CA1155828A - Olefin polymerization catalyst - Google Patents
Olefin polymerization catalystInfo
- Publication number
- CA1155828A CA1155828A CA000368287A CA368287A CA1155828A CA 1155828 A CA1155828 A CA 1155828A CA 000368287 A CA000368287 A CA 000368287A CA 368287 A CA368287 A CA 368287A CA 1155828 A CA1155828 A CA 1155828A
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- compound
- treated
- catalyst component
- metal
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Abstract
ABSTRACT
A component for an olefin polymerisation catalyst which component is the product of treating a particulate support material with (a) an organomagnesium compound, (b) a transition metal compound of Groups IVA, VA or VIA, e.g. bis-butoxy titanium dichloride, (c) a pacifying agent, e.g. HCl and (d) optionally an aluminium compound, e.g. ethyl aluminium dichloride, an organometallic compound, e.g. zirconium tetrabenzyl, a halogenating agent e.g. carbon tetrachloride, or a Lewis Base compound, e.g. ethyl benzoate.
A component for an olefin polymerisation catalyst which component is the product of treating a particulate support material with (a) an organomagnesium compound, (b) a transition metal compound of Groups IVA, VA or VIA, e.g. bis-butoxy titanium dichloride, (c) a pacifying agent, e.g. HCl and (d) optionally an aluminium compound, e.g. ethyl aluminium dichloride, an organometallic compound, e.g. zirconium tetrabenzyl, a halogenating agent e.g. carbon tetrachloride, or a Lewis Base compound, e.g. ethyl benzoate.
Description
1 ~55828 Catalyst Component The present invention relates to a component of an olefin polymerisatior. catalyst, a process for the production thereof, polymerisation catalysts including the said component and an olefin polymerisation process using such catalysts.
~ e have found that so-called Ziegler-Natta catalyst components obtained by treating a particulate support material with an organomagnesium compound and a compound of a transition metal of Groups IVA to VIA of the Periodic Table may be treated with a pacifying agent as hereinafter defined to reduce or remove the polymer-isation activity of the catalyst component. Furthermore, we have found that Ziegler-Natta catalyst components obtained by treating a particulate support material with an aluminium compound, or certain halogen-containing com-pounds, an organomagnesium compound, a compound of a transition metal of Groups IVA to VIA and a pacifying agent often give rise, when activated with a suitable activator, to catalysts having an activity higher than that of catalysts prepared from corresponding unpacified catalyst components.
Accordingly, one aspect of the present invention provides a catalyst component which is the product of treating at least one particulate support materi.al, preferably having a reactive surface (as hereinafter '.`~
1 ~ S582~
defined) with:
(a) at least one organomagnesium compound, (b) at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table, (c) at least one pacifying agent, and (d) optionally one or more compounds, hereinafter for convenience referred to as "optional compounds"
selected from the group consisting of:
i) an aluminium compound of the general formula:
RnAlY3_n wherein R, each of which may be the same or different, represents a hydrocarbyl group, or substituted hydrocarbyl group, such as alkyl, aryl, cycloalkyl, aralkyl, alkenyl or alkadienyl, n is 0, 1, 2, 3 or a fraction less than 3, and Y is a singly charged ligand such as hydride, fluoride, chloride, bromide, iodide or oxyhydro-carbyl, ii) an organometalli~ compound of the general formula:
RlMX
wherein M is a metal of Grou~s IA, IIA, IIB, IIIB, IVA, VA or VIA of the Periodic Table, Rl is a hydrocarbyl or a substituted hydrocarbyl group, X is a singly charged anionic ligand or a mono-dentate neutral ligand, m is an integer up to the highest valency of the metal M and p is 0 or an integer up to 2 less than the valency of the metal M,except that when M is a metal ~rom Group VIA p is always ~, and m has a value ~rom 2 to ~he highest valen~y o~ the met~l and when M is a metal $rom Groups IVA or VA m has a value from 2 to the hlghest valqncy o~ the mekal and p has a value ~rom ~ to a value o~ ss than the valency of the metal M, 1 ~5582~
iii) a halogen containing compound and iv) a Lewis Base compound, with the proviso (i) that the at least one particulate support material is treated with the at least one organomagnesium compound, the at least one transitiQn metal compound of Groups IVA, VA or VIA, and the one or more optional com-pounds where one or more is used, prior to being treated with the at least one pacifying agent, except that where (a) the pacifying agent is a hydrogen halide, (b) the at least one particulate support material is treated with an aluminium compound of general formula RnAlY3 n and (c) the at least one particulate support material is treated with the aluminium compound of general formula RnAlY3_n and the at least one organomagnesium compound separately, the pacifying agent may be added to the at least one par-ticulate support material after it has been treated with the at least one organomagnesium compound and the aluminium compound of general formula RnAlY3 n and before it is treated with the at least one transition metal com-pound of Groups IVA, VA or VIA and (ii) that where the atleast one particulate support material is treated with two compounds selected from the aforesaid group of optional compounds they are not exclusively an aluminium compound RnAlY3_n and an organometallic compound RmMXp.
In a preferred aspect the present invention pro-vides a catalyst component which is the product of treating at least one particulate support material, pre-ferably having a reactive surface (as hereinafter defined) with:
30 (a) at least one aluminium compound of the general formula RnAlY3_n where R, Y and n have the meanings hereinbefore ascribed to them, (b) at least one organomagnesium compound, (c) at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table, and (d) at least one pacifying agent, 11S582~
with the proviso that the at least one particulate support material is treated with the at least one aluminium compound RnAlY3 n' the at least one organo-magnesium compound and the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table prior to being treated with the at least one pacifying agent except that where the at least one pacifying agent is a hydrogen halide and the at least one particulate support material is treated with the at least one aluminium compound of general formula RnAlY3_n and the at least one organomagnesium ~ompound separately the at least one pacifying agent may be added to the at least one particulate support material after it has been treated with the at least one aluminium compound RnAlY3_n and the at least one organomagnesium compound and before it is treated with the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table.
In the aforementioned preferred aspect of the present invention the at least one particulate support material is preferably treated with the at least one aluminium compound of general formula RnAlY3_n prior to treatment with the at least one organomagnesium compound and, where the pacifying agent is a hydrogen halide, it is preferably treated with the at least one transition metal compound of Groups IVA, VA or VIA prior to treatment with the at least one pacifying agent.
Where an optional compound which is a Lewis Ba~e compound is used, it is preferred that the support is treated with the at least one organomagnesium compound prior to being treated with the Lewis Base Compound.
All references to the Periodic Table are to the 1 15582~
version of the Periodic Table of the Elements printed inside the back cover of "Advanced Inorganic Chemistry"
by F A Cotton and G Wilkinson 3rd Edition, Interscience Publishers, 1976.
By a "reactive surface" we mean a plurality of sites on, and preferably attached ~o, the.surface of t~e at least one substantially inert particulate support material, which sites are capable of abstracting e.g. a magnesium hydro-carbyl from a solution thereof. Preferably the said sites are OH groups chemically bonded to the surface of the particulate support material and the particulate support material is an inorganic material. Such a material will be "substantially inert" in that, whereas the said -OH groups are capable of reacting with, say, the organomagnesium compound and the organometallic com-pound Rl~Xp where one is used, the bulk of the matrix mat-erial-is chemically inert. Particularly goQd examples of such matrix materials are silica and alumina or mixtures there-of. Th~se comprise a matrix of silicon or aluminium and oxygen atoms, to the surface of which -OH groups are attached, the hydrogen atoms of said groups having an acidic function. However, apart from the presence of these -OH groups, silica and alumina are generally regarded as chemically inert. Within the terms silica and alumina we include silica and alumina based materials containing small amounts of other suitable inorganic oxides, such as magnesium oxide and zinc oxide. The pre-ferred particulate support materials are silica and/or alumina.
The at least one organomagnesium compound used for the preparation of the catalyst components according to the present invention are compounds in which at least one hydrocarbyl group is directly bonded to magnesium through a carbon atom. Preferably two hydrocarbyl groups bonded in this way are present for each magnesium atom, which hydrocarbyl groups may be the same or different, although 1 1558~
we do not exclude the possibility that one of the groups bonded to the magnesium may ke halogen or oxyhydrocarbyl.
The hydrocarbyl group may be an alkyl group, aryl group, cycloalkyl group, aralkyl group, alkadienyl group or an alkenyl group. The number of carbon atoms in the hydro-carbyl group is generally between 1 and 30, but this number is not critical. Examples of magnesium compounds partic-ularly suitable in the preoaration of catalyst components according to the present invention are diethyl magnesium, dipropyl magnesium, di-isopro?vl magnesium, dibutyl or diisobutyl ma~nesium, butyl octyl magnesium, diamyl magnesium, dihexyl magnesium, diallyl magnesium, didecyl magnesium and didodecyl magnesium, dicycloalkyl magnesium with identical ox different cyclo-alkyl groups containing 3 to 12 carbon atoms, preferably 5 or 6 carbon atoms.
The magnesium may carry an alkyl and a cyclo-alkyl group. Diphenyl-magnesium is the preferred aromatic compound although, e.g. ditolyl and dixylyl magnesium, and - magnesium aryls derived from compounds with two or more con~ensed or non-condensed aromatic nuclei can also be used. Catalysts prepared with diaryl magnesium compounds may have a relatively lower activity.
Preferably a dialkyl magnesium is used wherein the alkyl groups are C1-Cl~ groups, particularly prefer-ably dibutyl magnesium,which may be present as a mixtureof dibutyl magnesiums, for example a mixture of di-n-butyl magnesium and di-iso-butyl magnesium.
Preferably the amount of the at least one organo-magnesium compound used in the preparation of catalyst components of the present invention is sufficient to react with at least substantially all the reactive sites on the surface of the at least one particulate support material, where such sites are present thereon.
The at least one transition metal co~pound of Gro~s IVA, VA or T~7I~ of the Periodic Table employed in the preparation of the catalyst component of the present 1 1 5 582 ~ ~
invention may be any of the transition metal compounds, or mixtures thereof, known to be useful in forming Ziegler-Natta catalysts.
The transition metal is preferably titanium, vanadium, molybdenum, zirconium or chromium, especially titanium. Suitable compounds incIude halides, halo-oxides, alkoxides, haloalkoxides, and acetyl acetonates, especially chlorides and alkoxides. The preferred compounds are titanium tetrachloride and bis-alkoxy dichloride.
