CA1139048A - Polyester resin granules and process - Google Patents
Polyester resin granules and processInfo
- Publication number
- CA1139048A CA1139048A CA000366153A CA366153A CA1139048A CA 1139048 A CA1139048 A CA 1139048A CA 000366153 A CA000366153 A CA 000366153A CA 366153 A CA366153 A CA 366153A CA 1139048 A CA1139048 A CA 1139048A
- Authority
- CA
- Canada
- Prior art keywords
- granules
- polyester resin
- polyester
- water
- base
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
- C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
- C08F299/04—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyesters
- C08F299/0407—Processes of polymerisation
- C08F299/0414—Suspension or emulsion polymerisation
Abstract
ABSTRACT OF THE INVENTION
This invention relates to a process of preparing aqueous slurries of vesiculated granules of crosslinked polyester resin wherein the granules have a maximum shrinkage on drying of 5% of the granule diameter.
Previously-known processes for the preparation of granules of this type have utilised polyamines; this has led to odour and colour problems. These problems may be eliminated or substantially reduced by the use of bases which are metal oxides, hydroxides or salts wherein the metal cation is selected from Ca, Mg, Ba, Ti, Zn, Pb, Sr and Co and, when a metal salt is used, the pKa value of the conjugate acid of the anion is greater than 2.
The resulting granules are useful as matting and opacifying agents in, fur example, paint compositions.
This invention relates to a process of preparing aqueous slurries of vesiculated granules of crosslinked polyester resin wherein the granules have a maximum shrinkage on drying of 5% of the granule diameter.
Previously-known processes for the preparation of granules of this type have utilised polyamines; this has led to odour and colour problems. These problems may be eliminated or substantially reduced by the use of bases which are metal oxides, hydroxides or salts wherein the metal cation is selected from Ca, Mg, Ba, Ti, Zn, Pb, Sr and Co and, when a metal salt is used, the pKa value of the conjugate acid of the anion is greater than 2.
The resulting granules are useful as matting and opacifying agents in, fur example, paint compositions.
Description
This invention relates to an improved process of preparing vesiculated polyester resin gran~les.
The techni~ue of preparing porous articles from carboxylated, unsatura~ed polyester resin by emulsifying water into the polyester resin in the presence of a base and then polymerising th~ resin has been known for some time. For example 7 Will 9 in German Auslegeschrift 1,220,606, discloses such a process~u~ing bases such as sodium, potassium and calcium hydroxidesJ ammonia and magnesium oxide to react ~ith and neutralise the carboxyl groups of the polyester. An extension of ~his tech~ique is the preparation of '~double emulsions", that is, emulsions wherein the disperse phase is itself an emulsion.
15 An example o this can be fou~d in United States Pa~ent No.3,255,137 where von Bonin and Bartl prepare porous polymeric materials which can be readily worked up industri~lly by dispersin~ water in a polymerisable liquid, dispersing the resulting emulsion i~ water and polymerising the liquid. For the stabilisation of the initial water-in-oil emulsion, von Bonin asserts that "there are in principle sui~able all those emulsifiers which can be used for the production o~
reversed emulsions " o~ the particular polymerisable liquid used.USP 3,255,127 lists a substantial number of emulsifiers, including fatty acid salts of alkaline earth metals.
Ihis was the state of the art when United States Patent No.3,822,224 issued. In this patent, Kershaw and Gillan describe a proeess of preparing vesiculated polyester resin granules by dispersing a selected styrene solution of carboxylated unsaturated polyester resin in an aqueous continuous phase in the presence of a selec-ted base. Here, the vesicles ~ormed spontaneously within the granules. However, if it was desired to include pigment within the granules, a particularly convenient way was to use a double emulsion process, which involved the dispersion of pigment in water, the dispersion of the pigment dispersion into the polyester solution to give an emulsion of pigment dispersion in polyester) and the dispersion of this emulsion into the base-containing aqueous phase. For the specialised purposes of this invention, the teachin~s of Will and von Bonin, which placed no restriction on the types o ~olyester or base, were inadequate; the polyester had to have an acid value falling within a specific range and the base had to be a strong base with a dissociation exponent of less than 8. Typical bases included sodium, lithium, potassium and ammonium hydroxides.
Granules of this type were useful for many purposes, bu~ in some applications, the fact that these granules shrank on drying gave rise to unacceptable deects. This was very noticeable in paint compositions comprising such granules - ilms ~ormed from such paint compositions often cracked on drying.
This problem was overcome by Gunning, Henshaw and L.ubbock in IJnited States Patent No. 3,879,314.
In this patent Gunning found that granule shrinkage could be reduced to an acceptable level by a careful selection of both polyester acid value and base type.
The bases which could be used in this invention were water-soluble polyamines having at least three amine groups per polyamine molecule and a pKa value oE
between 8.5 and 10.5, suitable examples being diethylene triamine and triethylene tetramine. ~unning shows conclusively in Example III of USP 3,879,314 that only amines h~ving these characteristics will work; bases such as ammonia and triethanolamine which were favoured by the abovementioned prior art will not give the desired results. In this patent, the amine appears to perorm a dual function; it stabilises the initial water-in-oil emulsion and it forms part of a redox curing system. The "dimension-ally stable" granules produced by the process accordingto USP 3 l 879, 314 are satisfactory for use as opacifying agents in coating compositions and such compositions have been commercially acceptable.
However, these granules are not without their drawbacks.
For example, the amine imparts a yellowish colour to the granules and this is in turn imparted to coating compositions` in which they are incorporated. A
further disadvantage is the strong and often unpleasant odour of the amines; this is often detectable in the coating compositions and leads to some consumer resistance.
We have now found that it is possible to prepare dimensionally stable granules by a double emulsion process from which all the polyamine previously used or stabilisation can be eliminated. We the.refore provide, according to the present invention, a process of preparing an aqueous slurry of vesiculated granules of crosslinked polyester resin which granules are dimensionally stable as hereinunder defined, the process comprising the steps of ~ 8 - -- 5 ~
(a) emulsifying water into a solu~ion in essentially water-insoluble ~ ethyl-` enically unsaturated monomer of a carboxylated unsaturated polyester resin, in the presence of a base, to give a stable emulsion of water in polyester solution; ~
(b) dispersing this emulsion into water containing a stabilis.er for the resulting droplets of emulsion; and (c) initiating addition polymerisation within the droplets to convert them to cross-linked vesiculated polyester resin;
characterised in that ~5 ~i) the aeid value of the polyester is from 5-50 mg. KOH/g;
(ii) the base is a metal o~ide, hydroxide or salt wherein the metal cation is chosen from the group consisting of caleium, magnesium, barium, titanium, zinc, lead, strontium and cobalt and, where a metal salt is used, the pKa value of the conjugate acid o the anion is greater than 2; and (iii) the base is present to the extent o~
from 0.3 equivalents of metal cation per equivalent of polyester carboxyl group to that quantity required for the complete neutralisation of all the carboxyl groups.
