CA1185058A - Dye mixtures and their use - Google Patents
Dye mixtures and their useInfo
- Publication number
- CA1185058A CA1185058A CA000395915A CA395915A CA1185058A CA 1185058 A CA1185058 A CA 1185058A CA 000395915 A CA000395915 A CA 000395915A CA 395915 A CA395915 A CA 395915A CA 1185058 A CA1185058 A CA 1185058A
- Authority
- CA
- Canada
- Prior art keywords
- dye
- formula
- parts
- mixture
- dye mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/26—Dyes with amino groups substituted by hydrocarbon radicals
- C09B1/32—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups
- C09B1/34—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups sulfonated
- C09B1/343—Dyes with amino groups substituted by hydrocarbon radicals substituted by aryl groups sulfonated only sulfonated in the anthracene nucleus
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0034—Mixtures of two or more pigments or dyes of the same type
- C09B67/0038—Mixtures of anthraquinones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/96—Dyeing characterised by a short bath ratio
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/06—Material containing basic nitrogen containing amide groups using acid dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/917—Wool or silk
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/92—Synthetic fiber dyeing
- Y10S8/924—Polyamide fiber
Abstract
Dye mixtures and their use Abstract The invention relates to a dye mixture which contains a dye of the formula (1) wherein Z is hydrogen or methyl, and a dye of the formula
Description
~ 5~5 Case 1-13740/13741 Dye mixtures and their use It was the object of the present invention to provide anthraquinone dyes or dye mixtures which would be suitable for dyeing natural or synthetic polyamide materials from an aqueous bath, which would have very good fastness properties, particularly fastness to light, and which would exhibit, especially in combination with other dyes, good strike properties, in particular from short liquors.
It has now been found that the dye mixture of dyes of the formulae (1) and (2) satisfies the stated requirements.
The present invention thus relates to a dye mixture which contains a dye of the formula R ~ 2 SO H
,~\./\/~/ 3 !~ ,', ,i!, ~! /z (l~
\. = ./ 3 wherein Z is hydrogen or methyl, and a dye of the formula 5~
It has now been found that the dye mixture of dyes of the formulae (1) and (2) satisfies the stated requirements.
The present invention thus relates to a dye mixture which contains a dye of the formula R ~ 2 SO H
,~\./\/~/ 3 !~ ,', ,i!, ~! /z (l~
\. = ./ 3 wherein Z is hydrogen or methyl, and a dye of the formula 5~
2~S03~1 l! 1l a ~ ~;~ (2), Nil-CO-CH CH
Z in the formula (1) being hydrogen when the propionyl-amino group in the formula (2) is bound in the m-position with respect to the NH group. The dye mixture according to the invention can therefore contain a dye of the formula .~ ~ ,Q ~o~ ,s03E
!~ ,1!, ,~!, ~! ~CH3 B ~H- o\ ~- -CH3 ( 3 ) and a dye of the formula R ~H2 ~ \ / \ / ~ / 3 (4) ! l' il !
~ / \ , \ ~
--~ ~-N}I-CO-CH2CH3 ~=o or a dye of the formula ~ ~ ,Q ,~ ~So3H
i j o ,.~ ~ ~ ~ (s \~= / 3 and a dye of the formula (2) s an applicable dye as dye of the formula (2) being the dye of the formula (4) or the dye of the formula ~5~
~ ~ ,Q ~2~s03l~
!~ iI il i ( 6).
\NII-CO-CH2C~13 In the dye mixtures according to the invention, the preferred ratio between the dyes of the formulae (1) and (2), (3) and (4), (5) and (2), (5) and (~3 or (5) and (6) is 20:80 to 80:20; and in particular the ratio between the dyes of the formulae (3) and (4), (5) and (4) or (5) and (6) is preferably 40:60 to 60:40. The ratio between the dyes of the formulae (3) and (4) or (5) and (4~ of 50:50 to 60:40 and particularly of 55:45 to 57:43 and between the dyes of the formulae (5) and (6) of 50:50 to 60:40 and in particular of 52:48 is more especially preferred.
The anthraquinone dyes of the formulae (3), (4), (5) and (6) are known. Thus, the dyes of the formulae (3) and (5) can be produced in a manner analogous to that described in the U.S. Patent Specification No. 3,778,453, and the dye of the formula (4) in a manner analogous to that given in the German Patent Specification No. 945,643.
The dye of the formula (6) can be produced, using a process analogous to that described in the German Patent Specification No. 538,310, by using propionyl chloride in place of chloroacetyl chloride.
The dye mixture according to the invention can be produced by mixing the individual dyes together. This mixing process is carried out for example in suitable mills, for example in ball and dowelled-disc mills, and also in kneaders or mixers. Furthermore, the dye mixtures can bP
~ S 8 produced by spray drying of the aqueous dye mixtures.
Further subject matter of the present invention is a process for dyeing and printing natural or synthetic polyamide materials with a dye mixture containing the dyes of the formulae (1) and (2) or (3~ and (4), (5) and (4) or (5) and (6). Suitable synthetic polyamide materials are for example nylon or Perlon; and a suitable natural polyamide material is for example wool. The customary dyeing and printing processes are used for dyeing or printing the materials.
The dye mixture containing the dyes of the formulae (1) and (2) or (3) and (~), (5) and (4) or (5) and (6) is particularly suitable for dyeing and printing in combination with other dyes, and especially for dyeing and printing according to the trichromatic principle.
By this is meant the additive dye mixture of three suitably selected yellow-, red- and blue-dyeing dyes in the amounts necessary to produce the desired shade. The dye mixture according to the invention is sultable in particular for dyeing from short liquors, for example in the continuous dyeing process, or discontinuous and continuous froth dyeing processes.
The dye mixture according to the invention is character-ised by generally good properties, for example by good solubility and stability to cold dissolving, by good strike properties andt in particular, by its suitability for being combined with other dyes.
The textile material to be dyed or printed can be in various stages of processing: it can be for example in the form of fibres, yarns, fabrics or knitted goods, and especially in the form of carpets.
In the dye mixture according to the invention, the dyes of the formulae (1) and (2) or (3) and (4), (5) and (4) or (5) and (6) are either in the form of their fre~ sulfonic acid or preferably in the form of salts thereof, for example the alkali metal, alkaline-earth metal or ammonium salts, or they are in the form of salts of an organic amine.
Examples which may be mentioned are the sodium, lithium or ammonium salts, or the salt of triethanolamine.
The dye mixture contains as a rule further additives, for example sodium chloride or dextrin.
The dye liquors or printing pastes can also contain further additives, for example wetting agents, anti-foaming agents, levelling agents or agents affecting the properties of the textile material, for example softening agents, additives for imparting a fireproof finish, or dirt-, water- and oil-repelling agents, as well as water-softening agents and natural or synthetic thickeners, for example alginates and cellulose ethers.
The term 'parts' in the following Examples denotes parts by weight, and temperature values are given in degrees Centigrade. The relationship between parts by weight and parts by volume is the same as that between gram and cubic centimeter.
