrate mono- and di-succinates, oxydisuccinate, crystalline or amorphous aluminosilicates and mixtures thereof.
Polycarboxylic homo- and co-polymers may also be included as builders and to function as powder structurants or processing aids. Particularly preferred are polyacrylic acid (available under the trademark Acrysol from the Rohm and Haas Company) and acrylic-2~382~
C 6115 (R) maleic acid co-polymers (available under the trademark Sokalan from the BASF Corporation) and alkali metal or other salts thereof.
These builder materials may be present at a level of, for example, from about l to 80% by weight, preferably from 10 to 60% by weight.
Upon dispersal in a wash water, the initial amount of peroxygen compound should range anywhere from about 0.05 to about 250 ppm active oxygen per liter of water, preferably between about 1 to 50 ppm. Within the wash media, the amount of oxygen transfer agent initially present should be from about 0.01 to about 300 ppm, preferably from about 5 to 100 ppm. Bleach precursor may be present in the wash media in an amount from about 0.05 to 20 ppm, preferably from about 5 to about 100 ppm. Surfactant should be present in the wash water from about 0.05 to 1.0 grams per liter, preferably from 0.15 to 0.20 grams per liter. When present, the builder amount will range from about 0.1 to 3.0 grams per liter.
Apart from the components already mentioned, the detergent compositions of the invention can contain any of the conventional additives in the amounts in which such materials are normally employed in fabric washing detergent compositions. Examples of these additives include lather boosters such as alkanolamides, particularly the monoethanolamides derived from palmkernel fatty acids and coconut fatty acids~ lather depressants such as alkyl phosphates and silicones, anti-redeposition agents such as sodium carboxymethylcellulose and alkyl or substituted alkylcellulose ethers, other stabilizers such as ethylene diamine tetraacetic acid and phosphonic acid derivatives (Dequest ~ , fabric softening agents, 2~1382~
C 6115 (R) inorganic salts such as sodium sulphate, and, usually present in very small amounts, fluorescent agents, perfumes, enzymes such as proteases, cellulases, lipases and amylases, germicides and colorants.
The oxygen transfer agents in combination with a peroxygen compound may be useful for removing stains both in consumer type products and for industrial applications. ~mong consumer products incorporating this invention are laundry detergents, laundry bleaches, hard surface cleaners, toilet bowl cleaners, automatic dishwashing compositions and even denture cleaners.
Stained consumer products benefiting from treatment with compositions of this invention may include clothes and other fabrics; household fixtures and appliances such as sinks, toilet bowls and oven ranges; tableware such as drinking glasses, dishes, cookware and utensils; and even dentures. ~air colorants may also be fGrmulated with the bleach composition of this invention.
The bleaching system of this invention may also be applied to industrial uses such as for the bleaching of wood pulp.
The system of the present invention may be delivered in a variety of product forms including powders, on sheets or other substrates, in pouches, in tablets, in aqueous liquids, or in non-aqueous liquids such as liquid nonionic detergents.
The following examples will more fully illustrate the embodiments of this invention. All parts, percentages and proportions referred to herein and in the appended claims are by weight unless otherwise illustrated.
~382~
C 6115 (R) Synthesis of N-Sulfonimines Sulfonimines used for the present invention were prepared by a modified version of procedures set forth by Davis et al~ Synthesis of the imines was accomplished by condensing commercially available aromatic aldehydes and sulfonamides. Thus, sulfonimines were prepared by heating equimolar amounts of the requisite sulfonamide and aldehyde in either toluene or chlorobenzene containing a catalytic amount of toluenesulfonic acid.
Reaction vessels were either fitted with a drying tube (calcium sulfate) or with a nitrogen flow system. Any water formed from these condensations was removed by equipping the reaction vessels with a Soxhlet extractor cont~;ning 3A molecular sieves. Formation of product sulfonimines was monitored by TLC and lH NMR analyses.
Complete reaction times varied from 1.5 hours to 2 days.
The carboxysulfonimine products were isolated by filtering the reaction mixtures at room temperature.
Specific syntheses are outlined in the following examples which focus upon product yield and spectroscopic analyses.
N-Benzylidenebenzenesulfonamide was prepared by reacting an equimolar mixture of benzenesulfonamide and benzaldehyde diethyl acetal as described by Davis et al.
in J. Amer. Chem. Soc., 1980, 102, 2000.
~382~
C 6115 (R) N-(4~Carboxybenzylidene)-4--chlorobenzenesulfonamide (SULF-l) A well-stirred slurry consisting of 4.64 g (31 mmol) of
4-carboxybenzaldehyde and 5.92 g (31 mmol) of 4-chlorobenzenesulfonamide and 20 mg of p-toluenesulfonic acid (TsOH) in 130 mL of toluene was heated to reflux for a total of 5 hours. The water formed from the reaction was removed by a Soxhlet extractor packed with 3A molecular sieves as described above. The mixture was allowed to cool to room temperature and was filtered to provide 9.76 g (98%) of SULF-l as a white powder: mp >245~C; IR (Nujol) 3300-2300 (br), 3090, 1689, 1616, 1168, 1013 cm~l; lH NMR
(DSMO-d6, TMS ext standard, 60 MHz) ~ 9.15 (s, 1), 8.01 (s, 4), 7-79 (AB, 4, JAB = 11, ~ ~= 16).
~3~2~9 C 6115 (R) N-(4-Carboxybenzylidene)benzenesulfonamide (SULF-2) In a manner similar to Example 2, 1.00 g (6.6 mmol) of 4-carboxybenzaldehyde, 1.05 g (6.6 mmol) of benzenesulfonamide and 20 mg of TsOH in 120 mL of toluene were heated for 2.5 hours to afford 1.82 g (90%) of SULF-2 as a white powder; IR (Nujol) 3400 - 2400 (br), 1680, 1605, 1283, 1160, 1083 cm~l; lH NMR (DMSO-d6, TMS ext std) ~ 9.17 (s, 1), 8.1 - 7.3 (m, 9).
2~3~0~
C 6115 (R) N-(4-Chlorobenzylidene)-4-carboxybenzenesulfonamide (SULF-3) In a similar manner to Example 2, 4.00 g (29 mmol) of 4-chloroben~aldehyde, 5.72 g (29 mmol) of 4-carboxybenzenesulfonamide and 20 mg of TsOH in 150 mL
of toluene were heated for 24 hours to provide 6.60 g (71%) of SULF-3 as a light tan powder: IR (Nujol) 3400-2500 (br), 1685, 1595, 1285, 1215, 1005 cm~l; lH NMR
(DMSO-d6, TMS ext std) ~ 9.15 (s, 1), 8.2 - 7.3 (m, 8).
2~2~
C 6115 (R) N-Benzylidene-4-carboxybenzenesulfonamide (SULY~
In the same manner as Example 2, 4.00 g (38 mmol) of benzaldehyde, 7.58 g (38 mmol) of 4-carboxybenzene sulfonamide and 20 mg of TsOH in 150 mL of toluene were heated for 36 hours to afford 7.40 g ~71%) of SULF-4 as a light tan powder: IR (Nujol~ 3800 - 2600 (br)~ 1685, 1600, 1283, 1155 cm 1, 1H NMR (DMS0-d6, TMS ext std) ~ 9.05 (s, 1), 8.2 - 7.2 (m, 9).
