CA2004112A1 - Dispersions - Google Patents
DispersionsInfo
- Publication number
- CA2004112A1 CA2004112A1 CA2004112A CA2004112A CA2004112A1 CA 2004112 A1 CA2004112 A1 CA 2004112A1 CA 2004112 A CA2004112 A CA 2004112A CA 2004112 A CA2004112 A CA 2004112A CA 2004112 A1 CA2004112 A1 CA 2004112A1
- Authority
- CA
- Canada
- Prior art keywords
- dispersions
- titanium dioxide
- light
- absorbant
- absorbancy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0245—Specific shapes or structures not provided for by any of the groups of A61K8/0241
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/044—Suspensions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/29—Titanium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y5/00—Nanobiotechnology or nanomedicine, e.g. protein engineering or drug delivery
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/04—Oxides; Hydroxides
- C01G23/047—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/36—Compounds of titanium
- C09C1/3607—Titanium dioxide
- C09C1/3615—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
- C09C1/3623—Grinding
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
- C09D17/007—Metal oxide
- C09D17/008—Titanium dioxide
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/84—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by UV- or VIS- data
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
Abstract
An aqueous dispersion of acicular fine particle size titanium dioxide containing from 20 to 60% by weight solids content and a polycarboxylic dispersant is of outstanding use in the preparation of sun screens. The dispersions are transparent to visible light and absorbant to UV light of broad spectrum. Usually the titanium dioxide has a largest dimension within the range 0.01 to 0.15 micron.
The dispersions are produced by milling, preferably in a high speed mill, until the required UV absorbancy is attained.
The dispersions are produced by milling, preferably in a high speed mill, until the required UV absorbancy is attained.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB888829402A GB8829402D0 (en) | 1988-12-16 | 1988-12-16 | Dispersion |
GB8829402.0 | 1988-12-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2004112A1 true CA2004112A1 (en) | 1990-06-16 |
CA2004112C CA2004112C (en) | 1995-08-08 |
Family
ID=10648618
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA002004112A Expired - Lifetime CA2004112C (en) | 1988-12-16 | 1989-11-29 | Dispersions |
Country Status (13)
Country | Link |
---|---|
US (1) | US5068056A (en) |
JP (1) | JP2781433B2 (en) |
AU (1) | AU620473B2 (en) |
BE (1) | BE1004166A5 (en) |
CA (1) | CA2004112C (en) |
DE (1) | DE3941543B4 (en) |
ES (1) | ES2029152A6 (en) |
FR (1) | FR2640635B1 (en) |
GB (2) | GB8829402D0 (en) |
IT (1) | IT1238010B (en) |
MY (1) | MY105755A (en) |
NL (1) | NL8903014A (en) |
ZA (1) | ZA899319B (en) |
Families Citing this family (69)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9121143D0 (en) * | 1991-10-04 | 1991-11-13 | Tioxide Chemicals Limited | Dispersions |
GB9121153D0 (en) * | 1991-10-04 | 1991-11-13 | Tioxide Chemicals Ltd | Method of preparing sunscreens |
DE4139993A1 (en) * | 1991-12-04 | 1993-06-09 | Merck Patent Gmbh, 6100 Darmstadt, De | PIGMENT PREPARATION |
FR2686793B1 (en) * | 1992-01-31 | 1994-04-15 | Oreal | COSMETIC COMPOSITION FOR MAKE-UP CONTAINING A TRANSPARENT PIGMENT OF TITANIUM OXIDE AND SILICON OXIDE. |
