CA1226704A - Laundry softener concentrate - Google Patents
Laundry softener concentrateInfo
- Publication number
- CA1226704A CA1226704A CA000441938A CA441938A CA1226704A CA 1226704 A CA1226704 A CA 1226704A CA 000441938 A CA000441938 A CA 000441938A CA 441938 A CA441938 A CA 441938A CA 1226704 A CA1226704 A CA 1226704A
- Authority
- CA
- Canada
- Prior art keywords
- carbon atoms
- chloride
- laundry
- concentrate according
- laundry softener
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
Abstract
ABSTRACT OF THE DISCLOSURE
A laundry softener concentrate consists of one or several laundry softeners, synthetic silicic acid and if necessary one or several solvents. The laundry softener concentrate is a pourable powder.
A laundry softener concentrate consists of one or several laundry softeners, synthetic silicic acid and if necessary one or several solvents. The laundry softener concentrate is a pourable powder.
Description
2~7~
The puissant invention zealots to a laundry softener con-cent rate.
sundry softeners are added to laundry wash water in order to improve the feel and increase the softness of textile fabrics. Laundry softeners of this kind may be primarily cat ionic tetraalkyl amonium compounds and imidazoline derive-lives, the effectiveness of which depends on the chemical char-acterists of the alkyd groups. Since laundry softeners are in-soluble in water as a result of these long chain alkyd group, they are commercially available in the form of 5-8% aqueous disk pensions. The great dilution has clear economic disadvantages.
Large, bulky and costly containers are needed and a great deal of water has to be transported. Further, a conceivable, auto-matte dispensing in an automatic domestic washing machine is rendered extremely difficult on account of the large volume of the required tanks.
It is known to use laundry softener concentrates that are also dispersions having a laundry softener content of 15-30~.
However, the viscosity of these laundry softener concentrates increase exponentially with increasing concentration. (Tensile Detergents 18, ~1981) 5, pp. 243 - 246).
The present invention provides a laundry softener con-cent rate that consists of a mixture of one or several laundry softeners, synthetic silicic acid and, it necessary, one or several solvents.
In a preferred embodiment of the invention the laundry softener concentrate consists of the laundry softener alone, with up to White synthetic silicic acid.
In a particularly preferred embodiment the laundry sol-loner concentrate may contain up to White synthetic silicic acid. The active substance content then amounts to 70~.
In addition to oven-dried and ground precipitated silicic pa ~2~7~
acids, spray dried precipitated silicic acids that can be either ground or unground can be used. High-temperature hydrolytic ally produced (pyrogenically produced) silicic acids can also be used.
The cat ionic laundry softeners present in the laundry softener concentrate are commercially available and well known products. These are preferably cat ionic compounds that contain nitrogen, such as qua ternary ammonium compounds and amine salts that have one or two straight chain organic groups that contain lo at least eight carbon atoms, of which at least one group con-twins 12-22 carbon atoms. It is preferable that qua ternary ammonium compounds of the following formula are present as laundry softeners.
--Al R Go \ N
2 / \ 4 wherein Al is a long-chain aliphatic group with 8 to 22 carbon atoms or a fatty acid ester group, R is a long-chain aliphatic group with 8 to 22 carbon atoms or an alkyd group with l to 6 carbon atoms or an aureole, airlocks, alkoxy, or aralkyl group with 6 to 28 carbon atoms or a fatty acid ester group, R3 and R4 are alkyd or hydroxyalkyl groups with l to 6 carbon atoms or hydroxypolyalkoxyalkyl groups with 4 to 20 carbon atoms and I is an anion that forms a water-soluble salt, such as for example, a halide e.g., chloride, bromide, or iodide, sulfate, methosulfate, acetate, hydroxide anion or a similar inorganic solvent and moo or dibasic group. The nitrogen can be a cyclic nitrogen and the R2 and R3 groups can be replaced by a ring of 4 to 5 carbon atoms. Especially good results are obtained with compounds of the above-quoted formulae in that the groups Al, R , R and R groups are straight-chain aliphatic groups such ~2~i'7~
as, for example, aliphatic groups. Tile following are good ox-apples of ~uaternary ammonium compounds that can be used as laundry softeners in the laundry softening agent according to the present invention: hydrated di-talloldimethylammonium chloride; ethoxylated distearyl-dimethylammonium chloride;
dimethyldistearylammonium chloride; trimethylstearyl-ammonium bromide; cetyltrimethyl-ammonium chloride, dicocodimethyl-ammonium-chloride; cetylpyridinium chloride; alkyldimethylbenzyl-ammonium chloride with a higher alkyd group; diisobutylphenoxy-ethyldimethylbenzyl-ammonium chloride; laurylisochinolinium bromide; distearyldimethyl-ammonium bromide; distearyldimethyl-ammonium sulfate; dimèthyl-diacachidyl-behenyl-ammonium chloride;
di(soya)-dimethylammonium chloride; and stearyldimethylbenzyl--ammonium chloride.