We further provide an aqueous slurry of dimensionally stable vesiculated granules of crosslinked polyester resin, prepared by the abovementioned process.
Granules prepared by the process according to this invention ha~e the advantage of being amine-free, and they are thus free from the cons~quen~
discolouring effects and odour. Coating compositions 5 comprising such granules have "cleaner" colours and no unpleasant amine odour. Amines may be used in the curing stage (as hereinunder described) but ~he quantity involved here is very small compared to the quantities formerly required for stabilisation of water in the 10 solution in Monomer of the polyester resin.
By "dimensionally stable" granules, we mPan granules which on drying exhibit a shrinkage in diameter of not more than 5% of the diameter of the "wet"
granule. This is measured microscopically by the 15 method described in the specification of USP 3,879,314, the disclosures of which are incorporated herein by reference.
Carbox~lated unsaturated polyester resins which will cross-link by reaction with unsaturated 20 monomers are well known. Suitable polyester resins are the condensation products of dicarboxylic acids (or their corresponding anhydrides) and dihydric alcohols, polymerisable unsaturation being introduced into the chain by the use of a proportion o ~, ~-e-thyl-25 enically unsaturated acid.
The polyester resins from which a selectionis made are condensation products o~ polybasic acids (or the corresponding anhydrides) and dihydric alcohols.
Polymerisable unsaturation is introduced into the 30 molecule by the seleetion of an ~ ethylenically unsaturated acid, optionally in combinatlon with a saturated acid or anhydride.
Thu~ suitable acids are, for example:
unsaturated aliphatic acids, e.g.
maleicr fumaric and ita~.onic acids;
saturated aliphatic acids, e.g.
malonic, succinic, glutaric, adipic, pimelic, azelaic, ~etrahydrophthalic, chlorendic and sebacic acids; and saturated aromatic acids, e.g. phthalic~
isophthalic, terephthalic, tetra-1~ chlorophthalic, trimallitic and trimesic.
Suitable dihydric alcohols are chosen from, for example, ethyle~e glycol, poly~ethylene glycols) e.g.
diethylene glycol, hexane 1, 6-diol, propylene glycol, di-cyclohexanol and neopentyl glycol. Alternatively, the alcohol may be one which initially contained three or more hydroxyl groups, the groups in e~cess of ~w~
optionally being at least in part etheri~ied with, for example, a monohydric alcohol e.g. methanol, ethanol and n-bu~anol or esteriied with a monobasic acid, e.g. benzoie acid1 p tert.-butyl benzoic acld and chain-like aliphatic acids o~ up to 18 carbon a~om~
chain lengt~ e.~. coconut oil monoglyceride.
The methods by which unsaturat~d polyesters o~
this type are ~ormulated and made are well known in the art.
It is essential to the wor~ing of our invention that the acid v~lue of the polyes~er lie within certain limits. We have ound it essential to select poly-esters whose acid values lie in the range 5~50 mg K0~ /g, prefera~ly 10-25 mg KOH/g.
The unsa~urated monomer in which the unsaturated polyester resin is dissolved and crosslinked must be essen~ially wa~er~insoluble. Monomers which have a solubility at 20C of less than 5~/O (w/w) in wa~er are 5 considered to be sui~ably water-insoluble for our purpose. A single monomer or a mixture of monomers may be used and in general the monomer will contain only a single polymerisable double bond. However, it is known that poly-functional monomers, that is,monomers con~aining more than one polymerisable dou~le bond, are also used to cross-link unsaturated polyester resins. Such poly-functional monomers are, however, normally presen~ only as a minor constituent of a mixture of monom~rs, the major proportion of w~ich is mono~unctional monomer.
Hence mixtures comprising e.g. divinyl benzene may be used in the performance o~ our invention.
-The preferred ethylenically unsaturated monomers for general use in our proce~s are selected ~rom styrene, the mixed isomers of methyl styrene commercially available as 'vinyl toluene' and methyl methacrylate, because o~
the ease with which they can be copolymerised with the unsaturated polyester resin. For the best results, we prefer that the monomer shall comprise a~ least 50%
by weigh~ o~ styrene.
The cholce o~ monomer iq not, however, restricted to t~e above monomers alonc. Bearing in mind the requiremen~s that the total monomer ~ust be Pssentially insoluble in water and also be a solvent for the unsaturated polyester resin, there may be presen~ in a 30 minor proportion other polymerisable unsaturated monomers to, ~or e~ample, modify the physical properties o~ the coreacted resins. Typical co-monomers are, for example, ethyl acrylate~ n-butyl metha~rylate, acrylo-v~
nitrile, and triallyl cyanurate. In general, we have found that the upper limit of usefulness of ~u~h monomers in 10% by weight based on the total monomer used. Higher concentrations give granules which are either ~oo bri~tle or too rubbery to be used effectively in paint~.
Op~ionally a few percent by weight of a non-polymerising organic liquid, e.g. n-butanol or toluene, may be mixed with the monomer to increase the solubility of the polyester resin therein or may be ~ntroduced as an incidental part of ~he process, e.g. in preparing the polyester.
The initial stage in the preparation o~
dimensionall~ s~able granules according to the present invention is the emulsification o~ water into the solution in ethylenically unsaturated monomer of carboxylated unsaturated polyester (the solution in ethylenically unsaturated monomer o carboxylated unsaturated polyester resin shall hereina~er be referred to as "the polyester solution" and the emulsion of water in the polyester solution shall hereinater be referred to as "the first emulsion").
This is carried out by mechanic~l agitation which i5 continued until the disperse w~er droplets are approximately the size of the desired vesicles. The agitation is carried out i7L~ the presence of a base which may be present in the polyester solution, the water or both. The base is a metal oxide, hydroxide or salt, wherein the metal is cnosen from the group consisting of calcium, magnesi~lm, barium, titanium, zinc, lead, strontium and cobalt. We believe, without restricting our invention in any way,that the stabilisation of the disperse water phase in the polyester solution is achieved by an acid-base interac~ion of the 'oase with the carboxyl groups of the polyester resin. The bases of our invention must thus be capable of participating in such an i.nteraction, and any metal oxide, hydroxide or salt which does not is not a base for the purposes of this invention. One particular example of ~his is titanium dioxide which, although satisfac~ory for use in its hydrated (titanium hydroxide) form, does not work in its anhydrous (titanium dioxide) form. Where a metal salt is used9 the pKa value of the conjugate acid of the anion must be greater than 2. Thus, a metal salt having an anion the coniugate acid of which has a pKa value of less than 2, for exam~le calcium sulphate and magnesium chloride, will not work in our invention. Compounds which are bases for the purposes of our invention include titanium hydroxide, calcium hydroxide, zinc oxide, calcium carbonate, cobalt aytenate, barium hydroxide, strontium carbonate and basic lead carbonate.
