CA2017952A1 - Thermoplastic elastomeric hydrophilic polyetherurethane expandable catheter - Google Patents
Thermoplastic elastomeric hydrophilic polyetherurethane expandable catheterInfo
- Publication number
- CA2017952A1 CA2017952A1 CA2017952A CA2017952A CA2017952A1 CA 2017952 A1 CA2017952 A1 CA 2017952A1 CA 2017952 A CA2017952 A CA 2017952A CA 2017952 A CA2017952 A CA 2017952A CA 2017952 A1 CA2017952 A1 CA 2017952A1
- Authority
- CA
- Canada
- Prior art keywords
- thermoplastic elastomeric
- agent
- catheter
- expandable catheter
- synthesized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L29/00—Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
- A61L29/04—Macromolecular materials
- A61L29/06—Macromolecular materials obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L29/00—Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
- A61L29/14—Materials characterised by their function or physical properties, e.g. lubricating compositions
- A61L29/16—Biologically active materials, e.g. therapeutic substances
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L29/00—Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
- A61L29/14—Materials characterised by their function or physical properties, e.g. lubricating compositions
- A61L29/18—Materials at least partially X-ray or laser opaque
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61M—DEVICES FOR INTRODUCING MEDIA INTO, OR ONTO, THE BODY; DEVICES FOR TRANSDUCING BODY MEDIA OR FOR TAKING MEDIA FROM THE BODY; DEVICES FOR PRODUCING OR ENDING SLEEP OR STUPOR
- A61M25/00—Catheters; Hollow probes
- A61M25/0009—Making of catheters or other medical or surgical tubes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
- A61L2300/40—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices characterised by a specific therapeutic activity or mode of action
- A61L2300/404—Biocides, antimicrobial agents, antiseptic agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
- A61L2300/40—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices characterised by a specific therapeutic activity or mode of action
- A61L2300/404—Biocides, antimicrobial agents, antiseptic agents
- A61L2300/406—Antibiotics
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
- A61L2300/40—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices characterised by a specific therapeutic activity or mode of action
- A61L2300/42—Anti-thrombotic agents, anticoagulants, anti-platelet agents
Abstract
A melt extruded cathether of thermoplastic elastomeric hydrophilic polyurethane synthesized from a diisocyanate, a polyglycol component comprising a polyethyleneoxide glycol of high molecular weight and a chain extender expands to a larger lumen size when contacted with an aqueous liquid. The catheter may include an antithrombogenic agent, antiinfective agent and radiopaque agent. The hydrophilic polyurethane may be synthesized by one-shot bulk polymerization, and may be melt extruded into the catheter tubing, and may encapsulate a stripe of a stiffening polyurethane.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US36948489A | 1989-06-21 | 1989-06-21 | |
US369,484 | 1989-06-21 | ||
US499,154 | 1990-03-26 | ||
US07/499,154 US5061254A (en) | 1989-06-21 | 1990-03-26 | Thermoplastic elastomeric hydrophilic polyetherurethane expandable catheter |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2017952A1 true CA2017952A1 (en) | 1990-12-22 |