~38~
C 6115 (R) EX~MPLE 6 N~(4-Carboxybenzylidene)-4-carboxybenzenesul~onamide (SULF 5) In the same manner as Example 2, 0.60 g (4 mmol) of 4-carboxybenzaldehyde, 0.80 g (4 mmol) o~ 4-carboxyb~nzenesulfonamide and 15 mg of TsOH in 80 mL of chlorobenzene under nitrogen were heated to provide 80%
of SULF-5 as a light tan powder: IR (Nujol) 3400 - 2600 (br), 3082, 1688, 1614, 1160 cm~l; lH NMR (DMSO-d6, TMS
ext std) ~ 9.17 (s, 1), 8.2 - 7.8 (m, 8).
2~3~2~
C 6115 (~) N-(4-Carboxybenzylidene)-3-nitrobenzenesulfonamide (SULF-6) In a similar manner to Example 2, 2.02 g (10 mmol) of 3-nitrobenzenesulfonamide, 1.50 g (10 mmol) of 4-carboxybenzaldehyde and 20 mg of TsOH in 150 mL of toluene were heated for 5 hours to yield 3.23 g (97%) of SULF-6 as a white powder: IR (Nujol) 3200 - 2500 (br), 1685, 1554, 1379, 1352, 1165 cm~l~ lH NMR (DMSO-d6, TMS ext std) ~ 9.24 (s, 1), 8.47 (s, 1), 7.9 - 6.9 (m, 7).
2~382~
C 6115 (R) N-(4-Cvanobenzylidene)-4-carboxybenzenesulfonamide ~SULF-7~
In a similar manner to Example 2, 1.25 q (9 mmol) of 4-cyanobenzaldehyde, 1.9~ g ~9 mmol) of 4-carboxybenzene-sulfonamide and 20 mg of TsOH in 150 mL of chlorobenzene under nitrogen were heated for 18 hours to give 2.58 g (86%) of SULF-7 as a white powder: IR (Nujol) 3400-2400 (br), 2224, 1682, 1605, 1155 cm~l; lH NMR (DMSO-d6, TMS
ext std) ~ 9.35 (s, 1), 8.3 - 7.8 (m, 8).
2~2~
C 6115 (R) EX~MPLE 9 N-(4-Methoxybenzylidene)-4-carboxybenzenesulfonamide (SULF-8) In a similar manner to Example 2, 1.28 g (9 mmol) of anisaldehyde, 1.89 g (9 mmol) of 4-carboxybenzene sulfonamide and 20 mg of TsOH in 150 mL of chlorobenzene and under nitrogen were heated for 4.5 hours to yield 2.86 g (96%) of SULF-8 as a white powder: IR (Nujol) 3300 - 2700 (br), 1693, 1601, 1584, 1155 cm~l; lH NMR
(DMSO-d6, TMS ext std) ~ 8.91 (s, 1), 8.4 - 7.7 (m, 8), 3.92 (s, 3).
~382~9 C 6115 (R) N-(3-Hydroxybenz~lidene)-4-chlorobenzenesulfonamide (SULF-9l In a similar manner to Example 2, 1.24 g (10 mmol) of 3-hydroxybenzaldehyde, 1.94 g (10 mmol) of 4-chlorobenzenesulfonamide and 20 mg of TsOH in 150 mL of toluene were heated for 12 hours to give 0.29 g (10%) of SULF-9 as a brown powder: IR (Nujol) 3400, 1658, 1556, 1458, 1155, 1025 cm~1; 1H NMR (DMSO-d6, TMS ext std) ~ 8.85 (s, 1), 8.73 (s, 1), 7.7 - 7.2 (m, 8).
2~3~2~
31 C 6115 (R) Bis-N-terephthalidene-4-carboxYbenzenesulfonamide (SULF-10) In a similar manner to Example 2, 0.50 g (4 mmol) of terephthaldicarboxaldehyde, 1.50 g (8 mmol) of 4-carboxybenzenesulfonamide and 20 mg of TsOH in 100 mL
of toluene were heated for 18 h to afford 90% of SULF-10 as a fine, light tan powder: IR (Nujol) 3400 - 2400 (br), 3081, 1689, 1597, 1154, 719 cm~1; lH NMR (DMSO-d6, TMS ext std) ~ 9.17 (s, 2), 8.3 - 7.8 (m, 12).
%~382~9 32 C 6115 (R) 3-Methyl-1,2-benzisothiazole-1,1-dioxide (SULF-ll) This cyclic sulfonimine was prepared by reacting saccharin with 2 equivalents of methyllithium in tetrahydrofuran according to a procedure described in the Journal of the Chemical Society. Perkin I, 2589 (1974~, ~3~2~9 C 6115 (~) N-(3-Pyridinvlmethylene)-4-chlorobenzenesulfonamide (SULF-12) In a similar manner to Example 2, 18.5 mmol of 3-pyridinecarboxaldehyde, 18.5 mmol of 4-chlorobenzenesulfonamide and 20 mg of TsOH in 100 mL of toluene reacted under reflux conditions to afford SULF-12 in 65% yield and high purity: 1H N~R
(DSM0-d6, TMS ext std) ~ 9.3 (s, 1), 9.2 (d, 1), 8.9 (m, 1), 8.4 (m, 1), 8.0-7.8 (AB. 4).
2~3~2~9 C 6115 (R) Activation of Peracid Precursor-Perborate sYstems bY
Sulfonimines Stain bleaching experiments were conducted in a Terg-O-Tometer in 500 mL of milli-Q water using two tea-stained cotton cloths measuring 3 x 4 inches. In a typical test, 0.75 g of Surf ~ was added to the system and the pH of the solution was constantly buffered to the indicated level by the addition of dilute aqueous sodium hydroxide or hydrochloric acid. A given oxidant was added to the system, followed by an appropriate amount of sulfonimine. Washes were carried out at 40~C for 15 minutes.
Stain bleaching was measured reflectometrically, using a Colorgard System/05 Reflectometer. Bleaching was indicated by an increase in reflectance, reported as ~ R.
In general, a ~R of one unit is perceivable in a paired comparison while a ~R of two units is perceivable monadically.
The precursor TAED, when formulated with sodium perborate monohydrate, provides peracetic acid when placed in an alkaline aqueous medium. Table I reports results with TAED and various other peracid precursor-perborate systems both in the presence and SULF-l.
When TAED (9 x 10-4 M) was used in conjunction with a lar~e excess of sodium perborate, there was observed 4.1 units of bleaching on a tea-tained cloth. However, when a small amount of SULF-l was included in the system, the overall bleaching performance improved to 12.4 units, representing an activation of over 200%.
~38~
C 6115 (R) Similarly, a comparable level of peracetic acid generated through the precursor sodium acetyloxybenzene sulfonate (SABS) afforded a ~R of 4.7 units, which was raised to 11.3 units of bleaching by addition of SULF-l. The perbenzoic acid precursor, sodium ben~oyloxybenzenesulfonate (SBOBS) was also stud.ied. At a low level (5 ppm), SBOBS delivered 2.3 units of bleaching at pH 905. When a stoichiometric amount of SULF-l was included in the test, the overall bleaching became 3.8 units, demonstrating that SBOBS performance can be enhanced slightly by sulfonimines. The peracid precursor sodium nonanoyloxybenzenesulfonate (SNOBS) was also examined at pH 9.5 and 10Ø SNOBS provided 4.6 units of bleaching at pH 9.5 which could be increased to
(DSMO-d6, TMS ext standard, 60 MHz) ~ 9.15 (s, 1), 8.01 (s, 4), 7-79 (AB, 4, JAB = 11, ~ ~= 16).
