CA1336924C - Solar aquatic method and apparatus for treating waste - Google Patents
Solar aquatic method and apparatus for treating wasteInfo
- Publication number
- CA1336924C CA1336924C CA 614367 CA614367A CA1336924C CA 1336924 C CA1336924 C CA 1336924C CA 614367 CA614367 CA 614367 CA 614367 A CA614367 A CA 614367A CA 1336924 C CA1336924 C CA 1336924C
- Authority
- CA
- Canada
- Prior art keywords
- water
- tanks
- tank
- pollutants
- series
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
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- 241000157856 Cephalanthus Species 0.000 description 1
- QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical class ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 1
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- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
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- -1 polytetrafluoroethylene Polymers 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
- C02F3/1205—Particular type of activated sludge processes
- C02F3/1215—Combinations of activated sludge treatment with precipitation, flocculation, coagulation and separation of phosphates
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
- C02F3/327—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae characterised by animals and plants
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/33—Wastewater or sewage treatment systems using renewable energies using wind energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Abstract
A method and apparatus useful for removing pollutants from wastewater is described. Wastewater is directed through electromagnetic energy transmitting treatment tanks containing microorganisms, situated so that electromagnetic energy may be transmitted throughout substantially all of the wastewater therein. The wastewater then flows through a second series of energy transmitting treatment tanks stocked with non-aquatic plants supported so that the plant roots extend into the wastewater flowing through the tanks. Next the wastewater flows through marsh plants and through a third set of energy transmitting treatment tanks. The second and third series-of treatment tanks contain higher animal species. The biological activity of the bacteria, plants and animals purifies the wastewater in conjunction with the energy transmitted into the waster water substantially throughout its entire volume.
Description
13~ G92~
, I
SOLAR AQUATIC METHOD AND APPARATUS FOR TREATING WASTE
This invention relates in general to treating waste, and in specific to a method and apparatus for removing pollutants from various types of wastewater, using biologically active organisms and without using chemicals and without producing large quantities of sludge containing pollutants.
Background of the Invention Urban and industrial communities face the serious problem of how to safely dispose pollutants. The pollutants are often deposited in wastewater, which is of several forms. It may be septage, or sewage.
Septage consists of the contents of residential and industrial septic treatment tanks. The major constituent of residential septage is solid human waste. ~uman waste often carries with it human pathogens, which are microorganisms that cause illness or otherwise stre~s humans. Human waste include~
biodegradable organic matter either dissolved or suspended, which are quantified by a factor known as the biochemical oxygen demand ("BOD"). BOD is a measure of the degree to which constituents in wastewater will take up free oxygen (2) The oxygen absorbing constituents are largely decomposing organic matter in a decomposinq state. Biological methods of wastewater treatment (discussed below) depend on the presence of sufficient quantities of free oxygen in the water. Typically, biological waste treatment is conducted in part by oxygen breathing bacteria.
Thus, a high BOD indicates that the waste in the water is monopolizing all of the available oxygen and "suffocating" any oxygen breathing bacteria that may be present. Septage may also include carbonaceous organic compounds (dissolved and suspended) and nitrogen, phosphorus and potassium, referred to as "nutrients"
because they are necessary for the metabolism of organisms, including both microscopic and macroscopic, of the 5 living kingdoms of (plants, animals, fungi, protoctists and monera (bacteria)). Septage also includes paints, oils, cleaning fluids, heavy metals, and other toxins such as "PCBs" (polychlorinated biphenols), "teflon" (polytetrafluoroethylene) etc. A toxin is generally defined as a poison.
The wastewater may also be sewage, which has a much higher liquid content than septage, but which may contain the same types of pollutants mentioned above. Typically, septage is 30-100 times more concentrated than sewage. Typically, sewage has a BOD less than 700 and septage has a BOD of greater than 800.
Typically, sewage enters the municipal sewage system from the user's facility hookup, or through storm drains, and then proceeds to a sewage treatment center, where various treatment methods are applied. Septage, conversely, is collected by tanker trucks as part of regular maintenance when an individual septage tank needs servicing, for example, the 3eptic system becomes clogged or de ~ ~ f k 133692~
otherwise unusable so t~at pumping is required. The septaqe trucks ~ransport the septage to a waste facility and deposit the septaqe there for treatment.
The principal mode of conventional treatment involves separating out harmful substances from the water in various stages. Particulates are separated using mechanical processes, including filtration, centrifuging and settling. The concentrated particulates are then disposed of in a solid waste landfill.
~owever, these particulates still include the harmful pollutants and landfill must be considered to be and treated as a hazardous waste site. Additional pollutants dissolved in the water are maintained in coarse suspension or are precipitated from the water by combination with chemicals that reduce their solubility. These additional particulates are then removed as were those in the earlier stages. Finally, pathogens, harmful organisms in thQ
wa~eF, ar~ kllled ~y chlo~ine o~ oth~ chemicals and al~o by exposure to ultraviolet light.
The foregoing conventional processes have many drawbacks.
The mechanical processes require machinery to move large quantities of water against a pressure gradient and are thu~
capital intensive. Further, construction and operational costs are extremely'high. Large amounts of energy must be applied to the system to effect the filtration and the segregation of the solid particulates from the water. Finally, and most ~33~24 distressinqly, in most cases the pollutants are not changed in ~heir basic form, and remain harmfu~ substances. Although they are buried in landfills, they may eventually harm the environment, ~ith the washing of rains and passage of ground water, they return to the hydrological system.
Known systems attempt to minimize the use of chemicals and emphasize the use of biological systems to remove pollutants from sewage. To date, no biological system successfully treats septage. One system passes polluted sewage water through beds of certain living plants to remove certain pollutants. Prior to treatment with the plants, the water is separated from emulsible components, such as oil or tar, which components float in a layer above the water. Coarse suspended matter settles to a sludge layer at the bottom of a settling treatment tank. A two stage living plant filtration system is typical. In the first stage, a plant such as Phraqmites communis, which has roots extending from nodes, is rooted in a two layer sand bed. The root structure maintains open passageways through the sand so that the water can flow through freely. The upper layer is composed of fine sand, as compared to the lower layer. Slime and other suspended matters which are too coarse to pass through the fine sand filtration bed collect on top. After a suitable amount of slime has collected, the treatment tank is drained and dried out. The slime concentrates into a thin layer which cracks and curls up and is physically removed.
Water leaving the filtration bed contains dissolved material and pathogenic organisms. In the second stage, the water passes through a second bed of sand, in which is rooted a plant such as Scirpus lacustris. This plant removes organic compounds and inorganic ions and bacteria from the water. If necessary, additional stages using other plants that remove organic compounds, ions and bacteria not removed by Scirpus lacustris may be applied.
It is known that certain plants effectively remove particular dissolved pollutants from sewage. Scirpus lacustris (mentioned above) and ~ypha angustifolia remove organic aromatic compounds and pathogenic organisms, including E. coli, Salmonella, acid-fast bacteria, Ascarides and Oxyuris. They also effectively remove chemical anions, phosphates, nitrates, sulfates and chlorides.
It is also known that the roots of several species of tall growing bulrushes are effective for removing halogenated phenols such as pentachlorphenol from sewage. In harsh environments, plants must be protected by using a hot house type system. Water laden with pathogens can be purified with vegetation having certain bacterial root nodules. Bacteria live in the nodule.
Many types of bacteria produce an antibiotic, which in nature protects those bacteria from other strains of bacteria by killing 1 3 3 6 9 2 ~
them. These bacteria can be used in a wastewater treatment system to kill bacteria that are harmful to humans and animals. Known systems cover the surface of the containment vessel with opaque material to prevent access of light to the water, which light makes possible the growth of algae.
This known method has many drawbacks. Principally, it produces large quantities of sludge which must be disposed of.
~dditionally, the slime can only be removed if the filtration bed is allowed to dry out. Thus, redundant e~uipment must be available to process the water while the bed is drying out.
Further, removing the dried slime is a tedious and labor intensive process and also results in slime, which must be disposed.
Additional known systems for treating sewage (but not septage) use biological methods of wastewater treatment including wetland systems; aquatic plant processes; and combined aqua culture systems.
Wetland methods for sewage treatment use marshes, either natural marshes or man-made marshes. The use of natural marshes must be monitored very carefully so as not to pollute the natural environment. Wetland systems have been used successfully in pilot operations to reduce BOD, suspended solids ("SS"), trace organic compounds and trace heavy metals. However, problems with insects, such as mosquitoes, are prevalent. Further, wetland systems take up huge amounts of surface area. Further, as they mature, they 13369~
become less effective. Eventually, .hey ~ecomD so inefficient that they cannot be used.
Also known for treating sewage are aquati- piant systems where free floating aquatic plants (known as "~acrophytes") are used for the treatment or refinement (sometimes referred to as "polishing") of wastewater. Water hyacinth systems may reduce BOD, SS, metals, nitrogen and refractory trace organics. Water hyacinths, however, cannot remove phosphorous in high degrees. An active mass of organisms lives in the root system of the water hyacinths. These organisms play the major role in the chemical breakup of the pollutants. In order to maintain the system, the water hyacinths must be harvested and removed. The amount of plant biomass produced in a water hyacinth pon~ system is about four times the quantity of waste sludge produced in conventional activated sludge secondary wastewater treatment. This plant mass must be disposed of. Disposal of the plant macs is a problem, as the plant mass will probably have incorporated the pollutants within its structure and may constitute a haza~dous waste.
Further, the mosquito control is very difficult with water hyacinth systems. Mosquito eating fish must be used.
The use of duckweed rather than or in addition to water hyacinth has been suggested for treating sewage, however, very little data is presented.
1336~24 Combined aqua culture systems have also been proposed for treating sewage. An aqua-culture system is defined as one ~Aat produces a useful biomass from a controlled aquatic media.
Examples of a useful biomass are plants that are consumable by either humans or animals. These systems, however, are unacceptably labor intensive.
A method of treating wastewater from citrus processing factories has been proposed which includes introducing the wastewater into a pool containing an absorbent material such as peat moss or shredded paper and a large quantity of earth worms.
The peat moss or shredded paper absorbs the pollutants from the liquid and the worms consume the paper or peat moss.
Additionally, downstream, fish that feed on the lower end of the food chain (i.e., smaller animals such as plankton), such as ~ilapia, are introduced. This method may not be used to treat wastewater containing petroleum oils and/or industrial chemicals, which would destroy the worms.
An aquatic pond stocked with a large number of organisms, such as fish, snails, worms, turtles, pollywogs, bacteria, microorganisms, algae, water lilies and other vegetation has been proposed to further reduce by 80-95% the BOD already reduced by other processes. A method of protecting the aquatic pond against ruin caused by a waste overload from the sewage plant has been proposed. It provides a haven where a seed colony of the aquatic 13369~4 life necessary to re-populate the pond will also (and always) be presen~ due to the constant addition of oxygen saturated water.
Another sewage treatment system has been proposed that includes a stage where solids are decomposed by the action of unspecified anaerobic bacteria, which hydrolyze and ferment complex organic compounds to simple organic acids. An additional stage is provided where the wastewater is treated with activated carbon and a mixed microbial population, which removes organic matter, organic nitrogen, ammonia (NH3) and nitrogen in the forms of nitrate (NO3) and nitrite (NO2) from the processed wastewater.
~owever, chemicals must be used to remove phosphates and a chemical coagulant and additional chemicals such as hypochlorite are added. Ozone (03) is also added to the wastewater, which may result in chlorinated compounds, a potential health hazard.
Another sewage treatment system has been proposed using a combination of natural ecological processes, including: an aerated lagoon; submerged, high surface area, activated bio-web substrates providing a fixed bacterial film; floating a~uatic plants for nutrient (pollutant) removal; a polyculture of micro-invertebrates, fish, and shell fish in a balanced food chain for removal of nutrients and organics from the wastewater and concentration into a biomass. A solar heated greenhouse-type cover is disclosed to prevent the system from damage due to cold.
Drawbacks of this system are that management is time consuming; it ~ 133~2~
is difficult to maintain physical segregation between oxygenated and unoxygenated zcnes.
It has been disclosed that certain bacteria plasmids (small molecules of DNA) enable bacteria to degrade obnoxious halogenated organic wastes, such as chlorinated aromatic compounds.
A process for the purification of polluted water has been proposed including applying aquatic plants to the water. The method is particularly directed towards non-punctiform pollutants, such as fertilizers. The system has four different types of plant zones: a swamp 20ne, a marsh zone, a reed zone, and a quaking bog.
This system suffers from seasonal fluctuations in functionality;
senescence: excessive cleaning requirements and bad effects on qround water.
It has also been proposed to purify sewage using an expanded bed reactor containing film upon which grow methane producing anaerobic bacteria. This system must be shielded from light, because the bacteria cannot tolerate light.
All of the foreqoing methods suffer from certain drawbacks, as have been discussed.
Brief Description of the Invention.
The invention relates to both a method and an apparatus for treating wastewater, including sewage and septage, by removing unwanted substances therefrom. Both the method and the apparatus use biological cleansing elements. The invention is particularly 133692~
effectlve in lts capacity to treat septage, a very concentrated form of waste contalnlng fluid.
In one aspect, the lnventlon provldes an apparatus for removlng pollutants from water comprlslngs A) a serles of tanks containlng water whlch lncludes organlsms for removlng pollutants from the water, whereln each of sald tanks comprlses a bottom and llght-transmlttlng sldes and transmlts energy lnto the water substantlally throughout lts entlre volume; B) means for connecting said tanks in series such that water can be transferred along sald serles of tanks from a flrst tank to a last tank; C) means for lnputtlng water contalnlng pollutants to the flrst tank; and D) means for outputtlng water from which said pollutants have been removed from the last tank; wherein series of tanks further comprises: a) a first tank or plurallty of tanks containing polluted water and bacteria for removing at least some of the pollutants from the water; b) a second tank or plurallty of tanks connected ln serles with sald flrst tank or plurality of tanks contalnlng non-aquatlc plants capable of removing at least some of the pollutants from the water, and a support for malntaining the non-aquatic plants at the surface of the water; and c) a thlrd tank or plurallty of tanks connected ln serles wlth said second tank or plurallty of tanks contalnlng polluted water and fish capable of removlng at least some of the pollutants from the water.
