CA1265032A - Easily breakable sticking material - Google Patents
Easily breakable sticking materialInfo
- Publication number
- CA1265032A CA1265032A CA000503846A CA503846A CA1265032A CA 1265032 A CA1265032 A CA 1265032A CA 000503846 A CA000503846 A CA 000503846A CA 503846 A CA503846 A CA 503846A CA 1265032 A CA1265032 A CA 1265032A
- Authority
- CA
- Canada
- Prior art keywords
- layer
- breakable
- peel
- adhesive
- sticking material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/08—Fastening or securing by means not forming part of the material of the label itself
- G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
- G09F3/02—Forms or constructions
- G09F3/0291—Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time
- G09F3/0292—Labels or tickets undergoing a change under particular conditions, e.g. heat, radiation, passage of time tamper indicating labels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/26—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer which influences the bonding during the lamination process, e.g. release layers or pressure equalising layers
- B32B2037/268—Release layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2519/00—Labels, badges
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/916—Fraud or tamper detecting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1438—Metal containing
- Y10T428/1443—Aluminum
Abstract
ABSTRACT OF THE DISCLOSURE
An easily breakable sticking material is disclosed which comprises a surface layer, an easily breakable layer laminated on one main surface of the surface layer, a first peel-off layer facilitating peeling of the surface layer off the easily breakable layer, a second peel-off layer formed on a part of the main surface of the easily breakable layer, a covering layer formed on the second peel-off layer side main surface of the easily breakable layer, and an adhesive layer formed on the main surface of the covering layer. When the surface layer is peeled off, only the easily breakable layer where the second layer is formed is peeled off the covering layer. As a result, the easily breakable layer is peeled off and separated from the other parts of the sticking mat-erial and cannot adhere again as in the original laminate.
An easily breakable sticking material is disclosed which comprises a surface layer, an easily breakable layer laminated on one main surface of the surface layer, a first peel-off layer facilitating peeling of the surface layer off the easily breakable layer, a second peel-off layer formed on a part of the main surface of the easily breakable layer, a covering layer formed on the second peel-off layer side main surface of the easily breakable layer, and an adhesive layer formed on the main surface of the covering layer. When the surface layer is peeled off, only the easily breakable layer where the second layer is formed is peeled off the covering layer. As a result, the easily breakable layer is peeled off and separated from the other parts of the sticking mat-erial and cannot adhere again as in the original laminate.
Description
The present invention relates to an easily break-able sticking ma-terial wherein a lower breakable layer is easily broken when a surface layer is peeled off by hand, and specifically relates to a breakable st:icking material sui.table for a lable for p~eventiny re-sticking or the like which is stuck on an article as a price tay or to seal an opening part of a container.
Conventionally, labels for preventing re-sticking used for price tags or the like have been known wherein a proper line of sewing machine holes or the like is formed in advance on the surface base material, and for example, when it is intended to be peeled off at a shop front or the like to be illicitly replaced with another price -tag, it is sep-arated and broken along the line of sewing machine holes or the like and thereby a dishonest.act of peeling can be detected at a glance.
On the other hand, a s-ticking paper which is stuck on an opening part of a container.to indicate.the not-opened state can be easily peeled off,.for example, by taking up a 20. commodity:placed in a show case of a shop front, depending upon the material of the opening part of the package and the method of surface.treatment.thexeof, and then a foreign.sub-stance or~ the llke oan be introduced into the package and thereafter the.sticker can be.stuck so.that the peel-off 25 :condltion cannot be detected, and.therefore just looking at ~the.sticking paper from the outside one cannot detect whether or not the package has already.been opened. .E'or this reason, ~ r , .
the contents of the packaye miyht be chanyed before sale.
For example, a cake in the pclckage miyht be mixed with a toxic substance.
Recently, adhesive labels whlch can indicate a trace of peeliny-off after sticking haviny been widely avail-able.
This type of adhesive label comprises a film with a silicon layer formed on a par-t of the back surface of the film, and then an evaporation layer on which a metal is evaporated is formed on the surface of the silicon layer.
Accordinyly, a part of the evaporation layer is not formed directly on the film due to intervention of -the silicon layer.
Furthermore, a pressure-sensitive adhesive layer is formed on the surface of this evaporation layer, and a release sheet is stuck temporarily on this pressure-sensitive adhesive layer.
This adhesive label is stuck in a manner such that the release sheet is separated and then -the exposed surface of the adhesive coated layer ls pressed onto the opening part of the package. Then, when the adhesive label stuck on the openlng part is peeled off, only the part of the evapor-ation film which is not evaporated directly on the film base material by means of the peel-off agent coated layer remains intact, whlle stuck to the opening part by the adhesive coated film. ~Furthermore, if the opening part iS opened, the~evaporation fllm remaining~there while stuck is cut or torn,~and thereby~the opened state can be detected.
~` However, in such an adhesive label, when the film : . : , ,--~. ~ . : :
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3~2 is peeled off, it is difficult to retain part oE the evapora-tion film on the adhesive coated film, the film being peeled off while adhering intact to the coated film sur~ace, and thereby the formation of characters or the like by means of the remaininy evaporation film cannot be made easily In addition, when the film base material is peeled off, a part of the adheslve coated layer remains on the stuck part of the material to which the label is -to be stuck, ~nd the exposed surEace of the adhesive coated layer is sticky and dust adheres thereto. Thus, this adhesive label has -the dis-advantage described above and also has a sanitary problem.
~ herefore, a principal object of the present inven-tion is to provide a sticking material in respect of which any peeling-off after sticking can be detected and no adhes~
ive appears on the peeled-off.surface, and thereby the sur-face is not sticky.
Accordingly, the inven-tion provides an easily breakable sticking material which comprises a surface layer, a breakable layer laminated on one main surface of the sur-face layer, a first peel-off layer facili-tating peeling of the surface member off the breakable layer, a second peel-off layer formed on a part of the main surface of the breakable layer, a covering layer formed on the second peel-ofE side of the main surface of the breakable layer, and an adhesive layer formed on the main surface of the covering layer, which material meets the requirement:
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wherein a represents ~he adhes~ve force between the first peel-off layer and the bre~kable layer, and b represen~s the adhesive force be~ween the second peel-off layer and the covering layer.
A particular aspect of the inventlon provides an easily breakable sticking material which comprises a surface layer having an upper surface and a lower surface, a first peel-off layer located on the lower surface of said surface layer and having an upper su~face and a lower surface, a breakable layer laminated on the lower surface of said first peel-off layer and having an upper surface and a lower surface, a second peel-off layer formed on a port~on of the lower surface of said breakable layer and having an upper surface and a lower surface, a covering layer formed on the lower surface of said second peel-off layer and on a portion of the lower surface of said breakable layer and having an upper surface and a lower surface, an adhesive layer formed on the lower surface of said coverin~ layer, said breakable layer being formed of a material which is relatively easily breakable compared with the material of said surface layer and said covering layer so that the breakable layer is readily breakable, a first adhesive having an adhesive force "a" between said first peel-off layer and said breakable layer, and a second adhesive having an adhesive force "b" between said second peel-off layer and said covering layer, said adhesive forces a and b satisfying the relationship: a >
b.
Thus, the sticking material is formed in a manner such that the adhesive force between the first peel-off layer and the breakable layer is lar~er than that between the second peel-off layer and the covering layer.
The second peel-off layer is formed on the main surface of the breakable layer with a part thereof lacking, and therefore the adhesive force of each part of the breakable stlcking material stuck on the material to which the label is to be stuck differs between the parts where the second peel-off layer is formed and not formed, and when the `~' :: :
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- 4a -surface member ls peeled off, the breakable layer is broken at the boundary between the part where the second peel-off layer is formed and the part where it is lacking, and the hreakable layer and the covering layer of the part where the second peel-off layer i8 lackin~ remain on the surface of the material to which the label is to be stuck, while the other parts are peeled off the covering layer.
With this arrangement, the breakable layer is torn and separated from the other part and cannot adhere again in the original state, and therefore it can be visually detected that the breakable layer has been separated. ~ccordingly, any peel-off of the sticking material adhering can be detected at a glance, and also whether or not a ~, , , . : , :- . , :
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toxic substance has been mixed into the package can be easily discerned. Furthermore, since the coveriny layer isformed on the whole surEace of the adhesive layer, unlike in conventional cases~ after -the surface me~llber is peeled off, the sticky surEace of the adhesive layer is not exposed, and also no surface member can be stuck again by the adhesive force of the exposed adhesive layer.
Embodimen-ts oE the present invention will now be described, by way of example, with reference to the accom-panying drawings, in which:
Fig. 1 is a cross-sectional view of a label of one embodiment in accordance with the present invention;
Fig. 2 is a cross-sectional view showing a state wherein the above-men-tioned embodimen-t is broken;
Fig. 3 through Fig. 5 are diagrammatic views showing one example of an apparatus for manufacturing a lam-inated sheet;
Fig. 6 is a diagrammatic view showing one example of an apparatus for manufacturing a laminated ma-terial;
Fig. 7 is a diagrammatic view showing one example of an apparatus for-manufacturing a label;
Fig. 8 is a dlagrammatic view showing another method for formlng a breakable layer;
Fig. 9 is a perspectlve view showing a method of utillzing the embodiment oE Figs. 1 and 2;
~ Fig. lO is a cross-sectional view oE another-embod~iment of a label;
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Fig. 11 is a cross-sectional view of the label of Fi.~. 10 in a broken condition;
Fiy. 12 is a diagrammatic view show.ing another example of an apparatus for manufac-turiny a larninated sheet;
and Fig.. 13 is a diagrammatic view showing a still further method for forming a breakable layer.
Referring now to Fig. 1, a label 10 is stuck temporarily on a release sheet 12, being formed by laminating in sequence.an adhesive layer 14, a covering layer 16, a second peel-off layer 18, a breakable layer 20, a first peel~
off layer 22 and a surface layer 24. A printed layer 26 is formed on the surface of the surface layer 24.
The surface layer 24 is formed to prevent the breakable layer 20 from being cu-t or torn, and is stuck temporarily on the breakable layer 20 through the intermediary of the first peel-off layer 22.
In addition, the:surface Iayer 24 is formed of material which is relatively stif and are unlikely to be 20. contracted.by heat, such as polyester.film and nylon filmt paper, synthetic paper and the like, and, as described later, in order that traces of peeling-off can be clearly evident from the surface side of the surface layer 24, it is better to select a transparent or semi-transparent material. By doing so, ~it is readlly.ound that a part of the breakable layer 20 remains on a ma:terial A .(Fig. 2) on which the label is stuck,.and a part.thereof;is peeled off.the material A on :, , , : :
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which the label is stuckl and adheres to the surface layer 24, and thus this is convenient.
~ he first peel-off layer 22 stlcks the surface layer 24 temporarily to the b.reakable layer 20 in a state wherein re-sticking can no-t be effected and thereby makes easier the peeling of the surface layer 24 ofE the breakable layer 20. I,ayer 22 is composed of a peel-off agent layer which is formed by coating with a peel-off agent, for example, silicon resin, fluorene resin, paraffin, wax or the like, and is formed between the surface layer 24 and the breakable layer 20.
The breakable layer 20 is composed of a metallizing film which is formed by vacuum-evaporating an evaporation substance such as aluminum silver, zinc or the like, being a layer having breakable properties which can be broken easily by hand.
This breakable layer 20 may.also be formed, for example,. of a printed layer on which silver is directly printed in place of the metallizing film formed by the above-mentioned vacuum evaporation method. ~ printed film producedby means of UV type ink and other films coated with resins can also be enumerated. However, a relatlvely flexible material ls preferably.used such that~the surface layer 24 does~not~cause peel-off due to restoration -to the origlnal state against the adhesive force of ~this breakable layer 20 when the Label 10 is stuck in a:bent.confiyuration to a bent part.
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Other examples of the breakable layer 20 include resin layers which can be cut.or torn by applylng a rela-tively weak force, for example, a resin layer wh:ich is formed by coating a copolymer resin of vinyl chloride and acrylate wherein metal powder is mixed therewith, such as acrylate copolymer resin and the like.
; The second peel-ofE layer 18 is formed by pattern-coating a peel-off agent such as silicon resin, fluorene resin, wax or the like on a part of the surface of the above-mentioned breakable layer 20. .For example, a pattern such as characters, for example, the words "Already opened", a picture or the like is coated by printing, and, as described later, the pattern appears when the surface layer 24 is peeled off and -the breakable layer 20.is broken, and thereby a layer which is more conformable to the intended use of the label 10 can be formed.
