CA2031827A1 - Process for producing multilayer polytetrafluoroethylene porous membrane - Google Patents
Process for producing multilayer polytetrafluoroethylene porous membraneInfo
- Publication number
- CA2031827A1 CA2031827A1 CA002031827A CA2031827A CA2031827A1 CA 2031827 A1 CA2031827 A1 CA 2031827A1 CA 002031827 A CA002031827 A CA 002031827A CA 2031827 A CA2031827 A CA 2031827A CA 2031827 A1 CA2031827 A1 CA 2031827A1
- Authority
- CA
- Canada
- Prior art keywords
- porous membrane
- extrudate
- liquid lubricant
- producing multilayer
- polytetrafluoroethylene porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 polytetrafluoroethylene Polymers 0.000 title abstract 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 title abstract 3
- 239000004810 polytetrafluoroethylene Substances 0.000 title abstract 3
- 239000012528 membrane Substances 0.000 title abstract 2
- 239000010687 lubricating oil Substances 0.000 abstract 3
- 229940058401 polytetrafluoroethylene Drugs 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/005—Shaping by stretching, e.g. drawing through a die; Apparatus therefor characterised by the choice of materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1212—Coextruded layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/30—Polyalkenyl halides
- B01D71/32—Polyalkenyl halides containing fluorine atoms
- B01D71/36—Polytetrafluoroethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/023—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets using multilayered plates or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2027/00—Use of polyvinylhalogenides or derivatives thereof as moulding material
- B29K2027/12—Use of polyvinylhalogenides or derivatives thereof as moulding material containing fluorine
- B29K2027/18—PTFE, i.e. polytetrafluorethene, e.g. ePTFE, i.e. expanded polytetrafluorethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
Abstract
A process for producing a multilayer polytetrafluoro-ethylene porous membrane comprising at least two layers having different average pore diameters is disclosed, the process comprising the steps of: filling the inside of a cylinder of an extruding mold distinctively with at least two kinds of polytetrafluoroethylene fine powders with each of which a liquid lubricant has been mixed; subsequently paste-extruding the powders to obtain a multilayer extrudate, which is then optionally rolled; and then stretching the extrudate or the rolled extrudate at least monoaxially after the liquid lubricant is removed therefrom or without removing the liquid lubricant.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1320273A JPH078926B2 (en) | 1989-12-07 | 1989-12-07 | Method for producing polytetrafluoroethylene multilayer porous membrane |
JPHEI.1-320273 | 1989-12-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2031827A1 true CA2031827A1 (en) | 1991-06-08 |
CA2031827C CA2031827C (en) | 2002-09-03 |
Family
ID=18119663
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002031827A Expired - Lifetime CA2031827C (en) | 1989-12-07 | 1990-12-07 | Process for producing multilayer polytetrafluoroethylene porous membrane |
Country Status (12)
Country | Link |
---|---|
US (1) | US5064593A (en) |
EP (1) | EP0433787B1 (en) |
JP (1) | JPH078926B2 (en) |
KR (1) | KR0150640B1 (en) |
CN (1) | CN1030690C (en) |
AU (1) | AU623068B2 (en) |
BR (1) | BR9006236A (en) |
CA (1) | CA2031827C (en) |
DE (1) | DE69019694T2 (en) |
ES (1) | ES2075123T3 (en) |
PL (1) | PL165872B1 (en) |
RU (1) | RU2045328C1 (en) |
Families Citing this family (79)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5225131A (en) * | 1989-12-07 | 1993-07-06 | Daikin Industries, Ltd. | Process for producing multilayer polytetrafluoroethylene porous membrane and semisintered polytetrafluoroethylene multilayer structure |