GB9204388D0 (en) * | 1992-02-29 | 1992-04-15 | Tioxide Specialties Ltd | Water-in-oil emulsions |
GB9204387D0 (en) * | 1992-02-29 | 1992-04-15 | Tioxide Specialties Ltd | Oil-in-water emulsions |
DE4222413C2 (en) * | 1992-07-08 | 1996-07-25 | Schulz Gmbh & Co Kg Farben Und | wood stain |
WO1994018940A1 (en) * | 1993-02-26 | 1994-09-01 | Estee Lauder, Inc. | Titanium dioxide dispersions, cosmetic compositions and methods for using the same |
US5603863A (en) * | 1993-03-01 | 1997-02-18 | Tioxide Specialties Limited | Water-in-oil emulsions |
GB9307658D0 (en) * | 1993-04-14 | 1993-06-02 | Tioxide Specialties Ltd | Compositions containing sunscreens |
US5747012A (en) * | 1993-06-11 | 1998-05-05 | Tioxide Specialties Limited | Compositions containing sunscreens |
DE4329129A1 (en) * | 1993-08-30 | 1995-03-02 | Merck Patent Gmbh | Photostabilisation of titanium dioxide sols |
AU675000B2 (en) * | 1993-10-22 | 1997-01-16 | Ishihara Sangyo Kaisha Ltd. | Dendrite or asteroidal titanium dioxide micro-particles and process for producing the same |
US5599530A (en) * | 1994-12-16 | 1997-02-04 | Revlon Consumer Products Corporation | Surface treated pigments |
US5567353A (en) * | 1995-04-13 | 1996-10-22 | Rohm And Haas Company | Method for dispersing ceramic material in an aqueous medium |
WO1997015526A1 (en) * | 1995-10-27 | 1997-05-01 | E.I. Du Pont De Nemours And Company | Hydrothermal process for making ultrafine metal oxide powders |
EP0880561B1 (en) * | 1995-11-06 | 2003-01-08 | M & J Bos Consultants Pty. Ltd. | Uv absorbing compositions |
US6113873A (en) * | 1995-12-27 | 2000-09-05 | Sakai Chemical Industry Co., Ltd. | Stable anatase titanium dioxide and process for preparing the same |
CA2250962C (en) * | 1996-04-04 | 2003-06-03 | Nanophase Technologies Corporation | Siloxane star-graft polymers, ceramic powders coated therewith and method of preparing coated ceramic powders |
GB9616978D0 (en) * | 1996-08-13 | 1996-09-25 | Tioxide Specialties Ltd | Zinc oxide dispersions |
US5993967A (en) * | 1997-03-28 | 1999-11-30 | Nanophase Technologies Corporation | Siloxane star-graft polymers, ceramic powders coated therewith and method of preparing coated ceramic powders |
US7226966B2 (en) * | 2001-08-03 | 2007-06-05 | Nanogram Corporation | Structures incorporating polymer-inorganic particle blends |
US6290735B1 (en) * | 1997-10-31 | 2001-09-18 | Nanogram Corporation | Abrasive particles for surface polishing |
US6599631B2 (en) * | 2001-01-26 | 2003-07-29 | Nanogram Corporation | Polymer-inorganic particle composites |
US6099798A (en) * | 1997-10-31 | 2000-08-08 | Nanogram Corp. | Ultraviolet light block and photocatalytic materials |
US5997887A (en) * | 1997-11-10 | 1999-12-07 | The Procter & Gamble Company | Skin care compositions and method of improving skin appearance |
US6013270A (en) * | 1998-04-20 | 2000-01-11 | The Procter & Gamble Company | Skin care kit |
KR100277164B1 (en) * | 1998-07-16 | 2001-01-15 | 장인순 | A preparing method for crystalline micropowder of Titania from aqueous Titanium(Ⅳ) chloride by homogeneous precipitation process at low temperature |
US6440383B1 (en) * | 1999-06-24 | 2002-08-27 | Altair Nanomaterials Inc. | Processing aqueous titanium chloride solutions to ultrafine titanium dioxide |
US6548039B1 (en) * | 1999-06-24 | 2003-04-15 | Altair Nanomaterials Inc. | Processing aqueous titanium solutions to titanium dioxide pigment |
GB0015381D0 (en) * | 2000-06-26 | 2000-08-16 | Acma Ltd | Particulate metal oxide |