We have found that, for our purposes, magnesium oxide gives the best resul~s and this is our preferred base.
The base should be present in the quantity o from 0.3 e~uivalents of metal cation per equivalent of carboxyl group to that quantity required ~or complete neutralisation of the carboxyl groups.
If it is required that the granules be pigmented, the pigment may be dispersed in the polyester solution prior to the emulsification of water therein, or into the water to be emulsified therein or into both, the pigmentation of the water being an especially convenient method. Pigmentation may be carried out using methods and dispersing agents known to the art. The pigment may be a primary white opacifying pigmen~ such as titanium dioxide or it may be selec~ed from the wide range of coloured pigments used by the art. I~ may also be an extender pigment such as mica, clay or chalk. A
further method of pigmentation ls the addition of base in excess of the quantity needed for complete neutral-isation of the carboxyl groups of the polyester resin.All of the bases of our invention are capable of acting as extenders and some of them, for example, zinc oxide, are primary opacifying pigments in their own right. Thus, the addition of a quanti~y of base in excess of that required for the complete neutralisation of the carboxyl groups ~or ~he pu-cpose of pigmentation is encompassed by our invention.
The first emulsion is dispersed in water which contains a stabiliser for the dispersed first emulsion particles and stirred until the desired granule size is achieved. The stabiliser may be chosen ~rom the wide range of materials known to be suitable for this purpose but we have found that an especially suitable material is a water-soluble partially hydrolysed poly(vinyl acetate) with a molecular weight - of about 100,000 and a degree of hydrolysis of 85-90%. As a general guide, we have found that a concentration of stabiliser of the order of 0.1-1.0%
by weight of the water gives satisfactory results.
An increase in the viscosity o~ the water can often assist in the dispersion of the emulsion; such an increase can be achieved by the addi~ion to ~he water of a water-soluble polymeric thickener.
Suitable thickeners are well known to the art and include such compounds as hydroxyethyl cellulose, typically used at a concentration of about 0.3% by weight of the water phase.
Pol~merisa~ion of the polyester resin is e~ected by free radical means. Thi8 can be achieved by the use of a free radical initiator such as an organic peroxide or by exposure to a radiation source such as ultra-violet radiation or a radio-active element. When a ~ree radical initiator is used it is convenien~ly dissolved in the polyester resin solution before the dispersion of the solution in water. Our preferred initiation system is a redox system of diethylene triamine and cumene hydroperoxide triggered by ferrous ions derived from ferrous sulphate.
The aqueous slurry o vesiculated polyester - granules thus formed may be used directly in an aqueous latex paint, or it may be used directly in an aqueous latex paint, or it may be dewatered, by any convenient means, for example the method described in United Sta~es Patent No.4,154~923, and subsequently redispersed in an aqueous or non-aqueous medium, or .incorporated into a paste, for example, for use as a filler or a putty.
The beads prepared by the process o this invention are often noticeably whi~er tha~ those prepared by k~own methods, 2nd paints incorporatin~ them exhibi~ ~his improvement in whiteness. This i8 trtle e~en of beads where a qalt such as cobalt naPhthenate has been used -cobalt naphthenate imparts a very slight violet tinge tothe beads, but this is not noticeable in a paint film _ 13 -comprising such beads and even helps to give an impression of increased whiteness by imparting to the observer a distinct impression o non-yellowness.
The invention is illustrated by the ~ollowing example in which all parts are expressed by weight.
Preparation of 25 ~m pigmented, vesiculated poIyester resin granules using magnesium oxide base.
The following materials and quantities were used;
Parts A water 3.088 surfactantl 1.595 anti~oam ("Bevaloid" 60 ex Richard 0.016 Hodgson) B titanium dioxide pigment 10.601 ("Tioxide" RHD 6 ex Tioxide International Ltd.) C water 1.029 D polyester2 8.686 styrene 4.817 magnesium oxide 0.045 E water 1.647 F hydroxy ethyl cellulose solution34.117 poly(vinyl alcohol) solution4 6.175 surfactant ("Aerosol" M~ ex American 0.103 water C~anamid Co.) 32.934 G water 24.701 H cumene hydroperoxide 0.206 diethylene ~riaminP 0.051 ~errous sulphate 0.003 5 I bactericide ("Proxel" PL ex IC~ Australia Ltd.) 0.021 o. 9 ammonia sGlution O .165 1 A 33% wt. solids aqueous solution of a styrene-maleic anhydride resin (SMA 1440A ex Sinclair Petrochemicals, Inc.) neutralised wi~h 2-amino-
The techni~ue of preparing porous articles from carboxylated, unsatura~ed polyester resin by emulsifying water into the polyester resin in the presence of a base and then polymerising th~ resin has been known for some time. For example 7 Will 9 in German Auslegeschrift 1,220,606, discloses such a process~u~ing bases such as sodium, potassium and calcium hydroxidesJ ammonia and magnesium oxide to react ~ith and neutralise the carboxyl groups of the polyester. An extension of ~his tech~ique is the preparation of '~double emulsions", that is, emulsions wherein the disperse phase is itself an emulsion.
15 An example o this can be fou~d in United States Pa~ent No.3,255,137 where von Bonin and Bartl prepare porous polymeric materials which can be readily worked up industri~lly by dispersin~ water in a polymerisable liquid, dispersing the resulting emulsion i~ water and polymerising the liquid. For the stabilisation of the initial water-in-oil emulsion, von Bonin asserts that "there are in principle sui~able all those emulsifiers which can be used for the production o~
reversed emulsions " o~ the particular polymerisable liquid used.USP 3,255,127 lists a substantial number of emulsifiers, including fatty acid salts of alkaline earth metals.
Ihis was the state of the art when United States Patent No.3,822,224 issued. In this patent, Kershaw and Gillan describe a proeess of preparing vesiculated polyester resin granules by dispersing a selected styrene solution of carboxylated unsaturated polyester resin in an aqueous continuous phase in the presence of a selec-ted base. Here, the vesicles ~ormed spontaneously within the granules. However, if it was desired to include pigment within the granules, a particularly convenient way was to use a double emulsion process, which involved the dispersion of pigment in water, the dispersion of the pigment dispersion into the polyester solution to give an emulsion of pigment dispersion in polyester) and the dispersion of this emulsion into the base-containing aqueous phase. For the specialised purposes of this invention, the teachin~s of Will and von Bonin, which placed no restriction on the types o ~olyester or base, were inadequate; the polyester had to have an acid value falling within a specific range and the base had to be a strong base with a dissociation exponent of less than 8. Typical bases included sodium, lithium, potassium and ammonium hydroxides.