The covering layer. 16, as described later, is a layer.for covering the adhesive layer 14 to prevent.the sticky adhesive layer 14 from being exposed when the surface layer 24 is peeled off. This covering layer 16 is formed, for example, by coatlng urethane resin, EVA resin, PVA, vinylace-tochlor.ide, acrylate or the like, or a resin of the nitrocellulose-, polyamido- or acrylate-family on the surface of the.bre~kable layer 20 where.the second peel-off layer 18 is formed.
The adhesive layer. 14. i5 fqrmed on one ma:Ln.surface of the covering layer 16:and provides.the label lO.with an ~ ~., . :. '.,;: :, '...
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g adheslve force for adheriny to the mate.rial A to which the la~el is to be stuck. Layer 14 is composed~ for example, of an adhesive layer formed by coating a pressure-sensitive adhesive.
On the main surface of this adhes.ive layer 14, the release sheet 12 is stuck -temporarily so as to protect the adhesive layer 14.
When the adhesive force between the firs-t peel-off layer 22 and the breakable layer 20 is d~signa-ted as a, the adhesive force between the second peel-off layer 18 and the covering layer 16 is designated as b, the adhesive force of the adhesive layer 14 is designated as d, the force required for.separating the release sheet 12 of the adhesive layer 14 is designated as c, and the force required for breaking the breakable layer 20 is designated as e, -this label 10 is constltuted.so as to meet the following expres-sion:
c < b < e < a.< d This label 10 is used in a manner such that flrst the release sheet 12 is separa-ted, and for example, as shown in.Fig. 9 A, 9B and~9C, it lS stuck as a price tag or stuck on the opening part o a cake:package by the adhesive layer 14.
:~ Thus, in order.to open ~the opening part of the ~package to which the label 10 is stuck, the stuck label 10 has to.be peeled off and.then the.sealed part opened.
: In this.case, the.breakable layer 20.is stuck~to ' :
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the surface layer 24 through the first peel-off l~yer 22, and the breakable layer Z0 adheres stronyly to the covering layer 16, and at the portion where the second peel-off layer 18 is formed, the adhesive strength is weaker compared with that of -the portion whlch adheres directly to -the covering layer 16. ~ccordingly, as shown in Fig~ 2, while the sur-face layer 24 is being peeled off, the breakable layer 20 is torn along the boundaries between the breakable layer 20 of the second peel-off layer. 18 part and the breakable layer 20 of the part adhering directly to the covering layer 16, and also the main surface of the second peel-off layer 18 and the covering layer. 16 are peeled off, and then a part of the breakable layer 20 (the part where the second peel-off layer 18 is formed):is peeled off the material A to which the label is stuck, while adhering.intact -to the surface layer 24.
The part of the breakable layer 20.where the second peel-off layer 18 is not formed remains intact while adhering to the material A. Accordingly, once the surface layer 24 is peeled off, the.breakable layer 20 is broken at the boundary between the part where the second peel-off layer 18 is formed and -the part where it is not formed, and a situation obtains in which the surface layer 2~ cannot be stuck again to the~surface of the covering layer 16, and the original state cannot.be:restored, and therefore the opened state can be clearly seen at.a glance.
:r-n addition, in the present.specification,.an , ,~
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~L~332 optimum example is enumera,ted in each case, and the sheet, film and equivalents thereof are generally represented as "sheet" or "film". Also, when referred to as "sheet", needless to say, this designates not only the leaf type, but also includes -the roll (~eb) type.
Elereinafter, in order to fur-ther clarify embodi-ments ln accordance with the present invention, Eurther description is made based on one example of a method of manu-facturing a sticking material relating to -the present inven-tion.
Fig. 3 through Fib. 5 are diagrammatic viewsshowing one example of an apparatus for manufacturing a lami-nated sheet 30 used for an embodiment in accordance with the present invention.
This laminated sheet 30 is such that the,first peel-off layer 22, the breakable layer 20, the second peel-off layer 18 and the covering layer 16 are laminated on the main surface of the surface layer 24 in this sequence.
An apparatus lOO,comprises a holding roller 102 for holding a surface-material 24a forming the band-shaped sur-face layer 24 in a r~oll shape. The surface material 24a held by the holding roller 102 is unrolled at one end thereof, and led to a peel-off agent coating apparatus 104.
The peel-off agent coating apparatus 104,is for p~inting ~or coating) a peel-off agent 22a, for example, silicon restn,~,fluorene resin, paraffin, wax or,-the like on one surfa e of the surface material 24a, and comprises two ' ,, ' ~ ~''' " " ' '' ' : ' ' ` '' :' ~ '"' ' ';, '' ' " ' '''. .~':
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rollers 106a and 106b and a reservoir 108, the coating of the peel-off agent 22a beiny effected wh:Lle rotating the rollers 106a and 106b. For the peel-off agerlt coating appar-atus 104, a coating apparatus such as the gravure roll coater, a reverse roll coater or the like may be ernployed, and also a publicly available printer such as an of[.set printer, a screen printer or the like may be employed.
This peel-off agent 22a is led -to a drier 110 com-prising a heater which is installed next, and is dried. In the drier 110, the peel-off agent 22a which is printed (or coated) on the surface material 24a is dried, and forms the first peel-off layer 22.
Thereafter, the surface material 24a on whi.ch the flrst peel-off layer 22 is formed is led to a take-up appara-tus 112.
Subsequently,.the surface material 24a on which thepeel-off agent 22a is thus coa.ted is fed to a laminating apparatus 120 which forms the breakable layer 20.. This laminating apparatus 120 may.be,:for example, a semi-continuous type vacuum evaporation apparatus with a structure employing both the batch system and the con-tinuous take-up system. The structure of -this.apparatus, when roughly clas-sified as to functions, comprises a vacuum tank 122, an internal apparatus provided wi-th a take-up shaft 126, a feed-out shaft 128 and a cooling drum 130 in an upper chamber 124,.an.evaporation source 134 and a~heating apparatus in a lower chamber 132, a vacuum exhaus.ting system 136 and other -. .... . .
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~2~3~dl various meters.
By means of this semi-continuous type vacuum evaporation apparatus, the surface material 24a sent out from the feed-out shaft 128 passes through the cooling drum 130 and a slit and is led to the lower chamber 132, being vacuum evaporated to form the breakable layer 20 on the main surface of the first peel-off layer 22 formed on the surface of the surface material 24a with aluminum,silver, zinc or other metal or metal compound used for an evaporation material. In addition, the surface material 24a returns again to the upper chamber 124 after evaporation, being taken up on the take-up shaft 126.
For other examples of this laminating apparatus, there may be men-tioned, for example, a printing apparatus such as an offset printer and a coating apparatus as shown in Fig. 8.
~ laminating apparatus 220 as illustrated in Fig.
8 is for print-coating a breakable material 20a forming the breakable layer 20 on the surface of the first peel-off layer 22 formed on the surface of -the surface layer 24. The apparatus comprises a main roller 222a and a roller 222b which is lnstalled opposite to this main roller 222a~ ~he lower part of the main roller 222a is immersed lnto the breakable material 20a stored in a reservoir 224, and the breakable material 20a is printed (or coated) by the roller 222b on the surface o~ the~first peel-ofE layer 22 of the s~urface material 24a~pinched by the rollers 22~b and 222b.
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~s mentioned above, this breakable material 20a may comprise inks such as UV type ink and the l:ike, or resins such as synthetic resin containing metal powder and -the like.
Thereafter, the surface material 24a on which the breakable material 20a is printed (or coated) is led, Eor example, to a drier 226 comprisiny a heater. In the drier 226, the breakable material 20a print-coated on the surface material 24a is dried to form the breakable layer 20, -there-after being taken up on a take-up roller 228. A lap of the surface layer 24 on which this breakable layer 20 is formed is fed to a laminating apparatus 140 as shown iJI Fig. 5.
The laminating apparatus 140 as shown in Fig. 5 comprises an apparatus 142 wherein the lap of this surface layer 24 is loaded. The surface layer 24 drawn out from the lap loading apparatus 142 loading this lap is led to a peel-off agent coating apparatus 144. The peel-off agent coatin~
apparatus 144 is for printing ~or coating) a peel-off agen-t 18a, for example silicon resin, fluorene resin, paraffin~, wax or the like, on one surface oE the breakable layer 20, and comprises two rollers 146a and 146b and a reservoir 148, coating the peel-off agent 18a while rotating the rollers 146a and 146b. This peel-off agent 18a is led to a drier 149 comprlsinq a hea-ter. For the peel-ofE agent coating apparatus 144, a coating apparatus such as a gravure roll coaterJ a reverse roll coater or the like may be employed, and also a commercially known prin-ter such as an oEfset printer, a acreen printer or the like may be employed.
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This peel-off ayent 18a which forms the second peel-off layer 18 is printed (or coated) partly on -the sur-face of the breakable layer 20, and the layer 18 is formed, for example, by printing words such as "~lready opened" or the like. The surface layer 24 on which the peel-off agent 18a is coated i5 next fed to a laminate apparatus 150 which laminates a covering material 16a forming the covering layer 16.
This laminating apparatus 150 for the covering material 16a comprises a roller 152 which coa-tes the covering material 16a such as EVA resin or the like. In this laminating apparatus 150, coating is performed while pressing by a roller 154 to laminate the covering material 16a on the surface of the breakable layer 20 on which the peel-off agent 18a forming the second peel-off layer 18 has previously been coated, and the surface layer 24 is fed in a melted state to a cooler 156 which is installed next.
The cooler 156 is for cooling the covering mater-ial 16a. In the cooler 156, the covering ma-terial 16a is cooled and solidified, so as to form the covering layer 16 Thus, on the main surface of the surface layer 24, the laminated sheet 30 is formed in which the first peel-off layer 22, the breakable layer 20, the second peel-off layer 18 and the coverin~ layer 16 are laminated in sequence. This laminated sheet~30 is taken up on a take-up roller 158.
The laminated sheet 30 thus formed is loaded next in a laminating apparatus 160 as shown in Fig. 6, which is a . . , , . . , . j ~
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diagra~natic view showing the laminating apparatus which laminates the adhesive l~yer ]4 on the laminated sheet 30 This laminating appa,ratus 160 comprises a lap loading apparatus 162 loading a lap of the laminated sheet 30 and a lap loading apparatus 164 loading a lap of the release sheet 12.
The release sheet 12 drawn out from tllis lap loading apparatus 164 is led to an adhesive coating apparatus 166 which is a coating appara-tus for the adhesive 14 with the surface of the peel-off agent layer 12a set as the bottom surface in Fig. 6. In this adhesive coating apparatus 166, an adhesive such as -the pressure-sensitive type adhesive or the like is printed (or coated).
The adhesive coating appara-tus 166 coats an adhesive 14a on a peel-off agent layer 12a of the release sheet 12, comprising a main roller 168a and a roller 168b which is installed opposite to -this main roller 168a. Then, the lower part of the main roller 168a is immersed into the adhesive 14a stored in a reservoir 170, and the adhesive 14a is printed (or coated) by the main roller 168a on -the surface of the peel-off agent layer 12a of the release sheet 12 which is pinched by the main roller 168a and the roller 168b.
Then, the release sheet 12 on which the adhesive 14a is printed (or coated) is led to a drier 172 comprising, for example, a heater. In the drier, 172, the adheslve 14a prin-ted (or coated)'on the release sheet 12 is dried to form the adhesive layer 14, and a lamination of the adhesive layer ':`'`
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14 and the release sheet 12 is led to a laminatiny apparatus 174 for the laminated shee-t 3U prepared separately. This laminating apparatus 174 for the laminated sheet 30 ~omprises the lap loading apparatus 162 which loads a lap of the laminated sheet 30. The laminated sheet 30 led out from -this lap loading appara-tus 162 is led between two rollers 176a and 176b, and the surface of the above-mentioned adhesive layer 14 formed on the surface of the release sheet 12 and the covering layer 16 side surface of the laminated sheet 30 are superposed, and are laminated by the pressure of -the two rollers 176a and 176b and the adhesive force of the adhesive layer 14, being taken up on a roller 178 in a laminated sta-te.
In order to make a label with the sticking material thus manufacturad, the laminated sheet has only to be loaded in an apparatus for manufacturing a label comprising a printing apparatus for this laminated sheet and the like.
Fig. 7 is a diagrammatic view showing one example of an apparatus for manufacturing a label.