Compounds of the following formula can be used as laundry softeners:
N SHEA I
L I
wherein R5 is a long-chain aliphatic group with 8 to 22 carbon atoms, R6 is an alkyd group with 1 to 6 carbon atoms, R7 is an alkylamidoalkyl group with 8 to 22 carbon atoms or a hydroxyl-alkyd group with 2 to 6 carbon atoms. Examples of these are 2-heptadecyl-1-methyl-1-[(2-stearyl-amido-ethyl]-iimidazoline-methyl sulfate and 2-heptadecyl-1-hydroxyethyl-imidazoline chloride.
The hollowing are examples of amine that can be used in the laundry softener according to the present invention primary tallolamine, primary cocoa mine, primary hydrated tallow-amine, tallol-1,3-propylenediamine, olyl-1,3-propylenedimaine and coco-1,3-propylenediamine. The water-soluble salts of the issue 4 amine listed are, for example, the sulfate, the hydrogen sulfate and the chloride. The assignation "coo" stands for Patty acid groups present in the fatty acids of the coconut oil. Such acids contain 8 to 18 carbon atoms per molecule, acids with 12 to 14 carbon atoms predominating The laundry softener concentrates according to the present invention can contain up to a total of White of a solvent and water, relative to the quantity of softener.
The following can be used as solvents: isopropanol, ethanol, glycol, bouncily sulfonate, toluol sulfonate and xylol sulfonate or wetting agents such as non-lonic wetting agents, for example, nonylphenolethoxylate and fatty alcohol ethoxylates.
The laundry softener concentrate according to the present invention is an easy-running powder. It is easily stored and requires very little packaging space since it is in powder form. It can be easily measured and can, if necessary, be come brined with washing agents.
The present invention will be further illustrated by way of the following Examples Example 1 ROCKET 3099 (100%) (a trademark for a Deft acid ester ~imethylammonium sulfate) is heated to 60 deg. C and mixed with White Superannuate 22 S (a trade mark. The laundry softener concentrate that is obtained is a parboil powder.
- Example 2 The 75% laundry softener dispersion urea W 7500 (75%) (a trade mark for a qua ternary imidazolineiumdialkyl compound 75%
with 25% isopropanol) is mixed with White Superannuate 22 (a trade mark). The laundry softener concentrate that is obtained is a 3Q parboil powder.
The 75% laundry softener dispersion ROCKET W 7500 H
Tao (a trade mark) is first melted and then mixed with 35% Superannuate 50 (a trade mark).
The laundry softener concentrate that is obtained is a parboil powder.
The 755 laundry softener dispersion Praepagen WOK (a trade mark for distearyldimethyl ammonium chloride) is mixed with 32% Superannuate 50 S (a trade Merck The laundry softener concentrate that is obtained is a parboil powder.
The silicic acid Superannuate 22 (a trade mark) is a pro-cipitated and spray-dried silicic acid to which the following data apply:
Surface area as per BUT m go 190 Average size of primary particles no 18 Tamped density as per DIN 53 194 g/l 270 Drying loss as per DIN 55 921 (oh at 105C) 6 Annealing loss as per DIN 55 921 for substance dried for oh at 105C
(oh at 1000C) % 5 pi value as per DIN 53 200 (in I aqueous solution) 6.3 Sue (relative to substance annealed oh at 1000C) % 98.00 Aye (relative to substance annealed oh at 1000C % 0.20 Noah (relative to substance annealed oh at 1000C % 1.00 Foe (relative to substance annealed oh at 1000C) % 0-03 Coo (relative to substance annealed oh at lQ00C~ % Jo ,.
