CA1280282C - Method and apparatus for controlling the gas content of dispensed hot melt thermoplastic adhesive foam - Google Patents

Abstract

METHOD AND APPARATUS FOR CONTROLLING
THE GAS CONTENT OF DISPENSED HOT
MELT THERMOPLASTIC ADHESIVE FOAM

Abstract of the Disclosure A method and apparatus for controlling the gas content of dispensed hot melt thermoplastic adhesive foam. Air or another relatively inert gas is mixed with molten thermoplastic adhesive, and the mixture is pressurized to form a gas and molten adhesive "solution". When the molten adhesive and gas "solution" is dispensed at atmospheric pressure, the gas is released from "solution" and becomes entrapped in the adhesive in order to form a homogeneous closed cellular adhesive foam. In order to control the gas content of the dispensed adhesive and gas "solution"
in accordance with one preferred embodiment, the pressure drop across a restriction in the flow path of the solution is sensed, and a control circuit controls the addition of gas to the adhesive to maintain the sensed pressure drop at a desired level. Other sensing techniques can be used to measure a parameter of the dissolved gas/molten adhesive single phase liquid solution which is correlated to the dissolved gas content of the solution and substantially indepen-dent of the molten adhesive content thereof, such as measuring the transmittance of infrared radiation through the gas/adhesive single phase solution at a wavelength relatively heavily absorbed by the gas and unabsorbed by the adhesive.

Description

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. _ _ ...... . . ...... _ . _ _ _ _ . _ _ _ _ _ _ This invention relates generally to hot melt thermoplastic adhesive dispensing systems and, more particularly, concerns systems for dispensing hot melt thermoplastic adhesive foam. The invention is more specifically related to such systems in which the gas content of the hot melt adhesive foam is controlled.
Hot melt thermoplastic adhesives are used in a number of applications such as packaging and product assembly. If the hot melt adhesive is applied as a cellular foam rather than as a non-foamed adhesive, ' certain improved characteristics are obtained, such as increased bonding strength and a longer "open" time during which the adhesive retains its bonding strength after being applied to a substrate. The details of a - - ~LZ802~

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number of hot melt thermoplastic adhesive foam systems - are set forth in U.S. Patents No. 4,059,466 to Scholl et al, No. 4,059,714 to Scholl et al, and No. 4,200,207 to Akers et al, all commonly assigned herewith.
In an exemplary foamed hot melt adhesive system, a dual stage gear pump supplies an adhesive and gas solution to an adhesive dispenser, or gun.
The gun contains a valve at an outlet nozzle through which the solution is dispensed to atmospheric pres-sure. When the solution is dispensed, the gas is released from solution to become entrapped in the adhesive to form a foam on a substrate to which the adhesive is applied.
. In the foregoing description, and throughout this specification and the claims, the term "solution"
is used to describe the liquid adhesive/gas dispersion supplied under high pressure to the gun, which disper-sion when dispensed from the gun at atmospheric pressure cools and creates a foamed adhesive. The applicants are of the view that this mixture is a true solution in which the molecules of the dissolved yas are dispersed among those of the liquid adhesive. The term "solution", though, as used in the specification and the claims of the application is intended to encompass the broader generic definition of solution which is a gas homogeneously mixed with the molten liquid adhesive, whether or not the molecules of the . .

. .
dissolved gas are in fact dispersed among those of the solvent.
- In the above-mentioned exemplary dual stage gear pump system, adhesive is supplied from a hot melt ^ 5 adhesive source to the f:irst stage of the gear pump, : and a suitable gas, such as nitrogen, carbon dioxide, or air, is introduced at the inlet of the second stage ~; of the pump together with the adhesive discharged from the first pump stage. Typically, the pump capacity of the second stage is greater than that of the first stage, such as by a factor of 50~, so that the gas is substantially drawn into solution with the adhesive.
. :.
: When the adhesive and gas solution is output from the second pump stage, it is coupled to the gun for dispensing through the gun valve.
In order to permit continuous operation of ` the pump, and to facilitate homogeneous mixing of the gas with the adhesive, when the gun valve is closed, the adhesive and gas solution is recirculated from the gun back to the inlet of the first pump stage.
Preferably, when the gun valve is open for dispensing the adhesive and gas solution, a portion of the solution (such as 75~, for example) is recirculated.
New raw adhesive is introduced at the first pump stage inlet as necessary to replace adhesive dispensed from the gun. A recirculation valve is present in the recirculation loop in order to establish the degree of recirculation. In one form of foamed hot melt system, ' ~

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the recirculation valve is a pressure reyulator which maintains the adhesive and gas solution at the gun at a constant pressure.
In the above-described system, if the adheslve and gas solution is recirculated for a period of time with the gun valve closed, gas continues to be introduced into the adhesive, so that the gas content of the adhesive increases. If the gas content of the ~; adhesive and gas solu-tion is allowed to increase without limit, the quality of the foamed adhesive from :' .
the dispensing gun can become unacceptable. In some cases, during dispensing of a very high gas content adhesive solution, gas may be released from the adhesive at the nozzle causing sputtering.
In order to avoid the problems caused by the presence of excess gas in the hot melt adhesive and gas solution, it has been proposed to control a gas ' valve in the gas line between the gas supply and the ' adhesive pump. This control valve is turned off whenever the gun is turned off, stopping the flow of gas to the pump.
' The gas content of the adhesive and gas ~;
solution decreases, however, when the system is in a strictly recirculation mode, with the gun valve and the gas valve closed, due apparently to gas leakage from the pump, such as along the pump shafts and at the inlet to the first pump stage. It has, therefore, also been proposed in the past to open the gas valve .

~80Z~32 occasionally when the gun i5 ofE for exte~ded periods of time in order to keep the gas content of the solution from becoming too low.
In this prior control system, which is disclosed in the commonly assigned Patent No. 4,405,063 to Wydro et al, the gas valve is also opened during initial start-up of the foamed hot melt adhesive system, such as for the first two or three minutes of system operation.
This prior approach to controlling the gas content of the adhesive and gas solution suffers from the drawback that the gas flow is controlled only to an approximation of the amount necessary to produce .. . .
foamed adhesive of proper quality. Further, even if the quality of such a system is acceptable in steady state conditions, this prior approach does not deal with the difficulties of initializing the hot melt system each time it is operated from a cold start-up condition. Typically, with such a prior system, the operator of the foamed adhesive dispenser must adjust, by observation, various system parameters to obtain the proper foaming of the adhesive which is dispensed i from the gun. For example, the operator may have . adjustments for setting the gear pump drive, control-; 25 ling the cycling of the gas valve, setting the pressure drop of the recirculation valve, and regulating the gas flow rate and pressure. Since adjusting any of these parameters affects the other parameters, initial _5_ '' ' ''' ' " ' :