Example 1 To produce the dye mixture containing a dye of the formula R ~H2 so 11 ,i!, ,!, ~s! ~CH3 (3) \.=./ 3 \so2-NH-c~l2cH2oH
or a dye of the formula 5~1 ., R, ~2~S03~1 il i (5) ~, / \./ \.~ ._.
\ . = . / 3 \S0 2-NII-CII ~CH 20H
and a dye of the formula Q ~2 S03H
i '! i! ! (4) ~, / \ / \.~ . .
.-NH-CO-CH2CH3 or a dye of the formula ~. R ,~ ~S03H
t i1 i1 ~./-, /-\o~ . (6), .=.
\NH-CO-CH2CH3 with the exception of the combination of the dyes of the formulae (3) and (6), the following operations are carried out in a mixer:
a~ 30.2 parts of the dye of the formula (3) and 69.8 parts of the dye of the formula (4) àre homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye mixture A;
b) 56.6 parts of the dye of the formula (3) and 43.4 parts of the dye of the formula (4) are homogeneously mixed to obtain 100 parts of the mix~ure denoted in the following as dye mixture B;
c) 79.6 parts of the dye of the formula (3) and 20.4 parts of the dye of the formula (4) are homogeneously mixed to ~ 5~3~ ~
obtain 100 parts of the mixture denoted in the following as dye mixture C;
d) 30.2 parts of the dye of the formula (5) and 69.8 parts of the dye of the formula (4) are homogeneously mixed to obtaln 100 parts of the mixture denoted in the following as dye mixture D;
e) 56.6 parts of the dye of the formula (5) and 43.4 parts of the dye of the formula (4) are homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye mixture E;
f) 79.6 par~s of the dye of the formula (5) and 20.4 parts of the dye of the formula (4) are homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye miXt-lre F;
g) 26.6 parts of the dye of the formula (5) and 73.4 parts of the dye of the formula (6) are homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye mixture G;
h) 52 parts of the dye of the formula (5) and 48 parts of the dye of the formula (6) are homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye mixture H; and i) 76.5 parts of the dye of the formula (5) and 23.5 parts of the dye of the formula (6) are homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye mixture J.
Exam~le 2 10 parts of Helanca tricot are dyed in 500 parts of an aqueous liquor containing per litre 2 g of ammonium acetate, the pH value having been set to 5 with acetic acid.
The dyes used are 0.27% of the yellow dye of the formula ~OC~13 N=N--~ ~-N=N--~ ~- -OCH 3 ( ) s~3~
0.12% of the red dye of the formula C~13-~- ~ H ~
-N=N- ~ ~- ( 8 ) / HO / \~
and 0.13% of the blue dye mixture B obtained according to Example lb), the percentage amounts being relative to the weight of fibre. The dyeing time at a temperature of 60 to 98C i5 30 to 90 minutes. The dyed Helanca piece is subsequently removed and is rinsed and dried in the usual manner. The fabric piece obtained is completely evenly dyed in a neutral brown shade and exhibits no sign at all of streakiness induced by the material.
By using, instead of 0.27% of the yellow dye of the formula (7) and 0.12% of the red dye of the formula (8) with 0.13% of the blue dye mixture B, the dyes of the formulae (7) and (8) together with the dye mixtures from Example 1 which are given in the following Table 1, there are obtained fabric pieces completely evenly dyed in the shades indicated.
Table 1 .
Eample Dyes used Shade ... .
Z in the formula (1) being hydrogen when the propionyl-amino group in the formula (2) is bound in the m-position with respect to the NH group. The dye mixture according to the invention can therefore contain a dye of the formula .~ ~ ,Q ~o~ ,s03E
!~ ,1!, ,~!, ~! ~CH3 B ~H- o\ ~- -CH3 ( 3 ) and a dye of the formula R ~H2 ~ \ / \ / ~ / 3 (4) ! l' il !
~ / \ , \ ~
--~ ~-N}I-CO-CH2CH3 ~=o or a dye of the formula ~ ~ ,Q ,~ ~So3H
i j o ,.~ ~ ~ ~ (s \~= / 3 and a dye of the formula (2) s an applicable dye as dye of the formula (2) being the dye of the formula (4) or the dye of the formula ~5~
~ ~ ,Q ~2~s03l~
!~ iI il i ( 6).
\NII-CO-CH2C~13 In the dye mixtures according to the invention, the preferred ratio between the dyes of the formulae (1) and (2), (3) and (4), (5) and (2), (5) and (~3 or (5) and (6) is 20:80 to 80:20; and in particular the ratio between the dyes of the formulae (3) and (4), (5) and (4) or (5) and (6) is preferably 40:60 to 60:40. The ratio between the dyes of the formulae (3) and (4) or (5) and (4~ of 50:50 to 60:40 and particularly of 55:45 to 57:43 and between the dyes of the formulae (5) and (6) of 50:50 to 60:40 and in particular of 52:48 is more especially preferred.
The anthraquinone dyes of the formulae (3), (4), (5) and (6) are known. Thus, the dyes of the formulae (3) and (5) can be produced in a manner analogous to that described in the U.S. Patent Specification No. 3,778,453, and the dye of the formula (4) in a manner analogous to that given in the German Patent Specification No. 945,643.
The dye of the formula (6) can be produced, using a process analogous to that described in the German Patent Specification No. 538,310, by using propionyl chloride in place of chloroacetyl chloride.
The dye mixture according to the invention can be produced by mixing the individual dyes together. This mixing process is carried out for example in suitable mills, for example in ball and dowelled-disc mills, and also in kneaders or mixers. Furthermore, the dye mixtures can bP
~ S 8 produced by spray drying of the aqueous dye mixtures.
Further subject matter of the present invention is a process for dyeing and printing natural or synthetic polyamide materials with a dye mixture containing the dyes of the formulae (1) and (2) or (3~ and (4), (5) and (4) or (5) and (6). Suitable synthetic polyamide materials are for example nylon or Perlon; and a suitable natural polyamide material is for example wool. The customary dyeing and printing processes are used for dyeing or printing the materials.
The dye mixture containing the dyes of the formulae (1) and (2) or (3) and (~), (5) and (4) or (5) and (6) is particularly suitable for dyeing and printing in combination with other dyes, and especially for dyeing and printing according to the trichromatic principle.
By this is meant the additive dye mixture of three suitably selected yellow-, red- and blue-dyeing dyes in the amounts necessary to produce the desired shade. The dye mixture according to the invention is sultable in particular for dyeing from short liquors, for example in the continuous dyeing process, or discontinuous and continuous froth dyeing processes.
The dye mixture according to the invention is character-ised by generally good properties, for example by good solubility and stability to cold dissolving, by good strike properties andt in particular, by its suitability for being combined with other dyes.
The textile material to be dyed or printed can be in various stages of processing: it can be for example in the form of fibres, yarns, fabrics or knitted goods, and especially in the form of carpets.
In the dye mixture according to the invention, the dyes of the formulae (1) and (2) or (3) and (4), (5) and (4) or (5) and (6) are either in the form of their fre~ sulfonic acid or preferably in the form of salts thereof, for example the alkali metal, alkaline-earth metal or ammonium salts, or they are in the form of salts of an organic amine.
