CA1074939A

CA1074939A - Adhesives

Info

Publication number: CA1074939A
Application number: CA252,506A
Authority: CA
Inventors: Heinz H. Dickmann; Dieter Hechenberger; Richard Krattner
Original assignee: Lingner and Fischer GmbH
Current assignee: Lingner and Fischer GmbH
Priority date: 1975-09-10
Filing date: 1976-05-13
Publication date: 1980-04-01
Also published as: DE2620721C2; ZA762870B; IT1065978B; FI64389B; SE425503B; ATA347476A; IE42812B1; CH603779A5; FR2323750A1; AT349591B; SE7605246L; AR206964A1; IE42812L; FR2323750B1; FI761352A; IL49552A0; GR60622B; DE2620721A1; IL49552A; FI64389C

Abstract

ABSTRACT OF THE DISCLOSURE

An improved adhesive composition is disclosed which contains at least one adhesive polymer, at least one non-toxic volatile solvent or liquid dispersant for the adhesive polymer and a gelling agent for the solvent or dispersant in an amount sufficient to reduce the tendency of the solution or dispersion to flow under the influence of gravity, the gelling agent being a salt of a compound of formula (I):-

Description

~074~?39 This ir.vention re~ates to adhesive compositions which contain gelling agents. More particularly the invention relates to self supporting adhesive compositions and to gelled liquid adhesives, the latter having little or no tendency to run or "tail". In the compositions of this invention, the gelling agent is a salt of a monoamide of terephthalic acid.

Adhesive compositions are in widespread industrial, domestic and office use. By their very nature, they can be unpleasant and difficult to handle when used unskillfully. Consequently manufacturers of adhesives, especially for domestic or office ` use, have tried to formulate their compositions so as to make them as convenient as possible to handle and use, and to minimise the risk of accidental spillage on or contact with surfaces other than the work surface.
. 1 In the home or office, by far the most widely used type of ~, adhesive composition has been a solution or dispersion of an ;~ adhesive polymer in a volatile liquid vehicle. Unfortunately, because such compositions are liquid, they are also the most difficult to control in use. They tend to run when applied to . 20 inclined surfaces; they have a tendency to form strands or "tails" when the applicator (usually a squeezable tube or a ,- bottle with a flexible dispensina nozzle) is withdrawn from the work surface; they tend to run out of such applicators when ' left uncapped or otherwise carelessly on the workbench.
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1074~39 Since the majority of the above difficulties arise because the composition is a flowable liquid, attempts have been made to overcome them by thickening or gelling the liquid to the point where it is no longer spontaneously flowable.
5 However, the adhesive properties of a polymer depend quite critically on intimate contact between the two surfaces to be joined and the intermediate polymer film. Any extraneous materials present in the film tend to have an anti-adhesive effect. Hence the proposed addition of a s 10 gelling agent to the uncomplicated basic system of polymer plus volatile solvent is always approached with caution, and with careful evaluation of the effect of the proposed gelling agent on the adhesion characteristics of the composition. Very many of ~he gelling agents used in areas of technology outside the adhesives area are unsuitable, for example because they intrinsically are incompatible ` with the adhesive polymer, or because they must be used in too high a concentration and thus destroy adhesion, or because they adversely affect drying-out time, or because $ 20 they do not gel the solvent system in question.

In spite of these fundamental problems over the choice of a suitable gellant, formulations have been proposed which are in the form of an adhesive stick or crayon which is rubbed onto the work suface, and leave behind an effective adhesive film.

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These proposcd adhesive sticks are either dispersions of the adhesive polymer in a waxy solid base or gelled solutions ; or dispersions of the adhesive in a normally liquid vehicle.
The latter cases have normally required at least 10% and S more usually at least 15% of the gellant to achieve the desired stick consistency. In addition, the previously proposed gellants, particularly fatty acid salts have a small but noticeable anti-adhesive effect.
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This invention is based on the discovery that certain derivatives of terephthalic acid can be used in relatively , small quantities to gel solutions or dispersions of adhesive i polymers without a marked anti-adhesive effect.

3 Accordingly, the present invention provides an adhesive composition comprising at least one adhesive polymer, at ~-~ 15 least one non~toxic volatile solvent or liquid dispersant , for the adhesive polymer and a gelling agent for the x~ solvent or dispersant in an amount sufficient to reduce the tendency of the solution or dispersion to flow under the influence of gravity, characterised in that the gelling agent is a salt of a compound of formula (I):-~OOC ~ C0 ~

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~ ~074939 wherein R is hydrogen or a Cl 18 alkyl group and Rl is a Cl_l8 hydrocarbon group.

Preferably R is hydrogen and Rl is a C4 16 alkyl group.

Suitable salts of the compounds of formula (I) include alkali metal, alkaline earth metal, ammonium and substituted ammonium salts. Particularly suitable salts include the sodium, potassium and ammonium salts, the sodium salt being preferred.