Such a label manufacturing appara-tus 180 comprises a holding appara-tus 182 which loads a lap of the laminated sheet 30 wherein the peel-off sheet 12 is laminated on the surface of the adhesive layer 14. ~ laminated sheet composed of the release sheet 12 and the laminated sheet 30 drawn out from this hoIding apparatus 182 ifi led to a printing appara-tus 184. This printing appara-tus 184 is composed, for example, of a publicly available printer such as an offset printer or the like. By means of this prin-ting apparatus .~, : :
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184, the printed layer 26 on which a pattern, for example the words "-trade name" or the like, i.s pr:Lnted is formed on the surface of the surface layer 24. ~'he lamlnated sheet on which the printed layer 26 is formed as described above is led to a punclling machine 186. rrhe punchiny machine 186 comprises a so-called die cutter havi.ng a cutting edge, and properly shaped cuts are formed on -the surface layer 24, the first peel-oEf layer 22, the breakable layer 20, -the covering layer 16 and the adhesive layer 14 by means of this die cutter.
In addition, the punching machine 186 may employ a roll with a cutting edge, a so-called die roll.
The laminated sheet on which cuts are formed is divided into a useless part and a plurality of labels 10 (required part) by rollers 188a and 188bt and the useless part is taken up in a roll shape by a stripper roller 190, while the labels trequired part) are taken up in a roll shape by a take-up roller 192 in the state wherein they are stuck temporarily on the release sheet 12. In addition, a cut-forming machine may be installed in place of the punching machine 186 and the take-up roller 192. This cut-forming machine comprises a cutting edge for forming cuts on the surface layer 24, the firs-t peel-off layer 22, the breakable layer 20, the covering layer 16 and the adhesive layer 14 to : 25 make each label plece 10. :.
Specific examples of mater~als in accordance wlth the above embodiment wll] now be given.
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(l) Polyethylene terephthalate film of about 50 in thickness is used for the gurface layer, and a silicon resin is coated on one main surface thereof to form the first peel-off layer, and subsequently in order to form the break-able layer, aluminum is vacuum-evaporated on this first peel-off layer to form a breakable layer of about 7~ in thickness.
A silicon resin manufactured by Iloray Industries, Inc having a peeling force smaller than that of the silicon resin forming the above-mentioned peel-off layer is partly coated on this surface of the breakable layer formed by evaporating aluminum so that the dried coated film thickness is 0.1-5~ and forms the second peel-off layer.
A covering layer is formed on this layer by coating a synthetic resin whose main component is the EVA resin as listed in the following Table 1 to a thickness o-f about 5-50~.
Thereafter, the adhesive layer is formed by coating the acrylate adhesive (BPS-5127) manufactured by Toyo Ink Mfg.
Co. Ltd. so tha-t the dried coated film thickness is 5-50p.
In this case, the adhesive force ~a) between the first peel-off layer and the breakable layer is about 50g, the adhesive force (b) between the second peel-off layer and the covering layer is about 30g, the adheslve orce ~d) of the adheslve layer is about l,OOOg, and the force (c) required for separ-ating the release sheet from the adhesive layer is about 20g.
The pressure-sensitive adhesive material thus constituted was made into a lab~l piece, which was stuck onto~a material to be sealed ~(paper box or the like).
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The adhesive force (d) to the material -to which the label is stuck and ~he adhesive force (d') between the coverin~ layer and -the adhesive layer are about :I,OOOy, res-pec-tively.
When the stuck label piece was peeled forcibly ofE
the material, the brea]cable layer was torn at th~ boundary between the part where the second peel-off layer is formed and the part where it is not formed, and the torn breakable layer was peeled toge-ther with the surface layer off the material to which the label was stuck at -the seco~d peel-off layer portion.
Table 1 Componen-tsComposition Ethylene vinylVinylacetate content 10^50r~ 20^50 1 acetate co- Melt index (MI) 5 500 polymer resin Molecular weight Rosln 10,000 100,00020~60 Elydrogenerated rosin Adhesion- Glycerine resin (0 60) dative resin Polyturpentine resin Turpentine phenol resin G5 group petroleum resin G9 group pe-troleum resin Alicyclic group hydro ~-0 generated petroleum resin Paraffin wax 5 50 Micro wax (5 703 Polyethylene wax Polypropylene wax Para~fin group, Naphthene group resin ~1 5 Hea-t stabilizer : 0 .
Aging preventlng 25 In place of ethylene vinyll~beutane may ~e u resin, SIS
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Conventionally, labels for preventing re-sticking used for price tags or the like have been known wherein a proper line of sewing machine holes or the like is formed in advance on the surface base material, and for example, when it is intended to be peeled off at a shop front or the like to be illicitly replaced with another price -tag, it is sep-arated and broken along the line of sewing machine holes or the like and thereby a dishonest.act of peeling can be detected at a glance.
On the other hand, a s-ticking paper which is stuck on an opening part of a container.to indicate.the not-opened state can be easily peeled off,.for example, by taking up a 20. commodity:placed in a show case of a shop front, depending upon the material of the opening part of the package and the method of surface.treatment.thexeof, and then a foreign.sub-stance or~ the llke oan be introduced into the package and thereafter the.sticker can be.stuck so.that the peel-off 25 :condltion cannot be detected, and.therefore just looking at ~the.sticking paper from the outside one cannot detect whether or not the package has already.been opened. .E'or this reason, ~ r , .
the contents of the packaye miyht be chanyed before sale.
For example, a cake in the pclckage miyht be mixed with a toxic substance.
Recently, adhesive labels whlch can indicate a trace of peeliny-off after sticking haviny been widely avail-able.
This type of adhesive label comprises a film with a silicon layer formed on a par-t of the back surface of the film, and then an evaporation layer on which a metal is evaporated is formed on the surface of the silicon layer.
Accordinyly, a part of the evaporation layer is not formed directly on the film due to intervention of -the silicon layer.
Furthermore, a pressure-sensitive adhesive layer is formed on the surface of this evaporation layer, and a release sheet is stuck temporarily on this pressure-sensitive adhesive layer.
This adhesive label is stuck in a manner such that the release sheet is separated and then -the exposed surface of the adhesive coated layer ls pressed onto the opening part of the package. Then, when the adhesive label stuck on the openlng part is peeled off, only the part of the evapor-ation film which is not evaporated directly on the film base material by means of the peel-off agent coated layer remains intact, whlle stuck to the opening part by the adhesive coated film. ~Furthermore, if the opening part iS opened, the~evaporation fllm remaining~there while stuck is cut or torn,~and thereby~the opened state can be detected.
~` However, in such an adhesive label, when the film : . : , ,--~. ~ . : :
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3~2 is peeled off, it is difficult to retain part oE the evapora-tion film on the adhesive coated film, the film being peeled off while adhering intact to the coated film sur~ace, and thereby the formation of characters or the like by means of the remaininy evaporation film cannot be made easily In addition, when the film base material is peeled off, a part of the adheslve coated layer remains on the stuck part of the material to which the label is -to be stuck, ~nd the exposed surEace of the adhesive coated layer is sticky and dust adheres thereto. Thus, this adhesive label has -the dis-advantage described above and also has a sanitary problem.
~ herefore, a principal object of the present inven-tion is to provide a sticking material in respect of which any peeling-off after sticking can be detected and no adhes~
ive appears on the peeled-off.surface, and thereby the sur-face is not sticky.
Accordingly, the inven-tion provides an easily breakable sticking material which comprises a surface layer, a breakable layer laminated on one main surface of the sur-face layer, a first peel-off layer facili-tating peeling of the surface member off the breakable layer, a second peel-off layer formed on a part of the main surface of the breakable layer, a covering layer formed on the second peel-ofE side of the main surface of the breakable layer, and an adhesive layer formed on the main surface of the covering layer, which material meets the requirement:
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wherein a represents ~he adhes~ve force between the first peel-off layer and the bre~kable layer, and b represen~s the adhesive force be~ween the second peel-off layer and the covering layer.
A particular aspect of the inventlon provides an easily breakable sticking material which comprises a surface layer having an upper surface and a lower surface, a first peel-off layer located on the lower surface of said surface layer and having an upper su~face and a lower surface, a breakable layer laminated on the lower surface of said first peel-off layer and having an upper surface and a lower surface, a second peel-off layer formed on a port~on of the lower surface of said breakable layer and having an upper surface and a lower surface, a covering layer formed on the lower surface of said second peel-off layer and on a portion of the lower surface of said breakable layer and having an upper surface and a lower surface, an adhesive layer formed on the lower surface of said coverin~ layer, said breakable layer being formed of a material which is relatively easily breakable compared with the material of said surface layer and said covering layer so that the breakable layer is readily breakable, a first adhesive having an adhesive force "a" between said first peel-off layer and said breakable layer, and a second adhesive having an adhesive force "b" between said second peel-off layer and said covering layer, said adhesive forces a and b satisfying the relationship: a >
b.
Thus, the sticking material is formed in a manner such that the adhesive force between the first peel-off layer and the breakable layer is lar~er than that between the second peel-off layer and the covering layer.
The second peel-off layer is formed on the main surface of the breakable layer with a part thereof lacking, and therefore the adhesive force of each part of the breakable stlcking material stuck on the material to which the label is to be stuck differs between the parts where the second peel-off layer is formed and not formed, and when the `~' :: :
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- 4a -surface member ls peeled off, the breakable layer is broken at the boundary between the part where the second peel-off layer is formed and the part where it is lacking, and the hreakable layer and the covering layer of the part where the second peel-off layer i8 lackin~ remain on the surface of the material to which the label is to be stuck, while the other parts are peeled off the covering layer.
With this arrangement, the breakable layer is torn and separated from the other part and cannot adhere again in the original state, and therefore it can be visually detected that the breakable layer has been separated. ~ccordingly, any peel-off of the sticking material adhering can be detected at a glance, and also whether or not a ~, , , . : , :- . , :
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toxic substance has been mixed into the package can be easily discerned. Furthermore, since the coveriny layer isformed on the whole surEace of the adhesive layer, unlike in conventional cases~ after -the surface me~llber is peeled off, the sticky surEace of the adhesive layer is not exposed, and also no surface member can be stuck again by the adhesive force of the exposed adhesive layer.
Embodimen-ts oE the present invention will now be described, by way of example, with reference to the accom-panying drawings, in which:
Fig. 1 is a cross-sectional view of a label of one embodiment in accordance with the present invention;
Fig. 2 is a cross-sectional view showing a state wherein the above-men-tioned embodimen-t is broken;
Fig. 3 through Fig. 5 are diagrammatic views showing one example of an apparatus for manufacturing a lam-inated sheet;
Fig. 6 is a diagrammatic view showing one example of an apparatus for manufacturing a laminated ma-terial;
Fig. 7 is a diagrammatic view showing one example of an apparatus for-manufacturing a label;
Fig. 8 is a dlagrammatic view showing another method for formlng a breakable layer;
Fig. 9 is a perspectlve view showing a method of utillzing the embodiment oE Figs. 1 and 2;
~ Fig. lO is a cross-sectional view oE another-embod~iment of a label;
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Fig. 11 is a cross-sectional view of the label of Fi.~. 10 in a broken condition;
Fiy. 12 is a diagrammatic view show.ing another example of an apparatus for manufac-turiny a larninated sheet;
and Fig.. 13 is a diagrammatic view showing a still further method for forming a breakable layer.
Referring now to Fig. 1, a label 10 is stuck temporarily on a release sheet 12, being formed by laminating in sequence.an adhesive layer 14, a covering layer 16, a second peel-off layer 18, a breakable layer 20, a first peel~
off layer 22 and a surface layer 24. A printed layer 26 is formed on the surface of the surface layer 24.
The surface layer 24 is formed to prevent the breakable layer 20 from being cu-t or torn, and is stuck temporarily on the breakable layer 20 through the intermediary of the first peel-off layer 22.
In addition, the:surface Iayer 24 is formed of material which is relatively stif and are unlikely to be 20. contracted.by heat, such as polyester.film and nylon filmt paper, synthetic paper and the like, and, as described later, in order that traces of peeling-off can be clearly evident from the surface side of the surface layer 24, it is better to select a transparent or semi-transparent material. By doing so, ~it is readlly.ound that a part of the breakable layer 20 remains on a ma:terial A .(Fig. 2) on which the label is stuck,.and a part.thereof;is peeled off.the material A on :, , , : :
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which the label is stuckl and adheres to the surface layer 24, and thus this is convenient.
~ he first peel-off layer 22 stlcks the surface layer 24 temporarily to the b.reakable layer 20 in a state wherein re-sticking can no-t be effected and thereby makes easier the peeling of the surface layer 24 ofE the breakable layer 20. I,ayer 22 is composed of a peel-off agent layer which is formed by coating with a peel-off agent, for example, silicon resin, fluorene resin, paraffin, wax or the like, and is formed between the surface layer 24 and the breakable layer 20.