In another aspect, the lnventlon provldes a method for treating water comprlslng: A) connectlng a plurality of tanks each capable of holding water in series such that water can be B~ ~
, =
.
1~692~ 66956-24 transferred along sald serles of tanks from a first tank to a last tank, wherein each of said tanks comprlses a bottom and light-transmitting sldes so that energy may be transmltted to substantlally the entlre volume of water contalned thereln; B) stocking said tanks with water and organisms for removing pollu-tants from the water; C) inputting water containing pollutants to the first tank7 D) outputtlng water from which at least some of said pollutants have been removed from the last tank; wherein the method lncludes the steps of: a) stocklng a flrst tank or 1~ plurality of tanks contalnlng polluted water wlth bacterla for removlng at least some of the pollutants from the water; b) stocking a second tank or plurallty of tanks connected in serles with sald flrst tank or plurality of tanks with non-aquatlc plants capable of removlng at least some of the pollutants from the water, and provlding a support for maintalning the non-aquatlc plants at the surface of the water; and c) stocking a thlrd tank or plurallty of tanks connected ln serles wlth sald second tank or plurallty of tanks wlth flsh capable of removlng at least some of the pollutants from the water.
The apparatus features, ln a preferred embodlment, a multistage course through whlch the wastewater wlll flow, the course comprlslng a flrst plurallty of energy transmlttlng treatment tanks sltuated so that electromagnetic energy, lncludlng light, may be transmltted throughout substantially all of the wastewater therein. A diverse plurallty of types of microorganlsms are provided ln the treatment tanks. The mlcro-organlsms lnclude bacterla, protoctlsts, fungl, plants and lla B
133~92~
anlmals. The course further includes a second plurallty of energy transmlttlng treatment tanks also sltuated so that electromagnetlc energy, lncluding light, may be transmitted throughout substantlally all of the wastewater therein, and is stocked with a diverse plurallty of non-a~uatic plants. The plants are supported on flxtures, so that the plant roots extend lnto the wastewater flowlng through the second plurallty of treatment tanks. The course also has a marsh in whlch grow a plurallty of varietles of marsh plants and a third plurallty of energy transmittlng treatment tanks ls provlded, also sltuated so that electromagnetlc energy, lncluding light, may be transmltted throughout substantlally all of the wastewater therein. A plurallty of specles of hlgher anlmals, including zooplankton, phytoplankton (algae) flsh and mollusks such as snails and fresh water clams are llb B~
provided in the second and third pluralities of tanks. In relatively cold climates, a greenhouse must be provided to maintain the system warm enough during the winter for the plants and animals to grow. The wastewater is caused to flow through all of the pluralities of treatment tanks and through the marsh. The biological activity of the species of bacteria, plants and animals purifies the wastewater.
An important aspect of the apparatus is that the treatment tanks transmit energy into the wastewater substantially throughout its entire volume. The treatment tanks may transmit energy through their outer walls, preferably 100% around their perimeter and over their full height. The energy is predominantly in the wavelengths of light, both visible and non-visible. A large surface area for energy transmission allows for a very active and populous photosynthetic microorganism population, both aerobic and anaerobic, from top to bottom of the treatment tanks and around their perimeter throughout the entire volume. The photosynthetic microorganisms occupy a substantial portion of the surface area of the treatment tanks. This arrangement has spawned communities of organisms which have not been seen before either in such quality or such quantities. Known biological sewage treatment systems have only used conventional, in-ground pools. Light is transmitted only through the upper surface of the water. In many -133~92~
known systems, in ~act, only minimal light s transmitted, due to shading by water plants.
The method of the invention comprises the steps of providinq the apparatus described above and initially stocking it with plants, animals and microorganism as described above. The microorganisms stocked in the first two pluralities of tanks include bacteria and algae. The microorganism populations must be restocked frequently to maintain high diversity of types.
~ he method also includes the step of agitating the wastewater contained in the treatment tanks, through aeration and other means, to prevent sludge from settling in the bottom of the treatment tanks and to keep particulates spread throughout the full volume of the treatment tank. This permits virtually all of the contaminants in the wastewater to be removed from the wastewater by the organisms living therein, rather than allowing the contaminants to settle to the bottom. Agitation through aeration also introduces oxygen (2) into the treatment tanks.
This replaces free oxygen taken up by decaying biodegradable organic compounds. Free oxygen is needed by aerobic bacteria, which metabolize and thus degrade many pollutants.
It is beneficial to maintain as diverse a population of types of bacteria and other microorganisms as is possible. Different pollutants serve as nutrients for different microorganisms.
Maintaining a large variety of types of microorganisms facilitates 133~924 the removal of a lar~e number of differen~ nutrients in dif~erent forms. Furth~r, it is beneficial to maintain various types of bacterla that are redundant with respect to their nutrient needs, and that vary with respect to their survivability in harsh environments (e.g. temperature, light, antibiotic variations) so that given any of a variety of environmental pressures, there will be present a type of bacteria that can withstand the environment and metabolize the nutrients. Variety in bacterial types is discussed in A New Bacteriology, by Sorin Sonea and Maurice Panisset, Jones & 3artlett Publishers, Inc. (1983), New York, published first in French in 1980 by Les Presses de l'Universite de Montreal.
It is also an aspect of the method of the invention to recycle a small but significant volume of the partially treated wastewater from various mid-stages of the flow course back to earlier stages, including the input. Recycling provides a means of automatically maintaining a higher level of diversity of microorganisms at the earlier stages, primarily the input, where conditions are harshest.
Finally, it is an aspect of the method of the invention to maintain in the first treatment tank the ratio, by weight, of the amount of carbon, in the form of calclum carbonate, to the amount of ammonia and dissolved nitrates, within a specified range. rt 13~9~
has been found that this ratio provides the appropriate amount of carbon for nutrition to the growing microorganisms.
Objects of the Invention Thus, several objects of the invention are to provide an apparatus and a method for treating wastewater by removing unwanted substances therefrom:
by using biologically active organisms;
without using chemicals that are harmful to the environment;
without producing large quantities of sludge that contain pollutants;
that effectively removes biodegradable organic contaminants;
that effectively removes paints, oils, cleaning fluids, ~heavy metais and other toxins;
that can be used to treat septage;
that can be used to treat sewage:
that requires a capital expenditure lower than conventional waste treatment systems:
that is easy and quick to construct:
that requires a relatively low operating budget as compared to conventional treatment systems;
that does not place harmful chemicals in the natural environment;
~ 1336924 that is flexible and responsive tO changes in the contents of the ~nwanted substances in the wastewater;
that requires relatively low amounts of energy to operate;
that can be added to conventional waste treatment systems as a retrofit module:
that can be used over a wide range of temperature and light conditions;
that can be used in developing countries;
that can be used in conjunction with a natural marsh wastewater treatment system;
that can purify sewage and septage to a degree that it may be returned to the natural water system; and that can treat sewage and septage without the formation of sludge or biomass, such as plants, fish, etc., that contain hazardous materials.
Other objects of the invention will be evident from consideration of the following description of preferred em~odiments and the figures of the drawing.
Figures of the Drawing Figure 1 is a schematic perspective view of the apparatus of the invention, showing the multiple stage flow course including a plurality of stages of treatment tanks, and an artificial marsh.
~ 133~92 1 Figure 2 is a schematic perspective view, with parts broken a-~ay, of a preferred embodiment o~ a tre~tment tank of the apparatus of the invention.
Figure 3 is a schematic cross-sectional view of an artificial marsh of the apparatus of the invention.
Figure 4 is a schematic plan view of several modules of the apparatus of the invention housed in a greenhouse.
Figure S is a schematic perspective view of a preferred embodiment of an oval treatment tank of the apparatus of the invention.
Figure 6 is a schematic perspective view of a preferred embodiment of a bottom lighted treatment tank of the apparatus of the invention.
Figure 7 is a schematic perspective view of a preferred embodiment of a treatment tank of the apparatus of the invention having a large surface area.
Figure 8 is a schematic perspective view of a preferred embodiment of a treatment tank of the apparatus of the invention having light chimneys.
Figure 9 is a schematic perspective view of a preferred embodiment of a treatment tank of the invention that is below ground and artificially lighted.
Figure 10 is a schematic perspecti~e ~iew of a preferred e~odiment of a treatmert tank of t~e apparatus of the inventi~n that has an internal light.
Figure 11 is a schematic perspective view of a preferred embodiment of an annular treatment tank of the apparatus of the invention that has an internal light.
Figure 12 is a schematic plan view showing an embodiment of the apparatus of the invention including a second marsh at the output end of the system.
Detailed Description of Preferred Embodiments of the Invention Referring to Figure 1, a schematic diagram of a perspective view of the apparatus of the invention is shown. A plurality of energy transmitting treatment tanks (1-20) form a flow course, sometimes referred to as "an artificial river", through which wastewater, for instance, septage, that bears pollutants passes.
For purposes of clarity, some of the components of individual treatment tanks 1-20 are omitted from Figure 1. The structure of an individual treatment tank, for instance tank 1, is discussed below with reference to Figure 2. The hookup of the treatment tanks to each other, and to the wastewater input and output is also discussed below. An artificial marsh 22 is placed approximately mid-way along the course of the artificial river of treatment tanks. Wastewater is provided to the system at input 24. Depending upon whether the wastewater ~s in the for~ of septage or sewage, the input may be either an underground holding tank or an open lagoon (in the case of septage) or may be any stage of a municipality's sewage treatment system, from the raw sewage to fully treated sewage. From input 24, the wastewater is introduced through pipe 26 to treatment tank 1. Treatment tank 1 is the first of a first plurality of treatment tanks all arranged so as to receive a high amount of electromaqnetic energy, including light.
Turning now to figure 2, the structure of a typical treatment tank in a preferred embodiment, treatment tank 1, will be reviewed. The treatment tank is a cylinder 30 approximately one and a half to two meters high and one and a half to two meters in diameter, which transmits electromagnetic energy, including light.
The wall thickness is approximately 1.1 mm (.045 in). The wastewater enters cylinder 30 through pipe 26. Wastewater leaves cylinder 30 through standpipe 32. Water is siphoned up standpipe 32 from the bottom of the treatment tank 30 and into the adjacent treatment tank (in this case treatment tank 2).
Alternatively, gravity feed can be used by having the upper extension of standpipe 32 remain below the water level of the tank in which it stands. For the embodiment shown, standpipe 32 is approximately S cm (2 in) in diameter.
l` 1336924 Air is provided below the water level 34 through pipe 36 and airstones 37a, 37b, which receive air that has been compressed by compressor 38 (fig. 1) through pipes 28 and 36. The number of airstones per treatment tank varies from treatment tank to treatment tank, dependin~ upon the oxygen needs of the biota in each particular treatment tank.
A floating support 40 is provided in each treatment tank.
(For clarity, supports 40 are not shown in figure 1. Plants 41 supported by such supports 40 are shown in treatment tanks 3, 8, 13 and 18. However, it should be understood that the floating supports 40 and the plants supported thereby (discussed below) are provided for each of the treatment tanks 1-20.) Supports 40 may be of styrofoam or of wooden lattices or any other structure that will physically support a mass of plants above the surface of the wastewater, while allowing the roots of the plants to pass through the support and into the wastewater. Further, the supports should be easily removable, in order to harvest the plants, or to service the mechanical components, or the wastewater in the treatment tank, or to move the plants to another location in the system, as discussed below. As shown in figure 2, a plurality of plant species 42, 44, 46 (shown schematically only) are supported by support 40. The roots 41 of the plants extend deep into the wastewater, substantially to the bottom of a treatment tank. (It will be understood that even in figure 2, the number of plants has been r~duced below a realistic amount, ln order ~o prevent the ~igure ~rom beco~ing overly cluttered.) Returning ncw to rigure 1, the plumbing among the ~re~tment tanks 1-10 will be explained. As has been mentioned, wastewater flows through standpipe 32 from treatment tank 1 into treatment tank 2 and similarly from tank 2 to tank 3, tank 3 to tank 4 all the way to treatment tank 10. Similarly, compressed air from compressor 38 is introduced into each treatment 'ank through pipe 28 and a respective line 36. Airstones 37a and 37b introduce the air into the treatment tank as a multitude of bubbles, and disperse the air generally throughout the water in the treatment tank. For the embodiment shown, with a daily septage influent BOD
of 1,000 mg/l and suspended solids of 200 mg/l, dissolved oxygen should be maintained at 5 mg/l or greater. 50 scfm transfers 56 pounds of dissolved oxygen per day into the wastewater.
At various stages of the artificial river, some wastewater is recycled. In the embodiment shown in figure 1, wastewater from the output pipe 33 is directed by pump and valve assembly 54 back through pipe 56 to input to treatment tank 1. Similarly, output from treatment tank 10 is directed by pump and valve assembly 58 through pipe 60 into treatment tank 5. Thus, through the combination of the recycling pipes 60 and 56, some wastewater from treatment tank 10, along with the small organisms living therein ~ 1336924 will be recycled all the back to treatment tank 1. Recycling from other locations to other locations is also possible.
In the embodiment shown in figure 1, the wastewater leaving treatment tank 10 next passes through an artificial marsh 22. For a system of the size shown in figure 1, the artificial marsh is constructed in a plywood frame 86 having a triangular cross-section approximately 1 meter wide at the top and approximately 1/2 meter deep at the bottom apex. The plywood 86 is lined with a plastic or suitable waterproof material 88 so that the environment is maintained in control. The length of the marsh is approximately 40 m. (116 ft.). The plywood frame is filled for its entire length with sand 64. The marsh is inclined so that the input, near line 62, is higher than the output at the opposite end. Various species of plants are provided in the marsh. The selection and function of the plants will be discussed below.
