CA1270441A

CA1270441A - Sunscreen composition for hair protection

Info

Publication number: CA1270441A
Application number: CA000503267A
Authority: CA
Inventors: Joseph P. Ciaudelli; Elizabeth Brand
Original assignee: Revlon Inc
Current assignee: Revlon Inc
Priority date: 1985-03-06
Filing date: 1986-03-04
Publication date: 1990-06-19
Anticipated expiration: 2007-06-19
Also published as: ES8707663A1; US4567038A; KR860006980A; EP0193932A3; NO169045B; DK100486A; EP0193932A2; IL78054A0; FI83034C; KR900000210B1; CA1270441C; IN164403B; BR8600972A; FI83034B; FI860942A0; NO860836L; JPS61218511A; ZA861564B; IL78054A; AU584173B2

Abstract

ABSTRACT
A sunscreen composition for application to hair is provided comprising a mousse base or concentrate containing a sunscreen agent therein, said mousse base or concentrate comprising a cationic surfactant substantive to hair and a nonionic film-former which in combination with a nonionic surfactant produces foam in the composition and upon application to hair forms a coating thereon.

Description

1 SUNSCREEN COMPOSITIoN ~OR HAIR PROTECTION

This invention relates to new cosmetic compositions for the protection of the hair from the bleaching effect of sunlight and more particularly to sunscreen mousse products for use in protectinq the hair from bleaching by sunlight.
Radiation of light having wavelengths ranging from 2950 A. to 4000 A. produces pigmentation or tanning on the human skin. Light of wavelengths ranging from 2950 A. to 3150 A. of sufficient intensity produces erythema, while light of wavelengths from 3150 A. to 4000 A. produces an apparent direct tanning after exposure of sufficient duration and intensity without an accompanying erythema.
The prior art utilizes sunscreen agents r applied to the skin in suitable formulations, to provide protection against erythema causing radiation and to provide the desired degree of tanning with safety. Sunscreen formulations are generally tailor-made to possess sun protective factors (SP~) ranging from 2 to 15 to provide for various degrees of protection and tanning. The agents used in sunscreen formulations include para-aminobenzoates, benzophenones, cinnamates, salicylates, gallates and mixtures thereof.
Radiation of light having wavelengths ranging from 2950 A. to 4000 A. not only affects the skin but also the hair and may result in physical and chemical changes such as weakened, dry and brittle hair !
structure. The most apparent of these changes is the "bleached" appearance of the hair after exposure to intense sunlight especially during the summer months.

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1 Hair treatment products in the form of shampoos/ conditioners, rinses, setting lotions, permanent wave agents and the like do not provide protection against damage caused by radiation and especially against the bleaching effect.
The present invention addresses this problem by providing sunscreen mousse products which, when applied to the hair, substantially block or reduce the amount of radiation reaching the hair and thereby inhibit the bleaching thereof.
The present invention relates to a sun-screen composition comprising an effective amount of a water miscible sunscreen agent contained in a mousse base or concentrate; said mousse base or concentrate comprises a cationic surfactant which is substantive to the hair by virtue of electrostatic attraction and a nonionic film-former which in combination with a nonionic surfactant produces foam in the composition and upon application to hair forms a coating thereon and thereby provides holding effect to the hair.
The sunscreen ager.ts used in the composition of the present invention must be compatible with the mousse-base or concentrate, i.e. must be at least water miscible and preferably water soluble. In addition, the sunscreen agents should not affect the ideal ` white color of the foam and consistency of the mousse base or concentrate.
The composition of the present invention,

3 in the form of a generally white foam contained in a pressurized container, is useful for conditioning the hair while at the same time protecting the hair ~ ~7~3~