~3~2~9 C 6115 (R) N-(4-Carboxybenzylidene)benzenesulfonamide (SULF-2) In a manner similar to Example 2, 1.00 g (6.6 mmol) of 4-carboxybenzaldehyde, 1.05 g (6.6 mmol) of benzenesulfonamide and 20 mg of TsOH in 120 mL of toluene were heated for 2.5 hours to afford 1.82 g (90%) of SULF-2 as a white powder; IR (Nujol) 3400 - 2400 (br), 1680, 1605, 1283, 1160, 1083 cm~l; lH NMR (DMSO-d6, TMS ext std) ~ 9.17 (s, 1), 8.1 - 7.3 (m, 9).
2~3~0~
C 6115 (R) N-(4-Chlorobenzylidene)-4-carboxybenzenesulfonamide (SULF-3) In a similar manner to Example 2, 4.00 g (29 mmol) of 4-chloroben~aldehyde, 5.72 g (29 mmol) of 4-carboxybenzenesulfonamide and 20 mg of TsOH in 150 mL
of toluene were heated for 24 hours to provide 6.60 g (71%) of SULF-3 as a light tan powder: IR (Nujol) 3400-2500 (br), 1685, 1595, 1285, 1215, 1005 cm~l; lH NMR
(DMSO-d6, TMS ext std) ~ 9.15 (s, 1), 8.2 - 7.3 (m, 8).
2~2~
C 6115 (R) N-Benzylidene-4-carboxybenzenesulfonamide (SULY~
In the same manner as Example 2, 4.00 g (38 mmol) of benzaldehyde, 7.58 g (38 mmol) of 4-carboxybenzene sulfonamide and 20 mg of TsOH in 150 mL of toluene were heated for 36 hours to afford 7.40 g ~71%) of SULF-4 as a light tan powder: IR (Nujol~ 3800 - 2600 (br)~ 1685, 1600, 1283, 1155 cm 1, 1H NMR (DMS0-d6, TMS ext std) ~ 9.05 (s, 1), 8.2 - 7.2 (m, 9).
~38~
C 6115 (R) EX~MPLE 6 N~(4-Carboxybenzylidene)-4-carboxybenzenesul~onamide (SULF 5) In the same manner as Example 2, 0.60 g (4 mmol) of 4-carboxybenzaldehyde, 0.80 g (4 mmol) o~ 4-carboxyb~nzenesulfonamide and 15 mg of TsOH in 80 mL of chlorobenzene under nitrogen were heated to provide 80%
of SULF-5 as a light tan powder: IR (Nujol) 3400 - 2600 (br), 3082, 1688, 1614, 1160 cm~l; lH NMR (DMSO-d6, TMS
ext std) ~ 9.17 (s, 1), 8.2 - 7.8 (m, 8).
2~3~2~
C 6115 (~) N-(4-Carboxybenzylidene)-3-nitrobenzenesulfonamide (SULF-6) In a similar manner to Example 2, 2.02 g (10 mmol) of 3-nitrobenzenesulfonamide, 1.50 g (10 mmol) of 4-carboxybenzaldehyde and 20 mg of TsOH in 150 mL of toluene were heated for 5 hours to yield 3.23 g (97%) of SULF-6 as a white powder: IR (Nujol) 3200 - 2500 (br), 1685, 1554, 1379, 1352, 1165 cm~l~ lH NMR (DMSO-d6, TMS ext std) ~ 9.24 (s, 1), 8.47 (s, 1), 7.9 - 6.9 (m, 7).
2~382~
C 6115 (R) N-(4-Cvanobenzylidene)-4-carboxybenzenesulfonamide ~SULF-7~
In a similar manner to Example 2, 1.25 q (9 mmol) of 4-cyanobenzaldehyde, 1.9~ g ~9 mmol) of 4-carboxybenzene-sulfonamide and 20 mg of TsOH in 150 mL of chlorobenzene under nitrogen were heated for 18 hours to give 2.58 g (86%) of SULF-7 as a white powder: IR (Nujol) 3400-2400 (br), 2224, 1682, 1605, 1155 cm~l; lH NMR (DMSO-d6, TMS
ext std) ~ 9.35 (s, 1), 8.3 - 7.8 (m, 8).
2~2~
C 6115 (R) EX~MPLE 9 N-(4-Methoxybenzylidene)-4-carboxybenzenesulfonamide (SULF-8) In a similar manner to Example 2, 1.28 g (9 mmol) of anisaldehyde, 1.89 g (9 mmol) of 4-carboxybenzene sulfonamide and 20 mg of TsOH in 150 mL of chlorobenzene and under nitrogen were heated for 4.5 hours to yield 2.86 g (96%) of SULF-8 as a white powder: IR (Nujol) 3300 - 2700 (br), 1693, 1601, 1584, 1155 cm~l; lH NMR
(DMSO-d6, TMS ext std) ~ 8.91 (s, 1), 8.4 - 7.7 (m, 8), 3.92 (s, 3).
~382~9 C 6115 (R) N-(3-Hydroxybenz~lidene)-4-chlorobenzenesulfonamide (SULF-9l In a similar manner to Example 2, 1.24 g (10 mmol) of 3-hydroxybenzaldehyde, 1.94 g (10 mmol) of 4-chlorobenzenesulfonamide and 20 mg of TsOH in 150 mL of toluene were heated for 12 hours to give 0.29 g (10%) of SULF-9 as a brown powder: IR (Nujol) 3400, 1658, 1556, 1458, 1155, 1025 cm~1; 1H NMR (DMSO-d6, TMS ext std) ~ 8.85 (s, 1), 8.73 (s, 1), 7.7 - 7.2 (m, 8).
2~3~2~
31 C 6115 (R) Bis-N-terephthalidene-4-carboxYbenzenesulfonamide (SULF-10) In a similar manner to Example 2, 0.50 g (4 mmol) of terephthaldicarboxaldehyde, 1.50 g (8 mmol) of 4-carboxybenzenesulfonamide and 20 mg of TsOH in 100 mL
of toluene were heated for 18 h to afford 90% of SULF-10 as a fine, light tan powder: IR (Nujol) 3400 - 2400 (br), 3081, 1689, 1597, 1154, 719 cm~1; lH NMR (DMSO-d6, TMS ext std) ~ 9.17 (s, 2), 8.3 - 7.8 (m, 12).
%~382~9 32 C 6115 (R) 3-Methyl-1,2-benzisothiazole-1,1-dioxide (SULF-ll) This cyclic sulfonimine was prepared by reacting saccharin with 2 equivalents of methyllithium in tetrahydrofuran according to a procedure described in the Journal of the Chemical Society. Perkin I, 2589 (1974~, ~3~2~9 C 6115 (~) N-(3-Pyridinvlmethylene)-4-chlorobenzenesulfonamide (SULF-12) In a similar manner to Example 2, 18.5 mmol of 3-pyridinecarboxaldehyde, 18.5 mmol of 4-chlorobenzenesulfonamide and 20 mg of TsOH in 100 mL of toluene reacted under reflux conditions to afford SULF-12 in 65% yield and high purity: 1H N~R
(DSM0-d6, TMS ext std) ~ 9.3 (s, 1), 9.2 (d, 1), 8.9 (m, 1), 8.4 (m, 1), 8.0-7.8 (AB. 4).
