CA1128759A - Method and apparatus for generating a vapor stream - Google Patents

Method and apparatus for generating a vapor stream

Info

Publication number
CA1128759A
CA1128759A CA373,272A CA373272A CA1128759A CA 1128759 A CA1128759 A CA 1128759A CA 373272 A CA373272 A CA 373272A CA 1128759 A CA1128759 A CA 1128759A
Authority
CA
Canada
Prior art keywords
particles
jet
vaporizer
electrostatically
generating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA373,272A
Other languages
French (fr)
Inventor
Rama Iyengar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AT&T Corp
Original Assignee
Western Electric Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Western Electric Co Inc filed Critical Western Electric Co Inc
Application granted granted Critical
Publication of CA1128759A publication Critical patent/CA1128759A/en
Expired legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M27/00Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
    • F02M27/04Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by electric means, ionisation, polarisation or magnetism
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B17/00Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups
    • B05B17/04Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods
    • B05B17/06Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods using ultrasonic or other kinds of vibrations
    • B05B17/0607Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods using ultrasonic or other kinds of vibrations generated by electrical means, e.g. piezoelectric transducers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/08Plant for applying liquids or other fluent materials to objects
    • B05B5/14Plant for applying liquids or other fluent materials to objects specially adapted for coating continuously moving elongated bodies, e.g. wires, strips, pipes
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/012Manufacture of preforms for drawing fibres or filaments
    • C03B37/014Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
    • C03B37/018Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/44Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
    • C23C16/448Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for generating reactive gas streams, e.g. by evaporation or sublimation of precursor materials
    • C23C16/4486Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating characterised by the method used for generating reactive gas streams, e.g. by evaporation or sublimation of precursor materials by producing an aerosol and subsequent evaporation of the droplets or particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S261/00Gas and liquid contact apparatus
    • Y10S261/65Vaporizers

Abstract

METHOD AND APPARATUS FOR GENERATING A VAPOR STREAM

Abstract To generate and accurately and rapidly control the quantity of a vapor of a dielectric material, a jet of liquid particles of the material is formed, at least some of the particles are electrostatically charged, and the paths of different ones of the particles are electrostatically controlled for selecting a desired proportion of the particles of the jet which are vaporized within a vaporizer.

Description

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~ 1 -Method and a~paratus for generatin~ a vapor stream Technical Field This invention relates to methods and apparatuses for generating vapor streams.
Background of the Invention Vapor streams are today generated and utilized in a number of industrial applications. For example, in con-structing preforms from which optical fibers may ~e drawn, vapors of materials such as SiC14, GeC14, POC13 and BBr3 ar~ ~enerated and delivered to a preform ~onstruc-tion site where they are reacted and deposited in or on a support.
Vapor streams are also generated and utilized in internal combustion engines such as those used in powering motor vehicles. In this application a vapor stream is ordinarily created either by the use of carburetion or fuel injection systems.
A long term problem and limitation commonly associated with known described methods of generating vapor streams, however, has been that of accurately and rapidly con-trolling the mass flow rate of the vapor present within the vapor stream, and a need thus exists for means for generating vapor streams with enhanced control speed and accuracy in diverse fields of technology. Accordingly, it i5 to this general problem to which the present invention is primarily directed.

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-~LZ~3759 - la -According to the invention there is provided a method of generating a vapor stream characterized by providing a jet of electrostatically chargeable liquid particles, electrostatically charging at least some of said par-ticles, injecting at least some of said particles intoa vaporizer for said particles, and electrostatically controlling the proportion of particles from said jet which are vaporized within said vaporizer.
In one form of the invention, a jet of electro-statically chargeable liquid particles is provided which is electrostatically controlled for selectively metering some of the liquid particles into a vaporizer where the particles are vaporized.
In another form of the invention, all of the select-ively metered particles are injected into a carrier gas stream where the particles are vaporized.