CA2017952C CA2017952C (en) | 1995-08-08 |
Family
ID=27004603
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002017952A Expired - Lifetime CA2017952C (en) | 1989-06-21 | 1990-05-31 | Thermoplastic elastomeric hydrophilic polyetherurethane expandable catheter |
Country Status (6)
Country | Link |
---|---|
US (1) | US5061254A (en) |
EP (1) | EP0404517B1 (en) |
AT (1) | ATE160092T1 (en) |
CA (1) | CA2017952C (en) |
DE (1) | DE69031698T2 (en) |
ES (1) | ES2111530T3 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013030148A1 (en) | 2011-08-29 | 2013-03-07 | Bayer Intellectual Property Gmbh | Hydrophilic thermoplastic polyurethanes and use thereof in medical equipment |
Families Citing this family (93)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IE67657B1 (en) * | 1990-03-26 | 1996-04-17 | Becton Dickinson Co | Catheter tubing of controlled in vivo softening |
IE70756B1 (en) * | 1990-04-11 | 1996-12-30 | Becton Dickinson Co | Radiopaque optically transparent medical tubing |
US5102401A (en) * | 1990-08-22 | 1992-04-07 | Becton, Dickinson And Company | Expandable catheter having hydrophobic surface |
US5344411A (en) * | 1991-02-27 | 1994-09-06 | Leonard Bloom | Method and device for inhibiting HIV, hepatitis B and other viruses and germs when using a catheter in a medical environment |
WO1992015286A1 (en) * | 1991-02-27 | 1992-09-17 | Nova Pharmaceutical Corporation | Anti-infective and anti-inflammatory releasing systems for medical devices |
US5437656A (en) * | 1991-02-27 | 1995-08-01 | Leonard Bloom | Method and device for inhibiting H.I.V. hepatitis B and other viruses and germs when using a needle, scalpel and other sharp instrument in a medical environment |
CA2062433C (en) * | 1991-03-08 | 2000-02-29 | Takashi Matsumoto | Medical tube |
CA2068584C (en) * | 1991-06-18 | 1997-04-22 | Paul H. Burmeister | Intravascular guide wire and method for manufacture thereof |
US5443907A (en) * | 1991-06-18 | 1995-08-22 | Scimed Life Systems, Inc. | Coating for medical insertion guides |
WO1993007217A1 (en) * | 1991-10-01 | 1993-04-15 | Otsuka Pharmaceutical Factory, Inc. | Antithrombotic resin, tube, film and coating |
US5281677A (en) * | 1992-09-03 | 1994-01-25 | Becton, Dickinson And Company | Thermoplastic polyurethane blends |
US5342621A (en) * | 1992-09-15 | 1994-08-30 | Advanced Cardiovascular Systems, Inc. | Antithrombogenic surface |
US6090072A (en) | 1992-10-15 | 2000-07-18 | Scimed Life Systems, Inc. | Expandable introducer sheath |
US5266669A (en) * | 1992-10-26 | 1993-11-30 | Becton, Dickinson And Company | Softening non-swelling polyurethane |
US5512051A (en) * | 1993-02-16 | 1996-04-30 | Boston Scientific Corporation | Slip-layered catheter balloon |
US5567495A (en) * | 1993-08-06 | 1996-10-22 | The Trustees Of Columbia University In The City Of New York | Infection resistant medical devices |
EP0737084B1 (en) * | 1993-12-28 | 2003-03-19 | Boston Scientific Corporation | Slip-layered catheter balloon |
DE69530928T2 (en) * | 1994-08-22 | 2003-12-24 | Zeon Corp | POLYURETHANE OBJECT IN A TUBULAR BALLOON SHAPE |
DE4481181T1 (en) * | 1994-09-01 | 1997-07-17 | Gore & Ass | Hydrophilic polyurethane |
US5601538A (en) * | 1995-03-07 | 1997-02-11 | Medtronic, Inc. | Flow directed catheter with hydrophilic distal end |