Granules of this type were useful for many purposes, bu~ in some applications, the fact that these granules shrank on drying gave rise to unacceptable deects. This was very noticeable in paint compositions comprising such granules - ilms ~ormed from such paint compositions often cracked on drying.
This problem was overcome by Gunning, Henshaw and L.ubbock in IJnited States Patent No. 3,879,314.
In this patent Gunning found that granule shrinkage could be reduced to an acceptable level by a careful selection of both polyester acid value and base type.
The bases which could be used in this invention were water-soluble polyamines having at least three amine groups per polyamine molecule and a pKa value oE
between 8.5 and 10.5, suitable examples being diethylene triamine and triethylene tetramine. ~unning shows conclusively in Example III of USP 3,879,314 that only amines h~ving these characteristics will work; bases such as ammonia and triethanolamine which were favoured by the abovementioned prior art will not give the desired results. In this patent, the amine appears to perorm a dual function; it stabilises the initial water-in-oil emulsion and it forms part of a redox curing system. The "dimension-ally stable" granules produced by the process accordingto USP 3 l 879, 314 are satisfactory for use as opacifying agents in coating compositions and such compositions have been commercially acceptable.
However, these granules are not without their drawbacks.
For example, the amine imparts a yellowish colour to the granules and this is in turn imparted to coating compositions` in which they are incorporated. A
further disadvantage is the strong and often unpleasant odour of the amines; this is often detectable in the coating compositions and leads to some consumer resistance.
We have now found that it is possible to prepare dimensionally stable granules by a double emulsion process from which all the polyamine previously used or stabilisation can be eliminated. We the.refore provide, according to the present invention, a process of preparing an aqueous slurry of vesiculated granules of crosslinked polyester resin which granules are dimensionally stable as hereinunder defined, the process comprising the steps of ~ 8 - -- 5 ~
(a) emulsifying water into a solu~ion in essentially water-insoluble ~ ethyl-` enically unsaturated monomer of a carboxylated unsaturated polyester resin, in the presence of a base, to give a stable emulsion of water in polyester solution; ~
(b) dispersing this emulsion into water containing a stabilis.er for the resulting droplets of emulsion; and (c) initiating addition polymerisation within the droplets to convert them to cross-linked vesiculated polyester resin;
characterised in that ~5 ~i) the aeid value of the polyester is from 5-50 mg. KOH/g;
(ii) the base is a metal o~ide, hydroxide or salt wherein the metal cation is chosen from the group consisting of caleium, magnesium, barium, titanium, zinc, lead, strontium and cobalt and, where a metal salt is used, the pKa value of the conjugate acid o the anion is greater than 2; and (iii) the base is present to the extent o~
from 0.3 equivalents of metal cation per equivalent of polyester carboxyl group to that quantity required for the complete neutralisation of all the carboxyl groups.
We further provide an aqueous slurry of dimensionally stable vesiculated granules of crosslinked polyester resin, prepared by the abovementioned process.
Granules prepared by the process according to this invention ha~e the advantage of being amine-free, and they are thus free from the cons~quen~
discolouring effects and odour. Coating compositions 5 comprising such granules have "cleaner" colours and no unpleasant amine odour. Amines may be used in the curing stage (as hereinunder described) but ~he quantity involved here is very small compared to the quantities formerly required for stabilisation of water in the 10 solution in Monomer of the polyester resin.
By "dimensionally stable" granules, we mPan granules which on drying exhibit a shrinkage in diameter of not more than 5% of the diameter of the "wet"
granule. This is measured microscopically by the 15 method described in the specification of USP 3,879,314, the disclosures of which are incorporated herein by reference.
Carbox~lated unsaturated polyester resins which will cross-link by reaction with unsaturated 20 monomers are well known. Suitable polyester resins are the condensation products of dicarboxylic acids (or their corresponding anhydrides) and dihydric alcohols, polymerisable unsaturation being introduced into the chain by the use of a proportion o ~, ~-e-thyl-25 enically unsaturated acid.
The polyester resins from which a selectionis made are condensation products o~ polybasic acids (or the corresponding anhydrides) and dihydric alcohols.
Polymerisable unsaturation is introduced into the 30 molecule by the seleetion of an ~ ethylenically unsaturated acid, optionally in combinatlon with a saturated acid or anhydride.
Thu~ suitable acids are, for example:
unsaturated aliphatic acids, e.g.
maleicr fumaric and ita~.onic acids;
saturated aliphatic acids, e.g.
malonic, succinic, glutaric, adipic, pimelic, azelaic, ~etrahydrophthalic, chlorendic and sebacic acids; and saturated aromatic acids, e.g. phthalic~
isophthalic, terephthalic, tetra-1~ chlorophthalic, trimallitic and trimesic.
Suitable dihydric alcohols are chosen from, for example, ethyle~e glycol, poly~ethylene glycols) e.g.
diethylene glycol, hexane 1, 6-diol, propylene glycol, di-cyclohexanol and neopentyl glycol. Alternatively, the alcohol may be one which initially contained three or more hydroxyl groups, the groups in e~cess of ~w~
optionally being at least in part etheri~ied with, for example, a monohydric alcohol e.g. methanol, ethanol and n-bu~anol or esteriied with a monobasic acid, e.g. benzoie acid1 p tert.-butyl benzoic acld and chain-like aliphatic acids o~ up to 18 carbon a~om~
chain lengt~ e.~. coconut oil monoglyceride.
The methods by which unsaturat~d polyesters o~
this type are ~ormulated and made are well known in the art.
It is essential to the wor~ing of our invention that the acid v~lue of the polyes~er lie within certain limits. We have ound it essential to select poly-esters whose acid values lie in the range 5~50 mg K0~ /g, prefera~ly 10-25 mg KOH/g.
The unsa~urated monomer in which the unsaturated polyester resin is dissolved and crosslinked must be essen~ially wa~er~insoluble. Monomers which have a solubility at 20C of less than 5~/O (w/w) in wa~er are 5 considered to be sui~ably water-insoluble for our purpose. A single monomer or a mixture of monomers may be used and in general the monomer will contain only a single polymerisable double bond. However, it is known that poly-functional monomers, that is,monomers con~aining more than one polymerisable dou~le bond, are also used to cross-link unsaturated polyester resins. Such poly-functional monomers are, however, normally presen~ only as a minor constituent of a mixture of monom~rs, the major proportion of w~ich is mono~unctional monomer.
Hence mixtures comprising e.g. divinyl benzene may be used in the performance o~ our invention.
-The preferred ethylenically unsaturated monomers for general use in our proce~s are selected ~rom styrene, the mixed isomers of methyl styrene commercially available as 'vinyl toluene' and methyl methacrylate, because o~
the ease with which they can be copolymerised with the unsaturated polyester resin. For the best results, we prefer that the monomer shall comprise a~ least 50%
by weigh~ o~ styrene.
