CA1195114A - Heat-sensitive magnetic transfer element - Google Patents
Heat-sensitive magnetic transfer elementInfo
- Publication number
- CA1195114A CA1195114A CA000398280A CA398280A CA1195114A CA 1195114 A CA1195114 A CA 1195114A CA 000398280 A CA000398280 A CA 000398280A CA 398280 A CA398280 A CA 398280A CA 1195114 A CA1195114 A CA 1195114A
- Authority
- CA
- Canada
- Prior art keywords
- heat
- transfer element
- transferring layer
- magnetic
- wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000005291 magnetic effect Effects 0.000 title claims abstract description 56
- 239000000843 powder Substances 0.000 claims abstract description 15
- 239000000126 substance Substances 0.000 claims abstract description 14
- 230000005294 ferromagnetic effect Effects 0.000 claims abstract description 9
- 238000002844 melting Methods 0.000 claims abstract description 9
- 230000008018 melting Effects 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 13
- 239000001993 wax Substances 0.000 claims description 13
- -1 polypropylene Polymers 0.000 claims description 12
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 239000004793 Polystyrene Substances 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 239000005061 synthetic rubber Substances 0.000 claims description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- 239000004203 carnauba wax Substances 0.000 claims description 3
- 235000013869 carnauba wax Nutrition 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920003051 synthetic elastomer Polymers 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- 239000001856 Ethyl cellulose Substances 0.000 claims description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 2
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 2
- 229920000459 Nitrile rubber Polymers 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 229930182556 Polyacetal Natural products 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 claims description 2
- 235000013871 bee wax Nutrition 0.000 claims description 2
- 239000012166 beeswax Substances 0.000 claims description 2
- 229940092738 beeswax Drugs 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 239000012170 montan wax Substances 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 235000019809 paraffin wax Nutrition 0.000 claims description 2
- 235000019271 petrolatum Nutrition 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920006324 polyoxymethylene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000005060 rubber Substances 0.000 claims description 2
- 150000003505 terpenes Chemical class 0.000 claims description 2
- 235000007586 terpenes Nutrition 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 239000002174 Styrene-butadiene Substances 0.000 claims 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
- 229910052729 chemical element Inorganic materials 0.000 claims 1
- 229920003244 diene elastomer Polymers 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 229960004667 ethyl cellulose Drugs 0.000 claims 1
- 239000004200 microcrystalline wax Substances 0.000 claims 1
- 235000019808 microcrystalline wax Nutrition 0.000 claims 1
- 239000011115 styrene butadiene Substances 0.000 claims 1
- 239000000123 paper Substances 0.000 description 11
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 6
- 239000011800 void material Substances 0.000 description 5
- 239000004606 Fillers/Extenders Substances 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- 229910018104 Ni-P Inorganic materials 0.000 description 2
- 229910018536 Ni—P Inorganic materials 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- AYTAKQFHWFYBMA-UHFFFAOYSA-N chromium dioxide Chemical compound O=[Cr]=O AYTAKQFHWFYBMA-UHFFFAOYSA-N 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910000521 B alloy Inorganic materials 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 229910020598 Co Fe Inorganic materials 0.000 description 1
- 229910002519 Co-Fe Inorganic materials 0.000 description 1
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 101000965313 Legionella pneumophila subsp. pneumophila (strain Philadelphia 1 / ATCC 33152 / DSM 7513) Aconitate hydratase A Proteins 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 229910017709 Ni Co Inorganic materials 0.000 description 1
- 229910003267 Ni-Co Inorganic materials 0.000 description 1
- 229910003271 Ni-Fe Inorganic materials 0.000 description 1
- 229910003262 Ni‐Co Inorganic materials 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 241000206607 Porphyra umbilicalis Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920013623 Solprene Polymers 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 229940058172 ethylbenzene Drugs 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011086 glassine Substances 0.000 description 1
- 238000007757 hot melt coating Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/38285—Contact thermal transfer or sublimation processes characterised by magnetic components in the transfer ink
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K1/00—Methods or arrangements for marking the record carrier in digital fashion
- G06K1/12—Methods or arrangements for marking the record carrier in digital fashion otherwise than by punching
- G06K1/126—Methods or arrangements for marking the record carrier in digital fashion otherwise than by punching by photographic or thermographic registration
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/90—Magnetic feature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/913—Material designed to be responsive to temperature, light, moisture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/914—Transfer or decalcomania
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/256—Heavy metal or aluminum or compound thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/256—Heavy metal or aluminum or compound thereof
- Y10T428/257—Iron oxide or aluminum oxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/31855—Of addition polymer from unsaturated monomers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/31931—Polyene monomer-containing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31935—Ester, halide or nitrile of addition polymer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
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- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
Abstract
Title: Heat-sensitive magnetic transfer element Abstract Heat-sensitive magnetic transfer element for printing a magnetic image to be recognized by a magnetic ink character reader (MICR), comprising a heat-resisting foundation and a heat-sensitive trasferrring layer provided on the foundation, the transferring layer which includes a ferromagnetic substance powder and has a melting point of 50 to 120°C. being readily melted and transferred on a receiving paper in the form of magnetic image by a thermal printer.
Description
~95~
- 2 BAC~ROUND OF THE IN~rENTION
The present invention relates to a heat-sensitive magnetlc transfer element and more particularly to a heat-sensitive magnetic transfer element which allows a thermal printer to prepare a printed magnetic image recognized by a magne-tic ink character reader The magnetic ink character reader (hereinafter referred to as MICR) can read and recognize the certain printed magnetic image, such as character, or mark, which is printed to bill, check, credit card, pass, traffic census card, or the like. A magne~ic head in the MICR
converts the variations of magnetic portions corresponding to various characters and marks into predetermined signals, and volt;ages are detected to recognize the characters and marks.