I
(relative to substance annealed oh at 1000C) % 0.8 Of (relative to substance annealed oh at 1000C) % Jo Sieve residue as per DIN 53 580 (according to Mocker, 45 m) % 0.5 The silicic acid Superannuate 22 S (a trade mark) that is used is a spray-dried and ground precipitation silicic acid to which the following data apply:
Surface area as per set m go 190 Average size of primary particles no 18 Tamped density as per DIN 53 194 g/l 120 Drying loss as per DIN 55 921 (2 h at 105C) % 6 Annealing loss as per DIN 55 921 for substance dried for oh at 105C
(2 h at 1000C) % 5 pi value as per DIN 53 200~
(in I aqueous solution) 6.3 . Sue (relative to substance annealed oh at 1000C) 98.00 Aye (relative to substance annealed oh at 1000C) 0.20 Noah (relative to substance annealed OH at 1000C) % 1.00 Foe (relative to substance annealed oh at 1000C) 0~03 Coo (relative to substance annealed oh at 1000C) % --relative to substance annealed oh at 1000C) % 0.8 Of (relative to substance annealed oh at 10n0C) Jo Sieve residue as per DIN 53 580 (according to Mocker, 45 m) 0.2 The silicic acids Superannuate 50 and 50 S (-trade marks) are spray-dried and ground precipitation silicic acids to which the following data apply:
Superannuate Surface area as per BET m go 450 450 Tamped density as per DIN 53 194 g/l 200 100*
Drying loss as per DIN 55 921 (oh at 105C) % 6 6 Annealing loss as per DIN 55 921 for substance dried for await 105C (oh at 1000C) % 5 5 pi value as per DIN 53 200 (in 5% aqueous solution 7.0 7.0 Sue (relative to substance annealed oh at 1000C) % 99.00 99.0 Aye (relative to substance annealed oh at 1000C) % 0.20 0.20 Noah (relative to substance annealed oh at 1000C) % 0.30 0.30 pa Foe (relative to substance annealed oh at 1000C) % 0.03 0.03 (relative to substance annealed oh at 1000C) % 0.4 0-4 Sieve group as per DIN 53 580 (according to Mocker, 45 m) % 0.5 0.1 Dibutylphthalate uptake % 330.0 330.0 * - uncompressed material
The puissant invention zealots to a laundry softener con-cent rate.
sundry softeners are added to laundry wash water in order to improve the feel and increase the softness of textile fabrics. Laundry softeners of this kind may be primarily cat ionic tetraalkyl amonium compounds and imidazoline derive-lives, the effectiveness of which depends on the chemical char-acterists of the alkyd groups. Since laundry softeners are in-soluble in water as a result of these long chain alkyd group, they are commercially available in the form of 5-8% aqueous disk pensions. The great dilution has clear economic disadvantages.
Large, bulky and costly containers are needed and a great deal of water has to be transported. Further, a conceivable, auto-matte dispensing in an automatic domestic washing machine is rendered extremely difficult on account of the large volume of the required tanks.
It is known to use laundry softener concentrates that are also dispersions having a laundry softener content of 15-30~.
However, the viscosity of these laundry softener concentrates increase exponentially with increasing concentration. (Tensile Detergents 18, ~1981) 5, pp. 243 - 246).
The present invention provides a laundry softener con-cent rate that consists of a mixture of one or several laundry softeners, synthetic silicic acid and, it necessary, one or several solvents.
In a preferred embodiment of the invention the laundry softener concentrate consists of the laundry softener alone, with up to White synthetic silicic acid.
In a particularly preferred embodiment the laundry sol-loner concentrate may contain up to White synthetic silicic acid. The active substance content then amounts to 70~.
In addition to oven-dried and ground precipitated silicic pa ~2~7~
acids, spray dried precipitated silicic acids that can be either ground or unground can be used. High-temperature hydrolytic ally produced (pyrogenically produced) silicic acids can also be used.
The cat ionic laundry softeners present in the laundry softener concentrate are commercially available and well known products. These are preferably cat ionic compounds that contain nitrogen, such as qua ternary ammonium compounds and amine salts that have one or two straight chain organic groups that contain lo at least eight carbon atoms, of which at least one group con-twins 12-22 carbon atoms. It is preferable that qua ternary ammonium compounds of the following formula are present as laundry softeners.