US6569920B1 (en) * | 2000-08-16 | 2003-05-27 | Millennium Inorganic Chemicals, Inc. | Titanium dioxide slurries having improved stability |
JP2004518599A (en) * | 2000-08-30 | 2004-06-24 | カイザー インダストリーズ、リミテッド | Additive carrier made of disintegrable gel for ion-containing composition |
WO2002032574A2 (en) | 2000-10-17 | 2002-04-25 | Altair Nanomaterials Inc. | Method for producing catalyst structures |
US6890510B2 (en) | 2001-07-20 | 2005-05-10 | Altair Nanomaterials Inc. | Process for making lithium titanate |
EP1282180A1 (en) * | 2001-07-31 | 2003-02-05 | Xoliox SA | Process for producing Li4Ti5O12 and electrode materials |
US6982073B2 (en) | 2001-11-02 | 2006-01-03 | Altair Nanomaterials Inc. | Process for making nano-sized stabilized zirconia |
GB0127325D0 (en) * | 2001-11-14 | 2002-01-02 | Acma | Metal oxide composition |
GB0130658D0 (en) * | 2001-12-21 | 2002-02-06 | Acma | Particulate metal oxide |
ATE485241T1 (en) * | 2002-03-08 | 2010-11-15 | Altair Nanomaterials Inc | METHOD FOR PRODUCING NANOSCALE AND SUBMICRON SCALE LITHIUM TRANSITION METAL OXIDES |
DE10225123A1 (en) | 2002-06-06 | 2003-12-18 | Goldschmidt Ag Th | Highly concentrated aqueous dispersion containing hydrophilic microfine metal oxide particles and dispersing agents |
US20060264520A1 (en) * | 2003-03-31 | 2006-11-23 | Shuji Sonezaki | Surface-modified titanium dioxide fine particles and dispersion comprising the same, and method for producing the same |
US7482304B2 (en) * | 2003-12-10 | 2009-01-27 | Altair Nanomaterials Inc. | Method for producing structures |
DE10359839A1 (en) * | 2003-12-19 | 2005-07-21 | Sachtleben Chemie Gmbh | Process for the preparation of a catalyst preparation and use of the catalyst preparation |
GB0406037D0 (en) * | 2004-03-18 | 2004-04-21 | Ici Plc | Metal oxide dispersion |
JP4780635B2 (en) * | 2004-06-16 | 2011-09-28 | 東邦チタニウム株式会社 | Method for producing titanium oxide dispersion |
JP4523344B2 (en) * | 2004-06-16 | 2010-08-11 | 東邦チタニウム株式会社 | Method for producing titanium oxide dispersion |
US7482054B2 (en) * | 2004-08-09 | 2009-01-27 | Behr Process Corporation | Pigment spacing |
PT1688129E (en) | 2005-02-02 | 2015-11-04 | Omega Pharma Innovation & Dev Nv | New therapeutic formulation |
WO2007048142A2 (en) * | 2005-10-21 | 2007-04-26 | Altairnano, Inc. | Lithium ion batteries |
US9365460B2 (en) * | 2006-11-09 | 2016-06-14 | Akzo Nobel N.V. | Pigment dispersion |
US7972691B2 (en) * | 2006-12-22 | 2011-07-05 | Nanogram Corporation | Composites of polymers and metal/metalloid oxide nanoparticles and methods for forming these composites |
DE102006062641A1 (en) * | 2006-12-28 | 2008-07-03 | Ltn Nanovation Ag | Producing a dispersion of nanoparticles useful for producing coatings and as a binder comprises introducing primary nanoparticles into a dispersion medium containing a neutral or basic polymer |
US8119233B2 (en) * | 2007-02-17 | 2012-02-21 | Nanogram Corporation | Functional composites, functional inks and applications thereof |
WO2008121660A2 (en) * | 2007-03-30 | 2008-10-09 | Altairnano, Inc. | Method for preparing a lithium ion cell |
US8357426B2 (en) * | 2008-01-11 | 2013-01-22 | Nanomateriales S.A. De C.V. | Single step milling and surface coating process for preparing stable nanodispersions |
EP2351803B1 (en) * | 2008-11-25 | 2018-12-12 | Toppan Printing Co., Ltd. | Coating liquid and gas barrier laminate |
JP5688032B2 (en) | 2009-01-08 | 2015-03-25 | ナノグラム・コーポレイションNanoGram Corporation | Composite of polysiloxane polyester and inorganic nanoparticles |