Compounds of formula (I) are described and their gellant j 10 properties referred to in Industrial and Engineering 7 ~ Chemistry, Vol. 49, No. 10, October 1957, 1691~1694 and in N.L.G.I. Spokesman, 20, No. 11, February 1957, 10-15. There is nothing in these publications which suggests the use of these compounds in adhesives compositions~

In the compositions of the invention the adhesive polymer may be selected from those conventionally used in the preparation of adhesive sticks and liquid adhesives.
Suitable adhesive polymers include polyvinyl acetate, polyvinylalcohol, polyvinyl chloride, polyvinylpyrrolidone, polyurethane, polyacrylic acid or polymethacrylic acid of esters thereof, polyacrylamides, methyl cellulose, ethoxylated starch derivativ~s ~nd the like.

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iO749~9 The liquid base present in the compositions o~ the invention will de~end to some ex~ent Oll the identity of the adhesive !polymer to be used, and to some extent on whether the composition is to be in the Eorm of a solld qelled stick or a gelled but flowable liquid. In most cases the liquid ' I
base will be a blend of solvents chosen to give the required drying rate and the required solubility or dispersive characteristics. Water will normally be a major co~ponent of a stick composition, and mixtures of water and lower alcohols such as methanol, ethanol and glycerine are sometimes useful liquid bases for sticks.
' ,For a more flowable composition the liquid ~ase will 'r, l normally be a mixture of solvents of intermediate polarity.
Solvents which have been used in stick and liquid adhesives in the past include water, lower alcohols, low molecular weight esters and ketones. Mixtures of two or more of the following have been used: water, glycerine, methanol, ethanol, isopropanol, ethylene glycol, methylacetate, ethylacetate, butyl acetate, dibutylphthalate, cyclohexanone, ~20 acetone, methylethylketone and methylisobutylketone.
.~The choice of solvent will also depend on the gelling agent employed.
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Long chain compounds of formula (I) ~R1 and/or R~10 carbon atoms) tend to be relatively insoluble in water and non-aqueous solvent systems may be necessary if highly rigid sticks are desired. Short chain compounds (Rl and/or R <3) àre very soluble in water and may therefore be uneconomic in aqueous solvent systems.

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., 1C~74~39 Small amounts of emulsifiers or disperslng agents may be necessary in certain cases to ach:Leve a homogeneous mix.

! Normally the compositions of the invention wlll contain 5% to 50%
of the adhesive polymer, usually from 10% to 40% and very often from 15% to 30%.

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' ` 16)74939 The concentration of the gelling agent will be chosen according to the required degree of gelling. Smaller amounts, for example from 0.1 to 2%,will normally be sufficient to gel a liquid adhesive to the point where its tendency to run and "tail" is substantially eliminated. Larger amounts, e.g. from 2.5% to 10~, but sometimes as much as 10 to 25%,may be used in the preparation of adhesive sticks.
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We have found that the inclusion of an ionic compound in the compositions of the invention which contain large I amounts of water is beneficial in that it enhances the stability of the composition. Although the mechanism is ,, .
not fully understood, it is believed that the ionic ~ compound produces a certain "salting out" effect which ; 15 increases the gelling temperature. I
.. 1 Suitable ionic compounds for inclusion in such compositions include NaCl, XCl, NH4Cl, Na2SO4 and other stable, water-soluble ionic salts.
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' We have preferred to include sodium chloride in our self-20 supporting adhesive compositions.

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Normally such ionic compounds are present by from 2~ to 15% of the final composition, more usually from 5% to 10%

$ and preferably at about 7~ to 8% by weight of the composition.

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- 107~ 9 The sel~-supportin~adhesive compositions of this invention may be prepared by blending the ingredients and heating (generally to 60-90C) either during or after blending.
If desired or if more convenient the free acid of formula ' 5 (I) above may be converted in situ into the desired salt to act as gelling agent by the addition of a base, such as sodium, potassium or ammonium hydroxide during blending.
When a homogeneous melt has been prepared it may then be left to cool. During cooling it is best to avoid any ;~ 10 substantial agitation of the mixture. Sticks may be ~ made by cooling the mix in moulds.
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Alternatively, if as is desirable, an ionic compound is to be included in the composition this may be stirred into the mix already formed by blending and heating the other components of the composition. Frequently the addition of this ionic compound alters the gelling point of the composition and so helps bring about solidification.

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Once formed adhesive sticks may be incluaed in a , conventional adhesive applicator such as a screw-up lipstick-type dispenser. Alternatively the homogeneous melt may be poured into such an applicator which can thus also serve as the mould in which the melt solidifies.
For other adhesive compositions the heated mix may be filled into collapsible tubes and allowed to cool in situ.