--Al R Go \ N
2 / \ 4 wherein Al is a long-chain aliphatic group with 8 to 22 carbon atoms or a fatty acid ester group, R is a long-chain aliphatic group with 8 to 22 carbon atoms or an alkyd group with l to 6 carbon atoms or an aureole, airlocks, alkoxy, or aralkyl group with 6 to 28 carbon atoms or a fatty acid ester group, R3 and R4 are alkyd or hydroxyalkyl groups with l to 6 carbon atoms or hydroxypolyalkoxyalkyl groups with 4 to 20 carbon atoms and I is an anion that forms a water-soluble salt, such as for example, a halide e.g., chloride, bromide, or iodide, sulfate, methosulfate, acetate, hydroxide anion or a similar inorganic solvent and moo or dibasic group. The nitrogen can be a cyclic nitrogen and the R2 and R3 groups can be replaced by a ring of 4 to 5 carbon atoms. Especially good results are obtained with compounds of the above-quoted formulae in that the groups Al, R , R and R groups are straight-chain aliphatic groups such ~2~i'7~
as, for example, aliphatic groups. Tile following are good ox-apples of ~uaternary ammonium compounds that can be used as laundry softeners in the laundry softening agent according to the present invention: hydrated di-talloldimethylammonium chloride; ethoxylated distearyl-dimethylammonium chloride;
dimethyldistearylammonium chloride; trimethylstearyl-ammonium bromide; cetyltrimethyl-ammonium chloride, dicocodimethyl-ammonium-chloride; cetylpyridinium chloride; alkyldimethylbenzyl-ammonium chloride with a higher alkyd group; diisobutylphenoxy-ethyldimethylbenzyl-ammonium chloride; laurylisochinolinium bromide; distearyldimethyl-ammonium bromide; distearyldimethyl-ammonium sulfate; dimèthyl-diacachidyl-behenyl-ammonium chloride;
di(soya)-dimethylammonium chloride; and stearyldimethylbenzyl--ammonium chloride.
Compounds of the following formula can be used as laundry softeners:
N SHEA I
L I
wherein R5 is a long-chain aliphatic group with 8 to 22 carbon atoms, R6 is an alkyd group with 1 to 6 carbon atoms, R7 is an alkylamidoalkyl group with 8 to 22 carbon atoms or a hydroxyl-alkyd group with 2 to 6 carbon atoms. Examples of these are 2-heptadecyl-1-methyl-1-[(2-stearyl-amido-ethyl]-iimidazoline-methyl sulfate and 2-heptadecyl-1-hydroxyethyl-imidazoline chloride.
The hollowing are examples of amine that can be used in the laundry softener according to the present invention primary tallolamine, primary cocoa mine, primary hydrated tallow-amine, tallol-1,3-propylenediamine, olyl-1,3-propylenedimaine and coco-1,3-propylenediamine. The water-soluble salts of the issue 4 amine listed are, for example, the sulfate, the hydrogen sulfate and the chloride. The assignation "coo" stands for Patty acid groups present in the fatty acids of the coconut oil. Such acids contain 8 to 18 carbon atoms per molecule, acids with 12 to 14 carbon atoms predominating The laundry softener concentrates according to the present invention can contain up to a total of White of a solvent and water, relative to the quantity of softener.
The following can be used as solvents: isopropanol, ethanol, glycol, bouncily sulfonate, toluol sulfonate and xylol sulfonate or wetting agents such as non-lonic wetting agents, for example, nonylphenolethoxylate and fatty alcohol ethoxylates.
The laundry softener concentrate according to the present invention is an easy-running powder. It is easily stored and requires very little packaging space since it is in powder form. It can be easily measured and can, if necessary, be come brined with washing agents.
The present invention will be further illustrated by way of the following Examples Example 1 ROCKET 3099 (100%) (a trademark for a Deft acid ester ~imethylammonium sulfate) is heated to 60 deg. C and mixed with White Superannuate 22 S (a trade mark. The laundry softener concentrate that is obtained is a parboil powder.
- Example 2 The 75% laundry softener dispersion urea W 7500 (75%) (a trade mark for a qua ternary imidazolineiumdialkyl compound 75%
with 25% isopropanol) is mixed with White Superannuate 22 (a trade mark). The laundry softener concentrate that is obtained is a 3Q parboil powder.
The 75% laundry softener dispersion ROCKET W 7500 H
Tao (a trade mark) is first melted and then mixed with 35% Superannuate 50 (a trade mark).
The laundry softener concentrate that is obtained is a parboil powder.