The marsh has an output 68, which is connected through pipe 70 to a T-valve 72 and pump 73. Through action of the pump 73 and T-valve 72, approximately 10% of the flow of partially treated wastewater is redirected through pipe 74 to the input of treatment tank 1. The remaining 90% travels through pipe 76 into the input of treatment tank 11. Treatment tanks 11-20 are connected to each other in the same manner as were treatment 133692~
t nks l-10, however, no feedback, such as through pi~es 60 and 5 ~s provided. Feedback may be provided but the benefits r~ceived are usually minimal, due to the lower levels of microbial activity downstream, due to the lower nutrient level of the partially treated water.
Treatment tank 20 is equipped with an air pump and fiberglass-type filter 80, to provide a pH buffer and additional denitrifying capacity. The output of treatment tank 20 is directed to a sand filled filter treatment tank 82, which additionally removes plankton and other suspended solids. After passage through the sand filter 82, the treated wastewater can be passed through an ultraviolet light chamber (not shown) for sterilization.
The method of treating wastewater using the basic apparatus described above is described below. Once the apparatus has been provided, each of the treatment tanks 1-20 is filled with clean water. The flow through treatment tanks 1-10 and 11-20 is initiated. Cuttings of the plants selected for growth in the plant supports 40 are inserted in the supports 40 and the supports 40 are placed in each of the respective treatment tanks 1-20. The selection of plants is discussed below. Marsh plants are also planted in the marsh with specific plants being placed in specific locations along the length of the marsh.
~ 1336924 Microorganisms and phytoplankton (algae) and small animals including zooplankton are seeded in treatment tanks 1-10.
Initially, each of the treatment tanks is seeded with an identical compliment of microorganisms. The treatment tanks are seeded with a wide diversity of bacteria including the following: Bacillus, Pseudomonas, Nitrobacter, Nitrosomonas, Cellulomonas, Aerobacter, and ~hodopseudomonas. In addition, microorganisms are ubiquitous and are supplied by the influent, on the roots of the plants added to the system, and from the atmosphere. Therefore, all of the types of microorganisms present cannot be identified. One such microorganism which has been identified is Anabaena.
In addition to the microorganisms, treatment tanks 11-20 are stocked with higher animals. All are stocked with several varieties of mollusks, including snails, including Lymnaeidae (right hand) and Planorbidae (ramshorn) and fresh water clams, including Unio and Ondonta. Plankton is int~oduced at treatment tanks 15 and 16 and move downstream with the effluent. Small-mouthed bass and river trout are stocked in treatment tanks 16, 17, 18 and 19 and Plecostomous (suckerfish) are also provided in treatment tank 19.
Turning now to the types of plants that are used, in general, the plants in the treatment tanks 1-20 and the marsh 22 should be young and at a stage of high growth, to maximize nutrient uptake.
In an experimental septage treatment system established at 133692~
~arwich, L~assachusetts, the f~llowing plants are used as indicated. Treatment tank 1 is provided with a large wi~low and water willows which are supported by plant supports 40, and water starwart. Treatment tank 2 is provided with a water willow plant and willow cuttings, again supported by a support. Treatment tank 3 has water hyacinths, a water plant which floats on the surface and does not re~uire a support. Treatment tank 4 is provided with the floating plant star duckweed. Treatment tank 5 is provided with willow cuttings which must be supported.
Treatment tank 6 is provided with buttonbush and water willow, both of which must be supported. Treatment tank 7 is provided with umbrella plants, tomato plants, nasturtium and eucalyptus, all of which are supported, and the floating plants pondweed and water starwart. Treatment tank 8 is provided with supported willow cuttings and floating water hyacinths. Treatment tank 9 is provided with floating water hyacinths and supported tomatoes, nasturtium and pokeweed. Treatment tank 10, just before the marsh, is provided with fragrant water lily and pickeral weed, both of which must be supported, along with water hyacinths.
After the marsh, treatment tank 11 is provided with supported tomatoes and nasturtiums. Treatment tank 12 is provided with floating duckweed. Treatment tanks 13 and 14 are provided with~
floating hyacinths and duckweed. Treatment tank 15 is provided with supported pickeral weed and fragrant water lily and floating 1~3692~
hyacinths. mreatment t~nK 16 is provided with tomatoes, nasturtium and wate~ hyaci~th. ~reatment tank 17 is provided w~th floating water hyacinths and tomatoes, nasturtium and eucalyptus.
Treatment tank 18 is provided with floating duckweed and supported pickeral weed. Treatment tank 19 is provided with supported nasturtium and eucalyptus. Treatment tank 20 is provided with floating Azolla. The roots of Azolla provide a habitat for the nitrogen fixing bacteria Anabaena. It will be understood that this list is illustrative only, with respect to both species and location. It is possible to place specific plants in different locations. It is also often beneficial to move the plants from place to place, as they grow and mature, and as the seasons change.
Turning now to the plants grown in the marsh 22, the plants include Scirpus lacustrus (bulrushes), Iris pseudacorus (yellowflag), Typha spp (cattails) and other plant species having nonbactericidal and antiviral action. As with the plants growing in the treatment tanks, these plants are illustrative only.
After the system has been stocked as described above, the flow from the input source 24 is begun at a flow rate of approximately 1,200 gals per day for the tank size described above. Each treatment tank holds approximately 600 gallons of wastewater. The wastewater remains in each treatment tank for approximately twelve hours, thus providing for an overall retention time through the twenty treatment tanks and the marsh of approximately ten days. If artificial lighting is used, as discussed below, the throughput can be increased. Natural sunlight, applied to septage retained in treatment tanks described above provides enough energy to treat 1,200 gallons per day, during the summer months at Harwich, MA, U.S.A.
As will be discussed in more detail below, a beneficial result is obtained from using treatment tanks of approximately two meters in diameter. Thus, the overall size of the treatment tank system using natural light and simple cylindrical treatment tanks, is limited to roughly the size of the system illustrated in figure 1. It is possible to extend the height and diameter of the treatment tanks slightly, increasing the capacity by perhaps a factor of two. ~owever, the system described in figure L is easily used in parallel with any number of identical systems, as shown schematically in Figure 4, thereby creating a system of any desired capacity. The system 84 shown in figure 1 having twenty treatment tanks should be considered to be a module of a specified cleaning capacity. Other configurations of treatment tanks are possible, as discussed below.
Before the wastewater has passed through the entire course of treatment tanks 1-20, it may be necessary to provide nutrients to the microorganisms and plants stocked in the downstream treatment tanks. Or, alternatively, the downstream treatment tanks can be 133692~
stocked at a r~spectively later time than the ~pstream treatmenc t~nks, tLmed to cGincide with the first arrivai of the partiall~y treated wastewater.
As has been mentioned, initially, all of the first ten treatment tanks are stocked with identical assortments of microorganisms. However, as the system achieves relative stability, certain types of microorganisms predominate at various stages along the treatment tank course and different types of microorganisms either die or decrease greatly in number.
In this context, the importance of the electromagnetic energy transmitting treatment tanks will be understood. The treatment tanks are of a thin, 1.1 mm (.0~5 in), fiberglass, which transmits a spectrum of electromagnetic energy, including all light energy except for ultraviolet light. The treatment tanks need not be of the thin material, so long as the treatment tanks transmit this spectrum of electromagnetic energy. The above-mentioned material is adequate and due to its thin-wall size, is relatively lightweight, inexpensive and easy to set up. Because the treatment tanks transmit electromagnetic energy, in particular li~ht, of various bandwidths, into the wastewater around the entire perimeter of the treatment tan~ and over its entire height, a high amount of electromagnetic energy i5 available for the use of photosynthetic and other microorganisms. This is so even in the case where leafy plants, such as water hyacinths, completely 133~924 cover the water surface of the treatment tank. In known septage and sewage systems, such hlgh degree of llght energY
has never been provlded, and has, in fact been discouraged due to the percelved disadvantage of hlgh algae growth.
As the system achieves equilibrium, the walls of the upstream treatment tanks (e.g. tanks 1-5) become covered with many different types of photosynthetic bacteria and micro-organisms, including various types of cyanobacterla, both purple and green. The coating of biota on the walls grows to a thickness of approximately 3 mm (.125 inches).
A by-product of photosynthesis is oxygen gas (2)~
whlch is used by aerobic microorganisms. Aerobic organlsms cannot take direct advantage of energy in the form of light to produce 2 Natural systems that have been evaluated to-date have not shown such a large quantlty and such a large variety of photosynthetic mlcroorganisms as exist in the treatment tanks operating in accordance with the invention. Thls is because most natural systems, such as ponds or streams, are designed to admit electromagnet energy in the form of light only through the surface, however, that surface is often covered with plants. In the treatment tank system of the present invention, the large quantity of admitted light is uni~ue. Thus, even micro-animals (as distingulshed from bacteria) wlth photosynthetic capacity have been observed.
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Photosynthetlc actlvlty results in the consumption of nutrients and the production of oxygen gas (2) As has been discussed above, raw septage has a characterlstlcally high BOD. A typical BOD for septage lnfluent ls greater than 1,000 mg/l (or 1,000 ppm). The photosynthetic bacteria, which produce ~2~ such as cyanobacterla, are anaeroblc and thus do not need oxygen to grow. The oxygen produced by the bacteria ls taken up by the organlc materlal ln the waste responsible for the hlgh BOD, thus reducing the BOD.
Various types of photosynthetlc mlcroorganlsms are capable of uslng different bandwidths of the electromagnetic energy spectrum for photosynthetic energy. Water attenuates the transmission of electromagnetic energy as a function of its wavelength. Shorter wavelength electromagnetic energy is dampened more quickly than that of longer wavelength. Thus, microorganisms that can only use the shorter wavelengths are more commonly found closer to the surface than are micro-organisms that can take advantage of longer wavelengths.
After transmission through one meter of water, all of the useful electromagnetic energy has been absorbed by the water.
Therefore, no photosynthetic activlty can occur more than approxlmately one meter from an energy admlttlng source.
Thus, ln the case of the treatment tanks of the present lnvention, virtually no photosynthetic activlty can take place more than one meter from a surface at which light 133692~
enters the wastewater. Thus, for a basic embodiment of the lnvention, the maxlmum dlameter of the treatment tank 30 for whlch photosynthetlc actlvity across the entlre width and depth of the treatment tank 30 can be expected is approxi-mately two meters. It is possible to increase the effective photosynthetic volume of a treatment tank by providing a long oval tank 130 having a minor axis of less than two meters (Figure 5). It is also possible to use treatment tanks 230 havlng a corrugated surface (Flgure 7) to increase the surface area and light transmlttlng capaclty, thereby lncreaslng the microbial diversity and thus the photosynthetic activity.
Alternatively, needle-like or comb-like pro~ections can radiate inward from the walls.
It is also possible to exploit artificial light and to provide a treatment tank 330 (Figure 10) of approximately 4.5 meters in diameter and providing an axially located artiflcial light source 110. The artificlal llght source 110 may be a submersible light. Alternatively, a concentric, translucent light transmitting chlmney 434 (Figure 11) may be provlded in the center of a treatment tank 430 into which can be hung a conventional light source 410. In this manner, an annulus two meters thick can be effectlvely used. Additional schemes of artificially illuminating tanks can be devised, such as llghtlng the bottom of the tanks 530 (Figure 6), or providlng a plurality of llght transmitting chlmneys 634 t~
(Flgure 8) inside a large pool 630 (Figure 8). If artlflcial llghts 710 are used it is not necessary that the treatment tankæ be situated above ground. They may be below ground, such as with conventional pools 730 and tanks (Flgure 9).
Further, if artificial llght is used, the system also operate at night, when natural light is unavailable.
The light absorbing property of water, coupled with various bacterla's narrow frequency band energy requlrements and anaerobic nature, limit the amount of photosynthetic actlvlty ln open surface, below water, unlighted tanks such as those conventionally found in previous "natural" treatment systems. Most photosynthetic anaerobic bacteria cannot tolerate oxygen. At the surface of a pool, oxygen content is sometimes high, due to mixlng caused by wlnd and waves. Thus, anaeroblc, photosynthetlc bacterla whlch requlre the shorter wavelength light cannot survive. These bacteria can survive, however, in abundance ln the treatment tanks of the present invention.
In addltion to the photosynthetic anaerobic and the aerobic schemes for energy productlon, a thlrd mechanlsm, which capitalizes on energy ln certain molecules exists.
Chemoautotrophy uses C02 and energy bound up in hydrogen sulfide (H2S), ammonia (NH3) and methane (CH4) gases. These organisms dominate in dark, oxygen poor regions where H2S, NH3 or CH4 are present. They cannot survive in highly lighted areas.
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Turnlng now to the plants supported at the surface of the treatment tanks, the prlnclple functlon of the plants ls to provlde a physical envlronment or substrate for the growth of the microorganlsms that wlll metabollze the pollu-tants. It is important that the upstream plants be of a type that wlll qulckly establlsh an extenslve and sturdy root structure, extending deep lnto the wastewater, substantlally all the way to the bottom of the treatment tank. As the wastewater in the treatment tank ls stlrred-up, by the aera-tlon dellvered through plpe 36, as a result of the suctlon of wastewater from the bottom of the treatment tank up through standplpe 32, and by flsh foraglng ln treatment tanks 15-~0, solld partlculates wlll be dlspersed unlformly throughout the treatment tank and eventually wlll become trapped ln the root system of the plants. In the root systems tiny local envlron-ments will arlse. Some wlll be aeroblc, where oxygen bubbles from the aeration are trapped. Others wlll be anaerobic where no oxygen is present. Others wlll be comblnatlons thereof with lower levels of oxygen.
In the ~lrst few treatment tanks, lt ls believed that purple cyanobacterla break down toxins, such as phenols, benzenes, chloramines, pesticides and herblcldes.
Rhodopseudomonas, an anaeroblc bacterla, uses light energy to oxidlze organlc compounds. The fermentatlon products provlde nutrlents for other bacterla. Durlng thls flrst stage also, heterotrophlc bacterla (those bacterla whlch metabollze 6~956-24 J
133692~
organlc material) Baclllus and Pseudomonas, remove soluble compounds. Bacillus oxldlzes a varlety of carbohydrates, organic acids, fats, oils, proteins and starches. These two bacteria recelve oxygen from the metabolism of the substances mentioned above, and thus, the aeration and oxygen production of the photosynthetlc and aeroblc bacterla is very important.