1 from the harmful rays of the sun which tend to weaken, break and bleach the hair. The composition may be used on dry as well as wet hair which has been shampooed or cleaned or at any time when a "wet look" or a custom styling of the hair is desired.
The general formula for compositions of the present invention is as follows:
Ingredients % w/w Sunscreen agent 0.001-15.0 lO Alcohol 2.0 -15.0 Nonionic resin/film-former0.5 -10.0 ~onionic surfactant/emulsifier/
foam producer 0.1 - 2.0 ~ragrance 0.01 - 0.2 15 Protein conditioner 0.01 - 0.5 Water soluble plas.icizer0.1 - 0.8 Cationic surfactant 0.1 - 5.0 Acid to maintain pH at 4.5-6.5 0.001- 1.0 Nonionic surfactant/stabilizer 0.1 - 1.0 ~O ~ater qs. to 100 Sunscreening agents normally used to absorb sunlight are oil miscible and water immiscible.
The sunscreen agent of the present invention must be water miscible and preferably water soluble. Water soluble sunscreen agents of the present invention include: ethoxylated p-amino benzoate (Peg-25 PABA, sold by BASF), diethanol amine salt of p-methoxycinnamic *

acid (Parsol Hydro sold by Givaudan Corp.), 2-hydroxy-

4-methoxy-benzophenone-5-sulfonic acid and disodium 2,2' dihydroxy-4-4'-dimethoxy-5-5'-disulfobenzophenone, p-dimethylamino benzoic acid dimethylamino propyl amine salt, p-dimethylamino benzoic acid diethanol amine salt, and trimethyl 2-hydroxy propyl-p-dimethylamino benzoate ammonium chloride.

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1 other sunscreen agents used in the present invention are those soluble in alcohols and compatible with water, such as 2,4-dihydro~ybenzophenone, 2-hydro~y-4-methoxybenzophenone/ 2,2',4,4'-tetra-

5 hydro~y~enzophenone and 2,2'-dihydroxy-4-4'-dimetho~y-benzophenone.
While the concentration of a sunscreen agent or a mixture of sunscreen agents according to the present invention may be as high as 15% w/w, we prefer to use a concentration from about 0.001% to about 0.5~ and more prefera~ly from about 0.001% to 0.1~. The reason for this preferance is that some sunscreen agents at or about 0.5% w/w or higher may impart an esthetically undesirable color to the mousse formulation.
The preferred alcohol used in the practice of the present invention is ethanol; however, the use of other low molecular weight alcohols is also con-templated, such as n-propanol and iso-propanol.
The preferred nonionic polymer which upon application of the mousse formulation forms a film coating on the hair is a copolymer of vinyl acetate and vinyl pyrrolidone, sold as a liquid in 50~
ethanol as PVP/VAE735. This nonionic polymer used ~5 together with a nonionic surfactant, acting as an emulsifier, such as Oleth 20 (polyethylene glycol ether of Oleyl Alcohol that conforms to the formula C 3(CH2)7 H CH(C 2)7 2( 2 2)n an average value of 20) produces the desired foam 3 consistency and degree of hold characteristic of mousse formulations~

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1 In addition to Oleth 20, other nonionic surfactants may be used, such as: Oleth 10 (polyethylene glycol ether of Oleyl Alcohol that conforms to the formula C333(CH2)7cH=cH(cH2)7cH2(OcH2cH2)noH~
where n has an average value of 10); Steare-th 2 (~olyethylene glycol ether of Stearyl Alcohol that conforms to the formula CH3(CH2)l6c}l2(Ocl32cH2)~oH
where n has an average value of 2); Steareth 20 1 (polyethylene glycol ether of Stearyl Alcohol that conforms to the formula CH3(CH2)l6cH2(OcH2cH2)noH
wilere n has an average value of 20); Polysorbate 20 (mixture of laurate esters of sorbitol and sorbitol anhydrides, conforming generally to the formula OCH2CH2)WOH

~0 (OCH2CH2 ) XOH
CH-(OCH2CH2)yOH ~OI
CH2-(OcH2cH2)zO- (CH2)10 3 where w + x + y + z has an average value ~5 of 20); and Polysorbate 80 (mixture of oleate esters of sorbitol and sorbitol anhydrides, conforming ~enerally to the formula 3o * = trade mark (OCH2CH2)WOH