Examples which may be mentioned are the sodium, lithium or ammonium salts, or the salt of triethanolamine.
The dye mixture contains as a rule further additives, for example sodium chloride or dextrin.
The dye liquors or printing pastes can also contain further additives, for example wetting agents, anti-foaming agents, levelling agents or agents affecting the properties of the textile material, for example softening agents, additives for imparting a fireproof finish, or dirt-, water- and oil-repelling agents, as well as water-softening agents and natural or synthetic thickeners, for example alginates and cellulose ethers.
The term 'parts' in the following Examples denotes parts by weight, and temperature values are given in degrees Centigrade. The relationship between parts by weight and parts by volume is the same as that between gram and cubic centimeter.
Example 1 To produce the dye mixture containing a dye of the formula R ~H2 so 11 ,i!, ,!, ~s! ~CH3 (3) \.=./ 3 \so2-NH-c~l2cH2oH
or a dye of the formula 5~1 ., R, ~2~S03~1 il i (5) ~, / \./ \.~ ._.
\ . = . / 3 \S0 2-NII-CII ~CH 20H
and a dye of the formula Q ~2 S03H
i '! i! ! (4) ~, / \ / \.~ . .
.-NH-CO-CH2CH3 or a dye of the formula ~. R ,~ ~S03H
t i1 i1 ~./-, /-\o~ . (6), .=.
\NH-CO-CH2CH3 with the exception of the combination of the dyes of the formulae (3) and (6), the following operations are carried out in a mixer:
a~ 30.2 parts of the dye of the formula (3) and 69.8 parts of the dye of the formula (4) àre homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye mixture A;
b) 56.6 parts of the dye of the formula (3) and 43.4 parts of the dye of the formula (4) are homogeneously mixed to obtain 100 parts of the mix~ure denoted in the following as dye mixture B;
c) 79.6 parts of the dye of the formula (3) and 20.4 parts of the dye of the formula (4) are homogeneously mixed to ~ 5~3~ ~
obtain 100 parts of the mixture denoted in the following as dye mixture C;
d) 30.2 parts of the dye of the formula (5) and 69.8 parts of the dye of the formula (4) are homogeneously mixed to obtaln 100 parts of the mixture denoted in the following as dye mixture D;
e) 56.6 parts of the dye of the formula (5) and 43.4 parts of the dye of the formula (4) are homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye mixture E;
f) 79.6 par~s of the dye of the formula (5) and 20.4 parts of the dye of the formula (4) are homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye miXt-lre F;
g) 26.6 parts of the dye of the formula (5) and 73.4 parts of the dye of the formula (6) are homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye mixture G;
h) 52 parts of the dye of the formula (5) and 48 parts of the dye of the formula (6) are homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye mixture H; and i) 76.5 parts of the dye of the formula (5) and 23.5 parts of the dye of the formula (6) are homogeneously mixed to obtain 100 parts of the mixture denoted in the following as dye mixture J.
Exam~le 2 10 parts of Helanca tricot are dyed in 500 parts of an aqueous liquor containing per litre 2 g of ammonium acetate, the pH value having been set to 5 with acetic acid.
The dyes used are 0.27% of the yellow dye of the formula ~OC~13 N=N--~ ~-N=N--~ ~- -OCH 3 ( ) s~3~
0.12% of the red dye of the formula C~13-~- ~ H ~
-N=N- ~ ~- ( 8 ) / HO / \~
and 0.13% of the blue dye mixture B obtained according to Example lb), the percentage amounts being relative to the weight of fibre. The dyeing time at a temperature of 60 to 98C i5 30 to 90 minutes. The dyed Helanca piece is subsequently removed and is rinsed and dried in the usual manner. The fabric piece obtained is completely evenly dyed in a neutral brown shade and exhibits no sign at all of streakiness induced by the material.
By using, instead of 0.27% of the yellow dye of the formula (7) and 0.12% of the red dye of the formula (8) with 0.13% of the blue dye mixture B, the dyes of the formulae (7) and (8) together with the dye mixtures from Example 1 which are given in the following Table 1, there are obtained fabric pieces completely evenly dyed in the shades indicated.
Table 1 .
Eample Dyes used Shade ... .
3 0.18% oE the dye of formula (7) reddish-0.18% of the dye of formula (8) brown 0,077% of ~he dye rnixture C
4 0.25% of the dye of formula (7) olive 0.04% of the dye of formula (8) 0014% of the dye mixture A
0.27% of the dye of formula (7) neutral 0.12% of the dye of formula (8) brown 0.13% of the dye mixture H
6 0.18% of the dye of formula (7) reddish 0.17% of the dye of formula (8) brown 0.07% of the dye mixture J
7 0.25% of the dye of formula (7) olive 0.036% of the dye of formula (8) 0.124% of the dye mixture G
8 0.2'a% of the dye of formula (7) neutral 0.13% of the dye of formula (8) brown 0.13% of the dye mixture E
9 0.18% of the dye of formula (7) reddish-0.18% of the dye of formula (8) brown 0.077% of the dye mixture F
0.25% of the dye of formula (7) olive 0004% of the dye of formula (8) 0.14% of the dye mixture D
Example 11 10 parts of Helanca tricot are dyed in 500 parts ofan aqueous liquor containing per litre 2 g of amrnonium ~3~
acetate, the pH-v~lue of the liquor having been adjusted to 5 wi~h acetic acid. The proportion of the dye mixture B, E or G is 0.9%, relative to the weight of the fibre.
The dyeing time at a temperature of 98C is 30 to 90 minutes.
The dyed Helanca piece is subsequently removed and is rinsed and dried in the customary manner. With dye mixture B or E is obtained a fabric piece evenly dyed in a greenish-blue shade, and with the dye mixture & a fabric piece evenly dyed in a reddish-blue shade, the fabric in all cases exhibiting no sign at all of streakiness induced by the material.
10 parts of polyamide 66 yarn are dyed in 400 parts of an aqueous liquor containing per litre 1.5 g of ammonium acetate, the pH-value of the liquor having been adjusted to 5.5 with acetic acid. As dyes are used 0.27% of the dye of the formula (7), 0.12% of the dye of the formula (8) and 0.13% of the dye mixture B obtained according to Example lb), the percentage amounts being relative to the weight of fibre. The dye bath is heated within 30 minutes to 98C, and is held for 60 minutes at 96 to 98C. The dyed yarn is subsequently removed, and is rinsed and dried in the customary manner. The result is a yarn dyed in a neutral brown shade.
By using, instead of 0.27% of the yellow dye of the formula (7) and 0.12% of the red dye of the formula (8) with 0.13% of the blue dye mixture B, the dyes of the formulae (7) and (8) together with the dye mixtures from Example 1 which are given in the following Table 2, there is obtained yarn dyed in the shades listed in the Table.