Soluble organlc chemicals are removed according to the bio-chemical e~uation 2 CH3COOH + 202 becomes 2CO2 + 2H2O.
Baclllus also secretes enzymes, known as exoenzymes, whlch degrade proteins, fat and starch into smaller molecular units that can be metabolized by other bacterla downstream. During low oxygen conditions, Pseudomonas also reduce nitrate and nitrogen levels. In addition, Aerobacter ferments carbo-hydrates to produce short chain organic compounds, carbon dioxide (CO2) and water (H2O). The short chaln organic compounds provlde carbon and energy for Pseudomonas.
The overall environment in the first five treatment tanks is predominantly anaerobic. For septage, the initial BOD is greater than 1,000 mg/l. Suspended solids, which are made up largely of biodegradable and nonblodegradable organic compounds, are normally present ln the lnput septage at greater than about 500 mgtl.
Durlng the flrst stage (treatment tanks 1-5), the prlmary ob~ective ls to reduce the BOD and suspended sollds.
Therefore, photosynthetic anaerobic bacterla thrive.
Addltlonally, the type of plants desired at the beginning of the waste stream are hardy, i.e. able to withstand toxins, which have a well-established or quickly establishing root system to provide a substrate for the growth of the anaerobic microorganisms. The septage should remain in the anaerobic stage for at least one day for the embodiment under discussion.
The second stage of treatment generally occurs in treatment tanks 6-10 and takes place during the third and fourth days for a treatment center of the size and flow rate described above and illustrated in figure l. This stage is characterized by higher dissolved oxygen levels than in the first stage i.e. it is predominately aercbic. In this stage, additional ammonia is removed by the two hacteria, Nitrosomonas and Nitrobacter.
Nitrosomonas oxidizes ammonia to nitrite. Nitrobacter oxidizes the nitrites to nitrates. The overall formula from ammonia to nitrate is according to the chemical formula 2~H3 + 402 become 2NO3- + 2H20+ 2H+. Ammonia, nitrates and soluble orthophosphates are also directly removed from the water by green algae and bacteria growing on the roots of plants.
During the phase of treatment from treatment tanks 6-10, typical BOD levels are reduced to 50-150 mg/l and suspended solids are reduced to approximately 100 mg/l. Also during this stage, snails survive and significantly reduce the sludge volume by eating the sludge and converting some of it into energy, some into tissue and some of it into waste. The treated septage should remain in the aerobic phase for at least one day for the embodiment under discussion.
Turning to Figure 1, approximately 2.5% - 20% of the flow from treatment tank 5, at valve 54, is recycled through pipe 56 to treatment tank 1. This recycling replenishes the microbial community in treatment tank 1, which may have been depleted due to its harsh anaerobic conditions.
The end of the second group of treatment tanks 6-10 is characterized by predominately aerobic activity. In this environment, Aerobacter oxidize~ carbohydrates and short chain organic acids to carbon dioxide (CO2) and water (H2O).
Cellulomonas converts cellulose to soluble carbohydrates which it then uses for growth as a cell constituent and energy source.
Other bacteria also use the produced carbohydrates.
Higher plants in the aerobic stage, treatment tanks 6-10, take up pollutants as nutrients.~ Certain higher plants (including Phragmites) take up nitrates preferentially, if certain other nutrients, such as potassium and soluble orthophosphate are present in the correct ratio. The nitrates are taken up directly and incorporated into the tissue of the plants. At this stage, faster growing plants that can rapidly remove nutrients are used.
The root systems of these plants also reach deep into the treatment tanks and support a large population of grazing animals, 13~692~
particularly snails. Snails also eat and remove suspended solids in this manner. Phosphorus is also removed during this phase, being directly taken up by the plants and animals, being converted into tissue. By treatment tank 10, ammonia (NH3) has been reduced to approximately 4 mg/l.
Turning now to the operation of the marsh, the marsh 22 is used primarily to kill unwanted bacteria and viruses and to remove heavy metals and certain toxic organic compounds. Profusely rooted plants, such as Phragmites communis are used to provide passage ways through the sand for the passage of water. As has been mentioned above, Scirpus lacustrus (bulrushes), Iris pseudacorus (yellow flag) and Typha spp (cattails) create an environment that is hostile to bacteria and also to certain viruses. Certain plants, particularly Alnus glutinosa, have nodules, known as rhizomes, along their roots. These rhizomes are the home of the bacteria Rhizobium, which fixes nitrogen (i.e., removes N directly from N2 molecules in the air) and also produce an antibiotic, which kills certain other bacteria. Rhizobium are also found in many leguminous plants.
These marsh plants 90 (Fig. 3) are also capable of preferentially taking up into their tissue certain metals and also toxic organic compounds. Absorption of heavy metals into fast growing plants does not present a waste disposal problem, because the plants grow so fast that the metals do not concentrate at a 133~92~
dangerous level. U.S. Patent No. 3,770,623, to Seldel, identifies many different useful plants and thelr functions.
In addition, the plants transfer oxygen gas (2) from their leaves g2 to the root system g4. This activity provides additional aeratlon used by microorganisms remaining ln the system that break down organlc compounds. Denitrifi-catlon, i.e., the reduction of nltrates (N03) to free Nitrogen (N2) and water, continues in the marsh through the mechanism of metabolism. The environment of the marsh varies by virtue of depth. ~ertain parts 96 are aerobic and deeper zones 98 are anaeroblc. At these stages, nitrates (N03) are converted into nitrogen gas (N2) by actlon of bacteria.
If heavy metals present a significant problem, special marsh plants known as "hypoaccumulators" should be provided. Hypoaccumulators selectively accumulate specific metals in a concentration high enough so that the metals may be smelted from or refined from the plants according to known methods. Examples of hypoaccumulators are umbrella plant and some species of willow plants, both of which accumulate toxic aluminum.
The effluent from the marsh ls passed through T-valve 72 (Figure 1). A pump 73 recycles a portion of the marsh effluent through pipe 74 back to the input of treatment tank 1. Approximately 2.5% - 20% of the effluent should be recycled. Thls 6695~-24 133692~
provides another route for microorganism replenishment as ciscussed above. The remaining effluent from the marsh is pumped by oump 73 through pipe 76 to treatment tank 11.
Treatment tanks 11-20 principally provide for polishing of the treated wastewater. By "polishing", it is meant that the water quality is improved to a fine degree and that additional nutrients are removed. Snails and fresh water clams in these sections continue to digest sludge and are in turn eaten by the fish, including small-mouthed bass and river trout. In the experimental Harwich septage system described above, ammonia (NH3) is reduced by treatment tank 20 to less than 1 mg/l and phosphorus is reduced to less than 10 mg/l. Total Kjeldahl nitro~en is educed to less than 10 mg/l. Suspended solids are reduced from over 500 mg/l to less than 10 mg/l and BOD is reduced from over 1,000 mg/l to less than 10 mg/l. Fecal coloform are reduced to below 100, less than 99% of influent and total coloform was ~educed to below 1,000, also less than 99% of influent. It is beneficial for the treated septage to remain in this polishing section for at least three days, for the embodiment under discussion.
The fish in the last several treatment tanks reduce the plankton population and are also used as water quality indicators.
Generally, if the water quality is poor, the fish will evidence symptoms that will help diagnose the problem.
13369~4 It is also beneficial to maintain the ratio of carbon, in the form of calcium carbonate, to the combined ammonia and nitrate concentration in a predetermined r~nge. For the system discussed above, it has been discovered that this ratio is 7-to-1. This ratio should be maintained in the first treatment tank of the first plurality of treatment tanks. For instance, if calcium carbonate is present at 210 mg/l and the combined ammonia and nitrates amount to 30 mg/l, the system should perform adequately.
The ratio tends to reduce as the system operates and thus limestone must be added to increase the calcium carbonate content.
In addition to calcium carbonate, sodium bicarbonate can be used to increased alkalinity. Sodium bicarbonate acts more quickly than does calcium carbonate.
With respect to the general operation of the system, of course, variations in plant and animal placement may arise. The general rule of thumb is that if an organism survives in a certain _ocation, it should be used there and if it does not, then it should not. If it survives, this means that it is extracting what it requires as nutrients from the water. If it does not survive, then it is not getting what it needs and thus, is not performing any useful water treatment function. One can think of treatment of wastewater as harvesting nutrients from the water, using the 1336g2~
plants, animals and bacteria as collectors. If they survive, then they must be removing pollutants. Variations of environment with ~he seasons will generally require variation in plant location.
Because conditions are not always apt for the survival of all plants, animals and microorganisms, the diversity in the system tends to decrease over time. Thus, the plant, animal, and microbial species must be replenished periodically to maintain diversity. Plant species can be observed visually and thus need only be replenished when the diversity is observed to have diminished. With respect to bacterial and other microbial diversity, a periodic regimen should be adopted.
In colder climates, it is necessary to insulate the system from cold. This can be accomplished by building a conventional greenhouse around the system. A greenhouse 100 is shown schematically in Fig. 4, surrounding six modules 84 of treatment tanks and marshes, as discussed above. Normal greenhouse technology should be applied. Additionally, the treatment tanks provide a thermal capacitance which helps regulate the temperature. Further, the photosynthetic bacteria trap light energy. The chemical reactions mediated by the bacteria are, on balance, exothermic (i.e. they give off heat), and thus the treatment tank temperature is maintained without a need for externally applied heat, from sources other than the sun or the artificial lights, if used. As has been mentioned above, the 133692~
capacity of the system is largely limited by the absorptive and ~ransmissive properties of the wastewater with respect to light.
~s noted above, it is possible to increase the capacity somewhat by increasing the height of the treatment tanks. It is also possible to use supplemental artificial light for natural light embodiments, such as the axially located light source embodiment discussed above. This increases the capacity of the system by a factor o approximately four. Further, the system is relatively straight forward to set up and may be considered as a modular element of a larger system having many similar modules. As many modules as are necessary to fully treat a municipality's wastewater may be provided. The system described above, which is capable of treating at least 1,200 gallons a day, occupies a space of approximately 1,200 ft.2 The configuration of the system may be altered, for instance by providing a U-shaped marsh, by placing all of the treatment tanks in a single file, dividinq the treatment tanks up into two or three ranks, etc. The possibilities are virtually limitless.
It is also sometimes beneficial to rearrange the order of the marsh with respect to the treatment tanks. For instance, in treating wastewater that has high levels of heavy metals, the marsh can be introduced earlier in the system. Further, in order to accommodate varying seasonal pollutants, the marsh could actually be mobile, on a sma-ll railroad car-type setup.
l33~924 Alternatively, because the marsh is simply connected to the wastewater treatment tank stream through plumbing, the plumbing can easily be rerouted at various times during the year in order to customize the particular Elow then needed. It may be beneficial to add a second marsh stage 122 after the final treatment tank stage of the system 8~, to sterilize the water (Figure 12).
It is also possible to introduce the components of the system, in particular the treatment tanks, into any stage of a conventional waste treatment system, so long as chemicals introduced by the waste treatment system are not introduced at a stage in the natural system that will kill the natural constituents.
Finally, variations in light and temperature during operation of the system are beneficial, in that the variation allows for a varying habitat for the various organisms living in the system.
Some function well in lighted environments and some in dark.
Thus, the daily application of natural sunlight alternating with unilluminated periods of night time darkness are beneficial.
~urther, some organisms function better in cooler (or warmer) conditions than do others. The experimental ~arwich system experienced daily temperature fluctuations of at least 20F, within the overall range of form 50F to 100P, with beneficial esults.
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The foregoing description shall be considered to be illustrative and shall not be considered limiting in any way.
Variations within the scope of the invention will be understood by those of ordinary skill in the art. Having thus described the invention, what is claimed is:
, I
SOLAR AQUATIC METHOD AND APPARATUS FOR TREATING WASTE
This invention relates in general to treating waste, and in specific to a method and apparatus for removing pollutants from various types of wastewater, using biologically active organisms and without using chemicals and without producing large quantities of sludge containing pollutants.
Background of the Invention Urban and industrial communities face the serious problem of how to safely dispose pollutants. The pollutants are often deposited in wastewater, which is of several forms. It may be septage, or sewage.
Septage consists of the contents of residential and industrial septic treatment tanks. The major constituent of residential septage is solid human waste. ~uman waste often carries with it human pathogens, which are microorganisms that cause illness or otherwise stre~s humans. Human waste include~
biodegradable organic matter either dissolved or suspended, which are quantified by a factor known as the biochemical oxygen demand ("BOD"). BOD is a measure of the degree to which constituents in wastewater will take up free oxygen (2) The oxygen absorbing constituents are largely decomposing organic matter in a decomposinq state. Biological methods of wastewater treatment (discussed below) depend on the presence of sufficient quantities of free oxygen in the water. Typically, biological waste treatment is conducted in part by oxygen breathing bacteria.
Thus, a high BOD indicates that the waste in the water is monopolizing all of the available oxygen and "suffocating" any oxygen breathing bacteria that may be present. Septage may also include carbonaceous organic compounds (dissolved and suspended) and nitrogen, phosphorus and potassium, referred to as "nutrients"
because they are necessary for the metabolism of organisms, including both microscopic and macroscopic, of the 5 living kingdoms of (plants, animals, fungi, protoctists and monera (bacteria)). Septage also includes paints, oils, cleaning fluids, heavy metals, and other toxins such as "PCBs" (polychlorinated biphenols), "teflon" (polytetrafluoroethylene) etc. A toxin is generally defined as a poison.
The wastewater may also be sewage, which has a much higher liquid content than septage, but which may contain the same types of pollutants mentioned above. Typically, septage is 30-100 times more concentrated than sewage. Typically, sewage has a BOD less than 700 and septage has a BOD of greater than 800.
Typically, sewage enters the municipal sewage system from the user's facility hookup, or through storm drains, and then proceeds to a sewage treatment center, where various treatment methods are applied. Septage, conversely, is collected by tanker trucks as part of regular maintenance when an individual septage tank needs servicing, for example, the 3eptic system becomes clogged or de ~ ~ f k 133692~
otherwise unusable so t~at pumping is required. The septaqe trucks ~ransport the septage to a waste facility and deposit the septaqe there for treatment.