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/ ( OCH 2 C~I 2 3 XOH
CH- ( CH2cH2 ) yOH o CH2- (OCH2CH2) ZO-c (CH2) 711 CH3 (CH2) 7CH

where w + x + y ~ z has an average value of 20).
As a plasticizer, we prefer to use Dimethicone copolyol (a polymer of dimethylsiloxane with polyoxyethylene and/or polyoxypropylene side chains) sold under various trade names, such as Dow Corning 193 Surfactant (Dow Corning) and Silicone L-720 (Union Carbide). However, other water soluble silicone plasti-cizers may also be used as well.
A catlonic salt which is substantive to the hair by electrostatic attraction is used in the formulations of the present invention. *Quaternium-26 (Minkamidopropyl dimethyl 2-hydroxy-ethyl ammonium chloride) is preferred; however, other cationic salts, such as Quaternium-24 (Decyl dimethyl octyl ammonium chloride) or Quaternium-30 (Isododecylbenzyl triethanol-ammonium chloride) may also be used.
The nonionic surfactant Octoxynol-9 (C8H17C6H4(0CH2CH2)nOH where n has an average value of 9) is used as a stabilizer in the present invention.
In its place, or in admixture therewith other nonionic -surfactants may also be used, such as Octoxynol-7 (Polyethylene glycol (7) oc~yl phenyl ether that *trade marks ... ',.. ... .
`:, ` . '~`
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1 conforms generally to the formula C8H17C8H4(OCH2CH2)nOH
where n has an average value of 7) and octoxynol-10 (Polyoxyethylene (10) octyl phenyl ether that conforms generally to the formula C8H17C6H4(0CH2CH2)n has an average value of 10).
To provide for the desired foam properties, the pH should be maintained at about 4.5 to 6.5 and preferably at 4.5 to 5.5.
The following non-limiting examples illustrate the compositions of the present invention.

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In~redients % w/w 5 2 parts Lusantan-25/l part Parsol Hydro (Ethoxylated p-arnino benzoate/
diethanol amine salt of p-methoxy-cinnamic acid) 13.8 SDA 40 (Ethyl alcohol) 5.0 PVP~VAE735 tCopolymer of vinyl acetate lO and vinyl pyrrolidone) 2.0 Oleth-20 (Polyethylene glycol ether of oleyl alcohol-20 ethylene glycol units) 0.5 ~ragrance 0.l 15 t~ydroly2ed animal protein 0.0l Dimethicone copolyol (Polymer of di~ethylsiloxane with polyoxy-ethylene and/or polyoxypropylene side chain) 0.15 Quat 26 (Mink amido propyl dimethyl 2~
20 hydroxy ammonium chloride - Van Dyk's Ceraphyl 65) 0.25 Citric Acid pH 4.5-5.5 0. no3 Octoxynol 9 (Ethoxylated octylphenol-TritonX-l00, Rohm & Haas) 0.2 ~5 Water ~s,to l00 3o * = trade mark :
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Ingredients % w/~
Hydroxyethyl cellulose 0.225 Benzophenone-9 0.001 Hyd. animal protein 0.010 Steareth-2 0.500 lO Dimethicone copolyol 0.300 Nonoxynol-10 0.150 Polysorbate-20 0.638 Polyquat-ll 2.000 SDA 40B 3.000 Tallo~trimonium Cl 0.500 Polyquaternium-4 0.050 Benzophenone-2 0.001 ~0 PVP/VA Copolymer 6.750 Water q.s. 100 * = trade mark , , .
, Ingredients % w/w Hydroxyethyl cellulose 0.300 Ammonium hydroxide 0.050 Benzophenone-9 0.001 Hydrolyzed animal protein 0.010 lO Nonoxynol-10 0.150 Dimethicone copolyol 0.300 Trimethyl tallow ammonium chloride 0.500 Polyquaternium 11 2.000 15 Polysorbate-20 0.638.
Citric acid 0.050 Palmitoyldimonium hyd.
animal collagen 0.300 20 SDA alcohol 40B 3.000 Benzophenone-2 0.001 Sorbitan sesquioleate 0.362 PVP/VA copolymer (50% in alcohol) 3.000 25 Fragrance 0.200 Water q.s. 100 3o ,, . :~ ' ;; ~;:; ,.
: .. . ..

