CA1247726A - Alignment layer orientation in raster scan thermally addressed smectic liquid crystal displays - Google Patents

Alignment layer orientation in raster scan thermally addressed smectic liquid crystal displays

Info

Publication number
CA1247726A
CA1247726A CA000464051A CA464051A CA1247726A CA 1247726 A CA1247726 A CA 1247726A CA 000464051 A CA000464051 A CA 000464051A CA 464051 A CA464051 A CA 464051A CA 1247726 A CA1247726 A CA 1247726A
Authority
CA
Canada
Prior art keywords
liquid crystal
alignment layer
cyanobiphenyl
cell
laser
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000464051A
Other languages
French (fr)
Inventor
Nicholas J. Clecak
Jerry Leff
Robert J. Cox
Joseph S. Feng
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
International Business Machines Corp
Original Assignee
Nicholas J. Clecak
Jerry Leff
Robert J. Cox
Joseph S. Feng
International Business Machines Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nicholas J. Clecak, Jerry Leff, Robert J. Cox, Joseph S. Feng, International Business Machines Corporation filed Critical Nicholas J. Clecak
Application granted granted Critical
Publication of CA1247726A publication Critical patent/CA1247726A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/132Thermal activation of liquid crystals exhibiting a thermo-optic effect
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133502Antiglare, refractive index matching layers
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers

Landscapes

  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Mathematical Physics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Liquid Crystal (AREA)
  • Liquid Crystal Substances (AREA)

Abstract

ALIGNMENT LAYER ORIENTATION IN RASTER
SCAN THERMALLY ADDRESSED SMECTIC
LIQUID CRYSTAL DISPLAYS

Abstract of the Disclosure The orientation of the alignment layer in a raster-scanned thermally addressed smectic liquid crystal display device can be chosen relative to the writing orientation to accentuate a selected characteristic. A
perpendicular alignment with respect to the scan direction produces uniformly written images in both scan directions to allow high quality bidirectional writing.
In a preferred embodiment the liquid crystal cell includes a liquid crystal material comprising 4-octyloxy-4'-cyanobiphenyl 37.5%, 4-decyl-4'-cyanobiphenyl 36.8% weight percent and 4-undecyl-4'-cyanobiphenyl 25.7 weight percent.

Description

S~9 83 032 ~ ~
~7~

ALIGNMENT LAYER ORIENTATION IN RASTER
SCAN THERMALLY ADDRESSED SMECTIC
LIQUID CRYSTAL DISPLAYS

DESCRIPTION

Technical Field -- This invention relates to an improved reflective raster scanned laser addressed liquid crystal cell, and more particularly a liquid crystal cell in which the alignment layer is oriented relative to the scanning raster.

Background Art The alignment of liquid crystal molecules in liquid crystal devices is important for obtaining a high contrast ratio. The purpose of the alignment layers is to give a preferred direction to the liquid crystal molecules in th~ neighhorhood o~ the surface ~hat i~, it determines the angle the liquid crystal director makes with the plane of the alignment layer. The patent to Sprokel, U.S. 4,261,650, describes a method for producing uniform parallel alignment in liquid crystal cells and discusses random in-plane alignment;
alignment with the molecules being tilted out of the plane of the substrate surface, and parallel alignment in the plane of the substrate surface. This patent did not discuss the angle between the raster scan direction and the liquid crystal director as projected onto the plane of the alignment layer.

SA9 83 032 ~ -~
J ,~
7;;~

Dewey et al in the IBM Journal of Research and Development, Vol. 26 No. 2, March 1982, pages 177-185 describes reflective raster-scanned laser addressed liquid crystal cells. In the Dewey et al paper, the purpose of the alignment layers was to give a preferred direction,of the liquid crystal molecules in the neighborhood of the surface in a manner similar to that described in the patent above.- The paper points out that the performance of the liquid crystal cell is - 10 highly dependent upon these aligning forces and that a strong uniform alignment tends to realign the written scattered texture thereby giving excellent bulk erase properties. The articles does not address the angle between the raster scan direction and the liquid crystal director as projected onto the plane of the alignment layer.

