CA1095319A - Chewing gum composition - Google Patents
Chewing gum compositionInfo
- Publication number
- CA1095319A CA1095319A CA292,002A CA292002A CA1095319A CA 1095319 A CA1095319 A CA 1095319A CA 292002 A CA292002 A CA 292002A CA 1095319 A CA1095319 A CA 1095319A
- Authority
- CA
- Canada
- Prior art keywords
- per cent
- gum composition
- fructose
- weight
- chewing gum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 30
- 229940112822 chewing gum Drugs 0.000 title claims abstract description 18
- 235000015218 chewing gum Nutrition 0.000 title claims abstract description 18
- 150000007524 organic acids Chemical class 0.000 claims abstract description 21
- 229930091371 Fructose Natural products 0.000 claims abstract description 17
- 239000005715 Fructose Substances 0.000 claims abstract description 17
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims abstract description 17
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims abstract description 15
- 239000008121 dextrose Substances 0.000 claims abstract description 15
- 206010039424 Salivary hypersecretion Diseases 0.000 claims abstract description 12
- 208000026451 salivation Diseases 0.000 claims abstract description 12
- 235000015165 citric acid Nutrition 0.000 claims abstract description 11
- 235000011037 adipic acid Nutrition 0.000 claims abstract description 5
- 235000011087 fumaric acid Nutrition 0.000 claims abstract description 5
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 5
- 235000011090 malic acid Nutrition 0.000 claims abstract description 5
- 159000000001 potassium salts Chemical class 0.000 claims abstract description 5
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric Acid Chemical class [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000010323 ascorbic acid Nutrition 0.000 claims abstract description 4
- 230000004936 stimulating effect Effects 0.000 claims abstract description 4
- 235000002906 tartaric acid Nutrition 0.000 claims abstract description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 22
- 159000000000 sodium salts Chemical class 0.000 claims description 9
- 230000001055 chewing effect Effects 0.000 claims description 6
- 235000013305 food Nutrition 0.000 claims description 6
- 235000003599 food sweetener Nutrition 0.000 claims description 6
- 239000003765 sweetening agent Substances 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- 239000006188 syrup Substances 0.000 claims description 3
- 235000020357 syrup Nutrition 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 2
- 239000000796 flavoring agent Substances 0.000 claims 2
- 239000004902 Softening Agent Substances 0.000 claims 1
- 235000019634 flavors Nutrition 0.000 claims 1
- 239000005454 flavour additive Substances 0.000 claims 1
- 235000013355 food flavoring agent Nutrition 0.000 claims 1
- 239000004615 ingredient Substances 0.000 abstract description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 7
- 239000011734 sodium Substances 0.000 abstract description 7
- 150000003839 salts Chemical class 0.000 abstract description 6
- 229910052708 sodium Inorganic materials 0.000 abstract description 6
- 210000003296 saliva Anatomy 0.000 abstract description 4
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 239000003230 hygroscopic agent Substances 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 235000005985 organic acids Nutrition 0.000 description 9
- 239000011591 potassium Substances 0.000 description 9
- 229910052700 potassium Inorganic materials 0.000 description 9
- 230000000694 effects Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 241000207199 Citrus Species 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 235000020971 citrus fruits Nutrition 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 4
- 235000005979 Citrus limon Nutrition 0.000 description 3
- 244000131522 Citrus pyriformis Species 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 235000019640 taste Nutrition 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 244000299507 Gossypium hirsutum Species 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 235000013361 beverage Nutrition 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- -1 fruits Natural products 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 230000003387 muscular Effects 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- 239000000021 stimulant Substances 0.000 description 2
- 235000012976 tarts Nutrition 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- 241000208140 Acer Species 0.000 description 1
- 241000271043 Agkistrodon piscivorus Species 0.000 description 1
- 244000080767 Areca catechu Species 0.000 description 1
- 235000006226 Areca catechu Nutrition 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000905957 Channa melasoma Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 208000006558 Dental Calculus Diseases 0.000 description 1
- 206010013911 Dysgeusia Diseases 0.000 description 1
- INJOMKTZOLKMBF-UHFFFAOYSA-N Guanfacine Chemical compound NC(=N)NC(=O)CC1=C(Cl)C=CC=C1Cl INJOMKTZOLKMBF-UHFFFAOYSA-N 0.000 description 1
- 244000141359 Malus pumila Species 0.000 description 1
- 101710084933 Miraculin Proteins 0.000 description 1
- BQVZDJJLMKBJMC-UHFFFAOYSA-L S(=O)([O-])[O-].[K+].C(C(O)C(O)C(=O)O)(=O)O.[K+] Chemical compound S(=O)([O-])[O-].[K+].C(C(O)C(O)C(=O)O)(=O)O.[K+] BQVZDJJLMKBJMC-UHFFFAOYSA-L 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 241001611093 Stimula Species 0.000 description 1
- 206010043268 Tension Diseases 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 235000021016 apples Nutrition 0.000 description 1
- 235000021028 berry Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- GPUADMRJQVPIAS-QCVDVZFFSA-M cerivastatin sodium Chemical compound [Na+].COCC1=C(C(C)C)N=C(C(C)C)C(\C=C\[C@@H](O)C[C@@H](O)CC([O-])=O)=C1C1=CC=C(F)C=C1 GPUADMRJQVPIAS-QCVDVZFFSA-M 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 206010013781 dry mouth Diseases 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 210000004124 hock Anatomy 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 210000000663 muscle cell Anatomy 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- YXPHKGYWYNBTLU-UHFFFAOYSA-L potassium sodium dihydrogen phosphate phosphono hydrogen phosphate Chemical compound [Na+].[K+].OP(O)([O-])=O.OP(O)(=O)OP(O)([O-])=O YXPHKGYWYNBTLU-UHFFFAOYSA-L 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- PSBAZVJEUNOIDU-UHFFFAOYSA-L potassium;sodium;diacetate Chemical compound [Na+].[K+].CC([O-])=O.CC([O-])=O PSBAZVJEUNOIDU-UHFFFAOYSA-L 0.000 description 1
- ASHGTUMKRVIOLH-UHFFFAOYSA-L potassium;sodium;hydrogen phosphate Chemical compound [Na+].[K+].OP([O-])([O-])=O ASHGTUMKRVIOLH-UHFFFAOYSA-L 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 description 1
- 229940081974 saccharin Drugs 0.000 description 1
- 235000019204 saccharin Nutrition 0.000 description 1
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 235000021262 sour milk Nutrition 0.000 description 1
- 235000019614 sour taste Nutrition 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 229940095064 tartrate Drugs 0.000 description 1
- 229940065385 tenex Drugs 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G4/00—Chewing gum
- A23G4/06—Chewing gum characterised by the composition containing organic or inorganic compounds
- A23G4/064—Chewing gum characterised by the composition containing organic or inorganic compounds containing inorganic compounds
Abstract
ABSTRACT
Novel chewing gum composition for use by athletes and other persons to stimulate salivation while exercising, compris-ing the combination of at least three per cent by weight of an organic acid selected from the group consisting of adipic, ascorbic, citric, fumaric, lactic, malic and tartaric acids, and fructose. The organic acid and fructose combination provides a synergistic saliva stimulating effect greater than that of either ingredient alone. Sodium and potassium salts are inclu-ded to help replenish those salts lost in prespiration, and high levels of dextrose or fructose provide a quick energy source and a hygroscopic agent for improved shelf life.