The 755 laundry softener dispersion Praepagen WOK (a trade mark for distearyldimethyl ammonium chloride) is mixed with 32% Superannuate 50 S (a trade Merck The laundry softener concentrate that is obtained is a parboil powder.
The silicic acid Superannuate 22 (a trade mark) is a pro-cipitated and spray-dried silicic acid to which the following data apply:
Surface area as per BUT m go 190 Average size of primary particles no 18 Tamped density as per DIN 53 194 g/l 270 Drying loss as per DIN 55 921 (oh at 105C) 6 Annealing loss as per DIN 55 921 for substance dried for oh at 105C
(oh at 1000C) % 5 pi value as per DIN 53 200 (in I aqueous solution) 6.3 Sue (relative to substance annealed oh at 1000C) % 98.00 Aye (relative to substance annealed oh at 1000C % 0.20 Noah (relative to substance annealed oh at 1000C % 1.00 Foe (relative to substance annealed oh at 1000C) % 0-03 Coo (relative to substance annealed oh at lQ00C~ % Jo ,.
I
(relative to substance annealed oh at 1000C) % 0.8 Of (relative to substance annealed oh at 1000C) % Jo Sieve residue as per DIN 53 580 (according to Mocker, 45 m) % 0.5 The silicic acid Superannuate 22 S (a trade mark) that is used is a spray-dried and ground precipitation silicic acid to which the following data apply:
Surface area as per set m go 190 Average size of primary particles no 18 Tamped density as per DIN 53 194 g/l 120 Drying loss as per DIN 55 921 (2 h at 105C) % 6 Annealing loss as per DIN 55 921 for substance dried for oh at 105C
(2 h at 1000C) % 5 pi value as per DIN 53 200~
(in I aqueous solution) 6.3 . Sue (relative to substance annealed oh at 1000C) 98.00 Aye (relative to substance annealed oh at 1000C) 0.20 Noah (relative to substance annealed OH at 1000C) % 1.00 Foe (relative to substance annealed oh at 1000C) 0~03 Coo (relative to substance annealed oh at 1000C) % --relative to substance annealed oh at 1000C) % 0.8 Of (relative to substance annealed oh at 10n0C) Jo Sieve residue as per DIN 53 580 (according to Mocker, 45 m) 0.2 The silicic acids Superannuate 50 and 50 S (-trade marks) are spray-dried and ground precipitation silicic acids to which the following data apply:
Superannuate Surface area as per BET m go 450 450 Tamped density as per DIN 53 194 g/l 200 100*
Drying loss as per DIN 55 921 (oh at 105C) % 6 6 Annealing loss as per DIN 55 921 for substance dried for await 105C (oh at 1000C) % 5 5 pi value as per DIN 53 200 (in 5% aqueous solution 7.0 7.0 Sue (relative to substance annealed oh at 1000C) % 99.00 99.0 Aye (relative to substance annealed oh at 1000C) % 0.20 0.20 Noah (relative to substance annealed oh at 1000C) % 0.30 0.30 pa Foe (relative to substance annealed oh at 1000C) % 0.03 0.03 (relative to substance annealed oh at 1000C) % 0.4 0-4 Sieve group as per DIN 53 580 (according to Mocker, 45 m) % 0.5 0.1 Dibutylphthalate uptake % 330.0 330.0 * - uncompressed material
Claims (12)
THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLUSIVE
PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:
1. A laundry softener concentrate consisting essentially of a mixture of at least one laundry soft-ener and synthetic silicic acid.
2. A laundry softener concentrate according to claim 1, consisting essentially of at least one laundry softener and up to 50%-wt of synthetic silicic acid.
3. A laundry softener concentrate according to claim 1, consisting essentially of at least one laundry soft-ener and up to 35%-wt of synthetic silicic acid.
4. A laundry softener concentrate according to claim 1, consisting essentially of at least one laundry softener and up to 30%-wt of synthetic silicic acid.