The breakable layer 20 is composed of a metallizing film which is formed by vacuum-evaporating an evaporation substance such as aluminum silver, zinc or the like, being a layer having breakable properties which can be broken easily by hand.
This breakable layer 20 may.also be formed, for example,. of a printed layer on which silver is directly printed in place of the metallizing film formed by the above-mentioned vacuum evaporation method. ~ printed film producedby means of UV type ink and other films coated with resins can also be enumerated. However, a relatlvely flexible material ls preferably.used such that~the surface layer 24 does~not~cause peel-off due to restoration -to the origlnal state against the adhesive force of ~this breakable layer 20 when the Label 10 is stuck in a:bent.confiyuration to a bent part.
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Other examples of the breakable layer 20 include resin layers which can be cut.or torn by applylng a rela-tively weak force, for example, a resin layer wh:ich is formed by coating a copolymer resin of vinyl chloride and acrylate wherein metal powder is mixed therewith, such as acrylate copolymer resin and the like.
; The second peel-ofE layer 18 is formed by pattern-coating a peel-off agent such as silicon resin, fluorene resin, wax or the like on a part of the surface of the above-mentioned breakable layer 20. .For example, a pattern such as characters, for example, the words "Already opened", a picture or the like is coated by printing, and, as described later, the pattern appears when the surface layer 24 is peeled off and -the breakable layer 20.is broken, and thereby a layer which is more conformable to the intended use of the label 10 can be formed.
The covering layer. 16, as described later, is a layer.for covering the adhesive layer 14 to prevent.the sticky adhesive layer 14 from being exposed when the surface layer 24 is peeled off. This covering layer 16 is formed, for example, by coatlng urethane resin, EVA resin, PVA, vinylace-tochlor.ide, acrylate or the like, or a resin of the nitrocellulose-, polyamido- or acrylate-family on the surface of the.bre~kable layer 20 where.the second peel-off layer 18 is formed.
The adhesive layer. 14. i5 fqrmed on one ma:Ln.surface of the covering layer 16:and provides.the label lO.with an ~ ~., . :. '.,;: :, '...
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g adheslve force for adheriny to the mate.rial A to which the la~el is to be stuck. Layer 14 is composed~ for example, of an adhesive layer formed by coating a pressure-sensitive adhesive.
On the main surface of this adhes.ive layer 14, the release sheet 12 is stuck -temporarily so as to protect the adhesive layer 14.
When the adhesive force between the firs-t peel-off layer 22 and the breakable layer 20 is d~signa-ted as a, the adhesive force between the second peel-off layer 18 and the covering layer 16 is designated as b, the adhesive force of the adhesive layer 14 is designated as d, the force required for.separating the release sheet 12 of the adhesive layer 14 is designated as c, and the force required for breaking the breakable layer 20 is designated as e, -this label 10 is constltuted.so as to meet the following expres-sion:
c < b < e < a.< d This label 10 is used in a manner such that flrst the release sheet 12 is separa-ted, and for example, as shown in.Fig. 9 A, 9B and~9C, it lS stuck as a price tag or stuck on the opening part o a cake:package by the adhesive layer 14.
:~ Thus, in order.to open ~the opening part of the ~package to which the label 10 is stuck, the stuck label 10 has to.be peeled off and.then the.sealed part opened.
: In this.case, the.breakable layer 20.is stuck~to ' :
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the surface layer 24 through the first peel-off l~yer 22, and the breakable layer Z0 adheres stronyly to the covering layer 16, and at the portion where the second peel-off layer 18 is formed, the adhesive strength is weaker compared with that of -the portion whlch adheres directly to -the covering layer 16. ~ccordingly, as shown in Fig~ 2, while the sur-face layer 24 is being peeled off, the breakable layer 20 is torn along the boundaries between the breakable layer 20 of the second peel-off layer. 18 part and the breakable layer 20 of the part adhering directly to the covering layer 16, and also the main surface of the second peel-off layer 18 and the covering layer. 16 are peeled off, and then a part of the breakable layer 20 (the part where the second peel-off layer 18 is formed):is peeled off the material A to which the label is stuck, while adhering.intact -to the surface layer 24.
The part of the breakable layer 20.where the second peel-off layer 18 is not formed remains intact while adhering to the material A. Accordingly, once the surface layer 24 is peeled off, the.breakable layer 20 is broken at the boundary between the part where the second peel-off layer 18 is formed and -the part where it is not formed, and a situation obtains in which the surface layer 2~ cannot be stuck again to the~surface of the covering layer 16, and the original state cannot.be:restored, and therefore the opened state can be clearly seen at.a glance.
:r-n addition, in the present.specification,.an , ,~
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~L~332 optimum example is enumera,ted in each case, and the sheet, film and equivalents thereof are generally represented as "sheet" or "film". Also, when referred to as "sheet", needless to say, this designates not only the leaf type, but also includes -the roll (~eb) type.
Elereinafter, in order to fur-ther clarify embodi-ments ln accordance with the present invention, Eurther description is made based on one example of a method of manu-facturing a sticking material relating to -the present inven-tion.
Fig. 3 through Fib. 5 are diagrammatic viewsshowing one example of an apparatus for manufacturing a lami-nated sheet 30 used for an embodiment in accordance with the present invention.
This laminated sheet 30 is such that the,first peel-off layer 22, the breakable layer 20, the second peel-off layer 18 and the covering layer 16 are laminated on the main surface of the surface layer 24 in this sequence.
An apparatus lOO,comprises a holding roller 102 for holding a surface-material 24a forming the band-shaped sur-face layer 24 in a r~oll shape. The surface material 24a held by the holding roller 102 is unrolled at one end thereof, and led to a peel-off agent coating apparatus 104.
The peel-off agent coating apparatus 104,is for p~inting ~or coating) a peel-off agent 22a, for example, silicon restn,~,fluorene resin, paraffin, wax or,-the like on one surfa e of the surface material 24a, and comprises two ' ,, ' ~ ~''' " " ' '' ' : ' ' ` '' :' ~ '"' ' ';, '' ' " ' '''. .~':
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rollers 106a and 106b and a reservoir 108, the coating of the peel-off agent 22a beiny effected wh:Lle rotating the rollers 106a and 106b. For the peel-off agerlt coating appar-atus 104, a coating apparatus such as the gravure roll coater, a reverse roll coater or the like may be ernployed, and also a publicly available printer such as an of[.set printer, a screen printer or the like may be employed.
This peel-off agent 22a is led -to a drier 110 com-prising a heater which is installed next, and is dried. In the drier 110, the peel-off agent 22a which is printed (or coated) on the surface material 24a is dried, and forms the first peel-off layer 22.
Thereafter, the surface material 24a on whi.ch the flrst peel-off layer 22 is formed is led to a take-up appara-tus 112.
Subsequently,.the surface material 24a on which thepeel-off agent 22a is thus coa.ted is fed to a laminating apparatus 120 which forms the breakable layer 20.. This laminating apparatus 120 may.be,:for example, a semi-continuous type vacuum evaporation apparatus with a structure employing both the batch system and the con-tinuous take-up system. The structure of -this.apparatus, when roughly clas-sified as to functions, comprises a vacuum tank 122, an internal apparatus provided wi-th a take-up shaft 126, a feed-out shaft 128 and a cooling drum 130 in an upper chamber 124,.an.evaporation source 134 and a~heating apparatus in a lower chamber 132, a vacuum exhaus.ting system 136 and other -. .... . .
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By means of this semi-continuous type vacuum evaporation apparatus, the surface material 24a sent out from the feed-out shaft 128 passes through the cooling drum 130 and a slit and is led to the lower chamber 132, being vacuum evaporated to form the breakable layer 20 on the main surface of the first peel-off layer 22 formed on the surface of the surface material 24a with aluminum,silver, zinc or other metal or metal compound used for an evaporation material. In addition, the surface material 24a returns again to the upper chamber 124 after evaporation, being taken up on the take-up shaft 126.
For other examples of this laminating apparatus, there may be men-tioned, for example, a printing apparatus such as an offset printer and a coating apparatus as shown in Fig. 8.
~ laminating apparatus 220 as illustrated in Fig.
8 is for print-coating a breakable material 20a forming the breakable layer 20 on the surface of the first peel-off layer 22 formed on the surface of -the surface layer 24. The apparatus comprises a main roller 222a and a roller 222b which is lnstalled opposite to this main roller 222a~ ~he lower part of the main roller 222a is immersed lnto the breakable material 20a stored in a reservoir 224, and the breakable material 20a is printed (or coated) by the roller 222b on the surface o~ the~first peel-ofE layer 22 of the s~urface material 24a~pinched by the rollers 22~b and 222b.
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~s mentioned above, this breakable material 20a may comprise inks such as UV type ink and the l:ike, or resins such as synthetic resin containing metal powder and -the like.
Thereafter, the surface material 24a on which the breakable material 20a is printed (or coated) is led, Eor example, to a drier 226 comprisiny a heater. In the drier 226, the breakable material 20a print-coated on the surface material 24a is dried to form the breakable layer 20, -there-after being taken up on a take-up roller 228. A lap of the surface layer 24 on which this breakable layer 20 is formed is fed to a laminating apparatus 140 as shown iJI Fig. 5.
The laminating apparatus 140 as shown in Fig. 5 comprises an apparatus 142 wherein the lap of this surface layer 24 is loaded. The surface layer 24 drawn out from the lap loading apparatus 142 loading this lap is led to a peel-off agent coating apparatus 144. The peel-off agent coatin~
apparatus 144 is for printing ~or coating) a peel-off agen-t 18a, for example silicon resin, fluorene resin, paraffin~, wax or the like, on one surface oE the breakable layer 20, and comprises two rollers 146a and 146b and a reservoir 148, coating the peel-off agent 18a while rotating the rollers 146a and 146b. This peel-off agent 18a is led to a drier 149 comprlsinq a hea-ter. For the peel-ofE agent coating apparatus 144, a coating apparatus such as a gravure roll coaterJ a reverse roll coater or the like may be employed, and also a commercially known prin-ter such as an oEfset printer, a acreen printer or the like may be employed.
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This peel-off ayent 18a which forms the second peel-off layer 18 is printed (or coated) partly on -the sur-face of the breakable layer 20, and the layer 18 is formed, for example, by printing words such as "~lready opened" or the like. The surface layer 24 on which the peel-off agent 18a is coated i5 next fed to a laminate apparatus 150 which laminates a covering material 16a forming the covering layer 16.
This laminating apparatus 150 for the covering material 16a comprises a roller 152 which coa-tes the covering material 16a such as EVA resin or the like. In this laminating apparatus 150, coating is performed while pressing by a roller 154 to laminate the covering material 16a on the surface of the breakable layer 20 on which the peel-off agent 18a forming the second peel-off layer 18 has previously been coated, and the surface layer 24 is fed in a melted state to a cooler 156 which is installed next.
The cooler 156 is for cooling the covering mater-ial 16a. In the cooler 156, the covering ma-terial 16a is cooled and solidified, so as to form the covering layer 16 Thus, on the main surface of the surface layer 24, the laminated sheet 30 is formed in which the first peel-off layer 22, the breakable layer 20, the second peel-off layer 18 and the coverin~ layer 16 are laminated in sequence. This laminated sheet~30 is taken up on a take-up roller 158.
The laminated sheet 30 thus formed is loaded next in a laminating apparatus 160 as shown in Fig. 6, which is a . . , , . . , . j ~
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diagra~natic view showing the laminating apparatus which laminates the adhesive l~yer ]4 on the laminated sheet 30 This laminating appa,ratus 160 comprises a lap loading apparatus 162 loading a lap of the laminated sheet 30 and a lap loading apparatus 164 loading a lap of the release sheet 12.
The release sheet 12 drawn out from tllis lap loading apparatus 164 is led to an adhesive coating apparatus 166 which is a coating appara-tus for the adhesive 14 with the surface of the peel-off agent layer 12a set as the bottom surface in Fig. 6. In this adhesive coating apparatus 166, an adhesive such as -the pressure-sensitive type adhesive or the like is printed (or coated).
The adhesive coating appara-tus 166 coats an adhesive 14a on a peel-off agent layer 12a of the release sheet 12, comprising a main roller 168a and a roller 168b which is installed opposite to -this main roller 168a. Then, the lower part of the main roller 168a is immersed into the adhesive 14a stored in a reservoir 170, and the adhesive 14a is printed (or coated) by the main roller 168a on -the surface of the peel-off agent layer 12a of the release sheet 12 which is pinched by the main roller 168a and the roller 168b.