JP5526690B2 (en) * | 2009-10-06 | 2014-06-18 | 堺化学工業株式会社 | Dispersion containing zinc oxide or titanium oxide |
CN101757662B (en) * | 2010-01-14 | 2013-04-24 | 广州三瑞环保科技有限公司 | Nano TiO2 emulsion, synthesis method thereof and use thereof |
FI20115968A0 (en) | 2011-10-03 | 2011-10-03 | Oy Granula Ab Ltd | ANHYDROUS SUSPENSIONS, ANTIMICROBIC GELS AND THEIR APPLICATIONS |
US9139737B1 (en) | 2011-11-21 | 2015-09-22 | Nanophase Technologies Corporation | Multifunctional coated powders and high solids dispersions |
WO2014141992A1 (en) * | 2013-03-15 | 2014-09-18 | 株式会社ダイセル | Titanium oxide liquid dispersion, titanium oxide liquid coating, and photocatalyst coating film |
JP2015193595A (en) * | 2014-03-25 | 2015-11-05 | 東洋インキScホールディングス株式会社 | Aqueous dispersion composition for sunscreen |
CN111498897B (en) * | 2015-02-27 | 2022-07-12 | 堺化学工业株式会社 | Method for producing dispersion of titanium oxide particles |
US10555892B1 (en) | 2017-03-09 | 2020-02-11 | Nanophase Technologies Corporation | Functionalized siloxane or polysiloxane coated particles with enhanced light filtering properties |
US10590278B2 (en) | 2017-04-10 | 2020-03-17 | Nanophase Technologies Corporation | Coated powders having high photostability |
JP2022100722A (en) * | 2020-12-24 | 2022-07-06 | 株式会社Screenホールディングス | Zinc oxide dispersion, titanium oxide dispersion, and cosmetic composition |
CN115449348B (en) * | 2022-10-12 | 2023-06-27 | 江西广源化工有限责任公司 | Grinding aid and preparation method and application thereof |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA780512A (en) * | 1968-03-12 | R. Kane Joseph | Aqueous titanium dioxide suspensions | |
GB1017475A (en) * | 1963-11-28 | 1966-01-19 | British Titan Products | Aqueous titanium dioxide suspensions |
FR1533007A (en) * | 1966-08-01 | 1968-07-12 | Kao Corp | Method of dispersing fine powders |
US3579310A (en) * | 1967-06-28 | 1971-05-18 | Du Pont | Preparation of acicular rutile tio2 |
DE1902175A1 (en) * | 1969-01-17 | 1970-07-30 | Bayer Ag | Process for the production of high molecular weight, linear polyesters |
US3728443A (en) * | 1971-09-14 | 1973-04-17 | Du Pont | PRODUCTION OF HIGH ASPECT RATIO ACICULAR RUTLE TiO{11 |
US3923968A (en) * | 1971-10-18 | 1975-12-02 | Dow Chemical Co | Method of preparing titanium dioxide pigment |
GB1387281A (en) * | 1972-01-11 | 1975-03-12 | C A Lab Inc | Ultra-violet light absorber compositions |
JPS49450A (en) * | 1972-04-17 | 1974-01-05 | ||
LU71867A1 (en) * | 1975-02-17 | 1977-01-05 | ||
FR2311823A1 (en) * | 1975-05-23 | 1976-12-17 | Du Pont | PIGMENT TIO2 COATED WITH DENSE SILICA AND ALUMINA / POROUS SILICA |
GB1479988A (en) * | 1975-07-17 | 1977-07-13 | Tioxide Group Ltd | Treatment of pigment |
JPS5272833A (en) * | 1975-12-13 | 1977-06-17 | Rando Engineering Kk | Body paint compound |
US4177081A (en) * | 1976-12-22 | 1979-12-04 | E. I. Dupont De Nemours And Company | Titanium dioxide pigment slurries to impart high gloss to water-based acrylic paint systems |
CA1087775A (en) * | 1976-12-22 | 1980-10-14 | Raymond L. Decolibus | Titanium dioxide pigment slurries to impart high gloss to water-based paint systems |
JPS5842167B2 (en) * | 1977-04-01 | 1983-09-17 | 株式会社資生堂 | skin cosmetics |
JPS6010720B2 (en) * | 1977-11-18 | 1985-03-19 | 武田薬品工業株式会社 | Production method of antibiotic C-15003 P-4 |
JPS55154317A (en) * | 1979-05-18 | 1980-12-01 | Ishihara Sangyo Kaisha Ltd | Manufacture of fine titanium dioxide composition powder |