The quantity of the at least one transition metal compound used in the preparation of the catalyst component of the present invention is generally not more than stoichiometric and preferably is less than stoichiometric.
In the attached formula drawings, A, B and C
represent halogenating agents and D represents Lewis Base compounds which are suitable for use in the preparation of a catalyst component according to the present invention.
Suitable pacifying agents which may be employed in the preparation of catalyst components of the present invention include agents which, it is believed, are capable of breaking metal-carbon or metal-hydrogen bonds in the catalyst component but which do not have a deleterious effect on the catalyst component. Such agents include inter alia oxygen, carbon monoxide, carbon dioxide, halohydrocarbons of formula (C) and protic agents. Typically, protic agents are hydrogen halides, carboxylic acids, alcohols, water, amines and acetylactone. Preferably the pacifying agent is an aliphatic alcohol having from 1 to about 6 carbon atoms; an anhydrous hydrogen halide e.g. hydrogen chlorlde or hydrogen bromide; a halohydrocarbon of formula (C), e.g. an alkyl halide such as t-butyl chloride, or a carbon tetrahalide, e.g. carbon tetra-chloride.
1 ~5582~
` 7a The quantity of the at least one pacifying agent used ls sufficient to break substantially all the metalhydrocarbyl or metal-hydride bonds in the catalyst component. Conveniently, the pacifying , 5 agent is added to a suspension~of the particulate support material which has been treated with at least the at least one organo~
. ~ .
magnesium compound and the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table. Where an excess of a gaseous pacifying agent is used the excess may be removed by sparging with nitro~en.
Where at least one aluminium compound RnAlY3 n is used in the preparation of catalyst components of the present invention preferably R, where present, is alkyl, having l to 4 carbon atoms, more preferably ethyl or isobutyl, and preferahly Y, where present, is a halide, particularly preferably chloride or bromide, more particularly preferably chloride.
Suitable aluminium compounds R AlY3 n include aluminium chloride, aluminium bromide, monoethyl aluminium, dichloride, ethyl aluminium sesqui-c}~.loride and diethyl aluminium chloride.
The molar ratio of the at least one aluminium compound, where it is used, to the at least one organomagnesium compound in the catalyst component of the present invention is preferably between 0.5 and lO0, particularly preferably between l.0 and 80 and more particularly preferably between l.0 and lOØ The molar ratio of the at least one aluminium compound to the at least one transition metal compound is preferably between l and 2000, particularly preferably between 2 and 1500 and more particularly preferably between 2 and lO0.
Where an organometallic compound RmMXp is used and M is a metal from Groups IA, IIA, IIB or IIIB of the Periodic Table it is preferred that p is O and m is the highest valency of the metal.
Preferred organometallic compounds RmMXp are those in which the metal M is a transition metal of Groups IVA, VA or VIA
more preferably titanium, vanadium, molybdenum, zirconium or chromium, and especially zirconium. The monovalent ligand X, where it is present, is preferably halogen.
-.
~1 Hydrocarbyl groups of different types may be associated with a single metal atom M.
Suitable hydrocarbyl groups Rl include alkyl and alkenyl groups (including ~-alkenyl groups such as ~-allyl) and substituted derivatives thereof. Examples oftransition metal complexes include tetrakis (~-allyl) zirconium or hafnium, tris (~-allyl) chromium, tetrakis (~-methallyl) zirconium or hafnium, tris (~-methallyl) chromium and zirconium tris (~-allyl) bromide.
A preferred class of organometallic compounds RmMXp are organic transition metal complexes in which some or all of the groups, or ligands, Rl are substituted alkyl groups of general formula -CH2Z ~-bonded to the transition metal through the carbon atom. In this general formula Z may represent a group capable of interaction with the vacant d-orbitals of the metal M. Preferably all the groups Rl have this formula, but it is possible for some of them to comprise other hydrocarbyl or substituted hydrocarbyl groups.
Suitable substituent groups Z include aromatic and polyaromatic groups such as phenyl and naphthyl, giving rise in the formula -CH2Z to the alkaryl groups benzyl and (1-methylene-1-naphthyl) and ring substituted derivatives thereof, for example ~-methyl benzyl.
Z may also be a cycloalkenyl group, such as a cyclo-octenyl group.
Z may also comprise a group of general formula: A(R2)3 where A represents carbon, silicon, germanium, tin or lead, and each R2, which may be the same or different, represents a hydrocarbyl group or hydrogen; preferably at ieast oneR2 ls an alkyl group.
Examples of this preferred class of organometallic compounds ~ ~p include zirconium and titanium tetra(benzyl), tris(benzyl)zirconium chloride, zirconium tetrakis (p-methyl benzyl), zirconium and titanium tetrakis (l-methylene-l-naphthyl), zirconium tetrakis (trimethylsilylmethylene), 1 ~5582~
zirconium tetrakis (neopentyl) and zirconium tetrakis (neophyl).
Examples of preferred organometallic compounds RmMXp containing monovalent ligands X include tris (~-allyl) zirconium chloride, bromide or iodide and the equivalent ~-methallyl and benzyl compounds.
Where an organometallic compound RmMXp and an aluminium compound RnAIY3_n are used in the preparation of catalyst components of the present invention the molar ratio of aluminium compound to organometallic compound is preferably between 0.1 and 100 and particularly prefer-ably between 1 and 20.
Where an optional compound which is a halogen containing compound is used in the preparation of a catalyst component of the present invention it is pre-ferably a halogenating agent and particularly preferably a chlorinating agent. Suitable halogenating agents include hydrogen halides such as hydrogen chloride, silicon halides of the formula A in the attached formula drawings, carboxylic acid halides of the formula B in the attached formula drawings, halohydrocarbons of the formula C in the attached formula drawings, phosphorus pentachloride, thionyl chloride, sulphuryl chioride, phosgene, nitrosyl chloride, halides of mineral acids, chlorine, bromine, chlorinated polysiloxanes, hydrocarbyl aluminium halides, aluminium, chloride, boron halides, and ammonium hexafluorosilicate. In the attached formula drawings A, B, C, R3 is a hydrogen or a hydro-carbyl group, preferably an alkyl group containing 1 up to 6 carbon atoms or an aryl, alkaryl or aralkyl group containing 6 up to 15 carbon atoms; R4 is a hydrocarbyl group, preferably an alkyl group containing 1 up to 4 carbon atoms or an aryl, alkaryl or aralkyl group con-taining 6 up to 12 carbon atoms; ~5, each of which may be the same or different, is hydrogen, a hydrocarbyl grou or a substituted hydrocarbyl aroun, e.g. a halogenated hydrocarbyl group, ~1 is a halide, 1 ;5582~
preferably chloride; a is 0 or an integer from l up to 3.
The silicon halides of formula (A) include silicon tetrachloride, silicon tetrabromide and halosilanes such as trimethyl silicon monochloride, diethyl silicon di-chloride and monobutyl silicon trichloride.
The carboxylic acid halides of formula (B) include acetyl chloride, benzoyl chloride and p-methylbenzoyl chloride.
The halohydrocarbons of formula (C) include carbon tetrachloride, chloroform, ethyl chloride, ethylene di-chloride and l,l,l-trichloroethane.
Halides of mineral acids include boron trichloride and antimony pentachloride.
Hydrocarbyl aluminium halides include diethyl aluminium chloride and monoethyl aluminium dichloride.
The quantity of the halogenating agent is conven-iently sufficient to provide at least 0.1, and especially at least 1.0, halogen atom at every reactive site on the at least one particulate support material. The treatment can be effected at ambient temperature or at an elevated temperature of up to 100C. The preferred temperature is dependent on the particular halogenating agent used, for example, using silicon tetrachloride, the temperature is preferably at least 60C. The treatment is conveniently carried out by adding the halogenating agent to a stirred suspension of the at least one particulate support material or of the at least one particulate support material treated with the at least one organomagnesium compound. Using a gaseous halogenating agent such as hydrogen chloride, the gas can be passed into the reaction medium until no further absorption is observed to occur.
The treatment with the halogenating agent is conveniently effected for a time of at least 0.25 up to 10 hours, preferably from 1 up to 5 hours.
lla Where an optional compound which is at least one halogen containing compound is used in the preparation of a catalyst component of the present invention and where the at least one halogen-containing compound is a halohydrocarbon of formula (C) in the attached drawings the at least one particulate support material is prefer-ably treated with it, at elevated temperature, e.g. 300C
to 600C, prior to treatment with the at least one organo-magnesium compound, the at least one transition metal com-pound of Groups IVA, VA or VIA and the at least onepacifying agent. Preferably the halohydrocarbon has a plurality of halogen atoms, and a particularly preferred halohydrocarbon is carbon tetrachloride. Conveniently the halohydrocarbon in gaseous form is passed through a fluidised bed of the at least one particulate support material. Catalyst components prepared in the aforesaid procedure give rise to catalysts of increased activit~
compared with catalysts prepared from unpacified catalyst components. It is believed that in this aspect of the present invention the haloatoms of the at least one halo-hydrocarbon (C) replace hydroxyl groups on the surface of the at least one particulate support material.
IR a further preferred aspect the present invention provides a catalyst component which is the product of treating at least one particulate support material with:
(a) at least one halohydrocarbon of the general formula (C) in the attached drawings, (b) at least one organomagnesium compound, (c) at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table, and (d) at least on pacifying agent with the proviso that the at least one particulate support material is treated firstly with the at least one halo-hydrocarbon and fourthly with the at least one pacifying a~ent.
1 15582~
Where an optional compound which is a Lewis base compound is used it can be any organic Lewis base compound which has been proposed for use in a Ziegler polymerisation catalyst and which affects either the activity or stereo-specificity of such a system. Thus, the Lewis Base com-pound may be an ether, an ester, a ketone, an alcohol, a thioether, a thioester, a thioketone, a thiol, a sulphone, a sulphonamide, a fused ring compound containing a heterocyclic sulphur atom, an organo-silicon compound such as a silane or siloxane, an amide such as formamide, urea and the substituted derivatives thereof such as tetramethylurea, thiourea, an alkanolamine, an amine, a cyclic amine such as pyridine or quinoline, a diamine such as tetramethylethylenediamine or an organo-phosphorus compound such as an organo-phosphine, an organo-phosphine oxide, an organo-phosphite or an organo-phosphate. The use of organo Lewis Base compounds is disclosed, inter alia, in British Patent Speci~icat~ons 803 198, 809 717, 880 998, 896 509, 920 118, 921 954, 933 236, 940 125, 966 025, 969 074, 971 248, 1 013 363, 1 017 977, 1 049 723, 1 122 010, 1 150 845, 1 208 815, 1 234 657, 1 324 173, 1 359 328, 1 383 207, 1 423 658, 1 423 659 and 1 423 660.