US5670601A (en) † | 1995-06-15 | 1997-09-23 | Arco Chemical Technology, L.P. | Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation |
US5836893A (en) * | 1996-03-08 | 1998-11-17 | Scimed Life Systems, Inc. | Intravascular guidewire |
DE19619327A1 (en) * | 1996-05-14 | 1997-11-20 | Dunzendorfer Udo Priv Doz Dr M | Catheter of silicone or polyurethane, with lower infection rate |
US5817057A (en) * | 1996-09-13 | 1998-10-06 | Micro Interventional Systems, Inc. | Fluid propulsion steerable catheter and method |
US5800412A (en) * | 1996-10-10 | 1998-09-01 | Sts Biopolymers, Inc. | Hydrophilic coatings with hydrating agents |
US6106473A (en) | 1996-11-06 | 2000-08-22 | Sts Biopolymers, Inc. | Echogenic coatings |
US7229413B2 (en) * | 1996-11-06 | 2007-06-12 | Angiotech Biocoatings Corp. | Echogenic coatings with overcoat |
US5997517A (en) * | 1997-01-27 | 1999-12-07 | Sts Biopolymers, Inc. | Bonding layers for medical device surface coatings |
US5924998A (en) * | 1997-03-06 | 1999-07-20 | Scimed Life System, Inc. | Guide wire with hydrophilically coated tip |
US6251086B1 (en) | 1999-07-27 | 2001-06-26 | Scimed Life Systems, Inc. | Guide wire with hydrophilically coated tip |
DE69818362T2 (en) * | 1997-07-17 | 2004-07-01 | Nisshinbo Industries, Inc. | Water absorbent polyurethane fiber and process for its manufacture |
US6132388A (en) | 1997-10-16 | 2000-10-17 | Scimed Life Systems, Inc. | Guide wire tip |
US6093157A (en) * | 1997-10-22 | 2000-07-25 | Scimed Life Systems, Inc. | Radiopaque guide wire |
DE19751132C2 (en) * | 1997-11-19 | 2000-04-06 | Udo Dunzendorfer | Surface coated catheter |
US6340441B1 (en) | 1998-03-13 | 2002-01-22 | Scimed Life Systems, Inc. | Multi-layer guide wire and method of manufacture therefor |
US6342047B1 (en) | 1998-06-02 | 2002-01-29 | Terumo Kabushiki Kaisha | Indwelling catheter |
WO2000051660A1 (en) * | 1999-03-05 | 2000-09-08 | Medtronic, Inc. | Polyurethane balloon catheter |
US6358238B1 (en) | 1999-09-02 | 2002-03-19 | Scimed Life Systems, Inc. | Expandable micro-catheter |
US6251136B1 (en) | 1999-12-08 | 2001-06-26 | Advanced Cardiovascular Systems, Inc. | Method of layering a three-coated stent using pharmacological and polymeric agents |
US7179849B2 (en) | 1999-12-15 | 2007-02-20 | C. R. Bard, Inc. | Antimicrobial compositions containing colloids of oligodynamic metals |
US6716895B1 (en) | 1999-12-15 | 2004-04-06 | C.R. Bard, Inc. | Polymer compositions containing colloids of silver salts |
EP1178063A1 (en) * | 2000-08-01 | 2002-02-06 | Huntsman International Llc | Process for preparing a polyurethane material |
US7329412B2 (en) | 2000-12-22 | 2008-02-12 | The Trustees Of Columbia University In The City Of New York | Antimicrobial medical devices containing chlorhexidine free base and salt |
US6585719B2 (en) | 2001-01-04 | 2003-07-01 | Scimed Life Systems, Inc. | Low profile metal/polymer tubes |
US7820284B2 (en) | 2001-12-03 | 2010-10-26 | C.R. Bard Inc. | Microbe-resistant medical device, microbe-resistant polymeric coating and methods for producing same |
CA2433269A1 (en) * | 2002-06-25 | 2003-12-25 | Kieran P. Murphy | Surgical chair for percutaneous spinal catheter insertion |
DE60331552D1 (en) * | 2002-08-13 | 2010-04-15 | Medtronic Inc | PHARMACEUTICALS COMPOSITIONS USING POLY (ETHYLENE-CO (METH) ACRYLATE, MEDICAL DEVICE AND METHOD |