~35~
Table 2 Ex- Dyes used Shade ~ple __ _ _____ __ 13 0.18% of the dye of the formula (7) reddish-0.18% of the dye of the formula (8) brown 0.077% of the dye mixture C
14 0.25% of the dye of the formula (7) olive 0.04% of the dye of the formula (8) 0.14% of the dye mixture A
0.27% of the dye of the formula (7) neutral 0.12% of the dye of the formula (8) brown 0.13% of the dye mixture H
16 0.18% of the dye of the formula (7) reddish-0.17% of the dye of the formula (8) brown 0.07% of the dye mixture J
17 0.25% of the dye of the formula ~7) olive 0.036% of the dye of the formula (8) 0.124% of the dye mixture G
18 0.29% of the dye of the formula (7) neutral 0.13% of the dye of the formula (8) brown 0.13% of the dye mixture E
19 0.18% of the dye of the formula (7) reddish-0.18% of the dye of the formula (8) brown 0.077% of the dye mixture E
0.25% of the dye of the formula (7) olive 0.04% of the dye of the formula (8) 0.14% of the dye mixture D
By using moreover, in place of the yellow dye of theformula (7), the orange dye of the formula B
~OCH3 HO S~ -N=N--~ ~-N=N-~ -OCH3 together with the red dye of the formula (8) and the respective dye mixtures from Example 1, there are obtain~d, with the dyes given in the following Table 3, the yarn dyed in the shades indicated in the Table.
Table 3 Ex- Dyes used Shade ample 21 0.27% of the dye of formula (9) neutral 0.1 % of the dye of formula (8) brown 0.14% of the dye mixture B
22 0.18% of the dye of formula (9) reddish 0.12% of the dye of formula (8) brown 0.09% of the dye mixture C
23 0.25% of the dye of formula (9) olive 0.03% of the dye of formula (8) 0.16% of the dye mixture A
24 0~27% of the dye of formula (9) neutral 0.09% of the dye of formula (8) brown 0.14% of the dye mixture H
0.18% of the dye of formula (9) reddish-0.11% of the dye of formula (8) brown 0.09% of the dye mixture J
26 0.25% of the dye of formula (9) olive O.Q2% of the dye of formula (8) 0,14% of the dye mixture G
Table 3 (continued) Ex- Dyes used Shade ample _ __ 27 0.27% of the dye of formula (~) neutral 0.1 % of the dye of formula (8) brown 0.14% of the dye mixture E
28 0.18% of the dye of formula (9) reddish-0.12% of the dye of formula (8) brown 0.09% of the dye mixture F
29 0.25% of the dye of formula (9) olive 0.03% of the dye of formula (8) 0.16% of the dye mixture D
Example 30 (Carpet exhaust process):
A beam dyeing apparatus (laboratory piece-dyeing apparatus, Model 10, supplier Rudolf Then) consists principally of a horizontal dyeing vessel fitted with a cooling jacket, and a secondary vessel with a special circula-ting pump, and the two vessels are connected together to form a circulation system. Into this dyeing apparatus is introduced a cloth beam loaded with a polyamide-6 uncut pile carpet piece, which is 50 cm wide, 135 cm long and weighs 380 g. Six litres of softened water are then fed into the secondary vessel and 60 ml of 2 N sodium hydroxide solution are added. When the corresponding valves (secondary vessel, and connecting pipes, pumpldyeing vessel) are opened, the liquor flows under its own head into the dyeing vessel, the displaced air then passing through the vent pipe into the secondary vessel. After the dyeing apparatus has been filled, a residue of liquor about 5 cm deep remains in the secondary vessel, and the circulating pump is then switched on. For checking the pH-value, a drilled hole is located in the
0.27% of the dye of formula (7) neutral 0.12% of the dye of formula (8) brown 0.13% of the dye mixture H
6 0.18% of the dye of formula (7) reddish 0.17% of the dye of formula (8) brown 0.07% of the dye mixture J
7 0.25% of the dye of formula (7) olive 0.036% of the dye of formula (8) 0.124% of the dye mixture G
8 0.2'a% of the dye of formula (7) neutral 0.13% of the dye of formula (8) brown 0.13% of the dye mixture E
9 0.18% of the dye of formula (7) reddish-0.18% of the dye of formula (8) brown 0.077% of the dye mixture F
0.25% of the dye of formula (7) olive 0004% of the dye of formula (8) 0.14% of the dye mixture D
Example 11 10 parts of Helanca tricot are dyed in 500 parts ofan aqueous liquor containing per litre 2 g of amrnonium ~3~
acetate, the pH-v~lue of the liquor having been adjusted to 5 wi~h acetic acid. The proportion of the dye mixture B, E or G is 0.9%, relative to the weight of the fibre.
The dyeing time at a temperature of 98C is 30 to 90 minutes.
The dyed Helanca piece is subsequently removed and is rinsed and dried in the customary manner. With dye mixture B or E is obtained a fabric piece evenly dyed in a greenish-blue shade, and with the dye mixture & a fabric piece evenly dyed in a reddish-blue shade, the fabric in all cases exhibiting no sign at all of streakiness induced by the material.
10 parts of polyamide 66 yarn are dyed in 400 parts of an aqueous liquor containing per litre 1.5 g of ammonium acetate, the pH-value of the liquor having been adjusted to 5.5 with acetic acid. As dyes are used 0.27% of the dye of the formula (7), 0.12% of the dye of the formula (8) and 0.13% of the dye mixture B obtained according to Example lb), the percentage amounts being relative to the weight of fibre. The dye bath is heated within 30 minutes to 98C, and is held for 60 minutes at 96 to 98C. The dyed yarn is subsequently removed, and is rinsed and dried in the customary manner. The result is a yarn dyed in a neutral brown shade.
By using, instead of 0.27% of the yellow dye of the formula (7) and 0.12% of the red dye of the formula (8) with 0.13% of the blue dye mixture B, the dyes of the formulae (7) and (8) together with the dye mixtures from Example 1 which are given in the following Table 2, there is obtained yarn dyed in the shades listed in the Table.
~35~
Table 2 Ex- Dyes used Shade ~ple __ _ _____ __ 13 0.18% of the dye of the formula (7) reddish-0.18% of the dye of the formula (8) brown 0.077% of the dye mixture C
14 0.25% of the dye of the formula (7) olive 0.04% of the dye of the formula (8) 0.14% of the dye mixture A
0.27% of the dye of the formula (7) neutral 0.12% of the dye of the formula (8) brown 0.13% of the dye mixture H
16 0.18% of the dye of the formula (7) reddish-0.17% of the dye of the formula (8) brown 0.07% of the dye mixture J
17 0.25% of the dye of the formula ~7) olive 0.036% of the dye of the formula (8) 0.124% of the dye mixture G
18 0.29% of the dye of the formula (7) neutral 0.13% of the dye of the formula (8) brown 0.13% of the dye mixture E
19 0.18% of the dye of the formula (7) reddish-0.18% of the dye of the formula (8) brown 0.077% of the dye mixture E
0.25% of the dye of the formula (7) olive 0.04% of the dye of the formula (8) 0.14% of the dye mixture D
By using moreover, in place of the yellow dye of theformula (7), the orange dye of the formula B
~OCH3 HO S~ -N=N--~ ~-N=N-~ -OCH3 together with the red dye of the formula (8) and the respective dye mixtures from Example 1, there are obtain~d, with the dyes given in the following Table 3, the yarn dyed in the shades indicated in the Table.
Table 3 Ex- Dyes used Shade ample 21 0.27% of the dye of formula (9) neutral 0.1 % of the dye of formula (8) brown 0.14% of the dye mixture B
22 0.18% of the dye of formula (9) reddish 0.12% of the dye of formula (8) brown 0.09% of the dye mixture C
23 0.25% of the dye of formula (9) olive 0.03% of the dye of formula (8) 0.16% of the dye mixture A
24 0~27% of the dye of formula (9) neutral 0.09% of the dye of formula (8) brown 0.14% of the dye mixture H
0.18% of the dye of formula (9) reddish-0.11% of the dye of formula (8) brown 0.09% of the dye mixture J
26 0.25% of the dye of formula (9) olive O.Q2% of the dye of formula (8) 0,14% of the dye mixture G
Table 3 (continued) Ex- Dyes used Shade ample _ __ 27 0.27% of the dye of formula (~) neutral 0.1 % of the dye of formula (8) brown 0.14% of the dye mixture E
28 0.18% of the dye of formula (9) reddish-0.12% of the dye of formula (8) brown 0.09% of the dye mixture F
29 0.25% of the dye of formula (9) olive 0.03% of the dye of formula (8) 0.16% of the dye mixture D
Example 30 (Carpet exhaust process):
A beam dyeing apparatus (laboratory piece-dyeing apparatus, Model 10, supplier Rudolf Then) consists principally of a horizontal dyeing vessel fitted with a cooling jacket, and a secondary vessel with a special circula-ting pump, and the two vessels are connected together to form a circulation system. Into this dyeing apparatus is introduced a cloth beam loaded with a polyamide-6 uncut pile carpet piece, which is 50 cm wide, 135 cm long and weighs 380 g. Six litres of softened water are then fed into the secondary vessel and 60 ml of 2 N sodium hydroxide solution are added. When the corresponding valves (secondary vessel, and connecting pipes, pumpldyeing vessel) are opened, the liquor flows under its own head into the dyeing vessel, the displaced air then passing through the vent pipe into the secondary vessel. After the dyeing apparatus has been filled, a residue of liquor about 5 cm deep remains in the secondary vessel, and the circulating pump is then switched on. For checking the pH-value, a drilled hole is located in the
5~5~
pipe line between the dyeing vessel and secondary vessel (flow direction), and a combined glass electrode is inserted. The dye liquor circulates from the inside to the outside during the entire dyeing process, the pressure gradient being 0.1 to 0.2 bar, and the delivery of the pump about 6 litres per minute. The liquor is heated to 98~C and 7.6 g of an anionic levelling agent, which has affinity for the fibres and is dissolved in 100 ml of water, are introduced within 5 minutes into the secondary vessel. The dyeing temperature is adjusted to 97 to 98C
and the pH-value is 10.7. The pH-value of a specimen taken out and cooled to 20C is 11.9.
There are then fed from a dropping funnel into the secondary vessel, within 10 minutes, 2.5 g of the yellow dye of the formula (7) of Example 2, and 1.8 g of the blue dye mixture C of Example 1, both dissolved in 200 ml of hot water. After 30 minutes is added, by means of a plunger burette, a total amount oE 100 ml of 1 N sulfuric acid, for 10 minutes at a rate of 5.5 ml per minute and for a further 20 minutes at a rate of 2.25 ml per minute. The pH-value after a further 10 minutes is 3.8. The dye bath is exhausted, that is to say, the dyes have been absorbed to the extent of 99% onto the dyed material. Heating is switched off, and the temperature is lowered to 60C with the aid of indirect cooling. The pH-value during this time rises to 3.9. The liquor 3 which is almost as clear as water, is pumped back into the secondary vessel and the cloth beam is removed. The carpet material is unrolled, centrifuged and dried. The polyamide uncut pile carpet material is dyed evenly green over the whole surface.
By using, instead of 1.8 g of the blue dye mixture C, 1.8 g of the blue dye mixture F, with otherwise the same procedure, there is likewise obtained a polyamide uncut pile carpet material dyed evenly green over the whole surface.
Example 31 (Carpet printing) A velvet pile carpeting piece made from polyamide 6 weighing 350 to 400 g/m2 is impregnated, on a padding machine, with a padding liquor consisting of 988 parts of wa~er, 10 parts of sodium hydroxide solution 36 Bé and 2 parts of a wetting agent, and the material is afterwards squeezed out to give a liquor absorption of 80%. There is then sprayed onto the pretreated carpet material, by means of a nozzle, in the form of a pattern a printing paste of the following composition:
942 parts of water, parts of a thickener, 3 parts of an antifoaming agent, 3 parts of the yellow dye of the formula (7) of Example 2, 1 part of the red dye of the formula (8) of Example 2, and 1 part of the blue dye mixture A of Example 1, or 1 part of the blue dye mixture D of Example 1.
The employed -thickener has the following composition:
240 parts of white spirit, parts of a water-in-oil emulsifier, parts of an oil-in-water emulsifier, parts of an antifoaming agent, parts of a crosslinked carboxyvinyl polyvinyl polymer having a molecular weight of about 4,000,000, parts of a linear carboxyvinyl polymer having a molecular weight of about 1,000,000, and 550 parts of water, the pH-value of which has been adjusted to 4.5 with acetic acid.
The material sprayed with printing ink is subsequently treated for 5 minutes with saturated s~eam at 101C to fix the dyes; it is then rinsed, neutralised, rinsed again and dried.
~ ~5~35 The velvet pile carpeting piece obtained displays a sharply outlined brown pattern which has very good penetration and sho~s no signs at all of "frosting".
When one part of the blue dye mixture G of Example 1 is used instead of one part of the blue d~e mixture A or D
of Example 1, the procedure otherwise being the same, a velvet pile carpeting piece displaying a brown pattern and having similarly good properties is obtained.
Example 32 (Carpet continuous dyeing) 4.5 parts of the yel]ow dye of the formula (7) of Example 2 and 1.5 parts of the blue dye mixture B of Example 1 are dissolved in 100 parts of water by brief boiling. This solution is then added to solution containing 3 parts of a thickener based on locust bean flour, S.0 parts of a coacervate-forming padding auxiliary based on a condensation product of a higher molecular fatty acid with an oxyalkylamine, 2.0 parts of cryst. monosodium phosphate and 1.0 part of cryst. disodium phosphate in 500 parts of cold water. The solution is subsequently made up with cold water to 1000 parts. Of this liquor having a pH-value of 5.5 to 6.5, 300%, relative to the weight of carpet, is applied to a polyamide-6.6 tufted crude carpet at a carpet speed of 8 metres per minute. The impregnated carpet passes into a loop steamer, where it is treated for 10 minutes with saturated steam at 98 to 100C. The result after washing in a full width washing machine is a carpet material evenly dyed in a green shade.
By using, instead of 4.5 parts of the yellow dye of the formula (7) and 1.5 parts of the blue dye mixture B, the dyes and dye mixtures listed in the following Table 4, there are obtained carpets evenly dyed in the given shades.
~ ~ 5 ~ 5 Table 4 Example ¦ Dyes used Shade 33 ~2.i parts of the dye of formula (7) neutral 1.2 parts of the dye of formula (8) brown 1.3 parts of the dye mixture B
34 2.4 parts of the dye of formula (7) reddish-2.3 parts of the dye of formula (8) brown 1.0 part of the dye mixture B
3.0 parts of the dye of formula (7) olive 0.4 part of the dye of formula (8) 1.2 parts of the dye mixture B
36 4.5 parts of the dye of formula (7) green 1.5 parts of the dye mixture E
37 2.7 parts of the dye of formula (7) neutral 1.2 parts of the dye of formula (8) brown 1.3 parts of the dye mixture E
38 2.4 parts of the dye of formula (7) reddish-2.3 parts of the dye of formula (8) brown 1.0 part of the dye mixture E
39 3.0 parts of the dye of formula (7) olive 0.4 part of the dye of formula (8) 1.2 parts of the dye mixture E
2.7 parts of the dye of formula (7) neutral 1.2 parts of the dye of formula (8) brown 1.3 parts of the dye mixture H
41 2.4 parts of the dye of formula (7) reddish-2.3 parts of the dye of formula (8) brown 1.0 part of the dye mixture H
42 3.0 parts of the dye of formula (7) . olive 0.4 part of the dye of formula (8) 1.2 parts of the dye mixture H
~ V 5 Example 43 (Wool continuous dyeing) A wool material is padded with a liquor containing 2.6 parts of the yellow dye of the formula (7), 5.2 parts of the red dye of the formula (8), 15.7 parts of the blue dye mixture B, 2.0 parts of a thickener based on alginate, 22.0 parts of a coacervate-forming padding auxiliary based on a condensation product of a higher molecular fatty acid with an oxyalkylamine and 8.0 parts of 80% formic acid in 1000 parts of water, a liquor absorbtion of 85%, relative to the weight of wool, being obtained. The material is subsequently steamed for 15 minutes in saturated steam at 98 to 100C and is then washed. The result is an even olive dyeing.
When 15.7 parts of the blue dye mixture E or H are used in place of 15.7 parts of the blue dye mixture B, with otherwise the same procedure, there is likewise obtained wool evenly dyed in an olive shade.
Example 44 500 m of a polyamide(6.6) cut pile carpet (velvet pile material with polypropylene ribbon backing) having a weight per square metre of 535 g are continuously wetted in a liquor containing per litre 1 g of the reaction product of 1 mol of nonylphenol and 9 mols of ethylene oxide, and the material is ther~ subjected to suction to give a liquor absorption of 40 per cent by weight.
In a frothing apparatus (mixer) there is produced from the following aqueous liquor a dye froth having a frothing degree of 1:10:
0.6 g of the dye of the formula (7) per litre, 0.40 g of the dye of the formula (8) per litre, 0.35 g of the dye mixture B from Example 1 per litre, 2.5 g of a foam-stabilising mixture of coconut fatty acid-diethanolamide/nonylphenolpolyglycol(ll) ?5 ether and sodium lauryltriglycol ether sulfate per litre, o.6 g of a siloxanoxyalkylene-copolymer of the formula (c1~3)3si-o + Il-o ~ Ii-o ~ si(C~13)3 C~13 50 (CH2) 3-0- (C~2c~12o) 16 3 15 per litre, and 1 g of sodiumacetate perlitre, as well as acetic acid for adjusting the pH-value of ~he liquor to 6.o.
This froth is then applied from a froth container, which is provided with an adjustable doctor blade for obtaining the desired thickness of froth, by means of a chute onto the pile side of the carpet material passing through the dyeing plant (speed 9 m/minute). The coating thickness of froth is 8 mm~ and the amount of froth applied is 135%. The carpet material subsequently passes through a vacuum passage in which, from the reverse side, the froth coating is partially sucked into the carpet (reduced pressure~0.1 bar), in consequence of which the thic'~ness of the froth layer is somewhat reduced. The carpet passes then over a transport roller into a steamer (102C, saturated steam), where a slight foaming up and subsequent breaking down of the froth occurs. The carpet is afterwards sprayed with water at about 80C; it is then subjected to suction, and dried at 100 to 130C in a perforated cylinder dryer. The carpet material obtained is levelly dyed in a beige shade; there is excellent dye penetration, and the softness and fluffiness of the material are favourably affected by the froth dyeing process.
By using per litre 0.35 g of the blue dye mixture E or G, in place of 0.35 g of the blue dye mixture ~ per li~re, with otherwise the same procedure, there are likewise obtained beige-coloured, level and non-streaky carpet dyeings.
pipe line between the dyeing vessel and secondary vessel (flow direction), and a combined glass electrode is inserted. The dye liquor circulates from the inside to the outside during the entire dyeing process, the pressure gradient being 0.1 to 0.2 bar, and the delivery of the pump about 6 litres per minute. The liquor is heated to 98~C and 7.6 g of an anionic levelling agent, which has affinity for the fibres and is dissolved in 100 ml of water, are introduced within 5 minutes into the secondary vessel. The dyeing temperature is adjusted to 97 to 98C
and the pH-value is 10.7. The pH-value of a specimen taken out and cooled to 20C is 11.9.
There are then fed from a dropping funnel into the secondary vessel, within 10 minutes, 2.5 g of the yellow dye of the formula (7) of Example 2, and 1.8 g of the blue dye mixture C of Example 1, both dissolved in 200 ml of hot water. After 30 minutes is added, by means of a plunger burette, a total amount oE 100 ml of 1 N sulfuric acid, for 10 minutes at a rate of 5.5 ml per minute and for a further 20 minutes at a rate of 2.25 ml per minute. The pH-value after a further 10 minutes is 3.8. The dye bath is exhausted, that is to say, the dyes have been absorbed to the extent of 99% onto the dyed material. Heating is switched off, and the temperature is lowered to 60C with the aid of indirect cooling. The pH-value during this time rises to 3.9. The liquor 3 which is almost as clear as water, is pumped back into the secondary vessel and the cloth beam is removed. The carpet material is unrolled, centrifuged and dried. The polyamide uncut pile carpet material is dyed evenly green over the whole surface.
By using, instead of 1.8 g of the blue dye mixture C, 1.8 g of the blue dye mixture F, with otherwise the same procedure, there is likewise obtained a polyamide uncut pile carpet material dyed evenly green over the whole surface.
Example 31 (Carpet printing) A velvet pile carpeting piece made from polyamide 6 weighing 350 to 400 g/m2 is impregnated, on a padding machine, with a padding liquor consisting of 988 parts of wa~er, 10 parts of sodium hydroxide solution 36 Bé and 2 parts of a wetting agent, and the material is afterwards squeezed out to give a liquor absorption of 80%. There is then sprayed onto the pretreated carpet material, by means of a nozzle, in the form of a pattern a printing paste of the following composition:
942 parts of water, parts of a thickener, 3 parts of an antifoaming agent, 3 parts of the yellow dye of the formula (7) of Example 2, 1 part of the red dye of the formula (8) of Example 2, and 1 part of the blue dye mixture A of Example 1, or 1 part of the blue dye mixture D of Example 1.
The employed -thickener has the following composition:
240 parts of white spirit, parts of a water-in-oil emulsifier, parts of an oil-in-water emulsifier, parts of an antifoaming agent, parts of a crosslinked carboxyvinyl polyvinyl polymer having a molecular weight of about 4,000,000, parts of a linear carboxyvinyl polymer having a molecular weight of about 1,000,000, and 550 parts of water, the pH-value of which has been adjusted to 4.5 with acetic acid.
The material sprayed with printing ink is subsequently treated for 5 minutes with saturated s~eam at 101C to fix the dyes; it is then rinsed, neutralised, rinsed again and dried.
~ ~5~35 The velvet pile carpeting piece obtained displays a sharply outlined brown pattern which has very good penetration and sho~s no signs at all of "frosting".
When one part of the blue dye mixture G of Example 1 is used instead of one part of the blue d~e mixture A or D
of Example 1, the procedure otherwise being the same, a velvet pile carpeting piece displaying a brown pattern and having similarly good properties is obtained.
Example 32 (Carpet continuous dyeing) 4.5 parts of the yel]ow dye of the formula (7) of Example 2 and 1.5 parts of the blue dye mixture B of Example 1 are dissolved in 100 parts of water by brief boiling. This solution is then added to solution containing 3 parts of a thickener based on locust bean flour, S.0 parts of a coacervate-forming padding auxiliary based on a condensation product of a higher molecular fatty acid with an oxyalkylamine, 2.0 parts of cryst. monosodium phosphate and 1.0 part of cryst. disodium phosphate in 500 parts of cold water. The solution is subsequently made up with cold water to 1000 parts. Of this liquor having a pH-value of 5.5 to 6.5, 300%, relative to the weight of carpet, is applied to a polyamide-6.6 tufted crude carpet at a carpet speed of 8 metres per minute. The impregnated carpet passes into a loop steamer, where it is treated for 10 minutes with saturated steam at 98 to 100C. The result after washing in a full width washing machine is a carpet material evenly dyed in a green shade.
By using, instead of 4.5 parts of the yellow dye of the formula (7) and 1.5 parts of the blue dye mixture B, the dyes and dye mixtures listed in the following Table 4, there are obtained carpets evenly dyed in the given shades.
~ ~ 5 ~ 5 Table 4 Example ¦ Dyes used Shade 33 ~2.i parts of the dye of formula (7) neutral 1.2 parts of the dye of formula (8) brown 1.3 parts of the dye mixture B
34 2.4 parts of the dye of formula (7) reddish-2.3 parts of the dye of formula (8) brown 1.0 part of the dye mixture B
3.0 parts of the dye of formula (7) olive 0.4 part of the dye of formula (8) 1.2 parts of the dye mixture B
36 4.5 parts of the dye of formula (7) green 1.5 parts of the dye mixture E
37 2.7 parts of the dye of formula (7) neutral 1.2 parts of the dye of formula (8) brown 1.3 parts of the dye mixture E
38 2.4 parts of the dye of formula (7) reddish-2.3 parts of the dye of formula (8) brown 1.0 part of the dye mixture E
39 3.0 parts of the dye of formula (7) olive 0.4 part of the dye of formula (8) 1.2 parts of the dye mixture E
2.7 parts of the dye of formula (7) neutral 1.2 parts of the dye of formula (8) brown 1.3 parts of the dye mixture H
41 2.4 parts of the dye of formula (7) reddish-2.3 parts of the dye of formula (8) brown 1.0 part of the dye mixture H
42 3.0 parts of the dye of formula (7) . olive 0.4 part of the dye of formula (8) 1.2 parts of the dye mixture H
~ V 5 Example 43 (Wool continuous dyeing) A wool material is padded with a liquor containing 2.6 parts of the yellow dye of the formula (7), 5.2 parts of the red dye of the formula (8), 15.7 parts of the blue dye mixture B, 2.0 parts of a thickener based on alginate, 22.0 parts of a coacervate-forming padding auxiliary based on a condensation product of a higher molecular fatty acid with an oxyalkylamine and 8.0 parts of 80% formic acid in 1000 parts of water, a liquor absorbtion of 85%, relative to the weight of wool, being obtained. The material is subsequently steamed for 15 minutes in saturated steam at 98 to 100C and is then washed. The result is an even olive dyeing.
When 15.7 parts of the blue dye mixture E or H are used in place of 15.7 parts of the blue dye mixture B, with otherwise the same procedure, there is likewise obtained wool evenly dyed in an olive shade.
Example 44 500 m of a polyamide(6.6) cut pile carpet (velvet pile material with polypropylene ribbon backing) having a weight per square metre of 535 g are continuously wetted in a liquor containing per litre 1 g of the reaction product of 1 mol of nonylphenol and 9 mols of ethylene oxide, and the material is ther~ subjected to suction to give a liquor absorption of 40 per cent by weight.
In a frothing apparatus (mixer) there is produced from the following aqueous liquor a dye froth having a frothing degree of 1:10:
0.6 g of the dye of the formula (7) per litre, 0.40 g of the dye of the formula (8) per litre, 0.35 g of the dye mixture B from Example 1 per litre, 2.5 g of a foam-stabilising mixture of coconut fatty acid-diethanolamide/nonylphenolpolyglycol(ll) ?5 ether and sodium lauryltriglycol ether sulfate per litre, o.6 g of a siloxanoxyalkylene-copolymer of the formula (c1~3)3si-o + Il-o ~ Ii-o ~ si(C~13)3 C~13 50 (CH2) 3-0- (C~2c~12o) 16 3 15 per litre, and 1 g of sodiumacetate perlitre, as well as acetic acid for adjusting the pH-value of ~he liquor to 6.o.
This froth is then applied from a froth container, which is provided with an adjustable doctor blade for obtaining the desired thickness of froth, by means of a chute onto the pile side of the carpet material passing through the dyeing plant (speed 9 m/minute). The coating thickness of froth is 8 mm~ and the amount of froth applied is 135%. The carpet material subsequently passes through a vacuum passage in which, from the reverse side, the froth coating is partially sucked into the carpet (reduced pressure~0.1 bar), in consequence of which the thic'~ness of the froth layer is somewhat reduced. The carpet passes then over a transport roller into a steamer (102C, saturated steam), where a slight foaming up and subsequent breaking down of the froth occurs. The carpet is afterwards sprayed with water at about 80C; it is then subjected to suction, and dried at 100 to 130C in a perforated cylinder dryer. The carpet material obtained is levelly dyed in a beige shade; there is excellent dye penetration, and the softness and fluffiness of the material are favourably affected by the froth dyeing process.