JP3116410B2 (en) * | 1991-04-11 | 2000-12-11 | 住友電気工業株式会社 | Method for producing colored polytetrafluoroethylene porous body |
US5217666A (en) * | 1991-05-29 | 1993-06-08 | Daikin Industries Ltd. | Process for producing porous polytetrafluoroethylene film |
ES2038556B1 (en) * | 1991-12-23 | 1994-02-16 | Univ Cantabria | BIOLOGICAL WASTEWATER TREATMENT PROCESS BASED ON A BIOFILM DEVELOPED ON A GAS PERMEABLE SUPPORT. |
CA2131902C (en) * | 1992-03-13 | 2004-08-03 | Paul Martakos | Controlled porosity expanded polytetrafluoroethylene products and fabrication |
DE69327041T2 (en) * | 1992-07-30 | 2000-04-13 | Daikin Ind Ltd | POROESES POLYTETRAFLUORETHYLENE MATERIAL AND METHOD FOR THE PRODUCTION THEREOF |
US5453235A (en) * | 1993-01-29 | 1995-09-26 | Impra, Inc. | Method of forming dual porosity FTFE tubes by extrusion of concentric preforms |
DE4308368C2 (en) * | 1993-03-16 | 1997-05-22 | Gore & Ass | Porous polytetrafluoroethylene (PTFE) and a process for its production |
US5399307A (en) * | 1993-06-18 | 1995-03-21 | Dalton; Robert E. | Methods of compression molding two or more polytetrafluoroethylene resin layers |
AT399507B (en) * | 1993-07-30 | 1995-05-26 | Chemiefaser Lenzing Ag | BICOMPONENT MOLDED BODIES MADE OF POLYTETRAFLUORETHYLENE (PTFE) AND METHOD FOR THE PRODUCTION THEREOF |
US5393929A (en) * | 1993-11-23 | 1995-02-28 | Junkosha Co. Ltd. | Electrical insulation and articles thereof |
JP3003500B2 (en) * | 1994-04-28 | 2000-01-31 | ダイキン工業株式会社 | Polytetrafluoroethylene composite porous membrane |
CA2193804A1 (en) * | 1994-06-30 | 1996-01-11 | Shinji Tamaru | Bulky long fiber and split yarn of polytetrafluoroethylene, method of manufacturing the same, cotton-like material manufacturing method using the fiber and yarn, and dust collecting filter cloth |
ATE202971T1 (en) * | 1994-09-23 | 2001-07-15 | Impra Inc | CARBON VASCULAR TRANSPLANT AND PRODUCTION METHOD |
DE19544912A1 (en) | 1995-12-01 | 1997-06-05 | Gore W L & Ass Gmbh | PTFE body made of microporous polytetrafluoroethylene with filler and process for its production |
US6428571B1 (en) * | 1996-01-22 | 2002-08-06 | Scimed Life Systems, Inc. | Self-sealing PTFE vascular graft and manufacturing methods |
US5800512A (en) * | 1996-01-22 | 1998-09-01 | Meadox Medicals, Inc. | PTFE vascular graft |
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DE19638416C1 (en) * | 1996-09-19 | 1997-11-13 | Gore W L & Ass Gmbh | Microporous fluoro-polymer blend with thermoplastic to increase strength |
US5925074A (en) * | 1996-12-03 | 1999-07-20 | Atrium Medical Corporation | Vascular endoprosthesis and method |
US6010529A (en) | 1996-12-03 | 2000-01-04 | Atrium Medical Corporation | Expandable shielded vessel support |
JP2000079332A (en) * | 1998-07-08 | 2000-03-21 | Nitto Denko Corp | Filter medium for air filter |
US6517571B1 (en) | 1999-01-22 | 2003-02-11 | Gore Enterprise Holdings, Inc. | Vascular graft with improved flow surfaces |
US6342294B1 (en) * | 1999-08-12 | 2002-01-29 | Bruce G. Ruefer | Composite PTFE article and method of manufacture |
US6454744B1 (en) * | 1999-12-23 | 2002-09-24 | Tfx Medical, Inc. | Peelable PTFE sheaths and methods for manufacture of same |
US6923927B2 (en) * | 2000-10-03 | 2005-08-02 | Atrium Medical Corporation | Method for forming expandable polymers having drugs or agents included therewith |
US6616876B1 (en) | 2000-10-03 | 2003-09-09 | Atrium Medical Corporation | Method for treating expandable polymer materials |
DE10061936A1 (en) * | 2000-12-13 | 2002-07-04 | Valentin Kramer | Object from ePTFE and method of manufacturing the same |