In that case, it is necessary that each of the charcters and marks to be read by the magnetic head has a certain shape, dimensions and allowable ranges of dimensions in addition to the certain magnetic signal levels. Therefore, the allowable ranges as to E13B type face employed in American Bank Association are defined in JIS C 6251 (Japanese Industrial Standard).
E13B type face defined in JIS C 6251 consists of 10 numbers (0 to 9) and 4 special marks. According to JIS C 6251~ a character height, a character width, a corner radius, allowable ranges of those and an allowable range of a void with respect to each character are described. In addition to E13B type face, CMC7 type face is well known as type face for MICR. CMC7 type face is formed by arranging 7 longitudinal bars with 2 kinds of intervals, and each of CMC7 type faces can be magnetically recognized by combinations of 2 kinds of intervals. Thus, CMC7 type faces consist of 10 numbers, 26 large alphabets and 5 special marks, and dimensions and magnetic property of CMC7 type face are determined by European Computer Manufactures Association.
The prin~ed image of the above type ace for MICR is formed by transferring a magnetic ink onto a receiving paper by an impact printer such as typewriter.
The magnetic ink including a magnetic substallce powcler is coated and dried on a foundation such as plas~lc film to form a pressure-sensitive magntic transfer element.
Such a pressure-sensitive magnetic transfer element is disclosed in, for example, Japanese Patent Publication No. 21449/1970.
However~ the use of the pressure-sensitive magnetic transfer element results in generating noise due to impact system, and further cannot perform high printing speed. In addition, the above transfer element tends to generate voids in the printed magnetic image.
OBJECTS OF THF. INVENTION
.. . .
A main object of the invention is to provide a heat-sensitive magnetic transfer element which can easily produce a printed magnetic image by a thermal printer with hlgh printing speed without generating noise .
Another object of the invention is to provide a heat-sensitive magnetic transfer element which can produce a printed magnetic image having high accuracy of dimensions and high magnetlc pro~erties.
Other objects and advantages of the invention will become apparent from the following descriptions with reference to the accompanying drawings.
BRIEF DESCRIPTION OF THE IN~ENrION
Fig. 1 is a schematically sectional view for showing an embodiment of a heat-sensitive magnetic transfer element of the invention; and ~ ig. 2 is a explanatory view for showing a printing method using a heat-sensitive magnetic transfer element of the invention.
DFTAILED EXPLANATION OF THE INVENTION
Fig. 1 shows a heat-sensitive magnetic transfer element according to the invention comprising a heat--- '1 --resisting foundation 1, and a heat-sensitive transferring laver 2 including a ferromagnetic substance powder and having a melting temperature of 50 to :L2~C., which is measured at a heating-up velocity of 40C./min. by Meihosha-type melting point measuring device available from Meihosha ~actory Ltd.
The heat-sensitive transferring layer 2 is one layer formed by uniformly admixing a binder material of wax and/or thermoplastic resin including, if necessary, additives such as fat and oil, extender pigment, or dispersant, with the magnetic substance powder. Such a transferring layer can be obtained by means of ~lot-melt coating or solvent coating.
The magnetic substance powder is pre:Eerably included in the heat-sensitive transferring layer 2 at a range of 30 to 97 % by weight per total amount of the transferring layer 2. When the magnetic substance powder content is less than the above range, the magnetic properties of the printed image are lowered, whereby reading of MICR becomes difficult. On the other hand, when the magnetic substance powder content is more than the above range, the melt-transfer property of the transferring layer 2 and the adhesion strength of the printed image against the image receiving paper are lowered.
In the case that the heat-sensitive transferring layer 2 is provided on the heat-resisting foundation 1 by means of hot-melt coating, wax is preferably employed as a main ingredient of the binder material to prepare the heat-sensitive transferring layer. In that case, 30 to 97 % by weight of the ferromagnetic substance powder, 20 to 70 % by weight of wax, n to 30 ~ by weight of thermoplastic resin~ o to 30 % by weight of fat and oil, 0 to 30 % by weight of extender pigment and 0 to 2 % by weight of dispersant are used per total amount of the heat-sensitive transferring layer 2.
In the case that the heat-sensitive 95~
trans-Eerring ].ayer 2 is provided on the heat-resisting :Eollndati.on l by means o solvent coating, 3n to ~7 ~ by weight of t~e ferromagnetic su~s~ance powder, ~ to 2() %
by weight of wax, 20 to 7n ~ by we;.ght o:E thermoplastic resin, 0 to 30 ~ by we;ght o:E fat and oil, 0 to 3() % by weight of extender pigment and n to 2 % by weight of clispersant are used per total amonnt of the heat-sensitive trans:Eerring layer~ and are homogeneously dispersed in organic solvent such as toluene, metilyl ethyl ketone, methyl isobutyl ketone, cyclohexane, butyl butyrate, dioxane, or ethyl-benzene.