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~ 2 --In another form of the invention the stream of electrostatically chargeable liquid droplets is introduced ; within a carrier gas stream, but only selected quantities of the droplets are allowed to remain within the stream long enough to become vaporized.
Brief Description oE the Drawiny The drawing is a schematic diagram of apparatus for generating a vapor stream in accordance with the invention.
Detailed Description ~ eferring to the drawing, there is schematically illustrated apparatus for generating a vapor stream which includes a conventional non-impact ink jet generator generally designated at 10. The jet generator includes an ultrasonic drop generator 12, a charge tunnel 14, and a pair of deflection plates lh and 16', such as those sold by the A. B. Dick Company of Elkgrove, Illinois, as their Part Nos. 339000-11, 339015 and 331312, respectively. For a detailed explanation of the generator and its operation reference may be made to the article by Kuhn and Myers titled "Ink-Jet Printing" in the April 1979 issue of Scientific American.
The ultrasonic drop generator, charge tunnel, and the deflection plate 1~ are each electrically coupled with control electronics while the deflection plate 16' is electrically grounded. The jet generator is positioned adjacent to a conduit 18 having an aperture 20 formed in its side Eacing and in direct line with the jet gerlerator.
A funnel 22 is located behind and slightly above the conduit and aperture. A drain tube 24 depends downwardly from the funnel and back to the ultrasonic drop generator 12 through unshown pump means. The jet generator 10 is housed within an enclosure through which conduit 18 extends.
In one application, the apparatus may be used for generating a vapor stream for use at an optical fiber preform construction site. In this application, the - . . - .

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'.~ 37S9 ultrasonic drop generator 12, rather than being filled with ink as it would be where used as a printer, is instead filled with a dielectric liquid (i.e., one which can be electrostatically charged) such as SiC14, GeC1~, POC13 or BBr3. Preferably, the dielectric liquid has a viscosity of less than 100 cps Eor efficient drop generation. For an internal combustion engine application, a liquid ~uel such as gasoline, ethyl alcohol or methyl alochol is instead supplied to the ultrasonic drop generator. A carrier gas, such as oxygen, helium or argon having a liquefaction temperature substantially lower than the boiling temperature of the dielectric liquid is then drawn through the conduit 18 for preform construction. ~ith the engine application air, comprised of oxygen and nitrogen, is instead drawn through the conduit. Since the jet generator is enclosed in a dead space about the aperture 12 the dead space itself will also be filled with the carrier gas. A
stream or jet of droplets is then generated and propelled towards the aperture 20 from the ultrasonic drop generator 12 at a selected, preferably constant rate, by a control signal transmitted over line 26 between the control electronics and the drop generator. A constant electrostatic potential is established across plates 16 and 16' by means of line 27. Digital signals are generated by the control electronics and applied to the charge tunnel 1 over line 28. During the application of a voltage to the tunnel 1~, the liquid droplets then passing there through become charged. In the intervals between the digital voltage pulses, the liquid droplets passing through the 3~ tunnel are not charged. Since only some of the droplets become charged, only some are deflected (upwardly, in this embodiment) as they pass through the electrostatic field between the deflection plates 16 and 16'. In this arrangement,only the uncharged and undeflected portions of the jet or train of droplets emitted by the ultrasonic drop generator are introduced into conduit 18 through aperture 20 where they vaporize. The charged portions of the jet .