~ 25 The following Exa~ples illustrate the invention:
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t 1~74~39 '` , An adhesive of the following composition:

Polyvinylpyrrolidone tMol. Wt. 100000) 20~
Glycerine 10%
Sodium-N-EIexylterephthalic acid amide 5%
NaCl 7-5%
Watex 57.5%

was prepared blending together the warmed components. The mix was poured into moulds and on cooling self-supporting sticks were obtained.

' i~ An adhesive of the following composition:
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Polyvinylacetate 30%
Ethanol 24%
Water 0.6%
Methanol 9.9%
Methylacetate 35.25%
Sodium N-tn-octyl~ -Terephthalamide 0.25%
100 . 00%

, was prepared by blending the warmed components. The mix r, was filled into collapsible aluminium tubes, and allowed to cool. An extrudable jelly like composition was obtained which was an effective adhesive with little tendency to run and "tail".
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An adhesive was prepared according to the following formula:-n-octyl-terephthalic acid amide 7%
Water 52%
Glycerine 10%
Sodium hydroxide (30%) 6%
Polyvinylpyrrolidone 25%
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The above ingredients were warmed to a temperature of about 80C, the mixture being blended during warming. The free acid is not ~- very soluble in water but gradually reaction with the sodium i hydroxide converts the acid to the soluble sodium and a homogeneousmix is obtained. The mix was poured into moulds and on cooling, " self-supporting adhesive sticks were obtained.

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x n-octyl-terephthalic acid amide 3.5%
n-hexyl-terephthalic acid amide 3.5%
Glycerine 15~
Polyvinylpyrrolidone \ 25%
Sodium hydroxide (30%) 4.5%
` Water 48.5%
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The procedure was as in Example 3.

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.1 1~37~39 n-octyl-terephthalic acid amide5% t Sodium hydroxide (30%) 5%
1,2 propylene glycol 7%
Glycerine 10%
Polyvinyl alcohol - partially saponified 25%
Water 48%

The procedure was as in Example 3.

n-decyl-terephthalic acid amide3%
1,2 propylene glycol 17% ,~
Polyvinylpyrrolidone 25%
Sodium hydroxide (30%) 5%
Water 50%

The procedure was as in Example 3.

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Claims

THE EMBODIMENTS OF THE INVENTION IN WHICH AN EXCLU-SIVE PROPERTY OR PRIVILEGE IS CLAIMED ARE DEFINED AS FOLLOWS:

1. An adhesive composition comprising at least one adhesive polymer, at least one non-toxic volatile solvent or liquid dispersant for the adhesive polymer and a gelling agent for the solvent or dispersant in an amount sufficient to reduce the tendency of the solution or dispersion to flow under the influence of gravity, characterised in that the gelling agent is a salt of a compound of formula (I):- (I) wherein R is hydrogen or a C1-18 alkyl group and R1 is a C1-18 hydrocarbon group.

2. An adhesive composition as claimed in claim 1 wherein the gelling agent is a salt of a compound of formula (I) wherein R is hydrogen and R1 is a C4-16 alkyl group.

3. A composition as claimed in claim 1 wherein the gelling agent is an alkali metal, alkaline earth metal, ammonium or substituted ammonium salt of a compound of formula (I).

4. A composition as claimed in claim 2 wherein the adhesive polymer is selected from polyvinyl acetate, polyvinyl-alcohol, polyvinyl chloride, polyvinylpyrrolidone, polyurethane, polyacrylic acid or polymethacrylic acid of esters thereof, polyacrylamides, methyl cellulose, and ethoxylated starch derivatives.

5. A composition as claimed in any one of claims 2, 3 or 4 which contains from 5% to 50% by weight of adhesive polymer.

6. A composition as claimed in claims 2, 3 or 4 wherein from 10% to 40% of adhesive polymer is present.

7. A composition as claimed in claims 2, 3 or 4 wherein from 15% to 30% of adhesive polymer is present.

8. A composition as claimed in any one of claims 1 to 3 wherein the gelling agent is present in an amount of from 0.1%
to 2% by weight.

9. A composition as claimed in any one of claims 1 to 3 wherein the gelling agent is present in an amount of from 2.5%
to 10% by weight.

10. A composition as claimed in any one of claims 1 to 3 wherein the gelling agent is present in an amount of from 10%
to 25% by weight.

11. A composition as claimed in claim 1 which includes a water soluble ionic salt.

12. A composition as claimed in claim 11 wherein the ionic salt is sodium, potassium or ammonium chloride or sodium sulphate.

13. A composition as claimed in claim 11 or claim 12 wherein the ionic salt is present in an amount of from 2% to 15% by weight.

14. A composition as claimed in claim 11 or 12 wherein from 5% to 10%
by weight of the ionic salt is present.

15. A composition as claimed in claim 11 or 12 wherein from 7% to 8%
by weight of the ionic salt is present.