Numerous liquid crystal mixtures have been used for display devices. Liquid crystal mixtures are described in the IBM Technical Disclosure Bulletin Vol 19, No. 4, 20 September 1976 page 1401 in which a mixture of 4-octyl-4'-cyanohiphenyl, and 4-n-decyl-4'-cyanobiphenyl i5 discLosed. Another mixture is described containing 4-n-octyIoxy-4'-cyanobiphenyl, 4-n-decyl-4'-cyanobiphenyl, and 4-rL-undecyL-4'-cyanobiphenyl. No percentages of this composition were disclosed.

Summarv of the Invention It is a primary object of this invention to provide an improved raster-scanned thermally addressed liquid crystal display.

It is another object of this invention to provide a raster-scanned liguid crystal display having uniform contrast in the written image;

It is another object of this invention to provide a raster-scanned liquid crystal display in which written images are produced uniformly in both scan directions.

It is still another object of this invention to provide a raster- scanned liquid crystal display having maximized contrast in unidirectional writing.

These and other objects are accomplished with the orientation of the alignment layer in a thermally addressed smectic liquid crystal display device being chosen relative to the writing orientation to accentuate a selected characteristic. A perpendicular alignment with respect to the scan direction produces uniformly written images in both scan directions to allow high quality bidirectional writing. Parallel alignment maximizes the contrast in unidirectional writing.
Antiparallel alignment increases the selective erase window and improves the resolution in unidirectionally written pages. In a preferred embodiment the liquid crystal cell includes a li~uid crystal material comprising 4-octyloxy-4'-cyanobiphenyl 37.5%, 4-decyl-4'-cyanobiphenyl 36.8% weight percent and 4~undecyl-4'-cyanobiphenyl 25.7 weight percent.

Other objects of this invention wlll be apparent . from the following detailed description, reference being made to the following drawings in which specific embodiments of the invention are shown.

Brief Description of the Drawin~s FIGURES lA, B, and C are prior art liquid crystal cells showing random in-plane, uniform tilted and uniform in-plane alignment;

SA9 83 032 r~

FIGURES 2A-C (which appears with Figs. 3A-D) show the relationship be~ween the evaporation source and the alignment layer;
FIGURES 3A-3D show the relationship between the raster-scanned direction and the orientation of the 5 liquid crystal directors;

FIGURE 4 (which appears with Figs. lA-C) is a liquid crystal cell in accordance with this invention.

Descri~tion of the Preferred Embodiment The orientation of the alignment layer in a thermally addressed smectic liquid crystal device, is chosen relative to the writing direction to accentuate a selected characteristic.
-The alignment layer may be formed by vacuumevaporation of an inert inorganic material at a shallow oblique angle such as described in the patent to Janning, U.S. 3,834,792. This technique usually results in the formation of a textured dendritic structure with the axes of the dentrites formed in the general direction of the evaporation source 1 as shown in Fig. 2A. The microscopic structure of the alignment layer 2 is related to the source l-to-substrate 3 orientation . during deposition. This directionality is shown schematically in Figure 2B for the special case of a point source aligned with the centerline of the substrate. In practice the lines are in fact more parallel than shown in Fig. 2B. If a rectilinear coordinate system coincident with the sides 4 of a rectangular (or square) substrate is imposed on the cell, there are three significantly different directions, shown in Figure 2C as perpendicular, parallel and antiparallel.

As shown in Fig. 3A, the direction of the raster scan 5 forms an angle ~ with the direction of the projection of the liquid crystal director 6 onto the plane of the alignment layer. The angle ~ may vary from O
to 180C. In accordance with this invention, the angle ~
is 90 as shown in Fig. 3B, an angle of 0 in Fig. 3C and an angle of 180 in Fig. 3D.

When the alignment layer is oriented so that the liquid crystal directors 6 are positioned perpendicular to the scan direction of the raster 5 as shown in Fig. 3B, uniformly written images in both scan directions allows high quality bidirectional writing thereby improving display performance by reducing writing time.

The parallel alignment where a = oo as shown in Fig.
3C maximized the contrast in unidirectional writing. An antiparallel alignment, that is, where ~ is 180 as shown in Fig. 3C increases the selective erase window and improves the resolution in unidirectional written images. Parallel and antiparallel alignments can be combined in a single image if the display can write bidirectionally. One application of this capability would be to mix text and images with the text written in the high contrast mode and the pictures written in the high resolution mode.