Then, the release sheet 12 on which the adhesive 14a is printed (or coated) is led to a drier 172 comprising, for example, a heater. In the drier, 172, the adheslve 14a prin-ted (or coated)'on the release sheet 12 is dried to form the adhesive layer 14, and a lamination of the adhesive layer ':`'`
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14 and the release sheet 12 is led to a laminatiny apparatus 174 for the laminated shee-t 3U prepared separately. This laminating apparatus 174 for the laminated sheet 30 ~omprises the lap loading apparatus 162 which loads a lap of the laminated sheet 30. The laminated sheet 30 led out from -this lap loading appara-tus 162 is led between two rollers 176a and 176b, and the surface of the above-mentioned adhesive layer 14 formed on the surface of the release sheet 12 and the covering layer 16 side surface of the laminated sheet 30 are superposed, and are laminated by the pressure of -the two rollers 176a and 176b and the adhesive force of the adhesive layer 14, being taken up on a roller 178 in a laminated sta-te.
In order to make a label with the sticking material thus manufacturad, the laminated sheet has only to be loaded in an apparatus for manufacturing a label comprising a printing apparatus for this laminated sheet and the like.
Fig. 7 is a diagrammatic view showing one example of an apparatus for manufacturing a label.
Such a label manufacturing appara-tus 180 comprises a holding appara-tus 182 which loads a lap of the laminated sheet 30 wherein the peel-off sheet 12 is laminated on the surface of the adhesive layer 14. ~ laminated sheet composed of the release sheet 12 and the laminated sheet 30 drawn out from this hoIding apparatus 182 ifi led to a printing appara-tus 184. This printing appara-tus 184 is composed, for example, of a publicly available printer such as an offset printer or the like. By means of this prin-ting apparatus .~, : :
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184, the printed layer 26 on which a pattern, for example the words "-trade name" or the like, i.s pr:Lnted is formed on the surface of the surface layer 24. ~'he lamlnated sheet on which the printed layer 26 is formed as described above is led to a punclling machine 186. rrhe punchiny machine 186 comprises a so-called die cutter havi.ng a cutting edge, and properly shaped cuts are formed on -the surface layer 24, the first peel-oEf layer 22, the breakable layer 20, -the covering layer 16 and the adhesive layer 14 by means of this die cutter.
In addition, the punching machine 186 may employ a roll with a cutting edge, a so-called die roll.
The laminated sheet on which cuts are formed is divided into a useless part and a plurality of labels 10 (required part) by rollers 188a and 188bt and the useless part is taken up in a roll shape by a stripper roller 190, while the labels trequired part) are taken up in a roll shape by a take-up roller 192 in the state wherein they are stuck temporarily on the release sheet 12. In addition, a cut-forming machine may be installed in place of the punching machine 186 and the take-up roller 192. This cut-forming machine comprises a cutting edge for forming cuts on the surface layer 24, the firs-t peel-off layer 22, the breakable layer 20, the covering layer 16 and the adhesive layer 14 to : 25 make each label plece 10. :.
Specific examples of mater~als in accordance wlth the above embodiment wll] now be given.
:
:
:: . . -: ~ ~ ..
- 19 ~
(l) Polyethylene terephthalate film of about 50 in thickness is used for the gurface layer, and a silicon resin is coated on one main surface thereof to form the first peel-off layer, and subsequently in order to form the break-able layer, aluminum is vacuum-evaporated on this first peel-off layer to form a breakable layer of about 7~ in thickness.
A silicon resin manufactured by Iloray Industries, Inc having a peeling force smaller than that of the silicon resin forming the above-mentioned peel-off layer is partly coated on this surface of the breakable layer formed by evaporating aluminum so that the dried coated film thickness is 0.1-5~ and forms the second peel-off layer.
A covering layer is formed on this layer by coating a synthetic resin whose main component is the EVA resin as listed in the following Table 1 to a thickness o-f about 5-50~.
Thereafter, the adhesive layer is formed by coating the acrylate adhesive (BPS-5127) manufactured by Toyo Ink Mfg.
Co. Ltd. so tha-t the dried coated film thickness is 5-50p.
In this case, the adhesive force ~a) between the first peel-off layer and the breakable layer is about 50g, the adhesive force (b) between the second peel-off layer and the covering layer is about 30g, the adheslve orce ~d) of the adheslve layer is about l,OOOg, and the force (c) required for separ-ating the release sheet from the adhesive layer is about 20g.
The pressure-sensitive adhesive material thus constituted was made into a lab~l piece, which was stuck onto~a material to be sealed ~(paper box or the like).
:~
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..
~i;5~;~
The adhesive force (d) to the material -to which the label is stuck and ~he adhesive force (d') between the coverin~ layer and -the adhesive layer are about :I,OOOy, res-pec-tively.
When the stuck label piece was peeled forcibly ofE
the material, the brea]cable layer was torn at th~ boundary between the part where the second peel-off layer is formed and the part where it is not formed, and the torn breakable layer was peeled toge-ther with the surface layer off the material to which the label was stuck at -the seco~d peel-off layer portion.
Table 1 Componen-tsComposition Ethylene vinylVinylacetate content 10^50r~ 20^50 1 acetate co- Melt index (MI) 5 500 polymer resin Molecular weight Rosln 10,000 100,00020~60 Elydrogenerated rosin Adhesion- Glycerine resin (0 60) dative resin Polyturpentine resin Turpentine phenol resin G5 group petroleum resin G9 group pe-troleum resin Alicyclic group hydro ~-0 generated petroleum resin Paraffin wax 5 50 Micro wax (5 703 Polyethylene wax Polypropylene wax Para~fin group, Naphthene group resin ~1 5 Hea-t stabilizer : 0 .
Aging preventlng 25 In place of ethylene vinyll~beutane may ~e u resin, SIS
SBS, polyisobutylen~ or r : ' ' ';., ' :
' ~ : ' , ~' ;
" ' ' ~ '' ' . '~ ' :' '' '' :' ' ' - ' . :, : ~ . ' :"
, ..,.. "
' .,~
~2~ 3;~
2) Polyester film o about 501l in thi-kness i6 used for the surface layer, and silicon resin is coated on one main surface thereof to form the first peel-oEf layer.
Subsequently, to form the breakable layer, a printed layer is formed on the first peel-off layer by UV ink, and -thereby a breakable layer of about 7~ in thickness is formed.
Furthermare, the second peel-off layer is formed by partly coa-ting a silicon resin manufactured by Toray Indus-tries, Inc. (the peeling force of which is smaller than that of the silicon resin forming the above-mentioned first peel-off layer) on the surface of the breakable layer so that the dried coated film thickness is 0.1-5ll.
On this layer, a syn-thetic resin whose main compon-ent is EVA resin is coated to a -thickness of about 5-50~ to form the covering layer. Thereafter, an acrylate adhesive ~BPS-5127) manufactured by Toyo Ink Mfg. Co. ~td~ is coated to a dried coated film thickness of 5-50~ to form the adhesive layer.
In this case, the adhesive force (a) between the first peel-off layer and the breakable layer is about 50g, the adhesive force (b) be-tween the second peel off layer and the cover~ing layer is about 30gl the adhesive force (d) of the adhesive layer ls ahout 1,000g and -the Eorce (c) required for peeling the release sheet off the adhesive layer i9 aboUt 20g.~
The pressure-sensitive adhesive material thus constituted was made into a label piece, and was stuck onto , : :
.,.,, ;, -.: - . - , : ., ~ .,:
~6~3Z~
a material to be sealed (paper box or -the ]ike).
The adhesive force (d) -to the mater:Lal to which the label is stuck and the adllesive force (d'~ betweerl the covering layer and -the adhesive layer in this case are about l,OOOg, respectively.
When -the stuck label piece was peeled ~orcibly off the material, the breakable layer was -torn at the boundary between the part where -the second peel-off layer is formed and the part where it is not formed, and the torn breakable layer was peeled together wi-th the surface layer off the material to which the label was stuck.
Fig. lO is a cross-sectional view of a label of another embodiment in accordance with the present invention.
This label 310 is stuck temporarily on a release sheet 312, on which an adhesive layer 314, a covering layer 316, a second peel-off layer 318, a breakable layer 320, a temporarily stuck layer 321, a first peel-off layer 322 and a surface layer 324 are laminated in sequencel and a print~d layer 326 is formed on the surPace of the above-mentioned surface layer 324.
For the breakable layer 320, breakable sheets which can be broken easily by hand~may be employed, such as aluminum foil and~synthetic resin films whlch are exemplified by~a brittle film made of a mixture of copolymer resin of vinyl chloride~and acrylate and a pigment (Por example, titan-ium white~or calcium carbonate).
~lowever, a relatively Plexible sheet is preferable :
~:
Subsequently, to form the breakable layer, a printed layer is formed on the first peel-off layer by UV ink, and -thereby a breakable layer of about 7~ in thickness is formed.
Furthermare, the second peel-off layer is formed by partly coa-ting a silicon resin manufactured by Toray Indus-tries, Inc. (the peeling force of which is smaller than that of the silicon resin forming the above-mentioned first peel-off layer) on the surface of the breakable layer so that the dried coated film thickness is 0.1-5ll.
On this layer, a syn-thetic resin whose main compon-ent is EVA resin is coated to a -thickness of about 5-50~ to form the covering layer. Thereafter, an acrylate adhesive ~BPS-5127) manufactured by Toyo Ink Mfg. Co. ~td~ is coated to a dried coated film thickness of 5-50~ to form the adhesive layer.
In this case, the adhesive force (a) between the first peel-off layer and the breakable layer is about 50g, the adhesive force (b) be-tween the second peel off layer and the cover~ing layer is about 30gl the adhesive force (d) of the adhesive layer ls ahout 1,000g and -the Eorce (c) required for peeling the release sheet off the adhesive layer i9 aboUt 20g.~
The pressure-sensitive adhesive material thus constituted was made into a label piece, and was stuck onto , : :
.,.,, ;, -.: - . - , : ., ~ .,:
~6~3Z~
a material to be sealed (paper box or -the ]ike).
The adhesive force (d) -to the mater:Lal to which the label is stuck and the adllesive force (d'~ betweerl the covering layer and -the adhesive layer in this case are about l,OOOg, respectively.
When -the stuck label piece was peeled ~orcibly off the material, the breakable layer was -torn at the boundary between the part where -the second peel-off layer is formed and the part where it is not formed, and the torn breakable layer was peeled together wi-th the surface layer off the material to which the label was stuck.
Fig. lO is a cross-sectional view of a label of another embodiment in accordance with the present invention.
This label 310 is stuck temporarily on a release sheet 312, on which an adhesive layer 314, a covering layer 316, a second peel-off layer 318, a breakable layer 320, a temporarily stuck layer 321, a first peel-off layer 322 and a surface layer 324 are laminated in sequencel and a print~d layer 326 is formed on the surPace of the above-mentioned surface layer 324.
For the breakable layer 320, breakable sheets which can be broken easily by hand~may be employed, such as aluminum foil and~synthetic resin films whlch are exemplified by~a brittle film made of a mixture of copolymer resin of vinyl chloride~and acrylate and a pigment (Por example, titan-ium white~or calcium carbonate).
~lowever, a relatively Plexible sheet is preferable :
~:
3~
used such that the surface layer 324 docs not cause a peel-off due to restoration to the original state against the adhesive force of the temporarily stuck layer 321 when the label 310 is in a bent configuration and stuck to a bent part.
The temporarily stuck layer 321 is a layer which sticks the breakable layer 320 to the surEace layer 324, and this temporarily s-tuck layer 321 is formed by coating a biliquid-reaction polymer resin, for example, urethane resin, EVA resin, or a resin of PV~, vinylacetochloride or acrylate.
In addition, other examples of the temporarily stuck layer 321, include adhesive layers on w~ich a heat-hardening adhesive of the polyester family, polyurethane family or the like are coated.
In order to open the opening part of the package to which this label 310 is stuck, the stuck label 310 is required to be peeled off and then the sealed part is opened.
In this case, the breakable layer 320 is stuck temporarily to the surface layer 324 through the first peel-20~ off layer 322, and the breakable layer 320 adheres strongly to the covering layer 316, and adheslon a-t -the portion where the second peel-off layer 318 ls ormed is weaker as compared w.ith -that at the por-tion where adhesion does not occur directly to the covering layer'316. Accordingly, as shown in Fig. 11, when the surface layer'324 is peeled off, the breakable layer 320 is torn at the boundary between the breakable layer 320 of~ the second peel-off layer'318 part and 12~
the breakable layer 320 of the part to which the coveriny layer 316 adheres direc-tly, and also the coveriny layer 316 is peeled off the main surEace of the second peel-of layer 318, and a part of the breakable layer 320 (where the second peel-off layer 318 is ormed) is peeled off the material A
to which the label is stuck, while adhering intact to the surface layer 324.