The cholce o~ monomer iq not, however, restricted to t~e above monomers alonc. Bearing in mind the requiremen~s that the total monomer ~ust be Pssentially insoluble in water and also be a solvent for the unsaturated polyester resin, there may be presen~ in a 30 minor proportion other polymerisable unsaturated monomers to, ~or e~ample, modify the physical properties o~ the coreacted resins. Typical co-monomers are, for example, ethyl acrylate~ n-butyl metha~rylate, acrylo-v~
nitrile, and triallyl cyanurate. In general, we have found that the upper limit of usefulness of ~u~h monomers in 10% by weight based on the total monomer used. Higher concentrations give granules which are either ~oo bri~tle or too rubbery to be used effectively in paint~.
Op~ionally a few percent by weight of a non-polymerising organic liquid, e.g. n-butanol or toluene, may be mixed with the monomer to increase the solubility of the polyester resin therein or may be ~ntroduced as an incidental part of ~he process, e.g. in preparing the polyester.
The initial stage in the preparation o~
dimensionall~ s~able granules according to the present invention is the emulsification o~ water into the solution in ethylenically unsaturated monomer of carboxylated unsaturated polyester (the solution in ethylenically unsaturated monomer o carboxylated unsaturated polyester resin shall hereina~er be referred to as "the polyester solution" and the emulsion of water in the polyester solution shall hereinater be referred to as "the first emulsion").
This is carried out by mechanic~l agitation which i5 continued until the disperse w~er droplets are approximately the size of the desired vesicles. The agitation is carried out i7L~ the presence of a base which may be present in the polyester solution, the water or both. The base is a metal oxide, hydroxide or salt, wherein the metal is cnosen from the group consisting of calcium, magnesi~lm, barium, titanium, zinc, lead, strontium and cobalt. We believe, without restricting our invention in any way,that the stabilisation of the disperse water phase in the polyester solution is achieved by an acid-base interac~ion of the 'oase with the carboxyl groups of the polyester resin. The bases of our invention must thus be capable of participating in such an i.nteraction, and any metal oxide, hydroxide or salt which does not is not a base for the purposes of this invention. One particular example of ~his is titanium dioxide which, although satisfac~ory for use in its hydrated (titanium hydroxide) form, does not work in its anhydrous (titanium dioxide) form. Where a metal salt is used9 the pKa value of the conjugate acid of the anion must be greater than 2. Thus, a metal salt having an anion the coniugate acid of which has a pKa value of less than 2, for exam~le calcium sulphate and magnesium chloride, will not work in our invention. Compounds which are bases for the purposes of our invention include titanium hydroxide, calcium hydroxide, zinc oxide, calcium carbonate, cobalt aytenate, barium hydroxide, strontium carbonate and basic lead carbonate.
We have found that, for our purposes, magnesium oxide gives the best resul~s and this is our preferred base.
The base should be present in the quantity o from 0.3 e~uivalents of metal cation per equivalent of carboxyl group to that quantity required ~or complete neutralisation of the carboxyl groups.
If it is required that the granules be pigmented, the pigment may be dispersed in the polyester solution prior to the emulsification of water therein, or into the water to be emulsified therein or into both, the pigmentation of the water being an especially convenient method. Pigmentation may be carried out using methods and dispersing agents known to the art. The pigment may be a primary white opacifying pigmen~ such as titanium dioxide or it may be selec~ed from the wide range of coloured pigments used by the art. I~ may also be an extender pigment such as mica, clay or chalk. A
further method of pigmentation ls the addition of base in excess of the quantity needed for complete neutral-isation of the carboxyl groups of the polyester resin.All of the bases of our invention are capable of acting as extenders and some of them, for example, zinc oxide, are primary opacifying pigments in their own right. Thus, the addition of a quanti~y of base in excess of that required for the complete neutralisation of the carboxyl groups ~or ~he pu-cpose of pigmentation is encompassed by our invention.
The first emulsion is dispersed in water which contains a stabiliser for the dispersed first emulsion particles and stirred until the desired granule size is achieved. The stabiliser may be chosen ~rom the wide range of materials known to be suitable for this purpose but we have found that an especially suitable material is a water-soluble partially hydrolysed poly(vinyl acetate) with a molecular weight - of about 100,000 and a degree of hydrolysis of 85-90%. As a general guide, we have found that a concentration of stabiliser of the order of 0.1-1.0%
by weight of the water gives satisfactory results.
An increase in the viscosity o~ the water can often assist in the dispersion of the emulsion; such an increase can be achieved by the addi~ion to ~he water of a water-soluble polymeric thickener.
Suitable thickeners are well known to the art and include such compounds as hydroxyethyl cellulose, typically used at a concentration of about 0.3% by weight of the water phase.
Pol~merisa~ion of the polyester resin is e~ected by free radical means. Thi8 can be achieved by the use of a free radical initiator such as an organic peroxide or by exposure to a radiation source such as ultra-violet radiation or a radio-active element. When a ~ree radical initiator is used it is convenien~ly dissolved in the polyester resin solution before the dispersion of the solution in water. Our preferred initiation system is a redox system of diethylene triamine and cumene hydroperoxide triggered by ferrous ions derived from ferrous sulphate.
The aqueous slurry o vesiculated polyester - granules thus formed may be used directly in an aqueous latex paint, or it may be used directly in an aqueous latex paint, or it may be dewatered, by any convenient means, for example the method described in United Sta~es Patent No.4,154~923, and subsequently redispersed in an aqueous or non-aqueous medium, or .incorporated into a paste, for example, for use as a filler or a putty.
The beads prepared by the process o this invention are often noticeably whi~er tha~ those prepared by k~own methods, 2nd paints incorporatin~ them exhibi~ ~his improvement in whiteness. This i8 trtle e~en of beads where a qalt such as cobalt naPhthenate has been used -cobalt naphthenate imparts a very slight violet tinge tothe beads, but this is not noticeable in a paint film _ 13 -comprising such beads and even helps to give an impression of increased whiteness by imparting to the observer a distinct impression o non-yellowness.
The invention is illustrated by the ~ollowing example in which all parts are expressed by weight.
Preparation of 25 ~m pigmented, vesiculated poIyester resin granules using magnesium oxide base.