2~3~2~9 C 6115 (R) Activation of Peracid Precursor-Perborate sYstems bY
Sulfonimines Stain bleaching experiments were conducted in a Terg-O-Tometer in 500 mL of milli-Q water using two tea-stained cotton cloths measuring 3 x 4 inches. In a typical test, 0.75 g of Surf ~ was added to the system and the pH of the solution was constantly buffered to the indicated level by the addition of dilute aqueous sodium hydroxide or hydrochloric acid. A given oxidant was added to the system, followed by an appropriate amount of sulfonimine. Washes were carried out at 40~C for 15 minutes.
Stain bleaching was measured reflectometrically, using a Colorgard System/05 Reflectometer. Bleaching was indicated by an increase in reflectance, reported as ~ R.
In general, a ~R of one unit is perceivable in a paired comparison while a ~R of two units is perceivable monadically.
The precursor TAED, when formulated with sodium perborate monohydrate, provides peracetic acid when placed in an alkaline aqueous medium. Table I reports results with TAED and various other peracid precursor-perborate systems both in the presence and SULF-l.
When TAED (9 x 10-4 M) was used in conjunction with a lar~e excess of sodium perborate, there was observed 4.1 units of bleaching on a tea-tained cloth. However, when a small amount of SULF-l was included in the system, the overall bleaching performance improved to 12.4 units, representing an activation of over 200%.
~38~
C 6115 (R) Similarly, a comparable level of peracetic acid generated through the precursor sodium acetyloxybenzene sulfonate (SABS) afforded a ~R of 4.7 units, which was raised to 11.3 units of bleaching by addition of SULF-l. The perbenzoic acid precursor, sodium ben~oyloxybenzenesulfonate (SBOBS) was also stud.ied. At a low level (5 ppm), SBOBS delivered 2.3 units of bleaching at pH 905. When a stoichiometric amount of SULF-l was included in the test, the overall bleaching became 3.8 units, demonstrating that SBOBS performance can be enhanced slightly by sulfonimines. The peracid precursor sodium nonanoyloxybenzenesulfonate (SNOBS) was also examined at pH 9.5 and 10Ø SNOBS provided 4.6 units of bleaching at pH 9.5 which could be increased to
5.1 upon the addition of a stoichiometric amount of SULF-l. When a similar experiment was conducted at pH
lO, the performance of SNOBS dropped to 3.2, but still provided 5.1 units when accompanied by SULF-l.
2~3~209 C 6115 (R) TABLE I - Activations Usinq SULF-1 [SULF] CPrec] dR ~R
PrecursorNaBO3:Prec ~ x10-4M x10- 4MPrec SULF
TAED 12 9.5 6.0 9.0 4.112.4 SABS 3 10.1 3.0 18.6 4.711.3 SBOBS 5 9.5 3.0 3.0 2.33.8 SNOBS 5 9.5 3.0 3.0 4.65.1 SNOBS 5 10.0 3.0 3.0 3.25.1 The results set forth in Table I show that a variety of known peracid precursor - perborate bleaching systems can provide enhanced performance by the action of sulfonimines.
~382~
C 6115 (R) Effect of PH on the Activation of TAED By Sulfonimines Bleaching performance of TAED in conjunction with sodium perborate exhibited variation of activity dependent upon pH conditionsO At low pH, bleaching was ~i ;zed. At higher pH, a reduction in performance was observed.
Table II sets forth the data. These resulta were accumulated in a Terg-O-Tometer experiment, using 9 x 10 4 M TAED wîth a 12:1 perborate ratio.
2~3~2~
C 61~5 (R) TA~
P~ ~e~ende~e ~n ~RF~n ~ea-~tained C~o~h ~le~ch~na 2~ Q ~Q
~R 6.2 5.7 4.7 4.1 4.0 2.5 PrQcur~or SU ~-1 through ~U~F ~ w~r~ te8~ in con~unctlon with T~ED - perborate at v~rylng p~ levels between 8.0 a~nd 10.5~ Bleaching te~ts were ~onducted in a T~g-0-Tometer u~ing two tea-~ained cloth~ (3 x 4") in ~oo mL of water containing ~.7s g o~ P-SurP ~ . TAEP
w~ dosed At '~ X 10-4 ~ wi~h ~ 12;1 60dium perborAte mon~hydrate ~at~o. Sulfonimines were added at 6.0 x 10-4 concentra~lon. Wa~he~ were per~or~ed at 40~c ~r 15 ~in. Re~ult~ o~ the p~l prof'ile on the TAED SULF ~;y~tem are shown in Table III. ~he indlcated~R values re~er to the obser~e~ bleachlng enha~cement over the contr~butlo~ ~rom TAED alone , i . e ., R ~AED-suLF ~ ~R (~AED~U~F) - ~ (TAED~
~382t~
C 511~ (R) ~AR~
p1~ penr~enc~ on TA~ ;ulr~nih~lne TeA-~:t~ined Cloth ~ TA~-S~T~F
10.5 ~.~ S.3 7.~ S.9. 1.1 6.1 10.4 -0.4 10.0 7.3 ~.5 9~5 5.8 1.5 6.3 12.~ 0.3 3.7 9.5 8.3 6.~ 8.3 5.8 1.3 7.1 11.0 D.5 9.1~ 12.4 9.0 ~.6 4,5 7.9 4.~ 0.5 7.4 11.3 0.2 8.5 6~3 4.~ 6,~ 4.1 0.5 5.9 9.1 0.2 8.0 5~6 2.6 2.4 3.3 0.0 3.9 8.8 3.5 Study conduc~ed us$ng 3 x 10 4 ~ SULF.
~3g2~
C 6115 (T~) ~0 From T~bl~ I, on~ n obs~ th~t ~or 5UhF 1-8, maxlm~l~ ble~sh~ng ~nhunc~ nt ~n)~efi plhce e~t pH ~ . 5 or ~0 . O. Co~parlng overa~ v~lues (nc)t ~hown) ~or the new ble4c~ng ~y~item demon~3tr~tec tha$ A high lev~l o~
Eitalrl remov~l i6; ~ccolnpli~he~ ~t ~ny point be~ween pH
a . 5 and. 10. 5 . This t~ture o~ the T~ED-~3ULF ~y~tern 1~
~ulte ~ttr~c~lv~ ~lnce ~ective bleac~hltlg may r~sult evnn when pH control iE~ probl~matic.
~So~t o~ ~he ul~oni~ e~; provided ~;lgniflcant activatio o~ TAED. The sul~onimlnef; whlc:h ::ontEIin ~l~ctron-wlthdruw~ng moletle~3 (e.g. C:l, N02, Dr CN~ provided xlmum TAED enh~noement. ConVer~;ely, tho~:e sulfonimines containlng an electron-donatlng grouping, ~iuch a~ sV~F-5 ~nd SULF-8, provided minor bleachlng enhancement. SULF-9 ls the only actlva~or ~hown which do~s not contain u c~rboxy yroup, ~ut ~her co~tains a ~ydroxyl. Although only ~tudle~ ~t pH 10, notable cleaning ~nhancement W~5 observed. SULF-10 i5 structurally distincSive because it cont~lns two ~ulfonlmine ~oietie~. At o~e h~l~ th~
conoentr~tlon o~ the o~h~r ~ul~oni~ln~ s~own ln Tabls III, an equivAl~nt ~mount o~ ~le~chl ng occurred, sugge~in~ thh~ both im~no grouplng~ are utllized in the actlv~tlo~ proc~s~
SU~-7 provided th~ hig~e~t Amount o~ TAED ~ctlvation within th~ Ta~le III ~erie6. Int~r~tingly, SUL~-7 al~o de~on6~r~ted ~llght ac~lva~lon ~ 2) o~ 80~1u~
perborRte alon~ without TAED. It i~ ~el~v~d that the ~y~o group i~ a ~or contributor to the hlgh activl~y.