The principal mode of conventional treatment involves separating out harmful substances from the water in various stages. Particulates are separated using mechanical processes, including filtration, centrifuging and settling. The concentrated particulates are then disposed of in a solid waste landfill.
~owever, these particulates still include the harmful pollutants and landfill must be considered to be and treated as a hazardous waste site. Additional pollutants dissolved in the water are maintained in coarse suspension or are precipitated from the water by combination with chemicals that reduce their solubility. These additional particulates are then removed as were those in the earlier stages. Finally, pathogens, harmful organisms in thQ
wa~eF, ar~ kllled ~y chlo~ine o~ oth~ chemicals and al~o by exposure to ultraviolet light.
The foregoing conventional processes have many drawbacks.
The mechanical processes require machinery to move large quantities of water against a pressure gradient and are thu~
capital intensive. Further, construction and operational costs are extremely'high. Large amounts of energy must be applied to the system to effect the filtration and the segregation of the solid particulates from the water. Finally, and most ~33~24 distressinqly, in most cases the pollutants are not changed in ~heir basic form, and remain harmfu~ substances. Although they are buried in landfills, they may eventually harm the environment, ~ith the washing of rains and passage of ground water, they return to the hydrological system.
Known systems attempt to minimize the use of chemicals and emphasize the use of biological systems to remove pollutants from sewage. To date, no biological system successfully treats septage. One system passes polluted sewage water through beds of certain living plants to remove certain pollutants. Prior to treatment with the plants, the water is separated from emulsible components, such as oil or tar, which components float in a layer above the water. Coarse suspended matter settles to a sludge layer at the bottom of a settling treatment tank. A two stage living plant filtration system is typical. In the first stage, a plant such as Phraqmites communis, which has roots extending from nodes, is rooted in a two layer sand bed. The root structure maintains open passageways through the sand so that the water can flow through freely. The upper layer is composed of fine sand, as compared to the lower layer. Slime and other suspended matters which are too coarse to pass through the fine sand filtration bed collect on top. After a suitable amount of slime has collected, the treatment tank is drained and dried out. The slime concentrates into a thin layer which cracks and curls up and is physically removed.
Water leaving the filtration bed contains dissolved material and pathogenic organisms. In the second stage, the water passes through a second bed of sand, in which is rooted a plant such as Scirpus lacustris. This plant removes organic compounds and inorganic ions and bacteria from the water. If necessary, additional stages using other plants that remove organic compounds, ions and bacteria not removed by Scirpus lacustris may be applied.
It is known that certain plants effectively remove particular dissolved pollutants from sewage. Scirpus lacustris (mentioned above) and ~ypha angustifolia remove organic aromatic compounds and pathogenic organisms, including E. coli, Salmonella, acid-fast bacteria, Ascarides and Oxyuris. They also effectively remove chemical anions, phosphates, nitrates, sulfates and chlorides.
It is also known that the roots of several species of tall growing bulrushes are effective for removing halogenated phenols such as pentachlorphenol from sewage. In harsh environments, plants must be protected by using a hot house type system. Water laden with pathogens can be purified with vegetation having certain bacterial root nodules. Bacteria live in the nodule.
Many types of bacteria produce an antibiotic, which in nature protects those bacteria from other strains of bacteria by killing 1 3 3 6 9 2 ~
them. These bacteria can be used in a wastewater treatment system to kill bacteria that are harmful to humans and animals. Known systems cover the surface of the containment vessel with opaque material to prevent access of light to the water, which light makes possible the growth of algae.
This known method has many drawbacks. Principally, it produces large quantities of sludge which must be disposed of.
~dditionally, the slime can only be removed if the filtration bed is allowed to dry out. Thus, redundant e~uipment must be available to process the water while the bed is drying out.
Further, removing the dried slime is a tedious and labor intensive process and also results in slime, which must be disposed.
Additional known systems for treating sewage (but not septage) use biological methods of wastewater treatment including wetland systems; aquatic plant processes; and combined aqua culture systems.
Wetland methods for sewage treatment use marshes, either natural marshes or man-made marshes. The use of natural marshes must be monitored very carefully so as not to pollute the natural environment. Wetland systems have been used successfully in pilot operations to reduce BOD, suspended solids ("SS"), trace organic compounds and trace heavy metals. However, problems with insects, such as mosquitoes, are prevalent. Further, wetland systems take up huge amounts of surface area. Further, as they mature, they 13369~
become less effective. Eventually, .hey ~ecomD so inefficient that they cannot be used.
Also known for treating sewage are aquati- piant systems where free floating aquatic plants (known as "~acrophytes") are used for the treatment or refinement (sometimes referred to as "polishing") of wastewater. Water hyacinth systems may reduce BOD, SS, metals, nitrogen and refractory trace organics. Water hyacinths, however, cannot remove phosphorous in high degrees. An active mass of organisms lives in the root system of the water hyacinths. These organisms play the major role in the chemical breakup of the pollutants. In order to maintain the system, the water hyacinths must be harvested and removed. The amount of plant biomass produced in a water hyacinth pon~ system is about four times the quantity of waste sludge produced in conventional activated sludge secondary wastewater treatment. This plant mass must be disposed of. Disposal of the plant macs is a problem, as the plant mass will probably have incorporated the pollutants within its structure and may constitute a haza~dous waste.
Further, the mosquito control is very difficult with water hyacinth systems. Mosquito eating fish must be used.
The use of duckweed rather than or in addition to water hyacinth has been suggested for treating sewage, however, very little data is presented.
1336~24 Combined aqua culture systems have also been proposed for treating sewage. An aqua-culture system is defined as one ~Aat produces a useful biomass from a controlled aquatic media.
Examples of a useful biomass are plants that are consumable by either humans or animals. These systems, however, are unacceptably labor intensive.
A method of treating wastewater from citrus processing factories has been proposed which includes introducing the wastewater into a pool containing an absorbent material such as peat moss or shredded paper and a large quantity of earth worms.
The peat moss or shredded paper absorbs the pollutants from the liquid and the worms consume the paper or peat moss.
Additionally, downstream, fish that feed on the lower end of the food chain (i.e., smaller animals such as plankton), such as ~ilapia, are introduced. This method may not be used to treat wastewater containing petroleum oils and/or industrial chemicals, which would destroy the worms.
An aquatic pond stocked with a large number of organisms, such as fish, snails, worms, turtles, pollywogs, bacteria, microorganisms, algae, water lilies and other vegetation has been proposed to further reduce by 80-95% the BOD already reduced by other processes. A method of protecting the aquatic pond against ruin caused by a waste overload from the sewage plant has been proposed. It provides a haven where a seed colony of the aquatic 13369~4 life necessary to re-populate the pond will also (and always) be presen~ due to the constant addition of oxygen saturated water.
Another sewage treatment system has been proposed that includes a stage where solids are decomposed by the action of unspecified anaerobic bacteria, which hydrolyze and ferment complex organic compounds to simple organic acids. An additional stage is provided where the wastewater is treated with activated carbon and a mixed microbial population, which removes organic matter, organic nitrogen, ammonia (NH3) and nitrogen in the forms of nitrate (NO3) and nitrite (NO2) from the processed wastewater.
~owever, chemicals must be used to remove phosphates and a chemical coagulant and additional chemicals such as hypochlorite are added. Ozone (03) is also added to the wastewater, which may result in chlorinated compounds, a potential health hazard.
Another sewage treatment system has been proposed using a combination of natural ecological processes, including: an aerated lagoon; submerged, high surface area, activated bio-web substrates providing a fixed bacterial film; floating a~uatic plants for nutrient (pollutant) removal; a polyculture of micro-invertebrates, fish, and shell fish in a balanced food chain for removal of nutrients and organics from the wastewater and concentration into a biomass. A solar heated greenhouse-type cover is disclosed to prevent the system from damage due to cold.
Drawbacks of this system are that management is time consuming; it ~ 133~2~
is difficult to maintain physical segregation between oxygenated and unoxygenated zcnes.
It has been disclosed that certain bacteria plasmids (small molecules of DNA) enable bacteria to degrade obnoxious halogenated organic wastes, such as chlorinated aromatic compounds.
A process for the purification of polluted water has been proposed including applying aquatic plants to the water. The method is particularly directed towards non-punctiform pollutants, such as fertilizers. The system has four different types of plant zones: a swamp 20ne, a marsh zone, a reed zone, and a quaking bog.
This system suffers from seasonal fluctuations in functionality;
senescence: excessive cleaning requirements and bad effects on qround water.
It has also been proposed to purify sewage using an expanded bed reactor containing film upon which grow methane producing anaerobic bacteria. This system must be shielded from light, because the bacteria cannot tolerate light.
All of the foreqoing methods suffer from certain drawbacks, as have been discussed.
Brief Description of the Invention.
The invention relates to both a method and an apparatus for treating wastewater, including sewage and septage, by removing unwanted substances therefrom. Both the method and the apparatus use biological cleansing elements. The invention is particularly 133692~
effectlve in lts capacity to treat septage, a very concentrated form of waste contalnlng fluid.
In one aspect, the lnventlon provldes an apparatus for removlng pollutants from water comprlslngs A) a serles of tanks containlng water whlch lncludes organlsms for removlng pollutants from the water, whereln each of sald tanks comprlses a bottom and llght-transmlttlng sldes and transmlts energy lnto the water substantlally throughout lts entlre volume; B) means for connecting said tanks in series such that water can be transferred along sald serles of tanks from a flrst tank to a last tank; C) means for lnputtlng water contalnlng pollutants to the flrst tank; and D) means for outputtlng water from which said pollutants have been removed from the last tank; wherein series of tanks further comprises: a) a first tank or plurallty of tanks containing polluted water and bacteria for removing at least some of the pollutants from the water; b) a second tank or plurallty of tanks connected ln serles with sald flrst tank or plurality of tanks contalnlng non-aquatlc plants capable of removing at least some of the pollutants from the water, and a support for malntaining the non-aquatic plants at the surface of the water; and c) a thlrd tank or plurallty of tanks connected ln serles wlth said second tank or plurallty of tanks contalnlng polluted water and fish capable of removlng at least some of the pollutants from the water.
In another aspect, the lnventlon provldes a method for treating water comprlslng: A) connectlng a plurality of tanks each capable of holding water in series such that water can be B~ ~
, =
.
1~692~ 66956-24 transferred along sald serles of tanks from a first tank to a last tank, wherein each of said tanks comprlses a bottom and light-transmitting sldes so that energy may be transmltted to substantlally the entlre volume of water contalned thereln; B) stocking said tanks with water and organisms for removing pollu-tants from the water; C) inputting water containing pollutants to the first tank7 D) outputtlng water from which at least some of said pollutants have been removed from the last tank; wherein the method lncludes the steps of: a) stocklng a flrst tank or 1~ plurality of tanks contalnlng polluted water wlth bacterla for removlng at least some of the pollutants from the water; b) stocking a second tank or plurallty of tanks connected in serles with sald flrst tank or plurality of tanks with non-aquatlc plants capable of removlng at least some of the pollutants from the water, and provlding a support for maintalning the non-aquatlc plants at the surface of the water; and c) stocking a thlrd tank or plurallty of tanks connected ln serles wlth sald second tank or plurallty of tanks wlth flsh capable of removlng at least some of the pollutants from the water.
The apparatus features, ln a preferred embodlment, a multistage course through whlch the wastewater wlll flow, the course comprlslng a flrst plurallty of energy transmlttlng treatment tanks sltuated so that electromagnetic energy, lncludlng light, may be transmltted throughout substantially all of the wastewater therein. A diverse plurallty of types of microorganlsms are provided ln the treatment tanks. The mlcro-organlsms lnclude bacterla, protoctlsts, fungl, plants and lla B
133~92~
anlmals. The course further includes a second plurallty of energy transmlttlng treatment tanks also sltuated so that electromagnetlc energy, lncluding light, may be transmitted throughout substantlally all of the wastewater therein, and is stocked with a diverse plurallty of non-a~uatic plants. The plants are supported on flxtures, so that the plant roots extend lnto the wastewater flowlng through the second plurallty of treatment tanks. The course also has a marsh in whlch grow a plurallty of varietles of marsh plants and a third plurallty of energy transmittlng treatment tanks ls provlded, also sltuated so that electromagnetlc energy, lncluding light, may be transmltted throughout substantlally all of the wastewater therein. A plurallty of specles of hlgher anlmals, including zooplankton, phytoplankton (algae) flsh and mollusks such as snails and fresh water clams are llb B~
provided in the second and third pluralities of tanks. In relatively cold climates, a greenhouse must be provided to maintain the system warm enough during the winter for the plants and animals to grow. The wastewater is caused to flow through all of the pluralities of treatment tanks and through the marsh. The biological activity of the species of bacteria, plants and animals purifies the wastewater.
An important aspect of the apparatus is that the treatment tanks transmit energy into the wastewater substantially throughout its entire volume. The treatment tanks may transmit energy through their outer walls, preferably 100% around their perimeter and over their full height. The energy is predominantly in the wavelengths of light, both visible and non-visible. A large surface area for energy transmission allows for a very active and populous photosynthetic microorganism population, both aerobic and anaerobic, from top to bottom of the treatment tanks and around their perimeter throughout the entire volume. The photosynthetic microorganisms occupy a substantial portion of the surface area of the treatment tanks. This arrangement has spawned communities of organisms which have not been seen before either in such quality or such quantities. Known biological sewage treatment systems have only used conventional, in-ground pools. Light is transmitted only through the upper surface of the water. In many -133~92~
known systems, in ~act, only minimal light s transmitted, due to shading by water plants.
The method of the invention comprises the steps of providinq the apparatus described above and initially stocking it with plants, animals and microorganism as described above. The microorganisms stocked in the first two pluralities of tanks include bacteria and algae. The microorganism populations must be restocked frequently to maintain high diversity of types.