Preferred Lewis Base compounds are esters which may be represented by the ~ormula D) given in the attached formula drawings.
In the formula D), R~ is a hydrocarbyl group which may be substituted by one or more halogen atoms and/or hydrocarbyloxy groups;
and R7 is a hydrocarbyl group which may be substituted by one or more halogen atoms.
The groups R6 and R7 may be the same or different.
The group R6 is conveniently an alkyl or aryl group, for example, a methyl, ethyl, phenyl or tolyl group. The 1 ~ 5582 g group R7 is preferably an alkyl group containing up to 6 carbon atoms, for example an ethyl or a butyl group.
It is particularly preferred that R6 is an aryl group and R7 is an alkyl group.
A Lewis Base compound may be added to the at least one particulate support material treated with the at least one organomagnesium compound and optionally with the halogenating agent. This is conveniently effected by adding the 1ewis Base compound to a suspension, in an inert liquid medium such as an inert liquid hydrocarbon or halohydrocarbon, of the at least one particulate support material treated with the at least one organo-magnesium compound and optionally with the halogenating agent. The quantity of Lewis Base used is conveniently in an amount of up to 1 mole of Lewis Base compound for each gramme atom of magnesium which is present on the at least one particulate support material. Preferred quantities of the Lewis Base are from 0.1 to 0.8 mole for each gramme atom of magnesium and especially at least 0.5 to 0.8 mole for each gramme atom of magnesium.
The addition of the Lewis Base compound to the at least one particulate support material may be effected at temperatures of from 0C to 100C and is very conveniently carried out at ambiént temperature, that is from about 15C up to about 30C. After adding the Lewis Base com-pound to the at least one particulate support material the materials are conveniently allowed to remain in con-tact for 0.1 up to 70 hours, especially 1 up to 20 hours.
After the Lewis Base compound and the at least one particulate support material treated with at least the at least one magnesium compound have remained in con-tact for the desired period of time, the product thus formed is conveniently separated from the reaction medium and washed with an inert liquid.
Magnesium containing Ziegler-Natta catalyst components which have a tendency to be so reactive that they 1 ~S582 3 cannot be mixed with an olefin containing stream prior to char~ing the said stream to a ~olymerisation zone are known.
However, the catalyst components of the present invention are often of sufficiently low polymerisation activity S or are substantially completely inactive such that they can be added to the polymerisation zone in the presence of an olefin containing stream.
A further aspect of the present invention provides an olefin polymerisation catalyst which comprises (a) the catalyst component as hereinbefore defined and (b) an activator which is at least one organoFetallic co~ound of a metal of Groups T-IV of the Periodic Table.
Preferably the activator is an organometallic derivative of a metal of Groups IA, IIA, IIB, IIIB or IVB of the Periodic Table, particularly preferably the metal is aluminium and more particularly preferably the activator is a trialkyl aluminium, dihaloalkyl aluminium or halodialkyl aluminium. It will be appreciated that sufficient of the said activator is employed to trans-form the metal atoms of the transition metal compoundknown to be useful in forming Ziegler-Natta catalysts to an active state.
The catalyst component of the present invention may be treated with the aforesaid activator by methods known in the art, for example, they may be reacted totally outside or inside the polymerisation vessel in which the catalyst is to be used or activation may be effected partially outside the polymerisation vessel and completed inside the said polymerisation vessel.
A further aspect of the present invention pro-vides a process for the polymerisation or copolymer-isation of an olefinically unsaturated monomer which process comprises contacting, under polymerisation con-ditions, at least one olefin monomer with a catalyst in accordance with the present invention.
1 ~ S582~
The term "olefinically unsaturated monomer" is intended to include mono-olefins such as ethylene, propy-lene and 4-methylpentene-1.
The catalyst of the present invention may also be S used to initiate the copolymerisation of two or more ole~
finically unsaturated monomers. For example, ethylene may be copolymerised with a small amount of propylene, butene, hexene or decene, butadiene or styrene.
Polvmerisation processes according to the present invention may be carried out by techniques generally used for polymerisation processes of the type using Ziegler catalysts.
The choice of conditions of pressure and temperature will vary with factors such as the nature of the monomer and catalyst and whether liquid, e.g. bulk or diluent, or gas phase polymerisation is used.
For example, when ethylene is polymerised, pressures from sub-atmospheric to several thousand atmospheres may be used. Low pressure (say from 0.1 to 30 atmospheres) and intermediate pressures (say from 30 to 300 atmospheres) polymerisation may be carried out using conventional equipment; but very high pressure polymerisation must be performed using suitable specialised reactors and pumping equipment. However, since, generally speaking, the higher the pressure the higher the activity, the use of such techniques may be justified. If very high pressures are used, it is pre-ferred that conditions are such that the ethylene feed and polyethylene produced are maintained in a single fluid phase, i.e. the pressure should exceed 500 Kg/cm2 preferably 1000 to 3000 Kg/cm2 and the temperature should be greater than 125C, say 140-300C. This type of process is usually operated in a continuous manner.
A wide range of temperatures may be used, but in general low and intermediate pressure ethylene polymer-1 ~5$~Z8 isations are carried out at temperatures in the range50-160C.
When the process of the present invention is used to polymerise propylene, it is preferred to operate under conditions commonly used for the polymerisation of propylene. However, polymerisation of propylene under other conditions, e.g. high pressure, is not excluded.
It is also within the scope of the present inven-tion to use the catalysts thereof to initiate the copoly-merisation of ethylene and propylene together and/or withother olefinically unsaturated monomers.
The polymerisation process of the present invention may be carried out in the liquid or gaseous phase (i.e. in the essential absence of a liquid medium) and preferably in the gaseous phase. Where polymerisation is effected in the liquid phase, and the monomer is not li~uid under the polymerisation conditions, the monomer may be dissolved in a suitable solvent. Examples of suitable solvents are aliphatic or aromatic hydrocarbons;
for instance pentane, hexane, heptane, octane, decane, benzene, toluene and mixtures thereof.
Polymerisation may be effected either in a batch manner or on a continuous basis, and the catalyst components of the present invention and the activator therefor may be introduced into the polymerisation vessel separately or the catalyst component and activator may be mixed together before being introduced into the polymer-isatlon reactor.
Preferably however, the polymerisation process of the present invention is effected as a continuous gas phase process such as a fluid bed process. A fluid bed reactor for use in the process of the present invention typically comprises a reaction zone and a so-called velocity reduction zone. The reaction zone comprises a bed of growing polymer particles, formed polymer particles and a minor amount of catalyst particles fluidised by the 1 ~ 5582~
continuous flow of the gaseous monomer and the gaseous diluent which is used to remove heat of polymerisation from the reaction zone. A suitable rate of gas flow may be readily determi~ned by simple experiment. Make up of gas-eous monomer to the circulating gas stream is at a rate equalto the rate at which particulate polymer nrodl1ct and gas is withdrawn from the reactor and the composition of the gas passing thxough the reactor is adjusted to maintain an essentially steady state gaseous composition within the reaction zone. The gas leaving the reaction zone is passed to the velocity reduction zone where entrained particles are removed. Finer entrained particles and dust may be removed in a cyclone and/or fine filter. The said gas is compressed in a compressor and passed through a heat exchanger wherein it is stripped of the heat of polymerisation and then returned to the reaction zone.
Chain transfer agents may be used in a polymerisation process according to the present invention, and when ethy-lene is polymerised their use is normally desirable as the polyethylene produced is of very high molecular weight.
Hydrogen may be conveniently used in accordance with usual practice. However, some solvents may act as chain transfer agents.
The polymerisation process of the present inven-tion is preferably effected under an atmosphere free ofoxygen, for example under an atmosphere of an inert gas e.g. nitrogen, or of the monomer to be polymerised.
It ls also preferred to effect the process using apparatus and solvents which have been carbfully freed from impurities, such as oxygen, water and other substances which would otherwise react with the catalysts.
The invention is illustrated by the following examples.
In the example, hexane and heptane were purified by passage through R3_ll copper catalyst and 5A molecular sieve and finally by sparging with pure nitrogen immediately before use.
l~ssa2g 1~
Ethylene was purified by passage through ~3-11 copper catalyst and 5A molecular sieve. Hydrogen was purified by passage through a catalytic deoxygenation unit and 5A molecular sieve.
Example 1 A particulate support material comprising micro-spheroidal silica (Grace Davidson 952) was dried by heating at 250C for 2 hours under a flow of dry nitrogen.
~ portion of the dried silica (18.4 gms) was slurried in 150 mls of dry, deoxygenated hexane in an atmosphere of dry nitrogen. 36.8 mls of a l.0 M
solution of ethyl aluminium dichloride in hexane was added with stirring. After 15 minutes the slurry was filtered under dry nitrogen and the solid thoroughly washed with three 100 ml portions of hexane. The solid was then resuspended in lO0 mls of hexane and 30 mls of 0.62 M dibutyl magnesium in Isopar E was added with stirring. After 15 minutes a second filtration under nitrogen, followed by washing with three lO0 ml portions of dry hexane, was carried out and the solid suspended in 100 mls of hexane. 18.4 mls of a 0.5 molar solution of bis-n-butoxy titanium dichloride in hexane was then added and the slurry heated to reflux for 30 minutes.
The slurry was filtered and the resulting solid washed with hexane and then dried under vacuum. Analysis of the solid showed that it contained 0.355 milliatoms of titanium per gram.
A first sample of the Ti containing solid (2.9 gms) was slurried in 100 mls of heptane to give a slurry of a comparative catalyst component. A second sample of the Ti containing solid (2.9 gms) was slurried in heptane, anhydrous hydrogen chloride gas ~as passed through the slurry for l minute followed by sparging with nitrogen for 15 minutes to give a slurry of a catalyst component according to the present invention.
1 15~2~
Example 2 A particulate support material comprising alumina (Ketjen Grade B obtainable from A~zo Chemie of A~sterdam, Holland) was air-classified to 20 - 120~ and was dried by 5 heating to 500C for 2 hours in a stream of nitrogen.