An example of the ferromagnetic substance powder is ~-Fe2O3, ~-Fe2O3 inclllding Co, Fe3O4, Fe3O4 including Co, CrO2, Co-Cr alloy, Co-Fe alloy, Co-Ni-P
alloy, Co-Ni-Fe alloy, Co-Ni-Fe-B alloy, Co-Ni-~n alloy, Fe-Mn-Zn alloy, ~e-Co-Ni-Cr alloy, Fe-Co-Ni-P alloy, Ni-Co alloy, or the like. The aspect ratio (L/D) of the ferromagnetic substance powder mentioned above is 5 : l to 2~ : 1, more preferably 5 : 1 to 1~ : 1, and the diameter o:E the same is 0.01 to 1 ~, more preferably 0.02 to 0.5 ~. Furthermore, the length o-E the ferromagnetic substance powder is preferably 0.05 to 20 ~, more preferably 0.1 to 5 ~.
An example of wax is one or more of carnauba wax, montan wax, para:Efin wax, microcystaline wax, bees wax, or the like. Due to wax contained in the heat-sensitive tranferring layer 2 as a binder material, the melt-transer property of the transferring layer 2 obtained can he effectively increased. Thus, the transferred magnetic image 5 prepared is free from the void and the break, and further has an excellent adhesion on ~he receiving paper 3. Accordingly, it is especially preferable that wax is contained in the heat-sensitive transEerring layer 2.
An example of the thermoplastic resi.n is polyvinyl chloride, polyvinyl acetate, vinyl chloride vinyl acetate copolymer, polyethylene, polypropylene, polyacetal, eth.ylene-vinyl acetate copolymer, 5~
polystyrene, low molecul~r weight polystyrene, poly-acrylic ester, polyamide, ethyl cellulose, or the like.
Furthermore, epoxy resin, xylene resin, ketone resin, petroleum resin, rosin or the derivative.s thereof, cumarone-indene resin, terpene resin, polyurethane, synthetic rubber such as styrene-butadiene rubber, polyvinyl butyral, nitrile rubber, polyacrylate rubber, ethylene-propylene rubber, or the like can be also pre:Eerably employed.
An example of the above fat and oil is animal oil, vegetable oil, mineral oil, dioctyl phthalate, tricresyl phosphate, dibutyl phthalate, or the like.
An example of the above extender pigment is calcium carbonate, magnesium carbonate, diatomaceous lS earth, kaolin, white carbon, silicic acid powder, or the like. Furthermore, an example of the dispersant is nonionic surface active agent such as di(polyoxyethylene alkylether) phosphate, tri(polyoxyethylene alkylether) phosphate, polyoxyethylene stearylamine, polyoxyethylene laurylether, polyoxyethylene oleylether, polyoxyethylene cetyle~her, po].yoxyethylene stearylarylether, or the like.
The heat-sensitive transerring layer 2 thus obtained has preferably a thickness o-f 2 to 25 ~, and the heat-resisting foundation 1 has preferably a thickness of 3 to 4~ ~.
An example of the heat-resisting foundation is a plastic film such as polyester, moisture-protected cellophane, polycarbonate, nylon, polypropylene, or a paper such as condenser paper, glassine paper.
The heat-sensitive magnetic transfer element of the invention is overlapped with the receiving paper 3 such as check, and then is printed by a thermal head 4 of the thermal printer as shown in Fig. 2, whereby the magnetic image 5 is melted and transferred on the receiving paper 3.
In that case, the heat-sensi~ive transferring ` layer 2 according to the invention can be correctly ~195~
transferred only in the portion of the tr~nsferring layer 2 corresponding to the heatillg ancl printing portion Or the thermal head ~, because the heat-sensitive transferring l~yer 2 is a melting temperature o-f 5~ to 120C., and therefore is superior in the heat-transfer property an~ the adhesion property. As ~ result, the magnetic image prepared has a very sharp profile wi~hout causing the void, the break of the character and the smudge of the receiving paper 3.
In particular, the magnetic image 5 thus obtained has a high accuracy in dimension to ensure the reading operation of MICP~ so that a high reliability can be offered.
In addition, the invention has also signi-ficant advantages that a high-speed printing can be performed without generating noise, and the preparation of bill, chec}c, credit card, pass, traffic census card, or the like can be readily and rapidly carried out, since the magnetic image 5 is prepared by using the thermal printer.
~urther, the magnetic image obtained in the invention is not limited to only the certain type face such as E13B or CMC7 mentioned above, and other certain characters are also readily prepared from the heat-sensitive magnetic transfer element by means of the thermal printer.
The invention is rnore particularly described and explained bv means of the following Examples.
Example l A composition of heat-sensitive transferring layer described below was uniformly admixed and was applied on a polyester film having a thickness of 6 ~ by means of hot-melt coatillg to obtain a heat-sensitive transferring layer having a melting temperature of 68C.
and a thickness of 6 ~.
~s~
Ingredients Parts by Weight ~-Fe2O3 200 Coercive force: l20~ Oe Diameter: 0.
Length: 1 ~l Carnauba wax 15 Paraf-fin wax 32 (melting point: 68C.) Ethylene-vinyl acetate copolymer 3 10 Vaseline 5 The magnetic tranfer element thus obtained was overlapped with a fine paper, and then was printed by thermal printer commercially-available from Oki Electric Industry Co., Ltd. under "Thermal Printer 200" at a printing speed of 30 characters per second so that ~he heat-sensitive ~ransferring layer is melted and transferred on the fine paper to form magnetic images.
~e~
A composition of heat-sensitive transferring layer described below was uniformly admixed, and then was applied and dried on a condenser tissue to obtain a heat-sensitive transferring layer having a melting temperature of 90C. and a thickness of 8 ~.