~ he method also includes the step of agitating the wastewater contained in the treatment tanks, through aeration and other means, to prevent sludge from settling in the bottom of the treatment tanks and to keep particulates spread throughout the full volume of the treatment tank. This permits virtually all of the contaminants in the wastewater to be removed from the wastewater by the organisms living therein, rather than allowing the contaminants to settle to the bottom. Agitation through aeration also introduces oxygen (2) into the treatment tanks.
This replaces free oxygen taken up by decaying biodegradable organic compounds. Free oxygen is needed by aerobic bacteria, which metabolize and thus degrade many pollutants.
It is beneficial to maintain as diverse a population of types of bacteria and other microorganisms as is possible. Different pollutants serve as nutrients for different microorganisms.
Maintaining a large variety of types of microorganisms facilitates 133~924 the removal of a lar~e number of differen~ nutrients in dif~erent forms. Furth~r, it is beneficial to maintain various types of bacterla that are redundant with respect to their nutrient needs, and that vary with respect to their survivability in harsh environments (e.g. temperature, light, antibiotic variations) so that given any of a variety of environmental pressures, there will be present a type of bacteria that can withstand the environment and metabolize the nutrients. Variety in bacterial types is discussed in A New Bacteriology, by Sorin Sonea and Maurice Panisset, Jones & 3artlett Publishers, Inc. (1983), New York, published first in French in 1980 by Les Presses de l'Universite de Montreal.
It is also an aspect of the method of the invention to recycle a small but significant volume of the partially treated wastewater from various mid-stages of the flow course back to earlier stages, including the input. Recycling provides a means of automatically maintaining a higher level of diversity of microorganisms at the earlier stages, primarily the input, where conditions are harshest.
Finally, it is an aspect of the method of the invention to maintain in the first treatment tank the ratio, by weight, of the amount of carbon, in the form of calclum carbonate, to the amount of ammonia and dissolved nitrates, within a specified range. rt 13~9~
has been found that this ratio provides the appropriate amount of carbon for nutrition to the growing microorganisms.
Objects of the Invention Thus, several objects of the invention are to provide an apparatus and a method for treating wastewater by removing unwanted substances therefrom:
by using biologically active organisms;
without using chemicals that are harmful to the environment;
without producing large quantities of sludge that contain pollutants;
that effectively removes biodegradable organic contaminants;
that effectively removes paints, oils, cleaning fluids, ~heavy metais and other toxins;
that can be used to treat septage;
that can be used to treat sewage:
that requires a capital expenditure lower than conventional waste treatment systems:
that is easy and quick to construct:
that requires a relatively low operating budget as compared to conventional treatment systems;
that does not place harmful chemicals in the natural environment;
~ 1336924 that is flexible and responsive tO changes in the contents of the ~nwanted substances in the wastewater;
that requires relatively low amounts of energy to operate;
that can be added to conventional waste treatment systems as a retrofit module:
that can be used over a wide range of temperature and light conditions;
that can be used in developing countries;
that can be used in conjunction with a natural marsh wastewater treatment system;
that can purify sewage and septage to a degree that it may be returned to the natural water system; and that can treat sewage and septage without the formation of sludge or biomass, such as plants, fish, etc., that contain hazardous materials.
Other objects of the invention will be evident from consideration of the following description of preferred em~odiments and the figures of the drawing.
Figures of the Drawing Figure 1 is a schematic perspective view of the apparatus of the invention, showing the multiple stage flow course including a plurality of stages of treatment tanks, and an artificial marsh.
~ 133~92 1 Figure 2 is a schematic perspective view, with parts broken a-~ay, of a preferred embodiment o~ a tre~tment tank of the apparatus of the invention.
Figure 3 is a schematic cross-sectional view of an artificial marsh of the apparatus of the invention.
Figure 4 is a schematic plan view of several modules of the apparatus of the invention housed in a greenhouse.
Figure S is a schematic perspective view of a preferred embodiment of an oval treatment tank of the apparatus of the invention.
Figure 6 is a schematic perspective view of a preferred embodiment of a bottom lighted treatment tank of the apparatus of the invention.
Figure 7 is a schematic perspective view of a preferred embodiment of a treatment tank of the apparatus of the invention having a large surface area.
Figure 8 is a schematic perspective view of a preferred embodiment of a treatment tank of the apparatus of the invention having light chimneys.
Figure 9 is a schematic perspective view of a preferred embodiment of a treatment tank of the invention that is below ground and artificially lighted.
Figure 10 is a schematic perspecti~e ~iew of a preferred e~odiment of a treatmert tank of t~e apparatus of the inventi~n that has an internal light.
Figure 11 is a schematic perspective view of a preferred embodiment of an annular treatment tank of the apparatus of the invention that has an internal light.
Figure 12 is a schematic plan view showing an embodiment of the apparatus of the invention including a second marsh at the output end of the system.
Detailed Description of Preferred Embodiments of the Invention Referring to Figure 1, a schematic diagram of a perspective view of the apparatus of the invention is shown. A plurality of energy transmitting treatment tanks (1-20) form a flow course, sometimes referred to as "an artificial river", through which wastewater, for instance, septage, that bears pollutants passes.
For purposes of clarity, some of the components of individual treatment tanks 1-20 are omitted from Figure 1. The structure of an individual treatment tank, for instance tank 1, is discussed below with reference to Figure 2. The hookup of the treatment tanks to each other, and to the wastewater input and output is also discussed below. An artificial marsh 22 is placed approximately mid-way along the course of the artificial river of treatment tanks. Wastewater is provided to the system at input 24. Depending upon whether the wastewater ~s in the for~ of septage or sewage, the input may be either an underground holding tank or an open lagoon (in the case of septage) or may be any stage of a municipality's sewage treatment system, from the raw sewage to fully treated sewage. From input 24, the wastewater is introduced through pipe 26 to treatment tank 1. Treatment tank 1 is the first of a first plurality of treatment tanks all arranged so as to receive a high amount of electromaqnetic energy, including light.
Turning now to figure 2, the structure of a typical treatment tank in a preferred embodiment, treatment tank 1, will be reviewed. The treatment tank is a cylinder 30 approximately one and a half to two meters high and one and a half to two meters in diameter, which transmits electromagnetic energy, including light.
The wall thickness is approximately 1.1 mm (.045 in). The wastewater enters cylinder 30 through pipe 26. Wastewater leaves cylinder 30 through standpipe 32. Water is siphoned up standpipe 32 from the bottom of the treatment tank 30 and into the adjacent treatment tank (in this case treatment tank 2).
Alternatively, gravity feed can be used by having the upper extension of standpipe 32 remain below the water level of the tank in which it stands. For the embodiment shown, standpipe 32 is approximately S cm (2 in) in diameter.
l` 1336924 Air is provided below the water level 34 through pipe 36 and airstones 37a, 37b, which receive air that has been compressed by compressor 38 (fig. 1) through pipes 28 and 36. The number of airstones per treatment tank varies from treatment tank to treatment tank, dependin~ upon the oxygen needs of the biota in each particular treatment tank.
A floating support 40 is provided in each treatment tank.
(For clarity, supports 40 are not shown in figure 1. Plants 41 supported by such supports 40 are shown in treatment tanks 3, 8, 13 and 18. However, it should be understood that the floating supports 40 and the plants supported thereby (discussed below) are provided for each of the treatment tanks 1-20.) Supports 40 may be of styrofoam or of wooden lattices or any other structure that will physically support a mass of plants above the surface of the wastewater, while allowing the roots of the plants to pass through the support and into the wastewater. Further, the supports should be easily removable, in order to harvest the plants, or to service the mechanical components, or the wastewater in the treatment tank, or to move the plants to another location in the system, as discussed below. As shown in figure 2, a plurality of plant species 42, 44, 46 (shown schematically only) are supported by support 40. The roots 41 of the plants extend deep into the wastewater, substantially to the bottom of a treatment tank. (It will be understood that even in figure 2, the number of plants has been r~duced below a realistic amount, ln order ~o prevent the ~igure ~rom beco~ing overly cluttered.) Returning ncw to rigure 1, the plumbing among the ~re~tment tanks 1-10 will be explained. As has been mentioned, wastewater flows through standpipe 32 from treatment tank 1 into treatment tank 2 and similarly from tank 2 to tank 3, tank 3 to tank 4 all the way to treatment tank 10. Similarly, compressed air from compressor 38 is introduced into each treatment 'ank through pipe 28 and a respective line 36. Airstones 37a and 37b introduce the air into the treatment tank as a multitude of bubbles, and disperse the air generally throughout the water in the treatment tank. For the embodiment shown, with a daily septage influent BOD
of 1,000 mg/l and suspended solids of 200 mg/l, dissolved oxygen should be maintained at 5 mg/l or greater. 50 scfm transfers 56 pounds of dissolved oxygen per day into the wastewater.
At various stages of the artificial river, some wastewater is recycled. In the embodiment shown in figure 1, wastewater from the output pipe 33 is directed by pump and valve assembly 54 back through pipe 56 to input to treatment tank 1. Similarly, output from treatment tank 10 is directed by pump and valve assembly 58 through pipe 60 into treatment tank 5. Thus, through the combination of the recycling pipes 60 and 56, some wastewater from treatment tank 10, along with the small organisms living therein ~ 1336924 will be recycled all the back to treatment tank 1. Recycling from other locations to other locations is also possible.
In the embodiment shown in figure 1, the wastewater leaving treatment tank 10 next passes through an artificial marsh 22. For a system of the size shown in figure 1, the artificial marsh is constructed in a plywood frame 86 having a triangular cross-section approximately 1 meter wide at the top and approximately 1/2 meter deep at the bottom apex. The plywood 86 is lined with a plastic or suitable waterproof material 88 so that the environment is maintained in control. The length of the marsh is approximately 40 m. (116 ft.). The plywood frame is filled for its entire length with sand 64. The marsh is inclined so that the input, near line 62, is higher than the output at the opposite end. Various species of plants are provided in the marsh. The selection and function of the plants will be discussed below.
The marsh has an output 68, which is connected through pipe 70 to a T-valve 72 and pump 73. Through action of the pump 73 and T-valve 72, approximately 10% of the flow of partially treated wastewater is redirected through pipe 74 to the input of treatment tank 1. The remaining 90% travels through pipe 76 into the input of treatment tank 11. Treatment tanks 11-20 are connected to each other in the same manner as were treatment 133692~
t nks l-10, however, no feedback, such as through pi~es 60 and 5 ~s provided. Feedback may be provided but the benefits r~ceived are usually minimal, due to the lower levels of microbial activity downstream, due to the lower nutrient level of the partially treated water.
Treatment tank 20 is equipped with an air pump and fiberglass-type filter 80, to provide a pH buffer and additional denitrifying capacity. The output of treatment tank 20 is directed to a sand filled filter treatment tank 82, which additionally removes plankton and other suspended solids. After passage through the sand filter 82, the treated wastewater can be passed through an ultraviolet light chamber (not shown) for sterilization.
The method of treating wastewater using the basic apparatus described above is described below. Once the apparatus has been provided, each of the treatment tanks 1-20 is filled with clean water. The flow through treatment tanks 1-10 and 11-20 is initiated. Cuttings of the plants selected for growth in the plant supports 40 are inserted in the supports 40 and the supports 40 are placed in each of the respective treatment tanks 1-20. The selection of plants is discussed below. Marsh plants are also planted in the marsh with specific plants being placed in specific locations along the length of the marsh.
~ 1336924 Microorganisms and phytoplankton (algae) and small animals including zooplankton are seeded in treatment tanks 1-10.
Initially, each of the treatment tanks is seeded with an identical compliment of microorganisms. The treatment tanks are seeded with a wide diversity of bacteria including the following: Bacillus, Pseudomonas, Nitrobacter, Nitrosomonas, Cellulomonas, Aerobacter, and ~hodopseudomonas. In addition, microorganisms are ubiquitous and are supplied by the influent, on the roots of the plants added to the system, and from the atmosphere. Therefore, all of the types of microorganisms present cannot be identified. One such microorganism which has been identified is Anabaena.
In addition to the microorganisms, treatment tanks 11-20 are stocked with higher animals. All are stocked with several varieties of mollusks, including snails, including Lymnaeidae (right hand) and Planorbidae (ramshorn) and fresh water clams, including Unio and Ondonta. Plankton is int~oduced at treatment tanks 15 and 16 and move downstream with the effluent. Small-mouthed bass and river trout are stocked in treatment tanks 16, 17, 18 and 19 and Plecostomous (suckerfish) are also provided in treatment tank 19.
Turning now to the types of plants that are used, in general, the plants in the treatment tanks 1-20 and the marsh 22 should be young and at a stage of high growth, to maximize nutrient uptake.
In an experimental septage treatment system established at 133692~
~arwich, L~assachusetts, the f~llowing plants are used as indicated. Treatment tank 1 is provided with a large wi~low and water willows which are supported by plant supports 40, and water starwart. Treatment tank 2 is provided with a water willow plant and willow cuttings, again supported by a support. Treatment tank 3 has water hyacinths, a water plant which floats on the surface and does not re~uire a support. Treatment tank 4 is provided with the floating plant star duckweed. Treatment tank 5 is provided with willow cuttings which must be supported.
Treatment tank 6 is provided with buttonbush and water willow, both of which must be supported. Treatment tank 7 is provided with umbrella plants, tomato plants, nasturtium and eucalyptus, all of which are supported, and the floating plants pondweed and water starwart. Treatment tank 8 is provided with supported willow cuttings and floating water hyacinths. Treatment tank 9 is provided with floating water hyacinths and supported tomatoes, nasturtium and pokeweed. Treatment tank 10, just before the marsh, is provided with fragrant water lily and pickeral weed, both of which must be supported, along with water hyacinths.
After the marsh, treatment tank 11 is provided with supported tomatoes and nasturtiums. Treatment tank 12 is provided with floating duckweed. Treatment tanks 13 and 14 are provided with~
floating hyacinths and duckweed. Treatment tank 15 is provided with supported pickeral weed and fragrant water lily and floating 1~3692~
hyacinths. mreatment t~nK 16 is provided with tomatoes, nasturtium and wate~ hyaci~th. ~reatment tank 17 is provided w~th floating water hyacinths and tomatoes, nasturtium and eucalyptus.