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US20040220534A1 (en) * | 2003-04-29 | 2004-11-04 | Martens Paul W. | Medical device with antimicrobial layer |
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US9162037B2 (en) | 2005-07-06 | 2015-10-20 | Vascular Pathways, Inc. | Intravenous catheter insertion device and method of use |
GB0613333D0 (en) | 2006-07-05 | 2006-08-16 | Controlled Therapeutics Sct | Hydrophilic polyurethane compositions |
GB0613638D0 (en) | 2006-07-08 | 2006-08-16 | Controlled Therapeutics Sct | Polyurethane elastomers |
US10188826B2 (en) * | 2006-09-29 | 2019-01-29 | Covidien Lp | Catheters including antimicrobial sleeve and methods of making catheters |
GB0620685D0 (en) | 2006-10-18 | 2006-11-29 | Controlled Therapeutics Sct | Bioresorbable polymers |
US20080176083A1 (en) * | 2007-01-18 | 2008-07-24 | Noveon, Inc. | High Moisture Vapor Transmissive Polyurethanes |
US8637629B2 (en) | 2007-01-18 | 2014-01-28 | Lubrizol Advanced Materials, Inc. | High moisture vapor transmissive polyurethanes |
ATE489989T1 (en) | 2007-05-07 | 2010-12-15 | Vascular Pathways Inc | INTRODUCTION OF AN INTRAVENOUS CATHETER AND BLOOD COLLECTION DEVICE AND METHOD OF USE |
US9981069B2 (en) | 2007-06-20 | 2018-05-29 | The Trustees Of Columbia University In The City Of New York | Bio-film resistant surfaces |
WO2011005840A2 (en) | 2009-07-07 | 2011-01-13 | Med Institute, Inc. | Hydrogel enhanced medical devices |
US20110144689A1 (en) * | 2009-12-15 | 2011-06-16 | Med Institute, Inc. | Occlusion Device |
US9950139B2 (en) | 2010-05-14 | 2018-04-24 | C. R. Bard, Inc. | Catheter placement device including guidewire and catheter control elements |
US10384039B2 (en) | 2010-05-14 | 2019-08-20 | C. R. Bard, Inc. | Catheter insertion device including top-mounted advancement components |
US9872971B2 (en) | 2010-05-14 | 2018-01-23 | C. R. Bard, Inc. | Guidewire extension system for a catheter placement device |
US11925779B2 (en) | 2010-05-14 | 2024-03-12 | C. R. Bard, Inc. | Catheter insertion device including top-mounted advancement components |
US8932258B2 (en) | 2010-05-14 | 2015-01-13 | C. R. Bard, Inc. | Catheter placement device and method |
US8690833B2 (en) | 2011-01-31 | 2014-04-08 | Vascular Pathways, Inc. | Intravenous catheter and insertion device with reduced blood spatter |
EP3563898B1 (en) | 2011-02-25 | 2020-11-11 | C.R. Bard, Inc. | Medical component insertion device including a retractable needle |
USD903101S1 (en) | 2011-05-13 | 2020-11-24 | C. R. Bard, Inc. | Catheter |
WO2014120741A1 (en) | 2013-01-30 | 2014-08-07 | Vascular Pathways, Inc. | Systems and methods for venipuncture and catheter placement |
US10232146B2 (en) | 2014-09-05 | 2019-03-19 | C. R. Bard, Inc. | Catheter insertion device including retractable needle |
USD903100S1 (en) | 2015-05-01 | 2020-11-24 | C. R. Bard, Inc. | Catheter placement device |
US11040176B2 (en) | 2015-05-15 | 2021-06-22 | C. R. Bard, Inc. | Catheter placement device including an extensible needle safety component |
US10995175B2 (en) | 2015-10-14 | 2021-05-04 | Becton, Dickinson And Company | Thermoplastic polyurethane materials for forming medical devices |
CN108601865B (en) | 2015-12-22 | 2022-02-08 | 阿塞斯血管有限公司 | High strength biomedical materials |