In the breakable layer 320, the part where the second peel-off layer 318 is not formed remains intact while adhering to -the ma-ter:ial A to which the label is to be stuck.
Accordingly, once -the surface layer 32~ is peeled off, the breakable layer 320 is broken at the boundary between the part where the second peel-off layer 318 is formed and the part where it is not formed, and the situation exists wherein the surface layer 324 cannot be stuck again on the surface of the covering layer 316, and the original state can not be restored, and therefore the opened state can be clearly per-ceived at a glance.
An example of a method of manufacturing a sticking material in accordance with the present invention will now be described with reference to Fig. 12 which is a diagram-matic view showing one example of an apparatus for manufac-turing a laminated sheet'330 which comprises an embodiment of the ma-terial of the present invention.
Thls laminated sheet'330 is such that a firs~t peel-off layer~322, a breakable layer 320, a second peel-oEf layer 318 and a covering layer'316 are laminated in this sequence.
:
~.. i . .. . . . . ..
,: . ~ : -. . .
.. , , :- ., - . :. - ~ :~ - ,- , , , : . ., . ~ ~: . : ~ ' ' ,, "" . , 3~
A surface m~terial 3Z4a on which a peel-off agent 322a is coated, which is descr:ibed in the en~bodiment of ~iys.
10 and 11, is fed to a lamlnatiny apparatus 4Z0 which sup-plies the breakable layer 320. This laminatiny apparatus 420 comprises an apparatus which loads a lap of -the breakable layer material 320a. ~n aluminum foil 320a drawn out from this lap, which is a breakable material form:ing the breakable layer 320, is led -to a coating apparatus 422 co~lprising two rollers and a pan for storing a resin or adhesive 321a forming the temporarily stuck layer 321, and the resin or adhesive 321a is coated on the surface of -the aluminum foil 320a by rotation of the two rollers, and -thereafter the foil is further led between two other rollers 4Z4 and 426, and the aluminum foil 320a is superposed on and is ~ade to adhere by the adhesive 3Zla on the surface thereof to the surface of the first peel-off layer 3Z2 of the surface material 324a which is led separately. The laminate is led to an adhesion apparatus~428. For the adhesion apparatus 428, a "drier" is employed ln the case where an adhesive comprising an aqua-Z0 resin of the PVA family, vlnylacetate family, acrylatefamily or the like or a solvent type adhesive composed of~
vlnyI-acetochlorlde, ur~thane, acrylate or -the like is used as~the adheslve 321a, and a "cooler" is employed in the case where a hotmelt type adhesive of the rubber family or EV~
family is used. ~
~ A laminatinq apparatus as illustrated in Fig. 13 may be~employed in place of the laminating appara-tus illus-~:
:
~2~
trated in Fig. 12.
A laminating apparatus 5~0 as illustrated i.n Fig.
13 is for superposing and makiny adhere the breakable mater-ial 320a forming the breakahle layer 320 to the surface of the first peel-oEf layer 322 formed on the surface of the surface layer 324. The apparatus comprlses a main roller 522a and a roller 522b installed opposite to the main roller 522a. Then, the breakable material 320a composed of a brittle film is fed between the main roller 522a and the roller 522bo On the back surface of this breakable material 320a, the temporarily ~tuck layer 321 is formed on which a pressure-sensitive adhesive or the like is coated in advance, and furthermore on the surface of the temporarily stuck layer 321, a peel-off material 321b is temporarily stuck so that the temporarily stuck layer 321 does not adhere to the sur-face of the breakable material 320a. Then, this laminated sheet of the breakable material:320a, the temporarily stuck layer 321 and the peel-off material 321b is lapped and before the laminated sheet drawn out from this lap is fed to the 20 main roller~52~a and the roller 522b, only -the peel-off material 321b is peeled off the temporarily stuck layer 321 to expose the temporarily stuck layer 321, and thus the laminated.sheet is fed to the main roller 522a and the rol-ler 522b in thLs state, being laminated and made to adhere to the ~urface of the first peel-off layer 322 of -the surface material 324a. Thus, the breakable layer 320 is formed, : thereafter being taken u~ on a take-up roller 5~5.
:
:
:
, :
,:, i .: ., : -" : :~,: ~:: :, :
- ~2~
This lap of the sur:Eace layer 324 on willch the breakable layer 320 is formed is fed to the lam.inatlng appar-atus 140 as shown in Elg. 5 slmllarly to the case of the above-ment.ioned embocliment.
Examples of specific materials made i.n the above embodlment will now be given.
(1) A polyethylene telephthalate film of about 50 in thickness is used for the surface layer, and a silicon resin is coated on one main surface thereof to form the first peel-off layer, and subsequently to form the breakable layer~
an aluminum foil is temporarily stuck on this first peel-off layer using an adhesive to form the breakable layer of about 7~ in thickness.
Furthermore, a silicon resin manufactured by Toray Industries, Inc. and having a peeling force smaller than -that of the silicon resin forming the above-mentioned first peel-off layer, is coated partly on the surface of this breakable layer composed of the aluminum foil to form the second peel-off layer.
on ~this layer, a s~nthetic resin whose main compon-en-t.is the EVA resin speciEied in the above Table 1 is coated to a thickness of about 5-50~l to form the covering layer.
Thereafter, -the acrylate adhesive tBPS-5127) manuEactured by TOYO Ink. Co. is coated so that the dried coated film thick-ness~is 5-501l to form the adhesive layer. In this case, the adhesive~force~(à) between the first peel-off layer and the breakable layer is about 50g, the adhesive force (b) between -. . ~ .
.:. ~ , .-.
. - 2~ -the second peel-oEf layer and the covering layer i.s about 30g, -the adhesive force (d) of the adhesi.ve layer is about l,OOOg and the force (c) required for peeliny the release sheet off the adhesive layer ls about 20y.
The adhesive force (d) -to the material to which the label is to be stuck and the adhesive force (d') between the coated film layer and the adhesive layer in this case are about l,OOOg, respectively.
When the stuck label piece was peeled forcihly off the material to which the label was stuck, the breakable layer was -torn at the boundary be-tween the part where -the second peel-off layer is formed and the part where it is not formed, and the -torn breakable layer was peeled toyether with the surface layer off the material -to which the label was stuck at -the second peel-off layer portion.
(2) A polyester film of about 50~ in thickness is used for the surface layer, and a silicon resin is coated on one main surface thereof to form the firs-t peel-off layer, and subsequently a so-called bri-ttle Eilm is temporarily stuck with an adhesive so as to form the breakable layer with a thickness of about 7~.~
- Furthermore, the silicon resin manufactured by Toray Inc. having a peeling force smaller than that of the above-mentioned.silicon resin :Eorming the first peel-of:E
layer is coated partly Oll the surface of the breakable layer composed of -this brittle ilm so that the dried coated film thickness is 0.1-5~, and thereby the second peel-of.E layer is .. ~ . : :
:. , . ;, . . .
: . . ,........ . . . .. ~ ., , , .
: :, ... ~ . :., formed.
On this layer, a synthe-tic resln whose main com-ponent is EV~ resin is coated -to a thickness of about 5-50 to form the covering layer. Thereafter/ the acrylate adhesive (BPS-5127) manufactured hy Toyo Ink Mfg. Co., Ltd.
is coated to form the adhesive layer having a dried coa-ted film thickness of 5-50~. In this case, -the adhesive force (a) between the first peel-ofE layer and the breakable layer is about 50g, the adheslve force (b) between the second peel-off layer and the coveriny layer is about 30g, the adhesiveforce (d) of the adhesive layer is about ],000g, and the force (c) required ~or peeling the release sheet off the adhesive layer is about 20g.
The pressure-sensitive stickiny ma-terial thus con-stituted was made into a label piece, and was stuck onto amaterial to be sealed (paper box or the like).
The adhesive force ~d) to the material to which the label is s-tuck and the adhesive force (d') between the covering layer and the adhesive layer are about l,000g res-pectively.
When the stuck label piece was peeled forcibly offthe material to which the label was stuck, the breakable layer was torn at the boundary between the part where the second peel-off layer ~is formed and the~part where it is not formed, and the -torn breakable layer was peeled toyether with the~surface layer off the material to which the label was stuck.
: : : ~ :
:: : ::
:. : ,, :, . . .
used such that the surface layer 324 docs not cause a peel-off due to restoration to the original state against the adhesive force of the temporarily stuck layer 321 when the label 310 is in a bent configuration and stuck to a bent part.
The temporarily stuck layer 321 is a layer which sticks the breakable layer 320 to the surEace layer 324, and this temporarily s-tuck layer 321 is formed by coating a biliquid-reaction polymer resin, for example, urethane resin, EVA resin, or a resin of PV~, vinylacetochloride or acrylate.
In addition, other examples of the temporarily stuck layer 321, include adhesive layers on w~ich a heat-hardening adhesive of the polyester family, polyurethane family or the like are coated.
In order to open the opening part of the package to which this label 310 is stuck, the stuck label 310 is required to be peeled off and then the sealed part is opened.
In this case, the breakable layer 320 is stuck temporarily to the surface layer 324 through the first peel-20~ off layer 322, and the breakable layer 320 adheres strongly to the covering layer 316, and adheslon a-t -the portion where the second peel-off layer 318 ls ormed is weaker as compared w.ith -that at the por-tion where adhesion does not occur directly to the covering layer'316. Accordingly, as shown in Fig. 11, when the surface layer'324 is peeled off, the breakable layer 320 is torn at the boundary between the breakable layer 320 of~ the second peel-off layer'318 part and 12~
the breakable layer 320 of the part to which the coveriny layer 316 adheres direc-tly, and also the coveriny layer 316 is peeled off the main surEace of the second peel-of layer 318, and a part of the breakable layer 320 (where the second peel-off layer 318 is ormed) is peeled off the material A
to which the label is stuck, while adhering intact to the surface layer 324.
In the breakable layer 320, the part where the second peel-off layer 318 is not formed remains intact while adhering to -the ma-ter:ial A to which the label is to be stuck.
Accordingly, once -the surface layer 32~ is peeled off, the breakable layer 320 is broken at the boundary between the part where the second peel-off layer 318 is formed and the part where it is not formed, and the situation exists wherein the surface layer 324 cannot be stuck again on the surface of the covering layer 316, and the original state can not be restored, and therefore the opened state can be clearly per-ceived at a glance.
An example of a method of manufacturing a sticking material in accordance with the present invention will now be described with reference to Fig. 12 which is a diagram-matic view showing one example of an apparatus for manufac-turing a laminated sheet'330 which comprises an embodiment of the ma-terial of the present invention.
Thls laminated sheet'330 is such that a firs~t peel-off layer~322, a breakable layer 320, a second peel-oEf layer 318 and a covering layer'316 are laminated in this sequence.
:
~.. i . .. . . . . ..
,: . ~ : -. . .
.. , , :- ., - . :. - ~ :~ - ,- , , , : . ., . ~ ~: . : ~ ' ' ,, "" . , 3~
A surface m~terial 3Z4a on which a peel-off agent 322a is coated, which is descr:ibed in the en~bodiment of ~iys.
10 and 11, is fed to a lamlnatiny apparatus 4Z0 which sup-plies the breakable layer 320. This laminatiny apparatus 420 comprises an apparatus which loads a lap of -the breakable layer material 320a. ~n aluminum foil 320a drawn out from this lap, which is a breakable material form:ing the breakable layer 320, is led -to a coating apparatus 422 co~lprising two rollers and a pan for storing a resin or adhesive 321a forming the temporarily stuck layer 321, and the resin or adhesive 321a is coated on the surface of -the aluminum foil 320a by rotation of the two rollers, and -thereafter the foil is further led between two other rollers 4Z4 and 426, and the aluminum foil 320a is superposed on and is ~ade to adhere by the adhesive 3Zla on the surface thereof to the surface of the first peel-off layer 3Z2 of the surface material 324a which is led separately. The laminate is led to an adhesion apparatus~428. For the adhesion apparatus 428, a "drier" is employed ln the case where an adhesive comprising an aqua-Z0 resin of the PVA family, vlnylacetate family, acrylatefamily or the like or a solvent type adhesive composed of~
vlnyI-acetochlorlde, ur~thane, acrylate or -the like is used as~the adheslve 321a, and a "cooler" is employed in the case where a hotmelt type adhesive of the rubber family or EV~
family is used. ~
~ A laminatinq apparatus as illustrated in Fig. 13 may be~employed in place of the laminating appara-tus illus-~:
:
~2~
trated in Fig. 12.