203~9 C 6115 (R) MP~.~. 16 OnQ o~ the ~hd~ c~snt oxygen tran~er ~gent~ oP thl~
lnY~ntlon 1~ SUJ~F 11. T~rg-O-I~0~3tl3r cla~nlng ~e~t~ wlth a ~Ur,~ /T~D ~y{~em we~13 condu~::t~d on t~ ;talned cloth. The p~l pro~ and concentration datrl aro fihown in ~bl~ ~V. Evon a~ such a low concentr~t-~ on A6 ~ i X
10-5 ~ SULF-l~, t~ere wa~ ~chi~vs~d slgnirlc~nt enhancemen~ o~ ~AED bleaching.
2~3~2~9 C 6115 (R~
4;~
~ABT.~: IV
3~ndenc~e on q'AF.I~ T,F--11 T~ BtA1~d alo~
~1 e~oh ln~
!R SU~ rA~
~gx 10-4 ~ x 10 R 7.-1 24.6 8.5 ~.0 26.4 g 7.5 ~5.1 9.5 5.0 2~.
5.2 25.2 10.5 6.1 23.2 ~38~9 C 6115 ~R) ~3 Y
Concer~tr~tion ~onc~ntr~ltlon TAP~r~ r~lU 4 ~L, ,~ r.F~ ,F.D~ SU~'F
9 ~ x 10-4 5.025.~i .5 6 x 1~-4 3.0 20.5 3 ~ 10-4 6~2 2~.9 ~.5 3 ~c 10-4 3.9 1~.5 9 1 x 10-4 5.7 16.1 4-5 IL X 10~ 3.9 4-5 5 X 10-5 3-6 9.5 4.5 3 x 10-5 ~,.1 8.2 ~.5 1 x 10-5 3.6 6.0 C~ndltlon~; : pH g ~ 5; 15 min . 4 0 ~ C; sodium perborate 6: 1 2~13~2~
C 6115 tR) ~MPr.~: 3.7 l~ere~n report~d ~r~ th~ ~f'sct~ o~ vD.ryir~g conc:entrat~on~ o~ 6ul~0nam~ne, T~ED and sc~dium p~rbora~e on te~ t2l1n bleachlng~ The~e experlments ~e~e conducted ursd~r ~:ondltion~ eslmlla~ to that o~ Example 15. Result~
a~arlz~d ln T~ VI.
2~3~209 C 6115 (R) TABLE VI
Concentration Effects on TAED-SULF Tea-stain Bleachinq [SULP] [TAED] NaB03 SULF x 10-4M x 10-X4M :TAED AR TAED ~R TAED-SULF
1 6 9.01~ 5.613.7 4.512 2.4 7.5 3 9.012 5.712.1 4.512 2.~ 6.9 1 9.012 6.1 9.6 - 4.512 2.6 5.0 _____ ____________ ________________
lO, the performance of SNOBS dropped to 3.2, but still provided 5.1 units when accompanied by SULF-l.
2~3~209 C 6115 (R) TABLE I - Activations Usinq SULF-1 [SULF] CPrec] dR ~R
PrecursorNaBO3:Prec ~ x10-4M x10- 4MPrec SULF
TAED 12 9.5 6.0 9.0 4.112.4 SABS 3 10.1 3.0 18.6 4.711.3 SBOBS 5 9.5 3.0 3.0 2.33.8 SNOBS 5 9.5 3.0 3.0 4.65.1 SNOBS 5 10.0 3.0 3.0 3.25.1 The results set forth in Table I show that a variety of known peracid precursor - perborate bleaching systems can provide enhanced performance by the action of sulfonimines.
~382~
C 6115 (R) Effect of PH on the Activation of TAED By Sulfonimines Bleaching performance of TAED in conjunction with sodium perborate exhibited variation of activity dependent upon pH conditionsO At low pH, bleaching was ~i ;zed. At higher pH, a reduction in performance was observed.
Table II sets forth the data. These resulta were accumulated in a Terg-O-Tometer experiment, using 9 x 10 4 M TAED wîth a 12:1 perborate ratio.
2~3~2~
C 61~5 (R) TA~
P~ ~e~ende~e ~n ~RF~n ~ea-~tained C~o~h ~le~ch~na 2~ Q ~Q
~R 6.2 5.7 4.7 4.1 4.0 2.5 PrQcur~or SU ~-1 through ~U~F ~ w~r~ te8~ in con~unctlon with T~ED - perborate at v~rylng p~ levels between 8.0 a~nd 10.5~ Bleaching te~ts were ~onducted in a T~g-0-Tometer u~ing two tea-~ained cloth~ (3 x 4") in ~oo mL of water containing ~.7s g o~ P-SurP ~ . TAEP
w~ dosed At '~ X 10-4 ~ wi~h ~ 12;1 60dium perborAte mon~hydrate ~at~o. Sulfonimines were added at 6.0 x 10-4 concentra~lon. Wa~he~ were per~or~ed at 40~c ~r 15 ~in. Re~ult~ o~ the p~l prof'ile on the TAED SULF ~;y~tem are shown in Table III. ~he indlcated~R values re~er to the obser~e~ bleachlng enha~cement over the contr~butlo~ ~rom TAED alone , i . e ., R ~AED-suLF ~ ~R (~AED~U~F) - ~ (TAED~
~382t~
C 511~ (R) ~AR~
p1~ penr~enc~ on TA~ ;ulr~nih~lne TeA-~:t~ined Cloth ~ TA~-S~T~F
10.5 ~.~ S.3 7.~ S.9. 1.1 6.1 10.4 -0.4 10.0 7.3 ~.5 9~5 5.8 1.5 6.3 12.~ 0.3 3.7 9.5 8.3 6.~ 8.3 5.8 1.3 7.1 11.0 D.5 9.1~ 12.4 9.0 ~.6 4,5 7.9 4.~ 0.5 7.4 11.3 0.2 8.5 6~3 4.~ 6,~ 4.1 0.5 5.9 9.1 0.2 8.0 5~6 2.6 2.4 3.3 0.0 3.9 8.8 3.5 Study conduc~ed us$ng 3 x 10 4 ~ SULF.
~3g2~
C 6115 (T~) ~0 From T~bl~ I, on~ n obs~ th~t ~or 5UhF 1-8, maxlm~l~ ble~sh~ng ~nhunc~ nt ~n)~efi plhce e~t pH ~ . 5 or ~0 . O. Co~parlng overa~ v~lues (nc)t ~hown) ~or the new ble4c~ng ~y~item demon~3tr~tec tha$ A high lev~l o~
Eitalrl remov~l i6; ~ccolnpli~he~ ~t ~ny point be~ween pH
a . 5 and. 10. 5 . This t~ture o~ the T~ED-~3ULF ~y~tern 1~
~ulte ~ttr~c~lv~ ~lnce ~ective bleac~hltlg may r~sult evnn when pH control iE~ probl~matic.