5. A concentrate according to claim 1, 2 or 3, con-taining a plurality of water softeners.
6. A concentrate according to claim 1, which also contains at least one solvent.
7. A concentrate according to claim 1, 2 or 3, in which each laundry softener is the formula X?
where R1 is a long-chain aliphatic group with 8 to 22 carbon atoms or a fatty acid ester group, R2 is a long-chain alipha-tic group with 8 to 22 carbon atoms or an alkyl group with 1 to 6 carbon atoms or an aryl, aryloxy, alkoxy, or aralkyl group with 6 to 28 carbon atoms, or a fatty acid ester group or R2 and R3 together with the nitrogen atom form a 5- or 6-membered ring, R3 and R4 are alkyl or hydroxyalkyl group with 1 to 6 carbon atoms or hydroxypolyalkoxyalkl groups with 4 to 20 carbon atoms, and X? is an anion that forms a water-soluble salt.
where R1 is a long-chain aliphatic group with 8 to 22 carbon atoms or a fatty acid ester group, R2 is a long-chain alipha-tic group with 8 to 22 carbon atoms or an alkyl group with 1 to 6 carbon atoms or an aryl, aryloxy, alkoxy, or aralkyl group with 6 to 28 carbon atoms, or a fatty acid ester group or R2 and R3 together with the nitrogen atom form a 5- or 6-membered ring, R3 and R4 are alkyl or hydroxyalkyl group with 1 to 6 carbon atoms or hydroxypolyalkoxyalkl groups with 4 to 20 carbon atoms, and X? is an anion that forms a water-soluble salt.
8, A concentrate according to claim 1, 2 or 3, in which the laundry softener is selected from hydrated ditall-oldimethylammonium chloride; ethoxylated distearyl-dimethylamm-onium chloride; dimethyldistearylammonium chloride; trimethyl-stearyl-ammonium bromide; cetyltrimethyl-ammonium chloride;
dicocodimethyl-ammonium-chloride; cetylpyridinium chloride;
alkyldimethylbenzyl-ammonium chloride with a higher alkyl group; diisobutylphenoxyethyldimethylbenzyl-ammonium chloride;
laurylisochinolinium bromide; distearyldimethyl-ammonium brom-ide; distearyldimethyl-ammonium sulfate; dimethyl-diacachidyl-behenyl-ammonium chloride; di(soya)-dimethylammonium chloride;
and stearyldimethylbenzyl-ammonlium chloride.
dicocodimethyl-ammonium-chloride; cetylpyridinium chloride;
alkyldimethylbenzyl-ammonium chloride with a higher alkyl group; diisobutylphenoxyethyldimethylbenzyl-ammonium chloride;
laurylisochinolinium bromide; distearyldimethyl-ammonium brom-ide; distearyldimethyl-ammonium sulfate; dimethyl-diacachidyl-behenyl-ammonium chloride; di(soya)-dimethylammonium chloride;
and stearyldimethylbenzyl-ammonlium chloride.
9. A concentrate according to claim 1, 2 or 3, in which the laundry softener of the formula X?
where R5 is a long-chain aliphatic group with 8 to 22 carbon atoms, R6 is an alkyl group with 1 to 6 carbon atoms, R7 is an alkylamidoalkyl group with 8 to 22 carbon atoms or a hydroxy-alkyl group with 2 to 6 carbon atoms.
where R5 is a long-chain aliphatic group with 8 to 22 carbon atoms, R6 is an alkyl group with 1 to 6 carbon atoms, R7 is an alkylamidoalkyl group with 8 to 22 carbon atoms or a hydroxy-alkyl group with 2 to 6 carbon atoms.
10. A concentrate according to claim 1, 2 or 3, in which the laundry softener is selected from 2-heptadecyl-1-methyl-1-[(2-stearyl-amido-ethyl]-imidazolinemethylsulfate and 2-heptadecyl-1-hydroxyethyl-imidazoline chloride.
11. A concentrate according to claim 1, 2 or 3, in which the laundry softener is selected from primary tallola-mine, primary cocoamine, primary hydrated tallolamine, tallol-1,3-propylenediamine, olyl-1,3-propylenediamine and coco-1, 3-propylenediamine.