A laminating apparatus 5~0 as illustrated i.n Fig.
13 is for superposing and makiny adhere the breakable mater-ial 320a forming the breakahle layer 320 to the surface of the first peel-oEf layer 322 formed on the surface of the surface layer 324. The apparatus comprlses a main roller 522a and a roller 522b installed opposite to the main roller 522a. Then, the breakable material 320a composed of a brittle film is fed between the main roller 522a and the roller 522bo On the back surface of this breakable material 320a, the temporarily ~tuck layer 321 is formed on which a pressure-sensitive adhesive or the like is coated in advance, and furthermore on the surface of the temporarily stuck layer 321, a peel-off material 321b is temporarily stuck so that the temporarily stuck layer 321 does not adhere to the sur-face of the breakable material 320a. Then, this laminated sheet of the breakable material:320a, the temporarily stuck layer 321 and the peel-off material 321b is lapped and before the laminated sheet drawn out from this lap is fed to the 20 main roller~52~a and the roller 522b, only -the peel-off material 321b is peeled off the temporarily stuck layer 321 to expose the temporarily stuck layer 321, and thus the laminated.sheet is fed to the main roller 522a and the rol-ler 522b in thLs state, being laminated and made to adhere to the ~urface of the first peel-off layer 322 of -the surface material 324a. Thus, the breakable layer 320 is formed, : thereafter being taken u~ on a take-up roller 5~5.
:
:
:
, :
,:, i .: ., : -" : :~,: ~:: :, :
- ~2~
This lap of the sur:Eace layer 324 on willch the breakable layer 320 is formed is fed to the lam.inatlng appar-atus 140 as shown in Elg. 5 slmllarly to the case of the above-ment.ioned embocliment.
Examples of specific materials made i.n the above embodlment will now be given.
(1) A polyethylene telephthalate film of about 50 in thickness is used for the surface layer, and a silicon resin is coated on one main surface thereof to form the first peel-off layer, and subsequently to form the breakable layer~
an aluminum foil is temporarily stuck on this first peel-off layer using an adhesive to form the breakable layer of about 7~ in thickness.
Furthermore, a silicon resin manufactured by Toray Industries, Inc. and having a peeling force smaller than -that of the silicon resin forming the above-mentioned first peel-off layer, is coated partly on the surface of this breakable layer composed of the aluminum foil to form the second peel-off layer.
on ~this layer, a s~nthetic resin whose main compon-en-t.is the EVA resin speciEied in the above Table 1 is coated to a thickness of about 5-50~l to form the covering layer.
Thereafter, -the acrylate adhesive tBPS-5127) manuEactured by TOYO Ink. Co. is coated so that the dried coated film thick-ness~is 5-501l to form the adhesive layer. In this case, the adhesive~force~(à) between the first peel-off layer and the breakable layer is about 50g, the adhesive force (b) between -. . ~ .
.:. ~ , .-.
. - 2~ -the second peel-oEf layer and the covering layer i.s about 30g, -the adhesive force (d) of the adhesi.ve layer is about l,OOOg and the force (c) required for peeliny the release sheet off the adhesive layer ls about 20y.
The adhesive force (d) -to the material to which the label is to be stuck and the adhesive force (d') between the coated film layer and the adhesive layer in this case are about l,OOOg, respectively.
When the stuck label piece was peeled forcihly off the material to which the label was stuck, the breakable layer was -torn at the boundary be-tween the part where -the second peel-off layer is formed and the part where it is not formed, and the -torn breakable layer was peeled toyether with the surface layer off the material -to which the label was stuck at -the second peel-off layer portion.
(2) A polyester film of about 50~ in thickness is used for the surface layer, and a silicon resin is coated on one main surface thereof to form the firs-t peel-off layer, and subsequently a so-called bri-ttle Eilm is temporarily stuck with an adhesive so as to form the breakable layer with a thickness of about 7~.~
- Furthermore, the silicon resin manufactured by Toray Inc. having a peeling force smaller than that of the above-mentioned.silicon resin :Eorming the first peel-of:E
layer is coated partly Oll the surface of the breakable layer composed of -this brittle ilm so that the dried coated film thickness is 0.1-5~, and thereby the second peel-of.E layer is .. ~ . : :
:. , . ;, . . .
: . . ,........ . . . .. ~ ., , , .
: :, ... ~ . :., formed.
On this layer, a synthe-tic resln whose main com-ponent is EV~ resin is coated -to a thickness of about 5-50 to form the covering layer. Thereafter/ the acrylate adhesive (BPS-5127) manufactured hy Toyo Ink Mfg. Co., Ltd.
is coated to form the adhesive layer having a dried coa-ted film thickness of 5-50~. In this case, -the adhesive force (a) between the first peel-ofE layer and the breakable layer is about 50g, the adheslve force (b) between the second peel-off layer and the coveriny layer is about 30g, the adhesiveforce (d) of the adhesive layer is about ],000g, and the force (c) required ~or peeling the release sheet off the adhesive layer is about 20g.
The pressure-sensitive stickiny ma-terial thus con-stituted was made into a label piece, and was stuck onto amaterial to be sealed (paper box or the like).
The adhesive force ~d) to the material to which the label is s-tuck and the adhesive force (d') between the covering layer and the adhesive layer are about l,000g res-pectively.
When the stuck label piece was peeled forcibly offthe material to which the label was stuck, the breakable layer was torn at the boundary between the part where the second peel-off layer ~is formed and the~part where it is not formed, and the -torn breakable layer was peeled toyether with the~surface layer off the material to which the label was stuck.
: : : ~ :
:: : ::
:. : ,, :, . . .
Claims (24)
1. An easily breakable sticking material which comprises a surface layer, a breakable layer laminated on one main surface of said surface layer, a first peel-off layer facilitating peeling of said surface member off said breakable layer, a second peel-off layer formed on a part of the main surface of said breakable layer, a covering layer formed on the second peel-off side of the main surface of said breakable layer, and an adhesive layer formed on the main surface of said covering layer, which material meets the requirement:
a > b wherein a represents the adhesive force between the first peel-off layer and the breakable layer, and b represents the adhesive force between the second peel-off layer and the covering layer.
a > b wherein a represents the adhesive force between the first peel-off layer and the breakable layer, and b represents the adhesive force between the second peel-off layer and the covering layer.
2. An easily breakable sticking material in accor-dance with claim 1, wherein the surface member is formed of a synthetic resin film.
3. An easily breakable sticking material in accor-dance with claim 2, wherein the surface member comprises a transparent synthetic resin film.
4. An easily sticking material in accordance with claim 2, wherein the surface member comprises a polyethylene film.
5. An easily breakable sticking material in accor-dance with claim 1, 2 or 3, wherein the first peel-off layer comprises a peel-off agent layer which is formed by a coating of silicon resin.
6. An easily breakable sticking material in accor-dance with claim 1, 2 or 3, wherein the first peel-off layer comprises a peel-off agent layer which is formed by a coating of fluorene resin.
7. An easily breakable sticking material in accor-dance with claim 1, wherein the breakable layer comprises an evaporation layer.
8. An easily breakable sticking material in accor-dance with claim 7, wherein the breakable layer comprises a metal evaporation layer.
9. An easily breakable sticking material in accor-dance with claim 8, wherein the breakable layer comprises an evaporation layer which is formed by evaporating aluminum.
10. An easily breakable sticking material in accordance with claim 8, wherein the breakable layer com-prises an evaporation layer which is formed by evaporating silver.
11. An easily breakable sticking material in acccordance with claim 1, wherein the breakable layer com-prises a printed layer.
12. An easily breakable sticking material in accordance with claim 11, wherein the breakable layer com-prises a silver-printed layer.
13. An easily breakable sticking material in accordance with claim 1, wherein the breakable layer com-prises a metal foil layer.
14. An easily breakable sticking material in accordance with claim 13, wherein the breakable layer com-prises an aluminum foil layer.
15. An easily breakable sticking material in accordance with claim 1, wherein the breakable layer com-prises a brittle film layer.
16. An easily breakable sticking material in accordance with claim 13, wherein the breakable layer is caused to adhere to the surface layer by a temporarily stuck layer.
17. An easily breakable sticking material in accordance with claim 16, wherein the temporarily stuck layer comprises an adhesive agent layer.
18. An easily breakable sticking material in accordance with claim 16, wherein the temporarily stuck layer comprises a layer on which synthetic resin is coated.
19. An easily breakable sticking material in accordance with claim 1, wherein the second peel-off layer comprises a peel-off agent layer which is formed by a coating of silicon resin.
20. An easily breakable sticking material in accordance with claim 1, wherein the second peel-off layer comprises a peel-off agent layer which is formed by a coating of fluorene resin.
21. An easily breakable sticking material in accordance with claim 1, wherein the covering layer comprises a resin layer which is formed by a coating of a synthetic resin.
22. An easily breakable sticking material in accordance with claim 21, wherein the covering layer comprises a resin layer which is formed by a coating of an EVA resin.
23. An easily breakable sticking material in accordance with claim 1, wherein the adhesive layer comprises a pressure-sensitive adhesive layer.