Ingredi`ents Parts by Weight Fe3O4 68 Coercive force: 1100 Oe Diameter: 0.2 Ieng~h: 0.5 ~
30 Solprene T 4.5 (styrene-butadiene rubber available from Asahi Chemical Industry Co., Ltd.) Arkon P-90 g-~
(saturated alicyclic hydrocarbon resin available -from Arakawa Kagaku Kogyo Kabushiki Kaisha) - iloechst wax V 2.5 (Hoechs~ A~) 5~
To 1 uene 5 n Solvent naphtha 25 (boiling poiTlt: 125C.) The nagnetic transfer element thus obtained was 5 overlapped with a chec]~ paper, and then was printed by the same thermal printer as in Example 1 at a printing speed of 30 characters per second to melt and ~ransfer the heat-sensitive transferring layer in the form of magnetic images on the paper As a result, Dimensions of each magnetic image prepared in Examples 1 and 2 (character height, character width and line width) were included within the allowable ranges defined in JIS C 6251.
Also, voids existing in the magnetic images 15 were determined by observing whether single void is included within a square gauge of 0.21)3 mm. X 0.2n3 mm.
In that case, the void existing in a line having a width of 0.660 mm. or more was determined by employing a square gauge of 0.254 mm. X n.254 mm. according to the 20 definition of JIS C 6251. The results are shown in the following Table.
Furthermore, magnetic properties (coercive force, residual magnetic flux density and relative signal level) of each magnetic image prepared in Examples 1 and 25 2 are also shown in the same Table.
In that case, the relative signal level is determined by measuring a signal level with a MICR tester (commercially-available from Kidder Press Company Inc.
under "Kidder Magnetic Character Tester") defined in JIS
30 C 6251, and then calculating a percentage of the me~sured signal level against the standard signal level with reference to the same character. The relative signal level must be within a range of 50 to 2n() % against the standard signal level of the examined character.
Unable to recognize this page.
5~
In addition to the elements or ingredients used in Examples, other elements or ingredients can l)e used in F.xamples as set forth in the speclfication to obtain substantially the same results.
Variations and modi.fications will be apparent to a person skilled in the art in the ]ight of the present disclosure and within the scope of the presen~
cla:ims.
The present invention relates to a heat-sensitive magnetlc transfer element and more particularly to a heat-sensitive magnetic transfer element which allows a thermal printer to prepare a printed magnetic image recognized by a magne-tic ink character reader The magnetic ink character reader (hereinafter referred to as MICR) can read and recognize the certain printed magnetic image, such as character, or mark, which is printed to bill, check, credit card, pass, traffic census card, or the like. A magne~ic head in the MICR
converts the variations of magnetic portions corresponding to various characters and marks into predetermined signals, and volt;ages are detected to recognize the characters and marks.
In that case, it is necessary that each of the charcters and marks to be read by the magnetic head has a certain shape, dimensions and allowable ranges of dimensions in addition to the certain magnetic signal levels. Therefore, the allowable ranges as to E13B type face employed in American Bank Association are defined in JIS C 6251 (Japanese Industrial Standard).
E13B type face defined in JIS C 6251 consists of 10 numbers (0 to 9) and 4 special marks. According to JIS C 6251~ a character height, a character width, a corner radius, allowable ranges of those and an allowable range of a void with respect to each character are described. In addition to E13B type face, CMC7 type face is well known as type face for MICR. CMC7 type face is formed by arranging 7 longitudinal bars with 2 kinds of intervals, and each of CMC7 type faces can be magnetically recognized by combinations of 2 kinds of intervals. Thus, CMC7 type faces consist of 10 numbers, 26 large alphabets and 5 special marks, and dimensions and magnetic property of CMC7 type face are determined by European Computer Manufactures Association.
The prin~ed image of the above type ace for MICR is formed by transferring a magnetic ink onto a receiving paper by an impact printer such as typewriter.
The magnetic ink including a magnetic substallce powcler is coated and dried on a foundation such as plas~lc film to form a pressure-sensitive magntic transfer element.
Such a pressure-sensitive magnetic transfer element is disclosed in, for example, Japanese Patent Publication No. 21449/1970.
However~ the use of the pressure-sensitive magnetic transfer element results in generating noise due to impact system, and further cannot perform high printing speed. In addition, the above transfer element tends to generate voids in the printed magnetic image.
OBJECTS OF THF. INVENTION
.. . .
A main object of the invention is to provide a heat-sensitive magnetic transfer element which can easily produce a printed magnetic image by a thermal printer with hlgh printing speed without generating noise .
Another object of the invention is to provide a heat-sensitive magnetic transfer element which can produce a printed magnetic image having high accuracy of dimensions and high magnetlc pro~erties.
Other objects and advantages of the invention will become apparent from the following descriptions with reference to the accompanying drawings.
BRIEF DESCRIPTION OF THE IN~ENrION
Fig. 1 is a schematically sectional view for showing an embodiment of a heat-sensitive magnetic transfer element of the invention; and ~ ig. 2 is a explanatory view for showing a printing method using a heat-sensitive magnetic transfer element of the invention.
DFTAILED EXPLANATION OF THE INVENTION
Fig. 1 shows a heat-sensitive magnetic transfer element according to the invention comprising a heat--- '1 --resisting foundation 1, and a heat-sensitive transferring laver 2 including a ferromagnetic substance powder and having a melting temperature of 50 to :L2~C., which is measured at a heating-up velocity of 40C./min. by Meihosha-type melting point measuring device available from Meihosha ~actory Ltd.