~So~t o~ ~he ul~oni~ e~; provided ~;lgniflcant activatio o~ TAED. The sul~onimlnef; whlc:h ::ontEIin ~l~ctron-wlthdruw~ng moletle~3 (e.g. C:l, N02, Dr CN~ provided xlmum TAED enh~noement. ConVer~;ely, tho~:e sulfonimines containlng an electron-donatlng grouping, ~iuch a~ sV~F-5 ~nd SULF-8, provided minor bleachlng enhancement. SULF-9 ls the only actlva~or ~hown which do~s not contain u c~rboxy yroup, ~ut ~her co~tains a ~ydroxyl. Although only ~tudle~ ~t pH 10, notable cleaning ~nhancement W~5 observed. SULF-10 i5 structurally distincSive because it cont~lns two ~ulfonlmine ~oietie~. At o~e h~l~ th~
conoentr~tlon o~ the o~h~r ~ul~oni~ln~ s~own ln Tabls III, an equivAl~nt ~mount o~ ~le~chl ng occurred, sugge~in~ thh~ both im~no grouplng~ are utllized in the actlv~tlo~ proc~s~
SU~-7 provided th~ hig~e~t Amount o~ TAED ~ctlvation within th~ Ta~le III ~erie6. Int~r~tingly, SUL~-7 al~o de~on6~r~ted ~llght ac~lva~lon ~ 2) o~ 80~1u~
perborRte alon~ without TAED. It i~ ~el~v~d that the ~y~o group i~ a ~or contributor to the hlgh activl~y.
203~9 C 6115 (R) MP~.~. 16 OnQ o~ the ~hd~ c~snt oxygen tran~er ~gent~ oP thl~
lnY~ntlon 1~ SUJ~F 11. T~rg-O-I~0~3tl3r cla~nlng ~e~t~ wlth a ~Ur,~ /T~D ~y{~em we~13 condu~::t~d on t~ ;talned cloth. The p~l pro~ and concentration datrl aro fihown in ~bl~ ~V. Evon a~ such a low concentr~t-~ on A6 ~ i X
10-5 ~ SULF-l~, t~ere wa~ ~chi~vs~d slgnirlc~nt enhancemen~ o~ ~AED bleaching.
2~3~2~9 C 6115 (R~
4;~
~ABT.~: IV
3~ndenc~e on q'AF.I~ T,F--11 T~ BtA1~d alo~
~1 e~oh ln~
!R SU~ rA~
~gx 10-4 ~ x 10 R 7.-1 24.6 8.5 ~.0 26.4 g 7.5 ~5.1 9.5 5.0 2~.
5.2 25.2 10.5 6.1 23.2 ~38~9 C 6115 ~R) ~3 Y
Concer~tr~tion ~onc~ntr~ltlon TAP~r~ r~lU 4 ~L, ,~ r.F~ ,F.D~ SU~'F
9 ~ x 10-4 5.025.~i .5 6 x 1~-4 3.0 20.5 3 ~ 10-4 6~2 2~.9 ~.5 3 ~c 10-4 3.9 1~.5 9 1 x 10-4 5.7 16.1 4-5 IL X 10~ 3.9 4-5 5 X 10-5 3-6 9.5 4.5 3 x 10-5 ~,.1 8.2 ~.5 1 x 10-5 3.6 6.0 C~ndltlon~; : pH g ~ 5; 15 min . 4 0 ~ C; sodium perborate 6: 1 2~13~2~
C 6115 tR) ~MPr.~: 3.7 l~ere~n report~d ~r~ th~ ~f'sct~ o~ vD.ryir~g conc:entrat~on~ o~ 6ul~0nam~ne, T~ED and sc~dium p~rbora~e on te~ t2l1n bleachlng~ The~e experlments ~e~e conducted ursd~r ~:ondltion~ eslmlla~ to that o~ Example 15. Result~
a~arlz~d ln T~ VI.
2~3~209 C 6115 (R) TABLE VI
Concentration Effects on TAED-SULF Tea-stain Bleachinq [SULP] [TAED] NaB03 SULF x 10-4M x 10-X4M :TAED AR TAED ~R TAED-SULF
1 6 9.01~ 5.613.7 4.512 2.4 7.5 3 9.012 5.712.1 4.512 2.~ 6.9 1 9.012 6.1 9.6 - 4.512 2.6 5.0 _____ ____________ ________________
6 6 9.012 6.214.5 9.0 6 5.912~8 3 9.012 5.910.5 4.512 2.7 7.9 1 9.012 5.2 9.1 4.512 3.6 4.9 ________________ ______ ._________ 2 6 9.012 3.2 9.4 3 9.012 3.7 8.1 4.512 1.9 5.9 4 6 9.012 3.8 9.6 3 9.012 3.6 6.7 4.512 3.6 6.7 3 6 9.012 3.411.7 3 9.012 4.610.4 4.512 3.4 9.7 Perhaps more noteworthy of all the data in Table VI are the entries which correspond to utilizing 1 x 10-4 M
sulfonamine. At this concentration, SULF 1 and 6 provided a doubling in performance relative to a low dosage (4.5 x 10-4 M) of TAED. The large enhancement obtained from this small amount of SULF material strongly supports the notion that the sulfonamines are behaving catalytically.
The TAE~-SULF bleaching system, as seen frvm the data, operates ef*iciently at TAED concentrations between 4.5 - 9~0 x 10 4 M and sulfonamine concentrations ~3~
C 6115 (~) between 1 x 10-5 M to 6 x 10~4 M. The fact that such minute quantities of sulfonamines can enhance TAED
performance is quite unusual and surprising.
20382~9 C 6115 (R) Time-Dependence on TAED-SULF Bleachinq A study was conducted to determine the effect of time on the TAED-SULF bleaching system. Table VII shows the data from an experiment conducted, using tea-stained cloths in the Terg-0-Tometer with TAED and sodium perborate in the presence and absence of SULF-l. The amount of stain removal was measured in separate tests at 15, 30 and 45 minutes. The concentration of sulfonimine was varied between 3 - 6 x 10 4 M with a constant 9.0 x 10-4 M
dosage of TAED. Not surprisingly, the bleaching by TAED
alone increased yradually over a period of 45 minutes.
More importantly, the bleaching performance by the sulfonimine containing system also escalated throughout the 45-minute period, regardless of SULF concentration.
The net result after 45-minutes of washing is a doubling of TAED performance brought about by a relatively low level of sulfonimine.
2~38~09 C 6115 (R) TABLE VII
TAED - SULF-l Bleachin~ Performance over Time [SULF-1] t AR a R
x 10-4 M min TAEDSULF
6 15 3.09.6 3C 5.612.9
sulfonamine. At this concentration, SULF 1 and 6 provided a doubling in performance relative to a low dosage (4.5 x 10-4 M) of TAED. The large enhancement obtained from this small amount of SULF material strongly supports the notion that the sulfonamines are behaving catalytically.
The TAE~-SULF bleaching system, as seen frvm the data, operates ef*iciently at TAED concentrations between 4.5 - 9~0 x 10 4 M and sulfonamine concentrations ~3~
C 6115 (~) between 1 x 10-5 M to 6 x 10~4 M. The fact that such minute quantities of sulfonamines can enhance TAED
performance is quite unusual and surprising.
20382~9 C 6115 (R) Time-Dependence on TAED-SULF Bleachinq A study was conducted to determine the effect of time on the TAED-SULF bleaching system. Table VII shows the data from an experiment conducted, using tea-stained cloths in the Terg-0-Tometer with TAED and sodium perborate in the presence and absence of SULF-l. The amount of stain removal was measured in separate tests at 15, 30 and 45 minutes. The concentration of sulfonimine was varied between 3 - 6 x 10 4 M with a constant 9.0 x 10-4 M
dosage of TAED. Not surprisingly, the bleaching by TAED
alone increased yradually over a period of 45 minutes.