150 mls of a 0.62 M solution of magnesium dibutyl in isopar E was added to a slurry of 31 gms of the dried alumina in 150 mls of heptane and the mixture was stirred at room temperature for 2 hours. The solid was filtered 10 off, washed twice with 150 ml portions of heptane and then 300 mls of heptane were added to form a slurry.
31 mls of a solution of 1.0 M titanium tetrachloride in heptane were added to the slurry and the mixture was stirred for 30 minutes at 70C. The solid was filtered 15 off and dried to give a comparative catalyst component.
~ e have found that so-called Ziegler-Natta catalyst components obtained by treating a particulate support material with an organomagnesium compound and a compound of a transition metal of Groups IVA to VIA of the Periodic Table may be treated with a pacifying agent as hereinafter defined to reduce or remove the polymer-isation activity of the catalyst component. Furthermore, we have found that Ziegler-Natta catalyst components obtained by treating a particulate support material with an aluminium compound, or certain halogen-containing com-pounds, an organomagnesium compound, a compound of a transition metal of Groups IVA to VIA and a pacifying agent often give rise, when activated with a suitable activator, to catalysts having an activity higher than that of catalysts prepared from corresponding unpacified catalyst components.
Accordingly, one aspect of the present invention provides a catalyst component which is the product of treating at least one particulate support materi.al, preferably having a reactive surface (as hereinafter '.`~
1 ~ S582~
defined) with:
(a) at least one organomagnesium compound, (b) at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table, (c) at least one pacifying agent, and (d) optionally one or more compounds, hereinafter for convenience referred to as "optional compounds"
selected from the group consisting of:
i) an aluminium compound of the general formula:
RnAlY3_n wherein R, each of which may be the same or different, represents a hydrocarbyl group, or substituted hydrocarbyl group, such as alkyl, aryl, cycloalkyl, aralkyl, alkenyl or alkadienyl, n is 0, 1, 2, 3 or a fraction less than 3, and Y is a singly charged ligand such as hydride, fluoride, chloride, bromide, iodide or oxyhydro-carbyl, ii) an organometalli~ compound of the general formula:
RlMX
wherein M is a metal of Grou~s IA, IIA, IIB, IIIB, IVA, VA or VIA of the Periodic Table, Rl is a hydrocarbyl or a substituted hydrocarbyl group, X is a singly charged anionic ligand or a mono-dentate neutral ligand, m is an integer up to the highest valency of the metal M and p is 0 or an integer up to 2 less than the valency of the metal M,except that when M is a metal ~rom Group VIA p is always ~, and m has a value ~rom 2 to ~he highest valen~y o~ the met~l and when M is a metal $rom Groups IVA or VA m has a value from 2 to the hlghest valqncy o~ the mekal and p has a value ~rom ~ to a value o~ ss than the valency of the metal M, 1 ~5582~
iii) a halogen containing compound and iv) a Lewis Base compound, with the proviso (i) that the at least one particulate support material is treated with the at least one organomagnesium compound, the at least one transitiQn metal compound of Groups IVA, VA or VIA, and the one or more optional com-pounds where one or more is used, prior to being treated with the at least one pacifying agent, except that where (a) the pacifying agent is a hydrogen halide, (b) the at least one particulate support material is treated with an aluminium compound of general formula RnAlY3 n and (c) the at least one particulate support material is treated with the aluminium compound of general formula RnAlY3_n and the at least one organomagnesium compound separately, the pacifying agent may be added to the at least one par-ticulate support material after it has been treated with the at least one organomagnesium compound and the aluminium compound of general formula RnAlY3 n and before it is treated with the at least one transition metal com-pound of Groups IVA, VA or VIA and (ii) that where the atleast one particulate support material is treated with two compounds selected from the aforesaid group of optional compounds they are not exclusively an aluminium compound RnAlY3_n and an organometallic compound RmMXp.
In a preferred aspect the present invention pro-vides a catalyst component which is the product of treating at least one particulate support material, pre-ferably having a reactive surface (as hereinafter defined) with:
30 (a) at least one aluminium compound of the general formula RnAlY3_n where R, Y and n have the meanings hereinbefore ascribed to them, (b) at least one organomagnesium compound, (c) at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table, and (d) at least one pacifying agent, 11S582~
with the proviso that the at least one particulate support material is treated with the at least one aluminium compound RnAlY3 n' the at least one organo-magnesium compound and the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table prior to being treated with the at least one pacifying agent except that where the at least one pacifying agent is a hydrogen halide and the at least one particulate support material is treated with the at least one aluminium compound of general formula RnAlY3_n and the at least one organomagnesium ~ompound separately the at least one pacifying agent may be added to the at least one particulate support material after it has been treated with the at least one aluminium compound RnAlY3_n and the at least one organomagnesium compound and before it is treated with the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table.
In the aforementioned preferred aspect of the present invention the at least one particulate support material is preferably treated with the at least one aluminium compound of general formula RnAlY3_n prior to treatment with the at least one organomagnesium compound and, where the pacifying agent is a hydrogen halide, it is preferably treated with the at least one transition metal compound of Groups IVA, VA or VIA prior to treatment with the at least one pacifying agent.
Where an optional compound which is a Lewis Ba~e compound is used, it is preferred that the support is treated with the at least one organomagnesium compound prior to being treated with the Lewis Base Compound.
All references to the Periodic Table are to the 1 15582~
version of the Periodic Table of the Elements printed inside the back cover of "Advanced Inorganic Chemistry"
by F A Cotton and G Wilkinson 3rd Edition, Interscience Publishers, 1976.
By a "reactive surface" we mean a plurality of sites on, and preferably attached ~o, the.surface of t~e at least one substantially inert particulate support material, which sites are capable of abstracting e.g. a magnesium hydro-carbyl from a solution thereof. Preferably the said sites are OH groups chemically bonded to the surface of the particulate support material and the particulate support material is an inorganic material. Such a material will be "substantially inert" in that, whereas the said -OH groups are capable of reacting with, say, the organomagnesium compound and the organometallic com-pound Rl~Xp where one is used, the bulk of the matrix mat-erial-is chemically inert. Particularly goQd examples of such matrix materials are silica and alumina or mixtures there-of. Th~se comprise a matrix of silicon or aluminium and oxygen atoms, to the surface of which -OH groups are attached, the hydrogen atoms of said groups having an acidic function. However, apart from the presence of these -OH groups, silica and alumina are generally regarded as chemically inert. Within the terms silica and alumina we include silica and alumina based materials containing small amounts of other suitable inorganic oxides, such as magnesium oxide and zinc oxide. The pre-ferred particulate support materials are silica and/or alumina.
The at least one organomagnesium compound used for the preparation of the catalyst components according to the present invention are compounds in which at least one hydrocarbyl group is directly bonded to magnesium through a carbon atom. Preferably two hydrocarbyl groups bonded in this way are present for each magnesium atom, which hydrocarbyl groups may be the same or different, although 1 1558~
we do not exclude the possibility that one of the groups bonded to the magnesium may ke halogen or oxyhydrocarbyl.
The hydrocarbyl group may be an alkyl group, aryl group, cycloalkyl group, aralkyl group, alkadienyl group or an alkenyl group. The number of carbon atoms in the hydro-carbyl group is generally between 1 and 30, but this number is not critical. Examples of magnesium compounds partic-ularly suitable in the preoaration of catalyst components according to the present invention are diethyl magnesium, dipropyl magnesium, di-isopro?vl magnesium, dibutyl or diisobutyl ma~nesium, butyl octyl magnesium, diamyl magnesium, dihexyl magnesium, diallyl magnesium, didecyl magnesium and didodecyl magnesium, dicycloalkyl magnesium with identical ox different cyclo-alkyl groups containing 3 to 12 carbon atoms, preferably 5 or 6 carbon atoms.
The magnesium may carry an alkyl and a cyclo-alkyl group. Diphenyl-magnesium is the preferred aromatic compound although, e.g. ditolyl and dixylyl magnesium, and - magnesium aryls derived from compounds with two or more con~ensed or non-condensed aromatic nuclei can also be used. Catalysts prepared with diaryl magnesium compounds may have a relatively lower activity.
Preferably a dialkyl magnesium is used wherein the alkyl groups are C1-Cl~ groups, particularly prefer-ably dibutyl magnesium,which may be present as a mixtureof dibutyl magnesiums, for example a mixture of di-n-butyl magnesium and di-iso-butyl magnesium.
Preferably the amount of the at least one organo-magnesium compound used in the preparation of catalyst components of the present invention is sufficient to react with at least substantially all the reactive sites on the surface of the at least one particulate support material, where such sites are present thereon.
The at least one transition metal co~pound of Gro~s IVA, VA or T~7I~ of the Periodic Table employed in the preparation of the catalyst component of the present 1 1 5 582 ~ ~
invention may be any of the transition metal compounds, or mixtures thereof, known to be useful in forming Ziegler-Natta catalysts.
The transition metal is preferably titanium, vanadium, molybdenum, zirconium or chromium, especially titanium. Suitable compounds incIude halides, halo-oxides, alkoxides, haloalkoxides, and acetyl acetonates, especially chlorides and alkoxides. The preferred compounds are titanium tetrachloride and bis-alkoxy dichloride.
The quantity of the at least one transition metal compound used in the preparation of the catalyst component of the present invention is generally not more than stoichiometric and preferably is less than stoichiometric.
In the attached formula drawings, A, B and C
represent halogenating agents and D represents Lewis Base compounds which are suitable for use in the preparation of a catalyst component according to the present invention.
Suitable pacifying agents which may be employed in the preparation of catalyst components of the present invention include agents which, it is believed, are capable of breaking metal-carbon or metal-hydrogen bonds in the catalyst component but which do not have a deleterious effect on the catalyst component. Such agents include inter alia oxygen, carbon monoxide, carbon dioxide, halohydrocarbons of formula (C) and protic agents. Typically, protic agents are hydrogen halides, carboxylic acids, alcohols, water, amines and acetylactone. Preferably the pacifying agent is an aliphatic alcohol having from 1 to about 6 carbon atoms; an anhydrous hydrogen halide e.g. hydrogen chlorlde or hydrogen bromide; a halohydrocarbon of formula (C), e.g. an alkyl halide such as t-butyl chloride, or a carbon tetrahalide, e.g. carbon tetra-chloride.