A liquid crystal display cell suitable for use of this invention is shown in Fig. 4. A laser beam 7 strikes an antireflectance coating 8, designed to match the spectral output of the laser, which consists of a top layer of SiO2 and a bottom layer of TiO2 directly on the substrate surface lOB of substrate 10. Substrate 10 is typicalLy a borosilicate glass. On substrate surface lOA is a three-layer antireflectance coating 13 designed to match the spectral output of the laser which consists 6 ~ 7~

of two layers of TiO2 on either side of the middle layer of SiO2. Layer 18 is a conductive metallic absorbing layer which is typically a me~al such as chromium. A
layer 20 is a reflective conductive electrode, for example, of aluminum. Layer 19 is an insulating layer of sio2 .

In accordance with this invention the alignment layer 22 is evaporated at an angle to the substrate to provide the alignment described in either Fig. 3B, 3C or 3D. A spacing layer 28 of a material such as Mylar forms a cavity 14 which is filled with a liquid crystal mixture as will be hereinafter more fully described. Layer 27 is an insulating layer put down at 90. Layer 24 is a transparent conductor electrode layer of a material such as indium tin oxide. Substrate 12 is a borosilicate glass and layer 21 is a broad band antireflectance coating for the visible spectrum that consists of a number of layers, for example, 7 to 9 layers, consisting of materials such as TiOl, SiO2, MgF and the like.

The preferred li~uid crystal composition in the cavity 14 consists of a mixture of 37.5 + 0.5 weight ~ 4-octyloxy-4'-cyanobiphenyl, 36.8 +0.5 weight percent 4-decyl-4'-cyanobiphenyl and 25.7 +0.5 weight percent 4-undecyl-4'-cyanobiphenyl. The following table shows the criticality of the liquid crystal mixture composition.
The three components of the composition cannot vary by more than + 0.5 weight percent. Concentrations that vary by more than that amount tend to give poor cell performance as far as the contrast and the presence of a ghost image are concerned.

* Trade mark ~ .
'~`'-' ' i .~4 `

7~6 LIQUID CRYSTAL MIXTURES V. NEMATIC RANGE

Example Com~ tion N_matic Range Cell Performance C08 37.5% 1 deg C Excellent 1 C10 36.8%
Cll 25.7%

C08 37.0% 1.3 deg C Fair C10 37.3%
C11 25.7%

C08 37.0% 1.4 deg C Fair 3 C10 36.8%
Cll 26.2%

C08 36.5% 2 deg C Poor 4 C10 37.8%
Cll 25.7%

C08 36.5% 2~2 deg C Poor C10 36.8%
Cll 26.7%

C08 38.5% 1.7 deg C Poor 6 C10 36.8%
Cll 24.7%

C08 = 4-octyloxy-4'-cyanobiphenyl C10 = 4-decyl-4'-cyanobiphenyl Cll = 4-undecyl-4'-cyanobiphenyl t7?d6 Although preferred embodiments have been described, it is understood that numerous variations may be made in accordance with the principles of this lnvention.

Claims (4)

The embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows:
1. A reflective liquid crystal cell addressed by a scanning laser and having a first and second substrate being separated by a spacing member to form a cavity, said cell comprising an inplane alignment layer on said first substrate, said alignment layer being oriented in a direction taken from the group consisting of perpendicular, parallel and antiparallel to the scanning direction of the laser wherein the orientation direction of the alignment layer determines the characteristics of the written image, and wherein said cell includes a liquid crystal material in said cavity, said material comprising 4-octyloxy-4'-cyanobiphenyl, 37.5%?0.5 weight percent, 4 decyl-4'-cyanobiphenyl 36.8?0.5 weight percent and 4-undecyl-4'-cyanobiphenyl 25.7?0.5 weight percent.
2. A cell as described in claim 1 wherein said alignment layer is oriented perpendicular to the scanning direction of the laser to produce a uniform written image in a bidirectionally scanned area.
3. A cell as described in claim 1 wherein said alignment layer is oriented parallel to the scanning direction of the laser to maximize the contrast in a unidirectionally scanned area.
4. A cell as described in claim 1 wherein said alignment layer is oriented antiparallel to the scanning direction of the laser to increase the selective erase window and to improve the resolution in the unidirectionally written image.
CA000464051A 1983-12-12 1984-09-26 Alignment layer orientation in raster scan thermally addressed smectic liquid crystal displays Expired CA1247726A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US560,475 1983-12-12
US06/560,475 US4585310A (en) 1983-12-12 1983-12-12 Alignment layer orientation in raster scan thermally addressed smectic liquid crystal displays