The following materials and quantities were used;
Parts A water 3.088 surfactantl 1.595 anti~oam ("Bevaloid" 60 ex Richard 0.016 Hodgson) B titanium dioxide pigment 10.601 ("Tioxide" RHD 6 ex Tioxide International Ltd.) C water 1.029 D polyester2 8.686 styrene 4.817 magnesium oxide 0.045 E water 1.647 F hydroxy ethyl cellulose solution34.117 poly(vinyl alcohol) solution4 6.175 surfactant ("Aerosol" M~ ex American 0.103 water C~anamid Co.) 32.934 G water 24.701 H cumene hydroperoxide 0.206 diethylene ~riaminP 0.051 ~errous sulphate 0.003 5 I bactericide ("Proxel" PL ex IC~ Australia Ltd.) 0.021 o. 9 ammonia sGlution O .165 1 A 33% wt. solids aqueous solution of a styrene-maleic anhydride resin (SMA 1440A ex Sinclair Petrochemicals, Inc.) neutralised wi~h 2-amino-
2-methyl~propanol was used.
2 A 65% weight solids solution of a 3.11/1/4.73 (molar) umaric acid/phthalic anhydride/propylene glycol polyester in styrene was used.
2 A 65% weight solids solution of a 3.11/1/4.73 (molar) umaric acid/phthalic anhydride/propylene glycol polyester in styrene was used.
3 A 1.5% weigh~ solids aqueous solution of "Natrosol"*
250 HR (ex Hercules Powder Co.) was used.
250 HR (ex Hercules Powder Co.) was used.
4 A 7~5C/o weight solids aqueous solution o~ "Poval"*
224G (ex Kuraray Rayon) was used.
224G (ex Kuraray Rayon) was used.
5 A com~ercially-available 90%~ weight active ingredients. was used.
* trade mark The materials A were mixed and the pigment B added to A with stirring. Stirring was continued at high speed until the pigment was completely dispersed and the 5 water C was then added to give a millbase.
The materials D were mixed un~il the magnesiu~
oxid2 was completely dispersed and the wa~er E was then added to and emulsified into D with high speed mixing.
The millbase was added to this emulsion and similarly emulsified into it until the dispersed particles of millbase were about 1 ~ in diameter.
This is "the first emulsion".
The materials F were blended together and the first emLllsion added ~o it with high speed stirring, the stirring being continued until ~he globules of ~irst emulsion were 25 ~m in diameter. All but o~e part of the water G was added to this "double" emulsion.
The diethylene triamine and ferrous sulphate of H were slurried in 0.5 parts each of the water G and then the ma~erials H were added to the double emulsion in the ordPr shown above with suf~icient stirring ~o ineorporate them. Stirring was then discontinued and ~he mixture allowed to cure overnight.
Finally, the bactericide of I was added with stirring and the pH of the mixture adjusted to 8.5-9.5 with ammonia solution.
The final product was a 23.6% weight solids slurry of crosslinked polyester resin granules of 25 ~m maximum diameter. These were tested ~or shrinka~e by the method of USP 3,879,314 and were found to have a shrinkage of less than S~/O.
EX~MPL~ 2 Demons~ration o~ the use of other bases.
Example 1 was repeated except that the magnesiu~
oxide was substituted by a chemically equivalen~ quantity of o~e of the compounds in the following table:
- lG
Oxides ~ydro~ides Salts ___ (a) lead oxi~e (h) calci~l (n) calcium carbonate (b~ cobalt oxide hydroxide (o~ magnesium ~c) manganese (i) titanium carbonate dioxide hydroxide (p) magnesium sulphate (d) calcium oxide (j) barium (q) manganese chloride (e) zinc oxide hydroxide (r) co~alt aytenate (f) titanium (k) aluminium (s) aluminium sulphate dioxide hydroxide (t) magnesium ortho-10 (g) vanadium ~1) strontium phosphate pentoxide hydro~ide (u) ma~nesium acetate (m) ammonium ~v) basic lead hydroxide carbona~e (w) strontium carbonate Of ~hese preparations, those which utilised the following materials were found to give satisfactory granules w~ich passed the shrinkage testj Oxides Hydro~ides Salts (a) (h) (n) 20 (b) (i) (o) (d) (i) tr) (e) (~) (t) (u) (v) (w) The remaining preparations did not give granules because of failure to form a satisfactorily stable first emulsion or double emulsion. It can be seen from these results that on~y the metal cat;ons according to 30 the invention gave the desired results and that, when salts were used, only those salts whose conjugate acids had pKa values of greater than 2 gave the desired results.
:s~
EXAMPLE.3 Demonstration of the variation of the quantity o base present.
. In Example 1, O.4 equivalents of magnesium cation per equivalent of polyester carboxyl group was used. The preparation of Example 1 was repeat~d using ~he following quantities of magnesium oxide in place of those in that example;
Weight o MgO (par~s~ equivalents for equivalent of ~olyester carboxyl ~rou~
0.028 0.25 0.079 0.70 0.113 1.00 0.170 1.50 All of the preparations gave vesiculated granules with shrinkages of less than 5% excep~ for ~hat which utilised 0.25 equi~alents o ma~nesium cation per polyester carbo~yl group; in this case it was not possible to form a suitabl~ stable flrst emulsion.
EX~LE 4 Demonstration of the use o~ a number of different polyester re~ins.
Example 1 was repeated but using an identical weight of each of the following polyester resins;
(a) 374/2.46/0.792 propylene glycol/fumaric acid/
phthalic anhydride polyester, acid value 40;
(b) 4.4/1/2/1 propylene glycol/adipic acid/fumaric acid/
phthalic anhydride polyester, acid value 20; and (c) 5.9/3.1/1 propylene glycol/maleic acid/phthalie anhydride polyester, acid value 5.2.
All of the preparations gave vesicula~ed granules wi~h shrinkages of less than 5%.
1~ ~
Demonstration of the use of a variety of unsaturated monomers.
Example 1 was repeated, substituting the following unsaturated monomer for the 4.817 parts of styrene used in that example;
Monomer(s) Weight (parts) (a) styrene 2.408 methyl methacrylate 3.087 ~b) styrene 4.407 n-butyl methacrylate 0.410 Both preparations gave vesieulated granules with shrinkages of less than 5%1
* trade mark The materials A were mixed and the pigment B added to A with stirring. Stirring was continued at high speed until the pigment was completely dispersed and the 5 water C was then added to give a millbase.
The materials D were mixed un~il the magnesiu~
oxid2 was completely dispersed and the wa~er E was then added to and emulsified into D with high speed mixing.
The millbase was added to this emulsion and similarly emulsified into it until the dispersed particles of millbase were about 1 ~ in diameter.
This is "the first emulsion".
The materials F were blended together and the first emLllsion added ~o it with high speed stirring, the stirring being continued until ~he globules of ~irst emulsion were 25 ~m in diameter. All but o~e part of the water G was added to this "double" emulsion.
The diethylene triamine and ferrous sulphate of H were slurried in 0.5 parts each of the water G and then the ma~erials H were added to the double emulsion in the ordPr shown above with suf~icient stirring ~o ineorporate them. Stirring was then discontinued and ~he mixture allowed to cure overnight.