The heat-sensitive transferring layer 2 is one layer formed by uniformly admixing a binder material of wax and/or thermoplastic resin including, if necessary, additives such as fat and oil, extender pigment, or dispersant, with the magnetic substance powder. Such a transferring layer can be obtained by means of ~lot-melt coating or solvent coating.
The magnetic substance powder is pre:Eerably included in the heat-sensitive transferring layer 2 at a range of 30 to 97 % by weight per total amount of the transferring layer 2. When the magnetic substance powder content is less than the above range, the magnetic properties of the printed image are lowered, whereby reading of MICR becomes difficult. On the other hand, when the magnetic substance powder content is more than the above range, the melt-transfer property of the transferring layer 2 and the adhesion strength of the printed image against the image receiving paper are lowered.
In the case that the heat-sensitive transferring layer 2 is provided on the heat-resisting foundation 1 by means of hot-melt coating, wax is preferably employed as a main ingredient of the binder material to prepare the heat-sensitive transferring layer. In that case, 30 to 97 % by weight of the ferromagnetic substance powder, 20 to 70 % by weight of wax, n to 30 ~ by weight of thermoplastic resin~ o to 30 % by weight of fat and oil, 0 to 30 % by weight of extender pigment and 0 to 2 % by weight of dispersant are used per total amount of the heat-sensitive transferring layer 2.
In the case that the heat-sensitive 95~
trans-Eerring ].ayer 2 is provided on the heat-resisting :Eollndati.on l by means o solvent coating, 3n to ~7 ~ by weight of t~e ferromagnetic su~s~ance powder, ~ to 2() %
by weight of wax, 20 to 7n ~ by we;.ght o:E thermoplastic resin, 0 to 30 ~ by we;ght o:E fat and oil, 0 to 3() % by weight of extender pigment and n to 2 % by weight of clispersant are used per total amonnt of the heat-sensitive trans:Eerring layer~ and are homogeneously dispersed in organic solvent such as toluene, metilyl ethyl ketone, methyl isobutyl ketone, cyclohexane, butyl butyrate, dioxane, or ethyl-benzene.
An example of the ferromagnetic substance powder is ~-Fe2O3, ~-Fe2O3 inclllding Co, Fe3O4, Fe3O4 including Co, CrO2, Co-Cr alloy, Co-Fe alloy, Co-Ni-P
alloy, Co-Ni-Fe alloy, Co-Ni-Fe-B alloy, Co-Ni-~n alloy, Fe-Mn-Zn alloy, ~e-Co-Ni-Cr alloy, Fe-Co-Ni-P alloy, Ni-Co alloy, or the like. The aspect ratio (L/D) of the ferromagnetic substance powder mentioned above is 5 : l to 2~ : 1, more preferably 5 : 1 to 1~ : 1, and the diameter o:E the same is 0.01 to 1 ~, more preferably 0.02 to 0.5 ~. Furthermore, the length o-E the ferromagnetic substance powder is preferably 0.05 to 20 ~, more preferably 0.1 to 5 ~.
An example of wax is one or more of carnauba wax, montan wax, para:Efin wax, microcystaline wax, bees wax, or the like. Due to wax contained in the heat-sensitive tranferring layer 2 as a binder material, the melt-transer property of the transferring layer 2 obtained can he effectively increased. Thus, the transferred magnetic image 5 prepared is free from the void and the break, and further has an excellent adhesion on ~he receiving paper 3. Accordingly, it is especially preferable that wax is contained in the heat-sensitive transEerring layer 2.
An example of the thermoplastic resi.n is polyvinyl chloride, polyvinyl acetate, vinyl chloride vinyl acetate copolymer, polyethylene, polypropylene, polyacetal, eth.ylene-vinyl acetate copolymer, 5~
polystyrene, low molecul~r weight polystyrene, poly-acrylic ester, polyamide, ethyl cellulose, or the like.
Furthermore, epoxy resin, xylene resin, ketone resin, petroleum resin, rosin or the derivative.s thereof, cumarone-indene resin, terpene resin, polyurethane, synthetic rubber such as styrene-butadiene rubber, polyvinyl butyral, nitrile rubber, polyacrylate rubber, ethylene-propylene rubber, or the like can be also pre:Eerably employed.
An example of the above fat and oil is animal oil, vegetable oil, mineral oil, dioctyl phthalate, tricresyl phosphate, dibutyl phthalate, or the like.
An example of the above extender pigment is calcium carbonate, magnesium carbonate, diatomaceous lS earth, kaolin, white carbon, silicic acid powder, or the like. Furthermore, an example of the dispersant is nonionic surface active agent such as di(polyoxyethylene alkylether) phosphate, tri(polyoxyethylene alkylether) phosphate, polyoxyethylene stearylamine, polyoxyethylene laurylether, polyoxyethylene oleylether, polyoxyethylene cetyle~her, po].yoxyethylene stearylarylether, or the like.
The heat-sensitive transerring layer 2 thus obtained has preferably a thickness o-f 2 to 25 ~, and the heat-resisting foundation 1 has preferably a thickness of 3 to 4~ ~.
An example of the heat-resisting foundation is a plastic film such as polyester, moisture-protected cellophane, polycarbonate, nylon, polypropylene, or a paper such as condenser paper, glassine paper.
The heat-sensitive magnetic transfer element of the invention is overlapped with the receiving paper 3 such as check, and then is printed by a thermal head 4 of the thermal printer as shown in Fig. 2, whereby the magnetic image 5 is melted and transferred on the receiving paper 3.