More importantly, the bleaching performance by the sulfonimine containing system also escalated throughout the 45-minute period, regardless of SULF concentration.
The net result after 45-minutes of washing is a doubling of TAED performance brought about by a relatively low level of sulfonimine.
2~38~09 C 6115 (R) TABLE VII
TAED - SULF-l Bleachin~ Performance over Time [SULF-1] t AR a R
x 10-4 M min TAEDSULF
6 15 3.09.6 3C 5.612.9
7.315.7 3 15 3.88.8 5.612.9 7.315.7 20382~
C 6115 (R) Variable TemPerature Performance of the TAED-SULF
Bleachinq System sleaching results for the previous experiments were accumulated at a wash temperature of 40~c. Herein is demonstrated that the activation of TAED by sulfonimines also occurs at lower and higher wash temperatures.
Experiments were conducted in a Terg-0-Tometer under conditions identical with those described earlier except that the wash temperature was kept those at 12-13~C or 58-59~C. SULF-1 was used as the oxygen transfer agent in these experiments at 6 or 3 x 10-4 M with a 9.0 x 10-4 M
dosage of TAED. In the low-temperature cases, activation of TAED by the sulfonimine was observed between 15 and 45 minutes, regardless of concentration.
Analogously, the performance of TAED was enhanced at higher temperatures (about 60~C) over a 30-minute washing period. It should be pointed out that these lower temperatures represent the extremes found in actual fabric bleaching field conditions. The ability of sulfonimines to enhance TAED performance at variable temperatures may be of utility in countries where both hot and cold washes are practiced.
~38~9 C 6115 (R) TABLE VIII
Effects cf TemPerature on TAED - SULF-l Bleachinq Performance [SULF-l] t Temp ~ R ~ R
x 10-4 min ~C TAEDSULF
12 -0.2 1.8 13 1.3 4.1 13 1.7 5.5 3 15 12 0.0 1.2 13 1.2 3.7 12 2.1 5.3 ___ _ _ _____________________ 6 15 58 7.3 11.1 59 12.314.6 2~3~2~9 51 C 6115 tR) Hydrophobic Stain Bleaching by Sulfonimines and TAED-Perborate Systems A hydrophobic spaghetti stain was prepared by treating cotton cloths with spaghetti sauce. Removal of this stain was measured reflectometrically as described in Example 14. Bleaching of the oily stain is reported as B, i.e.~ = (Reflectance of stained fabxic washed with sulfonimine/TAED/perborate - reflectance of stained fabric before washing) - (reflectance of stained fabric washed with TAED/perborate alone (reflPctance of stained fabric before washing~.
The results using N-Benzylidenebenzenesulfonamide as oxygen transfer agent in conjunction with 4.5 x 10-4 M
TAED and 6:1 sodium perborate monohydrate in Surf ~ at pH g.S and 40~C (15-minute wash time) are shown in Table IX.
C 6115 (R) TABLE IX
Bleaching of Spaghetti Stain by Sulfonimine/TAED/Perborate sYstems [SULF]
x 10-4 M ~M
1.0 2.0 0.5 1.0 2~3821~9 C 6115 (R) ~he foregoing descriptions and Examples illustrate selected embodiments of the present invention. In light thereof, various modifications will be suggested to one skilled in the art, all of which are within the spirit and purview of this invention.
C 6115 (R) Variable TemPerature Performance of the TAED-SULF
Bleachinq System sleaching results for the previous experiments were accumulated at a wash temperature of 40~c. Herein is demonstrated that the activation of TAED by sulfonimines also occurs at lower and higher wash temperatures.
Experiments were conducted in a Terg-0-Tometer under conditions identical with those described earlier except that the wash temperature was kept those at 12-13~C or 58-59~C. SULF-1 was used as the oxygen transfer agent in these experiments at 6 or 3 x 10-4 M with a 9.0 x 10-4 M
dosage of TAED. In the low-temperature cases, activation of TAED by the sulfonimine was observed between 15 and 45 minutes, regardless of concentration.
Analogously, the performance of TAED was enhanced at higher temperatures (about 60~C) over a 30-minute washing period. It should be pointed out that these lower temperatures represent the extremes found in actual fabric bleaching field conditions. The ability of sulfonimines to enhance TAED performance at variable temperatures may be of utility in countries where both hot and cold washes are practiced.
~38~9 C 6115 (R) TABLE VIII
Effects cf TemPerature on TAED - SULF-l Bleachinq Performance [SULF-l] t Temp ~ R ~ R
x 10-4 min ~C TAEDSULF
12 -0.2 1.8 13 1.3 4.1 13 1.7 5.5 3 15 12 0.0 1.2 13 1.2 3.7 12 2.1 5.3 ___ _ _ _____________________ 6 15 58 7.3 11.1 59 12.314.6 2~3~2~9 51 C 6115 tR) Hydrophobic Stain Bleaching by Sulfonimines and TAED-Perborate Systems A hydrophobic spaghetti stain was prepared by treating cotton cloths with spaghetti sauce. Removal of this stain was measured reflectometrically as described in Example 14. Bleaching of the oily stain is reported as B, i.e.~ = (Reflectance of stained fabxic washed with sulfonimine/TAED/perborate - reflectance of stained fabric before washing) - (reflectance of stained fabric washed with TAED/perborate alone (reflPctance of stained fabric before washing~.
The results using N-Benzylidenebenzenesulfonamide as oxygen transfer agent in conjunction with 4.5 x 10-4 M
TAED and 6:1 sodium perborate monohydrate in Surf ~ at pH g.S and 40~C (15-minute wash time) are shown in Table IX.
C 6115 (R) TABLE IX
Bleaching of Spaghetti Stain by Sulfonimine/TAED/Perborate sYstems [SULF]
x 10-4 M ~M
1.0 2.0 0.5 1.0 2~3821~9 C 6115 (R) ~he foregoing descriptions and Examples illustrate selected embodiments of the present invention. In light thereof, various modifications will be suggested to one skilled in the art, all of which are within the spirit and purview of this invention.
Claims (15)
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A bleaching composition comprising:
( i) from about 1 to about 60% by weight of a peroxygen compound;
( ii) from about 0.05 to about 10% of an oxygen transfer agent whose structure is:
R1R2C=NSO2R3 wherein:
R1 may be a substituted or unsubstituted radical selected from the grouping consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl and cycloalkyl radicals;
R2 may be a substituted or unsubstituted radical selected from the group consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl, cycloalkyl, R1C=NSO2R3, nitro, halo, cyano, alkoxy, keto, carboxylic, and carboalkoxy radicals;
R3 may be a substituted or unsubstituted radical selected from the group consisting of phenyl, aryl, heterocyclic ring, alkyl, cycloalkyl, nitro, halo and cyano radicals;
R1 with R2 and R2 with R3 may respectively together form a cycloalkyl, heterocyclic, and aromatic ring system; and (iii) from about 0.1 to about 40% of a bleach precursor that reacts with peroxide anion and forms therewith a peracid or perimidic acid.