Treatment tank 18 is provided with floating duckweed and supported pickeral weed. Treatment tank 19 is provided with supported nasturtium and eucalyptus. Treatment tank 20 is provided with floating Azolla. The roots of Azolla provide a habitat for the nitrogen fixing bacteria Anabaena. It will be understood that this list is illustrative only, with respect to both species and location. It is possible to place specific plants in different locations. It is also often beneficial to move the plants from place to place, as they grow and mature, and as the seasons change.
Turning now to the plants grown in the marsh 22, the plants include Scirpus lacustrus (bulrushes), Iris pseudacorus (yellowflag), Typha spp (cattails) and other plant species having nonbactericidal and antiviral action. As with the plants growing in the treatment tanks, these plants are illustrative only.
After the system has been stocked as described above, the flow from the input source 24 is begun at a flow rate of approximately 1,200 gals per day for the tank size described above. Each treatment tank holds approximately 600 gallons of wastewater. The wastewater remains in each treatment tank for approximately twelve hours, thus providing for an overall retention time through the twenty treatment tanks and the marsh of approximately ten days. If artificial lighting is used, as discussed below, the throughput can be increased. Natural sunlight, applied to septage retained in treatment tanks described above provides enough energy to treat 1,200 gallons per day, during the summer months at Harwich, MA, U.S.A.
As will be discussed in more detail below, a beneficial result is obtained from using treatment tanks of approximately two meters in diameter. Thus, the overall size of the treatment tank system using natural light and simple cylindrical treatment tanks, is limited to roughly the size of the system illustrated in figure 1. It is possible to extend the height and diameter of the treatment tanks slightly, increasing the capacity by perhaps a factor of two. ~owever, the system described in figure L is easily used in parallel with any number of identical systems, as shown schematically in Figure 4, thereby creating a system of any desired capacity. The system 84 shown in figure 1 having twenty treatment tanks should be considered to be a module of a specified cleaning capacity. Other configurations of treatment tanks are possible, as discussed below.
Before the wastewater has passed through the entire course of treatment tanks 1-20, it may be necessary to provide nutrients to the microorganisms and plants stocked in the downstream treatment tanks. Or, alternatively, the downstream treatment tanks can be 133692~
stocked at a r~spectively later time than the ~pstream treatmenc t~nks, tLmed to cGincide with the first arrivai of the partiall~y treated wastewater.
As has been mentioned, initially, all of the first ten treatment tanks are stocked with identical assortments of microorganisms. However, as the system achieves relative stability, certain types of microorganisms predominate at various stages along the treatment tank course and different types of microorganisms either die or decrease greatly in number.
In this context, the importance of the electromagnetic energy transmitting treatment tanks will be understood. The treatment tanks are of a thin, 1.1 mm (.0~5 in), fiberglass, which transmits a spectrum of electromagnetic energy, including all light energy except for ultraviolet light. The treatment tanks need not be of the thin material, so long as the treatment tanks transmit this spectrum of electromagnetic energy. The above-mentioned material is adequate and due to its thin-wall size, is relatively lightweight, inexpensive and easy to set up. Because the treatment tanks transmit electromagnetic energy, in particular li~ht, of various bandwidths, into the wastewater around the entire perimeter of the treatment tan~ and over its entire height, a high amount of electromagnetic energy i5 available for the use of photosynthetic and other microorganisms. This is so even in the case where leafy plants, such as water hyacinths, completely 133~924 cover the water surface of the treatment tank. In known septage and sewage systems, such hlgh degree of llght energY
has never been provlded, and has, in fact been discouraged due to the percelved disadvantage of hlgh algae growth.
As the system achieves equilibrium, the walls of the upstream treatment tanks (e.g. tanks 1-5) become covered with many different types of photosynthetic bacteria and micro-organisms, including various types of cyanobacterla, both purple and green. The coating of biota on the walls grows to a thickness of approximately 3 mm (.125 inches).
A by-product of photosynthesis is oxygen gas (2)~
whlch is used by aerobic microorganisms. Aerobic organlsms cannot take direct advantage of energy in the form of light to produce 2 Natural systems that have been evaluated to-date have not shown such a large quantlty and such a large variety of photosynthetic mlcroorganisms as exist in the treatment tanks operating in accordance with the invention. Thls is because most natural systems, such as ponds or streams, are designed to admit electromagnet energy in the form of light only through the surface, however, that surface is often covered with plants. In the treatment tank system of the present invention, the large quantity of admitted light is uni~ue. Thus, even micro-animals (as distingulshed from bacteria) wlth photosynthetic capacity have been observed.
133692~
Photosynthetlc actlvlty results in the consumption of nutrients and the production of oxygen gas (2) As has been discussed above, raw septage has a characterlstlcally high BOD. A typical BOD for septage lnfluent ls greater than 1,000 mg/l (or 1,000 ppm). The photosynthetic bacteria, which produce ~2~ such as cyanobacterla, are anaeroblc and thus do not need oxygen to grow. The oxygen produced by the bacteria ls taken up by the organlc materlal ln the waste responsible for the hlgh BOD, thus reducing the BOD.
Various types of photosynthetlc mlcroorganlsms are capable of uslng different bandwidths of the electromagnetic energy spectrum for photosynthetic energy. Water attenuates the transmission of electromagnetic energy as a function of its wavelength. Shorter wavelength electromagnetic energy is dampened more quickly than that of longer wavelength. Thus, microorganisms that can only use the shorter wavelengths are more commonly found closer to the surface than are micro-organisms that can take advantage of longer wavelengths.
After transmission through one meter of water, all of the useful electromagnetic energy has been absorbed by the water.
Therefore, no photosynthetic activlty can occur more than approxlmately one meter from an energy admlttlng source.
Thus, ln the case of the treatment tanks of the present lnvention, virtually no photosynthetic activlty can take place more than one meter from a surface at which light 133692~
enters the wastewater. Thus, for a basic embodiment of the lnvention, the maxlmum dlameter of the treatment tank 30 for whlch photosynthetlc actlvity across the entlre width and depth of the treatment tank 30 can be expected is approxi-mately two meters. It is possible to increase the effective photosynthetic volume of a treatment tank by providing a long oval tank 130 having a minor axis of less than two meters (Figure 5). It is also possible to use treatment tanks 230 havlng a corrugated surface (Flgure 7) to increase the surface area and light transmlttlng capaclty, thereby lncreaslng the microbial diversity and thus the photosynthetic activity.
Alternatively, needle-like or comb-like pro~ections can radiate inward from the walls.
It is also possible to exploit artificial light and to provide a treatment tank 330 (Figure 10) of approximately 4.5 meters in diameter and providing an axially located artiflcial light source 110. The artificlal llght source 110 may be a submersible light. Alternatively, a concentric, translucent light transmitting chlmney 434 (Figure 11) may be provlded in the center of a treatment tank 430 into which can be hung a conventional light source 410. In this manner, an annulus two meters thick can be effectlvely used. Additional schemes of artificially illuminating tanks can be devised, such as llghtlng the bottom of the tanks 530 (Figure 6), or providlng a plurality of llght transmitting chlmneys 634 t~
(Flgure 8) inside a large pool 630 (Figure 8). If artlflcial llghts 710 are used it is not necessary that the treatment tankæ be situated above ground. They may be below ground, such as with conventional pools 730 and tanks (Flgure 9).
Further, if artificial llght is used, the system also operate at night, when natural light is unavailable.
The light absorbing property of water, coupled with various bacterla's narrow frequency band energy requlrements and anaerobic nature, limit the amount of photosynthetic actlvlty ln open surface, below water, unlighted tanks such as those conventionally found in previous "natural" treatment systems. Most photosynthetic anaerobic bacteria cannot tolerate oxygen. At the surface of a pool, oxygen content is sometimes high, due to mixlng caused by wlnd and waves. Thus, anaeroblc, photosynthetlc bacterla whlch requlre the shorter wavelength light cannot survive. These bacteria can survive, however, in abundance ln the treatment tanks of the present invention.
In addltion to the photosynthetic anaerobic and the aerobic schemes for energy productlon, a thlrd mechanlsm, which capitalizes on energy ln certain molecules exists.
Chemoautotrophy uses C02 and energy bound up in hydrogen sulfide (H2S), ammonia (NH3) and methane (CH4) gases. These organisms dominate in dark, oxygen poor regions where H2S, NH3 or CH4 are present. They cannot survive in highly lighted areas.
13~92~
Turnlng now to the plants supported at the surface of the treatment tanks, the prlnclple functlon of the plants ls to provlde a physical envlronment or substrate for the growth of the microorganlsms that wlll metabollze the pollu-tants. It is important that the upstream plants be of a type that wlll qulckly establlsh an extenslve and sturdy root structure, extending deep lnto the wastewater, substantlally all the way to the bottom of the treatment tank. As the wastewater in the treatment tank ls stlrred-up, by the aera-tlon dellvered through plpe 36, as a result of the suctlon of wastewater from the bottom of the treatment tank up through standplpe 32, and by flsh foraglng ln treatment tanks 15-~0, solld partlculates wlll be dlspersed unlformly throughout the treatment tank and eventually wlll become trapped ln the root system of the plants. In the root systems tiny local envlron-ments will arlse. Some wlll be aeroblc, where oxygen bubbles from the aeration are trapped. Others wlll be anaerobic where no oxygen is present. Others wlll be comblnatlons thereof with lower levels of oxygen.
In the ~lrst few treatment tanks, lt ls believed that purple cyanobacterla break down toxins, such as phenols, benzenes, chloramines, pesticides and herblcldes.
Rhodopseudomonas, an anaeroblc bacterla, uses light energy to oxidlze organlc compounds. The fermentatlon products provlde nutrlents for other bacterla. Durlng thls flrst stage also, heterotrophlc bacterla (those bacterla whlch metabollze 6~956-24 J
133692~
organlc material) Baclllus and Pseudomonas, remove soluble compounds. Bacillus oxldlzes a varlety of carbohydrates, organic acids, fats, oils, proteins and starches. These two bacteria recelve oxygen from the metabolism of the substances mentioned above, and thus, the aeration and oxygen production of the photosynthetlc and aeroblc bacterla is very important.
Soluble organlc chemicals are removed according to the bio-chemical e~uation 2 CH3COOH + 202 becomes 2CO2 + 2H2O.
Baclllus also secretes enzymes, known as exoenzymes, whlch degrade proteins, fat and starch into smaller molecular units that can be metabolized by other bacterla downstream. During low oxygen conditions, Pseudomonas also reduce nitrate and nitrogen levels. In addition, Aerobacter ferments carbo-hydrates to produce short chain organic compounds, carbon dioxide (CO2) and water (H2O). The short chaln organic compounds provlde carbon and energy for Pseudomonas.
The overall environment in the first five treatment tanks is predominantly anaerobic. For septage, the initial BOD is greater than 1,000 mg/l. Suspended solids, which are made up largely of biodegradable and nonblodegradable organic compounds, are normally present ln the lnput septage at greater than about 500 mgtl.
Durlng the flrst stage (treatment tanks 1-5), the prlmary ob~ective ls to reduce the BOD and suspended sollds.
Therefore, photosynthetic anaerobic bacterla thrive.
Addltlonally, the type of plants desired at the beginning of the waste stream are hardy, i.e. able to withstand toxins, which have a well-established or quickly establishing root system to provide a substrate for the growth of the anaerobic microorganisms. The septage should remain in the anaerobic stage for at least one day for the embodiment under discussion.
The second stage of treatment generally occurs in treatment tanks 6-10 and takes place during the third and fourth days for a treatment center of the size and flow rate described above and illustrated in figure l. This stage is characterized by higher dissolved oxygen levels than in the first stage i.e. it is predominately aercbic. In this stage, additional ammonia is removed by the two hacteria, Nitrosomonas and Nitrobacter.
Nitrosomonas oxidizes ammonia to nitrite. Nitrobacter oxidizes the nitrites to nitrates. The overall formula from ammonia to nitrate is according to the chemical formula 2~H3 + 402 become 2NO3- + 2H20+ 2H+. Ammonia, nitrates and soluble orthophosphates are also directly removed from the water by green algae and bacteria growing on the roots of plants.
During the phase of treatment from treatment tanks 6-10, typical BOD levels are reduced to 50-150 mg/l and suspended solids are reduced to approximately 100 mg/l. Also during this stage, snails survive and significantly reduce the sludge volume by eating the sludge and converting some of it into energy, some into tissue and some of it into waste. The treated septage should remain in the aerobic phase for at least one day for the embodiment under discussion.
Turning to Figure 1, approximately 2.5% - 20% of the flow from treatment tank 5, at valve 54, is recycled through pipe 56 to treatment tank 1. This recycling replenishes the microbial community in treatment tank 1, which may have been depleted due to its harsh anaerobic conditions.
The end of the second group of treatment tanks 6-10 is characterized by predominately aerobic activity. In this environment, Aerobacter oxidize~ carbohydrates and short chain organic acids to carbon dioxide (CO2) and water (H2O).
Cellulomonas converts cellulose to soluble carbohydrates which it then uses for growth as a cell constituent and energy source.
Other bacteria also use the produced carbohydrates.
Higher plants in the aerobic stage, treatment tanks 6-10, take up pollutants as nutrients.~ Certain higher plants (including Phragmites) take up nitrates preferentially, if certain other nutrients, such as potassium and soluble orthophosphate are present in the correct ratio. The nitrates are taken up directly and incorporated into the tissue of the plants. At this stage, faster growing plants that can rapidly remove nutrients are used.
The root systems of these plants also reach deep into the treatment tanks and support a large population of grazing animals, 13~692~
particularly snails. Snails also eat and remove suspended solids in this manner. Phosphorus is also removed during this phase, being directly taken up by the plants and animals, being converted into tissue. By treatment tank 10, ammonia (NH3) has been reduced to approximately 4 mg/l.