In that case, the heat-sensi~ive transferring ` layer 2 according to the invention can be correctly ~195~
transferred only in the portion of the tr~nsferring layer 2 corresponding to the heatillg ancl printing portion Or the thermal head ~, because the heat-sensitive transferring l~yer 2 is a melting temperature o-f 5~ to 120C., and therefore is superior in the heat-transfer property an~ the adhesion property. As ~ result, the magnetic image prepared has a very sharp profile wi~hout causing the void, the break of the character and the smudge of the receiving paper 3.
In particular, the magnetic image 5 thus obtained has a high accuracy in dimension to ensure the reading operation of MICP~ so that a high reliability can be offered.
In addition, the invention has also signi-ficant advantages that a high-speed printing can be performed without generating noise, and the preparation of bill, chec}c, credit card, pass, traffic census card, or the like can be readily and rapidly carried out, since the magnetic image 5 is prepared by using the thermal printer.
~urther, the magnetic image obtained in the invention is not limited to only the certain type face such as E13B or CMC7 mentioned above, and other certain characters are also readily prepared from the heat-sensitive magnetic transfer element by means of the thermal printer.
The invention is rnore particularly described and explained bv means of the following Examples.
Example l A composition of heat-sensitive transferring layer described below was uniformly admixed and was applied on a polyester film having a thickness of 6 ~ by means of hot-melt coatillg to obtain a heat-sensitive transferring layer having a melting temperature of 68C.
and a thickness of 6 ~.
~s~
Ingredients Parts by Weight ~-Fe2O3 200 Coercive force: l20~ Oe Diameter: 0.
Length: 1 ~l Carnauba wax 15 Paraf-fin wax 32 (melting point: 68C.) Ethylene-vinyl acetate copolymer 3 10 Vaseline 5 The magnetic tranfer element thus obtained was overlapped with a fine paper, and then was printed by thermal printer commercially-available from Oki Electric Industry Co., Ltd. under "Thermal Printer 200" at a printing speed of 30 characters per second so that ~he heat-sensitive ~ransferring layer is melted and transferred on the fine paper to form magnetic images.
~e~
A composition of heat-sensitive transferring layer described below was uniformly admixed, and then was applied and dried on a condenser tissue to obtain a heat-sensitive transferring layer having a melting temperature of 90C. and a thickness of 8 ~.
Ingredi`ents Parts by Weight Fe3O4 68 Coercive force: 1100 Oe Diameter: 0.2 Ieng~h: 0.5 ~
30 Solprene T 4.5 (styrene-butadiene rubber available from Asahi Chemical Industry Co., Ltd.) Arkon P-90 g-~
(saturated alicyclic hydrocarbon resin available -from Arakawa Kagaku Kogyo Kabushiki Kaisha) - iloechst wax V 2.5 (Hoechs~ A~) 5~
To 1 uene 5 n Solvent naphtha 25 (boiling poiTlt: 125C.) The nagnetic transfer element thus obtained was 5 overlapped with a chec]~ paper, and then was printed by the same thermal printer as in Example 1 at a printing speed of 30 characters per second to melt and ~ransfer the heat-sensitive transferring layer in the form of magnetic images on the paper As a result, Dimensions of each magnetic image prepared in Examples 1 and 2 (character height, character width and line width) were included within the allowable ranges defined in JIS C 6251.
Also, voids existing in the magnetic images 15 were determined by observing whether single void is included within a square gauge of 0.21)3 mm. X 0.2n3 mm.
In that case, the void existing in a line having a width of 0.660 mm. or more was determined by employing a square gauge of 0.254 mm. X n.254 mm. according to the 20 definition of JIS C 6251. The results are shown in the following Table.
Furthermore, magnetic properties (coercive force, residual magnetic flux density and relative signal level) of each magnetic image prepared in Examples 1 and 25 2 are also shown in the same Table.
In that case, the relative signal level is determined by measuring a signal level with a MICR tester (commercially-available from Kidder Press Company Inc.
under "Kidder Magnetic Character Tester") defined in JIS
30 C 6251, and then calculating a percentage of the me~sured signal level against the standard signal level with reference to the same character. The relative signal level must be within a range of 50 to 2n() % against the standard signal level of the examined character.
Unable to recognize this page.
5~
In addition to the elements or ingredients used in Examples, other elements or ingredients can l)e used in F.xamples as set forth in the speclfication to obtain substantially the same results.
Variations and modi.fications will be apparent to a person skilled in the art in the ]ight of the present disclosure and within the scope of the presen~
cla:ims.
Claims (7)
1. A heat-sensitive magnetic transfer ele-ment for printing a magnetic image comprising a heat-resisting foundation and a heat-sensitive transferring layer provided on the foundation, said transferring layer comprising a ferromagnetic substance powder and a binder material comprising a wax and at least one of a resin and a synthetic rubber, and said transferring layer having a melting temperature of 50° to 120°C.
2. The transfer element of claim 1 wherein said magnetic substance powder is included in the transferring layer at a range of 30 to 97% by weight.
3. The transfer element of claim 1 wherein the thickness of the foundation is within a range of 3 to 40 µ, and the thickness of the transferring layer is within a range of 2 to 25 µ.
4. The transfer element of claim 1 wherein the wax is at least one member selected from the group consisting of carnauba wax, montan wax, paraffin wax, microcrystalline wax and bees wax.