( i) from about 1 to about 60% by weight of a peroxygen compound;
( ii) from about 0.05 to about 10% of an oxygen transfer agent whose structure is:
R1R2C=NSO2R3 wherein:
R1 may be a substituted or unsubstituted radical selected from the grouping consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl and cycloalkyl radicals;
R2 may be a substituted or unsubstituted radical selected from the group consisting of hydrogen, phenyl, aryl, heterocyclic ring, alkyl, cycloalkyl, R1C=NSO2R3, nitro, halo, cyano, alkoxy, keto, carboxylic, and carboalkoxy radicals;
R3 may be a substituted or unsubstituted radical selected from the group consisting of phenyl, aryl, heterocyclic ring, alkyl, cycloalkyl, nitro, halo and cyano radicals;
R1 with R2 and R2 with R3 may respectively together form a cycloalkyl, heterocyclic, and aromatic ring system; and (iii) from about 0.1 to about 40% of a bleach precursor that reacts with peroxide anion and forms therewith a peracid or perimidic acid.
2. A composition according to Claim 1 wherein the peroxygen compound is present in an amount from about 1.5 to 25% and the oxygen transfer agent is present in an amount from about 0.2 to 5% by weight.
3. A composition according to Claim 1 wherein the peroxygen compound is an inorganic material selected from the group consisting of perborate, percarbonate, perphosphate, persilicate and monopersulphate salts.
4. A composition according to Claim 1 wherein at least one of R1, R2 and R3 is substituted with a water-solubilizing functional group.
5. A composition according to Claim 4 wherein the water-solubilizing functional group is selected from the group consisting of carboxylic acid, phosphoric acid, phosphonic acid, sulfuric acid, sulphonic acid and salts thereof.
6. A composition according to Claim 1 wherein said substituent on R1, R2 and R3 is a functional unit selected from the group consisting of nitro, halo, cyano, C1-C20 alkyl, amino, aminoalkyl, thioalkyl, sulfoxyalkyl, carboxyesters, hydroxy, C1-C20 alkoxy, polyalkoxy C1-C40 quaternary di- or tri-alkylammonium functional units and mixtures thereof.
7. A composition according to Claim 6 wherein said quaternary alkylammonium functional unit is a cholyl group.
8. A composition according to Claim 1 wherein the oxygen transfer agent is selected from N-(4-carboxy benzylidene)-4-chlorobenzenesulfonamide, N-(4-carboxybenzylidene)-benzenesulfonamide, N-(4-chlorobenzylidene)-4-carboxy- benzenesulfonamide, N-benzylidene-4-carboxybenzene sulfonamide, N-(4-carboxybenzylidene)-4-carboxy- benzenesulfonamide, N-(4-carboxybenzylidene)-3-nitro- benzenesulfonamide, N-(4-cyanobenzylidene)-4-carboxy benzenesulfonamide, N-(4-methoxybenzylidene)-4-carboxy benzenesulfonamide, N-(3-hydroxybenzylidene)-4-chloro benzenesulfonamide, bis-N-terephthalidene-4-carboxy benzenesulfonamide, 3-methyl-1,2-benzisothiazole-1,1-dioxide, N-(pyridinylmethylene) benzenesulfonamide, N-benzylidene benzenesulfonamide and 1,2-benzisothiazole-1,1-dioxide.
9. A composition according to Claim 1 wherein the bleach precursor is selected from N,N,N',N'-tetraacetyl ethylenediamine, tetraacetylglycoluril, glucose pentaacetate, and xylose tetraacetate.
10. A composition according to Claim 1 wherein the bleach precursor is selected from the group consisting of sodium nonanoylbenzenesulfonate, sodium benzoyl benzenesulfonate and sodium acetyloxybenzene sulfonate.
11. A composition according to Claim 1 wherein the bleach precursor is present in an amount from about 1%
to about 10% by weight.
to about 10% by weight.
12. A composition according to Claim 1 further comprising about 1 to about 80% of a detergent builder.
13. A composition according to Claim 1 further comprising an effective amount for cleaning of an enzyme selected from the group consisting of proteases, cellulases, lipases, amylases and mixtures thereof.
14. A method for bleaching a stained substrate, said method comprising treating said stained substrate with a peroxygen compound, a bleach precursor and with an oxygen transfer agent whose structure is ;
R1R2C=NSO2R3 wherein R1, R2 and R3 are as defined in Claim 1, bleaching occurring in a liquid medium containing about 0.05 to about 250 ppm active oxygen from the peroxygen compound, about 0.05 to about 200 ppm bleach precursor and about 0.01 to about 300 ppm oxygen transfer agent per liter of medium.
R1R2C=NSO2R3 wherein R1, R2 and R3 are as defined in Claim 1, bleaching occurring in a liquid medium containing about 0.05 to about 250 ppm active oxygen from the peroxygen compound, about 0.05 to about 200 ppm bleach precursor and about 0.01 to about 300 ppm oxygen transfer agent per liter of medium.
15. A bleaching composition as claimed in claim 1 and substantially as described herein.
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US494632 | 1990-03-16 | ||
US07/494,632 US5047163A (en) | 1990-03-16 | 1990-03-16 | Activation of bleach precursors with sulfonimines |
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EP (1) | EP0446982B1 (en) |
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US5653910A (en) * | 1995-06-07 | 1997-08-05 | Lever Brothers Company, Division Of Conopco Inc. | Bleaching compositions containing imine, hydrogen peroxide and a transition metal catalyst |
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-
1990
- 1990-03-16 US US07/494,632 patent/US5047163A/en not_active Expired - Lifetime
-
1991
- 1991-02-28 EP EP91200428A patent/EP0446982B1/en not_active Expired - Lifetime
- 1991-02-28 DE DE69104751T patent/DE69104751T2/en not_active Expired - Fee Related
- 1991-02-28 ES ES91200428T patent/ES2062662T3/en not_active Expired - Lifetime
- 1991-03-13 NO NO910996A patent/NO177432C/en not_active IP Right Cessation
- 1991-03-13 AU AU72873/91A patent/AU635620B2/en not_active Ceased
- 1991-03-14 CA CA002038209A patent/CA2038209C/en not_active Expired - Fee Related
- 1991-03-14 MY MYPI91000421A patent/MY105345A/en unknown
- 1991-03-15 ZA ZA911938A patent/ZA911938B/en unknown
- 1991-03-15 BR BR919101037A patent/BR9101037A/en not_active IP Right Cessation
- 1991-03-15 JP JP3075728A patent/JPH08920B2/en not_active Expired - Fee Related
- 1991-03-16 KR KR1019910004184A patent/KR950003427B1/en not_active IP Right Cessation
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US5047163A (en) | 1991-09-10 |
AU635620B2 (en) | 1993-03-25 |
ZA911938B (en) | 1992-11-25 |
EP0446982A3 (en) | 1992-06-03 |
JPH08920B2 (en) | 1996-01-10 |
KR950003427B1 (en) | 1995-04-12 |
NO910996D0 (en) | 1991-03-13 |
NO177432B (en) | 1995-06-06 |
ES2062662T3 (en) | 1994-12-16 |
KR910016911A (en) | 1991-11-05 |
MY105345A (en) | 1994-09-30 |
BR9101037A (en) | 1991-11-05 |
EP0446982A2 (en) | 1991-09-18 |
DE69104751T2 (en) | 1995-03-02 |
NO910996L (en) | 1991-09-17 |
EP0446982B1 (en) | 1994-10-26 |
NO177432C (en) | 1995-09-13 |
CA2038209A1 (en) | 1991-09-17 |
DE69104751D1 (en) | 1994-12-01 |
JPH0770597A (en) | 1995-03-14 |
AU7287391A (en) | 1991-09-19 |
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