1 ~5582~
` 7a The quantity of the at least one pacifying agent used ls sufficient to break substantially all the metalhydrocarbyl or metal-hydride bonds in the catalyst component. Conveniently, the pacifying , 5 agent is added to a suspension~of the particulate support material which has been treated with at least the at least one organo~
. ~ .
magnesium compound and the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table. Where an excess of a gaseous pacifying agent is used the excess may be removed by sparging with nitro~en.
Where at least one aluminium compound RnAlY3 n is used in the preparation of catalyst components of the present invention preferably R, where present, is alkyl, having l to 4 carbon atoms, more preferably ethyl or isobutyl, and preferahly Y, where present, is a halide, particularly preferably chloride or bromide, more particularly preferably chloride.
Suitable aluminium compounds R AlY3 n include aluminium chloride, aluminium bromide, monoethyl aluminium, dichloride, ethyl aluminium sesqui-c}~.loride and diethyl aluminium chloride.
The molar ratio of the at least one aluminium compound, where it is used, to the at least one organomagnesium compound in the catalyst component of the present invention is preferably between 0.5 and lO0, particularly preferably between l.0 and 80 and more particularly preferably between l.0 and lOØ The molar ratio of the at least one aluminium compound to the at least one transition metal compound is preferably between l and 2000, particularly preferably between 2 and 1500 and more particularly preferably between 2 and lO0.
Where an organometallic compound RmMXp is used and M is a metal from Groups IA, IIA, IIB or IIIB of the Periodic Table it is preferred that p is O and m is the highest valency of the metal.
Preferred organometallic compounds RmMXp are those in which the metal M is a transition metal of Groups IVA, VA or VIA
more preferably titanium, vanadium, molybdenum, zirconium or chromium, and especially zirconium. The monovalent ligand X, where it is present, is preferably halogen.
-.
~1 Hydrocarbyl groups of different types may be associated with a single metal atom M.
Suitable hydrocarbyl groups Rl include alkyl and alkenyl groups (including ~-alkenyl groups such as ~-allyl) and substituted derivatives thereof. Examples oftransition metal complexes include tetrakis (~-allyl) zirconium or hafnium, tris (~-allyl) chromium, tetrakis (~-methallyl) zirconium or hafnium, tris (~-methallyl) chromium and zirconium tris (~-allyl) bromide.
A preferred class of organometallic compounds RmMXp are organic transition metal complexes in which some or all of the groups, or ligands, Rl are substituted alkyl groups of general formula -CH2Z ~-bonded to the transition metal through the carbon atom. In this general formula Z may represent a group capable of interaction with the vacant d-orbitals of the metal M. Preferably all the groups Rl have this formula, but it is possible for some of them to comprise other hydrocarbyl or substituted hydrocarbyl groups.
Suitable substituent groups Z include aromatic and polyaromatic groups such as phenyl and naphthyl, giving rise in the formula -CH2Z to the alkaryl groups benzyl and (1-methylene-1-naphthyl) and ring substituted derivatives thereof, for example ~-methyl benzyl.
Z may also be a cycloalkenyl group, such as a cyclo-octenyl group.
Z may also comprise a group of general formula: A(R2)3 where A represents carbon, silicon, germanium, tin or lead, and each R2, which may be the same or different, represents a hydrocarbyl group or hydrogen; preferably at ieast oneR2 ls an alkyl group.
Examples of this preferred class of organometallic compounds ~ ~p include zirconium and titanium tetra(benzyl), tris(benzyl)zirconium chloride, zirconium tetrakis (p-methyl benzyl), zirconium and titanium tetrakis (l-methylene-l-naphthyl), zirconium tetrakis (trimethylsilylmethylene), 1 ~5582~
zirconium tetrakis (neopentyl) and zirconium tetrakis (neophyl).
Examples of preferred organometallic compounds RmMXp containing monovalent ligands X include tris (~-allyl) zirconium chloride, bromide or iodide and the equivalent ~-methallyl and benzyl compounds.
Where an organometallic compound RmMXp and an aluminium compound RnAIY3_n are used in the preparation of catalyst components of the present invention the molar ratio of aluminium compound to organometallic compound is preferably between 0.1 and 100 and particularly prefer-ably between 1 and 20.
Where an optional compound which is a halogen containing compound is used in the preparation of a catalyst component of the present invention it is pre-ferably a halogenating agent and particularly preferably a chlorinating agent. Suitable halogenating agents include hydrogen halides such as hydrogen chloride, silicon halides of the formula A in the attached formula drawings, carboxylic acid halides of the formula B in the attached formula drawings, halohydrocarbons of the formula C in the attached formula drawings, phosphorus pentachloride, thionyl chloride, sulphuryl chioride, phosgene, nitrosyl chloride, halides of mineral acids, chlorine, bromine, chlorinated polysiloxanes, hydrocarbyl aluminium halides, aluminium, chloride, boron halides, and ammonium hexafluorosilicate. In the attached formula drawings A, B, C, R3 is a hydrogen or a hydro-carbyl group, preferably an alkyl group containing 1 up to 6 carbon atoms or an aryl, alkaryl or aralkyl group containing 6 up to 15 carbon atoms; R4 is a hydrocarbyl group, preferably an alkyl group containing 1 up to 4 carbon atoms or an aryl, alkaryl or aralkyl group con-taining 6 up to 12 carbon atoms; ~5, each of which may be the same or different, is hydrogen, a hydrocarbyl grou or a substituted hydrocarbyl aroun, e.g. a halogenated hydrocarbyl group, ~1 is a halide, 1 ;5582~
preferably chloride; a is 0 or an integer from l up to 3.
The silicon halides of formula (A) include silicon tetrachloride, silicon tetrabromide and halosilanes such as trimethyl silicon monochloride, diethyl silicon di-chloride and monobutyl silicon trichloride.
The carboxylic acid halides of formula (B) include acetyl chloride, benzoyl chloride and p-methylbenzoyl chloride.
The halohydrocarbons of formula (C) include carbon tetrachloride, chloroform, ethyl chloride, ethylene di-chloride and l,l,l-trichloroethane.
Halides of mineral acids include boron trichloride and antimony pentachloride.
Hydrocarbyl aluminium halides include diethyl aluminium chloride and monoethyl aluminium dichloride.
The quantity of the halogenating agent is conven-iently sufficient to provide at least 0.1, and especially at least 1.0, halogen atom at every reactive site on the at least one particulate support material. The treatment can be effected at ambient temperature or at an elevated temperature of up to 100C. The preferred temperature is dependent on the particular halogenating agent used, for example, using silicon tetrachloride, the temperature is preferably at least 60C. The treatment is conveniently carried out by adding the halogenating agent to a stirred suspension of the at least one particulate support material or of the at least one particulate support material treated with the at least one organomagnesium compound. Using a gaseous halogenating agent such as hydrogen chloride, the gas can be passed into the reaction medium until no further absorption is observed to occur.
The treatment with the halogenating agent is conveniently effected for a time of at least 0.25 up to 10 hours, preferably from 1 up to 5 hours.
lla Where an optional compound which is at least one halogen containing compound is used in the preparation of a catalyst component of the present invention and where the at least one halogen-containing compound is a halohydrocarbon of formula (C) in the attached drawings the at least one particulate support material is prefer-ably treated with it, at elevated temperature, e.g. 300C
to 600C, prior to treatment with the at least one organo-magnesium compound, the at least one transition metal com-pound of Groups IVA, VA or VIA and the at least onepacifying agent. Preferably the halohydrocarbon has a plurality of halogen atoms, and a particularly preferred halohydrocarbon is carbon tetrachloride. Conveniently the halohydrocarbon in gaseous form is passed through a fluidised bed of the at least one particulate support material. Catalyst components prepared in the aforesaid procedure give rise to catalysts of increased activit~
compared with catalysts prepared from unpacified catalyst components. It is believed that in this aspect of the present invention the haloatoms of the at least one halo-hydrocarbon (C) replace hydroxyl groups on the surface of the at least one particulate support material.
IR a further preferred aspect the present invention provides a catalyst component which is the product of treating at least one particulate support material with:
(a) at least one halohydrocarbon of the general formula (C) in the attached drawings, (b) at least one organomagnesium compound, (c) at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table, and (d) at least on pacifying agent with the proviso that the at least one particulate support material is treated firstly with the at least one halo-hydrocarbon and fourthly with the at least one pacifying a~ent.
1 15582~
Where an optional compound which is a Lewis base compound is used it can be any organic Lewis base compound which has been proposed for use in a Ziegler polymerisation catalyst and which affects either the activity or stereo-specificity of such a system. Thus, the Lewis Base com-pound may be an ether, an ester, a ketone, an alcohol, a thioether, a thioester, a thioketone, a thiol, a sulphone, a sulphonamide, a fused ring compound containing a heterocyclic sulphur atom, an organo-silicon compound such as a silane or siloxane, an amide such as formamide, urea and the substituted derivatives thereof such as tetramethylurea, thiourea, an alkanolamine, an amine, a cyclic amine such as pyridine or quinoline, a diamine such as tetramethylethylenediamine or an organo-phosphorus compound such as an organo-phosphine, an organo-phosphine oxide, an organo-phosphite or an organo-phosphate. The use of organo Lewis Base compounds is disclosed, inter alia, in British Patent Speci~icat~ons 803 198, 809 717, 880 998, 896 509, 920 118, 921 954, 933 236, 940 125, 966 025, 969 074, 971 248, 1 013 363, 1 017 977, 1 049 723, 1 122 010, 1 150 845, 1 208 815, 1 234 657, 1 324 173, 1 359 328, 1 383 207, 1 423 658, 1 423 659 and 1 423 660.
Preferred Lewis Base compounds are esters which may be represented by the ~ormula D) given in the attached formula drawings.
In the formula D), R~ is a hydrocarbyl group which may be substituted by one or more halogen atoms and/or hydrocarbyloxy groups;
and R7 is a hydrocarbyl group which may be substituted by one or more halogen atoms.
The groups R6 and R7 may be the same or different.
The group R6 is conveniently an alkyl or aryl group, for example, a methyl, ethyl, phenyl or tolyl group. The 1 ~ 5582 g group R7 is preferably an alkyl group containing up to 6 carbon atoms, for example an ethyl or a butyl group.
It is particularly preferred that R6 is an aryl group and R7 is an alkyl group.