~. :~ : : . . : : : ~

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are deflected by the charge plates 16 and 16' over -the conduit and into the funnel 22. These droplets then gravitate downwardly and illtO conduit 2~ to be pumped back to the drop generator 12.
The ratio of vapor to carrier gas ~ay be nonitored downstream withir) conduit 1~ so that deviatiorls Erom a desired ratio may be corrected by the control electronics. For example, should a sensecl ratio of vapor to carrier gas required to deliver a desired vapor mass flow rate to an optical fiber preform construction si-te at a given carrier gas flow rate deviate from that ratio desired, a correction signal may be fed back to the control electronics. Through conventional control circuitry the control electronics then adjusts the digital signal applied to the charge tunnel whereupon a greater or lesser portion of the jet is then injected into the carrier gas stream.
In an engine application such control signals would ordinarily be generated in response to throttle and engine cycle changes. A typical flow rate for constructing a pre~orm would be one liter of carrier gas per minute into which 400 milligrams of droplets are injected per minute and 400 milligrams of droplets recirculated per minute.
~ith an engine fuel application some 1~5 grams of fuel may be injected per minute into an airstream flowing at a rate of some 2180 grams per minute.
Since the dead space about aperture 20 is filled with the carrier gas, at startup some portion of the droplets may vaporize within the dead space. However, as this space becomes more saturated most of the jet will then pass through the dead space and enter the conduit with little loss due to transit vaporization. In any event system stabilization is rapidly achieved.
The apparatus just described may assume other forms. For example, rather than have a signal applied to the charge tunnel, a constant DC charge may be placed thereon to charge all of the liquid particles passing therethrough. In this case a signal, digital or analog/ is ::

,....... .

~2~3759 appli~d to the plate 16 to effect deflection of selected portions of the stream of droplets passing there-through.
Then too, the conduit aper-ture 20 may be loca~ec] either within the flight path of the charyed or the un~harged particles, or within the path of those charged particles which have or have not been deflected. That the collectec~
droplets within the funnel 22 are recirculated is, of course, also optional.
A further modification is to place the entire jet generator (10) within the conduit 18 so as to maintain one stream of droplets within the carrier gas stream for a sufficient time in which to be vaporized while directing other droplets within the jet out of the carrier gas stream as through an aperture in a conduit side before they have had sufficient time in which to become vaporized. In the embodiment illustrated, however, the droplets vaporize after passing through aperture 20 before striking the opposite wall of conduit 18. The time of transit across the inside of the conduit may be varied by alteration in the inside diameter of the conductor, the orientation of the conduit relative to the flight path of the droplets entering the conduit, or by changing the velocity of -the jet emitted by the drop generator. If desired, a group of generators may be employed so as to create mixtures of vapors with variable mixture ratio control.
In addition, it may not always be necessary that the droplets ~e propelled into a carrier gas. For example, the droplets may be metered into a vaporizer of the type having a hot plate. Upon striking the plate the droplets are vaporized and create pressure sufficient to cause a vapor stream to be emitted from the vaporizer.

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Claims (6)

Claims
1. A method of generating a vapor stream characterized by providing a jet of electrostatically chargeable liquid particles, electrostatically charging at least some of said particles, injecting at least some of said particles into a vaporizer for said particles, and electrostatically controlling the proportion of particles from said jet which are vaporized within said vaporizer.
2. A method according to claim 1 CHARACTERIZED IN THAT
the proportion of particles injected into said vaporizer is electrostatically controlled, all of said so injected particles being vaporized.
3. A method according to claim 1 CHARACTERIZED IN THAT
all of the particles of said jet are injected into said vaporizer, an electrostatically controlled proportion of said particles being ejected from said vaporizer prior to being vaporized.
4. A method according to anyone of claims 1 through 3 CHARACTERIZED IN THAT
a carrier gas is passed through said vaporizer.
5. Apparatus for generating a vapor stream characterized by a generator for generating a jet of electrostatically chargeable liquid particles, electrostatic means for charging at least some of said particles, vaporizing means for vaporizing particles therein, and electrostatic deflection means for controlling the proportion of the particles which are vaporized within said vaporizer.
6. Apparatus according to claim 5 CHARACTERIZED IN THAT
said deflection means is effective to control the proportion of particles which enter said vaporizer for vaporization therein.
CA373,272A 1980-04-02 1981-03-18 Method and apparatus for generating a vapor stream Expired CA1128759A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/136,597 US4310474A (en) 1980-04-02 1980-04-02 Method and apparatus for generating a vapor stream
US136,597 1980-04-02

Publications (1)

Publication Number Publication Date
CA1128759A true CA1128759A (en) 1982-08-03

Family

ID=22473525

Family Applications (1)

Application Number Title Priority Date Filing Date
CA373,272A Expired CA1128759A (en) 1980-04-02 1981-03-18 Method and apparatus for generating a vapor stream