Novel chewing gum composition for use by athletes and other persons to stimulate salivation while exercising, compris-ing the combination of at least three per cent by weight of an organic acid selected from the group consisting of adipic, ascorbic, citric, fumaric, lactic, malic and tartaric acids, and fructose. The organic acid and fructose combination provides a synergistic saliva stimulating effect greater than that of either ingredient alone. Sodium and potassium salts are inclu-ded to help replenish those salts lost in prespiration, and high levels of dextrose or fructose provide a quick energy source and a hygroscopic agent for improved shelf life.
Description
9531g This invention relates to chewing gum and, more part-icularly, to :Elavored chewing gum having a combination if ingre-dients enabling it to stimulate salivation synergistically be-yond that attributable to the act of chewing Eood or either of the ingredients alone.
The present invention is directed to a chewing gum composition essentially comprising gum base; a sweetener; fla- :
voring additives, a palatable and safe amount of an organic acid selected from the group consisting of adipic, ascorbic, citric, fumaric, lactic, malic and tartaric acids, said organ-ic acid being capable of stimulating salivation beyond that attributable to the act of chewing food and constituting at least 3 per cent by weight of the final gum composition; and fructose constituting at least 10 per cent by weight of the final gum composition.
Chewing gum is used by athletes and other persons ::
while exercising to relieve nervous tension. Chewing ordinary gum for a prolonged exercise period sometimes causes a dry mouth condition known as "cottonmouth~. Exercising, of course, causes muscular fatigue along with loss of essential potassium and sodium salts through perspirationO Shelf life, that is, the ability to remain soft and readily chewable in storaye, is ~.
also important.
Known gum compositions typically contain some form of chewable gum base, a softener, a flavoring ingredient and a sweetener, which can be either natural or artificial~ While certain organic acids derived from natural products such as fruits, vegetables, plants and milk stimulate salivation, in ,,,\j i31~
: ;
order to be effective for this purpose, they have to be used in high concentrations (above 3% by weight), resulting in an ob-jectionable strong and sour taste. One example of such an organic acid, which is an excellent salivating agent, is citric acid. Straight lemon juice, containing 5 to 8 par cent citric acid, is too sour to use as is, and must be diluted substan-tially for use in foods and beverages. In the low concentra-tions normally found in foods and beverages, citric acid is not a very effective salivation agent.
Chewing gum is an ideal medium for the controlled re- ::
lease of salivation agents, quick energy sugars and sodium and potassium salts for athletes or other persons engaged in stren-uous exerciseO However, prior to the present invention, the only known gum composition developed to accomplish these re-sults is disclosed in U. S. Patent 4,088j788. This gum compo-sition contains high levels of an organic acid and saccharin, t.he latter ingredient being considered by some to be harmful~ ;:
Applicants are unaware of any other gum composition having a palatable taste yet containing a hi.gh concentration of an or-ganic acid to ach.ieve heavy saliva stimulation.
In Johnson Patent 3,681,087, sticks of gum containing citric acid are dusted with miraculin powder, an odd substance ~ .
which has the peculiar, taste~inverting characteristic of mak-ing sour things taste sweet~ This is exactly th~ opposite of the effect which is needed in a saliva-stimulating gum compo-sition, which should be quite tart for maximum salivation, yet not objectionably so.
Atkins and Attaway Patent 3,657,424 discloses a .
~! 2 S3~
commercial bottled citrus drink employing oranye, grape~ruit, lemon, lime or other acid Eruit juices. Reference is made to use by athlates or other parsons for replacing the loss oE
body 1uids which .results from exercising or working in high temperature anvironments. calcium, sodium and potassium ions are included as supplements to make up Eor loss oE these ions in perspiration. These citrus juices are very diluted and lack the concentration required for producing any salivation eEfect. Citrus -2a-~' , juices, marketed in a can or'hottle,:,cannot serve:the same purp~e as chewing gum. ~ professional at:hl'ete'ca,n che~ cJum ~h.ile play-ing ootball, ~sket~all or.hock~ey to obtain extended.slo~-release benefits therefro~m but obviously cannot carry a ~ottled be~eragé
into play.
Further example~ o:E the state'of thb art are'shown in Ogawa and Terasawa Patent 3~826r847'and Bilotti Patent 3,352 r 689 ~ ~oth relate to ch:e~i~ng gums~ NeIth.er discloses any salivation stimulating .percentage'(above 3~ by ~eight) of'any organic acid. The Ogawa et al;patent has only a single'exa~ple illustrat.ing about 0.2:per. cent-tartaric acid, which.amount is insufficlent for salivation~ The Bilotti patent does not men- ~
tion'any organic acid ingredient:at all~ The gums disclosed ., in the.se'patents-are'ineffecti.ve to act as stimulants of ~aliva '~;
to a deyree'greater than that attributabIe to the'act of chewin,g ~`
food itself.