A Lewis Base compound may be added to the at least one particulate support material treated with the at least one organomagnesium compound and optionally with the halogenating agent. This is conveniently effected by adding the 1ewis Base compound to a suspension, in an inert liquid medium such as an inert liquid hydrocarbon or halohydrocarbon, of the at least one particulate support material treated with the at least one organo-magnesium compound and optionally with the halogenating agent. The quantity of Lewis Base used is conveniently in an amount of up to 1 mole of Lewis Base compound for each gramme atom of magnesium which is present on the at least one particulate support material. Preferred quantities of the Lewis Base are from 0.1 to 0.8 mole for each gramme atom of magnesium and especially at least 0.5 to 0.8 mole for each gramme atom of magnesium.
The addition of the Lewis Base compound to the at least one particulate support material may be effected at temperatures of from 0C to 100C and is very conveniently carried out at ambiént temperature, that is from about 15C up to about 30C. After adding the Lewis Base com-pound to the at least one particulate support material the materials are conveniently allowed to remain in con-tact for 0.1 up to 70 hours, especially 1 up to 20 hours.
After the Lewis Base compound and the at least one particulate support material treated with at least the at least one magnesium compound have remained in con-tact for the desired period of time, the product thus formed is conveniently separated from the reaction medium and washed with an inert liquid.
Magnesium containing Ziegler-Natta catalyst components which have a tendency to be so reactive that they 1 ~S582 3 cannot be mixed with an olefin containing stream prior to char~ing the said stream to a ~olymerisation zone are known.
However, the catalyst components of the present invention are often of sufficiently low polymerisation activity S or are substantially completely inactive such that they can be added to the polymerisation zone in the presence of an olefin containing stream.
A further aspect of the present invention provides an olefin polymerisation catalyst which comprises (a) the catalyst component as hereinbefore defined and (b) an activator which is at least one organoFetallic co~ound of a metal of Groups T-IV of the Periodic Table.
Preferably the activator is an organometallic derivative of a metal of Groups IA, IIA, IIB, IIIB or IVB of the Periodic Table, particularly preferably the metal is aluminium and more particularly preferably the activator is a trialkyl aluminium, dihaloalkyl aluminium or halodialkyl aluminium. It will be appreciated that sufficient of the said activator is employed to trans-form the metal atoms of the transition metal compoundknown to be useful in forming Ziegler-Natta catalysts to an active state.
The catalyst component of the present invention may be treated with the aforesaid activator by methods known in the art, for example, they may be reacted totally outside or inside the polymerisation vessel in which the catalyst is to be used or activation may be effected partially outside the polymerisation vessel and completed inside the said polymerisation vessel.
A further aspect of the present invention pro-vides a process for the polymerisation or copolymer-isation of an olefinically unsaturated monomer which process comprises contacting, under polymerisation con-ditions, at least one olefin monomer with a catalyst in accordance with the present invention.
1 ~ S582~
The term "olefinically unsaturated monomer" is intended to include mono-olefins such as ethylene, propy-lene and 4-methylpentene-1.
The catalyst of the present invention may also be S used to initiate the copolymerisation of two or more ole~
finically unsaturated monomers. For example, ethylene may be copolymerised with a small amount of propylene, butene, hexene or decene, butadiene or styrene.
Polvmerisation processes according to the present invention may be carried out by techniques generally used for polymerisation processes of the type using Ziegler catalysts.
The choice of conditions of pressure and temperature will vary with factors such as the nature of the monomer and catalyst and whether liquid, e.g. bulk or diluent, or gas phase polymerisation is used.
For example, when ethylene is polymerised, pressures from sub-atmospheric to several thousand atmospheres may be used. Low pressure (say from 0.1 to 30 atmospheres) and intermediate pressures (say from 30 to 300 atmospheres) polymerisation may be carried out using conventional equipment; but very high pressure polymerisation must be performed using suitable specialised reactors and pumping equipment. However, since, generally speaking, the higher the pressure the higher the activity, the use of such techniques may be justified. If very high pressures are used, it is pre-ferred that conditions are such that the ethylene feed and polyethylene produced are maintained in a single fluid phase, i.e. the pressure should exceed 500 Kg/cm2 preferably 1000 to 3000 Kg/cm2 and the temperature should be greater than 125C, say 140-300C. This type of process is usually operated in a continuous manner.
A wide range of temperatures may be used, but in general low and intermediate pressure ethylene polymer-1 ~5$~Z8 isations are carried out at temperatures in the range50-160C.
When the process of the present invention is used to polymerise propylene, it is preferred to operate under conditions commonly used for the polymerisation of propylene. However, polymerisation of propylene under other conditions, e.g. high pressure, is not excluded.
It is also within the scope of the present inven-tion to use the catalysts thereof to initiate the copoly-merisation of ethylene and propylene together and/or withother olefinically unsaturated monomers.
The polymerisation process of the present invention may be carried out in the liquid or gaseous phase (i.e. in the essential absence of a liquid medium) and preferably in the gaseous phase. Where polymerisation is effected in the liquid phase, and the monomer is not li~uid under the polymerisation conditions, the monomer may be dissolved in a suitable solvent. Examples of suitable solvents are aliphatic or aromatic hydrocarbons;
for instance pentane, hexane, heptane, octane, decane, benzene, toluene and mixtures thereof.
Polymerisation may be effected either in a batch manner or on a continuous basis, and the catalyst components of the present invention and the activator therefor may be introduced into the polymerisation vessel separately or the catalyst component and activator may be mixed together before being introduced into the polymer-isatlon reactor.
Preferably however, the polymerisation process of the present invention is effected as a continuous gas phase process such as a fluid bed process. A fluid bed reactor for use in the process of the present invention typically comprises a reaction zone and a so-called velocity reduction zone. The reaction zone comprises a bed of growing polymer particles, formed polymer particles and a minor amount of catalyst particles fluidised by the 1 ~ 5582~
continuous flow of the gaseous monomer and the gaseous diluent which is used to remove heat of polymerisation from the reaction zone. A suitable rate of gas flow may be readily determi~ned by simple experiment. Make up of gas-eous monomer to the circulating gas stream is at a rate equalto the rate at which particulate polymer nrodl1ct and gas is withdrawn from the reactor and the composition of the gas passing thxough the reactor is adjusted to maintain an essentially steady state gaseous composition within the reaction zone. The gas leaving the reaction zone is passed to the velocity reduction zone where entrained particles are removed. Finer entrained particles and dust may be removed in a cyclone and/or fine filter. The said gas is compressed in a compressor and passed through a heat exchanger wherein it is stripped of the heat of polymerisation and then returned to the reaction zone.
Chain transfer agents may be used in a polymerisation process according to the present invention, and when ethy-lene is polymerised their use is normally desirable as the polyethylene produced is of very high molecular weight.
Hydrogen may be conveniently used in accordance with usual practice. However, some solvents may act as chain transfer agents.
The polymerisation process of the present inven-tion is preferably effected under an atmosphere free ofoxygen, for example under an atmosphere of an inert gas e.g. nitrogen, or of the monomer to be polymerised.
It ls also preferred to effect the process using apparatus and solvents which have been carbfully freed from impurities, such as oxygen, water and other substances which would otherwise react with the catalysts.
The invention is illustrated by the following examples.
In the example, hexane and heptane were purified by passage through R3_ll copper catalyst and 5A molecular sieve and finally by sparging with pure nitrogen immediately before use.
l~ssa2g 1~
Ethylene was purified by passage through ~3-11 copper catalyst and 5A molecular sieve. Hydrogen was purified by passage through a catalytic deoxygenation unit and 5A molecular sieve.
Example 1 A particulate support material comprising micro-spheroidal silica (Grace Davidson 952) was dried by heating at 250C for 2 hours under a flow of dry nitrogen.
~ portion of the dried silica (18.4 gms) was slurried in 150 mls of dry, deoxygenated hexane in an atmosphere of dry nitrogen. 36.8 mls of a l.0 M
solution of ethyl aluminium dichloride in hexane was added with stirring. After 15 minutes the slurry was filtered under dry nitrogen and the solid thoroughly washed with three 100 ml portions of hexane. The solid was then resuspended in lO0 mls of hexane and 30 mls of 0.62 M dibutyl magnesium in Isopar E was added with stirring. After 15 minutes a second filtration under nitrogen, followed by washing with three lO0 ml portions of dry hexane, was carried out and the solid suspended in 100 mls of hexane. 18.4 mls of a 0.5 molar solution of bis-n-butoxy titanium dichloride in hexane was then added and the slurry heated to reflux for 30 minutes.
The slurry was filtered and the resulting solid washed with hexane and then dried under vacuum. Analysis of the solid showed that it contained 0.355 milliatoms of titanium per gram.
A first sample of the Ti containing solid (2.9 gms) was slurried in 100 mls of heptane to give a slurry of a comparative catalyst component. A second sample of the Ti containing solid (2.9 gms) was slurried in heptane, anhydrous hydrogen chloride gas ~as passed through the slurry for l minute followed by sparging with nitrogen for 15 minutes to give a slurry of a catalyst component according to the present invention.
1 15~2~
Example 2 A particulate support material comprising alumina (Ketjen Grade B obtainable from A~zo Chemie of A~sterdam, Holland) was air-classified to 20 - 120~ and was dried by 5 heating to 500C for 2 hours in a stream of nitrogen.
150 mls of a 0.62 M solution of magnesium dibutyl in isopar E was added to a slurry of 31 gms of the dried alumina in 150 mls of heptane and the mixture was stirred at room temperature for 2 hours. The solid was filtered 10 off, washed twice with 150 ml portions of heptane and then 300 mls of heptane were added to form a slurry.
31 mls of a solution of 1.0 M titanium tetrachloride in heptane were added to the slurry and the mixture was stirred for 30 minutes at 70C. The solid was filtered 15 off and dried to give a comparative catalyst component.
2 mls of carbon tetrachloride were added to a slurry of 6.9 gm of the comparative catalyst component in 100 mls of heptane. The mixture was stirred for 1 hour at room temperature and then for 3 hours at 60C. The solid 20 was filtered off, washed with heptane and dried to give a catalyst component of the present invention.