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1 EXAMPI,E 4 Ingredient ~ w/w Hydroxyethyl cellulose 0.300 NH4OH 0.030 Benzophenone-9 0.050 lO Hydrolyzed animal protein 0.010 Nonoxynol-10 0.150 Dimethicone copolyol 0.300 Tallowtrimonium chloride 0.500 15 polyquaternium-ll 2.000 Polysorbate-20 0.638 Citric acid 0.040 SDA 40B 3.000 Benzophenone-2 0.050 PVP/VA copolymer 5.000 Water q.s. 100 3o , .. ; -,::. . :
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1 EXAMPL~S 5 - 8 Inqredients 5 6 7 8 .
% ~/w % ~J/~ J/W % W/~l Hydroxyethyl cellulose 0.150 0.150 0.150 0.150 NH40H q.s. q.s. q.s. q.s.
Ben2Ophenone-9 0.001 0.001 0.001 0.001 ~yd. animal protein 0.010 0.010 0.010 0.010 Nonoxynol-10 0.150 0.150 0.150 0.150 Demethicone copolyol 0.200 0.200 0.200 0.000 Polyquat-ll 2.000 2.000 2.000 2.000 Polysorbate-20 0.200 0.600 0.600 0.600 Tallowtrimonium Cl 0.400 0.400 0.400 0.400 20 Polyquat-4 0.200 0.200 0.200 0.200 Citric acid q.s. q.s. q.s. q.s.
SDA 40B 3.000 3.000 3.000 3.000 Benzophenone-2 0.001 0.001 0.001 0.001 25 PVP/VA E-735 6.750 6.750 6.750 6.750 Sorbitan sesquioleate 0.200 0.400 0.400 0.400 Laureth-4 ~ 0.250 0~000 0.000 0.000 Steareth-2 0.000 0.000 0.200 0.000 3 Water q.s. 100 q.s. 100 q.s. 100 q.s. 100 * = trade mark . .

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-13- ~ ~ 7 Ingredients 9 10 11 12 13 % w/w % w/w % w/w % ~t/~7 % ~
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Hydroxyethyl cellulose 0.150 0.300 0.300 0.3000.300 NH4OH q.s. 0.030 0.0300.030 0.030 Benzophenone-9 0.001 0.001 0.001 0.0010.001 Hyd. animal protein 0.010 0.010 0.0100.010 0.010 Dimethicone copolyol 0.200 0.300 0.3000.300 0.300 15 Polyquat-ll 2.000 2.000 2.000 2.0002.000 Polysorbate-20 0.200 0.638 0.638 0.6380.638 Polyquat-4 0.050 0.050 0.050 0.0500.050 Citric acid q.s. 0.040 0.040 0.0400.040 20 Nonoxynol-10 0.150 0.150 0.150 0.1500.150 SDA 40B 3.000 3.000 3.000 3.0003,000 Benzophenone-2 0.001 0.001 0.001 0.0010.001 PVP/VA E735 6.750 6.750 6.750 6.7506.750 5 Sorbitan sesquioleate 0.400 0.362 0.0000.000 0.050 Steareth-2 0.000 O.OOG 0.362 0.2000.362 ~ater q.s.100 q.s. 100 q.s. 100 q.s. 100 q.s. 100 , . , ~. ' .
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Inqredients 14 15 16 17 % ~/w % ~I/w % W/~7 % W/W