24. An easily breakable sticking material which comprises a surface layer having an upper surface and a lower surface, a first peel-off layer located on the lower surface of said surface layer and having an upper surface and a lower surface, a breakable layer laminated on the lower surface of said first peel-off layer and having an upper surface and a lower surface, a second peel-off layer formed on a portion of the lower surface of said breakable layer and having an upper surface and a lower surface, a covering layer formed on the lower surface of said second peel-off layer and on a portion of the lower surface of said breakable layer and having an upper surface and a lower surface, an adhesive layer formed on the lower surface of said covering layer, said breakable layer being formed of a material which is relatively easily breakable compared with the material of said surface layer and said covering layer so that the breakable layer is readily breakable, a first adhesive having an adhesive force "a" between said first peel-off layer and said breakable layer, and a second adhesive having an adhesive force "b" between said second peel-off layer and said covering layer, said adhesive forces a and b satisfying the relationship: a > b.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60067293A JPH0734145B2 (en) | 1985-03-28 | 1985-03-28 | Label for display |
| JP67293/1985 | 1985-03-28 | ||
| JP143537/1985 | 1985-06-28 | ||
| JP60143537A JPS623284A (en) | 1985-06-28 | 1985-06-28 | Easy to destroy sticking material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1265032A true CA1265032A (en) | 1990-01-30 |
Family
ID=26408480
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000503846A Expired - Fee Related CA1265032A (en) | 1985-03-28 | 1986-03-11 | Easily breakable sticking material |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4746556A (en) |
| KR (1) | KR900006509B1 (en) |
| CN (1) | CN1012262B (en) |
| BE (1) | BE904506A (en) |
| CA (1) | CA1265032A (en) |
| DE (1) | DE3608907A1 (en) |
| FR (1) | FR2579521B1 (en) |
| GB (1) | GB2173150B (en) |
| NL (1) | NL8600796A (en) |
Families Citing this family (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5582434A (en) * | 1986-12-15 | 1996-12-10 | Flexcon Company, Inc. | Tamper-resistant labeling |
| GB8716342D0 (en) * | 1987-07-10 | 1987-08-19 | Modern Labelling Methods Ltd | Tamper-proof labels |
| US4998666A (en) * | 1988-05-13 | 1991-03-12 | Frederick R. Ewan | Tamper indicating containers and seals |
| US5294470A (en) * | 1988-05-13 | 1994-03-15 | Ewan Frederick R | Tamper indicating containers and seals |
| EP0381008A3 (en) * | 1989-01-28 | 1991-04-17 | Shigenari Shishido | Sealed card |
| US5153042A (en) * | 1989-05-16 | 1992-10-06 | Minnesota Mining And Manufacturing Company | Tamper-indicating labelstock |
| US4980222A (en) * | 1989-06-21 | 1990-12-25 | Minnesota Mining And Manufacturing Company | Tamper indicating tape |
| AU7336691A (en) * | 1989-12-22 | 1991-07-24 | Data Tech Services, Inc. | Method and apparatus for masking confidential written material |
| FR2689670A1 (en) * | 1992-04-03 | 1993-10-08 | Bvf Advance Sa | Secure adhesive seal for envelope - incorporates layer of fragile material with hologram or personal symbols or designs to prevent tampering |
| DE4220344C2 (en) * | 1992-06-24 | 1994-06-23 | Trautwein Gmbh & Co | Plaque protected against duplication and / or improper removal and reuse |
| US5346259A (en) * | 1992-07-16 | 1994-09-13 | Avery Dennison Corporation | Anti-theft label construction |
| US5358281A (en) * | 1993-02-10 | 1994-10-25 | Moore Business Forms, Inc. | Security pressure sensitive label |
| CA2113932A1 (en) * | 1993-09-20 | 1995-03-21 | Pierre Caudal | Cleavable release structure |
| CA2134521A1 (en) * | 1993-11-02 | 1995-05-03 | Raymond R. Gosselin | Tamper-indicating label |
| US5751256A (en) * | 1994-03-04 | 1998-05-12 | Flexcon Company Inc. | Resonant tag labels and method of making same |
| US5895075A (en) * | 1994-04-22 | 1999-04-20 | Aquasol Limited | Security label |
| JPH10502745A (en) * | 1994-07-08 | 1998-03-10 | ミネソタ・マイニング・アンド・マニュファクチュアリング・カンパニー | Transparent multilayer film and its protection of data on documents and use as anti-fraud label |
| US5683774A (en) | 1994-12-09 | 1997-11-04 | Minnesota Mining And Manufacturing Company | Durable, tamper resistant security laminate |
| US5510171A (en) * | 1995-01-19 | 1996-04-23 | Minnesota Mining And Manufacturing Company | Durable security laminate with hologram |
| US20070065619A1 (en) * | 2003-08-05 | 2007-03-22 | Sellars Neil G | Reactive labels and methods of making and using the same |
| US6613410B1 (en) * | 1999-09-23 | 2003-09-02 | National Label Company | Extended wrap label |
| US20070148393A1 (en) * | 2003-08-05 | 2007-06-28 | Sellars Neil G | Reactive labels and methods of making and using the same |
| US6274236B1 (en) * | 1995-06-12 | 2001-08-14 | National Label Company | Labels and method of making same |
| DE29518961U1 (en) * | 1995-11-29 | 1997-03-27 | Zweckform Etikettiertechnik | Tamper-evident closure label |
| US5882116A (en) * | 1996-04-25 | 1999-03-16 | Backus; Alan | Tamper indication device |
| US5873607A (en) * | 1996-05-24 | 1999-02-23 | The Standard Register Company | Construction for a laminated window label |
| US5869160A (en) * | 1996-06-07 | 1999-02-09 | Avery Dennison Corporation | Release coated liners and security labels containing such release coated liners |
| US5876816A (en) | 1996-07-10 | 1999-03-02 | Avery Dennison Corporation | Tamper evident labels and methods of producing the same |
| WO1999013014A1 (en) * | 1997-09-11 | 1999-03-18 | Schreiner Etiketten Und Selbstklebetechnik Gmbh & Co. | Adhesive tape |
| DE19947282A1 (en) * | 1999-09-30 | 2001-04-05 | Hauni Maschinenbau Ag | Process for the production of packs by wrapping a packaged product |
| DE19963709A1 (en) | 1999-12-29 | 2002-12-05 | Tesa Ag | Security adhesive tape to prove unauthorized opening of a packaging |
| US6756095B2 (en) | 2001-01-10 | 2004-06-29 | Avery Dennison Corporation | Heat-sealable laminate |
| US6758000B2 (en) * | 2001-01-10 | 2004-07-06 | Avery Dennison Corporation | Livestock security tag assembly |
| US7095324B2 (en) * | 2001-03-06 | 2006-08-22 | Intermec Ip Corp | Tamper evident smart label with RF transponder |
| US6773653B2 (en) | 2001-10-05 | 2004-08-10 | Avery Dennison Corporation | In-mold labeling method |
| GB0129728D0 (en) * | 2001-12-12 | 2002-01-30 | Dupont Teijin Films Us Ltd | Plymeric film |
| DE10219876A1 (en) * | 2002-03-04 | 2003-09-18 | Tesa Ag | Process for the transmission of printed information and information carriers |
| JP2004012552A (en) * | 2002-06-03 | 2004-01-15 | Lintec Corp | Self-adhesive management tag with unsealing indication function and method for using same |
| GB0216052D0 (en) * | 2002-07-10 | 2002-08-21 | Arjobex Ltd | Synthetic paper label |
| US6716501B2 (en) | 2002-07-18 | 2004-04-06 | Avery Dennison Corporation | Multilayered film |
| US7029738B2 (en) * | 2003-04-11 | 2006-04-18 | Dinformatica del Noroeste S.A. de C.V. | System for discouraging the removal of identification labels adhered to a surface |
| KR20060010734A (en) * | 2003-05-01 | 2006-02-02 | 애버리 데니슨 코포레이션 | Multilayered film |
| US20060182955A1 (en) * | 2005-02-17 | 2006-08-17 | Sellars Neil G | Counterfeit and tamper evidence security labeling apparatus and method of making same |
| EA008115B1 (en) * | 2005-06-13 | 2007-04-27 | Шамрило, Валерий Михайлович | Multi-layer material for manufacturing self-adhesive protective tags (embodiment) and method therefor |
| US7855649B2 (en) * | 2007-11-21 | 2010-12-21 | Masin Joseph V | Tamper resistant RFID tags and associated methods |
| DE102008033323A1 (en) | 2008-07-16 | 2010-01-21 | Tesa Se | security label |
| US20100043694A1 (en) * | 2008-08-20 | 2010-02-25 | Patel Gordhanbhai N | Tamper evident indicating devices |
| US8804658B2 (en) * | 2008-10-22 | 2014-08-12 | Mediatek Inc. | Method and apparatus for handover between IEEE 802.16e and 802.16m systems |
| JP2011026717A (en) * | 2009-07-22 | 2011-02-10 | Sumitomo Wiring Syst Ltd | Fabric for binding tape and binding tape |
| JP5591662B2 (en) * | 2010-01-07 | 2014-09-17 | 株式会社パワーサポート | Film sheet |
| AT510505B1 (en) * | 2010-08-13 | 2013-02-15 | Hueck Folien Gmbh | SAFETY LABEL WITH MANIPULATION DETECTION |
| AT510520B1 (en) * | 2010-08-13 | 2013-02-15 | Hueck Folien Gmbh | SAFETY LABEL WITH MANIPULATION DETECTION |
| US8444058B2 (en) | 2011-01-20 | 2013-05-21 | Trovan, Ltd. | Embedded RFID tags and associated methods and systems |
| US8618938B2 (en) | 2011-11-21 | 2013-12-31 | Trovan, Ltd. | Gas cylinder and RFID transponder assemblies and related methods having fixed transponder orientations |
| JP5972009B2 (en) * | 2012-03-30 | 2016-08-17 | デクセリアルズ株式会社 | CIRCUIT CONNECTION MATERIAL, AND METHOD FOR PRODUCING MOUNTING BODY USING THE SAME |
| DE102013005486B4 (en) | 2013-04-02 | 2019-02-14 | Heraeus Deutschland GmbH & Co. KG | Layer structure with conductive polymer for tamper detection as well as method for its production |
| WO2017022541A1 (en) * | 2015-08-04 | 2017-02-09 | 株式会社ユポ・コーポレーション | Easy-to-peel layered label, production process therefor, use method therefor, adherend with easy-to-peel layered label, and method for judging opening |
| CN105385372B (en) * | 2015-11-06 | 2018-02-06 | 东莞职业技术学院 | A kind of diaphragm seal and the packaging product using the diaphragm seal |
| CN106113718B (en) * | 2016-06-28 | 2020-06-09 | 京东方科技集团股份有限公司 | Easy-to-tear sticker, easy-to-tear protective film and tearing method of protective film |
| US11281952B2 (en) | 2019-06-04 | 2022-03-22 | Trovan, Ltd. | Systems and methods to secure transponders within RFID tags without potting elements |
| CN110194936A (en) * | 2019-06-27 | 2019-09-03 | 格力电器（合肥）有限公司 | A kind of adhesive tape |
| US11461610B2 (en) | 2020-08-28 | 2022-10-04 | Trovan, Ltd. | Apparatus and methods for retrofitting an object with an RFID transponder |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1594197A1 (en) * | 1965-07-14 | 1971-02-11 | Compac Corp | Multi-layer composite structure made of paper and polymer film that can be bonded by pressure |
| GB1220882A (en) * | 1968-02-09 | 1971-01-27 | Sterling Coated Materials Ltd | Sealing means |
| US3631617A (en) * | 1969-10-27 | 1972-01-04 | Avery Products Corp | Tamperproof label construction |
| US3664910A (en) * | 1970-03-30 | 1972-05-23 | Manuel E Hollie | Identifying device for documents |
| US3925584A (en) * | 1972-08-24 | 1975-12-09 | Daiichi Seiyaku Co | Adhesive seal and tape for sealing |
| DE2239652C3 (en) * | 1972-08-29 | 1980-10-02 | Daiichi Seiyaku Co. Ltd., Tokio | Sticky notes or tape for packaging purposes |
| US4057919A (en) * | 1974-04-02 | 1977-11-15 | G.A.O. Gesellschaft Fur Automation Und Organisation Mbh | Laminated data carrier protected against forgery, particularly identification card |
| US4121003A (en) * | 1977-04-22 | 1978-10-17 | Monarch Marking Systems, Inc. | Tamper indicating labels |
| US4184701A (en) * | 1978-02-10 | 1980-01-22 | Monarch Marking Systems, Inc. | Tamper proof label |
| DE3025931A1 (en) * | 1980-07-09 | 1982-02-11 | Hoechst Ag, 6000 Frankfurt | THERMOPLASTIC FILM FOR USE IN THE PRODUCTION OF COUNTERFEIT-PROOF ID PAPERS |
| JPS5728776A (en) * | 1980-07-15 | 1982-02-16 | Kishimoto Akira | Packing vessel, which can be sterilized in retort and edge cutting of sealed section thereof is improved |
| US4423819A (en) * | 1981-08-19 | 1984-01-03 | U.S. Clinical Products, Inc. | Flexible sterile closure system for containers |
| US4604153A (en) * | 1982-01-15 | 1986-08-05 | Kroy Inc. | Method of manufacturing figures from a laminated tape and applying the same to a desired medium |
| US4544590A (en) * | 1982-03-17 | 1985-10-01 | Miller Products, Inc. | Laminated member and method of making same |
| US4521467A (en) * | 1983-12-12 | 1985-06-04 | Frito-Lay, Inc. | Ultrasonically-sealable peelable seal |
| US4557505A (en) * | 1984-01-05 | 1985-12-10 | Minnesota Mining And Manufacturing Company | Stress-opacifying tamper indicating tape |
| US4577205A (en) * | 1984-05-25 | 1986-03-18 | Ricoh Electronics, Inc. | Releasable heat-sensitive label with E. B. setting printing ink |
| US4608288A (en) * | 1984-08-21 | 1986-08-26 | Joachim Dudzik | Tamper proof label or seal |
| US4621442A (en) * | 1985-05-24 | 1986-11-11 | Pamco Label Co. | Simplified multilayer label |
-
1986
- 1986-03-10 GB GB8605877A patent/GB2173150B/en not_active Expired
- 1986-03-11 CA CA000503846A patent/CA1265032A/en not_active Expired - Fee Related
- 1986-03-17 DE DE19863608907 patent/DE3608907A1/en not_active Withdrawn
- 1986-03-18 US US06/840,761 patent/US4746556A/en not_active Expired - Fee Related
- 1986-03-24 FR FR868604176A patent/FR2579521B1/en not_active Expired
- 1986-03-25 CN CN86101926A patent/CN1012262B/en not_active Expired
- 1986-03-27 BE BE0/216465A patent/BE904506A/en not_active IP Right Cessation
- 1986-03-27 KR KR1019860002304A patent/KR900006509B1/en not_active IP Right Cessation
- 1986-03-27 NL NL8600796A patent/NL8600796A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| FR2579521B1 (en) | 1989-09-15 |
| KR860007622A (en) | 1986-10-15 |
| DE3608907A1 (en) | 1986-10-09 |
| FR2579521A1 (en) | 1986-10-03 |
| CN86101926A (en) | 1986-09-24 |
| US4746556A (en) | 1988-05-24 |
| CN1012262B (en) | 1991-04-03 |
| GB8605877D0 (en) | 1986-04-16 |
| GB2173150A (en) | 1986-10-08 |
| NL8600796A (en) | 1986-10-16 |
| KR900006509B1 (en) | 1990-09-03 |
| BE904506A (en) | 1986-07-16 |
| GB2173150B (en) | 1989-06-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |