CA1167616A - Method and apparatus for producing a tubular article having an annular groove therein - Google Patents
Method and apparatus for producing a tubular article having an annular groove thereinInfo
- Publication number
- CA1167616A CA1167616A CA000378540A CA378540A CA1167616A CA 1167616 A CA1167616 A CA 1167616A CA 000378540 A CA000378540 A CA 000378540A CA 378540 A CA378540 A CA 378540A CA 1167616 A CA1167616 A CA 1167616A
- Authority
- CA
- Canada
- Prior art keywords
- blank
- groove
- wall
- shaping
- thickness
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
- B65D1/0207—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C31/00—Handling, e.g. feeding of the material to be shaped, storage of plastics material before moulding; Automation, i.e. automated handling lines in plastics processing plants, e.g. using manipulators or robots
- B29C31/002—Handling tubes, e.g. transferring between shaping stations, loading on mandrels
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/071—Preforms or parisons characterised by their configuration, e.g. geometry, dimensions or physical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/08—Biaxial stretching during blow-moulding
- B29C49/10—Biaxial stretching during blow-moulding using mechanical means for prestretching
- B29C49/14—Clamps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/22—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using multilayered preforms or parisons
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C49/54—Moulds for undercut articles
- B29C49/541—Moulds for undercut articles having a recessed undersurface
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/22—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of tubes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/30—Drawing through a die
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
- B29C59/04—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts
- B29C59/043—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing using rollers or endless belts for profiled articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/0003—Moulding articles between moving mould surfaces, e.g. turning surfaces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/0014—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for shaping tubes or blown tubular films
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D1/00—Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
- B65D1/02—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
- B65D1/0223—Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by shape
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/36—Moulds for making articles of definite length, i.e. discrete articles
- B29C43/361—Moulds for making articles of definite length, i.e. discrete articles with pressing members independently movable of the parts for opening or closing the mould, e.g. movable pistons
- B29C2043/3615—Forming elements, e.g. mandrels or rams or stampers or pistons or plungers or punching devices
- B29C2043/3631—Forming elements, e.g. mandrels or rams or stampers or pistons or plungers or punching devices moving in a frame for pressing and stretching; material being subjected to compressing stretching
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2793/00—Shaping techniques involving a cutting or machining operation
- B29C2793/009—Shaping techniques involving a cutting or machining operation after shaping
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/072—Preforms or parisons characterised by their configuration having variable wall thickness
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/072—Preforms or parisons characterised by their configuration having variable wall thickness
- B29C2949/0723—Preforms or parisons characterised by their configuration having variable wall thickness at flange portion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/073—Preforms or parisons characterised by their configuration having variable diameter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/073—Preforms or parisons characterised by their configuration having variable diameter
- B29C2949/0732—Preforms or parisons characterised by their configuration having variable diameter at flange portion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/076—Preforms or parisons characterised by their configuration characterised by the shape
- B29C2949/0768—Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform
- B29C2949/077—Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform characterised by the neck
- B29C2949/0772—Closure retaining means
- B29C2949/0776—Closure retaining means not containing threads
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/076—Preforms or parisons characterised by their configuration characterised by the shape
- B29C2949/0768—Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform
- B29C2949/078—Preforms or parisons characterised by their configuration characterised by the shape characterised by the shape of specific parts of preform characterised by the bottom
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/079—Auxiliary parts or inserts
- B29C2949/08—Preforms made of several individual parts, e.g. by welding or gluing parts together
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/0861—Other specified values, e.g. values or ranges
- B29C2949/0862—Crystallinity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/253—Preform
- B29K2105/258—Tubular
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/004—Semi-crystalline
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
- Y10S425/218—Pipe machine: socket forming apparatus
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
Abstract
Abstract of the Disclosure A tubular article having a peripheral groove is formed by providing the groove in the wall of a tubular blank made of thermoplastic material such as polyethylene terephthalate by applying simultaneously a pressure against the wall of the blank and axial stretching forces. In the bottom of the groove the material is drawn to yielding and the blank is simultaneously elongated.
Description
~ ~ti~o~
This invention consists of a tubular article made of polyethylene terephthalate or a similar material having a wall consisting of mostly amorphous material, with a peripheral groove in the article wall arranged in such a way that the thickness of the material at the bottom of the groove is reduced relative to the rest of the wall.
Canadian Patent Application ~o. 378,503, filed May 28, 1981, explains how a tubular blank made of polyethylene terephthalate or similar material can be converted into an object consisting either in whole or in part of monoaxially-oriented material. During conversion, the transition zones between the amorphous material and the oriented material are moved in the axial direction of the blank by means of mechanical shaping devices consisting of drawing rings that surround '~.
]. ~
the blank and interact during conversion with a mandrel inserted in the blank.
In an alternative version of the invention described in the aforesaid Patent Application, conversion starts from an initiating groove in the wall of the blank. A blank in which an initiating groove has been made will hereinaf-ter be called an article. An article is thus an inter-mediate product formed during conversion of the blank into an object.
The aforesaid Patent Application states that the initiating groove is formed by applying external pressure by means of mechanical devices to the amorphous material in the blank in the region where the groove is to be formed while simultaneously applying stretching forces in the axial direction which affect the material in this same region.
The mechanical device gradually reduces the thickness of the material in the aforesaid region, which means that the axial stretching force per unit of cross-sectional surface area gradually increases in a cross-section taken through the region where the material thickness is to be reduced.
The axial stretching forces are adapted to the properties of the material in such a way that yield occurs in the material at the bottom of the groove when the final stage of groove formation commences. Moreover, the conversion of the blank takes place at a temperature close to or beneath the glass transition temperature of the blank, hereinafter abbreviated TG. As a rule, the temperature of the blank is considerably below TG, and it should preferably be at room temperature when the formation of the groove commences. Obviously, the mechanical work carried out in connection with conversion entails an increase in the temperature of the material which, in turn, affects the tendency of the material to yield.
This description explains in detail (a) a method of converting a blank into an article and (b) a device used to form the groove.
A method in accordance with the present invention for producing an article with a peripheral groove comprises providing a tubular blank of essentially amorphous polyethylene terephthalate, applying pressure against the wall of the blank by a mechanical shaping device which is relatively narrow in the axial direction of the blank and contacts the blank peripherally to compress the wall of the blank, applying axial stretch-ing forces by external devices which affect the material in the region in which the pressure is applied, whereby the thickness (d) of the material in said region is reduced to a thickness which corresponds to the thickness obtained when a panel made of the amorphous material having a thickness (a) of said blank is monoaxially drawn until yield occurs at an initial temperature immediately before drawing that is the same as the temperature of the material in the bottom of the groove immediately before yield commences as the groove is i*~;'7b;~.~
- 3a -formed.
The groove in the article comprises the initiation region for subsequent axial orientation of the essentially amorphous material in the article and for axial prolongation of this material to form the object. The thickness of the material at the bottom of the groove after the groove is formed corresponds closely to the thickness which the axially oriented parts of the object will acquire. One prerequisite for providing this material-wall thickness when the article is converted to an object is thus that the initial positions of the drawing rings are such that when they are moved in the article's axial direction, they will provide the necessary material reduction and thus the correct object material thickness. In a pre-ferred version of this invention, this is achieved by having the inside of the bottom of the groove largely flush with the inside of the adjacent amorphous material, thus making certain that it will be possible for the drawing rings to assume the aforesaid initial positions.
-7~ 4 In an alternative version of this invention, the final forming of the groove is accomplished by having the draw-ing rings, when being placed in the initial positions, provide the movement of material in the bottom of the groove towards the object's axis that is required to achieve the position of the material wall set forth in the previous paragraph.
Application of this invention provides an article with a peripheral groove arranged in such a way that the thick-ness of the material in the bottom of the groove is re-duced relative to the thickness of the adjacent walls.
The wall thickness in the bottom of the groove shall thus correspond to the thickness a sheet or panel, made of the same amorphous material as that adjacent to the groove and having a thickness corresponding to the thickness of the material of the article adjacent to the groove, obtains when having a temperature corresponding to the temperature which the material at the bottom of the groove has immediately before the final phase of formulation of the groove and the sheet or-the panel drawn monoaxially until it yields. The material in the wall at the bottom of the groove has a crystallization in the range 10-30 %, preferably in the range 10-17 %.
An article having a region of material at the bottom of the groove with an orientation and, sometimes, a supple-mentary thermal crystallization that causes overall ,, crystallization to the extent mentioned in the previous paragraph is well suited for conversion to an object.
As reduction of the wall thickness of the parts of the article adjacent to the groove continues due to the fact that its material is caused to yield, one obtains a region of reduced material thickness consisting of the initial region formed by the bottom of the groove and the adjacent areas having reduced material thickness.
The material region thus provided forms, sometimes after supplementary thermal crystallization, an essentially uniform material region both mechanically and thermally.
In connection with the production of a bottle, for example, one can permit this material region to form the neck and mouth of the bottle, thus making it possible to provide a bottle having considerably better characteristics with regard to strength and temperature resistance. Moreover, the material thickness in the neck and mouth of the bottle is reduced relative to what is possible with the methods and devices heretofore known.
One special advantage of the groove is that it makes it possible to provide regions of reduced-thickness material arranged symmetrically around the groove. This is important because it permits the article to be used in applications calling for two containers such as bottles arranged opposite each other and produced in one or more operations.
An apparatus in accordance with the present 76:~
- 5a -invention comprises a device for producing a tubular article with a peripheral groove from a tubular blank having a wall of essentially amorphous material, including fixing means for fixedly engaging the wall of the blank on both sides of a region in which the grocve is to be formed and for axial movement in opposite directions while maintaining secure engagement with the wall of the blank to produce axial stretching forces in the blank. Mechanical shaping means are provided for contacting and compressing the wall of the blank in the region in which the groove is to be formed while undergoing movement peripherally around the blank and also perpendicular to the axis of the blank such that the groove is formed in the wall of the blank with gradually increasing depth, and the axial stretching forces applied by the fixing means to the material in the bottom of the groove causes the material to yield while its thickness is simultaneously reduced.
In one version of this invention, successive reduction of 76~ 6 the material thickness is accomplished by a number of rollers, although only one roller is used in certain applications. When the groove is formed, the roller or rollers are moved around the periphery of the blank while the distance to the blank axis is gradually reduced and while the material which contacts the roller or rollers is exposed to the aforesaid stretching forces.
In a preferred version of this invention, three rollers are used, and they are brought into contact with the wall of the blank successively and are then moved gradually towards the axis of the blank as the groove is formed.
The roller which first contacts the wall of the blank and commences to form the groove has a relatively narrow con-tact surface. It is followed by the second roller which further deepens and widens the groove while simulta-neously reducing the thickness of the material in the bottom of the groove to a value which permits the stretch-ing forces per unit of area to accomplish the aforesaid yield of the material. This provides relatively symmetrical streching of the material while it is simultaneously being thinned, and as a result the inner surface of the material wall at the bottom of the groove is moved slightly away from the axis of the blank. The third roller serves as a shaping roller which moves the ma-terial wall to a position at which its inner surface is largely flush with the inner surfaces of the adjacent parts of the material.
~ ?~;'7~1~ 7 In an alternative version of this invention, the rollers are replaced by an extended shaping device having an edge against which the blank rolls while the distance of the edge from the axis of the blank is reduced. Preferably, the device terminates in a part having an edge with a width, a length and a position which, because of the movement relative to the blank will affect the material in the bottom of the groove in roughly the same way as set forth for the third roller mentioned in the previous paragraph. The extended shaping device shall preferably be roughly circular and designed in such a way that the shaping edge is on the inside of the ring. This simplifies control, guidance and movement of the blank and also simplifies its movements relative to the shaping device.
During formation of the groove, a central mandrel is usually provided inside the blank. The mandrel has a central part which serves as a support for the wall of the blank in the region where the groove is to be formed. At the two ends of the blank, the mandrel is also provided with sections which also serve as supports for the wall of the blank in order to prevent the blank from being deformed by the fixing devices which grip the blank in connection with the application of the aforesaid stretching forces used to form the groove.
Fixing devices are also needed to provide reliable guid-ance of the blank relative to the shaping device or de-vices while the groove is being formed.
~ 8 This invention is intended especially for use in connec-tion with the production of articles made of thermoplastic of the polyester or polyamide type. One example of such a material is polyethylene terephthalate. Other examples are S polyhexamethylene-adipamide, polycaprolactam~ polyhexa-methylene-sebacamide, polyethylene-2.~- an~
1,5-naphthalate, polytetramethylene-1,2-dioxy-benzoate and copolymers of ethylene terephthlate, ethy-lene isophthalate and other similar polymer plastics.
The description of this invention is related, for the most part, to polyethylene terephthalate, hereinafter often abbreviated to PET. However, this invention is not limited to the use of this material or any other of the previously mentioned materials. It is applicable for many other thermoplastic materials as well.
The crystallization percentages mentioned previously in connection with PET and which will be mentioned again in connection with PET, are related to~the theory set forth in the publication entitled "Die Makromolekulare Chemie"
176, 2459-2465 (1975).
This invention is described in greater detail in connec-tion with the following illustrations:
Fig. 1 a-d illustrates the general cycle used to form an article from a tubular blank.
J.,~ 9 Fig. 2 a, b illustrates in detail the final formulaticn of the groove in the article.
Fig. 3 presents a perspective view of one version of the invention.
Fig. 4 presents a perspective view of an alternative version of the invention.
Fig. 5 presents a cross section and axial section showing details of the version of the inven-tion shown in Fig. 3, particularly the ar-rangement of the shaping rollers.
Fig. 6 presents an axial section showing details of a fixing device and drawing device used ln either of the versions of this invention shown in Fig. 3 and Fig. 4.
15 Fig. 1 a-d illustrates the principles of this invention as follows. A blank 10 consisting essentially of amorphous material is provided with a peripheral groove 12 through-out a shaping cycle, sometimes called a conversion cycle, in which a number of shaping rollers 31-33 are success-ively brought to bear against the blank and simultaneous-ly moved peripherally around the blank and also towards the blank axis. Reference number 17 indicates a blank in which the formation of the groove has commenced. Reference number 18 indicates a blank in which the material in the bottom of the groove has yielded. Reference number 19 indicates an article made from blank 10 in which groove 12 has obtained its final form. The letter b at lower right in Fig. ld indicates half of the prolongation of the blank which occurs during conversion to article 19.
A mandrel 20 is provided inside the blank, and it has a central part 22 and outer parts 21 a, 21 b. The mandrel also has an axis 23 along which the outer parts of the mandrel can be moved. Springs (not shown in the illustra-tions) tend to keep the outer parts of the mandrel 21 atthe positions shown in Fig. 1 a. Moreover, fixing devices 34 a, 34 b are arranged to hold the outer parts of the blank by clamping them between the fixing device and the outer parts of the mandrel 21 a, 21 b. The fixing devices are also arranged so that they can be moved in the axial direction of the blank while simultaneously holding the blank securely by means of the aforesaid clamping arrange-ment. This movement is indicated by arrow H which also in-dicates the directions bf the axial stretching forces which are applied to the material via the fixing devices.
In connection with the application of this invention, blank 10 is threaded over the mandrel until it strikes a stopping surface 35 on fixing device 34 a. This provides accurate axial positioning of the blank on the mandrel.
The fixing devices grip the ends of the blank, after which the fixing devices are acted on by a driving device to provide stretching forces in the axial direction.
Rollers 31-33 are then brought to bear successively on the wall of the blank, and they are moved around the blank's periphery while simultaneously being moved gradually to-wards the blank axis. Roller 31, which contacts the wall of the blank first and commences to form the groove has a relatively narrow contact surface. It is followed by roller 32, which is brought into contact with the material in such a way as to widen and deepen the shallow groove formed by the first roller. The second roller deepens the groove while simultaneously reducing the thickness of the material in the bottom of the groove to a value which permits the stretching forces applied to the ma-terial 15 in the bottom of the groove to cause the ma-terlal to yield. The material is thus thinned, while its inner surface simultaneously moves slightly away from the central part of the mandrel 22. The third roller 33 which has a shape adapted to the desired final shape of the groove that is intended to be formed then moves the material 15 in the bottom of the groove into contact with the central part of the mandrel 22, whereupon the inner sur-face of material 15 in the bottom of the groove assumes a position that is largely flush with the adjacent inner surfaces of the article that is formed 19. When the forming of the groove com~ences, the material is at a temperature which is considerably below its glass transition tempera-ture (TG).
Fig. 2 a, b presents an enlarged, detailed illustration of the final phase of the forming of the groove. In addi-tion to the reference numbers and letters used in Fig. 1 a-d, the original thickness of the material wall is indi-cated by the letter a, and the thickness of the material in the bottom of the groove is indicated by the letter d.
S Fig. 3 presents one version of a device used to apply this invention in which shaping rollers are used as shap-ing devices. A frame 40 is arranged with a central drive shaft 41 on which are attached a number of holders 43 a-d.
A stepping motor 42 serves as the driving device for the central drive shaft and moves the conversion stations to the positions marked I-IV in the illustration. The holders support the devices which form the conversion stations in which the blank is converted to an article. In this illus-tration, and also in Fig. 4, the devices used in the con-version stations are indicated by reference numbers to which the letters a, b, c and d have been appended to indicate that the device in question belongs to a parti-cular conversion station.
~ supporting shaft 44 is attached to each holder and supports a first fixing device 67 which, at positions I
and I~, is moved by driving device 72 out to the exposed end of supporting shaft 44. Another driving device 74 is connected via lever 78 to this first fixing device 67 in order to secure one end of the blank 10 that is to be converted into article 19. A second fixing device is contained in holder 43. Another driving device 75 is connected via a lever 79 to secure the other end of the . . ' .
3'~ 7~ ~ 13 blank. A first and second pressure sleeve 97, 98 are provided between the two fixing devices in such a way that they straddle a sleeve 56 which contains shaping rollers 31-33. The illustration also shows driving device 46 which, via levers 47, provides the aforesaid movement of the shaping rollers perpendicular to the axis of the blank. Driving device 76, via a link system and eccentrics 95, moves pressure sleeves 97, 98 in the axial direction of the blank. Each conversion station is also provided with its own driving device 45 which rotates mandrel 20 and thus the blank which is secured to the mandrel by means of fixing devices 67, 68.
Fig. 3 also shows a feed device for blanks 10. This device feeds the blanks into the first fixing device 67 when the conversion station is at position I. Feed wheels 65, in combination with blank carrier 64 and a feed/discharge device 66 are all a part of the feed device.
Fig. 4 shows an alternative version of a device used for the'application of this invention in which the shaping rollers are replaced by an extended shaping device 60 with an edge 61. This edge forms a roughly circular limiting surface'which'has a varying width and varying distance from the centre of rotation. A part of the limiting sur-face'must have a length corresponding to at least the circumferance of the blank. Moreover, this part of the limiting surface must have a shape which corresponds to the shape which the groove is to have when conversion into i>76i1~
an article is completed.
Shaping device 60 is arranged as a roughly circular hol-der 59. The driving device (not shown in the illustration) can rotate the shaping device around its axis.
Frame 63 is arranged on base 62. The frame has a centrally located hole 58. Feed wheels 65, blank carrier 64 and feed/discharge device 66 are arranged relative to the hole in accordance with the description of Fig. 3.
A number of supporting arms 69 (four in this illustration) are arranged relative to frame 33 and on sliding shafts 70 by means of a bearing 71 in such a way that the supporting arms can be moved from one position adjacent to frame 63 to another position close to shaping device 60 and back again to the first position. At the other end, each sup-porting arm is provided with a first fixing device 67 which corresponds to the first fixing device mentioned in the description of Fig. 3. Sliding shaft 70 is also carried on bearing 77 in frame 63 so that, by means of driving device 73, it can be turned between one position in which the first fixing device 67 is located at the centre of hole 58 and a second position that corresponds approximately to the position of edge 61 on shaping device 60.
Supporting devices 69 are attached to the frame 63. Devices 69 have each a first fixing device 67, which interacts with a second 1 ~;'7~1~ lS
fixing device 68 arranged ad~acent to two pressure sleeves 98, 97. The second fixing device and the press-ure sleeves, together with the first fixing device form a conversion station for blank 10 when the first fixing device 67 is moved to a position adjacent to shaping de-vice 60. Driving devices 74-76 with their link system are provided for fixing devices 67, 68 and for pressure sleeves 97, 98 in the same way as shown in Fig. 3. The reference numbers for these link systems are the same as the reference numbers used in Fig. 3. Reference number 78 indicates a lever for the first fixing device 67. Refer-ence number 79 indicates a le~er for the second fixing device 68.
In Fig. 5 a, b, Fig. 5 b shows section 5b-5b in Fig. 5 a, i.e. a section taken along blank lO's axis in a device like the one shown in Fig. 4. Fig. 5 a, b illustrates the structure of a shaping device that consists of shaping rollers. Circular housing 50 contains supporting device 48 on which lever 47 is attached. The supporting device can rotate in housing 50. A number of guide rollers 49 are carried on supporting device 48 and follow it when it ~noves. Shaping rollers 31-33 are carried in roller holder 51. The roller holder has a guide surface 52 against which each of guide rollers 49 roll. The roller holders can rotate around pivot point 53. A spring 54 returns the roller holders to their initial positions so that blank 10 can be fed in between the rollers. Roller holders 51 are mounted on a ring 55 which is attached to circular housing 50.
.' I
~ 7~1~ 16 Fig. 6 presents a section taken in the axial direction of blank 10 through the part of the conversion station which secures one of the ends of the blank. In this illustration, the blank has been threaded onto the mandrel.
Reference number 25 indicates an extension of the mandrel axis 23. This extension is carried in bearing 99. In a version of this invention in which shaping rollers are used, extension 99 is connected to driving device 45, while in an alternative version where shaping is carried out by means of an extended shaping device, the mandrel runs freely in bearing 99. Reference number 81 indicates a fixed sleeve in which bearing 99 and the other devices located adjacent to the fixing devices and stretching devices used for blank 10 are mounted.
The aforesaid lever 7~ is attached to transmission device 82. When thé lever moves, transmission device 82 is screwed into threaded member 83 and simultaneously pulls tapered device 94 in and over fixing jaws 85. As a result, the blank is securely clamped between the fixing jaws and the outer part of mandrel 21. The fixing jaws are arranged in a holder 38. Bearings 87, 84 permit holder 38 and the tapered device 94 to rotate when blank 10 rotates.
The aforesaid lever 88 is attached to actuator 89 which, when the lever moves, is screwed out of holder 90 and moves a pressure sleeve 91 against part 83 which, in turn, moves into the fixed sleeve. This exerts a pulling force 3.~.~t~ 17 on blank 10 via ixing jaws 85. Part 83 is prevented from rotating by stop pin 93.
When a blank 10 is converted into an article 19 by means of the version of the invention shown in Fig. 3, blank 10 is fed by means of feed wheels 65, blank carrier 64 and feed/discharge device 66, whereupon the feeding operation is terminated by a shoulder in the first fixing device 67 a. Driving device 74 actuates the fixing device so that the blank is secured firmly by the first fixing device.
Simultaneously, the first fixing device is actuated by driving device 72 a in such a way that it moves into con-tact with the first pressure sleeve 97. Also simultaneous-ly, the blank is inserted between shaping rollers 31-33 (see Fig. 5 a, b). Also simultaneously, the other end of the blank is moved against stopping surface 35 in the second fixing device 68 a (hidden in the illustration).
Driving device 75 then actuates the second fixing device so that it secures the other end of the blank.
When driving device 46 a, which provides movement of the shaping rollers towards the axis of the blanks is actuated, the shaping rollers are moved as described above in connection with Fig. 5 a, b in order to form groove 12.
Driving device 76 a, when it is actuated, exposes the ma-terial to stretching forces in the same way as described previously. Then, when the thickness of the material in the bottom of the groove reaches a predetermined value, it will yield. As a result, the blank is stretched. Con-J~ j; 18 version to an article is then concluded when shaping roller 33 moves the material in the bottom of the groove into contact with the mandrel thus determining the final shape of the groove. Relative movement between the shaping 5 rollers on the one hand and the blank on the other is provided by driving device 45 a, after the two ends of the blank have been secured in the first and second fixing de-vices by that the driving device 45 a-- rotates the mandrel and thus rotates the blank itself.
While the cycle described above is being carried out, stepping motor 42 moves the conversion station step by step from position I to position IV, as shown in the il-lustration.
~t position IV, the shaping rollers are returned to their initial positions, and the second fixing device releases the' blank. Thereafter, driving device 72 a moves the first fixing device 67 a back to its initlal position. Driving device 74 a returns to its initial position and releases the end of the article, after which a new blank 10 can be moved in the axial direction into the first fixing device while'article l~ a is simultaneously discharged.
The above paragraphs have explained how a conversion sta-tion is ussd to convert a blank to an article. Each of the conversion statlons converts one blank in the same manner as set forth'above. Even thbugh the illustration shows four conversion stations, it is possible to arrange a de-3~ j 19 vice like the one shown in Fig. 3 with more or fewer con-version stations.
Moreover, the description refers to the use of three shaping rollers which successively shape the groove. De-pending upon the way in which, for example, the width and shape of the groove are to be formed, it is possible within the scope of this invention to use either more or fewer shaping rollers.
When converting a blank 10 into an article 19 using the version of this invention shown in Fig. 4, blank 10 is fed in the same way as described in connection with Fig.
3~ after which the first fixing device 67 a is moved by driving device 73 a to the position shown by the broken lines in Fig. 3. Driving device 72 a then moves the fixing device to a position adjacent to the extended shaping de-vice'60 where, together with the second fixing device 68 a and the intermediate devices such as actuator 89 and hol-der 90, it forms the composite device used to secure the bIank while it is being converted to an article.
Now, the'other end of the blank is secured in the same ,w,a~ as described in connection with Fig. 6, whereupon the material in the region where the groove is to be formed is exposed to axial stretching forces.
The driving devices rotate the extended shaping device 60 which, when the blank was moved to the aforesaid position ~ 7~ 1~ 2 assumed a position at which edge 61 did not obstruct axial movement of the blank. As rotation proceeds, edge 61 is gradually moved closer to the centre of the blank, where-with the blank rolls against the edge while the groove is being formed. In the same way as described previously, the material at the bottom of the groove y~elds after a certain time interval. The final shape of the groove is then determined by having the material in the bottom of the groove contact an edge shaped and located in such a way that the material wall is pressed against the central part of the mandrel throughout at least one full revolu-tion of the blank. This procedure provides the final shape of the groove.
~s the rotation of the extended shaping device continues, edge 61 moves away from the material in the newly-formed article, and the second fixing device releases the ar-ticle, after which the first fixing device i5 moved to its initial position. The article is then released and a new blank is moved axially into the first fixing device while the article that was formed is simultaneously dis-char~ed.
In this version of the invention, it is also possible to provide more or fewer conversion stations than shown in thé illustration.
The material in the bottom of the groove becomes crystal-lized to a maximum,of approximately 17%, which through ~ 21 supplementary thermal crystallization can provide a maxi-mum of approximately 30% without causing problems when the article is subsequently shaped into new products.
This invention is intended especially for application in connection with the production of articles made of thermo-plastic of the polyester or polyamide types. Examples of such materials were presented in the introductory part of this description.
In addition to the above specification, the invention is also described in the following Patent Claims.
MG/Fgi
This invention consists of a tubular article made of polyethylene terephthalate or a similar material having a wall consisting of mostly amorphous material, with a peripheral groove in the article wall arranged in such a way that the thickness of the material at the bottom of the groove is reduced relative to the rest of the wall.
Canadian Patent Application ~o. 378,503, filed May 28, 1981, explains how a tubular blank made of polyethylene terephthalate or similar material can be converted into an object consisting either in whole or in part of monoaxially-oriented material. During conversion, the transition zones between the amorphous material and the oriented material are moved in the axial direction of the blank by means of mechanical shaping devices consisting of drawing rings that surround '~.
]. ~
the blank and interact during conversion with a mandrel inserted in the blank.
In an alternative version of the invention described in the aforesaid Patent Application, conversion starts from an initiating groove in the wall of the blank. A blank in which an initiating groove has been made will hereinaf-ter be called an article. An article is thus an inter-mediate product formed during conversion of the blank into an object.
The aforesaid Patent Application states that the initiating groove is formed by applying external pressure by means of mechanical devices to the amorphous material in the blank in the region where the groove is to be formed while simultaneously applying stretching forces in the axial direction which affect the material in this same region.
The mechanical device gradually reduces the thickness of the material in the aforesaid region, which means that the axial stretching force per unit of cross-sectional surface area gradually increases in a cross-section taken through the region where the material thickness is to be reduced.
The axial stretching forces are adapted to the properties of the material in such a way that yield occurs in the material at the bottom of the groove when the final stage of groove formation commences. Moreover, the conversion of the blank takes place at a temperature close to or beneath the glass transition temperature of the blank, hereinafter abbreviated TG. As a rule, the temperature of the blank is considerably below TG, and it should preferably be at room temperature when the formation of the groove commences. Obviously, the mechanical work carried out in connection with conversion entails an increase in the temperature of the material which, in turn, affects the tendency of the material to yield.
This description explains in detail (a) a method of converting a blank into an article and (b) a device used to form the groove.
A method in accordance with the present invention for producing an article with a peripheral groove comprises providing a tubular blank of essentially amorphous polyethylene terephthalate, applying pressure against the wall of the blank by a mechanical shaping device which is relatively narrow in the axial direction of the blank and contacts the blank peripherally to compress the wall of the blank, applying axial stretch-ing forces by external devices which affect the material in the region in which the pressure is applied, whereby the thickness (d) of the material in said region is reduced to a thickness which corresponds to the thickness obtained when a panel made of the amorphous material having a thickness (a) of said blank is monoaxially drawn until yield occurs at an initial temperature immediately before drawing that is the same as the temperature of the material in the bottom of the groove immediately before yield commences as the groove is i*~;'7b;~.~
- 3a -formed.
The groove in the article comprises the initiation region for subsequent axial orientation of the essentially amorphous material in the article and for axial prolongation of this material to form the object. The thickness of the material at the bottom of the groove after the groove is formed corresponds closely to the thickness which the axially oriented parts of the object will acquire. One prerequisite for providing this material-wall thickness when the article is converted to an object is thus that the initial positions of the drawing rings are such that when they are moved in the article's axial direction, they will provide the necessary material reduction and thus the correct object material thickness. In a pre-ferred version of this invention, this is achieved by having the inside of the bottom of the groove largely flush with the inside of the adjacent amorphous material, thus making certain that it will be possible for the drawing rings to assume the aforesaid initial positions.
-7~ 4 In an alternative version of this invention, the final forming of the groove is accomplished by having the draw-ing rings, when being placed in the initial positions, provide the movement of material in the bottom of the groove towards the object's axis that is required to achieve the position of the material wall set forth in the previous paragraph.
Application of this invention provides an article with a peripheral groove arranged in such a way that the thick-ness of the material in the bottom of the groove is re-duced relative to the thickness of the adjacent walls.
The wall thickness in the bottom of the groove shall thus correspond to the thickness a sheet or panel, made of the same amorphous material as that adjacent to the groove and having a thickness corresponding to the thickness of the material of the article adjacent to the groove, obtains when having a temperature corresponding to the temperature which the material at the bottom of the groove has immediately before the final phase of formulation of the groove and the sheet or-the panel drawn monoaxially until it yields. The material in the wall at the bottom of the groove has a crystallization in the range 10-30 %, preferably in the range 10-17 %.
An article having a region of material at the bottom of the groove with an orientation and, sometimes, a supple-mentary thermal crystallization that causes overall ,, crystallization to the extent mentioned in the previous paragraph is well suited for conversion to an object.
As reduction of the wall thickness of the parts of the article adjacent to the groove continues due to the fact that its material is caused to yield, one obtains a region of reduced material thickness consisting of the initial region formed by the bottom of the groove and the adjacent areas having reduced material thickness.
The material region thus provided forms, sometimes after supplementary thermal crystallization, an essentially uniform material region both mechanically and thermally.
In connection with the production of a bottle, for example, one can permit this material region to form the neck and mouth of the bottle, thus making it possible to provide a bottle having considerably better characteristics with regard to strength and temperature resistance. Moreover, the material thickness in the neck and mouth of the bottle is reduced relative to what is possible with the methods and devices heretofore known.
One special advantage of the groove is that it makes it possible to provide regions of reduced-thickness material arranged symmetrically around the groove. This is important because it permits the article to be used in applications calling for two containers such as bottles arranged opposite each other and produced in one or more operations.
An apparatus in accordance with the present 76:~
- 5a -invention comprises a device for producing a tubular article with a peripheral groove from a tubular blank having a wall of essentially amorphous material, including fixing means for fixedly engaging the wall of the blank on both sides of a region in which the grocve is to be formed and for axial movement in opposite directions while maintaining secure engagement with the wall of the blank to produce axial stretching forces in the blank. Mechanical shaping means are provided for contacting and compressing the wall of the blank in the region in which the groove is to be formed while undergoing movement peripherally around the blank and also perpendicular to the axis of the blank such that the groove is formed in the wall of the blank with gradually increasing depth, and the axial stretching forces applied by the fixing means to the material in the bottom of the groove causes the material to yield while its thickness is simultaneously reduced.
In one version of this invention, successive reduction of 76~ 6 the material thickness is accomplished by a number of rollers, although only one roller is used in certain applications. When the groove is formed, the roller or rollers are moved around the periphery of the blank while the distance to the blank axis is gradually reduced and while the material which contacts the roller or rollers is exposed to the aforesaid stretching forces.
In a preferred version of this invention, three rollers are used, and they are brought into contact with the wall of the blank successively and are then moved gradually towards the axis of the blank as the groove is formed.
The roller which first contacts the wall of the blank and commences to form the groove has a relatively narrow con-tact surface. It is followed by the second roller which further deepens and widens the groove while simulta-neously reducing the thickness of the material in the bottom of the groove to a value which permits the stretch-ing forces per unit of area to accomplish the aforesaid yield of the material. This provides relatively symmetrical streching of the material while it is simultaneously being thinned, and as a result the inner surface of the material wall at the bottom of the groove is moved slightly away from the axis of the blank. The third roller serves as a shaping roller which moves the ma-terial wall to a position at which its inner surface is largely flush with the inner surfaces of the adjacent parts of the material.
~ ?~;'7~1~ 7 In an alternative version of this invention, the rollers are replaced by an extended shaping device having an edge against which the blank rolls while the distance of the edge from the axis of the blank is reduced. Preferably, the device terminates in a part having an edge with a width, a length and a position which, because of the movement relative to the blank will affect the material in the bottom of the groove in roughly the same way as set forth for the third roller mentioned in the previous paragraph. The extended shaping device shall preferably be roughly circular and designed in such a way that the shaping edge is on the inside of the ring. This simplifies control, guidance and movement of the blank and also simplifies its movements relative to the shaping device.
During formation of the groove, a central mandrel is usually provided inside the blank. The mandrel has a central part which serves as a support for the wall of the blank in the region where the groove is to be formed. At the two ends of the blank, the mandrel is also provided with sections which also serve as supports for the wall of the blank in order to prevent the blank from being deformed by the fixing devices which grip the blank in connection with the application of the aforesaid stretching forces used to form the groove.
Fixing devices are also needed to provide reliable guid-ance of the blank relative to the shaping device or de-vices while the groove is being formed.
~ 8 This invention is intended especially for use in connec-tion with the production of articles made of thermoplastic of the polyester or polyamide type. One example of such a material is polyethylene terephthalate. Other examples are S polyhexamethylene-adipamide, polycaprolactam~ polyhexa-methylene-sebacamide, polyethylene-2.~- an~
1,5-naphthalate, polytetramethylene-1,2-dioxy-benzoate and copolymers of ethylene terephthlate, ethy-lene isophthalate and other similar polymer plastics.
The description of this invention is related, for the most part, to polyethylene terephthalate, hereinafter often abbreviated to PET. However, this invention is not limited to the use of this material or any other of the previously mentioned materials. It is applicable for many other thermoplastic materials as well.
The crystallization percentages mentioned previously in connection with PET and which will be mentioned again in connection with PET, are related to~the theory set forth in the publication entitled "Die Makromolekulare Chemie"
176, 2459-2465 (1975).
This invention is described in greater detail in connec-tion with the following illustrations:
Fig. 1 a-d illustrates the general cycle used to form an article from a tubular blank.
J.,~ 9 Fig. 2 a, b illustrates in detail the final formulaticn of the groove in the article.
Fig. 3 presents a perspective view of one version of the invention.
Fig. 4 presents a perspective view of an alternative version of the invention.
Fig. 5 presents a cross section and axial section showing details of the version of the inven-tion shown in Fig. 3, particularly the ar-rangement of the shaping rollers.
Fig. 6 presents an axial section showing details of a fixing device and drawing device used ln either of the versions of this invention shown in Fig. 3 and Fig. 4.
15 Fig. 1 a-d illustrates the principles of this invention as follows. A blank 10 consisting essentially of amorphous material is provided with a peripheral groove 12 through-out a shaping cycle, sometimes called a conversion cycle, in which a number of shaping rollers 31-33 are success-ively brought to bear against the blank and simultaneous-ly moved peripherally around the blank and also towards the blank axis. Reference number 17 indicates a blank in which the formation of the groove has commenced. Reference number 18 indicates a blank in which the material in the bottom of the groove has yielded. Reference number 19 indicates an article made from blank 10 in which groove 12 has obtained its final form. The letter b at lower right in Fig. ld indicates half of the prolongation of the blank which occurs during conversion to article 19.
A mandrel 20 is provided inside the blank, and it has a central part 22 and outer parts 21 a, 21 b. The mandrel also has an axis 23 along which the outer parts of the mandrel can be moved. Springs (not shown in the illustra-tions) tend to keep the outer parts of the mandrel 21 atthe positions shown in Fig. 1 a. Moreover, fixing devices 34 a, 34 b are arranged to hold the outer parts of the blank by clamping them between the fixing device and the outer parts of the mandrel 21 a, 21 b. The fixing devices are also arranged so that they can be moved in the axial direction of the blank while simultaneously holding the blank securely by means of the aforesaid clamping arrange-ment. This movement is indicated by arrow H which also in-dicates the directions bf the axial stretching forces which are applied to the material via the fixing devices.
In connection with the application of this invention, blank 10 is threaded over the mandrel until it strikes a stopping surface 35 on fixing device 34 a. This provides accurate axial positioning of the blank on the mandrel.
The fixing devices grip the ends of the blank, after which the fixing devices are acted on by a driving device to provide stretching forces in the axial direction.
Rollers 31-33 are then brought to bear successively on the wall of the blank, and they are moved around the blank's periphery while simultaneously being moved gradually to-wards the blank axis. Roller 31, which contacts the wall of the blank first and commences to form the groove has a relatively narrow contact surface. It is followed by roller 32, which is brought into contact with the material in such a way as to widen and deepen the shallow groove formed by the first roller. The second roller deepens the groove while simultaneously reducing the thickness of the material in the bottom of the groove to a value which permits the stretching forces applied to the ma-terial 15 in the bottom of the groove to cause the ma-terlal to yield. The material is thus thinned, while its inner surface simultaneously moves slightly away from the central part of the mandrel 22. The third roller 33 which has a shape adapted to the desired final shape of the groove that is intended to be formed then moves the material 15 in the bottom of the groove into contact with the central part of the mandrel 22, whereupon the inner sur-face of material 15 in the bottom of the groove assumes a position that is largely flush with the adjacent inner surfaces of the article that is formed 19. When the forming of the groove com~ences, the material is at a temperature which is considerably below its glass transition tempera-ture (TG).
Fig. 2 a, b presents an enlarged, detailed illustration of the final phase of the forming of the groove. In addi-tion to the reference numbers and letters used in Fig. 1 a-d, the original thickness of the material wall is indi-cated by the letter a, and the thickness of the material in the bottom of the groove is indicated by the letter d.
S Fig. 3 presents one version of a device used to apply this invention in which shaping rollers are used as shap-ing devices. A frame 40 is arranged with a central drive shaft 41 on which are attached a number of holders 43 a-d.
A stepping motor 42 serves as the driving device for the central drive shaft and moves the conversion stations to the positions marked I-IV in the illustration. The holders support the devices which form the conversion stations in which the blank is converted to an article. In this illus-tration, and also in Fig. 4, the devices used in the con-version stations are indicated by reference numbers to which the letters a, b, c and d have been appended to indicate that the device in question belongs to a parti-cular conversion station.
~ supporting shaft 44 is attached to each holder and supports a first fixing device 67 which, at positions I
and I~, is moved by driving device 72 out to the exposed end of supporting shaft 44. Another driving device 74 is connected via lever 78 to this first fixing device 67 in order to secure one end of the blank 10 that is to be converted into article 19. A second fixing device is contained in holder 43. Another driving device 75 is connected via a lever 79 to secure the other end of the . . ' .
3'~ 7~ ~ 13 blank. A first and second pressure sleeve 97, 98 are provided between the two fixing devices in such a way that they straddle a sleeve 56 which contains shaping rollers 31-33. The illustration also shows driving device 46 which, via levers 47, provides the aforesaid movement of the shaping rollers perpendicular to the axis of the blank. Driving device 76, via a link system and eccentrics 95, moves pressure sleeves 97, 98 in the axial direction of the blank. Each conversion station is also provided with its own driving device 45 which rotates mandrel 20 and thus the blank which is secured to the mandrel by means of fixing devices 67, 68.
Fig. 3 also shows a feed device for blanks 10. This device feeds the blanks into the first fixing device 67 when the conversion station is at position I. Feed wheels 65, in combination with blank carrier 64 and a feed/discharge device 66 are all a part of the feed device.
Fig. 4 shows an alternative version of a device used for the'application of this invention in which the shaping rollers are replaced by an extended shaping device 60 with an edge 61. This edge forms a roughly circular limiting surface'which'has a varying width and varying distance from the centre of rotation. A part of the limiting sur-face'must have a length corresponding to at least the circumferance of the blank. Moreover, this part of the limiting surface must have a shape which corresponds to the shape which the groove is to have when conversion into i>76i1~
an article is completed.
Shaping device 60 is arranged as a roughly circular hol-der 59. The driving device (not shown in the illustration) can rotate the shaping device around its axis.
Frame 63 is arranged on base 62. The frame has a centrally located hole 58. Feed wheels 65, blank carrier 64 and feed/discharge device 66 are arranged relative to the hole in accordance with the description of Fig. 3.
A number of supporting arms 69 (four in this illustration) are arranged relative to frame 33 and on sliding shafts 70 by means of a bearing 71 in such a way that the supporting arms can be moved from one position adjacent to frame 63 to another position close to shaping device 60 and back again to the first position. At the other end, each sup-porting arm is provided with a first fixing device 67 which corresponds to the first fixing device mentioned in the description of Fig. 3. Sliding shaft 70 is also carried on bearing 77 in frame 63 so that, by means of driving device 73, it can be turned between one position in which the first fixing device 67 is located at the centre of hole 58 and a second position that corresponds approximately to the position of edge 61 on shaping device 60.
Supporting devices 69 are attached to the frame 63. Devices 69 have each a first fixing device 67, which interacts with a second 1 ~;'7~1~ lS
fixing device 68 arranged ad~acent to two pressure sleeves 98, 97. The second fixing device and the press-ure sleeves, together with the first fixing device form a conversion station for blank 10 when the first fixing device 67 is moved to a position adjacent to shaping de-vice 60. Driving devices 74-76 with their link system are provided for fixing devices 67, 68 and for pressure sleeves 97, 98 in the same way as shown in Fig. 3. The reference numbers for these link systems are the same as the reference numbers used in Fig. 3. Reference number 78 indicates a lever for the first fixing device 67. Refer-ence number 79 indicates a le~er for the second fixing device 68.
In Fig. 5 a, b, Fig. 5 b shows section 5b-5b in Fig. 5 a, i.e. a section taken along blank lO's axis in a device like the one shown in Fig. 4. Fig. 5 a, b illustrates the structure of a shaping device that consists of shaping rollers. Circular housing 50 contains supporting device 48 on which lever 47 is attached. The supporting device can rotate in housing 50. A number of guide rollers 49 are carried on supporting device 48 and follow it when it ~noves. Shaping rollers 31-33 are carried in roller holder 51. The roller holder has a guide surface 52 against which each of guide rollers 49 roll. The roller holders can rotate around pivot point 53. A spring 54 returns the roller holders to their initial positions so that blank 10 can be fed in between the rollers. Roller holders 51 are mounted on a ring 55 which is attached to circular housing 50.
.' I
~ 7~1~ 16 Fig. 6 presents a section taken in the axial direction of blank 10 through the part of the conversion station which secures one of the ends of the blank. In this illustration, the blank has been threaded onto the mandrel.
Reference number 25 indicates an extension of the mandrel axis 23. This extension is carried in bearing 99. In a version of this invention in which shaping rollers are used, extension 99 is connected to driving device 45, while in an alternative version where shaping is carried out by means of an extended shaping device, the mandrel runs freely in bearing 99. Reference number 81 indicates a fixed sleeve in which bearing 99 and the other devices located adjacent to the fixing devices and stretching devices used for blank 10 are mounted.
The aforesaid lever 7~ is attached to transmission device 82. When thé lever moves, transmission device 82 is screwed into threaded member 83 and simultaneously pulls tapered device 94 in and over fixing jaws 85. As a result, the blank is securely clamped between the fixing jaws and the outer part of mandrel 21. The fixing jaws are arranged in a holder 38. Bearings 87, 84 permit holder 38 and the tapered device 94 to rotate when blank 10 rotates.
The aforesaid lever 88 is attached to actuator 89 which, when the lever moves, is screwed out of holder 90 and moves a pressure sleeve 91 against part 83 which, in turn, moves into the fixed sleeve. This exerts a pulling force 3.~.~t~ 17 on blank 10 via ixing jaws 85. Part 83 is prevented from rotating by stop pin 93.
When a blank 10 is converted into an article 19 by means of the version of the invention shown in Fig. 3, blank 10 is fed by means of feed wheels 65, blank carrier 64 and feed/discharge device 66, whereupon the feeding operation is terminated by a shoulder in the first fixing device 67 a. Driving device 74 actuates the fixing device so that the blank is secured firmly by the first fixing device.
Simultaneously, the first fixing device is actuated by driving device 72 a in such a way that it moves into con-tact with the first pressure sleeve 97. Also simultaneous-ly, the blank is inserted between shaping rollers 31-33 (see Fig. 5 a, b). Also simultaneously, the other end of the blank is moved against stopping surface 35 in the second fixing device 68 a (hidden in the illustration).
Driving device 75 then actuates the second fixing device so that it secures the other end of the blank.
When driving device 46 a, which provides movement of the shaping rollers towards the axis of the blanks is actuated, the shaping rollers are moved as described above in connection with Fig. 5 a, b in order to form groove 12.
Driving device 76 a, when it is actuated, exposes the ma-terial to stretching forces in the same way as described previously. Then, when the thickness of the material in the bottom of the groove reaches a predetermined value, it will yield. As a result, the blank is stretched. Con-J~ j; 18 version to an article is then concluded when shaping roller 33 moves the material in the bottom of the groove into contact with the mandrel thus determining the final shape of the groove. Relative movement between the shaping 5 rollers on the one hand and the blank on the other is provided by driving device 45 a, after the two ends of the blank have been secured in the first and second fixing de-vices by that the driving device 45 a-- rotates the mandrel and thus rotates the blank itself.
While the cycle described above is being carried out, stepping motor 42 moves the conversion station step by step from position I to position IV, as shown in the il-lustration.
~t position IV, the shaping rollers are returned to their initial positions, and the second fixing device releases the' blank. Thereafter, driving device 72 a moves the first fixing device 67 a back to its initlal position. Driving device 74 a returns to its initial position and releases the end of the article, after which a new blank 10 can be moved in the axial direction into the first fixing device while'article l~ a is simultaneously discharged.
The above paragraphs have explained how a conversion sta-tion is ussd to convert a blank to an article. Each of the conversion statlons converts one blank in the same manner as set forth'above. Even thbugh the illustration shows four conversion stations, it is possible to arrange a de-3~ j 19 vice like the one shown in Fig. 3 with more or fewer con-version stations.
Moreover, the description refers to the use of three shaping rollers which successively shape the groove. De-pending upon the way in which, for example, the width and shape of the groove are to be formed, it is possible within the scope of this invention to use either more or fewer shaping rollers.
When converting a blank 10 into an article 19 using the version of this invention shown in Fig. 4, blank 10 is fed in the same way as described in connection with Fig.
3~ after which the first fixing device 67 a is moved by driving device 73 a to the position shown by the broken lines in Fig. 3. Driving device 72 a then moves the fixing device to a position adjacent to the extended shaping de-vice'60 where, together with the second fixing device 68 a and the intermediate devices such as actuator 89 and hol-der 90, it forms the composite device used to secure the bIank while it is being converted to an article.
Now, the'other end of the blank is secured in the same ,w,a~ as described in connection with Fig. 6, whereupon the material in the region where the groove is to be formed is exposed to axial stretching forces.
The driving devices rotate the extended shaping device 60 which, when the blank was moved to the aforesaid position ~ 7~ 1~ 2 assumed a position at which edge 61 did not obstruct axial movement of the blank. As rotation proceeds, edge 61 is gradually moved closer to the centre of the blank, where-with the blank rolls against the edge while the groove is being formed. In the same way as described previously, the material at the bottom of the groove y~elds after a certain time interval. The final shape of the groove is then determined by having the material in the bottom of the groove contact an edge shaped and located in such a way that the material wall is pressed against the central part of the mandrel throughout at least one full revolu-tion of the blank. This procedure provides the final shape of the groove.
~s the rotation of the extended shaping device continues, edge 61 moves away from the material in the newly-formed article, and the second fixing device releases the ar-ticle, after which the first fixing device i5 moved to its initial position. The article is then released and a new blank is moved axially into the first fixing device while the article that was formed is simultaneously dis-char~ed.
In this version of the invention, it is also possible to provide more or fewer conversion stations than shown in thé illustration.
The material in the bottom of the groove becomes crystal-lized to a maximum,of approximately 17%, which through ~ 21 supplementary thermal crystallization can provide a maxi-mum of approximately 30% without causing problems when the article is subsequently shaped into new products.
This invention is intended especially for application in connection with the production of articles made of thermo-plastic of the polyester or polyamide types. Examples of such materials were presented in the introductory part of this description.
In addition to the above specification, the invention is also described in the following Patent Claims.
MG/Fgi
Claims (13)
1. A device for producing a tubular article with a peripheral groove from a tubular blank having a wall of essentially amorphous material, comprising fixing means for fixedly engaging the wall of the blank on both sides of a region in which the groove is to be formed and for axial movement in opposite directions while maintaining secure engagement with the wall of the blank to produce axial stretching forces in the blank, and mechanical shaping means for contacting and compressing the wall of the blank in the region in which the groove is to be formed while undergoing movement peripherally around the blank and also perpendicular to the axis of the blank such that said groove is formed in the wall of the blank with gradually increasing depth and the axial stretching forces applied by said fixing means to the material in the bottom of the groove causes the material to yield while its thickness is simul-taneously reduced.
2. A device as claimed in claim 1, comprising an internal mandrel insertable into said blank to form a supporting surface for said wall upon application of said shaping means and fixing means to form said groove.
3. A device as claimed in claim 2, wherein said mandrel includes a central part and two outer parts each movable relative to the central part of the mandrel.
4. A device as claimed in claim 3, wherein said outer parts of the mandrel are shaped relative to the inside of the tubular blank to permit the mandrel to be placed inside the blank such that the central and outer parts of the mandrel provide supporting surfaces for the wall of the blank when the shaping means and the fixing means convert the blank to the article.
5. A device as claimed in claim 1, wherein said mechanical shaping means comprises at least one roller having an axis parallel to the axis of the blank.
6. A device as claimed in claim 1, wherein said mechanical shaping means comprises an elongated shaping device having a shaping edge against which the blank rolls while the distance to the axis of the blank axis is gradually reduced.
7. A method for producing an article with a peri-pheral groove comprising providing a tubular blank of essentially amorphous polyethylene terephthalate, applying pressure against the wall of the blank by a mechanical shaping device which is relatively narrow in the axial direction of the blank and contacts the blank peripherally to compress the wall of the blank, applying axial stretching forces by external devices which affect the material in the region in which said pressure is applied, whereby the thickness (d) of the material in said region is reduced to a thickness which corres-ponds to the thickness obtained when a panel made of said amorphous material having a thickness (a) of said blank is monoaxially drawn until yield occurs at an initial temperature immediately before drawing that is the same as the temperature of the material in the bottom of the groove immediately before yield commences as the groove is formed.
8. A method as claimed in claim 7, wherein said groove is formed peripherally around the blank in the region where the pressure is applied such that the thickness of the material in the bottom of the groove is gradually reduced and the concurrent axial stretching forces cause the material to yield before the bottom of the groove has reached its final thickness (d) while the blank is simultaneously elongated.
9. A method as claimed in claim 8, wherein the pressure is applied against the wall of the blank by means of one or more rollers which are moved relative to the blank in a peripheral direction.
10. A method as claimed in claim 8, wherein the pressure is applied against the wall of the blank by means of an extended shaping device against which the blank rolls throughout most of the groove-forming operation.
11. A method as claimed in claim 7, wherein the material of the blank in the region where the groove is formed has an initial temperature that is less than the region of the glass transition temperature (TG) of the material.
12. A method as claimed in claim 7, comprising moving the material in the bottom of the groove, after the material has yielded, by a mechanical final shaping device perpendicular to the axis of the blank so that the material in the bottom of the groove will have a surface approximately flush with one of the surfaces of the tubular article.