Country Status (7)

Country Link
US (1) US4310474A (en)
JP (1) JPS56155668A (en)
CA (1) CA1128759A (en)
DE (1) DE3112882A1 (en)
FR (1) FR2479709B1 (en)
GB (1) GB2073442B (en)
IT (1) IT1137117B (en)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3326043A1 (en) * 1983-07-20 1985-02-07 Licentia Gmbh METHOD FOR PRODUCING A AEROSOL FLOW AND THE USE THEREOF
DE3522979A1 (en) * 1985-06-27 1987-01-02 Bayer Ag METHOD FOR PRODUCING ELECTRICALLY CHARGED SPRAY MIST FROM CONDUCTIVE LIQUIDS
US5086972A (en) * 1990-08-01 1992-02-11 Hughes Aircraft Company Enhanced electrostatic paint deposition method and apparatus
US5246166A (en) * 1991-09-30 1993-09-21 Her Majesty The Queen In The Right Of Canada As Represented By The Minister Of Forestry Spraying apparatus
JPH06240456A (en) * 1992-12-21 1994-08-30 Kawasaki Steel Corp Method and device for forming aluminum circuit of semiconductor device
US6325475B1 (en) 1996-09-06 2001-12-04 Microfab Technologies Inc. Devices for presenting airborne materials to the nose
US6339897B1 (en) * 1997-07-08 2002-01-22 Microfab Technologies, Inc. Method and apparatus for dispensing airborne materials for controlling pests
JPH11111644A (en) * 1997-09-30 1999-04-23 Japan Pionics Co Ltd Vaporization supplying equipment
US6672129B1 (en) 1997-10-22 2004-01-06 Microfab Technologies, Inc. Method for calibrating a sensor for measuring concentration of odors
US6390453B1 (en) * 1997-10-22 2002-05-21 Microfab Technologies, Inc. Method and apparatus for delivery of fragrances and vapors to the nose
US20070095726A1 (en) * 2005-10-28 2007-05-03 Tihiro Ohkawa Chafftron
US7951421B2 (en) * 2006-04-20 2011-05-31 Global Oled Technology Llc Vapor deposition of a layer
TWI506391B (en) * 2010-04-15 2015-11-01 Novellus Systems Inc Gas and liquid injection system

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3281860A (en) * 1964-11-09 1966-10-25 Dick Co Ab Ink jet nozzle
US3266783A (en) * 1964-12-30 1966-08-16 Milton A Knight Electric carburetor
US3570275A (en) * 1965-02-08 1971-03-16 Halbmond Teppiche Veb Apparatus for the continuous dyeing of textile webs and the like
CH446809A (en) * 1966-05-24 1967-11-15 Walter Dr Ott Device for reducing the CO content in the exhaust gases of an internal combustion engine
US3769624A (en) * 1972-04-06 1973-10-30 Ibm Fluid droplet printer
US3761941A (en) * 1972-10-13 1973-09-25 Mead Corp Phase control for a drop generating and charging system
US3769627A (en) * 1972-12-13 1973-10-30 Dick Co Ab Ink jet printing system using ion charging of droplets
US3769625A (en) * 1972-12-29 1973-10-30 Ibm Traveling wave actuated segmented charging electrode for an ink jet printer
SU596782A1 (en) * 1976-07-20 1978-03-05 Shabalkin Anatolij Z Air humidification device
GB1527444A (en) * 1977-03-01 1978-10-04 Itt Creed Ink drop printhead

Also Published As

Publication number Publication date
IT8120849A0 (en) 1981-03-31
DE3112882A1 (en) 1982-01-07
IT1137117B (en) 1986-09-03
GB2073442A (en) 1981-10-14
JPH0131431B2 (en) 1989-06-26
US4310474A (en) 1982-01-12
FR2479709B1 (en) 1986-12-19
JPS56155668A (en) 1981-12-01
FR2479709A1 (en) 1981-10-09
GB2073442B (en) 1984-02-15
DE3112882C2 (en) 1989-08-17

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