Finally, the bactericide of I was added with stirring and the pH of the mixture adjusted to 8.5-9.5 with ammonia solution.
The final product was a 23.6% weight solids slurry of crosslinked polyester resin granules of 25 ~m maximum diameter. These were tested ~or shrinka~e by the method of USP 3,879,314 and were found to have a shrinkage of less than S~/O.
EX~MPL~ 2 Demons~ration o~ the use of other bases.
Example 1 was repeated except that the magnesiu~
oxide was substituted by a chemically equivalen~ quantity of o~e of the compounds in the following table:
- lG
Oxides ~ydro~ides Salts ___ (a) lead oxi~e (h) calci~l (n) calcium carbonate (b~ cobalt oxide hydroxide (o~ magnesium ~c) manganese (i) titanium carbonate dioxide hydroxide (p) magnesium sulphate (d) calcium oxide (j) barium (q) manganese chloride (e) zinc oxide hydroxide (r) co~alt aytenate (f) titanium (k) aluminium (s) aluminium sulphate dioxide hydroxide (t) magnesium ortho-10 (g) vanadium ~1) strontium phosphate pentoxide hydro~ide (u) ma~nesium acetate (m) ammonium ~v) basic lead hydroxide carbona~e (w) strontium carbonate Of ~hese preparations, those which utilised the following materials were found to give satisfactory granules w~ich passed the shrinkage testj Oxides Hydro~ides Salts (a) (h) (n) 20 (b) (i) (o) (d) (i) tr) (e) (~) (t) (u) (v) (w) The remaining preparations did not give granules because of failure to form a satisfactorily stable first emulsion or double emulsion. It can be seen from these results that on~y the metal cat;ons according to 30 the invention gave the desired results and that, when salts were used, only those salts whose conjugate acids had pKa values of greater than 2 gave the desired results.
:s~
EXAMPLE.3 Demonstration of the variation of the quantity o base present.
. In Example 1, O.4 equivalents of magnesium cation per equivalent of polyester carboxyl group was used. The preparation of Example 1 was repeat~d using ~he following quantities of magnesium oxide in place of those in that example;
Weight o MgO (par~s~ equivalents for equivalent of ~olyester carboxyl ~rou~
0.028 0.25 0.079 0.70 0.113 1.00 0.170 1.50 All of the preparations gave vesiculated granules with shrinkages of less than 5% excep~ for ~hat which utilised 0.25 equi~alents o ma~nesium cation per polyester carbo~yl group; in this case it was not possible to form a suitabl~ stable flrst emulsion.
EX~LE 4 Demonstration of the use o~ a number of different polyester re~ins.
Example 1 was repeated but using an identical weight of each of the following polyester resins;
(a) 374/2.46/0.792 propylene glycol/fumaric acid/
phthalic anhydride polyester, acid value 40;
(b) 4.4/1/2/1 propylene glycol/adipic acid/fumaric acid/
phthalic anhydride polyester, acid value 20; and (c) 5.9/3.1/1 propylene glycol/maleic acid/phthalie anhydride polyester, acid value 5.2.
All of the preparations gave vesicula~ed granules wi~h shrinkages of less than 5%.
1~ ~
Demonstration of the use of a variety of unsaturated monomers.
Example 1 was repeated, substituting the following unsaturated monomer for the 4.817 parts of styrene used in that example;
Monomer(s) Weight (parts) (a) styrene 2.408 methyl methacrylate 3.087 ~b) styrene 4.407 n-butyl methacrylate 0.410 Both preparations gave vesieulated granules with shrinkages of less than 5%1
Claims (6)
1. A process of preparing an aqueous slurry of vesiculated granules of crosslinked polyester resin which granules have a maximum shrinkage on drying of 5% of the granule diameter, the process comprising the steps of (a) emulsifying water into a solution in essentially water-insoluble .alpha., .beta.-ethylenically unsaturated monomer of a carboxylated unsaturated polyester resin, in the presence of a base, to give a stable emulsion of water in polyester solution;
(b) dispersing this emulsion into water containing a stabiliser for the resulting droplets of emulsion; and (c) initiating addition polymerisation within the droplets to convert them to crosslinked vesiculated polyester resin;
characterised in that (i) the acid value of the polyester is from 5-50 mg KOH/g;
(ii) the base is a metal oxide, hydroxide or salt wherein the metal cation is chosen from the group consisting of calcium, magnesium, barium, titanium, zinc, lead, strontium and cobalt and, where a metal salt is used, the pKa value of the conjugate acid of the anion is greater than 2; and the base is present to the extent of from (iii) 0.3 equivalents of metal cation per equivalent of polyester carboxyl group to that quantity required for the complete neutralisation of all the carboxyl groups.
(b) dispersing this emulsion into water containing a stabiliser for the resulting droplets of emulsion; and (c) initiating addition polymerisation within the droplets to convert them to crosslinked vesiculated polyester resin;
characterised in that (i) the acid value of the polyester is from 5-50 mg KOH/g;
(ii) the base is a metal oxide, hydroxide or salt wherein the metal cation is chosen from the group consisting of calcium, magnesium, barium, titanium, zinc, lead, strontium and cobalt and, where a metal salt is used, the pKa value of the conjugate acid of the anion is greater than 2; and the base is present to the extent of from (iii) 0.3 equivalents of metal cation per equivalent of polyester carboxyl group to that quantity required for the complete neutralisation of all the carboxyl groups.