13. A method as claimed in claim 7, wherein said mechanical shaping device and said blank undergo relative continuous annular movement during the formation of said groove.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA000447780A CA1178761A (en) | 1980-05-29 | 1984-02-17 | Tubular article having an annular groove therein |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE8004003-3 | 1980-05-29 | ||
SE8004003A SE429317B (en) | 1980-05-29 | 1980-05-29 | SETTING ASTADCOMMENDING ANY POLYETHYLTENE PREPARATE OR ITS LIKE THERMOPLASTIC MATERIAL AS A DEVICE FOR THIS |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000447780A Division CA1178761A (en) | 1980-05-29 | 1984-02-17 | Tubular article having an annular groove therein |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1167616A true CA1167616A (en) | 1984-05-22 |
Family
ID=20341077
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000378540A Expired CA1167616A (en) | 1980-05-29 | 1981-05-28 | Method and apparatus for producing a tubular article having an annular groove therein |
CA000378503A Expired CA1204908A (en) | 1980-05-29 | 1981-05-28 | Method and device for producing a tubular object |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000378503A Expired CA1204908A (en) | 1980-05-29 | 1981-05-28 | Method and device for producing a tubular object |
Country Status (24)
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US (8) | US4405546A (en) |
JP (5) | JPS5720332A (en) |
AR (1) | AR227044A1 (en) |
AT (2) | AT386799B (en) |
AU (1) | AU551869B2 (en) |
BE (2) | BE888999A (en) |
BR (1) | BR8103353A (en) |
CA (2) | CA1167616A (en) |
CH (2) | CH656091A5 (en) |
DE (2) | DE3121524A1 (en) |
DK (2) | DK158143C (en) |
ES (1) | ES503115A0 (en) |
FI (1) | FI74653C (en) |
FR (2) | FR2483315A1 (en) |
GB (3) | GB2092943B (en) |
HK (2) | HK45588A (en) |
IE (1) | IE53136B1 (en) |
IN (1) | IN155280B (en) |
IT (1) | IT1144570B (en) |
MX (1) | MX159145A (en) |
NL (2) | NL8102556A (en) |
NO (1) | NO161046C (en) |
SE (7) | SE429317B (en) |
ZA (2) | ZA813417B (en) |
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US4028037A (en) * | 1975-03-17 | 1977-06-07 | The Dow Chemical Company | Tube treating and apparatus therefor |
US4198370A (en) * | 1975-12-23 | 1980-04-15 | Sato Gasei Co., Ltd. | Method of molding and stretching stoppers |
JPS5280356A (en) * | 1975-12-27 | 1977-07-06 | Shinko Kagaku Kk | Method of molding bottle by elongating blow |
JPS52101264A (en) * | 1976-02-20 | 1977-08-25 | Yoshino Kogyosho Co Ltd | Method of deleting shrinkage of thick injection blow molded article at port end surface and thick injection for executing same |
US4083918A (en) * | 1976-05-28 | 1978-04-11 | Grandview Industries, Limited | Method for belling plastic pipe |
JPS5747154Y2 (en) * | 1976-08-13 | 1982-10-16 | ||
JPS5334868A (en) * | 1976-09-13 | 1978-03-31 | Sumitomo Electric Industries | Fine porous tube |
JPS5383884A (en) * | 1976-12-28 | 1978-07-24 | Yoshino Kogyosho Co Ltd | Gradation colored bottle and method of forming same |
JPS53108162A (en) * | 1977-03-03 | 1978-09-20 | Nippon Synthetic Chem Ind Co Ltd:The | Process for orienting multi-layered parison by blowing |
FR2416785A1 (en) * | 1978-02-13 | 1979-09-07 | Rhone Poulenc Ind | PROCESS FOR WATERPROOFING WITH POLYESTER HOLLOW BODY GAS |
US4260567A (en) * | 1979-02-26 | 1981-04-07 | Standard Oil Company (Indiana) | Shrinkage reduction of blow molded oriented pet bottle |
US4253392A (en) * | 1979-04-09 | 1981-03-03 | International Business Machines Corporation | Hollow fuser roll with variable taper |
US4212204A (en) * | 1979-04-26 | 1980-07-15 | St Amand Elmer F | Pipette and method of making same |
SE424287B (en) * | 1979-06-11 | 1982-07-12 | Plm Ab | PREFORMED PREFORM AND PROCEDURE AND DEVICE FOR PREPARING THIS AGREEMENT |
SE423981B (en) * | 1979-06-11 | 1982-06-21 | Plm Ab | PROCEDURE AND DEVICE FOR THE ESTABLISHMENT OF ORIENTED MATERIAL PARTS IN THE PREPARATION OF TERMOPLASTIC MATERIAL |
SE429317B (en) * | 1980-05-29 | 1983-08-29 | Plm Ab | SETTING ASTADCOMMENDING ANY POLYETHYLTENE PREPARATE OR ITS LIKE THERMOPLASTIC MATERIAL AS A DEVICE FOR THIS |
US4391861A (en) * | 1980-05-29 | 1983-07-05 | Plm Ab | Preform of a thermoplastic |
SE428774B (en) * | 1981-11-26 | 1983-07-25 | Plm Ab | SET TO ASTADCOMMA AND CONTAINER |
-
1980
- 1980-05-29 SE SE8004003A patent/SE429317B/en not_active IP Right Cessation
- 1980-12-10 SE SE8008651A patent/SE436405B/en not_active IP Right Cessation
- 1980-12-10 SE SE8008652A patent/SE446385B/en not_active IP Right Cessation
- 1980-12-10 SE SE8008653A patent/SE446386B/en not_active IP Right Cessation
- 1980-12-10 SE SE8008650A patent/SE451309B/en not_active IP Right Cessation
-
1981
- 1981-05-18 US US06/264,665 patent/US4405546A/en not_active Expired - Lifetime
- 1981-05-21 ZA ZA00813417A patent/ZA813417B/en unknown
- 1981-05-25 NL NL8102556A patent/NL8102556A/en not_active Application Discontinuation
- 1981-05-25 NO NO811759A patent/NO161046C/en unknown
- 1981-05-26 US US06/266,849 patent/US4416927A/en not_active Expired - Lifetime
- 1981-05-26 SE SE8103301A patent/SE435597B/en not_active IP Right Cessation
- 1981-05-26 GB GB8115981A patent/GB2092943B/en not_active Expired
- 1981-05-26 GB GB8115986A patent/GB2076734B/en not_active Expired
- 1981-05-26 SE SE8103302A patent/SE435467B/en not_active IP Right Cessation
- 1981-05-27 NL NL8102600A patent/NL8102600A/en not_active Application Discontinuation
- 1981-05-27 CH CH3487/81A patent/CH656091A5/en not_active IP Right Cessation
- 1981-05-27 DK DK232181A patent/DK158143C/en not_active IP Right Cessation
- 1981-05-27 CH CH3491/81A patent/CH668742A5/en not_active IP Right Cessation
- 1981-05-27 FI FI811617A patent/FI74653C/en not_active IP Right Cessation
- 1981-05-27 FR FR8110525A patent/FR2483315A1/en active Granted
- 1981-05-27 FR FR8110521A patent/FR2483312A1/en active Granted
- 1981-05-27 ES ES503115A patent/ES503115A0/en active Granted
- 1981-05-27 BE BE0/204926A patent/BE888999A/en not_active IP Right Cessation
- 1981-05-27 BE BE0/204922A patent/BE888995A/en not_active IP Right Cessation
- 1981-05-27 ZA ZA00813572A patent/ZA813572B/en unknown
- 1981-05-28 MX MX18751681A patent/MX159145A/en unknown
- 1981-05-28 JP JP8178581A patent/JPS5720332A/en active Granted
- 1981-05-28 JP JP8178281A patent/JPS5724219A/en active Granted
- 1981-05-28 AR AR28549481A patent/AR227044A1/en active
- 1981-05-28 JP JP8178481A patent/JPS5720331A/en active Granted
- 1981-05-28 JP JP8178681A patent/JPS5718222A/en active Granted
- 1981-05-28 CA CA000378540A patent/CA1167616A/en not_active Expired
- 1981-05-28 BR BR8103353A patent/BR8103353A/en not_active IP Right Cessation
- 1981-05-28 IT IT6770981A patent/IT1144570B/en active
- 1981-05-28 IE IE1193/81A patent/IE53136B1/en unknown
- 1981-05-28 JP JP8178381A patent/JPS5734925A/en active Granted
- 1981-05-28 CA CA000378503A patent/CA1204908A/en not_active Expired
- 1981-05-29 AT AT241481A patent/AT386799B/en not_active IP Right Cessation
- 1981-05-29 DE DE19813121524 patent/DE3121524A1/en active Granted
- 1981-05-29 AU AU71181/81A patent/AU551869B2/en not_active Ceased
- 1981-05-29 DE DE19813121525 patent/DE3121525A1/en active Granted
- 1981-05-29 AT AT241081A patent/AT384775B/en active
- 1981-11-28 IN IN1348/CAL/81A patent/IN155280B/en unknown
-
1982
- 1982-09-07 US US06/415,014 patent/US4468187A/en not_active Expired - Lifetime
- 1982-09-07 US US06/415,013 patent/US4462950A/en not_active Expired - Lifetime
-
1983
- 1983-04-29 US US06/490,027 patent/US4569866A/en not_active Expired - Lifetime
- 1983-04-29 US US06/489,750 patent/US4580968A/en not_active Expired - Lifetime
- 1983-10-10 GB GB8327044A patent/GB2137553B/en not_active Expired
- 1983-12-09 US US06/559,666 patent/US4631163A/en not_active Expired - Lifetime
-
1986
- 1986-10-21 US US06/921,336 patent/US4929168A/en not_active Expired - Lifetime
-
1988
- 1988-06-16 HK HK45588A patent/HK45588A/en not_active IP Right Cessation
- 1988-06-16 HK HK45688A patent/HK45688A/en not_active IP Right Cessation
-
1990
- 1990-01-26 DK DK21690A patent/DK165824C/en not_active IP Right Cessation
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