By using per litre 0.35 g of the blue dye mixture E or G, in place of 0.35 g of the blue dye mixture ~ per li~re, with otherwise the same procedure, there are likewise obtained beige-coloured, level and non-streaky carpet dyeings.
Claims (15)
1. A dye mixture which contains a dye of the formula (1) wherein Z is hydrogen or methyl, and a dye of the formula (2), Z in the formula (1) being hydrogen when the propionyl-amino group in the formula (2) is bound in the m-position with respect to the NH group.
2. A dye mixture according to Claim 1, which contains a dye of the formula (3) and a dye of the formula (4).
3. A dye mixture according to Claim 1, which contains a dye of the formula (5) and a dye of the formula (2).
4. A dye mixture according to Claim 3, which contains, as dye of the formula (2), a dye of the formula (4).
5. A dye mixture according to Claim 3, which contains, as dye of the formula (2), a dye of the formula (6).
6. A dye mixture according to Claim 1 wherein the ratio between the dyes is 20:80 to 80:20.
7. A dye mixture according to Claim 6, wherein the ratio between the dyes is 40:60 to 60:40.
8. A dye mixture according to Claim 7, wherein the ratio between the dyes is 50:50 to 60:40.
9. A process for dyeing and printing natural and synthetic polyamide materials with a dye mixture, wherein a dye mixture according to Claim 1 is used.
10. A process for dyeing and printing natural and synthetic polyamide materials by use of the dye mixture according to Claim 1 in combination with other dyes.
11. A process according to Claim 10 for trichromatic dyeing or printing, wherein there is used a dye mixture according to Claim 1 in combination with at least one red dye and at least one yellow or orange dye.
12. A method of dyeing and printing which comprises applying to a sub-strate a dye mixture according to claim 1.
13. A dyeing or printing composition containing a dye mixture according to Claim 1.
14. A material, dyed or printed according to Claim 9.
15. A textile material, dyed or printed according to Claim 9.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH832981 | 1981-12-29 | ||
| CH8329/81-0 | 1981-12-29 | ||
| CH8330/81-7 | 1981-12-29 | ||
| CH833081 | 1981-12-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1185058A true CA1185058A (en) | 1985-04-09 |
Family
ID=25703163
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000395915A Expired CA1185058A (en) | 1981-12-29 | 1982-02-10 | Dye mixtures and their use |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4396393A (en) |
| EP (1) | EP0083300B1 (en) |
| JP (1) | JPH0699642B2 (en) |
| AU (1) | AU551929B2 (en) |
| CA (1) | CA1185058A (en) |
| DE (1) | DE3273814D1 (en) |
| DK (1) | DK155370C (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE19533T1 (en) * | 1982-04-08 | 1986-05-15 | Ciba Geigy Ag | PROCESS FOR TRICHROMIC DYING OR PRINTING. |
| JPS5962696A (en) * | 1982-10-01 | 1984-04-10 | Hitachi Ltd | Improvement of coal |
| DE3466715D1 (en) * | 1983-05-25 | 1987-11-12 | Ciba Geigy Ag | Trichromatic dyeing or printing process |
| EP0387201B1 (en) * | 1989-03-10 | 1994-02-02 | Ciba-Geigy Ag | Mixture of dyestuffs and their use |
| DK0425434T3 (en) * | 1989-10-23 | 1995-12-18 | Ciba Geigy Ag | Dye mixtures and their use |
| EP0425435A1 (en) * | 1989-10-23 | 1991-05-02 | Ciba-Geigy Ag | Process for trichromic dyeing or printing |
| US6033445A (en) * | 1997-02-10 | 2000-03-07 | Ciba Specialty Chemicals Corporation | Dye mixtures and their use |
| EP0859034B1 (en) * | 1997-02-10 | 2002-04-24 | Ciba SC Holding AG | Mixtures of dyes and their use |
| CA2326195A1 (en) * | 1998-04-02 | 1999-10-14 | Tecnol Medical Products, Inc. | Multi-compartment package for mixing and dispensing measured amounts of a product |
| US6990904B2 (en) | 2000-10-31 | 2006-01-31 | International Imaging Materials, Inc | Thermal transfer assembly for ceramic imaging |
| US6796733B2 (en) | 2000-10-31 | 2004-09-28 | International Imaging Materials Inc. | Thermal transfer ribbon with frosting ink layer |
| US6854386B2 (en) | 2000-10-31 | 2005-02-15 | International Imaging Materials Inc. | Ceramic decal assembly |
| US20070179356A1 (en) * | 2005-12-29 | 2007-08-02 | Guidance Interactive Healthcare, Inc. | Programmable devices, systems and methods for encouraging the monitoring of medical parameters |
| US20080015422A1 (en) * | 2005-12-29 | 2008-01-17 | Guidance Interactive Healthcare, Inc. | Combined peripheral and health monitoring devices |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE538310C (en) | 1929-07-17 | 1931-11-12 | Ig Farbenindustrie Ag | Process for the production of wool dyes of the anthraquinone series to be dyed in an acid bath |
| CH300337A (en) | 1952-01-18 | 1954-07-31 | Ag Sandoz | Process for the preparation of a blue leveling dye of the anthraquinone series. |
| CH487222A (en) * | 1967-04-05 | 1970-03-15 | Geigy Ag J R | Process for the preparation of acidic anthraquinone dyes |
| GB1315237A (en) * | 1970-06-23 | 1973-05-02 | Ciba Geigy Ag | Dyeing and printing of polyamide fibres |
| BE788614R (en) * | 1970-09-22 | 1973-03-08 | Sandoz Sa | MATERIAL FINISHING PROCESS |
| DE2710152C2 (en) * | 1977-03-09 | 1978-11-02 | Bayer Ag, 5090 Leverkusen | Dyeing of synthetic polyamides |
| EP0042357B1 (en) * | 1980-06-13 | 1984-06-06 | Ciba-Geigy Ag | Azo dyes, their preparation and use |
-
1982
- 1982-02-05 EP EP82810053A patent/EP0083300B1/en not_active Expired
- 1982-02-05 DE DE8282810053T patent/DE3273814D1/en not_active Expired
- 1982-02-08 US US06/346,979 patent/US4396393A/en not_active Expired - Lifetime
- 1982-02-10 DK DK056182A patent/DK155370C/en not_active IP Right Cessation
- 1982-02-10 CA CA000395915A patent/CA1185058A/en not_active Expired
- 1982-02-10 JP JP1903382A patent/JPH0699642B2/en not_active Expired - Lifetime
- 1982-02-18 AU AU80583/82A patent/AU551929B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0699642B2 (en) | 1994-12-07 |
| AU551929B2 (en) | 1986-05-15 |
| EP0083300A1 (en) | 1983-07-06 |
| US4396393A (en) | 1983-08-02 |
| DK155370C (en) | 1989-09-11 |
| DK56182A (en) | 1983-06-30 |
| AU8058382A (en) | 1983-07-07 |
| DE3273814D1 (en) | 1986-11-20 |
| EP0083300B1 (en) | 1986-10-15 |
| JPS58118859A (en) | 1983-07-15 |
| DK155370B (en) | 1989-04-03 |
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