12. A concentrate according to claim 6, in which the solvent is selected from isopropanol, ethanol, glycol, benzol sulfonate, toluol sulfonate and xylol sulfonate.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3243983.0 | 1982-11-27 | ||
| DE3243983A DE3243983C2 (en) | 1982-11-27 | 1982-11-27 | Laundry softener concentrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1226704A true CA1226704A (en) | 1987-09-15 |
Family
ID=6179241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000441938A Expired CA1226704A (en) | 1982-11-27 | 1983-11-25 | Laundry softener concentrate |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4589989A (en) |
| EP (1) | EP0111074B2 (en) |
| JP (1) | JPS59106575A (en) |
| AT (1) | ATE25402T1 (en) |
| CA (1) | CA1226704A (en) |
| DE (2) | DE3243983C2 (en) |
| IL (1) | IL70057A (en) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3243983C2 (en) * | 1982-11-27 | 1984-11-22 | Degussa Ag, 6000 Frankfurt | Laundry softener concentrate |
| DE3402437A1 (en) * | 1984-01-25 | 1985-07-25 | Rewo Chemische Werke Gmbh, 6497 Steinau | POWDERED SOFT SOFT DETERGENT, METHOD FOR THE PRODUCTION THEREOF AND DETERGENT CONTAINING THIS |
| DE3416472A1 (en) * | 1984-05-04 | 1985-11-07 | Hoechst Ag, 6230 Frankfurt | DETERGENT CONTAINING SOFTENER |
| DE3434709A1 (en) * | 1984-09-21 | 1986-04-03 | Hoechst Ag, 6230 Frankfurt | ADSORBENTS BASED ON ORGANOPHILIC MODIFIED LAYERED SILICA |
| JPH0742649B2 (en) * | 1987-05-26 | 1995-05-10 | 花王株式会社 | Softening agent |
| ZA907746B (en) * | 1989-10-16 | 1992-05-27 | Colgate Palmolive Co | New softening compositions and methods for making and using same |
| US5185088A (en) * | 1991-04-22 | 1993-02-09 | The Procter & Gamble Company | Granular fabric softener compositions which form aqueous emulsion concentrates |
| GB9209170D0 (en) * | 1992-04-28 | 1992-06-10 | Unilever Plc | Rinse conditioner |
| WO1994007979A1 (en) * | 1992-09-28 | 1994-04-14 | The Procter & Gamble Company | Method for using solid particulate fabric softener in automatic dosing dispenser |
| US5458799A (en) * | 1993-08-03 | 1995-10-17 | Amway Corporation | Mix process for formulating detergents |
| SK284220B6 (en) * | 1994-04-07 | 2004-11-03 | Unilever Nv | Fabric softening composition |
| GB9406824D0 (en) * | 1994-04-07 | 1994-06-01 | Unilever Plc | Fabric softening composition |
| AU2074397A (en) * | 1996-03-15 | 1997-10-01 | Amway Corporation | Powder detergent composition having improved solubility |
| US5714451A (en) * | 1996-03-15 | 1998-02-03 | Amway Corporation | Powder detergent composition and method of making |
| AU2075097A (en) * | 1996-03-15 | 1997-10-01 | Amway Corporation | Discrete whitening agent particles, method of making, and powder detergent containing same |
| US5714450A (en) * | 1996-03-15 | 1998-02-03 | Amway Corporation | Detergent composition containing discrete whitening agent particles |
| US6177397B1 (en) | 1997-03-10 | 2001-01-23 | Amway Corporation | Free-flowing agglomerated nonionic surfactant detergent composition and process for making same |
| DE19721885A1 (en) * | 1997-05-26 | 1998-12-03 | Henkel Kgaa | Process for the production of granules containing cationic surfactants |
| US6130193A (en) * | 1998-02-06 | 2000-10-10 | Precision Fabrics Group, Inc. | Laundry detergent compositions containing silica for laundry detergent sheets |
| US7232962B2 (en) * | 1998-05-28 | 2007-06-19 | Richard Rynd | Mobile hospital bed scale |
| US5990423A (en) * | 1998-05-28 | 1999-11-23 | Eze Weigh, Llc | Mobile hospital bed scale |
| GB0207483D0 (en) | 2002-03-28 | 2002-05-08 | Unilever Plc | Fabric conditioning compositions |
| GB0207481D0 (en) | 2002-03-28 | 2002-05-08 | Unilever Plc | Solid fabric conditioning compositions |
| GB0207484D0 (en) | 2002-03-28 | 2002-05-08 | Unilever Plc | Solid fabric conditioning compositions |