2. A process according to claim 1 characterised in that the base is magnesium oxide.
3. A process according to claim 1 characterised in that the acid value of the polyester resin is from 10-25 mg KOH/g.
4. A process according to claim 1 characterised in that the monomer comprises at least 50% by weight of styrene.
5. A process according to claim 1 characterised in that the granules comprise pigment.
6. An aqueous slurry of vesiculated granules prepared by a process according to claim 1.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPE164379 | 1979-12-07 | ||
| AUPE.1643 | 1979-12-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1139048A true CA1139048A (en) | 1983-01-04 |
Family
ID=3768377
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000366153A Expired CA1139048A (en) | 1979-12-07 | 1980-12-04 | Polyester resin granules and process |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US4321332A (en) |
| EP (1) | EP0041508B1 (en) |
| JP (1) | JPH0354127B2 (en) |
| AT (1) | ATE8645T1 (en) |
| AU (1) | AU533959B2 (en) |
| BE (1) | BE886501A (en) |
| BR (1) | BR8008969A (en) |
| CA (1) | CA1139048A (en) |
| DE (1) | DE3068731D1 (en) |
| DK (1) | DK160260C (en) |
| ES (1) | ES8200914A1 (en) |
| IE (1) | IE50478B1 (en) |
| IT (1) | IT1141122B (en) |
| NZ (1) | NZ195624A (en) |
| WO (1) | WO1981001711A1 (en) |
| ZA (1) | ZA807354B (en) |
| ZW (1) | ZW29780A1 (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA812512B (en) * | 1980-05-09 | 1982-04-28 | Tioxide Group Ltd | Bead polymerisation process |
| GB2112400B (en) * | 1981-12-30 | 1985-05-22 | Tioxide Group Plc | Production of vesiculated polymer beads |
| ZW17683A1 (en) * | 1982-08-10 | 1985-03-06 | Dulux Australia Ltd | Process of preparing vesiculated polyester granules |
| US4461849A (en) * | 1983-07-26 | 1984-07-24 | The Sherwin-Williams Company | Vesiculated beads |
| GB2229726B (en) * | 1989-03-04 | 1992-04-08 | Tioxide Group Plc | Polymer granules and compositions containing them |
| US5332473A (en) * | 1989-09-21 | 1994-07-26 | Ici Canada Inc. | Vesiculated polymer granules and paper made therefrom |
| GB9014689D0 (en) * | 1990-07-02 | 1990-08-22 | Tioxide Group Services Ltd | Supports for active entities |
| GB9308895D0 (en) * | 1993-04-29 | 1993-06-16 | Ici Plc | Vesicular polymer beads |
| US5583162A (en) * | 1994-06-06 | 1996-12-10 | Biopore Corporation | Polymeric microbeads and method of preparation |
| US5990183A (en) * | 1996-02-26 | 1999-11-23 | Reika Kogyo Kabushiki Kaisha | Porous particles, porous hollow particles and method of preparing such particles |
| US6048908A (en) | 1997-06-27 | 2000-04-11 | Biopore Corporation | Hydrophilic polymeric material |
| AUPR604001A0 (en) * | 2001-06-29 | 2001-07-26 | Orica Australia Pty Ltd | Vesiculated polyester granules |
| CA2500132C (en) | 2002-09-30 | 2011-02-15 | Barloworld Plascon S.A. (Pty) Limited | Vesiculated polymer particles |
| US8389645B2 (en) * | 2004-01-30 | 2013-03-05 | Duluxgroup (Australia) Pty Ltd. | Initiating system for solid polyester granule manufacture |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1420831B2 (en) | 1959-07-28 | 1972-04-20 | Will, Günther, Dr , 6100 Darmstadt | METHOD FOR MANUFACTURING POROUS SHAPED BODIES |
| GB1515915A (en) * | 1969-09-16 | 1978-06-28 | Ashland Oil Inc | Water-in-oil emulsions |
| US3852376A (en) * | 1972-02-03 | 1974-12-03 | Kuraray Co | Low shrinkage unsaturated polyester resin compositions containing graft copolymers |
| CH583273A5 (en) * | 1972-03-11 | 1976-12-31 | Basf Farben & Fasern | |
| CA1021090A (en) * | 1972-06-08 | 1977-11-15 | Raymond R. Hindersinn | Tack free polymerizable polyester compositions |
| AR206777A1 (en) * | 1972-11-13 | 1976-08-23 | Dulux Australia Ltd | PROCEDURE FOR PREPARING AQUEOUS SUSPENSION OF VESICULAR GRANULES OF POLYESTER RESIN RESICULARS OF RETAINED POLYESTER RESIN |
| DE2311395C3 (en) * | 1973-03-08 | 1983-12-22 | Basf Ag, 6700 Ludwigshafen | Production of hardenable polyester molding compounds with accelerated thickening |
| GB1476510A (en) * | 1973-07-24 | 1977-06-16 | Du Pont | Manufacture of vesiculated polymer granules |
| US3979342A (en) * | 1973-07-24 | 1976-09-07 | E. I. Du Pont De Nemours And Company | Manufacture of vesiculated polymer granules |
-
1979
- 1979-12-07 AU AU64622/80A patent/AU533959B2/en not_active Expired
-
1980
- 1980-11-24 AT AT80902269T patent/ATE8645T1/en not_active IP Right Cessation
- 1980-11-24 IE IE2433/80A patent/IE50478B1/en not_active IP Right Cessation
- 1980-11-24 DE DE8080902269T patent/DE3068731D1/en not_active Expired
- 1980-11-24 EP EP80902269A patent/EP0041508B1/en not_active Expired
- 1980-11-24 JP JP56500004A patent/JPH0354127B2/ja not_active Expired - Lifetime
- 1980-11-24 BR BR8008969A patent/BR8008969A/en not_active IP Right Cessation
- 1980-11-24 WO PCT/AU1980/000097 patent/WO1981001711A1/en active IP Right Grant
- 1980-11-24 NZ NZ195624A patent/NZ195624A/en unknown
- 1980-11-25 ZA ZA00807354A patent/ZA807354B/en unknown
- 1980-12-01 US US06/211,942 patent/US4321332A/en not_active Expired - Lifetime
- 1980-12-02 ZW ZW297/80A patent/ZW29780A1/en unknown
- 1980-12-04 CA CA000366153A patent/CA1139048A/en not_active Expired
- 1980-12-04 BE BE0/203049A patent/BE886501A/en not_active IP Right Cessation
- 1980-12-05 DK DK521380A patent/DK160260C/en not_active IP Right Cessation
- 1980-12-05 ES ES497496A patent/ES8200914A1/en not_active Expired
- 1980-12-05 IT IT26476/80A patent/IT1141122B/en active
Also Published As
| Publication number | Publication date |
|---|---|
| IE50478B1 (en) | 1986-04-30 |
| IT1141122B (en) | 1986-10-01 |
| IT8026476A0 (en) | 1980-12-05 |
| BE886501A (en) | 1981-04-01 |
| EP0041508A1 (en) | 1981-12-16 |
| US4321332A (en) | 1982-03-23 |
| IE802433L (en) | 1981-06-07 |
| NZ195624A (en) | 1982-12-21 |
| JPS56501731A (en) | 1981-11-26 |
| DK160260B (en) | 1991-02-18 |
| JPH0354127B2 (en) | 1991-08-19 |
| DK160260C (en) | 1991-08-05 |
| ES497496A0 (en) | 1981-11-16 |
| DE3068731D1 (en) | 1984-08-30 |
| AU533959B2 (en) | 1983-12-22 |
| BR8008969A (en) | 1981-10-20 |
| WO1981001711A1 (en) | 1981-06-25 |
| DK521380A (en) | 1981-06-08 |
| ES8200914A1 (en) | 1981-11-16 |
| ZW29780A1 (en) | 1982-06-30 |
| EP0041508A4 (en) | 1982-04-29 |
| EP0041508B1 (en) | 1984-07-25 |
| ZA807354B (en) | 1982-07-28 |
| AU6462280A (en) | 1981-09-24 |
| ATE8645T1 (en) | 1984-08-15 |
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