Turning now to the operation of the marsh, the marsh 22 is used primarily to kill unwanted bacteria and viruses and to remove heavy metals and certain toxic organic compounds. Profusely rooted plants, such as Phragmites communis are used to provide passage ways through the sand for the passage of water. As has been mentioned above, Scirpus lacustrus (bulrushes), Iris pseudacorus (yellow flag) and Typha spp (cattails) create an environment that is hostile to bacteria and also to certain viruses. Certain plants, particularly Alnus glutinosa, have nodules, known as rhizomes, along their roots. These rhizomes are the home of the bacteria Rhizobium, which fixes nitrogen (i.e., removes N directly from N2 molecules in the air) and also produce an antibiotic, which kills certain other bacteria. Rhizobium are also found in many leguminous plants.
These marsh plants 90 (Fig. 3) are also capable of preferentially taking up into their tissue certain metals and also toxic organic compounds. Absorption of heavy metals into fast growing plants does not present a waste disposal problem, because the plants grow so fast that the metals do not concentrate at a 133~92~
dangerous level. U.S. Patent No. 3,770,623, to Seldel, identifies many different useful plants and thelr functions.
In addition, the plants transfer oxygen gas (2) from their leaves g2 to the root system g4. This activity provides additional aeratlon used by microorganisms remaining ln the system that break down organlc compounds. Denitrifi-catlon, i.e., the reduction of nltrates (N03) to free Nitrogen (N2) and water, continues in the marsh through the mechanism of metabolism. The environment of the marsh varies by virtue of depth. ~ertain parts 96 are aerobic and deeper zones 98 are anaeroblc. At these stages, nitrates (N03) are converted into nitrogen gas (N2) by actlon of bacteria.
If heavy metals present a significant problem, special marsh plants known as "hypoaccumulators" should be provided. Hypoaccumulators selectively accumulate specific metals in a concentration high enough so that the metals may be smelted from or refined from the plants according to known methods. Examples of hypoaccumulators are umbrella plant and some species of willow plants, both of which accumulate toxic aluminum.
The effluent from the marsh ls passed through T-valve 72 (Figure 1). A pump 73 recycles a portion of the marsh effluent through pipe 74 back to the input of treatment tank 1. Approximately 2.5% - 20% of the effluent should be recycled. Thls 6695~-24 133692~
provides another route for microorganism replenishment as ciscussed above. The remaining effluent from the marsh is pumped by oump 73 through pipe 76 to treatment tank 11.
Treatment tanks 11-20 principally provide for polishing of the treated wastewater. By "polishing", it is meant that the water quality is improved to a fine degree and that additional nutrients are removed. Snails and fresh water clams in these sections continue to digest sludge and are in turn eaten by the fish, including small-mouthed bass and river trout. In the experimental Harwich septage system described above, ammonia (NH3) is reduced by treatment tank 20 to less than 1 mg/l and phosphorus is reduced to less than 10 mg/l. Total Kjeldahl nitro~en is educed to less than 10 mg/l. Suspended solids are reduced from over 500 mg/l to less than 10 mg/l and BOD is reduced from over 1,000 mg/l to less than 10 mg/l. Fecal coloform are reduced to below 100, less than 99% of influent and total coloform was ~educed to below 1,000, also less than 99% of influent. It is beneficial for the treated septage to remain in this polishing section for at least three days, for the embodiment under discussion.
The fish in the last several treatment tanks reduce the plankton population and are also used as water quality indicators.
Generally, if the water quality is poor, the fish will evidence symptoms that will help diagnose the problem.
13369~4 It is also beneficial to maintain the ratio of carbon, in the form of calcium carbonate, to the combined ammonia and nitrate concentration in a predetermined r~nge. For the system discussed above, it has been discovered that this ratio is 7-to-1. This ratio should be maintained in the first treatment tank of the first plurality of treatment tanks. For instance, if calcium carbonate is present at 210 mg/l and the combined ammonia and nitrates amount to 30 mg/l, the system should perform adequately.
The ratio tends to reduce as the system operates and thus limestone must be added to increase the calcium carbonate content.
In addition to calcium carbonate, sodium bicarbonate can be used to increased alkalinity. Sodium bicarbonate acts more quickly than does calcium carbonate.
With respect to the general operation of the system, of course, variations in plant and animal placement may arise. The general rule of thumb is that if an organism survives in a certain _ocation, it should be used there and if it does not, then it should not. If it survives, this means that it is extracting what it requires as nutrients from the water. If it does not survive, then it is not getting what it needs and thus, is not performing any useful water treatment function. One can think of treatment of wastewater as harvesting nutrients from the water, using the 1336g2~
plants, animals and bacteria as collectors. If they survive, then they must be removing pollutants. Variations of environment with ~he seasons will generally require variation in plant location.
Because conditions are not always apt for the survival of all plants, animals and microorganisms, the diversity in the system tends to decrease over time. Thus, the plant, animal, and microbial species must be replenished periodically to maintain diversity. Plant species can be observed visually and thus need only be replenished when the diversity is observed to have diminished. With respect to bacterial and other microbial diversity, a periodic regimen should be adopted.
In colder climates, it is necessary to insulate the system from cold. This can be accomplished by building a conventional greenhouse around the system. A greenhouse 100 is shown schematically in Fig. 4, surrounding six modules 84 of treatment tanks and marshes, as discussed above. Normal greenhouse technology should be applied. Additionally, the treatment tanks provide a thermal capacitance which helps regulate the temperature. Further, the photosynthetic bacteria trap light energy. The chemical reactions mediated by the bacteria are, on balance, exothermic (i.e. they give off heat), and thus the treatment tank temperature is maintained without a need for externally applied heat, from sources other than the sun or the artificial lights, if used. As has been mentioned above, the 133692~
capacity of the system is largely limited by the absorptive and ~ransmissive properties of the wastewater with respect to light.
~s noted above, it is possible to increase the capacity somewhat by increasing the height of the treatment tanks. It is also possible to use supplemental artificial light for natural light embodiments, such as the axially located light source embodiment discussed above. This increases the capacity of the system by a factor o approximately four. Further, the system is relatively straight forward to set up and may be considered as a modular element of a larger system having many similar modules. As many modules as are necessary to fully treat a municipality's wastewater may be provided. The system described above, which is capable of treating at least 1,200 gallons a day, occupies a space of approximately 1,200 ft.2 The configuration of the system may be altered, for instance by providing a U-shaped marsh, by placing all of the treatment tanks in a single file, dividinq the treatment tanks up into two or three ranks, etc. The possibilities are virtually limitless.
It is also sometimes beneficial to rearrange the order of the marsh with respect to the treatment tanks. For instance, in treating wastewater that has high levels of heavy metals, the marsh can be introduced earlier in the system. Further, in order to accommodate varying seasonal pollutants, the marsh could actually be mobile, on a sma-ll railroad car-type setup.
l33~924 Alternatively, because the marsh is simply connected to the wastewater treatment tank stream through plumbing, the plumbing can easily be rerouted at various times during the year in order to customize the particular Elow then needed. It may be beneficial to add a second marsh stage 122 after the final treatment tank stage of the system 8~, to sterilize the water (Figure 12).
It is also possible to introduce the components of the system, in particular the treatment tanks, into any stage of a conventional waste treatment system, so long as chemicals introduced by the waste treatment system are not introduced at a stage in the natural system that will kill the natural constituents.
Finally, variations in light and temperature during operation of the system are beneficial, in that the variation allows for a varying habitat for the various organisms living in the system.
Some function well in lighted environments and some in dark.
Thus, the daily application of natural sunlight alternating with unilluminated periods of night time darkness are beneficial.
~urther, some organisms function better in cooler (or warmer) conditions than do others. The experimental ~arwich system experienced daily temperature fluctuations of at least 20F, within the overall range of form 50F to 100P, with beneficial esults.
133692~
The foregoing description shall be considered to be illustrative and shall not be considered limiting in any way.
Variations within the scope of the invention will be understood by those of ordinary skill in the art. Having thus described the invention, what is claimed is:
Claims (15)
1. An apparatus for removing pollutants from water comprising:
A) a series of tanks containing water which includes organisms for removing pollutants from the water, wherein each of said tanks comprises a bottom and light-transmitting sides and transmits energy into the water substantially throughout its entire volume;
B) means for connecting said tanks in series such that water can be transferred along said series of tanks from a first tank to a last tank;
C) means for inputting water containing pollutants to the first tank; and D) means for outputting water from which said pollutants have been removed from the last tank;
wherein series of tanks further comprises:
a) a first tank or plurality of tanks containing polluted water and bacteria for removing at least some of the pollutants from the water;
b) a second tank or plurality of tanks connected in series with said first tank or plurality of tanks containing non-aquatic plants capable of removing at least some of the pollutants from the water, and a support for maintaining the non-aquatic plants at the surface of the water; and c) a third tank or plurality of tanks connected in series with said second tank or plurality of tanks containing polluted water and fish capable of removing at least some of the pollutants from the water.
A) a series of tanks containing water which includes organisms for removing pollutants from the water, wherein each of said tanks comprises a bottom and light-transmitting sides and transmits energy into the water substantially throughout its entire volume;
B) means for connecting said tanks in series such that water can be transferred along said series of tanks from a first tank to a last tank;
C) means for inputting water containing pollutants to the first tank; and D) means for outputting water from which said pollutants have been removed from the last tank;
wherein series of tanks further comprises:
a) a first tank or plurality of tanks containing polluted water and bacteria for removing at least some of the pollutants from the water;
b) a second tank or plurality of tanks connected in series with said first tank or plurality of tanks containing non-aquatic plants capable of removing at least some of the pollutants from the water, and a support for maintaining the non-aquatic plants at the surface of the water; and c) a third tank or plurality of tanks connected in series with said second tank or plurality of tanks containing polluted water and fish capable of removing at least some of the pollutants from the water.
2. The apparatus of claim 1, wherein at least one of the tanks is cylindrical.
3. The apparatus of claim 2, wherein the cylindrical tank has a maximum diameter of 2 m.
4. The apparatus of claim 1, wherein at least one tank has an oval cross-sectional shape.
5. The apparatus of claim 4, wherein the tank has a maxi-mum minor axis of 2 m.
6. The apparatus according to any one if claims 1 to 5, further comprising a light-transmitting roof under which said series of tanks is disposed.
7. The apparatus according to any one of claims 1 to 5, further comprising means for providing artificial light to water contained in at least one of the tanks.
8. The apparatus according to any one of claims 1 to 5, wherein at least one of the tanks comprises support means for supporting a plant above the surface of the water contained in said at least one tank while allowing roots of the plant to extend into the water.
9. The apparatus according to any one of claims 1 to 5, further comprising marsh including sand between said second and said third tanks with plants growing therein capable of removing heavy metals from water.
10. The apparatus according to any of claims 1 to 5, wherein the water contained in at least one tank in said series of tanks comprises microorganisms including bacteria, protocists, fungi, plants and animals, non-aquatic plants, or higher animals including zooplankton, phytoplankton (algae), fish, and mollusks.
11. A method for treating water comprising:
A) connecting a plurality of tanks each capable of holding water in series such that water can be transferred along said series of tanks from a first tank to a last tank, wherein each of said tanks comprises a bottom and light-transmitting sides so that energy may be transmitted to substantially the entire volume of water contained therein;
B) stocking said tanks with water and organisms for removing pollutants from the water;
C) inputting water containing pollutants to the first tank;
D) outputting water from which at least some of said pollutants have been removed from the last tank;
wherein the method includes the steps of:
a) stocking a first tank or plurality of tanks containing polluted water with bacteria for removing at least some of the pollutants from the water;
b) stocking a second tank or plurality of tanks connected in series with said first tank or plurality of tanks with non-aquatic plants capable of removing at least some of the pollutants from the water, and providing a support for maintaining the non-aquatic plants at the surface of the water; and c) stocking a third tank or plurality of tanks connected in series with said second tank or plurality of tanks with fish capable of removing at least some of the pollutants from the water.
A) connecting a plurality of tanks each capable of holding water in series such that water can be transferred along said series of tanks from a first tank to a last tank, wherein each of said tanks comprises a bottom and light-transmitting sides so that energy may be transmitted to substantially the entire volume of water contained therein;
B) stocking said tanks with water and organisms for removing pollutants from the water;
C) inputting water containing pollutants to the first tank;
D) outputting water from which at least some of said pollutants have been removed from the last tank;
wherein the method includes the steps of:
a) stocking a first tank or plurality of tanks containing polluted water with bacteria for removing at least some of the pollutants from the water;
b) stocking a second tank or plurality of tanks connected in series with said first tank or plurality of tanks with non-aquatic plants capable of removing at least some of the pollutants from the water, and providing a support for maintaining the non-aquatic plants at the surface of the water; and c) stocking a third tank or plurality of tanks connected in series with said second tank or plurality of tanks with fish capable of removing at least some of the pollutants from the water.
12. The method of claim 11, further comprising recycling water between tanks in said series of tanks.
13. The method of claim 11 or 12, further comprising aerating water in at least one of the tanks.
14. The method of any one of claims 11 or 12, further comprising agitating water in at least one of the tanks.
15. The method of claim 13, further comprising agitating water in at least one of the tanks.
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US266,732 | 1988-11-03 | ||
US07/266,732 US5087353A (en) | 1988-11-03 | 1988-11-03 | Solar aquatic apparatus for treating waste |
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CA1336924C true CA1336924C (en) | 1995-09-05 |
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CA 614367 Expired - Fee Related CA1336924C (en) | 1988-11-03 | 1989-09-28 | Solar aquatic method and apparatus for treating waste |
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EP (1) | EP0442946B1 (en) |
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1988
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1989
- 1989-09-28 CA CA 614367 patent/CA1336924C/en not_active Expired - Fee Related
- 1989-10-30 WO PCT/US1989/004861 patent/WO1990005118A1/en active IP Right Grant
- 1989-10-30 EP EP89912938A patent/EP0442946B1/en not_active Expired - Lifetime
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1991
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US5389257A (en) | 1995-02-14 |
EP0442946B1 (en) | 1993-12-29 |
WO1990005118A1 (en) | 1990-05-17 |
DE68911931T2 (en) | 1994-07-07 |
EP0442946A4 (en) | 1991-10-30 |
EP0442946A1 (en) | 1991-08-28 |
DE68911931D1 (en) | 1994-02-10 |
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