5. The transfer element of claim 1 or 4 wherein the resin is at least one member selected from the group consisting of polyvinyl chloride, polyvinyl acetate, vinyl chloride-vinyl acetate copolymer, poly-ethylene, polypropylene, polyacetal, ethylene-vinyl acetate copolymer, polystyrene, low molecular weight polystyrene, polyacrylic ester, polyamide, ethyl cel-lulose, epoxy resin, xylene resin, ketone resin, pet-roleum resin, rosin, rosin derivative, cumarone-indene resin, terpene resin and polyurethane.
6. The transfer element of claim 1 or 4 wherein the synthetic rubber is at least one member selected from the group consisting of styrene-buta-diene rubber, polyvinyl butyral, nitrile rubber, polyacrylate rubber and ethylene-propylene rubber.
7. A process for printing a magnetic image on a receiving medium, which comprises the steps of:
providing a heat-sensitive magnetic transfer element comprising a heat-resisting foundation and a heat-sensitive transferring layer provided on the foundation, said transferring layer comprising a fer-romagnetic substance powder and a binder material com-prising a wax and at least one of a resin and a syn-thetic rubber, and said transferring layer having a melting temperature of 50° to 120°C;
superimposing the transfer element over a receiving medium so that the transferring layer of the element is brought to come into contact with the receiving medium; and applying the heat from a thermal head to the transfer element whereby the portions of the transferring layer corresponding to the areas heated with the thermal head were melted and transferred onto the receiving medium to give a magnetic image.
providing a heat-sensitive magnetic transfer element comprising a heat-resisting foundation and a heat-sensitive transferring layer provided on the foundation, said transferring layer comprising a fer-romagnetic substance powder and a binder material com-prising a wax and at least one of a resin and a syn-thetic rubber, and said transferring layer having a melting temperature of 50° to 120°C;
superimposing the transfer element over a receiving medium so that the transferring layer of the element is brought to come into contact with the receiving medium; and applying the heat from a thermal head to the transfer element whereby the portions of the transferring layer corresponding to the areas heated with the thermal head were melted and transferred onto the receiving medium to give a magnetic image.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60961/1981 | 1981-04-21 | ||
| JP56060961A JPS57174296A (en) | 1981-04-21 | 1981-04-21 | Heat transfer magnetic recording medium |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1195114A true CA1195114A (en) | 1985-10-15 |
Family
ID=13157505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000398280A Expired CA1195114A (en) | 1981-04-21 | 1982-03-12 | Heat-sensitive magnetic transfer element |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US4463034A (en) |
| JP (1) | JPS57174296A (en) |
| CA (1) | CA1195114A (en) |
| CH (1) | CH658734A5 (en) |
| DE (1) | DE3213937A1 (en) |
| FR (1) | FR2504289B1 (en) |
| GB (2) | GB2106038B (en) |
| HK (2) | HK36689A (en) |
| IT (1) | IT1150328B (en) |
| NL (1) | NL183445C (en) |
| SG (1) | SG87888G (en) |
Families Citing this family (80)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1203667B (en) * | 1983-03-30 | 1989-02-15 | Olivetti & Co Spa | HEAT-SENSITIVE INK ELEMENT FOR HIGH SPEED THERMAL PRINTERS |
| JPS59224394A (en) * | 1983-06-04 | 1984-12-17 | Canon Inc | Thermal transfer material |
| JPS59227489A (en) * | 1983-06-10 | 1984-12-20 | Tomoegawa Paper Co Ltd | Image recording sheet |
| US4533596A (en) * | 1983-06-28 | 1985-08-06 | Ncr Corporation | Thermal magnetic transfer ribbon |
| JPS6018388A (en) * | 1983-07-11 | 1985-01-30 | Dainippon Printing Co Ltd | Thermal magnetic recording medium |
| JPS6019588A (en) * | 1983-07-13 | 1985-01-31 | Ricoh Co Ltd | Thermal transfer recording type label |
| JPS6083890A (en) * | 1983-10-17 | 1985-05-13 | Konishiroku Photo Ind Co Ltd | Preparation of thermal transfer recording medium |
| JPS60101082A (en) * | 1983-11-08 | 1985-06-05 | Canon Inc | Thermal transfer recording method |
| JPS60101081A (en) * | 1983-11-08 | 1985-06-05 | Canon Inc | Thermal transfer material and thermal transfer recording method using the same |
| JPS60189490A (en) * | 1984-03-09 | 1985-09-26 | Canon Inc | Thermal transfer material |
| JPS60212387A (en) * | 1984-04-06 | 1985-10-24 | Canon Inc | Thermal transfer material and thermal transfer recording method using the same |
| JPS60234887A (en) * | 1984-05-09 | 1985-11-21 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
| JPS60234889A (en) * | 1984-05-09 | 1985-11-21 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
| JPS60234888A (en) * | 1984-05-09 | 1985-11-21 | Konishiroku Photo Ind Co Ltd | Thermal transfer recording medium |