Hydroxyethyl cellulose 0.150 0.150 0.150 0.150 NH40H q.s. q.s. q.s. q.s.
10 Benzophenone-9 0.001 0.001 0.001 0.001 Hyd. animal protein 0.010 0.010 0.010 0.010 Nonoxynol-10 0.150 0.150 0.150 0.150 `Dimethicone copolyol 0.200 0.200 0.200 0.200 15 PolyqUat-ll 2.000 2.000 2.000 2.000 Polysorbate-20 0.000 0.600 0.600 0.200 Tallowtrimonium Cl 0.400 0.400 0.400 0.400 Polyquat-4 0.200 0.200 0.200 0.200 Citric acid 0.020 0.020 0.020 0.020 Steareth-20 0.850 0.000 0.000 0.000 Polysorbate 85/Tween 185 0.000 0.000 0.000 0.200 25 SDA 40B - 3.000 3.000 3.000 3.000 Benzophenone-2 0.001 0.001 0.001 0.001 PVP/VA E735 6.750 6.750 6.750 6.750 Sorbitan sesquioleate o.boo o;ooo 0.200 0.200 3O Steareth-2 0.150 0.000 0.000 0.000 Sorbitan monolaurate 0.000 0.200 0.200 0.000 Water q.s. 100 q.s. 100 q.s. 100 q.s. lOD

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1 A preferred method of preparing sunscreen compositions of the present invention follows.
Insredients used in this method correspond to ingredients used in Example 2.
Mixture A
50-70 parts of cold water is charged into a manufacturing kettle equipped with variable speed propeller-type or counter rotation/side scraper-type agitation means. While -the water is being agitated, the formula amount of hydroxyethyl cellulose is added, and agitation continues until complete dispersion is obtained. Next, Benzophenone-9, Hydrolyzed animal protein, Steareth-2 and Dimethicone copolyol are added into the kettle while heating the mixture to 60-65C. Heating at 60-65C and agitation continue for at least 30 minutes so that the mixture is uniform and free of lumps. The mixture is next cooled to 40-45C, followed by the addition of Nonoxynol-10, Polysorbate-20 and Polyquat-ll. Slow agitation is maintained while the mixture is cooled at 30-35C.
Mixture B
Into a suitable size side tank are charged the formula amounts of special denatured alcohol, tallowtrimonium chloride, Benzophenone-2 and PVP/VA
copolymer and mixed until the ingredients are dissolved.
Mixture B is transferred into manufacturing kettle containing Mixture A while maintaining continuous slow agitation. The side tank is then rinsed with water sufficient to make the formula amount, and the 3 rinsing is charged into the kettle. The mixture is mixed for at least 30 minutes until uniform bulk is obtained. The pH is checked and, if necessary, is adjusted with citric acid or ammonium hydroxide.

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1 The sunscreen composition is filled into cans and the cans pressurized with propellents using conventional, state of the art techniques.
Formula-tions of the present inventions were tested on human hair by applying the same thereto using methods conventional with mousse applications.
The formulations were found effective both with respect to sunscreen properties and conditioning qualities characteristic of mousse formulations.

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Claims

THE EMBODIMENTS OF THE PRESENT INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. A sunscreen mousse composition comprising by weight:
0.001% to 15.0% of at least one sunscreen agent selected from the group consisting of ethoxylated p-amino benzoate, a diethanol amine salt of p-methoxycinnamic acid, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, disodium 2,2'-dihydroxy-4-4'-dimethoxy-5-5'-disulfobenzophenone, 2,4-dihydroxy-benzophenone, 2-hydroxy-4-methoxybenzophenone, 2,2', 4,4'-tetra-hydroxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, a dimethylamino propyl amine salt of p-dimethylamino-benzoic acid, a diethanolamine salt of p-dimethylamino benzoic acid, and trimethyl-2-hydroxy propyl-p-dimethylamino benzoate ammonium chloride;
0.5% to 10.0% of a nonionic film-former;
0.1% to 2.0% of a nonionic surfactant selected from the group consisting of polyethylene glycol ether of oleyl alcohol having the formula CH3(CH2)7CH=CH(CH2)7CH2(OCH2CH2)nOH wherein n has an average value of 20, polyethylene glycol ether of oleyl alcohol having the formula CH3(CH2)7CH=CH(CH2)7CH2(OCH2CH2)nOH
wherein n has an average value of 10, polyethylene glycol ether of stearyl alcohol having the formula CH3(CH2)16CH2(OCH2CH2)nOH
wherein n has an average value of 2, polyethylene glycol ether of stearyl alcohol having the formula CH3(CH2)16CH2(OCH2CH2)nOH
wherein n has an average value of 20, Polysorbate 20 and Polysorbate 80;
0.1% to 0.8% of a water soluble plasticizer;
0.1% to 5.0% of a cationic surfactant selected from the group consisting of minkamidopropyl dimethyl 2-hydroxy-ethyl ammonium chloride, decyl dimethyl octyl ammonium chloride and isododecylbenzyl triethanolammonium chloride; and q.s. 100% water.