CN100422741C (en) * | 2003-03-27 | 2008-10-01 | 泰尔茂株式会社 | Test paper and porous membrane |
WO2005118254A1 (en) * | 2004-06-03 | 2005-12-15 | Coltec Industrial Products Llc | Multifuncton multilayer ptfe tape and method of manufacture |
US8029563B2 (en) | 2004-11-29 | 2011-10-04 | Gore Enterprise Holdings, Inc. | Implantable devices with reduced needle puncture site leakage |
JP5097556B2 (en) * | 2004-12-22 | 2012-12-12 | インテグリス・インコーポレーテッド | Multilayer porous membrane and manufacturing method |
MX2008001671A (en) * | 2005-08-03 | 2008-02-19 | Donaldson Co Inc | Microporous membrane for flash distillation. |
JP5097826B2 (en) * | 2007-08-24 | 2012-12-12 | ヴラームス インステリング ヴール テクノロギシュ オンデルゾーク (ヴイアイティーオー) | Filled polymer membrane, use and manufacturing method |
JP5220369B2 (en) | 2007-09-04 | 2013-06-26 | 富士フイルム株式会社 | Crystalline polymer microporous membrane, method for producing the same, and filter for filtration |
US8637144B2 (en) * | 2007-10-04 | 2014-01-28 | W. L. Gore & Associates, Inc. | Expandable TFE copolymers, method of making, and porous, expended articles thereof |
US9650479B2 (en) | 2007-10-04 | 2017-05-16 | W. L. Gore & Associates, Inc. | Dense articles formed from tetrafluoroethylene core shell copolymers and methods of making the same |
US9040646B2 (en) | 2007-10-04 | 2015-05-26 | W. L. Gore & Associates, Inc. | Expandable TFE copolymers, methods of making, and porous, expanded articles thereof |
JP2009197147A (en) * | 2008-02-22 | 2009-09-03 | Kurabe Ind Co Ltd | Polytetrafluoroethylene (ptfe) porous material having fine layer structure and method for manufacturing the same |
JP5658860B2 (en) * | 2008-05-12 | 2015-01-28 | 日東電工株式会社 | Polytetrafluoroethylene porous membrane, method for producing the same, and filter medium |
US8075675B2 (en) * | 2008-06-12 | 2011-12-13 | Serveron Corporation | Apparatus and method for extracting gas from liquid |
US20100086767A1 (en) * | 2008-10-06 | 2010-04-08 | General Electric Company | Processes For Producing Multilayer Polytetrafluoroethylene Articles And Articles Formed Therefrom |
JP4944864B2 (en) * | 2008-11-04 | 2012-06-06 | 日東電工株式会社 | Polytetrafluoroethylene porous membrane, method for producing the same, and waterproof air-permeable filter |
CN102049886A (en) * | 2009-10-28 | 2011-05-11 | 上海金由氟材料有限公司 | PTEF (Polytetrafluoroethylene) film for sealing |
US8673440B2 (en) * | 2009-10-30 | 2014-03-18 | Bha Altair, Llc | Porous membrane |
UA97530C2 (en) * | 2010-01-12 | 2012-02-27 | Александр Анатолиевич Осадчий | Polymer diffusion membrane "forsplast-soft" |
JP5470140B2 (en) | 2010-03-31 | 2014-04-16 | 富士フイルム株式会社 | Crystalline polymer microporous membrane and filter for filtration |
US9944044B2 (en) | 2010-05-06 | 2018-04-17 | W. L. Gore & Associates, Inc. | Contamination resistant air permeable fabric laminate and garments made therefrom |
JP2012011369A (en) | 2010-06-01 | 2012-01-19 | Fujifilm Corp | Crystalline polymer microporous membrane, method for manufacturing the same, and filter for filtering |
CN102274694B (en) * | 2010-06-08 | 2013-08-07 | 吕晓龙 | Preparation method for polytetrafluoroethylene separating film |
CN103270108B (en) * | 2010-12-21 | 2016-04-20 | 大金工业株式会社 | Expanded material |
JP2012176361A (en) * | 2011-02-25 | 2012-09-13 | Sumitomo Electric Fine Polymer Inc | Porous multilayered filter |
JP2012206113A (en) * | 2011-03-16 | 2012-10-25 | Fujifilm Corp | Crystalline polymer microporous membrane, method for producing the same, and filtration filter |
KR20140056233A (en) * | 2011-07-05 | 2014-05-09 | 닛토덴코 가부시키가이샤 | Method for producing porous polytetrafluoroethylene film |