| EP1502942A1 (en) * | 2003-07-29 | 2005-02-02 | Clariant International Ltd. | Solid softener composition |
| CA2562107C (en) | 2004-04-09 | 2012-10-16 | Unilever Plc | Granulate for use in a cleaning product and process for its manufacture |
| US20070130694A1 (en) * | 2005-12-12 | 2007-06-14 | Michaels Emily W | Textile surface modification composition |
| US7655609B2 (en) | 2005-12-12 | 2010-02-02 | Milliken & Company | Soil release agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3095373A (en) * | 1959-01-30 | 1963-06-25 | Wyandotte Chemicals Corp | Fabric softeners |
| US3546115A (en) * | 1967-02-28 | 1970-12-08 | Cargill Inc | Fabric softener |
| US3573091A (en) * | 1967-11-13 | 1971-03-30 | Armour & Co | Method of preparing water-dispersible softener compositions and products thereby |
| US3533942A (en) * | 1968-04-29 | 1970-10-13 | American Potash & Chem Corp | Process for loading expanded water-solution hydrate salt particles |
| JPS4835637B1 (en) * | 1970-12-23 | 1973-10-29 | ||
| US4001123A (en) * | 1972-09-11 | 1977-01-04 | Colgate-Palmolive Company | Fabric softener compositions containing N-alkyl-1,3-propylene diamine treated with maleic anhydride |
| US3977980A (en) * | 1974-01-04 | 1976-08-31 | American Can Company | Solid fabric conditioner composition |
| LU71307A1 (en) * | 1974-11-18 | 1976-09-06 | ||
| US4255294A (en) * | 1975-04-01 | 1981-03-10 | Lever Brothers | Fabric softening composition |
| LU75088A1 (en) * | 1976-06-04 | 1978-01-18 | ||
| US4025444A (en) * | 1975-08-18 | 1977-05-24 | The Procter & Gamble Company | Fabric softening agents |
| US4155855A (en) * | 1977-07-06 | 1979-05-22 | The Procter & Gamble Company | Concentrated liquid fabric softener composition |
| US4199465A (en) * | 1977-12-23 | 1980-04-22 | The Procter & Gamble Company | Laundry detergent substrate articles |
| DE3069767D1 (en) * | 1979-09-29 | 1985-01-17 | Procter & Gamble | Detergent compositions |
| DE3066202D1 (en) * | 1979-11-03 | 1984-02-23 | Procter & Gamble | Granular laundry compositions |
| JPS604879B2 (en) * | 1981-02-20 | 1985-02-07 | 花王株式会社 | cleaning composition |
| US4392965A (en) * | 1981-11-12 | 1983-07-12 | Woodward Fred E | Laundry softener antistatic composition |
| US4417999A (en) * | 1982-06-03 | 1983-11-29 | Witco Chemical Corporation | Free flowing antistatic composition |
| GB2124644B (en) * | 1982-07-05 | 1986-03-19 | Lion Corp | Method for granulating cationic surfactant |
| DE3243983C2 (en) * | 1982-11-27 | 1984-11-22 | Degussa Ag, 6000 Frankfurt | Laundry softener concentrate |
| DE3402437A1 (en) * | 1984-01-25 | 1985-07-25 | Rewo Chemische Werke Gmbh, 6497 Steinau | POWDERED SOFT SOFT DETERGENT, METHOD FOR THE PRODUCTION THEREOF AND DETERGENT CONTAINING THIS |
-
1982
- 1982-11-27 DE DE3243983A patent/DE3243983C2/en not_active Expired
-
1983
- 1983-09-23 DE DE8383109466T patent/DE3369699D1/en not_active Expired
- 1983-09-23 AT AT83109466T patent/ATE25402T1/en not_active IP Right Cessation
- 1983-09-23 EP EP83109466A patent/EP0111074B2/en not_active Expired - Lifetime
- 1983-10-26 IL IL70057A patent/IL70057A/en unknown
- 1983-11-25 CA CA000441938A patent/CA1226704A/en not_active Expired
- 1983-11-25 JP JP58220823A patent/JPS59106575A/en active Granted
-
1984
- 1984-11-16 US US06/672,164 patent/US4589989A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US4589989A (en) | 1986-05-20 |
| IL70057A (en) | 1987-10-30 |
| EP0111074B1 (en) | 1987-02-04 |
| EP0111074A3 (en) | 1985-08-14 |
| ATE25402T1 (en) | 1987-02-15 |
| EP0111074A2 (en) | 1984-06-20 |
| IL70057A0 (en) | 1984-01-31 |
| DE3369699D1 (en) | 1987-03-12 |
| DE3243983A1 (en) | 1984-05-30 |
| EP0111074B2 (en) | 1990-04-18 |
| JPS59106575A (en) | 1984-06-20 |
| JPH0152506B2 (en) | 1989-11-09 |
| DE3243983C2 (en) | 1984-11-22 |
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| MKEX | Expiry |