2. The sunscreen mousse composition of Claim 1 wherein the water soluble plasticizer is dimethicone copolyol.

3. The sunscreen mousse composition of Claim 1 or 2 having a pH of 4.5 - 5.5.

4. The sunscreen mousse composition of Claim 1 or 2 wherein the sunscreen agent is present in a concentration of 0.001% to 0.5%.

5. The sunscreen mousse composition of Claim 1 or 2 which contains a nonionic surfactant/stabilizer.

6. The sunscreen mousse composition of Claim 1 or 2 wherein the composition contains ethanol.

7. The sunscreen mousse composition of any of Claim 1 or 2, wherein the nonionic film-former is a copolymer of vinyl acetate and vinyl pyrrolidone.

8. A process for preparing a sunscreen mousse composition which comprises combining by weight, 0.001% to 15.0%
of at least one sunscreen agent selected from the group consisting of ethoxylated p-amino benzoate, a diethanol amine salt of p-methoxycinnamic acid, 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid, disodium 2,2'-dihydroxy-4-4'-dimethoxy-5-5'-disulfobenzophenone, 2,4-dihydroxy-benzophenone, 2-hydroxy-4-methoxybenzophenone, 2,2',4,4'-tetrahydroxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxy-benzophenone, a dimethylamino propyl amine salt of p-dimethylamino-benzoic acid, a diethanolamine salt of p-dimethylamino benzoic acid, and trimethyl-2-hydroxy propyl-p-dimethylamino benzoate ammonium chloride;
0.5% to 10.0% of a nonionic film-former;
0.1% to 2.0% of a nonionic surfactant selected from the group consisting of polyethylene glycol ether of oleyl alcohol having the formula CH3(CH2)7CH=CH(CH2)7CH2(OCH2CH2)nOH
wherein n has an average value of 20, polyethylene glycol ether of oleyl alcohol having the formula CH3(CH2)7CH=CH(CH2)7CH2(OCH2CH2)nOH wherein n has an average value of 10, polyethylene glycol ether of stearyl alcohol having the formual CH3(CH2)16CH2(OCH2CH2)nOH wherein n has an average value of 2, polyethylene glycol ether of stearyl alcohol having the formula CH3(CH2)16CH2(OCH2CH2)nOH wherein n has an average value of 20, Polysorbate 20 and Polysorbate 80;
0.1% to 0.8% of a water soluble plasticizer;
0.1% to 5.0% of a cationic surfactant selected from the group consisting of minkamidopropyl dimethyl 2-hydroxy-ethyl ammonium chloride, decyl dimethyl octyl ammonium chloride and isododecylbenzyl triethanolammonium chloride; and q.s. 100% water.

9. The process of Claim 8, wherein the water soluble plasticizer is dimethicone copolyol.

10. The process of Claim 8 or 9, wherein the composition has a pH of 4.5 - 5.5.

11 . The process of Claim 8 or 9, wherein the sunscreen agent is incorporated into the composition in a concentration of 0.001% to 0.5%.

12. The process of claim 8 or 9, wherein there is incorporated into the composition a nonionic surfactant/stabilizer.

13. The process of Claim 8 or 9 , wherein ethanol is incorporated into composition.

14. The process of claim 8 or 9 wherein the nonionic film-former is a copolymer of vinyl acetate and vinyl pyrrolidone.