| DE3422908C2 (en) * | 1984-06-20 | 1986-04-30 | Leonhard Kurz GmbH & Co, 8510 Fürth | Embossing foil, in particular hot stamping foil, with a surface that can be written on |
| DE3422911C1 (en) * | 1984-06-20 | 1985-09-05 | Leonhard Kurz GmbH & Co, 8510 Fürth | Stamping foil, in particular hot stamping foil, with a magnetic layer |
| DE3422910C1 (en) * | 1984-06-20 | 1985-09-05 | Leonhard Kurz GmbH & Co, 8510 Fürth | Embossing foil, in particular hot stamping foil with a magnetic layer |
| JPS61211056A (en) * | 1985-03-15 | 1986-09-19 | General Kk | Thermal printing method |
| JPS61215670A (en) * | 1985-03-22 | 1986-09-25 | Seiko Epson Corp | Thermoplastic magnetic ink |
| JPS61228993A (en) * | 1985-04-03 | 1986-10-13 | Fuji Kagakushi Kogyo Co Ltd | Thermal fusion transfer recording medium |
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| US8709274B2 (en) | 2011-03-17 | 2014-04-29 | Xerox Corporation | Curable inks comprising surfactant-coated magnetic nanoparticles |
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| US8303838B2 (en) | 2011-03-17 | 2012-11-06 | Xerox Corporation | Curable inks comprising inorganic oxide coated magnetic nanoparticles |
| US8801954B2 (en) | 2011-03-17 | 2014-08-12 | Xerox Corporation | Curable inks comprising coated magnetic nanoparticles |
| US8657431B2 (en) | 2011-03-17 | 2014-02-25 | Xerox Corporation | Phase change magnetic ink comprising carbon coated magnetic nanoparticles and process for preparing same |
| US8646896B2 (en) | 2011-03-17 | 2014-02-11 | Xerox Corporation | Phase change magnetic ink comprising surfactant coated magnetic nanoparticles and process for preparing same |
| US8409341B2 (en) | 2011-03-17 | 2013-04-02 | Xerox Corporation | Solvent-based inks comprising coated magnetic nanoparticles |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2744031A (en) * | 1949-10-15 | 1956-05-01 | Ncr Co | Sheet having a transferable coating containing magnetizable material |
| GB873696A (en) * | 1958-03-27 | 1961-07-26 | Gen Electric | Improvements relating to magnetic print transfer medium |
| DE1074602B (en) * | 1958-05-05 | 1960-02-04 | ||
| US3141404A (en) * | 1961-04-12 | 1964-07-21 | Columbia Ribbon & Carbon | Novel imaging process |
| US3375125A (en) * | 1963-10-14 | 1968-03-26 | Gen Electric | Method of making transfer sheet and resultant article |
| US3284360A (en) * | 1964-02-24 | 1966-11-08 | Carters Ink Company | Magnetic transfer sheet |
| JPS4521449Y1 (en) * | 1965-12-15 | 1970-08-26 | ||
| US3496015A (en) * | 1966-11-09 | 1970-02-17 | Columbia Ribbon Carbon Mfg | Pressure-sensitive magnetic transfer elements |
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| JPS5721471B2 (en) * | 1972-03-27 | 1982-05-07 | ||
| JPS5179274A (en) * | 1974-12-30 | 1976-07-10 | Kyohiro Takemura | FUROOTOSUITSUCHI |
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| JPS5540574Y2 (en) * | 1978-05-29 | 1980-09-22 | ||
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| US4298935A (en) * | 1979-10-05 | 1981-11-03 | Honeywell Information Systems Inc. | Interface circuit for coupling an automated maintenance system to a CPU |
-
1981
- 1981-04-21 JP JP56060961A patent/JPS57174296A/en active Granted
-
1982
- 1982-03-12 CA CA000398280A patent/CA1195114A/en not_active Expired
- 1982-03-15 US US06/358,033 patent/US4463034A/en not_active Expired - Lifetime
- 1982-03-16 IT IT20188/82A patent/IT1150328B/en active
- 1982-03-16 GB GB08207591A patent/GB2106038B/en not_active Expired
- 1982-04-15 NL NLAANVRAGE8201588,A patent/NL183445C/en not_active IP Right Cessation
- 1982-04-16 DE DE19823213937 patent/DE3213937A1/en active Granted
- 1982-04-19 CH CH2368/82A patent/CH658734A5/en not_active IP Right Cessation
- 1982-04-21 FR FR8206866A patent/FR2504289B1/en not_active Expired
-
1984
- 1984-05-17 US US06/611,439 patent/US4581283A/en not_active Expired - Lifetime
-
1985
- 1985-02-21 GB GB08504433A patent/GB2152438B/en not_active Expired
-
1988
- 1988-12-16 SG SG878/88A patent/SG87888G/en unknown
-
1989
- 1989-05-04 HK HK366/89A patent/HK36689A/en not_active IP Right Cessation
- 1989-05-04 HK HK367/89A patent/HK36789A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| GB2152438A (en) | 1985-08-07 |
| IT1150328B (en) | 1986-12-10 |
| NL183445B (en) | 1988-06-01 |
| GB2106038B (en) | 1986-01-02 |
| GB2106038A (en) | 1983-04-07 |
| HK36789A (en) | 1989-05-12 |
| NL183445C (en) | 1988-11-01 |
| US4581283A (en) | 1986-04-08 |
| SG87888G (en) | 1989-06-16 |
| IT8220188A0 (en) | 1982-03-16 |
| NL8201588A (en) | 1982-11-16 |
| CH658734A5 (en) | 1986-11-28 |
| FR2504289B1 (en) | 1986-04-04 |
| FR2504289A1 (en) | 1982-10-22 |
| GB2152438B (en) | 1986-02-12 |
| HK36689A (en) | 1989-05-12 |
| US4463034A (en) | 1984-07-31 |
| DE3213937C2 (en) | 1988-03-31 |
| JPH0148157B2 (en) | 1989-10-18 |
| DE3213937A1 (en) | 1982-11-18 |
| GB8504433D0 (en) | 1985-03-27 |
| JPS57174296A (en) | 1982-10-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry | ||
| MKEX | Expiry |
Effective date: 20021015 |