Accordingly, it :is a~principal obj'ect of the'inven- :
tion to provide'a good'tasting.ch'ewing gum composition'having the ability, ~hen usea in:the'ordinary way~ to stimula:te, .~' 20 salivation:to a degrea'beyond that attributabIe'to the'mere act ~ , of c~wing ,~ood and to eIiminate:the'dry, so-called "cot-ton~
mouth" condition experienced wi'th.'conventional che~ing gum products; to reduce muscular ~atigue'by providing a quick ::
source'of energy; to replenish'a portion'o~'the ~od~ salts nor-mally lost in perspiration; and to have'lmprov.ed :shel~ life.
These'and other objects and advantages of the invention will be appaxent:from':the'following .descr'.iption'~
~hich dlscloses a prefe~rred em~odiment of ~he'in.ventionO` :'' ' The ch:ewing ~um composition'of'this invention is prl.-marily intended for use'by.athIet'es and other persons duringstrenuous physical exercise~' It is ~ell~kno~n that.ath.Ietes engaged ln competitive effQrts che~ gum to reIieve'.tension;
.
-3- :
.. - : ~ . :
9S3~9 chewing, whether i-t be gum, tob~cco, betel nut or a stick of wood, is a kno~n me~ns of xeIaxation`~ A che~ing ~um co~po~i tion typically includes a gum basej ~lavoring additi~es, enulsi-fying agents, a sweetener and sometimes coloring ingredients, among others. Into such a gu~ composition, the pxesent inven-tion incorporates three additional features, namely, a saliva-stimu-lating and acid-m~s~ng combi'nation'of ingredi~ents, a source of energy to reduce fatigue and a source of potassium and sodium salts to replenish'those $~1ts lost in perspiration during exercise.
In general, the present invention utilizes the hereto-fore unrecognized synergistic saliva-stimulating effect pxoduced by the combination of a high'level' of fructose with high ~ercent-ages (that is, above 3~ by weight) o~ certain specified organic acids in a pleasant-tasting chewing gum. Actual tests have dem- '~
onstrated that the~resultant saliva-st'imulating effect greatly exceeds that of either fructose'or organic acid alone in gum com-positions. The high'leveI of fructose, which is a strong s~eet-ener, partially masks the otherwise unacceptably soux taste caused by such high le~els of organic acids. ~n addition, high levels of dextrose or ~ructose'are'preferably incorporated to provide'both`a quick energy source'and a h~groscopic a~ent to improye shelf life.' Furthe~more~ potassium or sodium salts, or both,' are'incorporated for slow'~ controlled release with'the other ingredients.
It is weIl-known that the presence of a hi~h leveI of certain organic acids specified herein, above about 3% o~ the total ~eightf makes a gum product`unpleas~ntly sour~ Similarly~
a high leveI of fructose or'other sweetener makes it too sweat.
For these reasons, neithe'r of these'two ingredients is used separately at high'levels in gum compositions~ As pxeviously state~, however, their combined use in the pres'ent invention, a-t ~ss3~
the high:leveIs sta.ted~ pro~`.ides:the:excellent:desixed result~
nameIy,. eff.ective saliva-stimulat.ion in a pleasant-ta~tin~
che~i.ng gum. It should be no.ted that while certa:in organic acids are known saliva stimulants~ fructose'alone.is not thbught to have that attribute and is not typically used for that purpose~ The combination of these'two ingredients increases saliva flow/
reduces or. eliminates "cotton~outh"' inherent with'prolon~ea chewing while exercising and results in a tart-~l.ayoxed ~ut pleasant-tasting chewi:ng gum pr.od`uct:. .
Specifically, the'organic :acids~.. which,' ~ith~fructose~ ~.
will produce' the~des'irea sali~atlon:effect:in the'present inven-tion, are one or more of those'seIected fxom th~ grouP consist-ing of adipic, ascorbic, citric,'fumaric, lactic, malic and tartar;c acids. These'organic acids occur in natural products, although.,~ as a pr-act'ical matter,: they may ~e'synthes'i.zed for lo~'-co'st mass product'ionO Adipic acid occurs in .beet:jui.ce.
~c-orbic:acid is-found in citrus .ruits~ hip berries, and ~resh tea leaves. Citric acid is present:in lemon', lime'and grape- :~
fruit juicesr to name'a few sources. Fumaric acid is found in 20 many plants. Lactic acid makeb sour milk'tart. Malic acid is '~
found in unripe'fruits, maple:'~ice'and apples. Finally~ tc~.~aric acid occurs in fruit and vege~able tissues~
The ~ollow'ing examples~ill specifically list citric acid as the'organic acid ingredient, but it will be'understood' that:any one'or combination'of. the'other organic acids listed above may!be substituted ~ith:the'~ame.~bene~icial results.
One. example'of.the'ch'e~îng.gum compos'ition of the present invention, employîng the:Gom~ation'of h~h:le~els of organlc acids and ~ructose~ ~long ~îth a hl:gh'dextrQse'leveI~
3~ comprises the follo~ing in~xedîents on a weight' ~5i'5: gum ba~e~: ~rom'lQ per cent to '87 pex centi dextrose s~rup ~conven-tionaI:corn.s~rup), from'O per cent to 25 per cent; granulated ~9~9 dextrose, from O.per cent to 80.per .cent; citr.ic acid, from 3 per cent t.o lO pex cent; a sof.tenex such as glyce.rine, from O.psr cent to 25 per cent, fru-tose, .from lO per' cent to 70 p~r cent sol~lble food'~xade'po~a:ssium salts, from`0 p~r ~t t~ 4 pe~. cen'tu a sodium salt~ rom'0.per ce'nt to '4 per centg and sucrose~' a bulking component, from 0 per cent to'80'per cent. ~dditionally, conventional 1a~or's (f:rom'0.1 per cent to 6 per .cent~ and coloring Ingxedients can be added as desired.
~ithin the specified ranges~ the optimum leveIs of che~ing gum ingredients are determined empirically, depending on the par ticular end product desired. -Another advan-tage'of this inventionf nameIy improved shelf life! results from the'hygroscopic effect achieved by ' the.'combination of dextrose'or fructose and the specified organic acids. In addition'to 'supplying quick ener~y, the dextrose or fructose, when combined with these'organic acids, .
can readily absorb and retain moisture :Erom the'air, allowing the inal formulated gum product to hold moistu:re~and stay fres~
The'preferred chewing gum composition of the present invention further includes a potassium salt or a sodium salt, or both~' to replenish such'salts lost in perspiration.
Replenishment of'these salts tends to reduce dehydxation of muscle cells and retards fatigue.' It will be understood that any of the following potassium and sodium salts can be uti]ized~
potassium bi-sulfate`. sodium acetate potassium bi-tartrate' sodium bi-~phate potassium carhonate sodium carbbnate' potassium chloxide' sodium citrate:
potassium phosphate - sodium glucona.te`
(mono & di~basic)`
potassium pyro phosphate sodium phosphate' potassium stearate' sodium sulfate S3~L9 potassium sul:Eate sodi~ tartrate potassium sulfite potassium tri poly phosphate It should be noted that the presence of too high a level of either the potassium or sodium s~lts listed will adversely a~fect the -taste of the gum product.
The preferred formula for the chewing gum composi-tion of the present invention ls as follows:
Ingredient Per Cen`t By Weight Base 25.Q0 Dextrose Syrup 10.00 ;.
Dextrose (~ranulatedl 30~43 ~
Fructose 20~00 ~.
Citric ~cid 6.00 Glycerine (softener)2.00 ~lavors 1.25 Potassium Salts 0.~.27 Sodium:Salts 0.,05 Sucrose 5.00 If dextrose in syxup form is.not utilized in formu-lating the gum composition, the addition of some foxm o~
plasticizer will be necessary to assist in the manu~acture of such gum products and the percentage of granulated dextrose will have to be increased~
- .. .. .
. . - , ,................... : . . .............. :
,. . , , - ,
The present invention is directed to a chewing gum composition essentially comprising gum base; a sweetener; fla- :
voring additives, a palatable and safe amount of an organic acid selected from the group consisting of adipic, ascorbic, citric, fumaric, lactic, malic and tartaric acids, said organ-ic acid being capable of stimulating salivation beyond that attributable to the act of chewing food and constituting at least 3 per cent by weight of the final gum composition; and fructose constituting at least 10 per cent by weight of the final gum composition.
Chewing gum is used by athletes and other persons ::
while exercising to relieve nervous tension. Chewing ordinary gum for a prolonged exercise period sometimes causes a dry mouth condition known as "cottonmouth~. Exercising, of course, causes muscular fatigue along with loss of essential potassium and sodium salts through perspirationO Shelf life, that is, the ability to remain soft and readily chewable in storaye, is ~.
also important.
Known gum compositions typically contain some form of chewable gum base, a softener, a flavoring ingredient and a sweetener, which can be either natural or artificial~ While certain organic acids derived from natural products such as fruits, vegetables, plants and milk stimulate salivation, in ,,,\j i31~
: ;
order to be effective for this purpose, they have to be used in high concentrations (above 3% by weight), resulting in an ob-jectionable strong and sour taste. One example of such an organic acid, which is an excellent salivating agent, is citric acid. Straight lemon juice, containing 5 to 8 par cent citric acid, is too sour to use as is, and must be diluted substan-tially for use in foods and beverages. In the low concentra-tions normally found in foods and beverages, citric acid is not a very effective salivation agent.
Chewing gum is an ideal medium for the controlled re- ::
lease of salivation agents, quick energy sugars and sodium and potassium salts for athletes or other persons engaged in stren-uous exerciseO However, prior to the present invention, the only known gum composition developed to accomplish these re-sults is disclosed in U. S. Patent 4,088j788. This gum compo-sition contains high levels of an organic acid and saccharin, t.he latter ingredient being considered by some to be harmful~ ;:
Applicants are unaware of any other gum composition having a palatable taste yet containing a hi.gh concentration of an or-ganic acid to ach.ieve heavy saliva stimulation.
In Johnson Patent 3,681,087, sticks of gum containing citric acid are dusted with miraculin powder, an odd substance ~ .
which has the peculiar, taste~inverting characteristic of mak-ing sour things taste sweet~ This is exactly th~ opposite of the effect which is needed in a saliva-stimulating gum compo-sition, which should be quite tart for maximum salivation, yet not objectionably so.
Atkins and Attaway Patent 3,657,424 discloses a .
~! 2 S3~
commercial bottled citrus drink employing oranye, grape~ruit, lemon, lime or other acid Eruit juices. Reference is made to use by athlates or other parsons for replacing the loss oE
body 1uids which .results from exercising or working in high temperature anvironments. calcium, sodium and potassium ions are included as supplements to make up Eor loss oE these ions in perspiration. These citrus juices are very diluted and lack the concentration required for producing any salivation eEfect. Citrus -2a-~' , juices, marketed in a can or'hottle,:,cannot serve:the same purp~e as chewing gum. ~ professional at:hl'ete'ca,n che~ cJum ~h.ile play-ing ootball, ~sket~all or.hock~ey to obtain extended.slo~-release benefits therefro~m but obviously cannot carry a ~ottled be~eragé
into play.
Further example~ o:E the state'of thb art are'shown in Ogawa and Terasawa Patent 3~826r847'and Bilotti Patent 3,352 r 689 ~ ~oth relate to ch:e~i~ng gums~ NeIth.er discloses any salivation stimulating .percentage'(above 3~ by ~eight) of'any organic acid. The Ogawa et al;patent has only a single'exa~ple illustrat.ing about 0.2:per. cent-tartaric acid, which.amount is insufficlent for salivation~ The Bilotti patent does not men- ~
tion'any organic acid ingredient:at all~ The gums disclosed ., in the.se'patents-are'ineffecti.ve to act as stimulants of ~aliva '~;
to a deyree'greater than that attributabIe to the'act of chewin,g ~`
food itself.
Accordingly, it :is a~principal obj'ect of the'inven- :
tion to provide'a good'tasting.ch'ewing gum composition'having the ability, ~hen usea in:the'ordinary way~ to stimula:te, .~' 20 salivation:to a degrea'beyond that attributabIe'to the'mere act ~ , of c~wing ,~ood and to eIiminate:the'dry, so-called "cot-ton~
mouth" condition experienced wi'th.'conventional che~ing gum products; to reduce muscular ~atigue'by providing a quick ::
source'of energy; to replenish'a portion'o~'the ~od~ salts nor-mally lost in perspiration; and to have'lmprov.ed :shel~ life.
These'and other objects and advantages of the invention will be appaxent:from':the'following .descr'.iption'~
~hich dlscloses a prefe~rred em~odiment of ~he'in.ventionO` :'' ' The ch:ewing ~um composition'of'this invention is prl.-marily intended for use'by.athIet'es and other persons duringstrenuous physical exercise~' It is ~ell~kno~n that.ath.Ietes engaged ln competitive effQrts che~ gum to reIieve'.tension;
.
-3- :
.. - : ~ . :
9S3~9 chewing, whether i-t be gum, tob~cco, betel nut or a stick of wood, is a kno~n me~ns of xeIaxation`~ A che~ing ~um co~po~i tion typically includes a gum basej ~lavoring additi~es, enulsi-fying agents, a sweetener and sometimes coloring ingredients, among others. Into such a gu~ composition, the pxesent inven-tion incorporates three additional features, namely, a saliva-stimu-lating and acid-m~s~ng combi'nation'of ingredi~ents, a source of energy to reduce fatigue and a source of potassium and sodium salts to replenish'those $~1ts lost in perspiration during exercise.
In general, the present invention utilizes the hereto-fore unrecognized synergistic saliva-stimulating effect pxoduced by the combination of a high'level' of fructose with high ~ercent-ages (that is, above 3~ by weight) o~ certain specified organic acids in a pleasant-tasting chewing gum. Actual tests have dem- '~
onstrated that the~resultant saliva-st'imulating effect greatly exceeds that of either fructose'or organic acid alone in gum com-positions. The high'leveI of fructose, which is a strong s~eet-ener, partially masks the otherwise unacceptably soux taste caused by such high le~els of organic acids. ~n addition, high levels of dextrose or ~ructose'are'preferably incorporated to provide'both`a quick energy source'and a h~groscopic a~ent to improye shelf life.' Furthe~more~ potassium or sodium salts, or both,' are'incorporated for slow'~ controlled release with'the other ingredients.
It is weIl-known that the presence of a hi~h leveI of certain organic acids specified herein, above about 3% o~ the total ~eightf makes a gum product`unpleas~ntly sour~ Similarly~
a high leveI of fructose or'other sweetener makes it too sweat.
For these reasons, neithe'r of these'two ingredients is used separately at high'levels in gum compositions~ As pxeviously state~, however, their combined use in the pres'ent invention, a-t ~ss3~
the high:leveIs sta.ted~ pro~`.ides:the:excellent:desixed result~
nameIy,. eff.ective saliva-stimulat.ion in a pleasant-ta~tin~
che~i.ng gum. It should be no.ted that while certa:in organic acids are known saliva stimulants~ fructose'alone.is not thbught to have that attribute and is not typically used for that purpose~ The combination of these'two ingredients increases saliva flow/
reduces or. eliminates "cotton~outh"' inherent with'prolon~ea chewing while exercising and results in a tart-~l.ayoxed ~ut pleasant-tasting chewi:ng gum pr.od`uct:. .
Specifically, the'organic :acids~.. which,' ~ith~fructose~ ~.
will produce' the~des'irea sali~atlon:effect:in the'present inven-tion, are one or more of those'seIected fxom th~ grouP consist-ing of adipic, ascorbic, citric,'fumaric, lactic, malic and tartar;c acids. These'organic acids occur in natural products, although.,~ as a pr-act'ical matter,: they may ~e'synthes'i.zed for lo~'-co'st mass product'ionO Adipic acid occurs in .beet:jui.ce.
~c-orbic:acid is-found in citrus .ruits~ hip berries, and ~resh tea leaves. Citric acid is present:in lemon', lime'and grape- :~
fruit juicesr to name'a few sources. Fumaric acid is found in 20 many plants. Lactic acid makeb sour milk'tart. Malic acid is '~
found in unripe'fruits, maple:'~ice'and apples. Finally~ tc~.~aric acid occurs in fruit and vege~able tissues~
The ~ollow'ing examples~ill specifically list citric acid as the'organic acid ingredient, but it will be'understood' that:any one'or combination'of. the'other organic acids listed above may!be substituted ~ith:the'~ame.~bene~icial results.
One. example'of.the'ch'e~îng.gum compos'ition of the present invention, employîng the:Gom~ation'of h~h:le~els of organlc acids and ~ructose~ ~long ~îth a hl:gh'dextrQse'leveI~
3~ comprises the follo~ing in~xedîents on a weight' ~5i'5: gum ba~e~: ~rom'lQ per cent to '87 pex centi dextrose s~rup ~conven-tionaI:corn.s~rup), from'O per cent to 25 per cent; granulated ~9~9 dextrose, from O.per cent to 80.per .cent; citr.ic acid, from 3 per cent t.o lO pex cent; a sof.tenex such as glyce.rine, from O.psr cent to 25 per cent, fru-tose, .from lO per' cent to 70 p~r cent sol~lble food'~xade'po~a:ssium salts, from`0 p~r ~t t~ 4 pe~. cen'tu a sodium salt~ rom'0.per ce'nt to '4 per centg and sucrose~' a bulking component, from 0 per cent to'80'per cent. ~dditionally, conventional 1a~or's (f:rom'0.1 per cent to 6 per .cent~ and coloring Ingxedients can be added as desired.
~ithin the specified ranges~ the optimum leveIs of che~ing gum ingredients are determined empirically, depending on the par ticular end product desired. -Another advan-tage'of this inventionf nameIy improved shelf life! results from the'hygroscopic effect achieved by ' the.'combination of dextrose'or fructose and the specified organic acids. In addition'to 'supplying quick ener~y, the dextrose or fructose, when combined with these'organic acids, .
can readily absorb and retain moisture :Erom the'air, allowing the inal formulated gum product to hold moistu:re~and stay fres~
The'preferred chewing gum composition of the present invention further includes a potassium salt or a sodium salt, or both~' to replenish such'salts lost in perspiration.
Replenishment of'these salts tends to reduce dehydxation of muscle cells and retards fatigue.' It will be understood that any of the following potassium and sodium salts can be uti]ized~
potassium bi-sulfate`. sodium acetate potassium bi-tartrate' sodium bi-~phate potassium carhonate sodium carbbnate' potassium chloxide' sodium citrate:
potassium phosphate - sodium glucona.te`
(mono & di~basic)`
potassium pyro phosphate sodium phosphate' potassium stearate' sodium sulfate S3~L9 potassium sul:Eate sodi~ tartrate potassium sulfite potassium tri poly phosphate It should be noted that the presence of too high a level of either the potassium or sodium s~lts listed will adversely a~fect the -taste of the gum product.
The preferred formula for the chewing gum composi-tion of the present invention ls as follows:
Ingredient Per Cen`t By Weight Base 25.Q0 Dextrose Syrup 10.00 ;.
Dextrose (~ranulatedl 30~43 ~
Fructose 20~00 ~.
Citric ~cid 6.00 Glycerine (softener)2.00 ~lavors 1.25 Potassium Salts 0.~.27 Sodium:Salts 0.,05 Sucrose 5.00 If dextrose in syxup form is.not utilized in formu-lating the gum composition, the addition of some foxm o~
plasticizer will be necessary to assist in the manu~acture of such gum products and the percentage of granulated dextrose will have to be increased~
- .. .. .
. . - , ,................... : . . .............. :
,. . , , - ,
Claims (7)
1. A chewing gum composition essentially comprising gum base; a sweetener; flavoring additives; a palatable and safe amount of an organic acid selected from the group consis-ting of adipic, ascorbic, citric, fumaric, lactic, malic and tartaric acids, said organic acid being capable of stimulat-ing salivation beyond that attributable to the act of chewing food and constituting at least 3 per cent by weight of the final gum composition; and fructose constituting at least 10 per cent by weight of the final gum composition.
2. The chewing gum composition of claim 1 wherein said fructose constitutes from 10 per cent to 70 per cent by weight of the final gum composition.
3. The chewing gum composition of claim 1 wherein said sweetener is dextrose.
4. A chewing gum composition of claim 1 including potassium salts up to about 4 per cent by weight of the final gum composition.
5. The chewing gum composition of claim 1 including sodium salts up to about 4 per cent by weight of the final gum composition.
6. A chewing gum composition comprising on a weight basis: from about 10 per cent to about 87 per cent gum base;
from about 0 per cent to about 25 per cent dextrose syrup;
from about 0 per cent to about 80 per cent granualted dextrose;
from about 0 per cent to about 80 per cent sucrose; from about 10 per cent to about 70 per cent fructose; from about 3 per cent to about 10 per cent of an organic acid selected from the group consisting of adipic, ascorbic, citric, fumaric, lactic, malic and tartaric acids; from about 0 per cent to about 4 per cent potassium salts; from about 0 per cent to about 4 per cent sodium salts; and effective amounts of flavoring and softening agents.
from about 0 per cent to about 25 per cent dextrose syrup;
from about 0 per cent to about 80 per cent granualted dextrose;
from about 0 per cent to about 80 per cent sucrose; from about 10 per cent to about 70 per cent fructose; from about 3 per cent to about 10 per cent of an organic acid selected from the group consisting of adipic, ascorbic, citric, fumaric, lactic, malic and tartaric acids; from about 0 per cent to about 4 per cent potassium salts; from about 0 per cent to about 4 per cent sodium salts; and effective amounts of flavoring and softening agents.
7. A chewing gum composition comprising the follow-ing on a weight per cent basis:
gum base 25.00 per cent dextrose syrup 10.00 per cent granulated dextrose 30.43 per cent fructose 20.00 per cent citric acid 6.00 per cent glycerine 2.00 per cent flavors 1.25 per cent sodium salt 0.05 per cent potassium salt 0.27 per cent sucrose 5.00 per cent.
gum base 25.00 per cent dextrose syrup 10.00 per cent granulated dextrose 30.43 per cent fructose 20.00 per cent citric acid 6.00 per cent glycerine 2.00 per cent flavors 1.25 per cent sodium salt 0.05 per cent potassium salt 0.27 per cent sucrose 5.00 per cent.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/836,383 US4151270A (en) | 1977-09-26 | 1977-09-26 | Chewing gum composition |
US836,383 | 1977-09-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1095319A true CA1095319A (en) | 1981-02-10 |
Family
ID=25271859
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA292,002A Expired CA1095319A (en) | 1977-09-26 | 1977-11-29 | Chewing gum composition |
Country Status (10)
Country | Link |
---|---|
US (1) | US4151270A (en) |
AT (1) | AT361126B (en) |
BE (1) | BE864665A (en) |
CA (1) | CA1095319A (en) |
CH (1) | CH633166A5 (en) |
DE (1) | DE2811816C2 (en) |
GB (1) | GB1582499A (en) |
IE (1) | IE46689B1 (en) |
IT (1) | IT1104608B (en) |
NL (1) | NL7803145A (en) |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4233288A (en) * | 1979-03-12 | 1980-11-11 | Cornell John A | Gum emulsified liquid package for delivering and preserving liquid content in the mouth |
JPS588818B2 (en) * | 1979-09-21 | 1983-02-17 | 株式会社 ロツテ | Method for producing foamable chewing gum |
JPS588820B2 (en) * | 1980-03-11 | 1983-02-17 | 株式会社 ロツテ | Chewing gum containing high energy phosphoric acid compound |
US4400372A (en) * | 1981-03-05 | 1983-08-23 | Indiana University Foundation | Chewing gum |
CH658594A5 (en) * | 1982-02-22 | 1986-11-28 | Bruss Ni Sanitarno Gigieniches | MEDICINAL PRODUCT WITH ANTINICOTINE EFFECT AND METHOD FOR THE PRODUCTION THEREOF. |
US4568537A (en) * | 1983-06-06 | 1986-02-04 | Wm. Wrigley Jr. Company | Dental health method employing chewing gum |
US4639368A (en) * | 1984-08-23 | 1987-01-27 | Farmacon Research Corporation | Chewing gum containing a medicament and taste maskers |
US4790991A (en) * | 1985-02-05 | 1988-12-13 | Warner-Lambert Company | Ingestible aggregate and delivery system prepared therefrom |
US4818539A (en) * | 1985-02-05 | 1989-04-04 | Warner-Lambert Company | Ingestible aggregate and delivery system prepared therefrom |
US4851392A (en) * | 1985-02-05 | 1989-07-25 | Warner-Lambert Company | Ingestible aggregate and delivery system prepared therefrom |
US4747881A (en) * | 1985-02-05 | 1988-05-31 | Warner-Lambert Company | Ingestible aggregate and delivery system prepared therefrom |
US4843098A (en) * | 1985-02-05 | 1989-06-27 | Warner-Lambert Company | Ingestible aggregate and delivery system prepared therefrom |
US4800091A (en) * | 1986-11-25 | 1989-01-24 | Warner-Lambert Company | Chewing gum compositions having sequential acid release |
US4872884A (en) * | 1986-12-10 | 1989-10-10 | Warner-Lambert Company | Reduced calorie chewing gum base and compositions containing the same |
US4931293A (en) * | 1986-12-23 | 1990-06-05 | Warner-Lambert Company | Food acid delivery systems containing polyvinyl acetate |
AU2090488A (en) * | 1987-08-28 | 1989-03-02 | Avantgarde S.P.A. | Chewing gum having antitartar activity |
US4906455A (en) * | 1988-04-15 | 1990-03-06 | Wm. Wrigley Jr. Company | Method for treating xerostomia employing chewing gum containing relatively insoluble, hydrophobic, food-grade organic acid |
US4952407A (en) * | 1988-09-12 | 1990-08-28 | Wm. Wrigley Jr. Company | Chewing gum containing glycerol mono laurate |
US5057328A (en) * | 1988-11-14 | 1991-10-15 | Warner-Lambert Company | Food acid delivery systems containing polyvinyl acetate |
US4938963A (en) * | 1988-11-22 | 1990-07-03 | Parnell Pharmaceuticals, Inc. | Method and composition for treating xerostomia |
US5015474A (en) * | 1988-11-22 | 1991-05-14 | Parnell Pharmaceuticals, Inc. | Composition for imparting moisture to a substrate |
US4983378A (en) * | 1988-11-22 | 1991-01-08 | Parnell Pharmaceuticals, Inc. | Method and composition for treating xerostomia |
US4900563A (en) * | 1988-12-29 | 1990-02-13 | Warner-Lambert Company | Fructose sweetened chewing gum compositions |
US5139794A (en) * | 1989-04-19 | 1992-08-18 | Wm. Wrigley Jr. Company | Use of encapsulated salts in chewing gum |
US5106632A (en) * | 1990-01-23 | 1992-04-21 | Warner-Lambert Company | Enhanced sweetness of acesulfame-k in edible compositions |
US5731338A (en) * | 1992-07-02 | 1998-03-24 | Oramed, Inc. | Controlled release pilocarpine delivery system |
US6159448A (en) * | 1996-09-27 | 2000-12-12 | Enamelon, Inc. | Products and methods for the remineralization and prevention of demineralization of teeth |
WO1998013013A1 (en) * | 1996-09-27 | 1998-04-02 | Enamelon, Inc. | Improved products and methods for the remineralization and prevention of demineralization of teeth |
US6562382B1 (en) * | 1999-08-05 | 2003-05-13 | Wm. Wrigley Jr. Company | Confectionery products having improved shelf life and methods for their production |
FR2799372B1 (en) * | 1999-11-04 | 2003-04-04 | Olivier Claude Alain Roujansky | COATING OF MEDICINAL PRINCIPLES OR OF FOOD OR DIETETIC PRODUCTS, OF A SOLID NATURE, ORALLY ADMINISTERED WITH A WATER-SOLUBLE COMPOSITION INTENDED TO CAUSE AN IMPORTANT LOWERING OF ORAL PH |
IL138788A0 (en) * | 2000-09-29 | 2001-10-31 | Falk Fish | Method and kit for the transdermal determination of analyte concentration in blood |
AU1996802A (en) | 2000-12-15 | 2002-06-24 | Wrigley W M Jun Co | Encapsulated acid mixtures and products including same |
US20030118628A1 (en) * | 2001-04-05 | 2003-06-26 | Tutuncu Nurhan Pinar | Confectionery product having a salivation region and an oral comfort region |
WO2002092037A1 (en) | 2001-05-15 | 2002-11-21 | The Procter & Gamble Company | Oral care confectionery compositions |
MXPA03010455A (en) | 2001-05-15 | 2004-03-09 | Procter & Gamble | Oral care compositions. |
EP1448060A2 (en) | 2001-05-15 | 2004-08-25 | The Procter & Gamble Company | Confectionery compositions |
US20080213363A1 (en) * | 2003-01-23 | 2008-09-04 | Singh Nikhilesh N | Methods and compositions for delivering 5-HT3 antagonists across the oral mucosa |
US7041311B2 (en) * | 2003-02-28 | 2006-05-09 | International Flavors & Fragrances Inc. | Preparation for saliva flow |
US20050042281A1 (en) * | 2003-08-21 | 2005-02-24 | Singh Nikhilesh N. | Compositions for delivering therapeutic agents across the oral mucosa |
US20050196517A1 (en) * | 2005-02-14 | 2005-09-08 | Mars, Incorporated | Edible product having discrete regions with different heats of solution |
WO2007117537A2 (en) * | 2006-04-05 | 2007-10-18 | Cadbury Adams Usa Llc | Calcium phosphate complex in acid containing confectionery |
BRPI0712006A2 (en) * | 2006-06-12 | 2012-02-14 | Firmenich & Cie | compositions that cause tingling and salivation |
KR101828630B1 (en) * | 2010-07-09 | 2018-02-12 | 데이진 화-마 가부시키가이샤 | Orally disintegrating tablet |
JP6207820B2 (en) * | 2011-09-30 | 2017-10-04 | 三栄源エフ・エフ・アイ株式会社 | Method for enhancing acidity of chewing gum containing acidulant |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2224252A (en) * | 1938-10-10 | 1940-12-10 | Edward C Callaway | Food product and the process of making it |
US3632358A (en) * | 1968-04-18 | 1972-01-04 | Philip Morris Inc | Chewing gum with freeze-dried food particles |
US3657424A (en) * | 1970-04-01 | 1972-04-18 | Florida State | Full-flavored citrus juice energy supplement |
US3681087A (en) * | 1970-04-15 | 1972-08-01 | Meditron Inc | Chewing gum composition |
CA1082517A (en) * | 1975-05-15 | 1980-07-29 | Donald A. M. Mackay | Long-lasting flavored chewing gum and process for preparing same |
BE850810A (en) * | 1976-01-30 | 1977-05-16 | Indiana University Foundation | NON-CARIOGENIC EDIBLE PRODUCT |
CA1087905A (en) * | 1976-02-02 | 1980-10-21 | Donald A.M. Mackay | Long-lasting flavored chewing gum including chalk- free gum base |
-
1977
- 1977-09-26 US US05/836,383 patent/US4151270A/en not_active Expired - Lifetime
- 1977-11-29 CA CA292,002A patent/CA1095319A/en not_active Expired
-
1978
- 1978-03-08 BE BE1008752A patent/BE864665A/en not_active IP Right Cessation
- 1978-03-16 DE DE2811816A patent/DE2811816C2/en not_active Expired
- 1978-03-16 IT IT48470/78A patent/IT1104608B/en active
- 1978-03-23 CH CH324878A patent/CH633166A5/en not_active IP Right Cessation
- 1978-03-23 NL NL7803145A patent/NL7803145A/en not_active Application Discontinuation
- 1978-03-23 IE IE587/78A patent/IE46689B1/en not_active IP Right Cessation
- 1978-03-24 AT AT213378A patent/AT361126B/en not_active IP Right Cessation
- 1978-03-29 GB GB12261/78A patent/GB1582499A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
IT1104608B (en) | 1985-10-21 |
ATA213378A (en) | 1980-07-15 |
AT361126B (en) | 1981-02-25 |
BE864665A (en) | 1978-09-08 |
IE46689B1 (en) | 1983-08-24 |
DE2811816C2 (en) | 1988-11-10 |
DE2811816A1 (en) | 1979-03-29 |
US4151270A (en) | 1979-04-24 |
CH633166A5 (en) | 1982-11-30 |
IE780587L (en) | 1979-03-26 |
IT7848470A0 (en) | 1978-03-16 |
GB1582499A (en) | 1981-01-07 |
NL7803145A (en) | 1979-03-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA1095319A (en) | Chewing gum composition | |
US4088788A (en) | Saliva stimulating chewing gum composition | |
US5698215A (en) | Chewing gum composition with fluoride and citric acid | |
CA1334806C (en) | Sweetness and flavor enhanced compositions and method of preparing such compositions | |
US5002759A (en) | Oligosaccharide inhibition of Streptococcus pyogenes adhesion | |
CA2246730C (en) | Confections containing sweetener | |
US5266306A (en) | Oral composition | |
EP0009325A1 (en) | Erythritol cointaining anti-caries compositions | |
Linke et al. | Black tea extract and dental caries formation in hamsters | |
US5585110A (en) | Chewing gum composition with fluoride and citric acid | |
EP0431376A1 (en) | Hard confections containing hydrogenated isomaltulose and a medicinally active ingredient | |
RU2240016C2 (en) | Chewing gum including polyphosphate in the form of particles | |
US4568537A (en) | Dental health method employing chewing gum | |
EP1397050B1 (en) | Chewing gum to control malodorous breath | |
EP0328849B1 (en) | Use of a racemic mixture of alpha-D-glucopyranosyl-1-6-mannitol and alpha-D-glucopyranosyl-1-6-sorbitol in a sugarless low-moisture absorbing chewing gum composition | |
CA1210702A (en) | Method and composition to inhibit the growth of streptococcus mutans by the use of saccharin/fluoride combination | |
AU2002344797A1 (en) | Chewing gum to control malodorous breath | |
US4374122A (en) | Method of reducing dental caries | |
KR100513117B1 (en) | Toy for protecting an oral cavity and a teeth of a pet animal | |
CA2188387C (en) | Hard candy with tooth plaque-neutralizing effect | |
JP2912481B2 (en) | Chewing gum | |
KR100357046B1 (en) | Manufacturing method of dental floss using powder flavor and sugar alcohol | |
US11813229B2 (en) | Teeth cleaning composition | |
WO2006126657A1 (en) | Sugarless chewing gum | |
CZ279984B6 (en) | Dry mixture for preparing beverages based on whey |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
MKEX | Expiry |