JPS5767681A (en) * | 1980-10-14 | 1982-04-24 | Ishihara Sangyo Kaisha Ltd | Ultraviolet absorber |
DE3123732A1 (en) * | 1981-06-15 | 1982-12-30 | Basf Ag, 6700 Ludwigshafen | MEASURING AGENTS AND DISPERSING AGENTS FOR PIGMENTS |
ZA825176B (en) * | 1981-08-31 | 1983-09-28 | New Jersey Zinc Co | Titanium dioxide pigment having improved photostability and process for producing same |
JPS5862106A (en) * | 1981-10-09 | 1983-04-13 | Shiseido Co Ltd | Cosmetic |
JPS5915885B2 (en) * | 1982-08-20 | 1984-04-12 | 株式会社資生堂 | skin cosmetics |
JPS5962517A (en) * | 1982-10-04 | 1984-04-10 | Shiseido Co Ltd | Anti-suntan cosmetic |
JPS5998009A (en) * | 1982-11-29 | 1984-06-06 | Kanebo Ltd | Skin cosmetic |
JPS59172415A (en) * | 1983-03-18 | 1984-09-29 | Pola Chem Ind Inc | Anti-suntan agent |
JPS59223231A (en) * | 1983-05-31 | 1984-12-15 | Teikoku Kako Kk | Manufacture of fine-grained rutile type titanium oxide |
JPS60186418A (en) * | 1984-03-06 | 1985-09-21 | Hiroyoshi Inoue | Production of ultrafine particle of titanium oxide |
JPS6197133A (en) * | 1984-10-19 | 1986-05-15 | Mitsubishi Metal Corp | Composite granular titanium dioxide |
DE3688768T2 (en) * | 1985-03-05 | 1993-11-11 | Idemitsu Kosan Co | Process for the production of very fine spherical metal oxide particles. |
JPS61215216A (en) * | 1985-03-19 | 1986-09-25 | Teikoku Kako Kk | Hydrophobic spherical particle of titanium oxide |
GB8712752D0 (en) * | 1987-05-30 | 1987-07-01 | Tioxide Group Plc | Particulate material |
-
1988
- 1988-12-16 GB GB888829402A patent/GB8829402D0/en active Pending
-
1989
- 1989-11-24 GB GB8926575A patent/GB2226018B/en not_active Expired - Lifetime
- 1989-11-28 AU AU45640/89A patent/AU620473B2/en not_active Expired
- 1989-11-29 CA CA002004112A patent/CA2004112C/en not_active Expired - Lifetime
- 1989-12-01 US US07/444,811 patent/US5068056A/en not_active Expired - Lifetime
- 1989-12-06 ZA ZA899319A patent/ZA899319B/en unknown
- 1989-12-07 NL NL8903014A patent/NL8903014A/en active Search and Examination
- 1989-12-13 IT IT04865789A patent/IT1238010B/en active IP Right Grant
- 1989-12-15 JP JP1325734A patent/JP2781433B2/en not_active Expired - Lifetime
- 1989-12-15 DE DE3941543A patent/DE3941543B4/en not_active Expired - Lifetime
- 1989-12-15 ES ES8904229A patent/ES2029152A6/en not_active Expired - Fee Related
- 1989-12-15 FR FR8916667A patent/FR2640635B1/en not_active Expired - Lifetime
- 1989-12-15 BE BE8901340A patent/BE1004166A5/en not_active IP Right Cessation
- 1989-12-16 MY MYPI89001793A patent/MY105755A/en unknown
Also Published As
Publication number | Publication date |
---|---|
ZA899319B (en) | 1990-09-26 |
CA2004112C (en) | 1995-08-08 |
FR2640635B1 (en) | 1994-08-26 |
GB8829402D0 (en) | 1989-02-01 |
ES2029152A6 (en) | 1992-07-16 |
IT8948657A1 (en) | 1991-06-13 |
DE3941543B4 (en) | 2005-11-03 |
US5068056A (en) | 1991-11-26 |
JP2781433B2 (en) | 1998-07-30 |
AU620473B2 (en) | 1992-02-20 |
AU4564089A (en) | 1990-06-21 |
MY105755A (en) | 1995-01-30 |
GB2226018B (en) | 1992-08-05 |
BE1004166A5 (en) | 1992-10-06 |
IT8948657A0 (en) | 1989-12-13 |
IT1238010B (en) | 1993-06-21 |
NL8903014A (en) | 1990-07-16 |
GB8926575D0 (en) | 1990-01-17 |
JPH02212315A (en) | 1990-08-23 |
GB2226018A (en) | 1990-06-20 |
DE3941543A1 (en) | 1990-06-28 |
FR2640635A1 (en) | 1990-06-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed | ||
MKEC | Expiry (correction) |
Effective date: 20121202 |