Publications (1)

Publication Number Publication Date
CA1247726A true CA1247726A (en) 1988-12-28

Family

ID=24237972

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000464051A Expired CA1247726A (en) 1983-12-12 1984-09-26 Alignment layer orientation in raster scan thermally addressed smectic liquid crystal displays

Country Status (5)

Country Link
US (1) US4585310A (en)
EP (1) EP0144683B1 (en)
JP (1) JPS6117122A (en)
CA (1) CA1247726A (en)
DE (1) DE3480956D1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60262130A (en) * 1984-06-09 1985-12-25 Sony Corp Liquid-crystal display device
GB2177227B (en) * 1985-06-14 1989-12-28 Semiconductor Energy Lab Optical non-volatile liquid crystal memory
US4787713A (en) * 1987-05-22 1988-11-29 The Mead Corporation Transparent laser-addressed liquid crystal light modulator cell
CA2123658C (en) * 1993-05-19 1999-01-19 Willis H. Smith, Jr. Inducing tilted parallel alignment in liquid crystals
US6929953B1 (en) * 1998-03-07 2005-08-16 Robert A. Levine Apparatus for analyzing biologic fluids
US6587097B1 (en) 2000-11-28 2003-07-01 3M Innovative Properties Co. Display system
US6798189B2 (en) 2001-06-14 2004-09-28 Koa Corporation Current detection resistor, mounting structure thereof and method of measuring effective inductance
DE10329439A1 (en) * 2003-07-01 2005-01-27 Daimlerchrysler Ag Cabriolet vehicle with a hardtop
US20060215095A1 (en) * 2005-03-26 2006-09-28 Qin Liu Laser-writing alignment marks on alignment layer to align liquid crystals

Family Cites Families (13)

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Publication number Priority date Publication date Assignee Title
US3655269A (en) * 1971-01-25 1972-04-11 Rca Corp Liquid crystal display assembly having independent contrast and speed of response controls
US3834729A (en) * 1971-09-23 1974-09-10 Nissan Motor Sealing unit for pressurized gas generator of automotive safety device
GB1452826A (en) * 1973-10-17 1976-10-20 Secr Defence Liquid crystal compositions
JPS49122748A (en) * 1973-03-24 1974-11-25
FR2292253A1 (en) * 1974-11-21 1976-06-18 Thomson Csf METHOD AND DEVICE USING A THERMO-OPTICAL EFFECT IN A LIQUID CRYSTAL FOR THE REPRODUCTION OF IMAGES IN REAL TIME AND WITHOUT MEMORY
US4221471A (en) * 1977-06-24 1980-09-09 Motorola, Inc. Liquid crystal memory device and method of utilizing same
US4291948A (en) * 1977-11-10 1981-09-29 International Standard Electric Corporation Liquid crystal display incorporating positive and negative smectic material
US4261650A (en) * 1978-12-18 1981-04-14 International Business Machines Corporation Method for producing uniform parallel alignment in liquid crystal cells
US4277147A (en) * 1979-01-15 1981-07-07 General Motors Corporation Display device having reduced electrochromic film dissolution
JPS5624318A (en) * 1979-08-02 1981-03-07 Seiko Epson Corp Liquid crystal matrix display panel
US4367924A (en) * 1980-01-08 1983-01-11 Clark Noel A Chiral smectic C or H liquid crystal electro-optical device
US4422732A (en) * 1981-06-08 1983-12-27 Ditzik Richard J Beam addressed electrooptic display system
FR2507802A1 (en) * 1981-06-10 1982-12-17 Thomson Csf LIQUID CRYSTAL DISPLAY DEVICE HAVING TWO ADDRESSING MODES

Also Published As

Publication number Publication date
US4585310A (en) 1986-04-29
EP0144683B1 (en) 1990-01-03
EP0144683A3 (en) 1986-01-08
JPS6117122A (en) 1986-01-25
EP0144683A2 (en) 1985-06-19
JPS647365B2 (en) 1989-02-08
DE3480956D1 (en) 1990-02-08

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