Zt32 setup of such a foamed ho-t melt system can require several i-terations of adjusting the various system parameters before the desired quality oE hot melt foam is obtained.
It is consequently an object of the present invention to provide a foamed hot melt adhesive system in which the gas content of the adhesive and gas solution is controlled to provide a readily obtainable good quality of dispensed foamed adhesive. It is a related object of the invention to provide such a system in which the setup procedure permits arriving at the optimum quality foamed adhesive easily and ; accurately.
While initially it would appear that measure-ment and control of the gas content of the adhesive and gas solution is relatively straightforward, this is not the case. The hot melt adhesive and gas solution supplied from the adhesive pump outlet to the gun is typically at a high pressure, such as in the 20 range of 800-1,500 psi, and the gas is forced into solution with the adhesive. Due to the pressures involved, a straightforward densitometer reading of the adhesive and gas solution coupled from the pump to the gun yields densi-ty values which vary only a very i 25 small amount over a fairly large range of variations in the gas content of the solution. Stated different-ly, extremely small changes in density of the gas/
molten adhesive solution can produce very large ~LZ~3~2~3~
.; -7-changes in foam density when the gas/molten adhesive solution leaves the dispenser and converts to foam as the gas comes out of solution.
In practice it has been found that a "foam . 5 ratio" of 2-2.5 is desirable, where: foam ratio =
mass of gas/unit volume of solution 1 + 828 mass of adhesive/unit volume of solution, . where the constant, 828, represents the value for A-3 adhesive at atmospheric pressure and 350F. If, for : example, a foam ratio of 2.0 is desired, the percentage ' 10 of gas in the combined gas/adhesive foam will be approximately 0.12~. Thus, it is clear that the ~ contribution of the gas, from a mass standpoint, to . the combined mass of the gas/adhesive foam is very, : very small. As a consequence, if one looks at the density of the gas/adhesive solution, that is, as it leaves the pump and is still under very high pressure : to produce a single phase unfoamed liquid, in an effort to detect variations in density thereof for the .; purpose of controlling the percentage of gas in the: . 20 gas/adhesive solution (and ultimately the foam ratio), it would not be feasible to make a densitometer : . sufficiently sensitive to detect variations in the gas content thereof. Thus, it is clear that direct measurement of the density of the gas/adhesive solu-tion (pressure sufficiently high that have substan-tially single liquid phase with substantially all gas . .;~; dissolved in molten adhesive) is not a realistic : : solution from a practical standpoint.

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Unfortunately, it is not practlcal, i~ not virtually impossible, to monitor the density of the foam as it is dispensed from a ho-t melt dispenser.
While foaming starts in the noz~le of the dispenser, it is not complete until it is deposited in bead form on the surface of the product to which it is being applied. Since the product is often moving at high `: : speed, such as a cereal box top flap moving along a , .;
~` high speed conveyor, it is not really possible to monitor the density of the foam bead deposited on the moving box flap. In other cases, such as in making foam gaskets, the foam is deposited into a channel provided in the surface of the product in which the . .
gasket is formed. It is difficult, if not impossible, to monitor the density of foam located in a channel ~`~ formed in a product.

As a result of the difficulties in measuring density directly, and in accordance with one aspect of . i the present invention, in the present foamed ho-t melt system a measurement is made of a parameter other than density whose value is indicative of the gas content ` of the adhesive and gas solution. More particularly, this invention solves the problem of dispensing uniform density foam, which is a two phase mixture of ; 25 gas and liquid adhesive, by measuring a parameter of -: the single phase gas/molten adhesive solution, other than the density thereof, which is correlated to the dissolved gas present in the single phase unfoamed .

~36)Z~2 _9_ ' gas/molten adhesive solution and substantially incle-pendent of the molten adhesive content thereof. Thus, the density of the unfoamed gas/molten adhesive solu-tion is not measured, but rather some other parameter, such as flow rate of the unfoamed solution, the transmittance of infrared radiation through the unfoamed solu-tion at a wavelength heavily absorbed by - the gas and relatively unabsorbed by the adhesive, which is correlated to the dissolved gas present in the unfoamed single phase gas/molten adhesive solution.
Also, not measured is the density (or any other parameter) of the gas/molten adhesive in its foamed condition which exists at low pressure when the gas comes out of solution with the molten adhesive to give a two phase mixture of gas and molten adhesive.
In accordance with a preferred form of the invention, a measurement is made, in the flow path between the pump outlet and the gun, of the pressure -drop due to the flow of the solution through a restricted orifice in a movable slug in this flow ; path. This pressure drop is proportional to the ; mathematical product of (a) the mass flow rate of the solution from the pump and (b) the viscosity of the solution.
: 25 As will be explained hereafter, the mass flow rate and the viscosity of the solution from the pump are inversely proportional to the percentage of , gas in the solution and consequently the product of : - _9_ .

~28~282 these two quantities is also inversely proportional to the gas content. Therefore, the differentia] pressure which is measured across the restricted orifice slug has a determinable correlation to the gas content of - 5 the solution. This differential pressure is used to control a valve in the gas line from the gas source to the pump in order to control the addition of gas to the solution on a closed loop servo control basis. As the gas content of the solution falls, the pressure ; 10 differential at the slug sensor increases, and a control circuit coupled to the sensor activates the valve in the gas line to add gas to the solution.
In a typical foamed ho-t melt system, the hot melt adhesive is supplied to the first stage of a two stage gear pump through gravity feed from a heated, unpressuri~ed, adhesive tank. Consequently, the - pressure at the inlet to the first stage of the gear pump is only slightly above atmospheric pressure.
Since the adhesive and gas solution from the outlet of the second stage of the pump is recirculated to the . . ..
first stage inlet, through a restriction device or pressure regulator, the pressure of the solution in the portion of the recirculation path from the regu-lator to the return inlet at the first stage of the pump is at a relatively low pressure.
In employing a pressure drop slug sensor~ as described above, it has been observed that the predom-inant variable related to the pressure drop at the --10-- `

~8 [12~2 sensor is the mass flow rate of the adhesive and gas solu-tion. Apparently the reason for this is that due . : to the low pressure in the recirculation path between the regulator and the inlet of the first pump stage, the recirculated adhesive is partially "foamed"; the gas is beginning to come out of solution due to the .. relatively low pressure at the pump inlet. Therefore, : the amount of adhesive mass that is "bitten off" by . the first stage of the gear pump is less than the amount which would be drawn in from a pure raw adhesive -;j source. The first stage of the gear pump is, in ; effect, a metering stage since no more adhesive mass can be introduced through the pump than that introduced at the first stage inlet. Thus, and assuming constant pump speed, the mass flow rate through the gear pump, and exiting the second stage of the gear pump, decreases ; as the gas content increases. More gas can, however, be introduced at the inlet to the second pump stage.
As the percentage of gas in the ho-t melt . 20 adhesive and gas solution (exiting the second stage outlet of the pump) increases, the mass flow rate of the pump decreases, for a constant pump speed. The outlet pressure produced by the pump, such as in the above-mentioned range of 800-1,500 psi, is sufficient at the outlet of the second pump stage to maintain -the . gas in a compressed form in solution in the adhesive, and the density of the solution does not change substantially with changes in gas content. However, ~2~3~28~

there is a variation in the mass flow rate of the pump which is produced by the metering action at the first stage where almost-"foamed" adhesive is recirculated to the first stage inlet. It is presently believed that, in observed forms of ho-t melt adhesive systems constructed in accordance with the present invention, the effect of the just-described flow rate variation upon the pressure differential at the slug sensor is about four to five times or more than the effect of viscosity changes.
Due to the employment of the pressure ` differential slug sensor in the presently illustrated hot melt system, the system can be readily set up for .` optimum foamed adhesive production regardless of lengths of time during which -the gun valve is closed ; and the adhesive solution recirculated. To do this, the operator runs the system with the gun open to ~; obtain a desired foamed adhesive output in an initial : run, as selected by observation of the dispensed 20 foamed adhesive. The pressure drop across the -': restricted orifice slug is measured and noted or ;: electronically stored at this time. Subsequently, when the gun is off, a servo system coupled from the sensor to a gas line valve utili~es this stored pressure drop value to control the flow rate of gas ; into the solution in order to maintain the pressure . .
differential at the optimum value stored earlier during dispensing of adhesive solution from the gun.

-13- 128~Z~2 The precise manner in which the gas valve is controlled is subject to choice. For example, an on/off system may be used wherein a reduction of the differential pressure across the slug beyond a certain amount results in activation of the gas valve to introduce more gas into the adhesive and gas solution at the :~
inlet to the second pump stage. Alternatively, a proportional control may be used in order -to minimize overshoot and undershoot about the selected differen-,~ . .
. 10 tial pressure, which would otherwise be produced by "hunting" of the control.
It should be noted that when such a servo loop is employed for controlling the gas flow rate, the need for precise gas pressure regulation and gas : 15 flow rate measurement is eliminated. Since the gas - flow rate control servo loop operates to provide the requisite gas content of the solution, regardless of the particular gas supply pressure or valve opening, . there is no need to precisely measure the flow rate, for example, by using a precision meter.
The differential préssure at the slug sensor : is affected not only by factors related to the gas content of the hot melt solution, but also by factors which are not so related. Variation of the pump speed - 25 alters the flow rate of the adhesive and gas solution .: in a manner generally unrelated to the gas content of ; the solution. Variation of the temperature of the ;` solution alters the viscosity of the solution in a . ., ' .

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manner generally unrelated to the gas content of the solution.
In one version of the present invention, a ; closed loop system is provided in which the pressure drop across a restricted orifice sluq is sensed on a continuous basis and in which the "set point" pressure drop is changed to a new optimum value if the pump ; speed or the adhesive temperature changes. ~ne way to calibrate this type of system is to use a control - 10 circuit or microprocessor and to conduct one or more initial "teaching" runs to establish the operating ; parameters of the system. Thereafter, if the pump speed or the temperature should change, the control circuit calculates, or interpolates from a set of tabular values, the requisite "set point" differential pressure needed to maintain the gas content of the - adhesive and gas solution at the desired level.
In initializing such a control system, the hot melt pump is operated at a cer-tain speed, such as in a "fast" mode, and the pressure drop of the ; restricted orifice slug and the hot melt solution : temperature are noted when the properly foamed hot melt adhesive is dispensed. The pump speed is than reduced to a "low" speed and a new pressure differen-tial and adhesive temperature measured at this alter-native operating condition. The two pump speeds and their related pressure drops are used to approximate a linear relationship of pressure drop versus pump ~::

12~213~

speed. sased upon this approximated relationship, interpolation be-tween the measured points can be used to select the appropriate "set point" pressure drop for other purnp speeds.
The temperature of the hot melt solution changes when the pump speed changes due to the differ-ence in required energy input into the hot melt solution to move the solution a-t the different flow - rates resulting from the different pump speeds. For example, in some systems, a temperature differential ; attributable to a pump speed change in the range of 20-25F has been observed. -There is a known exponential relationship ~: between the viscosity of the adhesive and gas solution and the temperature of the solution. This relationship is taken into account in the present system to compen-sate for viscosity changes with temperature, and their -consequent effect upon the pressure differential sensed by the restricted orifice slug sensor. Depend-ing upon the degree of accuracy required, the pump speed versus pressure drop relationship may be adjusted based upon the known relationship between viscosity - and temperature, or the effect of such viscosity changes may be approximated.
In accordance with a further embodiment of the invention, the sensor includes a source of infrared radiation having a specified wavelength substantially absorbed by the gas and substantially unabsorbed by :

- the adhesive material, and a detec-tor for detecting radiation at the speciEied wavelength emerging from the substantially single phase unfoamed gas/molten adhesive single phase liquid solution when irradiated ; 5 by the IR source. Further included are sampling means defining a sample flow path for passing a sample of the substantially single phase unfoamed molten adhesive and gas solution between the infrared radiation source and detector. The sampling means preferably includes i lO a body having inlet and outlet ports between which is . "! connected an intermediate sample flow region. The intermediate sample flow region has a cross-sectional flow area defined by a width and by a height which is substantially smaller than the width to minimize the ~ 15 pressure drop across the intermediate sample flow - region. The inlet and outlet ports and said inter-, mediate sample flow region collectively comprise the sample flow path. The infrared radiation source passes infrared radiation along a radiation path `` 20 through the intermediate sample flow path to the detector in a direction approximately parallel to the height thereof to maximi~e transmission of infrared ; radiation from the source through the intermediate sample flow region to the detector, enhancing the signal-to-noise ratio.
Preferably, the radiation path through the intermediate sample flow region has a width measured parallel to the width of the intermediate sample flow 128~02~32 region cross-sectional area which is substantially less than, and approximately centered relative to, said width of said intermediate sample flow region cross-sectional area. This minimizes sampling errors due to effects at the edges of said intermediate sample flow region.
The sampling means further comprises a heater for heating the body to a temperature approxi-mating the temperature of said molten adhesive material output from said adhesive supply means, and a pair of - slightly spaced windows of solid state material transmissive to the infrared radiation located within - the body along the radiation path on opposite sides of, and adjacent to, the intermediate sample flow region. The body has a substantial thermal mass to avoid rapid temperature changes adjacent the radiation windows to minimize the risk of subjecting the windows to thermal shock.
, In practice, the windows and the body have -- 20 significantly different coefficients of thermal expansion. A layer of resilient sealant resiliently : mounts the windows in sealed relation to the body to accommodate thermally-induced dimensional changes between the body and windows, and seal the windows relative to the body to prevent seepage therebetween ; of the pressurized dissolved gas/molten adhesive : single phase liquid solution flowing in the inter-. ~ . .
mediate sample flow region.

18 12~0Z~Z

Other objects and advantages of the inven-tion, and the manner of their implementation, will become apparent upon reading the following detailed description and upon reference to the drawings, in which:
- Figure 1 is a diagrammatic illustration of an embodiment of an improved adhesive foam dispensing ; system in accordance with the present invention;
. - Figure 2 is a diagrammatic illustration of a .- 10 first pressure differential sensor for the system of Figure l;
Figure 3 is a diagrammatic illustration of : an alternative pressure differential sensor for the system of Figure l;

Figure 4 is a diagrammatic illustration of a servo control loop for the system of Figure l;
. . Figure 5 is a diagrammatic illustration of an alternative control loop for the system of Figure . l; ''.

Figure 6 is an idealized graphical represen- ;-tation of the relationship between hot melt solution flow rate and the percentage of gas in the hot melt adhesive and gas solution;
. Figure 7 is an idealized graphical represen-tation of the relationship between the hot melt - viscosity and the percentage of gas in the hot melt , adhesive and gas solution.
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- Figure 8 is a vertical cross-sectional view of a still further embodiment of a sensor for measuring a parameter of the dissolved gas/molten adhesive ~ single phase liquid solution which is correlated to the dissolved gas content of the solu-tion and substan-tially independent of the molten adhesive contentthereof.
Figure 9A is a cross-sectional view along 10 line 9A-9~ of Figure 8.
. Figure 9B is a cross-sectional view along line 9B-9B of Figure 8.
. Figure 10 is a plot of infrared transmit-. tance vs. radiation wavelength for an unfoamed molten adhesive containing substantially no gas.
Figure 11 is a plot of infrared transmit-tance vs. radiation wavelength for a substantially single phase liquid solution of carbon dioxide dis-solved in molten adhesive.
Figure 12 is a plot of IR absorbtivity vs.
radiation wavelength for single phase liquid solutions of carbon dioxide gas dissolved in molten adhesive having different dissolved gas concentrations, and thus different foam ratios.
Figure 13 is a idealized plot of the output of an infrared detector (transmittance) vs. time for a sensor of the type shown in Figures 8 and 9 when used to monitor the dissolved concentration of carbon ` -20- 128~2~2 dioxide in molten adhesive for a single phase solution - having a foam ratio of approximately 1.5.
While the invention is susceptible to various modifications and alternative forms, certain , 5 illustrative embodiments have been shown by way of example in the drawings and will herein be described ; in detail. It should be understood, however, that it is not intended to limit the invention to the particu-lar form disclosed, but, on the contrary, the intention - lO is to cover all modifications, equivalents, and :;alternatives falling within the spirit and scope of .:the invention as defined by the appended claims.
: - , .
iWith initial reference to Figure 1, a foamed ;
hot melt adhesive dispensing system arranged in accordance with the present invention includes a . .
two-stage gear pump 11 having a first stage 12 and a i'' .
second stage 13. Each stage includes oppositely rotating and meshed gear pairs 12a, 12b, and 13a, 13b, ` lrespectively. The driven gears 12a, 13a of each stage `20 are connected by a common drive shaft 14 and the idler : .-gears 12b, 13b of each stage are connected by a common idler shaft 16. Molten hot melt adhesive is introduced from a hot melt source 17, typically by gravity feed at atmospheric pressure, into the low pressure inlet 18 of the first stage 12 of the gear pump. The adhesive is delivered at the outlet 19 of the first stage 12 at a metered rate, and the adhesive is introduced into the inlet 21 of the second stage 13 of . '. ,'.

~.

-21- 1~2~2 the pump 11. Gas is supplied from a gas source 22 into the inlet 21 of the second stage 13 of the pump 11 through a gas line 23 The gas may be, for example, nitrogen, air, or carbon dioxide, and the gas is supplied in the line 23 th~ough a gas valve 24, the operation of which will be described in more detail - hereinafter.
The gas from the line 23 and the adhesive from the outlet 19 of the first pump stage 12 are : ; 10 intimately mixed in the second stage 13 of the gear :;~ pump ll. This mixing places the gas and the adhesive , under such pressure that the gas goes into solution with the molten adhesive to provide a molten adhesive ~ and gas solution. This solution is ejected from the ; 15 outlet 26 of the second stage 13 of the pump 11 and coupled through a filter 27 to a valved adhesive dispensing gun 28.
A recirculation path 29 couples the adhesive and gas solution from the outlet 26 of the pump 11 to the inlet 18 of the first stage 12 of the pump.
During normal operation of the system, the solution of adhesive and gas from the second stage outlet 26 is `:~ coupled through the filter 27 and the body of the ,, .;
,: dispensing gun 28, via a pressure regulator 31 and the : - .
recirculation line 29, to the inlet 18 of the first ; stage of the pump. The gun 28 lncludes a valve 32 ; which is opened and closed -to dispense the adhesive and gas solution onto a substrate. A portion, such as ~, , .

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for example 75%, of the solution is recirculated through the regulator 31 and the path 29 when the gun valve 32 is open, and the other 25% of the flow from the pump is dispensed through the gun. When the gun valve 32 is closed, all of the adhesive and gas . solution from the outlet 26 of the pump 11 is recircu-. lated through the recirculation path 29, with the pressure regulator 31 ma:intaining the pressure at the gun 28 at a substantially constant level in a range 10 of, for example, 800-1,500 psi.
In the event of a blockage beyond the outlet 26 of the second stage 13 of the pump, such as in the filter 27 or the gun body 28, the resultant pressure : buildup at the outlet 26 results in the opening of a pressure relief valve 33 in a pressure relief path 34 which couples the solution from the pump outlet to the .. recirculation line 29.
In accordance with the present invention, a parameter of the adhesive and gas solution is sensed and used to control the flow of gas through the valve 24. In the illustrated form of the invention, a sensor 36 is positioned in the flow path of the : solution between the filter 27 and the gun 28. A
: control circuit, indicated generally as 37, is respon-sive to the sensor 36 to open and close the gas valve 24.
As shown in Figure 2, in one illustrated form of the invention the sensor 36 takes the form of ~L2~ 282 a transducer, or differential pressure measuriny device, 38 in the flow line of the adhesive and gas solution. The device 38 includes a movable slug 39 positioned in the solution flow path and having an orifice 41 therethrough. The pressure drop across the slug 39 due to flow through the restricted orifice 41 is proportional to the gas content of the adhesive and gas solution. The transducer device 38 further includes a spring 42 for opposing movement of the slug 39 in the direction of flow of the solution. One end of the spring 42 bears against a suitable stop 43 in -the flow conduit, and the other end of the spring 42 bears against the slug 39. At a constant flow rate, the position of the slug is a function of the pressure drop across it. This pressure drop is in turn a function of the gas content of the solution. There-fore, by monitoring the position of the slug, an indication of the gas content of the adhesive and gas solution is obtained.
In a steady state condition, there is a net force urging the slug 39 downwardly, as shown in Figure 2, due to the pressure differential across the slug. In this steady state condition, the downward force is balanced by an opposing spring force produced by the compressed spring 42. Since the spring force increases with the compression of the spring 42, by an amount dependent upon the spring constant, the position of the slug 39 is indicative of the spring force, and ~;

-24- l~d~ O 2 8 2 of the opposite but equal force due to the pressure differential across the slug 39.
As shall be discussed in more detail herein-: after, as the gas content of the adhesive and gas solution increases, the pressure drop across the slug , 39 decreases. As the pressure differential decreases, i , . ~ the slug 39 moves upwardly, as shown in Figure 2, untensioning the spring 42 until the spring force -~
again balances the force on the slug produced by the 10 pressure differential. `
This movement of the slug 39 dependent upon the pressure differential may be employed with a . . .
`~: control system 44, as illustrated in Figure 2, to : , - ~ regulate the gas content of the adhesive and gas - 15 solution. The control system 44 includes an electri-cally conductive probe 46, the tip of which extends : into the flow channel 35 of the hot melt solution.

The flow channel 35 is electrically conductive as are , .. .
the slug 39 and the spring 42. The channel 35 is connected to an electrical ground, and the probe 46 is inserted through the wall of the channel 35 inside a suitable electrically insulating fluid seal 47.
The control system 44 further includes a `~ resistor 48 coupled between a voltage source +V and the probe 46. The side of the resistor 48 connected to the probe 46 is also coupled to an electrically . .:
controlled valve 49, such as a solenoid valve, embody-ing the valve 24 of Figure 1 in the gas line. When ~ .

~Z~ 2 the slug 39 contacts the probe 46, the probe is electrically grounded through a circuit path including the slug 39, the spring 42, and the conduit 35. When the slug 39 is not in contact with the probe 46, the probe is at a po-tential established by the voltage source +V, and this voltage is coupled to the solenoid valve.
-~In operation, when the gas content of the adhesive and gas solution is below a selected maximum : 10 level, the slug 39 is spaced apart from the probe 46, and voltage is applied to the solenoid valve 49. The - solenoid valve 49 is in turn activated by the applied voltage to an open condition wherein gas is coupled from the gas source 22 to the gear pump 11. Once the gas content of the solution has risen to the selected level, the slug 39 moves upwardly, into contact with the probe 46, grounding the probe and removing the applied voltage from the solenoid valve 49. The valve then closes, stopping the flow of gas from the gas 20 source to the pump. ;-As the adhesive and gas solution is dispensed through the valve 32 of the gun 28 (Figure 1), the gas : content of the solution decreases due to the introduc-tion of raw hot melt adhesive from the hot melt source 17 into the system. Even in the absence of operation -of the gun 28, due to gas leakage the gas content of the solution decreases. When the gas content of the adhesive and gas solution has decreased sufficiently .: :
-25- ;

-26- ~Z~Z~2 to increase the pressure drop across the slug 39, the slug moves downwardly out of contact with the probe, and the solenoid valve 49 is again activated to add -~ gas to the solution. The sensor 38 and the control system 44 shown in Figure 2 consequently serve as a closed loop servo control to maintain a desired gas concentration in the adhesive and gas solution of the hot melt system 10.
A further improvement in the control tech-! 10 nique may be obtained if the position of the slug is : sensed continuously. In this case, a measure of the . slug position is used to control the gas content of the solution on a continuous basis, such as through .: the use of a proportional controller. In implementing . 15 such a control system, it can be shown that the pressure differential across the slug 39 is related to : the mass flow rate m' of the hot melt solution through the conduit 35, and the viscosity u of the adhesive . and gas solution, by the following expression:
ZO ~1) Pl P2 Km In this expression, K is a constant of proportionality, . and Pl-P2 is the pressure drop across the slug 39. As . shown in idealized form in Figures 6 and 7, the mass flow rate m' and the viscosity u, such as are sensed ; 25 by a differential pressure sensor in the conduit 35, . l each decrease as the percentage of gas in the adhesive and gas solution increases. Consequently, viewing the .. relationship of Equation 1, since the pressure differen-. .

-tial is proportional to -the produet of m' and u; the . differential pressure also decreases as the percentage of gas in the solution increases. The differential : . -. pressure across the slug 39 is also related to the .~ ................ 5 slug position by the following expression:

t2) Pl - P2 = kx/A

In Equation 2, k is the spring constant of the spring 42, A is the cross-sectional area of the conduit, and .`................ x is the displacement of the slug in a direction -to .-' 10 compress the spring, measured from the point at which the slug is in contact with the spring but before the , .; .
spring is compressed. In practicing the present . control technique, the term "A" is, as stated, the ; cross-sectional area of the conduit. In theory, for :............... 15 greater precision than is presently required, the term ... "A" would represent an area slightly less than the - . cross-sectional area of the conduit due to fluid flow . . between the slug and the conduit wall.
The position of the slug may therefore be . . 20 related to the flow rate m' and the viscosity u of the solution, and hence to the percentage of gas in the solution, by the expression:
(3) x = (K/k)Am'u Therefore, if means are provided to monitor the slug position x, a signal indicative of this position can be used to control the flow rate of the gas from the gas source 22 to the gear pump 11 in the system 10 of :.. ; Figure 1.
.
. -27-~28~82 An illustrative system for accomplishing such control is shown in Figure 3. In Figure 3, the conduit 35, the slug 39, the orifice 41 in the slug, the spring 42, and the spring stop 43 are present as in the sensor arrangement of Figure 2. However, in Figure 3, the differential pressure sensor 50 includes a pick-up coil 51 wrapped around, and electrically insulated from, the conduit 35, with a tap and the ends of the coil 51 being electrically connected to a slug position sensing circuit 52. A variety of sensing circuits 52 may be employed, typically including circuitry which produces a slug position signal based upon inductance variations in the coil 51. The inductance of the coil 51 changes in dependence upon the position of the slug 39, which acts as a movable "core" for the coil. Exemplary magnetic core position sensing arrangements for use in fluid flow measurement are shown, for example, in U.S.
Patent No. 2,~36,614 to Godbey and U.S. Patent No.
3,931,737 to Conkling et al. Alternatively, the position of the slug 39 could be determined by optical or capacitive pick-ups or the like.
In the control arrangement illustrated in Figure 3, the actual slug position signal developed by the slug position sensing circuit 52 is coupled on a line 53 to a gas valve control circuit 54. The gas valve control circuit 54 also receives a desired slug position signal, such as from a potentiometer or '~' sd/sp -28-~L~28~)2B2 switch setting. This desired slug position setting is selected by the system operator based upon a trial run ; of the hot melt system wherein an acceptable quality foamed hot melt adhesive is dispensed at that setting.
The gas valve con-trol circuit 54 then con-trols the solenoid valve 49 to regulate the input of gas from the gas source 22 to the pump 11 as the ho-t melt system operates, whether the adhesive dispensing gun , valve is open or closed.
;; 10 The control system 50 is shown in the form of a servo control diagram in Figure 4. The gas valve control circuit 54 comprises a summing junction and a ; controller which operates the gas valve 49. The response of the system to the gas from the gas valve ; 15 49 is represented by the transfer function 55. As the actual position x of the slug 39 varies from the desired position, the control circuit 54 regulates the flow of gas through the gas valve 49 to return the slug to the desired position.
~- 20 In implementing the control systems of Figures 2 and 3, it is necessary to maintain the temperature of the hot melt adhesive solution and the - speed of the pump constant. In this way, variations in flow rate and viscosity are substantially due only to variations in the gas content of the adhesive and : gas solution. In some cases, i-t may be desired to - operate the pump at different speeds, such as in running the hot melt system 10 in a gear-to-line mode.
:
: -29-, .
..... :, ~ .... .. .

~,8~2 In a gear-to-line mode, the pump is operated at a speed related to the speed of movement of substrates past the dispensing gun, which speed varies. If the pump speed is varied, the amount of shear work per-formed on the hot melt adhesive material varies, and -- this in turn causes variations in the temperature of - the material.
With reference to the pressure differential sensor 50 of Figure 3, for example, and assuming Hagen-Pouselle flow through the slug 39, the differen-tial pressure may be stated as:
14) Pl - P2 = (8uLm')/(aR ) In this expression, u is the viscosity of the adhesive and gas solution, L is the length of the slug 39, m' is the mass flow rate of the solution, a is the effective cross sectional area of the orifice 41 of the slug 39, and R is the radius of the orifice 41.
The pressure differential across the slug 39 is also equal to the spring force divided by the effective 20 area upon which the pressure works: -`
(5) Pl - P2 = (kx)/A
In Equation 5, as in the earlier Equations 2 and 3, k is the spring constant of the spring 42, A is the cross-sectional area of the conduit, and x is the displacement of the slug 39 from a position in which the slug is in contact with the spring and the spring is uncompressed.

,:

~8C~ 2 E`or a material having a constant percentage of gas, the pump ou-tput is proportional to the pump speed:
(6) m' = sw In Equation 6, B is a proportionality constant and w ; is the angular rotational speed of the pump.
~-~ The viscosity-temperature dependence of the adhesive and gas solution may be represented as:

(7) u = u e ~b(T-To) where uO and To are representative of a base condition - of viscosity and temperature, and b is a proportion- ~;
ality constant.
Combining Equations 4, 5, 6, and 7 yields the following expression:

: (8) x = [(8LABu )/(aR2k)]we~b(T-To) In Equation 8, the terms within brackets comprise hardware parameters (L, A, R, k and a), a process parameter (B), and a material parameter (uO). For a given hardware/material configuration, the parameters within the brackets remain substantially constant.
Therefore, the slug position x as a function of temperature and pump speed may be expressed as follows:
(9) x(w,T) = ~x(wO,TO)/wO][w][e ( o)]
In Equation 9, x(wo,To) is the slug position at a reference or "teaching" condition of temperature and pump speed. x(w,T) is the "desired" slug position at some other pump speed and temperature.

Equations 8 and 9 may serve as the basis for hypothesizing control algorithms for the gas control loop. In using Equations 8 and 9, the proportionality constant b may be selected at a nominal value for the particular adhesive employed or as an approximation for the different types of adhesives which might be used. The proportionality constant b may also be .;: .
calculated by measurinq the slug position, temperature, -: and pump speed at a second "teaching" condition.
- 10 Equation 9 may then be solved for b by inserting the '. e observed values of x, w and T at the second "teaching"
- condition of the hot melt system.
As shown in Figure 5, a closed loop servo :~ control which implements Equations 8 and 9 includes a : 15 control circuit 54, a gas valve 49, and a system -transfer characteristic 55 similar to that shown in Figure 4. In the system illustrated in the diagram of Figure 5, however, instead of inputting a selected desired slug position x to the control circuit 54, , 20 circuits 61 and 62 implement Equations 8 and 9 to vary the "desired" x dependent upon system conditions.
.:-The first bracketed term of Equation 9 may be designated M, established from the "teaching"
,:
condition of the system, and the third bracketed term ; 25 of Equation 9, the viscosity-temperature dependence ` term, may be designated f(T). In this case, Equation 9 then becomes:

~10) x(w,T) = Mwf(T) . ;,; .

.... ,~ .. . . ..

-lZ~3~Z~32 As shown in Figure 5, the temperature of the adhesive and gas solution, which may be measured, for example, at the gun 28, is input to the circuit 61 and f(T) determined therefrom. This value is coupled to the circuit 62, which also receives a measure of the pump speed w. In the block 62, the constant K (stored in the circuit 62 from a "teaching" run of the system) is multiplied by the measured pump speed w and the temperature term f(T) to produce the desired slug position signal x. The control circuit 54 uses this "desired" slug position, and the "actual" slug posi-tion, to control the gas valve 49 in a manner to maintain the actual slug position equal to the instan-taneously calculated desired slug position.
The functions of the control circuit 54 and of the circuits 61 and 62 may be combined, for example, in a single microprocessor-based control circuit.
After an operator sets up one or more "teaching"
conditions for the system, the sets of data at these conditions are used for calculating the constant terms stored for the desired slug position calculation. The processor-based control circuit thereafter monitors the adhesive and gas solution temperature and pump speed to continuously adjust the desired value of the slug position x over a range of pump speeds and temperatures in the hot melt adhesive dispensing system. In like manner, other system variables not related to the gas content of the hot melt solution , ::

~L~ao2~2 '';
may be accommodated by appropriate adjustment of the desired slug position value.
. With reference to Figures 8 and 9 a gas concentration sensor utilizing infrared (IR) absorption technology is seen to include a split block 70 oE
substantial thermal mass, such as steel, containing a sample flow path for a single phase liquid solution of carbon dioxide gas dissolved in molten adhesive. The sample flow path includes an inlet port 72, an outlet port 74, and an intermediate sample flow region 76, to ~ be described in more detail hereafter, connected `i between the inlet and outlet ports. The split block 70 includes separable block sections 70a and 70b in : which the inlet ports 72 and 74 are formed, respec-tively. Inlet block 70a includes a conical infrared radiation inlet cavity 78, while the split block 70b includes an infrared radiation outlet cavity 80.
- Cavities 78 and 80 at their inner ends connect to confronting circular bores 82 and 84. Located within the bores 82 and 84 are infrared transmissive windows 86 and 88, respectively, fabricated of suitable material such as calcium flouride. An annular shim 87 having a thickness in the approximate range of .005-.010 ; inches is disposed between the confronting surfaces 70a' and 70b', respectively, of the split blocks 70a and 70b, respectively. ~ssuming the confronting surfaces of the windows 86 and 88 are flush wi-th the surfaces 70a' and 70b', which is preferred, a space is . .

provided between the confronting surfaces of the windows, defining the intermediate flow region 76, having a thickness equal to the thickness of the shim.
The substantially single phase solution of 5 gas dissolved in the heated molten adhesive is input to the inlet port 72 from the pump outlet (not shown in Figure 8) via a suitable conduit 90 whereupon it - flows through a circular bore 72a into an elongated cavity 72b having an approximately square cross section. The cavity 72b is formed by an elongated triangular cross-section cavity section 72b' formed in the surface 70a' of split block 70a and an elongated triangular cross-section cavity 72b'' formed in the surface 70b' of split block 70b. Cavity 72b' and ; 15 cavity 72b'' are in confronting relationship to each - other such that they collectively define the square cross- section elongated cavity 72b. Cavity 72b communicates with the internal flow region 76 located between the confronting surfaces of the infrared transmissive cylindrical windows 86 and 88. Also communicating with the internal flow region 76 is a ; second elongated cavity 74b having a generally square cross section comprising confronting elongated triang-~; ular cross-section cavities 74b' and 74b'' formed in surfaces 70a' and 70b' of split blocks 70a and 70b.
The square cross-section elongated cavity 74b communi-cates with a circular bore 74a formed in block 70b which in turn communicates with outlet port 74.

~Z~3132~32 As a consequence of the foregoing construc-tion, the single phase solution of dissolved gas in the molten adhesive entering inlet port 72 via conduit 90 exits the outlet port 74 to a suitable ou-tlet conduit 94 and ultimately a dispenser via a path which includes circular bore 72a, square cross-section elongated cavity 72b, intermediate flow region 76 a portion of which is between windows 86 and 88, elon-gated square cross-section cavity 74b, and the circular bore 74a. In the course of flowing through the sample :
flow path described, a portion of the flow, namely, that portion of the intermediate flow region co-exten- :
sive with the circular cross-sectional area between confronting circular surfaces of the cylindrical windows 86 and 88, is subjected to infrared radiation from a suitable source 98. In a preferred form, the infrared radiation source 98 is a resistive coil .
through which an electrical current is passed of a magnitude sufficient to heat the coil to a point .
whereat it emits infrared radiation of relatively .
constant intensity. The infrared radiation from the source 98, shown schematically by the arrow 100, passes through window 86 and irradiates the dissolved gas/molten adhesive single phase liquid solution in 25 that portion of the intermediate flow region 76 .
located between windows 86 and 88. The infrared .
radiation from the source 98 which is not absorbed by :
the windows 86 and 88 and the dissolved gas/molten -36- :.

-37- ~Z8~82 adheslve single phase solution in intermediate ~low region 76 exits the split block 70, as shown schemati-cally by the arrow 102. Of course, it is understood tha-t the difference between the incident radiation 100 and the exit radiation 102 is not solely attributable to radiation absorbed by the dissolved gas/molten : adhesive single phase solution flowing in region 76 ` since the IR transmissive windows 86 and 88 are not ; 100~ transmissive to infrared radiation, but do absorb ; 10 a rather small percent of the radiation from the ,~ . source 98 directed along the radiation path described . above. However, the amount of radiation absorbed by . the windows 86 and 88 can be ignored since this does not vary significantly and can therefore be zeroed out or otherwise electrically compensated for such that changes in the percent of incident radiation 100 that :. emerges at 102 can be attributed to absorption by the dissolved gas/molten adhesive single phase solution flowing in region 76.
.; 20 To maintain the heated adhesive input to the ; split block 70 via conduit 90 in a molten condition while flowing through the sample flow path in block 70, a heater 104 is wrapped around the perimeter of ;~
. --the split block. The heater 104 heats the block 70 to .~ 25 a temperature necessary to maintain the dissolved .
.;l gas/molten adhesive single phase solution at the ` , desired temperature to thereby avoid cooling it.
., ' ' .
. -37_ ~
. . ~

-38- 12~ 2 To detect the infrared radiation 102 that has passed through the IR path in the split block 70 across which -the single phase solution flows in sample flow region 76, a suitable IR detector 110, such as a lead selenide pho-toconductor, is provided. The emerging radiation 102 passes through a circular tube 112 to a suitable IR lens 110a which focuses the radiation on the active element (not shown) of the detector 110, providing an electrical output on line 114 correlated to the radiation incident on the detector.
To render the sensor insensitive to changes !in the intensity of the IR emitter 98, aging of the photoconductive detector 110, and other such changes 15 of a gradual nature, an IR dual filter wheel assembly --118 is provided. The filter wheel assembly 118 includes a disc 120 opaque to infrared radiation which is mounted for rotation on a shaft 122 journaled in a -stationary journal mount 124. The disc 120 has a - 20 toothed perimeter which is driven by a suitable pinion 126 mounted to the end of a motor shaft 128 of a stationarily mounted motor 130, preferably at approximately 300 RPM. The disc 120 is provided with a pair of apertures 120a and 120b which are fitted 25 with suitable narrow pass band IR filters 132 and 134.
One of the filters, such as filter 132, passes a narrow band of infrared radiation which is highly absorbed by the gas foaming constituent of the dis--39_ ~28~2~2 solved gas/molten adhesive single phase liquid solution being monitored, but not significantly absorbed by the molten adhesive. For example, if the foaming gas is - carbon dioxide, the filter 132 passes substantially : 5 only radiation in the 4.3 micron wavelength region corresponding to the absorption band of carbon dioxide.
- The filter 134, which is a narrow pass band reference filter, passes radiation in a narrow reference band which is substantially unabsorbed by the gas component and preferably not significantly absorbed by the .
molten adhesive and preferably close to the absorbed band. If the gas is carbon dioxide and the adhesive - is a conventional polyethylenebased ho-t melt adhesive such as EASTABOND A-3 manufactured by Eastman Chemical 15 Co. having a viscosity of 2200 CPS at 350F, the reference filter 134 can be selected to pass substan-tially only radiation in the 4. 5 micron wavelength :; region.
In operation the IR filter wheel assembly 20 118 alternately passes to the detector 110 radiation passing through filters 132 and 134 as these filters alternately pass in front of lens llOa at the rate of once per revolution of the disc 120. When neither filter 132 nor filter 134 overlies lens llOa, the 25 IR-opaque disc 120 is interposed between the lens llOa ..
and the tube 112, blocking the transmission of radia-tion 102 to the detector 110. The detector 110 is preferably substantially equally sensitive to radiation ., - 39 -, ,, ,; . ~ ~ : ., ~2~ 32 -40~

pa~sed by lenses 132 and 134, and under the circum-- stances described provides an electrical output on line 114 as shown in Figure 13. The amplitude of the smaller pulses is correlated to the transmittance of .
the 4.3 micron wavelength IR radiation through the , sample, with the amplitude decreasing as the CO2 concentration increases. The amplitude of larger pulses is correlated to the transmittance of the 4.5 . micron reference IR wavelength through the sample, .' 10 with the amplitude being substantially independent of - ~ C2 concentration in the dissolved gas/molten adhesive : .
; single phase liquid solution.

.: The split block 70, infrared radiation ''l `' ` ~ source 98, filter assembly wheel 98, and detector llO

are encased in a suitable housing 140, which is preferably purged with nitrogen gas to avoid inter-. ference from atmospheric carbon dioxide. An :
insulative shield 141 surrounds the tube 112 to ~ .
protect the filters and detector from heat from the block 70.

- To avoid leakage of the highly pressurized . ~ .
; dissolved gas/molten adhesive solution, which may have a pressure of 1500 psi or more, O-rings 95 and 96 located in suitably provided grooves in surfaces 70a' 25 and 70b' of split blocks 70a and 70b are provided on : either side of the shim 87 along with suitable clamp ; ` means (not shown) designed to clamp the split blocks ~` 70a and 70b in sandwiching relation to the shim 87 to ..

, ~L28~2~1~

compress the O-rings 95 and 96. Additionally, O-rings 92 and 93 are provided around the windows 86 and 88.
To further minimize leakage of the highly pressurized gas/adhesive liquid solution being monitored, the annular space between the cylindrical perimeter of the windows 86 and 88 and the circular bores 82 and 84 are - filled with a suitable sealant 105 and 106, such as room temperature vulcanizable silicone, which forms a - temperature and fluid resistant resilient seal between 10 the windows 86 and 88 and the bores 82 and 84. An advantage of the sealant 105 and 106, particularly the resilient nature thereof, is that it accommodates differing thermal expansion coefficients of the split blocks 70a and 70b and the windows 86 and 88, prevent-ing damage to the windows when the split block is sub]ected to heating and cooling cycles. Located between the outer surfaces of the windows 86 and 88 and annular shoulders 135 and 136 of bores 82 and 84 are annular brass washers 137 and 138, respectively, which afford some cushioning for the windows when the pressurized solution is flowing in sample flow region 76.
~, As shown in Figures 9A and 9B, suitable bolt holes 150 are provided in split blocks 70a and 70b for accommodating bolts 151 used for clamping the split blocks 70a and 70b together. To assure proper angular : orientation of the split blocks 70a and 70b relative .
to each other, alignment holes 152 are provided in .. . :

; -41-.: .,.. - , .: ~

split block 70a opposite suitably positioned alignment holes 152 in split block 70b for accommodatiny align~
ment pins 153.
sy virtue of the fact that the region of minimum flow cross section of the intermediate flow region 76 has a substantial transverse width W (Figures 9A and 9B) due to the elonga-ted nature of the cavities 72b and 74b, wherein W = 2.0" in a preferred form, and a rather small length L, e.g., L = 0.6", the pressure drop between bores 72a and 74a is relatively small, e.g. 50 psi, at an input liquid pressure in conduit 90 of 1500 psi.
To maximize the signal-to-noise ratio the thickness of the intermediate flow region 76 between the confronting surfaces of the windows 86 and 88 has been selected to be relatively small, such as in the approximate range of .005-.010 inches, as noted earlier. In this manner a substantial portion of the incident radiation 100 at the reference wavelength 20 corresponding to filter 134 emerges at 102 after : passing through the dissolved gas/molten adhesive single phase liquid under test which flows in inter-mediate flow region 76.
By reason of locating the windows 86 and 88 at the approximate midpoint of the width W of the sample flow region 76, the portion of the sample flow through which IR is transmitted is at the center of the sample flow path, thereby measuring the fastest 2~32 flowing portion of the sample which enhances response time to changes in gas concentration in the adhesive.
Figure 10 depicts the spectrum of a suitable IR source after passing through the~ windows 86 and 88 when a molten adhesive is flowing through the region 76 of a type which is in a nonfoamed state, that is, does not include gas dissolved in the pressurized molten adhesive liquid. With reference to Figure 10, which is a plot of transmittance vs. wavelength, it is . .:
noted that there is an absorption line at 4.3 microns which is heavily absorbed by carbon dioxide gas and substantially unabsorbed by the adhesive, and a reference absorption line at 4.5 microns which is not ` significantly absorbed by carbon dioxide gas or by the adhesive.
- With reference to Figure 11, a similar IR
spectrum is shown for the same adhesive having substan-; tial carbon dioxide gas dissolved in the single phase molten adhesive liquid solution for the purpose of rendering it highly foamed when applied to a suitable substrate at ambient pressure. It is noted that the transmittance at 4.5 microns for the highly foamable hot melt (Figure 11) is not substantially changed with respect to that shown for the nonfoaming hot melt (Figure 10). However, very substantial absorption has occurred at 4.3 microns due -to the presence of sub-stantial dissolved carbon dioxide gas in the highly pressurized molten adhesive liquid.