Example 3 A portion of the dried silica of Example 1 (24.85 gms) was slurried in 250 mls of dry, deoxygenated 25 heptane in an atmosphere of dry nitrogen. 49.7 mls of a 1.0 M solution of ethyl aluminium dichloride in heptane was added with stirring. The mixture was stirred for 15 minutes at room temperature and then heated to 70C
for 30 minutes. The slurry was filtered under dry 30 nltrogen and the solid thoroughly washed with three 100 ml portlons of hexane. The solid was then resuspended in 250 mls of heptane and 40.8 mls of 0.62 M dibutyl magnesium in Isopar*E was added with stirring. After 15 minutes at room temperature a second filtration under nitrogen, 35 followed by washing with three 100 ml portions of dry hexane, was carried out and the solid suspended in B * Trade Mark 1 155~8 250 mls of heptane. 12.43 mls of a 1.0 molar solution of bis-n-butoxy titanium dichloride in hexane was then added and the- slurry was heated to 70C for 2 hours. The slurry was filtered and the resulting solid washed with hexane and then dried under vacuum to give a comparative catalyst component. 21.2 mls of a 0.2 M solution of isopropanol in heptane was added to a slurry of 11.28 gms of the com-parative catalyst component of 100 mls of heptane. The mixture was heated to 70C for 2 hours. The solid was filtered off, washed with heptane and dried to leave a catalyst component according to the present invention.
Example 4 115.6 gms of the air-classified particulate support material used in Example 2 was dried at 500C under nitrogen for 1 hour in a fluid-bed drier. The fluidising gas was saturated with carbon tetrachloride vapour at 0C
and was passed through the particulate support material for 3 hours at 500C to afford 75.5 gms of chlorinated y-alumina. The chlorinated y-alumina was found to con-tain 9.8% chlorine and no hydroxyl groups could bedetected by infra-red spectroscopy.
50.85 mls of a 0.62M solution of magnesium dibutyl in isopar E was added to a slurry of 21.02 gms of the chlorinated y-alumina in 200 mls of heptane. The mixture was stirred at 50C for 2 hours, the solid was filtered off, and was washed twice with 200 ml portions of heptane.
12.0 mls of a 1.0 M solution of dibutoxy titanium dichloride in heptane was added to a slurry of the solid in 200 mls of heptane and the mixture was stirred for 30 minutes, filtered and the solid was dried to give a comparative catalyst component (0.44 milliatoms titanium per gram of comparative catalyst component).
A 4.02 gms portion of the comparative catalyst component was slurried in 88.4 mls of heptane and dry hydrogen chloride gas was passed through the slurry for 1 minute. The slurry was then sparged with nitrogen for 1 ~5S82~
15 minutes to give a slurry of a catalyst component according to the present invention.
Examples 5-7 General Procedure for the pol~merisation of ethylene The polymerisation of ethylene was carried out as follows. A commercial hydrogenator (Hydrogenation Control Unit from Electrosound Supplies Limited) was adapted to deliver ethylene to a 500 ml vessel containiny 200 ml iso-octane at ~0C. The vessel was stirred with a VIBR0-MIXER El. A solution of an aluminium trialkyl was added to the iso-octane which was then saturated with ethylene at 80C and the polymerisation started by addition of a slurry of a catalyst component. The polymerisation was stopped after 1 hour. The results are given in Table 1 from which it can be seen that the activity of catalysts according to the present invention is greater than that of corres?onding catalysts prepared from unpacified catalyst com?onents.
/
~ ' _ U~
~ ta U~
O ~D Ln O
n ~n ~ ~ ~ I
v~a ~r ~ ~ ~ ,1 .¢'1 6~
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~ ~ ' .. ~ 00 ~ 00 ~1 ~ ~3 O ~1 ~ 00 ~1 ~1 1~ L~ O O
o ~ ~- ~I ~ o ~, ~ ~ o E~ .,1 ~ ~
. o ~0 ~ ~ ~
X C~ 0~ ~ ~ ~ ~ ~ ~ .~ 3 E~ ~ ~ ~ ~ ~ ~ ~ ~ o ~ ~
-l ~ ~ ~l ~ --l ~ ~ ~ ~ ~ o ~ ~ ~ ~ ~ ~ ~ ~ ~ .,l : ~ ~ ~ ~
a) a~ ~ ~ ~ u~
.
o~ ~ ~ ~ ~
~ ~ 0 ~ ~ ~ ~ x S~ ~ S~ ~
X ~1 ~ ~ ,4 --~ R ~ R ^ ~dQ ^ R ^ ~ Q O
O ~ O ~ O~ O ~ O P~ O ~r o ~ ~ ~ a~
O X ~ o x ~i x ~ o x ~ x ~ o x x ~ o x -- U ~-- ~ _ ~-- V ~--. .. ___ .. ...... m U~
a) ~ ~ e ~ u~ E~ ~ ~ co E~ ~ O~
X ~ C~ O
Example 3 A portion of the dried silica of Example 1 (24.85 gms) was slurried in 250 mls of dry, deoxygenated 25 heptane in an atmosphere of dry nitrogen. 49.7 mls of a 1.0 M solution of ethyl aluminium dichloride in heptane was added with stirring. The mixture was stirred for 15 minutes at room temperature and then heated to 70C
for 30 minutes. The slurry was filtered under dry 30 nltrogen and the solid thoroughly washed with three 100 ml portlons of hexane. The solid was then resuspended in 250 mls of heptane and 40.8 mls of 0.62 M dibutyl magnesium in Isopar*E was added with stirring. After 15 minutes at room temperature a second filtration under nitrogen, 35 followed by washing with three 100 ml portions of dry hexane, was carried out and the solid suspended in B * Trade Mark 1 155~8 250 mls of heptane. 12.43 mls of a 1.0 molar solution of bis-n-butoxy titanium dichloride in hexane was then added and the- slurry was heated to 70C for 2 hours. The slurry was filtered and the resulting solid washed with hexane and then dried under vacuum to give a comparative catalyst component. 21.2 mls of a 0.2 M solution of isopropanol in heptane was added to a slurry of 11.28 gms of the com-parative catalyst component of 100 mls of heptane. The mixture was heated to 70C for 2 hours. The solid was filtered off, washed with heptane and dried to leave a catalyst component according to the present invention.
Example 4 115.6 gms of the air-classified particulate support material used in Example 2 was dried at 500C under nitrogen for 1 hour in a fluid-bed drier. The fluidising gas was saturated with carbon tetrachloride vapour at 0C
and was passed through the particulate support material for 3 hours at 500C to afford 75.5 gms of chlorinated y-alumina. The chlorinated y-alumina was found to con-tain 9.8% chlorine and no hydroxyl groups could bedetected by infra-red spectroscopy.
50.85 mls of a 0.62M solution of magnesium dibutyl in isopar E was added to a slurry of 21.02 gms of the chlorinated y-alumina in 200 mls of heptane. The mixture was stirred at 50C for 2 hours, the solid was filtered off, and was washed twice with 200 ml portions of heptane.
12.0 mls of a 1.0 M solution of dibutoxy titanium dichloride in heptane was added to a slurry of the solid in 200 mls of heptane and the mixture was stirred for 30 minutes, filtered and the solid was dried to give a comparative catalyst component (0.44 milliatoms titanium per gram of comparative catalyst component).
A 4.02 gms portion of the comparative catalyst component was slurried in 88.4 mls of heptane and dry hydrogen chloride gas was passed through the slurry for 1 minute. The slurry was then sparged with nitrogen for 1 ~5S82~
15 minutes to give a slurry of a catalyst component according to the present invention.
Examples 5-7 General Procedure for the pol~merisation of ethylene The polymerisation of ethylene was carried out as follows. A commercial hydrogenator (Hydrogenation Control Unit from Electrosound Supplies Limited) was adapted to deliver ethylene to a 500 ml vessel containiny 200 ml iso-octane at ~0C. The vessel was stirred with a VIBR0-MIXER El. A solution of an aluminium trialkyl was added to the iso-octane which was then saturated with ethylene at 80C and the polymerisation started by addition of a slurry of a catalyst component. The polymerisation was stopped after 1 hour. The results are given in Table 1 from which it can be seen that the activity of catalysts according to the present invention is greater than that of corres?onding catalysts prepared from unpacified catalyst com?onents.
/
~ ' _ U~
~ ta U~
O ~D Ln O
n ~n ~ ~ ~ I
v~a ~r ~ ~ ~ ,1 .¢'1 6~
~3 . .~.
~ ~ ' .. ~ 00 ~ 00 ~1 ~ ~3 O ~1 ~ 00 ~1 ~1 1~ L~ O O
o ~ ~- ~I ~ o ~, ~ ~ o E~ .,1 ~ ~
. o ~0 ~ ~ ~
X C~ 0~ ~ ~ ~ ~ ~ ~ .~ 3 E~ ~ ~ ~ ~ ~ ~ ~ ~ o ~ ~
-l ~ ~ ~l ~ --l ~ ~ ~ ~ ~ o ~ ~ ~ ~ ~ ~ ~ ~ ~ .,l : ~ ~ ~ ~
a) a~ ~ ~ ~ u~
.
o~ ~ ~ ~ ~
~ ~ 0 ~ ~ ~ ~ x S~ ~ S~ ~
X ~1 ~ ~ ,4 --~ R ~ R ^ ~dQ ^ R ^ ~ Q O
O ~ O ~ O~ O ~ O P~ O ~r o ~ ~ ~ a~
O X ~ o x ~i x ~ o x ~ x ~ o x x ~ o x -- U ~-- ~ _ ~-- V ~--. .. ___ .. ...... m U~
a) ~ ~ e ~ u~ E~ ~ ~ co E~ ~ O~
X ~ C~ O
Claims (11)
1. A catalyst component which is the product of treating at least one particulate support material with at least one organomagnesium compound, at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table, and at least one pacifying agent, which is capable of breaking metal-carbon or metal-hydrogen bonds in the catalyst component but does not have a deleter-ious effect on the catalyst component and which is used in sufficient quantity to break substantially all of said bonds.
2. A catalyst component which is the product of treating at least one particulate support material with at least one aluminium compound of general formula RnAlY3-n' wherein R, Y and n have the meanings ascribed to them in Claim 1, at least one organomagnesium compound, at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table and at least one pacifying agent, which is capable of breaking metal-carbon or metal-hydrogen bonds in the catalyst component but does not have a deleterious effect on the catalyst component and which is used in sufficient quantity to break substantially all of said bonds, with the proviso that the at least one particu-late support material is treated with the at least one aluminium compound RnAlY3-n' the at least one organomagnesium compound and the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table prior to being treated with the at least one pacifying agent except that where the at least one pacifying agent is a hydrogen halide and the at least one particulate support material is treated with the at least one aluminium compound of general formula RnAlY3-n and the at least one organomagnesium compound separately the at least one pacifying agent may be added to the at least one particulate support material after it has been treated with the at least one aluminium compound RnAlY3-n and the at least one organomagnesium compound and before it is treated with the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table.