JP6039673B2 (en) * | 2011-09-23 | 2016-12-07 | ダブリュ.エル.ゴア アンド アソシエイツ,インコーポレイティドW.L. Gore & Associates, Incorporated | Surface-modified fluoropolymer membrane and method for producing the same |
JP6069221B2 (en) * | 2011-12-05 | 2017-02-01 | 住友電工ファインポリマー株式会社 | Polytetrafluoroethylene porous resin membrane, polytetrafluoroethylene porous resin membrane composite, and separation membrane element |
CN102626990A (en) * | 2012-04-24 | 2012-08-08 | 江苏新氟隆塑胶有限公司 | PTFE (Polytetrafluoroethylene) packing stretch forming equipment system and production process |
US10808054B2 (en) * | 2012-10-10 | 2020-10-20 | Atrium Medical Corporation | Self-bonding fluoropolymers and methods of producing the same |
CN102961976B (en) * | 2012-12-14 | 2015-09-23 | 国家海洋局天津海水淡化与综合利用研究所 | Polytetrafluoroethylhollow hollow fiber perforated membrane and preparation method thereof |
US9573339B2 (en) | 2013-01-18 | 2017-02-21 | W. L. Gore & Associates, Inc. | Low gloss, air permeable, abrasion resistant, printable laminate containing an asymmetric membrane and articles made therefrom |
CN103386256B (en) * | 2013-06-21 | 2015-03-25 | 浙江理工大学 | Method for preparing hollow fiber membranes and tubular membranes with microporous PTFE hybrid flat membrane wrapping method |
KR101433774B1 (en) * | 2013-10-04 | 2014-08-27 | 한국생산기술연구원 | A triple layers filter media for dust collection |
US9814560B2 (en) | 2013-12-05 | 2017-11-14 | W. L. Gore & Associates, Inc. | Tapered implantable device and methods for making such devices |
US9644054B2 (en) | 2014-12-19 | 2017-05-09 | W. L. Gore & Associates, Inc. | Dense articles formed from tetrafluoroethylene core shell copolymers and methods of making the same |
CN105983352B (en) * | 2015-02-16 | 2018-05-15 | 上海灵氟隆新材料科技有限公司 | A kind of high throughput thicker polytetrafluoroethylene film and preparation method thereof |
JP5833263B1 (en) * | 2015-02-24 | 2015-12-16 | 株式会社サンケイ技研 | Method for producing polytetrafluoroethylene porous sheet |
EP3302619A1 (en) | 2015-06-05 | 2018-04-11 | W. L. Gore & Associates, Inc. | A low bleed implantable prosthesis with a taper |
FR3052718B1 (en) * | 2016-06-16 | 2019-08-09 | Faurecia Automotive Industrie | METHOD FOR MANUFACTURING A PIECE OF AUTOMOTIVE EQUIPMENT AND ASSOCIATED PIECE |
CN106364120B (en) * | 2016-08-30 | 2018-09-14 | 上海索康医用材料有限公司 | A kind of preparation method of pure expanded PTFE sheet material |
EP3551440B1 (en) * | 2016-12-09 | 2023-08-23 | 3M Innovative Properties Company | Polymeric multilayer film |
US11229350B2 (en) * | 2017-06-01 | 2022-01-25 | Hoya Corporation | Endoscope with bendable insertion unit |
JP2019192749A (en) * | 2018-04-24 | 2019-10-31 | 日本ゴア株式会社 | Polytetrafluoroethylene film for electronic components |
KR102218062B1 (en) | 2018-10-18 | 2021-02-19 | 주식회사 엘지화학 | Porous fluorine resin film and method for preparing the same |
JP6661098B1 (en) * | 2019-01-28 | 2020-03-11 | 有限会社ヤマカツラボ | Laminated polytetrafluoroethylene porous membrane and method for producing the same |
CN112044278A (en) * | 2020-09-14 | 2020-12-08 | 浙江格尔泰斯环保特材科技股份有限公司 | Preparation method of PTFE microporous membrane with multilayer structure |
CN113368695B (en) * | 2021-06-10 | 2023-01-20 | 盐城海普润科技股份有限公司 | Organic composite tubular membrane and preparation method and application thereof |
CN113844141B (en) * | 2021-09-23 | 2023-09-15 | 上海索康医用材料有限公司 | Expanded polytetrafluoroethylene surgical isolation membrane and manufacturing process thereof |
JP2023061322A (en) * | 2021-10-19 | 2023-05-01 | 株式会社オートネットワーク技術研究所 | Conductor covering material, electric wire, and method for manufacturing conductor covering material |