~ 2802B2 With reference to Figure 13, a plot of IR
detector output on detector output line 114 vs. time is shown for a moderately foamable hot melt adhesivè. As is apparent, pulses of approximately 1.7 millivolts and 2.5 millivolts are alternately provided, corresponding to the alternate passage of the 4.3 micron and 4.5 micron filters 132 and 134 in front of the detector lens llOa. The magnitude of the detector output pulses corresponding to radiation of 4.3 microns and 4.5 microns incident on detector 110 corresponds to the relative transmittance of infrared radiation at the gas component absorption wavelength of 4.3 microns and the reference wavelength of 4.5 microns, respectively. By monitoring the ratio of the amplitude of the pulse attributable to the reference wavelength transmittance and the amplitude of the pulse attributable to the gas component wavelength transmittance, which is known in the industry as the foam ratio, a measure of the foamability of the dissolved gas/molten adhesive single phase liquid solution can be provided. The relationship of foam ratio (FR) to the transmittance (TR) of the reference IR wavelength (4.5 microns)l and the transmittance (Tg) of the gas absorption IR

wavelength (4.3 microns) is: FR = e R g where A and B are experimentally determined constants.
Using closed loop servo techniques the concentration of the gas dissolved in the pressurized molten adhesive sd/ _44_ ~LX8~2~32 - -45~

liquid can be continuously adjusted to maintain the concentration of gas dissolved in the pressurized - single phase molten adhesive liquid gas/solution at the desired level to assure uniform foamability of the adhesive when applied to a substrate at substantially ambient pressure conditions.
: By virtue of utilizing a split klock 70 of substantial thermal mass, the split block heats up and cools down slowly, preventing sudden changes in temperature at the interface between the IR windows 86 and 88 and the block bores 82 and 84, thereby minimiz-ing problems occasioned by the differing coefficients ;- of thermal expansion of the material from which the windows are formed and the material from which the ; ~ 15 split block 70 is formed.
, Figure 12 is a plot of foam ratio FR vs.
wavelength for foamable adhesives having foam ratios of FR = 1.7, FR = 2.3, and FR = 4 5~ as well as for a nonfoaming adhesive (FR = 0). Note that the trans-mittance for the three foamable adhesives has a substantial peak at a wavelength of 4.3 microns, whereas at this same wavelength the nonfoaming adhesive , has a very small peak. As noted earlier, as the content of the foaming gas, such as carbon dioxide, is increased, the foam ratio measured at the 4.3 micron wavelength line corresponding to the absorption line for carbon dioxide, increases. By monitoring the foam . ; .
~ ratio at the wavelength of maximum absorption by the . ' ` ' .

. .

~X802~32 -~6-gas, a measure of the concen-tra-tion of the gas dis-solved in the pressurized molten adhesive liquid is obtained, enabling the gas concentration to be accur-ately controlled.
The sensors of Figures 2, 3, and 8 and 9 facilitate the measurement of a parameter of the dissolved gas/pressurized molten adhesive single phase ; liquid solution which is correlated to the concentra-tion of the gas dissolved in the substantially single phase solution, but which is substantially independent of the concentration of the mol-ten adhesive in the substantially single phase solution. In the one preferred embodiment of Figures 8 and 9, the sensor detects radiation transmitted through the single phase dissolved gas/molten adhesive liquid solution.
Alternatively, radiation reflected from the single phase liquid solution could be measured in accordance with well known a) cylindrical internal reflection (CIR) technology, such as available from Combustion Engineering, Inc., Process Analytics, Lewisburg, West Virginia, b) fiber optic probe technology available from Guided Wave, Inc., El Dorado Hills, California, and c) on-stream internally reflecting cylinder technology available from General Analysis Corp., Darien, Connecticut. Sensors capable of making the foregoing measurement other than those specifically described herein can be used without departing from the spirit and scope of the invention. For example, -~6-~ 12~31D282 sensors operating on the following principles can be used:
1. Vapor pressure using semipermeable membrane;
2. Dieleetric response (capaeitanee) at an a.e. frequency selected for maximum sènsitivity;

3. Ultrasonic techniques, including sound attenuation and capaeitative sensing of transient - eavitation; and - 10 4. Semieonductor conductivity.
What is claimed i9:

.

~.

, .; ~
:

Claims (5)

1. Apparatus for controlling the gas content of dispensed hot melt thermoplastic adhesive foam comprising:
means for supplying heated thermoplastic adhesive material in a molten state at all outlet;
means for supplying gas at an outlet;
means, coupled to the adhesive material supplying means outlet and to the gas supplying means outlet, for agitating and pressurizing the molten adhesive material in the presence of the gas to force the gas into solution with the molten adhesive material to form a substantially single phase unfoamed molten adhesive and gas solution at an outlet, whereby a dispenser may be coupled to the outlet of the agitating and pressurizing means for dispensing the molten adhesive and gas solution at a reduced pressure so that the gas is released from solution and forms a dispensed adhesive foam;
gas sensing means for sensing the gas content of the unfoamed molten adhesive and gas solution comprising a source of infrared radia-tion having a specified wavelength substantially absorbed by said gas and substantially unabsorbed by said adhesive material, and detecting means for sensing radiation at said specified wavelength, said source directing said radiation into said substantially single phase unfoamed molten adhesive and gas solution and said detecting means sensing said radiation emerging from said substantially single phase unfoamed molten adhesive and gas solution; and means, coupled to the gas sensing means and to the gas supply-ing means, for controlling the flow of gas from the gas supplying means to the agitating and pressurizing means dependent upon said gas sensing means output.

2. The apparatus of Claim 1 wherein said gas means further includes sampling means defining a sample flow path for passing a sample of said substantially single phase unfoamed molten adhesive and gas solution between said infrared radiation source and said detecting means, said sampling means comprising:
a body having inlet and outlet ports between which is connected an intermediate sample flow region, said intermediate sample flow region having a cross-sectional flow area defined by a width and by a height which is substantially smaller than said width to minimize the pressure drop across said intermediate sample flow region, said inlet and outlet ports and said intermediate sample flow region collectively comprising said sample flow path, said infrared radiation source passing infrared radiation along a radiation path through said intermediate sample flow path to said detecting means in a direction approximately parallel to said height thereof to maximize transmission of infrared radiation from said source through said intermediate sample flow region to said detecting means.

3. The apparatus of Claim 2 wherein said radiation path through said intermediate sample flow region has a width measured parallel to said width of said intermediate sample flow region cross-sectional area which is substantially less than, and approximately centered relative to, said width of said intermediate sample flow region cross-sectional area to minimize sampling errors due to effects at the edges of said intermediate sample flow region.

4. The apparatus of Claim 2 wherein said sampling means further comprises:
a heater for heating said body to a temperature approximating the temperature of said molten adhesive material output from said adhesive supply means, and first and second windows of solid state material transmissive to said infrared radiation located within said body along said radiation path on opposite sides of, and adjacent to, said intermediate sample flow region, said body having a substantial thermal mass to avoid rapid temperature changes adjacent said first and second radiation windows to minimize the risk of subjecting said windows to thermal shock.

5. The apparatus of Claim 4 wherein said windows and said body have significantly different coefficients of thermal expansion, said apparatus further comprising:
layer of resilient sealant mounting said windows within said body to resiliently mount said windows in sealed relation to said body -to accommodate thermally-induced dimensional changes between said body and windows and seal said windows relative to said body to prevent the flow therebetween of said solution from said intermediate sample flow region.