3. A catalyst component as claimed in Claim 2 wherein the at least one particulate support material is treated with the at least one aluminium compound RnAlY3-n prior to being treated with the at least one organomagnesium compound.
4. A catalyst component as claimed in Claim 1 wherein the at least one particulate support material is treated with at least one halogen-containing compound which is a halohydrocarbon of general formula R?CXl(4-a) wherein R5, each of which may be the same or different, is hydrogen, a hydrocarbyl residue or a substituted hydro-carbyl residue, Xl is a halide and a is 0 or an integer from 1 up to 3, at elevated temperature, prior to treatment with the at least one organomagnesium compound, the at least one transition metal compound of Groups IVA, VA or VIA of the Periodic Table and the at least one pacifying agent.
5. A catalyst component as claimed in Claim 4 wherein in the formula R?CXl(4-a) a is 0, 1 or 2.
6. A catalyst component as claimed in Claim 1 wherein the at least one pacifying agent comprises carbon dioxide, carbon monoxide, oxygen, a halohydrocarbon as defined in Claim 4 or a protic agent.
7. A catalyst component as claimed in Claim 1 wherein the at least one pacifying agent is an aliphatic alcohol having from 1 to 6 carbon atoms, an anhydrous hydrogen halide, or a halohydrocarbon.
8. An olefin polymerisation catalyst comprising a catalyst component as claimed in Claim 1 activated with a suitable activator which is at least one organo-metallic compound of a metal of Groups I to IV of the Periodic Table.
9. A process for the polymerisation or copolymer-isation of an olefinically unsaturated monomer which process comprises contacting, under polymerisation condi-tions, at least one olefin monomer with a catalyst as claimed in Claim 8.
10. A process as claimed in Claim 9 whenever effected in a fluidised bed reactor.
11. A catalyst component as claimed in Claim 1 in which the at least one particulate support material is treated with one or more compounds selected from the group consisting of:
i) an aluminium compound of the general formula:
RnAlY3-n wherein R, each of which may be the same or different, represents a hydrocarbyl group, or substituted hydrocarbyl group, such as alkyl, aryl, cycloalkyl, aralkyl, alkenyl or alkadienyl, n is 0, 1, 2, 3 or a fraction less than 3, and Y
is a singly charged ligand such as hydride, fluoride, chloride, bromide, iodide or oxyhydrocarbyl, ii) an organometallic compound of the general formula:
R?MXp wherein M is a metal of Groups IA, IIA, IIB, IIIB, IVA, VA or VIA of the Periodic Table, R1 is a hydrocarbyl or a substituted hydrocarbyl group, X is a singly charged anionic ligand or a mono-dentate neutral ligand, m is an integer up to the highest valency of the metal M and p is 0 or an integer up to 2 less than the valency of the metal M, except that when M is a metal from Group VIA, p is always 0, and m has a value from 2 to the highest valency of the metal, and when M is a metal from Groups IVA or VA m has a value from 2 to the highest valency of the metal and p has a value from 0 to a value of 2 less than the valency of the metal M, iii) a halogen containing compound and iv) a Lewis Base compound with the proviso (i) that the at least one particulate support material is treated with the at least one organo-magnesium compound, the at least one transition metal compound of Groups IVA, VA or VIA and one or more of the compounds i, ii, iii or iv prior to being treated with the at least one pacifying agent, which is capable of breaking metal-carbon or metal-hydrogen bonds in the catalyst component but does not have a deleterious effect on the catalyst component and which is used in sufficient quantity to break substantially all of said bonds, except that where (a) the at least one pacifying agent is a hydrogen halide, (b) the at least one particulate support material is treated with at least one aluminium compound of general formula RnAlY3-n and (c) the at least one particulate support material is treated with the at least one aluminium compound of general formula RnAlY3-n and the at least one organomagnesium compound separately, the at least one pacifying agent may be added to the at least one particulate support material after it has been treated with the at least one organomagnesium compound and the at least one aluminium compound of general formula RnAlY3-n and before it is treated with the at least one transition metal compound of Groups IVA, VA or VIA and (ii) that where the at least one particulate support material is treated with two compounds selected from the compounds i, ii, iii or iv they are not exclusively an aluminium compound RnAlY3-n and an organometallic compound R?MXp.
i) an aluminium compound of the general formula:
RnAlY3-n wherein R, each of which may be the same or different, represents a hydrocarbyl group, or substituted hydrocarbyl group, such as alkyl, aryl, cycloalkyl, aralkyl, alkenyl or alkadienyl, n is 0, 1, 2, 3 or a fraction less than 3, and Y
is a singly charged ligand such as hydride, fluoride, chloride, bromide, iodide or oxyhydrocarbyl, ii) an organometallic compound of the general formula:
R?MXp wherein M is a metal of Groups IA, IIA, IIB, IIIB, IVA, VA or VIA of the Periodic Table, R1 is a hydrocarbyl or a substituted hydrocarbyl group, X is a singly charged anionic ligand or a mono-dentate neutral ligand, m is an integer up to the highest valency of the metal M and p is 0 or an integer up to 2 less than the valency of the metal M, except that when M is a metal from Group VIA, p is always 0, and m has a value from 2 to the highest valency of the metal, and when M is a metal from Groups IVA or VA m has a value from 2 to the highest valency of the metal and p has a value from 0 to a value of 2 less than the valency of the metal M, iii) a halogen containing compound and iv) a Lewis Base compound with the proviso (i) that the at least one particulate support material is treated with the at least one organo-magnesium compound, the at least one transition metal compound of Groups IVA, VA or VIA and one or more of the compounds i, ii, iii or iv prior to being treated with the at least one pacifying agent, which is capable of breaking metal-carbon or metal-hydrogen bonds in the catalyst component but does not have a deleterious effect on the catalyst component and which is used in sufficient quantity to break substantially all of said bonds, except that where (a) the at least one pacifying agent is a hydrogen halide, (b) the at least one particulate support material is treated with at least one aluminium compound of general formula RnAlY3-n and (c) the at least one particulate support material is treated with the at least one aluminium compound of general formula RnAlY3-n and the at least one organomagnesium compound separately, the at least one pacifying agent may be added to the at least one particulate support material after it has been treated with the at least one organomagnesium compound and the at least one aluminium compound of general formula RnAlY3-n and before it is treated with the at least one transition metal compound of Groups IVA, VA or VIA and (ii) that where the at least one particulate support material is treated with two compounds selected from the compounds i, ii, iii or iv they are not exclusively an aluminium compound RnAlY3-n and an organometallic compound R?MXp.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8000889 | 1980-01-10 | ||
| GB8000889 | 1980-01-10 | ||
| GB8018583 | 1980-06-06 | ||
| GB8018583 | 1980-06-06 |
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| CA1155828A true CA1155828A (en) | 1983-10-25 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000368287A Expired CA1155828A (en) | 1980-01-10 | 1981-01-12 | Olefin polymerization catalyst |
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| Country | Link |
|---|---|
| US (1) | US4324691A (en) |
| EP (1) | EP0032307A3 (en) |
| AU (1) | AU6593480A (en) |
| CA (1) | CA1155828A (en) |
| NZ (1) | NZ195950A (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3222296A (en) * | 1963-07-29 | 1965-12-07 | Cabot Corp | Lewis base stabilization of polymerization catalyst in storage |
| US3400110A (en) * | 1963-08-01 | 1968-09-03 | Solvay | Polymerization of olefins in the presence of a catalyst comprising an organometallic compound and the reaction product of a transition metal compound and a hydroxychloride of a bivalent metal |
| GB1256913A (en) * | 1969-01-30 | 1971-12-15 | ||
| DE2001183C3 (en) * | 1970-01-13 | 1980-01-31 | Chemische Werke Huels Ag, 4370 Marl | Process for interrupting and restarting olefin polymerizations |
| DE2603919C2 (en) * | 1976-02-03 | 1984-08-09 | Basf Ag, 6700 Ludwigshafen | Process for the preparation of homo- and copolymers of C 2 -to C 6 -α-monoolefins |
| JPS5373279A (en) * | 1976-12-13 | 1978-06-29 | Mitsubishi Chem Ind Ltd | Preparation of olefin polymer |
| US4250288A (en) * | 1977-02-03 | 1981-02-10 | The Dow Chemical Company | High efficiency, high temperature catalyst for polymerizing olefins |
| US4136058A (en) * | 1977-02-28 | 1979-01-23 | Arco Polymers, Inc. | High efficiency catalysts for olefin polymerization |
| US4135046A (en) * | 1977-02-28 | 1979-01-16 | Arco Polymers, Inc. | High efficiency catalysts for olefin polymerization |
| DE2721058C2 (en) * | 1977-05-11 | 1983-08-25 | Basf Ag, 6700 Ludwigshafen | Process for the preparation of homo- and copolymers of C? 2? - to C? 6? -? -Monoolefins |
| US4130699A (en) * | 1977-11-25 | 1978-12-19 | Standard Oil Company (Indiana) | Vapor phase polymerization with temporarily inactive titanium catalyst |
| US4154701A (en) * | 1978-05-01 | 1979-05-15 | Standard Oil Company (Indiana) | Olefin polymerization catalyst |
| DE2847757A1 (en) * | 1978-11-03 | 1980-05-14 | Basf Ag | METHOD FOR PRODUCING HOMOUND AND COPOLYMERISATS FROM ALPHA MONOOLEFINES |
-
1980
- 1980-07-01 US US06/164,928 patent/US4324691A/en not_active Expired - Lifetime
- 1980-12-22 EP EP80304676A patent/EP0032307A3/en not_active Withdrawn
- 1980-12-31 AU AU65934/80A patent/AU6593480A/en not_active Abandoned
-
1981
- 1981-01-06 NZ NZ195950A patent/NZ195950A/en unknown
- 1981-01-12 CA CA000368287A patent/CA1155828A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US4324691A (en) | 1982-04-13 |
| EP0032307A3 (en) | 1982-03-03 |
| EP0032307A2 (en) | 1981-07-22 |
| NZ195950A (en) | 1983-07-15 |
| AU6593480A (en) | 1981-07-16 |
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Legal Events
| Date | Code | Title | Description |
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| MKEX | Expiry |