CN114181481B (en) * | 2021-11-23 | 2023-05-16 | 山东东岳高分子材料有限公司 | Screening method and application for preparing multilayer PTFE composite expanded plate material, expanded plate and preparation method of expanded plate |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4096227A (en) * | 1973-07-03 | 1978-06-20 | W. L. Gore & Associates, Inc. | Process for producing filled porous PTFE products |
US4082893A (en) * | 1975-12-24 | 1978-04-04 | Sumitomo Electric Industries, Ltd. | Porous polytetrafluoroethylene tubings and process of producing them |
US4208745A (en) * | 1976-01-21 | 1980-06-24 | Sumitomo Electric Industries, Ltd. | Vascular prostheses composed of polytetrafluoroethylene and process for their production |
JPS603842B2 (en) * | 1976-09-03 | 1985-01-31 | 住友電気工業株式会社 | Asymmetric pore diameter thin film material and its manufacturing method |
US4385093A (en) * | 1980-11-06 | 1983-05-24 | W. L. Gore & Associates, Inc. | Multi-component, highly porous, high strength PTFE article and method for manufacturing same |
US4596837A (en) * | 1982-02-22 | 1986-06-24 | Daikin Industries Ltd. | Semisintered polytetrafluoroethylene article and production thereof |
US4478898A (en) * | 1982-06-04 | 1984-10-23 | Junkosha Co., Ltd. | Laminated porous polytetrafluoroethylene tube and its process of manufacture |
JPS6116840A (en) * | 1984-07-04 | 1986-01-24 | Nippon Valqua Ind Ltd | Manufacture of porous film of polytetrafluoroethylene |
US4816339A (en) * | 1987-04-28 | 1989-03-28 | Baxter International Inc. | Multi-layered poly(tetrafluoroethylene)/elastomer materials useful for in vivo implantation |
US4961891A (en) * | 1988-10-04 | 1990-10-09 | Garlock, Inc. | Method of making high compressibility gasket material |
US4882113A (en) * | 1989-01-26 | 1989-11-21 | Baxter International Inc. | Heterogeneous elastomeric compositions containing a fluoroelastomer and PTFE and methods for manufacturing said compositions |
PL288122A1 (en) * | 1989-12-07 | 1991-08-26 | Daikin Ind Ltd | Method of obtaining a multilayer porous polyterafluoroethylene membrane and partially sintered miltilayer polytetrafluoroethylene product |
-
1989
- 1989-12-07 JP JP1320273A patent/JPH078926B2/en not_active Expired - Fee Related
-
1990
- 1990-12-06 EP EP90123478A patent/EP0433787B1/en not_active Expired - Lifetime
- 1990-12-06 DE DE69019694T patent/DE69019694T2/en not_active Expired - Fee Related
- 1990-12-06 RU SU904894073A patent/RU2045328C1/en active
- 1990-12-06 US US07/622,899 patent/US5064593A/en not_active Expired - Lifetime
- 1990-12-06 ES ES90123478T patent/ES2075123T3/en not_active Expired - Lifetime
- 1990-12-06 AU AU67846/90A patent/AU623068B2/en not_active Ceased
- 1990-12-06 PL PL90288123A patent/PL165872B1/en unknown
- 1990-12-07 KR KR1019900020071A patent/KR0150640B1/en not_active IP Right Cessation
- 1990-12-07 CA CA002031827A patent/CA2031827C/en not_active Expired - Lifetime
- 1990-12-07 CN CN90109725A patent/CN1030690C/en not_active Expired - Fee Related
- 1990-12-07 BR BR909006236A patent/BR9006236A/en unknown
Also Published As
Publication number | Publication date |
---|---|
CA2031827C (en) | 2002-09-03 |
JPH03179038A (en) | 1991-08-05 |
PL288123A1 (en) | 1991-08-12 |
BR9006236A (en) | 1991-09-24 |
RU2045328C1 (en) | 1995-10-10 |
EP0433787A1 (en) | 1991-06-26 |
US5064593A (en) | 1991-11-12 |
EP0433787B1 (en) | 1995-05-24 |
KR0150640B1 (en) | 1998-10-01 |
PL165872B1 (en) | 1995-02-28 |
AU623068B2 (en) | 1992-04-30 |
JPH078926B2 (en) | 1995-02-01 |
CN1052434A (en) | 1991-06-26 |
AU6784690A (en) | 1991-06-13 |
ES2075123T3 (en) | 1995-10-01 |
DE69019694D1 (en) | 1995-06-29 |
KR910011458A (en) | 1991-08-07 |
DE69019694T2 (en) | 1995-09-21 |
CN1030690C (en) | 1996-01-17 |
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