US10493262B2 (en) | 2016-09-12 | 2019-12-03 | C. R. Bard, Inc. | Blood control for a catheter insertion device |
CN106730247A (en) * | 2017-02-04 | 2017-05-31 | 成都鼎信致远科技有限公司 | A kind of blood vessel interposing catheter |
US11400260B2 (en) | 2017-03-01 | 2022-08-02 | C. R. Bard, Inc. | Catheter insertion device |
US10596302B2 (en) | 2017-04-17 | 2020-03-24 | Becton, Dickinson And Company | Catheter tubing with tailored modulus response |
CA3067850A1 (en) | 2017-06-21 | 2018-12-27 | Access Vascular, Inc | High strength porous materials incorporating water soluble polymers |
CN115671504A (en) | 2018-03-07 | 2023-02-03 | 巴德阿克塞斯系统股份有限公司 | Guidewire advancement and blood flashback system for medical device insertion systems |
USD921884S1 (en) | 2018-07-27 | 2021-06-08 | Bard Access Systems, Inc. | Catheter insertion device |
US11613719B2 (en) | 2018-09-24 | 2023-03-28 | Becton, Dickinson And Company | Self-lubricating medical articles |
CN112386778A (en) | 2019-08-19 | 2021-02-23 | 贝克顿·迪金森公司 | Midline catheter placement device |
US20210228781A1 (en) * | 2020-01-24 | 2021-07-29 | Becton, Dickinson And Company | Anti-thrombogenic catheter assembly and related methods |
CA3183979A1 (en) * | 2020-06-30 | 2022-01-06 | Michael Bassett | Articles comprising markings and related methods |
CN114000359A (en) * | 2021-12-01 | 2022-02-01 | 福建中裕水性超纤科技有限公司 | Waterproof breathable polyurethane mesh cloth synthetic leather for shoes and preparation method thereof |
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JPS588700B2 (en) * | 1980-09-12 | 1983-02-17 | 工業技術院長 | Method for producing antithrombotic high modulus polyurethane compound |
US4454309A (en) * | 1980-11-12 | 1984-06-12 | Tyndale Plains-Hunter, Ltd. | Polyurethane polyene compositions |
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WO1988000214A1 (en) * | 1986-06-26 | 1988-01-14 | Tyndale Plains-Hunter, Ltd. | Polyurethane polymers prepared from mixed alkylene glycol resins |
FR2612194A1 (en) * | 1987-03-27 | 1988-09-16 | Tyndale Plains Hunter Ltd | HYDROPHILIC POLYURETHANE AND PROCESS FOR PREPARING THE SAME |
US4798597A (en) * | 1987-04-29 | 1989-01-17 | Sherwood Medical Co | Flexible composite intubation tube |
US4789720A (en) * | 1988-03-09 | 1988-12-06 | Tyndale Plains-Hunter, Ltd. | Hydrophilic polyurethanes prepared from mixed oxyalkylene glycols |
-
1990
- 1990-03-26 US US07/499,154 patent/US5061254A/en not_active Expired - Lifetime
- 1990-05-31 CA CA002017952A patent/CA2017952C/en not_active Expired - Lifetime
- 1990-06-19 ES ES90306678T patent/ES2111530T3/en not_active Expired - Lifetime
- 1990-06-19 DE DE69031698T patent/DE69031698T2/en not_active Expired - Lifetime
- 1990-06-19 AT AT90306678T patent/ATE160092T1/en not_active IP Right Cessation
- 1990-06-19 EP EP90306678A patent/EP0404517B1/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013030148A1 (en) | 2011-08-29 | 2013-03-07 | Bayer Intellectual Property Gmbh | Hydrophilic thermoplastic polyurethanes and use thereof in medical equipment |
Also Published As
Publication number | Publication date |
---|---|
EP0404517B1 (en) | 1997-11-12 |
ES2111530T3 (en) | 1998-03-16 |
DE69031698D1 (en) | 1997-12-18 |
US5061254A (en) | 1991-10-29 |
DE69031698T2 (en) | 1998-04-23 |
EP0404517A1 (en) | 1990-12-27 |
ATE160092T1 (en) | 1997-11-15 |
CA2017952C (en) | 1995-08-08 |
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